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									- - - - - - - - - - - - - - - - MATERIAL SAFETY DATA SHEET - - - - - - - - - - - - - - Roussel UCLAF
NFPA DESIGNATION 704 DEGREE OF HAZARD: 4 = EXTREME HEALTH (BLUE): 2 3 = HIGH FLAMMABILITY (RED): 2 2 = MODERATE REACTIVITY (YELLOW): 1 1 = SLIGHT SPECIAL HAZARD: 0 = INSIGNIFICANT DATE: 3/1/93 ----------------------------------------------------------SECTION I - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION ----------------------------------------------------------PRODUCT NAME: Ford's Diazinon 25% EC PRODUCT CODE NUMBER: N/A CHEMICAL FAMILY: Organophosphate EPA REGISTRATION NUMBER: 10370-038 MANUFACTURER: ROUSSEL UCLAF CORPORATION 95 CHESTNUT RIDGE ROAD MONTVALE, NJ 07645 EMERGENCY TELEPHONE: 1-800-471-0660 ----------------------------------------------------------SECTION II - COMPOSITION/INFORMATION ON INGREDIENTS ----------------------------------------------------------COMPONENT/CAS NO. % EXPOSURE LIMITS (TWA) ----------------------------------------------------------Diazinon 25.0 10 mg/m3 333-41-5 Aromatic Petroleum Solvent 67.0 100 PPM 1330-20-7 Inerts 8.0 ----------------------------------------------------------SECTION III - HAZARDOUS IDENTIFICATION ----------------------------------------------------------EMERGENCY OVERVIEW HEALTH: WARNING. KEEP OUT OF REACH OF CHILDREN. May be fatal if swallowed or absorbed through skin. Avoid breathing vapors or spray mist. Causes substantial but temporary eye damage. Avoid contamination of food and feed stuffs. ENVIRONMENTAL: This product is highly toxic to birds, fish and wildlife. This product is highly toxic to bees exposed to direct treatment, or residues on blooming crops or weeds. POTENTIAL HEALTH EFFECTS: EYE: Causes substantial but temporary eye damage. SKIN: Moderately irritating to the skin. Repeated contact may cause dermal sensitization. May be fatal if absorbed through skin. INGESTION: May be fatal if swallowed. INHALATION: Can cause respiratory irritation. Avoid breathing spray mist. CHRONIC EFFECTS/CARCINOGENICITY: Neurotoxicity and liver damage can result from chronic exposure. Not a carcinogen. SIGNS AND SYMPTOMS: Eye and skin irritation (redness and swelling). Headache, Nausea, Dizziness, Muscle Twitches, Vomiting, Cramps, Sweating. Extreme overexposure may cause unconsciousness, convulsions and respiratory depression. ----------------------------------------------------------SECTION IV - FIRST-AID MEASURES ----------------------------------------------------------EYE: Rinse eyes with copious amounts of water or at least 15 minutes. Contact physician immediately. SKIN: Wash with soap and warm water. Rinse thoroughly. Remove contaminated clothing. Get medical attention if irritation persists. INGESTION: Call a physician immediately. DO NOT INDUCE VOMITING UNLESS NO OTHER TREATMENT IS AVAILABLE. Vomiting may cause aspiration pneumonia. If it is necessary to induce vomiting, give victim one or two glasses of water and insert finger in back of throat. Do not induce vomiting or give anything by mouth if a person is unconscious or convulsing.

INHALATION: Remove to fresh air and apply artificial respiration if indicated. Get medical attention. NOTES TO PHYSICIAN: Diazinon is a cholinesterase inhibitor. If symptoms of cholinesterase inhibition are present, Atropine Sulfate by injection is antidotal. 2-PAM is also antidotal and may be administered, but only in conjunction with Atropine. This product contains an Aromatic Petroleum Solvent which may present an aspiration hazard. Gastric lavage may be indicated if the product was taken internally. Never give opiates or phenothiazine tranquilizers. Do not allow re-exposure to any cholinesterase inhibitors until cholinesterase regeneration has taken place as evaluated by appropriate blood tests. MEDICAL CONDITIONS AGGRAVATED BY OVEREXPOSURE: Exposure to cholinesterase inhibitors should be restricted in persons with hemolytic anemia or pre-existing depression of cholinesterase. ----------------------------------------------------------SECTION V - FIRE-FIGHTING MEASURES ----------------------------------------------------------FLASH POINT: 107 deg F TCC FLAMMABLE LIMITS (% by volume): N/A AUTOIGNITION TEMPERATURE: N/A DECOMPOSITION TEMPERATURE: N/A FIRE EXTINGUISHING MEDIA: CO2, Foam, Water Mist PERSONAL PROTECTIVE EQUIPMENT: Use Self Contained Breathing Apparatus. Wear full Protective Clothing including boots. FIRE CONTROL TACTICS: Keep unnecessary people away. Use water spray or fog to cool containers. A solid stream may cause material and contaminated water to spread. Dike area of fire to prevent or control run-off. Do not allow run-off to enter sewer systems or any body of water. If run-off does enter sewer system or body of water, contact the appropriate authorities immediately. Stay up-wind of smoke and vapors. Do not decontaminate personnel, equipment, or handle broken packages or containers without wearing the specified protective equipment and clothing. Decontaminate emergency personnel with soap and water before leaving the fire area. ----------------------------------------------------------SECTION VI - ACCIDENTAL RELEASE MEASURES ----------------------------------------------------------SPILLS OR LEAKS: Wear prescribed safety equipment including protective boots. Soak up spill with absorbent material. Sweep or shovel spilled material into approved disposal container. Do not allow material to enter sewer systems or any body of water. Contact appropriate authorities immediately if material enters sewer system or body of water. Check local, state and Federal regulations before disposing of spilled material. ----------------------------------------------------------SECTION VII - HANDLING AND STORAGE INFORMATION ----------------------------------------------------------Wear gloves, eye protection, wear long sleeves and pants and other necessary protective clothing. Handle in well ventilated area, otherwise use NIOSH approved respirator for pesticides. Do not smoke, eat or drink in area where product is handled or stored. Do not contaminate water, food or feedstuff by storage or disposal. DO NOT store or handle near open flame or other ignition or heat source.

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- - - - - - - - - - - - - - - - MATERIAL SAFETY DATA SHEET - - - - - - - - - - - - - - Roussel UCLAF
----------------------------------------------------------SECTION VIII - EXPOSURE CONTROLS/PERSONAL PROTECTION ----------------------------------------------------------* Wear NIOSH approved pesticide respirator in poorly ventilated areas. * Long sleeves, pants and gloves should be worn to prevent contact with skin. * Safety glasses or goggles should be worn to prevent contact with eyes. * Wash thoroughly immediately after exposure. Smoking, eating and drinking should not be permitted before washing. * Wash contaminated clothing with soap and water before reuse. ----------------------------------------------------------SECTION IX - PHYSICAL AND CHEMICAL PROPERTIES ----------------------------------------------------------APPEARANCE AND ODOR: Light Straw Color Liquid. Distinctive Odor. BOILING POINT: N/A MELTING POINT: N/A VAPOR PRESSURE: N/A SPECIFIC GRAVITY: 0.90 FREEZING POINT: N/A % VOLATILE (by volume): N/A OCTANOL/H2O PARTITION COEFF.: N/A pH: N/A SATURATION IN AIR (by volume): N/A EVAPORATION RATE: N/A SOLUBILITY IN WATER: 100% ----------------------------------------------------------SECTION X - STABILITY AND REACTIVITY INFORMATION ----------------------------------------------------------STABILITY: Stable under normal conditions. HAZARDOUS POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: Avoid temperature extremes. INCOMPATIBLE MATERIALS: None under normal conditions. HAZARDOUS DECOMPOSITION PRODUCTS: SO2, NOx, CO2, CO, Aliphatic Organophosphates. ----------------------------------------------------------SECTION XI - TOXICOLOGICAL INFORMATION ----------------------------------------------------------1. ROUTES OF EXPOSURE: NO DATA ARE AVAILABLE FOR THIS FORMULATION EYE CONTACT: Causes substantial but temporary eye damage. SKIN CONTACT: Slightly Irritating [Diazinon 87%]. INHALATION: LC50 (Rat) >2.33 mg/l air - 4 hours [Diazinon 87%]. INGESTION: Oral LD50 (Rat) = 1,250 mg/kg [Diazinon 87%]. SKIN ABSORPTION: LD50 (Rabbit) = >2,020 mg/kg [Diazinon 87%]. 2. EFFECTS OF OVEREXPOSURE: ACUTE EXPOSURE: Diazinon is a cholinesterase inhibitor. Overexposure may cause headaches, nausea, dizziness, muscle twitches, vomiting, cramps, and sweating. Extreme overexposure may cause unconsciousness, convulsions, and respiratory depression. CHRONIC EXPOSURE: No long term effects other than symptoms associated with anticholinergic activity at high dose levels occurred in any of the studies conducted with Diazinon. ----------------------------------------------------------SECTION XII - ECOLOGICAL INFORMATION ----------------------------------------------------------AQUATIC AND WILDLIFE TOXICITY DATA: This product is highly toxic to fish and other aquatic organisms. ----------------------------------------------------------SECTION XIII - DISPOSAL CONSIDERATIONS ----------------------------------------------------------Do not reuse empty container. Thoroughly rinse container. Securely wrap in several layers of newspaper and discard in trash. If disposal of a partially full container is necessary, make sure cap is tightly closed, securely wrap the container in several layers of newspaper and discard in trash.

----------------------------------------------------------SECTION XIV - REGULATORY INFORMATION ----------------------------------------------------------SARA TITLE III DATA: SECTION 311 AND 312 HAZARD CATEGORIES: IMMEDIATE HEALTH HAZARD: No DELAYED HEALTH HAZARD: No FIRE HAZARD: Yes REACTIVE HAZARD: No SUDDEN PRESSURE RELEASE HAZARD: No SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES: Not listed SECTION 313 TOXIC CHEMICALS: Not listed CERCLA REPORTABLE QUANTITY: Diazinon 1 lb. This material is not listed as a carcinogen/potential carcinogen by IARC, OSHA or NTP HAZARDOUS MATERIAL IDENTIFICATION SYSTEM (HMIS) RATING: HEALTH: 2 FLAMMABILITY: 2 REACTIVITY: 1 PERSONAL PROTECTION: B ----------------------------------------------------------This information and statements herein are believed to be reliable but are not to be construed as a warranty or representation for which we assume legal responsibility. Users should undertake sufficient verification and testing to determine the suitability for their own particular purpose of any information or products referred to herein. NO WARRANTY OF FITNESS FOR A PARTICULAR PURPOSE IS MADE. ----------------------------------------------------------DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representation as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purpose(s). A request has been made to the manufacturer to approve the contents of this material safety data sheet. Upon receipt a new MSDS will be made available. ----------------------------------------------------------COMPAS Code: 14080041

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