Implant Mask - Henry Schein Halas by jizhen1947

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									Safety Data Sheet according to EC-guideline 2001/58/EC                                                      Page 1/4

Date of print:                   2007-11-14
Date of last alteration:         2007-11-14 - Version: English
Art. -No., product name:         02529 Implant Mask, base + catalyst

1     Identification of the substance / preparation and of the company / undertaking
1.1 Identification of the substance or preparation:
1.1.1 Commercial Product Name:                   Implant Mask
1.1.2 Use:                                       Silicone material for use in dental technology.

1.2   Company / undertaking identification:
      Manufacturer / distributor:                 DETAX GmbH & Co. KG
      Street / POB-No.:                           Carl-Zeiss-Str. 4
      State / postal code / city:                 D-76275 Ettlingen
      Telephone:                                  +49 7243/510-0 Telefax: +49 7243/510-100

2     Composition / information on ingredients
2.1   Chemical characterisation (preparation):    Description: Contains polydimethylsiloxane with functional groups
                                                  + fillers and pigment;
                                                  catalyst additionally: platinum-complex compound.

3     Hazards identification
3.1   Critical hazards to man and environment: Unknown.

4     First aid measures
4.1   General information:                        Remove all contaminated clothing.

4.2   After inhalation:                           No special measures required.

4.3   After contact with the skin:                Wash with plenty of water and soap. In case of persisting irritation
                                                  seek medical advice.
4.4   After contact with the eyes:                Rinse the open eyes immediately with plenty of water for at least
                                                  15 minutes, seek immediately medical advice.
4.5   After swallowing:                           Rinse mouth well with water and drink plenty of water. If you feel
                                                  unwell, seek medical advice.

5     Fire fighting measures
5.1   Suitable extinguishing media:               Water mist, dry powder, foam, carbon dioxide.

5.2   Extinguishing media which must not be used for safety reasons: Unknown.

5.3   Special exposure hazards arising from the substance or preparation itself, combustion products,
      resulting gases:                          Development of hydrogen may cause explosive hydrogen-air-
                                                mixtures.

5.4   Special protective equipment for fire fighting: Use respiratory protection independent of recirculated air.
                                                   Accomplish decontamination by means of explosion-proofed
                                                   equipment.

6     Accidental release measures
6.1   Personal precautions:                       No special precautions required.

6.2   Environmental precautions:                  Observe local byelaws. Keep away from sewage treatment plants
                                                  and in-shore waters.

6.3   Methods for cleaning up:                    Remove mechanically or absorb with liquid binding material (sand,
                                                  diatomaceous earth, sawdust) and dispose of according to
                                                  regulations.

7     Handling and storage
7.1   Handling:
      Precautions for safe handling:              The usual precautions in handling with chemicals are to be
                                                  observed. When using to not eat, drink or smoke.
Safety Data Sheet according to EC-guideline 2001/58/EC                                                                     Page 2/4

Date of print:                             2007-11-14
Date of last alteration:                   2007-11-14 - Version: English
Art. -No., product name:                   02529 Implant Mask, base + catalyst
      Precautions against fire and explosion:                     Take measures against static discharges. Keep away from
                                                                  sources of ignition - No smoking.

7.2   Storage:
      Conditions for storage rooms and vessels: Store in a cool, dry and well-ventilated place. Keep containers
                                                always tightly closed. Provide for sufficient ventilation.
      Advice for storage of incompatible materials: Keep away from acids, lyes, alcohols, metallic powders
                                                 resp. metallic oxides.
      Further information for storage:                            Keep at temperature not exceeding 25 oC / 77 oF.
                                                                  Keep away from humidity.

8     Exposure controls / personal protection
8.1   Further information for system design and engineering measures: No further information.

8.2   Associate substance with specific control parameters such as limit values: No associated substances.

8.3   Personal protection equipment:
      General protection and hygiene measures: The usual precautions in handling with chemicals
                                               are to be observed.
      Respiratory protection:                                     Not required.
      Hand protection:                                            Protective gloves are recommended (such as gloves of nitrile
                                                                  rubber, but never use latex gloves!).
      Eye protection:                                             To avoid mechanical injuring of the eyes wear protective goggles.

9     Physical and chemical properties
9.1   Appearance:
      Form:      paste
      Colour:    base: orange-brown                     catalyst: rose
      Odour:     faintly typical

9.2   Safety parameters:                                                                                Method (67 / 548 / EC)
      Flash point ......................................: =          > 100 oC/212 oF                               DIN 51755
      Inflammability ....................................:           not available
      Ignition temperature ..........................: =             > 400 oC/752 oF                               DIN 51794
      Autoflammability................................:              not available
      Oxidising properties ..........................: =             Increased temperatures advance the release of hydrogen.
      Explosive properties..........................:                not available
      Explosion limits .................................:            not available
      Vapour pressure ...............................: =             < 20 hPa at 20 oC/68 oF
      Density ..............................................: =      approx. 1.05 g/cm³ at 20 oC/68 oF             DIN 51757
      Solubility in water ..............................: =          virtually insoluble
      pH-value............................................:          n.a.
      Distribution coefficient octanol / water:                      not available
      Viscosity ............................................: =      approx. 18 000 mPa.s at 23 oC/73 oF          Brookfield

9.3   Further information:
      Thermal decomposition ....................: =                  > 180 oC/356 oF

10    Stability and reactivity
10.1 Conditions to avoid:                                         Temperatures > 150 oC/302 oF.

10.2 Materials to avoid:                                          Acids, lyes, alcohols, metallic powders resp. metallic oxides.

10.3 Hazardous decomposition products:                            In case of thermic decomposition hydrogen is released.
                                                                  At a temperature of approx. 150 oC/302 oF a small amount of
                                                                  formaldehyde can be released by oxidative degradation.
Safety Data Sheet according to EC-guideline 2001/58/EC                                                     Page 3/4

Date of print:                       2007-11-14
Date of last alteration:             2007-11-14 - Version: English
Art. -No., product name:             02529 Implant Mask, base + catalyst

11    Toxicological information
11.0 General information:                           According to present experience, the material shows no health
                                                    risk if handled appropriately.

11.1 Acute toxicity:
     Acute oral toxicity (LD50):                    species rat           > 5000 mg/kg
                                                    origin literature
                                                    these data refer to the polydimethylsiloxane components.

12    Ecological information
12.1 Information on elimination (persistence and degradability):
                                                No data known.

12.2 Behaviour in environmental compartments: No data known.

12.3 Ecotoxicological effects:
     Effects in sewage treatment plants (bacteria toxicity: respiration-/reproduction inhibition):
                                                Do not introduce large amounts into purification plants.

13    Disposal considerations
13.1 Material:                                      Recommendation: Dispose of according to regulations by
                                                    incineration in a special waste incinerator.
                                                    Observe the local byelaws.
      European Waste Catalogue Ref.No.:             07 02 17 (AVV)

13.2 Contaminated packaging:                        Recommendation: Fully empty containers (no tear drops, no
                                                    powder rest, scraped carefully). Containers may be recycled
                                                    or re-used.
                                                    Observe local/national byelaws.

14    Transportation information
14.1 Land transportation ADR/RDI and GGVS/GGVE:
     GGVS/GGVE-class...... :       Non-hazardous material
     ADR/RID-class............. :  Non-hazardous material
     Transportation emergency card number:
     Warning board - Hazard No.:
     Nomenclature............... :
     Further information....... :
     Limited Quantities ........ :

14.2 Inland navigation ADN/ADNR:
     Further information:        Non-hazardous material

14.3 Transportation by sea IMDG/GGVsea:
     IMDG/GGVsea-class .. :           Non-hazardous material
     EmS-No........................ :
     Marine pollutant ........... :
     Proper shipping name.. :
     Technical name............ :
     LTD. QTY. .................... :

14.4 Air transportation ICAO-TI and IATA-DGR transportation by air:
     ICAO/IATA-class.......... :   Non-hazardous material
     Proper shipping name.. :
     Technical name............ :
     Further information:
      Air mail transportation .. :      permitted
Safety Data Sheet according to EC-guideline 2001/58/EC                                                     Page 4/4

Date of print:                  2007-11-14
Date of last alteration:        2007-11-14 - Version: English
Art. -No., product name:        02529 Implant Mask, base + catalyst

15    Regulatory information
15.1 Identification according to EC directives
     Identification letter and hazard indication of the product:
                                                   According to the Regulations for Hazardous Goods and the
                                                   corresponding EC-Guidelines the product is not to be labelled.

15.2 National regulations (Germany):
     Classification of possible adverse effects in the aquatic environment (Wassergefährdungsklasse):
                                                  Class 1 (slight adverse effects in the aquatic environment).

16    Other information
      n.a. = not applicable                       n.s. = not subject to


      The above information describes exclusively the safety requirements of the product(s) and is based on our
      present-day knowledge. It does not represent a guarantee for the properties of the product(s) described in
      terms of the legal warranty regulations.
Safety Data Sheet according to EC-guideline 2001/58/EC                                                        Page 1/4

Date of print:                   2007-11-14
Date of last alteration:         2007-11-14 - Version: English
Art. -No., product name:         02690 Separating Agent

1     Identification of the substance / preparation and of the company / undertaking
1.1 Identification of the substance or preparation:
1.1.1 Commercial Product Name:                   Separating Agent
1.1.2 Use:                                       Liquid for use in dental technology.
1.2   Company / undertaking identification:
      Manufacturer / distributor:                 DETAX GmbH & Co. KG
      Street / POB-No.:                           Carl-Zeiss-Str. 4
      State / postal code / city:                 D-76275 Ettlingen
      Telephone:                                  +49 7243/510-0 Telefax: +49 7243/510-100

2     Composition / information on ingredients
2.1   Chemical characterisation (preparation):    Description: Alkyl silicone resin in organic solvents.
2.2   Substances presenting a health hazard:      Ethyl acetate                Methyl acetate
      Concentration:                              40 - 80%                     10 – 25%
      CAS-No.:                                    141-78-6                     79-20-9
      Identification letter:                      F Xi                         F Xi
      EC/R:                                       11-36-66-67                  11-36-66-67

3     Hazards identification
3.1   Critical hazards to man and environment: Risk phrases: 11-36-66-67
                                               Highly flammable. Irritating to eyes. Repeated exposure may
                                               cause skin dryness or cracking. Vapours may cause drowsiness
                                               and dizziness.

4     First aid measures
4.1   General information:                        Take off immediately all contaminated clothing.
4.2   After inhalation:                           Seek medical advice immediately. Move to fresh air and lay the
                                                  victim restful down, in case of respiratory distress in a half-sitting
                                                  position; in case of unconsciousness but with existing respiration
                                                  in a stable lateral position. As the case may be, give breathe
                                                  donation.
4.3   After contact with the skin:                Wash with plenty of water and soap. In case of persisting irritation
                                                  seek medical advice.
4.4   After contact with the eyes:                Rinse the open eyes immediately with plenty of water for at least
                                                  15 minutes, seek immediately medical advice.
4.5   After swallowing:                           Seek medical advice immediately. Rinse mouth well with water
                                                  and drink plenty of water. Do not induce vomiting.

5     Fire fighting measures
5.1   Suitable extinguishing media:               Water mist, dry powder, foam, carbon dioxide.
5.2   Extinguishing media which must not be used for safety reasons: Water jet.
5.3   Special exposure hazards arising from the substance or preparation itself, combustion products, resulting
      gases:                                    Do not breathe combustion gases.
5.4   Special protective equipment for fire fighting: Use respiratory protection independent of recirculated air.
                                                   Accomplish decontamination by means of explosion-proofed
                                                   equipment.

6     Accidental release measures
6.1   Personal precautions:                       Avoid unprotected exposure. Wear suitable protective clothing.
6.2   Environmental precautions:                  Observe local byelaws. Keep away from sewage treatment plants,
                                                  in-shore waters and earth.
6.3   Methods for cleaning up:                    Absorb with liquid binding material (mica, diatomaceous earth)
                                                  and dispose of according to regulations.
Safety Data Sheet according to EC-guideline 2001/58/EC                                                                     Page 2/4

Date of print:                             2007-11-14
Date of last alteration:                   2007-11-14 - Version: English
Art. -No., product name:                   02690 Separating Agent

7     Handling and storage
7.1   Handling:
      Precautions for safe handling:                               Avoid contact with eyes, skin and clothing.
      Precautions against fire and explosion:                      Take precautionary measures against static discharges. Keep
                                                                   away from sources of ignition - No smoking. Cool endangered
                                                                   containers with water mist.
7.2   Storage:
      Conditions for storage rooms and vessels: Store in a cool, dry and well-ventilated place, away from food-
                                                stuffs. Keep containers always tightly closed. Provide for sufficient
                                                ventilation.
      Advice for storage of incompatible materials: Keep away from combustible materials.
      Further information for storage:                             Keep at temperature not exceeding 25 oC / 77 °F.

8     Exposure controls / personal protection
8.1   Further information for system design and engineering measures:
                                                 Provide for sufficient ventilation/suction system.
8.2   Associate substance with specific control parameters such as limit values
      (Air limits according to TRGS 900):        CAS-No.         Substance                                 mg/m3
                                                 141-78-6        Ethyl acetate                             1500 mg/m3 = 400 ppm
                                                 79-20-9         Methyl acetate                             610 mg/m3 = 200 ppm
8.3   Personal protection equipment:
      General protection and hygiene measures: Take off immediately all contaminated clothing. Do not breathe
                                               vapours.
      Respiratory protection (filter type A):                      Necessary in case of prolonged exposure, insufficient ventilation.
      Hand protection:                                             Use protective gloves. Suitable are gloves of the following
                                                                   material (permeation time ≥ 1 hour):
                                                                   Butyl rubber – Butyl (0,5 mm).
                                                                   Unsuitable are gloves of the following materials:
                                                                   Natural rubber/Natural latex – NR; Polychloroprene – CR; Nitrile
                                                                   rubber/Nitrile latex – NBR; Fluoro carbon rubber – FKM; Polyvinyl
                                                                   chloride – PVC.
                                                                   Textile or leather gloves are completely unsuitable.
      Eye protection:                                              Wear protective glasses / face protection.

9     Physical and chemical properties
9.1   Appearance:
      Form:      liquid
      Colour:    transparent
      Odour:     like esters
9.2   Safety parameters:                                                                                 Method (67 / 548 / EC)
      Change in physical state:
      Boiling point... ...................................: =     66 oC / 151 oF                                     DIN 51356
      Flash point ......................................: =       5 oC / 41 oF                                       DIN 51755
      Inflammability ....................................:        not available
      Ignition temperature ..........................: =          approx. 465 oC / 869 oF                            DIN 51794
      Autoflammability................................:           not available
      Oxidising properties ..........................:            not available
      Explosive properties..........................:             not available
      Explosion limits .................................: =       lower: approx. 2.3 vol.-% upper: approx. 12.4 vol.-%
      Vapour pressure ...............................: =          approx. 124 hPa at 20 oC/68 oF approx. 46 kPa at 50 oC/122 oF
      Density ..............................................: =   approx. 0.93 g/cm³ at 20 oC/68 oF                  DIN 51757
      Solubility in water ..............................: =       sparely miscible
      pH-value............................................:       n.a.
      Distribution coefficient octanol / water:                   not available
      Viscosity ............................................: =   approx. 100 mPa.s at 23 oC/73 oF                   Brookfield
Safety Data Sheet according to EC-guideline 2001/58/EC                                                         Page 3/4

Date of print:                     2007-11-14
Date of last alteration:           2007-11-14 - Version: English
Art. -No., product name:           02690 Separating Agent
9.3   Further information:
      Thermal decomposition ....................:   not available

10    Stability and reactivity
10.1 Conditions to avoid:                            No data available.
10.2 Materials to avoid:                             Reacts violently with strong oxidising agents.
10.3 Hazardous decomposition products:               The following applies for the silicone content of the product: At a
                                                     temperature of approx. 150 oC / 302 °F a small amount of
                                                     formaldehyde can be released by oxidative degradation.

11    Toxicological information
11.0 General information:                            May be irritating to skin and mucous membranes of eyes and
                                                     respiratory system, may cause narcotic effects. In case of
                                                     accidental contact burning of the eyes, tickle in the throat and
                                                     respiratory distress may occur.
11.1 Acute toxicity:
     Acute inhalational toxicity (LCLO):             species mouse          31 g/m3 (2 hours)
                                                     species cat            61 g/m3
                                                     origin: literature
                                                     these data refer to the ingredient ethyl acetate.

12    Ecological information
12.1 Information on elimination (persistence and degradability):
                                                No data known.
12.2 Behaviour in environmental compartments: No data known.
12.3 Ecotoxicological effects:
     Effects in sewage treatment plants (bacteria toxicity: respiration-/reproduction inhibition):
                                                Do not introduce large amounts into purification plants.
12.4 Further ecological information:                 Do not lead into wastewater. Do not introduce into in-shore
                                                     waters and earth.

13    Disposal considerations
13.1 Material:                                       Recommendation: Dispose of according to regulations by
                                                     incineration in a special waste incinerator.
                                                     Observe the local byelaws.
      European Waste Catalogue Ref.No.:              07 02 99 (AVV).
13.2 Contaminated packaging:                         Recommendation: Fully empty containers (no tear drops, no
                                                     powder rest, scraped carefully). Containers may be recycled
                                                     or re-used. Observe local/national byelaws.

14    Transportation information
14.1 Land transportation ADR/RDI and GGVS/GGVE:
     GGVS/GGVE-class...... :       3   cl.-code F1
     ADR/RID-class............. :  3   cl.-code F1
     Transportation emergency card number: 3
     Warning board - Hazard No.: 33             Substance No.: 1866           PG: II
     Nomenclature............... : Resin solution
                                   (Vapour pressure at 50 oC/122 oF not more than 110 kPa)
     Further information....... :  Flammable liquid
     Limited Quantities ........ : LQ6 (5 L / 30 kg)
14.2 Inland navigation ADN/ADNR:
     Further information:        No data available.
14.3 Transportation by sea IMDG/GGVsea:
     IMDG/GGVsea-class .. :      3                   Label 3        UN-No.: 1866      PG: II
Safety Data Sheet according to EC-guideline 2001/58/EC                                                            Page 4/4

Date of print:                            2007-11-14
Date of last alteration:                  2007-11-14 - Version: English
Art. -No., product name:                  02690 Separating Agent
      EmS-No........................ :       F-E, S-E
      Marine pollutant ........... :         no
      Proper shipping name.. :               Resin solution
      Technical name............ :           Flammable liquid
      Flash point ................... :      5 oC c.c.
      LTD. QTY. .................... :       5 L / 30 kg
14.4 Air transportation ICAO-TI and IATA-DGR transportation by air:
     ICAO/IATA-class.......... :      3             UN-No.: 1866     PG: II             Page: 205 (48 edition)
     Proper shipping name.. :         Resin solution
     Technical name............ :     Flammable liquid
     Packing regulations...... :      PAC: 305                 Max. net.: 5 L
                                      CAO: 307                 Max. net.: 60 L
     Excepted Quantities..... :       30 mL / 500 mL
     LTD.QTY. ..................... : 1 L / 30 kg (Y305)
      Air mail transportation... :           not permitted

15    Regulatory information
15.1 Identification according to EC directives:          Identification letters: F Xi Hazard indication: highly flammable,
                                                                                                        irritating
                                                         Contains: Ethyl acetate, methyl acetate.
      EC/R: 11-36-66-67                                  Highly flammable. Irritating to eyes. Repeated exposure may
                                                         cause skin dryness or cracking. Vapours may cause drowsiness
                                                         and dizziness.
      EC/S: 16-26-33                                     Keep away from sources of ignition – No smoking. In case of
                                                         contact with eyes, rinse immediately with plenty of water and
                                                         seek medical advice. Take precautionary measures against
                                                         static discharges.
15.2 National regulations (Germany):
     Classification of possible adverse effects in the aquatic environment (Wassergefährdungsklasse):
                                                  Class 1 (slight adverse effects in the aquatic environment).
      Classification according to VbF:                   AI

16    Other information
      n.a. = not applicable                              n.s. = not subject to


      The above information describes exclusively the safety requirements of the product(s) and is based on our
      present-day knowledge. It does not represent a guarantee for the properties of the product(s) described in
      terms of the legal warranty regulations.

								
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