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					A&L LABORATORIES, INC. • 1001 Glenwood Avenue • Minneapolis, MN 55405 • (612) 374-9141 (800) 225-3832 MATERIAL SAFETY DATA SHEET
1. CHEMICAL PRODUCT IDENTIFICATION Trade Name: LAND O LAKES SENTINEL Chemical Name & Synonyms: DETERGENT - IODINE COMPLEX 2. COMPOSITION/INFORMATION ON INGREDIENTS Hazardous Ingredients/Identity: Hazardous Components: Surfactant-iodine complex Content 5.00% CAS No. N/A ACGIH TLV 0.1 ppm (iodine vapor) OSHA PEL N/A

NOTE: Nonionic surfactant - iodine complex (irritant, providing a minimum of 1.0 % titratable iodine) 3. HAZARD IDENTIFICATION Primary Routes of Entry: Skin contact, eye contact Routes of Entry/Affects of Exposure Inhalation: Dusts or mists can cause irritation of the upper respiratory tract. Skin: Can cause skin irritation. Eyes: Can cause eye irritation. Ingestion: Moderately toxic. May cause gastic irritation, nausea, burning and staining of the mucus membranes, and localized necrosis. Chronic Effects of Exposure: May cause areas of dermatitis. Carcinogenicity: The components in this product are not listed in the IARC, NTP, OSHA, or PA lists of carcinogens. CA Proposition 65: Components of this product may contain traces of ACETALDEHYDE, DIOXANE, ETHYLENE OXIDE, and FORMALDEHYDE, which the state of California has found to cause cancer, birth defects or other reproductive harm. Medical conditions aggravated by exposure: May aggravate existing skin, eye, or respiratory conditions. First Aid Measures Oral Ingestion: DO NOT INDUCE VOMITING! Drink plenty of water or milk. Never give anything by mouth to an unconscious person. Get immediate medical attention. Special Note: NOTE FOR PHYSICIAN: For ingestion cases, gastric lavage with a soluble starch or protein solution will remove iodine from stomach. Further treatment may consist of correcting fluid and electrolyte imbalance. Skin Contact: Flush with water. Remove contaminated clothing and footwear. If irritation occurs or persists, get medical attention. Eye Contact: Flush eyes with plenty of clean, running water. If irritaton occurs, get medical attention. Inhalation: N/A NOTE: Above data estimated from safety data for components. 4. FIRE AND EXPLOSION HAZARD DATA National Fire Prevention Association Hazard Ratings Health Hazard: 2 Flammability Hazard: 0 Reactivity Hazard: 1 Maximum Personal Protection: -Flash Point (ºC): N/A - water base Test Method: N/A Recommended Extinguishing Media: Water, CO2, Foam, Dry Chemical, Earth or Sand Unusual Fire and Explosion Hazards (Conditions to Avoid): None known to A&L Laboratories, Inc. Special Fire Fighting Procedures: Do not direct a solid stream of water or faom into hot, burning pools; this may cause frothing, and increase fire intensity. Use self-contained breathing apparatus and protective clothing.

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5. HANDLING AND STORAGE Handling Precautions: CAUTION! Can cause eye and skin irritations. Protect eyes, skin and clothing from contact with product. Wear recommended protective equipment. Keep container tightly closed when not in use. Wash thoroughly after handling product. Other Precautions: Do not contaminate water or food by the use, storage, or disposal of this product. Keep container tightly closed when not in use. 6. SPECIAL PROTECTION INFORMATION Ventilation Requirements: Local exhaust Recommended personal protective equipment (normal use conditions): EYE PROTECTION - Chemical goggles; SKIN PROTECTION - Rubber gloves, rubber boots and rubber apron. 7. PHYSICAL DATA Appearance: Odor: Available Chlorine: Water Miscibility: Water Solubility: Bulk Density: Boiling Point: Specific Gravity: ph:

Dark brown liquid Iodine N/A Complete Complete N/A 100 degrees C, solvent 1.04 4.0-4.8

8. REACTIVITY DATA Stability under normal conditions: Stable Incompatibility (Materials to Avoid): Base; Other - many metals, ammonia, chlorine releasers Hazardous Decomposition Products - Thermal & Other (List): Thermal - Iodine vapors, carbon oxides. Hazardous Polymerzation: Will not occur. 9. ENVIRONMENTAL INFORMATION STEPS TO BE TAKEN IF MATERIAL IS SPILLED: For small spills, add dry material to contain. For large spills, dike to contain. Wearing recommended protective equipment, remove bulk of liquid. Add dry material to absorb remaining liquid; pick up and containerize spilled material for recover or disposal. Flush spill area with water to eliminate residues. Waste disposal method: This product does not meet the EPA criteria of a hazardous waste as specified in 40 CFR 261. Dispose of product in an approved landfill in accordance with state and local regulations. Dispose of in a licensed hazardous waste disposal facility in compliance with all applicable laws. 10. TRANSPORTATION INFORMATION UN classification must be verified with current packaging UN Information Cleaning, Scouring or Washing Compound Not restricted 1-800-424-9300

Shipping Name: DOT Hazard Classification: Emergency Telephone No:

As the conditions or methods of use are beyond our control, we do not assume any responsibility and expressly disclaim any liability for any use of the material. Information contained herein is believed to be true and accurate but all statements and suggestions are made without any warranty, express or implied, regarding accuracy of the information, the hazards connected with the use of the material or the results obtained from the use thereof. Prepared by: Brian Saben, VP Technical Affairs Date Prepared: October 18, 2005

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