TCEQ Barnett Shale Phase Two Eimssion Calculator Oct 14 2010

Document Sample
TCEQ Barnett Shale Phase Two Eimssion Calculator Oct 14 2010 Powered By Docstoc
					Select form type to navigate to the emission calculator for the source type:

    Company Name:                                                                              Note: Don't forget to enable macros.
    Insert Company and/or site name here.

    Choose form type:

           Blowdown and/or process vents                                                       Throughout this workbook:

           Boilers and Heaters                                                                 ►Input variables into the blue boxes.

           Compressor engines                                                                  ►Emissions will be in the green boxes.

           Flares
           Frac tanks
           Glycol dehydrators                                                                  To be notified of any updates to this workbook:

           Loading
                                                                                               The Barnett Shale Special Inventory list server has been created to distribute
           Piping component fugitive areas
                                                                                               messages about the agency’s special inventory efforts in the Barnett Shale area.
           Separators                                                                          If you haven't already done so, we recommend you subscribe to this list server
                                                                                               to receive any important updates concerning the inventory, including this
           Condensate storage tanks
                                                                                               emission calculator. To do so, you will need to create a profile with the TCEQ’s
           Crude oil storage Tanks                                                             distribution service, GovDelivery.com, so that you can add and manage your
                                                                                               subscriptions. To create a profile or update your current subscriptions, please
           Produced water storage tanks                                                        visit: http://service.govdelivery.com/ service/user.html?code=TXTCEQ.

           Turbines

           Other:

           Non-flare combustive device

    Complete a form for each piece of equipment (listed above) that meets one of the
    following criteria for 2009:
            ◊ Emitted 1 ton or more of NOx,
            ◊ Emitted 1 ton or more of volatile organic compounds (VOC), or
            ◊ Emitted 0.1 tons per year or more of a hazardous air pollutant (HAP)


           If individual pieces of equipment do not meet the requirements listed above, they
           may be omitted from the inventory provided that the total emissions from all such
           ◊ less than 5 tons of NOx,
           ◊ less than 5 tons of VOC, and
           ◊ less than 1 ton of aggregate HAPs

               If the total emissions from the omitted pieces of equipment do not satisfy
               these requirements, report each source starting with the piece of equipment
               with the highest emissions until the total emissions of the remaining omitted
               sources satisfy the above requirements.
VENTING EMISSION CALCULATION (for blowdowns, starter vents, gas operated controllers, etc):                                                                       Back to Workbook Navigation Tab.



Barnett Shale Phase II Identification Information:                                                                           ►Input variables into the blue boxes
Company Name:               Insert Company and/or site name here.                                                            ►Emissions will be in the green boxes.
Blowdown #:
Company's Unique
Identification Number:

                                                                                  Molecular
                                                                                   Weight grams per
                                                                                  (grams/m 100 moles
                                                               mole %                ole)    of gas          weight %
Gas Analysis:                  Nitrogen                                           28.01348             0      #DIV/0!                                        VOC content of total gas sample (VAPOR)
                               CO2                                                 44.0095             0      #DIV/0!                                    VOC weight% = #DIV/0!
                               H2S                                                34.08188             0      #DIV/0!                               VOC weight fraction = #DIV/0!
                               methane (C1)                                       16.04246             0      #DIV/0!                                                 (VOC: total sample)
                               ethane (C2)                                        30.06904             0      #DIV/0!
                               propane (C3)                                       44.09562             0      #DIV/0!                         HAP content of gas sample
                               i-butane (C4)                                       58.1222             0      #DIV/0!                                 Benzene weight% =       #DIV/0!
                               n-butane (C4)                                       58.1222             0      #DIV/0!                                  Toluene weight% =      #DIV/0!
                               i-pentane (C5)                                     72.14878             0      #DIV/0!                            Ethylbenzene weight% =       #DIV/0!
                               n-pentane (C5)                                     72.14878             0      #DIV/0!                                   Xylene weight% =      #DIV/0!
                               n-hexane (C6)                                        86.17              0      #DIV/0!                                 n-hexane weight% =      #DIV/0!
                               heptanes (C7+)*                                      100.2              0      #DIV/0!
                               octanes (C8+)*                                       114.23             0      #DIV/0!
                               nonanes (C9+)*                                       128.26             0      #DIV/0!
                               decanes (C10+)*                                      142.29             0      #DIV/0!
                               benzene                                              78.11              0      #DIV/0!
                               toluene                                              92.14              0      #DIV/0!
                               ethylbenzene                                         106.16             0      #DIV/0!
                               xylenes (M, P, O)                                    106.16             0      #DIV/0!
                               undecanes (C11+)*                                    156.31             0      #DIV/0!
                                          TOTALS:                        0.0000                        0      #DIV/0!

* If the Molecular Weight is available on the gas analysis, enter it above, otherwise, can use the default value, or if                        Molecular Weight of Gas = 0               lb/lb-mole or grams/mole
MW or SG of total sample available on lab analysis, can adjust this value until MW or SG fields (to the right)                                  Specific Gravity of Gas = 0
match the lab analysis.
                                                                                                                                                        1 lb-mole of gas = 379.4832 SCF
                                     Enter Venting Volume per Event (SCF):                   (standard cubic feet)                                            at STP (standard temperature (60°F) and pressure (14.696
                                           Enter number of events per year:                                                                                   psia))


                                                                                     tpy
                                                                                                           Report Total VOC emissions
                                                              VOC emissions:       #DIV/0!                 on Blowdown(s) tab.
                                                                    benzene        #DIV/0!
                                                                      toluene      #DIV/0!                 Report HAP emissions on
                                                                                                           Blowdown(s) tab or HAP
                                                                ethylbenzene       #DIV/0!                 speciation tab if the values are
                                                                                                           greater than or equal to 0.1
                                                                        xylene     #DIV/0!                 tpy.
                                                                 n-hexane (C6)     #DIV/0!
Heater and Boiler Emission Calculations (fueled by natural gas)
                                                                                            Back to Workbook Navigation Tab.

Barnett Shale Phase II Identification Information:                                     ►Input variables into the blue boxes
Company Name:                        Insert Company and/or site name here.             ►Emissions will be in the green boxes.
Heater or Boiler #:
Company's Unique Identification
Number:



    Heater/Boiler rating (MMBtu/hr):

  Rating above is (select from list):            pick from list
              Operating hours/year:
         Fuel Heat Value (Btu/SCF):

             pollutant                    emission factor (lb/MMCF)*           tpy
               VOC                                    5.5                    #DIV/0!
               NOX                                     0                     #DIV/0!

* Emission Factors from AP-42, Chapter 1, Tables 1.4-1 and 1.4-2.
Engine Emission Calculations (fueled by natural gas)
                                                                                                                                                   Back to Workbook Navigation Tab.
Barnett Shale Phase II Identification Information:
Company Name:                       Insert Company and/or site name here.                                                      ►Input variables into the blue boxes

Engine #:                                                                                                                      ►Emissions will be in the green boxes.
Company's Unique
Identification Number:
                                                                                                                               Notes:
                   Horsepower:                                                                                                 The TCEQ preference for emission factor sources:
                                                                                                                               1. Stack test data from the engine
 Fuel consumption (Btu/hp-hr):
                                                                                                                               2. Manufacturer's specification sheet and control specification
   Hours of operation per year:                                                                                                sheet (if control used)
    Type of engine (select from                                                                                                3. AP-42 emission factors
                           list):       pick from list
                                                                                                                               (If no stack testing or manufacturer's emission factors are
                                                                                                                               available, the spreadsheet will automatically use appropriate AP-
                   Engine Load:         pick from list                                                                         42 factors based on the type of engine and load.)


                                                                                                                                           If present, enter the
                                      If available, enter                                                                                     efficiency of any
                                         stack test or                                                                                         control device
                                        manufacturer's         Appropriate                                                                      (ex: catalytic    Annual
                                       emission factor      AP-42 factor (From     emission factor            Uncontrolled    Uncontrolled        converter)     Emissions
                                           (g/hp-hr)        AP-42 Section 3.2)          used         units       lb/hr            tpy                (%)           (tpy)     Contaminant
                            VOC                                   0.0296               0.0296      lb/MMBtu            0.0000       0.0000                         0.000   VOC
                            NOX                                    2.21                 2.21       lb/MMBtu            0.0000       0.0000                         0.000   NOx
                 Formaldehyde                                     0.0205               0.0205     lb/MMBtu            0.0000            0.0000                         0.000    Formaldehyde*
                                                                                                                               * If formaldehyde emissions are greater than or equal to 0.1 tpy,
                                                                                                                               report the emission rate on the Phase II form.



If bold, value is greater than or equal to 0.1 ton and should be included on
the "HAPS >=0.1" Tab in the Barnett Shale Phase II workbook for this piece
of equipment.
                                                            If VOC factor used
                                                          above was a non-AP-
                                    If VOC factor used     42 factor (stack test
                                   above was from AP- or manufacturer), use
                                    42, use this column this column to check
 Hazardous Air Pollutant (HAP): to check for HAPs                for HAPs
1,1,2,2-Tetrachloroethane          Choose Engine Type Choose Engine Type
1,1,2-Trichloroethane              Choose Engine Type Choose Engine Type
1,2,4-Trimethylbenzene             Choose Engine Type Choose Engine Type
1,2-Dichloropropane                Choose Engine Type Choose Engine Type
1,3-Dichloropropene                Choose Engine Type Choose Engine Type
2,2,4-trimethlypentane             Choose Engine Type Choose Engine Type
Acenaphthylene                     Choose Engine Type Choose Engine Type
Acetaldehyde                       Choose Engine Type Choose Engine Type
Acrolein                           Choose Engine Type Choose Engine Type
Benzene                            Choose Engine Type Choose Engine Type
Biphenyl                           Choose Engine Type Choose Engine Type
Carbon Tetrachloride               Choose Engine Type Choose Engine Type
Chloroform                         Choose Engine Type Choose Engine Type
Ethylbenzene                       Choose Engine Type Choose Engine Type
Ethylene Dibromide                 Choose Engine Type Choose Engine Type
Fluoranthene                       Choose Engine Type Choose Engine Type
Methanol                           Choose Engine Type Choose Engine Type
Methylene Chloride                 Choose Engine Type Choose Engine Type
n-Hexane                           Choose Engine Type Choose Engine Type
Naphthalene                        Choose Engine Type Choose Engine Type
Phenanthrene                       Choose Engine Type Choose Engine Type
Phenol                             Choose Engine Type Choose Engine Type
Pyrene                             Choose Engine Type Choose Engine Type
Styrene                            Choose Engine Type Choose Engine Type
Toluene                            Choose Engine Type Choose Engine Type
Vinyl Chloride                     Choose Engine Type Choose Engine Type
Xylene-u                           Choose Engine Type Choose Engine Type
Flare
                                                                                                                                                       Back to Workbook Navigation Tab.
Barnett Shale Phase II Identification Information:                                                                                   Notes:
Company Name:                 Insert Company and/or site name here.                                                                  ►Input variables into the blue boxes
Flare #:                                                                                                                             ►Emissions will be in the green boxes.
Company's Unique
Identification Number:                                                                                                               ► Instructions are shaded.




General Information                                                                                                    Emission Factors
                                                                                                                       Emission Factors from TCEQ Guidance (lb/MMBtu)
(1) What type of flare is
                                            non-steam assisted flare with high Btu stream flared
this? Pick from list.                                                                                                                Non-steam assisted, high Btu                   Steam assisted, high Btu
                                  Emission Factors for Waste Gas Stream(s) (lb/MMBtu)                                                NOx                      0.138                 NOx                    0.0485
                                                   NOx                0.138                                                          Non-steam assisted, low Btu                    Steam assisted, low Btu
                                                                                                                                     NOx                     0.0641                 NOx                     0.068


(2) Is there one or more
continuous pilot streams?                                           Yes
Pick Yes or No. Follow                                                                                                 Emission Factors from AP-42 Table 1.4-1
instructions below.                                                                                                    and 1.4-2 (lb/MMscf)                             Emission Factors from AP-42 Table 1.4-3 (lb/MMscf)
                                    Enter pilot stream information into the boxes in the column for
                                     Stream No. 1 below. If there is more than one continous pilot
                                           stream, please enter it as one combined stream.                                           NOx                      100                   Total VOC                5.5
                                  Emission Factors for Pilot Stream (lb/MMscf)                                                                                                      benzene             2.10E-03
                                                 NOx                  100                                                                                                           toluene             3.40E-03
                                                                                                                                                                                    ethylbenzene               0 none listed
                                                                                                                                                                                    xylene                     0 none listed

(3) Is there an added fuel
                                                                     No
stream? Pick Yes or No.
Follow instructions below.                                                                                                                                                          n-hexane                    1.8

                                   Enter zeros into the boxes in the column for Stream No. 2 below.

                                  Emission Factors for Added Fuel Stream (lb/MMBtu)
                                                NOx                    0


(4) VOC percent                                                      98
destruction efficiency (%)




Stream Information

Stream Sent to Flare No.                1                2           3               4             5           6            7                 8                 9           10              11             12         Total for all
                                                                                                                                                                                                                      Streams
Enter Names of Each                                                                                                     ex: glycol
Stream sent to the flare                             Added                                      ex: glycol ex: amine    unit flash   ex: amine unit flash   ex: truck
Here →                               Pilot(s)         fuel      ex: oil tank   ex: water tank   unit vent unit vent       tank              tank             loading

Annual Volumetric Flow
Rate of Stream (scf/yr)                                                                                                                                                                                                     0

Heat Value of Stream
(Btu/scf)                                                                                                                                                                                                                #DIV/0!

Uncontrolled VOC and HAP                                                                                                ex: glycol                                                                                    Total for all
                                                     Added                                      ex: glycol ex: amine                 ex: amine unit flash   ex: truck
Emissions for each of                Pilot(s)                   ex: oil tank   ex: water tank                           unit flash                                                                         0          Streams
                                                      fuel                                      unit vent unit vent                         tank             loading
these stream                                                                                                              tank
Total VOC Annual Emissions              -                -                                                                                                                                                                  0
benzene Annual Emissions                -                -                                                                                                                                                                  0
toluene Annual Emissions                -                -                                                                                                                                                                  0
ethylbenzene Annual                     -                -                                                                                                                                                                  0
xylene Annual Emissions (tpy)           -                -                                                                                                                                                                  0
n-hexane Annual Emissions               -                -                                                                                                                                                                  0
other HAP (fill in name) Annual         -                -                                                                                                                                                                  0
other HAP (fill in name) Annual         -                -                                                                                                                                                                  0
Flare Total Emissions
                                    Annual
                                   Emissions
                                     (tpy)
NOX                                  0.00
Total VOC                            0.00                     Report NOx and Total VOC on the "Flare(s)" tab in the Phase II workbook.
Benzene                              0.00
Toluene                              0.00
Ethylbenzene                         0.00
Xylene(s)                            0.00                     Report Benzene, Ethylbenzene, Toluene, Xylene(s), and n-hexane and any other HAPs
n-hexane                             0.00                     on the Phase II workbook if they are ≥ 0.1 tpy on the "Flare(s)" tab.
other HAP                            0.00
other HAP                            0.00
Frac Storage Tank

Barnett Shale Phase II Identification Information:
Company Name:                    Insert Company and/or site name here.
Frac Tank#:
Company's Unique
Identification Number:



Tank emissions are made up of 3 different components, working, breathing and flash losses.

Using EPA TANKS 4.0 Software to calculate Working and Breathing losses

     Working and Breathing Losses

     EPA TANKS 4.0
     This software is available for download at www.epa.gov/ttn/chief/software/tanks/index.html




                                                 Working                                    Breathing


     VOCs, C3+
     Benzene
     Toluene
     E benzene
     Xylenes
     n-hexane
     2,2,4 - Trimethylpentane
     Any Additional HAP (if applicable):




Using E&P TANKS 4.0 Software to calculate Working and Breathing losses
     E&P Tanks (accounts for working, breathing and flash losses).
     This software can be purchased from www.global.ihs.com
     Component                         Controlled Emissions [ton/yr]

     VOCs, C3+
     Benzene
     Toluene
     E benzene
     Xylenes
     n-C6
     224Trimethylp
                                                                     Back to Workbook Navigation Tab.

                                     Notes:
                                     ► Enter variables into blue boxes
                                     ► Emissions will be in green boxes




hing and flash losses.




         Flash losses                                                     Total Emissions
         Valid Methods for Condensate (Use one of the
         following accepted methods):
               Direct Measurement of Emissions
               Process Simulator Models
               the gas/oil ratio (GOR) method

                Flash losses


         VOCs, C3+                                                        VOCs, C3+                         0.0000
         Benzene                                                          Benzene                           0.0000
         Toluene                                                          Toluene                           0.0000
         E benzene                                                        E benzene                         0.0000
         Xylenes                                                          Xylenes                           0.0000
         n-hexane                                                         n-C6                              0.0000
         2,2,4 - Trimethylpentane                                         2,2,4 - Trimethylpentane          0.0000
         Any Additional HAP (if applicable):                              Any Additional HAP (if applicable):
                                                                                                            0.0000
                                                                                                            0.0000
                                                                                                            0.0000
                                                                                                            0.0000




                                                                          Annual Emissions           tons per year

                                                                          VOCs, C3+                        0.0000
                                                                          Benzene                          0.0000
                                                                          Toluene                          0.0000
                                                                          E benzene                        0.0000
                                                                          Xylenes                          0.0000
                                                                          n-C6                             0.0000
                                                                          2,2,4 - Trimethylpentane         0.0000
Report VOC emissions on
Frac Tank(s) Tab.




Report HAP emissions on
Frac Tank(s) tab or HAP
speciation tab if the values
are greater than or equal to
0.1 tpy.




Report VOC emissions on
Frac Tank(s) Tab.



Report HAP emissions on
Frac Tank(s) tab or HAP
speciation tab if the values
are greater than or equal to
0.1 tpy.
Glycol Dehydrator Emission Calculations

Company Name:                                Insert Company and/or site name here.
Still#:

Company's Unique Identification Number:


There are two options that are used most commonly to determine the emissions from a glycol dehydrator.
Please chose the option you prefer:
                             • GRI-GLYCalc Software Program
                             • Rich/Lean Analysis

GRI-GLYCalc Program
Run the software program making sure to using a wet gas analysis for your input. This analysis should include an extended gas

The total emissions for a glycol dehydrator should include both the "Controlled Regenerator Emissions" or "Uncontrolled Regene
present and if the flash tank is not 100% controlled with the recycled/recompression option). By reviewing the GRI-GLYCalc Ag
emissions.
Click to see example reports:
                              Controlled regenerator with flash tank
                              Uncontrolled regenerator with flash tank
                              Uncontrolled regenerator vent with a flash tank with recycle/recompression option


     Uncontrolled/ Controlled Regenerator Emissions                                 Flash Gas Emissions
Component                                      tpy                      Component
Propane                                                                 Propane
Isobutane                                                               Isobutane
n-butane                                                                n-butane
Isopentane                                                              Isopentane
n-pentane                                                               n-pentane
cyclopentane                                                            cyclopentane
n-hexane                                                                n-hexane
cyclohexane                                                             cyclohexane
other hexanes                                                           other hexanes
heptanes                                                                heptanes
methylcyclohexane                                                       methylcyclohexane
2,2,4 Trimethylpentane                                                  2,2,4 Trimethylpentane
Benzene                                                                 Benzene
Toluene                                                                 Toluene
Ethylbenzene                                                            Ethylbenzene
Xylene(s)                                                               Xylene(s)
C8+ Heavies                                                             C8+ Heavies
Total VOC                                                               Total VOC




Rich/Lean Analysis

Using a laboratory analysis of enriched and lean glycol samples that includes benzene, toluene, ethylbenzene and xyle
following information.
Glycol recirculation rate (gal/min)
Annual hour of operation (hr)

Component                      Rich (mg/L)         Lean (mg/L)      tpy
Total VOC                                                              0.00
n-hexane                                                               0.00
2,2,4 Trimethylpentane                                                 0.00
Benzene                                                                0.00
Toluene                                                                0.00
Ethylbenzene                                                           0.00
Xylene(s)                                                              0.00
Additional HAPs
                                                                        0.00
                                                                        0.00
                                                                        0.00
                                                                        0.00

Equation used in Rich/Lean Analysis:

(Crich - Clean) * Qrecirc * t * 3.785 L/gal * 60 min/hr * lb/453,600 mg * ton/2,000 lb = tpy

Where:
Crich = concentration of the contaminant in rich sample
Clean = concentration of the contaminant in lean sample
Qrecirc = glycol recirculation rate (gal/min)
t = annual hours of operation
                                                                    Back to Workbook Navigation Tab.

                                             Notes:
                                             ► Enter variables into blue boxes

                                             ► Emissions will be in green boxes
                                             ► Instructions for using this form.
ycol dehydrator.




nalysis should include an extended gas analysis that includes but not limited to BTEX.

or Emissions" or "Uncontrolled Regenerator Emissions" and the "Flash Gas Emissions" (if the flash tank is
n). By reviewing the GRI-GLYCalc Aggregate Calculations report you will be able to determine your total




ecompression option


ash Gas Emissions                                    Total Glycol Still Emissions
                      tpy                    Component                         tpy
                                             Total VOC                          0
                                             Benzene                            0
                                             Toluene                            0
                                             Ethylbenzene                       0
                                             Xylene(s)                          0
                                             2,2,4 Trimethylpentane             0
                                             n-hexane                           0




zene, toluene, ethylbenzene and xylene(s), complete the
ading Emission Calculations                                                                                                      Back to Workbook Navigation
on LL = 12.46* SPM/T from AP-42, Chapter 5, Section 5.2-4

e Phase II Identification Information:                                                                                                                Notes:
                        Insert Company and/or site name here.                                                                                         ► Enter variables into blue boxes
                                                                                                                                                      ► Emissions will be in green boxes

                                                                                                                                                      ► Use these cells to convert data, completion is optional.
for your convenience (completion is optional)

                           T                             Enter Barrels
                     Temperature in                      of Liquid per      Gallons of liquid
                      Rankine (°R):                           year              per year:
                         459.67                                                     0

                                                                                                                                                                                                                                                         List additional HAPs if present and
                                                                                                                                                                                           Composition of Material Loaded                                percentages:

                         Saturation                                                                                                                        Total VOC
                     Factor (S) (See     True Vapor        Molecular                              Annual Loading       Control Efficiency (%)*        Percentage (This should
                      below table for    Pressure (P)      Weight (M)        Temperature in             Rate            See discussion below before    be 100% unless produced
                      list of options)      (psia)        (lb/lb-mole)        Rankine (°R)         (gallons/year)         applying an efficiency.        water is being loaded)   % Benzene      % Ethylbenzene       % Toluene % Xylene(s) % n-Hexane
                                                                                                                                    0                            100
                                                                                                                                    0                            100
                                                                                                                                    0                            100
                                                                                                                                    0                            100
                                                                                                                                    0                            100
                                                                                                                                    0                            100
                                                                                                                                    0                            100
                                                                                                                                    0                            100
                                                                                                                                    0                            100
                                                                                                                                    0                            100
                                                                                                                                    0                            100
                                                                                                                                    0                            100
                                                                                                                                    0                            100


                            tpy
                          0.0000                        Report VOC emissions on "Loading" Tab.
                          0.0000
                          0.0000
                          0.0000                        Report Benzene, Ethylbenzene, Toluene, Xylene, and n-hexane on the Phase II
                          0.0000                        calculator if they are greater than 0.1 tpy on the "Loading" tab.
                          0.0000

                          0.0000
                          0.0000                        Report any Additional HAPs if they are greater than or equal to 0.1 tpy.
                          0.0000


                     Note: According to AP-42, 5.2-6, if a control is being claimed (such as from a VRU or flare), even though the control device may have a very high efficiency, not all the truck vapors actually get there (due to leaks).
                     See the following for control limitations:
                     Can assume 99.2% of loading emissions get to control device if tanker truck passes the MACT-level annual leak test (not more than 1 inch water column pressure change in 5 minutes after pressurizing to 18 inches
                     Can assume 98.7% of loading emissions get to control device if tanker truck passes the NSPS-level annual test (3 inches pressure change)
                     Otherwise, can only assume 70% of loading emissions reach the control device.
Fugitives Emission Calculations
                                                                                                                                        Back to Workbook Navigation Tab.
Complete this form for each type of each stream type.

Barnett Shale Phase II Identification Information:                                                                                Notes:
Company Name:                Insert Company and/or site name here.                                                                ►Input variables into the blue boxes
Fugitive Area #:                                                                                                                  ►Emissions will be in the green boxes.
Company's Unique
Identification Number:


Gas Analysis:

                                                                                            Molecular      grams per
                                                                                             Weight        100 moles
                                                                          mole %          (grams/mole)       of gas  weight %
                               Nitrogen                                                     28.01348                0   #DIV/0!                   VOC content of hydrocarbon fraction only (VAPOR)
                               CO2                                                           44.0095                0   #DIV/0!                  VOC weight% =      #DIV/0!
                               H2S                                                          34.08188                0   #DIV/0!             VOC weight fraction =      #DIV/0!
                               methane (C1)                                                 16.04246                0   #DIV/0!                                     (VOC:THC)
                               ethane (C2)                                                  30.06904                0   #DIV/0!
                               propane (C3)                                                 44.09562                0   #DIV/0!        HAP content of gas sample
                               i-butane (C4)                                                 58.1222                0   #DIV/0!              Benzene weight% =         #DIV/0!
                               n-butane (C4)                                                 58.1222                0   #DIV/0!              Toluene weight% =         #DIV/0!
                               i-pentane (C5)                                               72.14878                0   #DIV/0!         Ethylbenzene weight% =         #DIV/0!
                               n-pentane (C5)                                               72.14878                0   #DIV/0!               Xylene weight% =         #DIV/0!
                               n-hexane (C6)                                                   86.17                0   #DIV/0!             n-hexane weight% =         #DIV/0!
                               heptanes (C7+)*                                                 100.2                0   #DIV/0!
                               octanes (C8+)*                                                 114.23                0   #DIV/0!
                               nonanes (C9+)*                                                 128.26                0   #DIV/0!
                               decanes (C10+)*                                                142.29                0   #DIV/0!
                               benzene                                                         78.11                0   #DIV/0!
                               toluene                                                         92.14                0   #DIV/0!
                               ethylbenzene                                                   106.16                0   #DIV/0!
                               xylenes (M, P, O)                                              106.16                0   #DIV/0!
                               undecanes (C11+)*                                              156.31                0   #DIV/0!
                                                         TOTALS:                 0.0000                             0   #DIV/0!
* If the Molecular Weight is available on the gas analysis, enter it above, otherwise, can use the default value.

Liquids Analysis:

                                                                                            Molecular      grams per
                                                                                             Weight        100 moles
                                                                          mole %          (grams/mole)       of gas  weight %
                               Nitrogen                                                     28.01348                0   #DIV/0!                   VOC content of hydrocarbon fraction only (LIQUIDS)
                               CO2                                                           44.0095                0   #DIV/0!                  VOC weight% =      #DIV/0!
                               H2S                                                          34.08188                0   #DIV/0!             VOC weight fraction =      #DIV/0!
                               methane (C1)                                                 16.04246                0   #DIV/0!
                               ethane (C2)                                                  30.06904                0   #DIV/0!
                               propane (C3)                                                 44.09562                0   #DIV/0!        HAP content of gas sample
                               i-butane (C4)                                                 58.1222                0   #DIV/0!              Benzene weight% =         #DIV/0!
                               n-butane (C4)                                                 58.1222                0   #DIV/0!              Toluene weight% =         #DIV/0!
                               i-pentane (C5)                                               72.14878                0   #DIV/0!         Ethylbenzene weight% =         #DIV/0!
                               n-pentane (C5)                                               72.14878                0   #DIV/0!               Xylene weight% =         #DIV/0!
                               n-hexane (C6)                                                   86.17                0   #DIV/0!             n-hexane weight% =         #DIV/0!
                               heptanes (C7+)*                                                 100.2                0   #DIV/0!
                               octanes (C8+)*                                                 114.23                0   #DIV/0!
                               nonanes (C9+)*                                                 128.26                0   #DIV/0!
                               decanes (C10+)*                                                142.29                0   #DIV/0!
                               benzene                                                         78.11                0   #DIV/0!
                               toluene                                                         92.14                0   #DIV/0!
                               ethylbenzene                                                   106.16                0   #DIV/0!
                               xylenes (M, P, O)                                              106.16                0   #DIV/0!
                               undecanes (C11+)*                                              156.31                0   #DIV/0!
                                                         TOTALS:                 0.0000                               0   #DIV/0!
* If the Molecular Weight is available on the gas analysis, enter it above, otherwise, can use the default value.

Fugitives Emission Calculations
                                                                                                                                                  Back to Workbook Navigation Tab.
  LDAR Program (Choose
        from list)             Please choose from the following:

Gas                                                                                                                                      Gas
                                                                      emission factor    emission factor                                    VOC                                                                      Control
                                                                        (kg/hr per      (lb/hr of TOC per                                content* (wt                            Ethylbenz                          Efficiency
            number             component                               component)*         component)         lb/hr         tpy              %)         Benzene       Toluene       ene        Xylene    n-hexane       (%)
                               Valve                                      0.0045             0.00992            0            0             #DIV/0!      #DIV/0!       #DIV/0!        #DIV/0!   #DIV/0!   #DIV/0!        0
                               Pump Seal                                  0.0024             0.00529            0            0             #DIV/0!      #DIV/0!       #DIV/0!        #DIV/0!   #DIV/0!   #DIV/0!        0
                               Connector                                  0.0002             0.00044            0            0             #DIV/0!      #DIV/0!       #DIV/0!        #DIV/0!   #DIV/0!   #DIV/0!        0
                               Flange                                    0.00039             0.00086            0            0             #DIV/0!      #DIV/0!       #DIV/0!        #DIV/0!   #DIV/0!   #DIV/0!        0
                               Open-ended Line                             0.002             0.00441            0            0             #DIV/0!      #DIV/0!       #DIV/0!        #DIV/0!   #DIV/0!   #DIV/0!        0
                               Other                                      0.0088             0.01940            0            0             #DIV/0!      #DIV/0!       #DIV/0!        #DIV/0!   #DIV/0!   #DIV/0!        0
                                                                                                    Total:      0            0                                                                                                   Total:

Light Oil                                                                                                                                Light Oil
                                                                      emission factor    emission factor                                    VOC                                                                      Control
                                                                        (kg/hr per      (lb/hr of TOC per                                  content*                              Ethylbenz                          Efficiency
            number             component                               component)          component)         lb/hr         tpy              (%)        Benzene       Toluene       ene        Xylene    n-hexane       (%)
                               Valve                                      0.0025             0.00551            0            0             #DIV/0!      #DIV/0!       #DIV/0!        #DIV/0!   #DIV/0!   #DIV/0!        0
                               Pump Seal                                   0.013             0.02866            0            0             #DIV/0!      #DIV/0!       #DIV/0!        #DIV/0!   #DIV/0!   #DIV/0!        0
                               Connector                                 0.00021             0.00046            0            0             #DIV/0!      #DIV/0!       #DIV/0!        #DIV/0!   #DIV/0!   #DIV/0!        0
                               Flange                                    0.00011             0.00024            0            0             #DIV/0!      #DIV/0!       #DIV/0!        #DIV/0!   #DIV/0!   #DIV/0!        0
                               Open-ended Line                            0.0014             0.00309            0            0             #DIV/0!      #DIV/0!       #DIV/0!        #DIV/0!   #DIV/0!   #DIV/0!        0
                               Other                                      0.0075             0.01653            0            0             #DIV/0!      #DIV/0!       #DIV/0!        #DIV/0!   #DIV/0!   #DIV/0!        0
                                                                                                    Total:      0            0                                                                                                   Total:
Heavy Oil                                                                                                                                Heavy Oil
                                                                      emission factor    emission factor                                   VOC                                                                       Control
                                                                        (kg/hr per      (lb/hr of TOC per                                 content*                               Ethylbenz                          Efficiency
            number             component                               component)          component)         lb/hr         tpy             (%)         Benzene       Toluene       ene        Xylene    n-hexane       (%)
                               Valve                                    0.0000084           0.0000185           0            0            100.0000                                                                      0
                               Pumps**                                      -                0.00113            0            0            100.0000      0.0000        0.0000         0.0000    0.0000     0.0000        0
                               Connector                                0.0000075           0.0000165           0            0            100.0000      0.0000        0.0000         0.0000    0.0000     0.0000        0
                               Flange                                  0.00000039           0.0000009           0            0            100.0000      0.0000        0.0000         0.0000    0.0000     0.0000        0
                               Open-ended Line                           0.00014            0.0003086           0            0            100.0000      0.0000        0.0000         0.0000    0.0000     0.0000        0
                               Other**                                      -               0.0000683           0            0            100.0000      0.0000        0.0000         0.0000    0.0000     0.0000        0
                                                                                                    Total:      0            0                                                                                                   Total:
Water/Oil                                                                                                                                Water/Oil
                                                                      emission factor    emission factor                                   VOC                                                                       Control
                                                                        (kg/hr per      (lb/hr of TOC per                                 content*                               Ethylbenz                          Efficiency
            number             component                               component)          component)         lb/hr         tpy             (%)         Benzene       Toluene       ene        Xylene    n-hexane       (%)
                               Valve                                     0.000098           0.0002161           0            0            100.0000                                                                      0
                               Pump Seal                                 0.000024           0.0000529           0            0            100.0000      0.0000        0.0000         0.0000    0.0000     0.0000        0
                               Connector                                 0.00011            0.0002425           0            0            100.0000      0.0000        0.0000         0.0000    0.0000     0.0000        0
                               Flange                                   0.0000029           0.0000064           0            0            100.0000      0.0000        0.0000         0.0000    0.0000     0.0000        0
                               Open-ended Line                           0.00025            0.0005512           0            0            100.0000      0.0000        0.0000         0.0000    0.0000     0.0000        0
                               Other                                       0.014            0.0308649           0            0            100.0000      0.0000        0.0000         0.0000    0.0000     0.0000        0
                                                                                                    Total:      0            0                                                                                                   Total:




Annual Emission Totals
             Contaminant                       tpy
                Total VOC                    #DIV/0!                                    Report Total VOC emissions on the "Fugitives" tab.
                  Benzene                    #DIV/0!
                  Toluene                    #DIV/0!                                    Report Benzene, Ethylbenzene, Toluene,
             Ethylbenzene                    #DIV/0!                                    Xylene, and n-hexane on the Phase II
                 Xylene(s)                   #DIV/0!                                    calculator if they are greater than 0.1 tpy on
                 n-Hexane                    #DIV/0!                                    the "Fugitive(s)" tab.
Emission factors are for oil and gas production facilities (not refineries), and come from the EPA's "Protocol for Equipment Leak Emission Estimates" November 1995, EPA 4531,
R-95-017, Table 2-4.

Emission factors that are not based on the EPA document are from the TCEQ "Air Permit Technical Guidance for Chemical Source Equipment
Leak Fugitives (Draft October 2000)

* For fugitive calculations, VOC content should be VOC content of total hydrocarbons, not of total sample.
 VOC      Benzene   Toluene   Ethylbenzene   Xylene    n-hexane


  tpy       tpy       tpy         tpy          tpy       tpy
#DIV/0!   #DIV/0!   #DIV/0!     #DIV/0!      #DIV/0!   #DIV/0!
#DIV/0!   #DIV/0!   #DIV/0!     #DIV/0!      #DIV/0!   #DIV/0!
#DIV/0!   #DIV/0!   #DIV/0!     #DIV/0!      #DIV/0!   #DIV/0!
#DIV/0!   #DIV/0!   #DIV/0!     #DIV/0!      #DIV/0!   #DIV/0!
#DIV/0!   #DIV/0!   #DIV/0!     #DIV/0!      #DIV/0!   #DIV/0!
#DIV/0!   #DIV/0!   #DIV/0!     #DIV/0!      #DIV/0!   #DIV/0!
#DIV/0!   #DIV/0!   #DIV/0!     #DIV/0!      #DIV/0!   #DIV/0!




  tpy       tpy       tpy         tpy          tpy       tpy
#DIV/0!   #DIV/0!   #DIV/0!     #DIV/0!      #DIV/0!   #DIV/0!
#DIV/0!   #DIV/0!   #DIV/0!     #DIV/0!      #DIV/0!   #DIV/0!
#DIV/0!   #DIV/0!   #DIV/0!     #DIV/0!      #DIV/0!   #DIV/0!
#DIV/0!   #DIV/0!   #DIV/0!     #DIV/0!      #DIV/0!   #DIV/0!
#DIV/0!   #DIV/0!   #DIV/0!     #DIV/0!      #DIV/0!   #DIV/0!
#DIV/0!   #DIV/0!   #DIV/0!     #DIV/0!      #DIV/0!   #DIV/0!
#DIV/0!   #DIV/0!   #DIV/0!     #DIV/0!      #DIV/0!   #DIV/0!



 tpy        tpy       tpy         tpy         tpy        tpy
0.000      0.000     0.000       0.000       0.000      0.000
0.000      0.000     0.000       0.000       0.000      0.000
0.000      0.000     0.000       0.000       0.000      0.000
0.000      0.000     0.000       0.000       0.000      0.000
0.000      0.000     0.000       0.000       0.000      0.000
0.000      0.000     0.000       0.000       0.000      0.000
  0          0         0           0           0          0



 tpy        tpy       tpy         tpy         tpy        tpy
0.000      0.000     0.000       0.000       0.000      0.000
0.000      0.000     0.000       0.000       0.000      0.000
0.000      0.000     0.000       0.000       0.000      0.000
0.000      0.000     0.000       0.000       0.000      0.000
0.000      0.000     0.000       0.000       0.000      0.000
0.000      0.000     0.000       0.000       0.000      0.000
0.000      0.000     0.000       0.000       0.000      0.000
VENTED SEPARATOR EMISSION CALCULATION
For separators that vent to the atmosphere under normal operating conditions. This does not                                    Back to Workbook Navigation Tab.
include separators that vent to the atmosphere through a pressure relief valve only under upset
conditions.

Barnett Shale Phase II Identification Information:                                                                        ►Input variables into the blue boxes
Company Name:               Insert Company and/or site name here.                                                         ►Emissions will be in the green boxes.
Separators #:
Company's Unique
Identification Number:

Gas Analysis of separator vent gas:
                                                                                Molecular
                                                                                 Weight grams per
                                                                                (grams/m 100 moles
                                                             mole %                ole)    of gas         weight %
                              Nitrogen                                          28.01348            0      #DIV/0!                                  VOC content of total gas sample (VAPOR)
                              CO2                                               44.0095             0      #DIV/0!                                    VOC weight% = #DIV/0!
                              H2S                                               34.08188            0      #DIV/0!                                VOC weight fraction = #DIV/0!
                              methane (C1)                                      16.04246            0      #DIV/0!                                                  (VOC: total sample)
                              ethane (C2)                                       30.06904            0      #DIV/0!
                              propane (C3)                                      44.09562            0      #DIV/0!                         HAP content of gas sample
                              i-butane (C4)                                     58.1222             0      #DIV/0!                                  Benzene weight% =         #DIV/0!
                              n-butane (C4)                                     58.1222             0      #DIV/0!                                  Toluene weight% =         #DIV/0!
                              i-pentane (C5)                                    72.14878            0      #DIV/0!                             Ethylbenzene weight% =         #DIV/0!
                              n-pentane (C5)                                    72.14878            0      #DIV/0!                                   Xylene weight% =         #DIV/0!
                              n-hexane (C6)                                       86.17             0      #DIV/0!                                 n-hexane weight% =         #DIV/0!
                              heptanes (C7+)*                                     100.2             0      #DIV/0!
                              octanes (C8+)*                                     114.23             0      #DIV/0!
                              nonanes (C9+)*                                     128.26             0      #DIV/0!
                              decanes (C10+)*                                    142.29             0      #DIV/0!
                              benzene                                             78.11             0      #DIV/0!
                              toluene                                             92.14             0      #DIV/0!
                              ethylbenzene                                       106.16             0      #DIV/0!
                              xylenes (M, P, O)                                  106.16             0      #DIV/0!
                              undecanes (C11+)*                                  156.31             0      #DIV/0!
                                         TOTALS:                       0.0000                       0      #DIV/0!

* If the Molecular Weight is available on the gas analysis, enter it above, otherwise, can use the default value. If                         Molecular Weight of Gas = 0                  lb/lb-mole or grams/mole
MW or SG of total sample available on lab analysis, can adjust this value until MW or SG fields (to the right) match                          Specific Gravity of Gas = 0
the lab analysis.
                                                                                                                                                     1 lb-mole of gas =      379.4832 SCF
                                                                                                                                                     at STP (standard temperature (60°F) and pressure
                                               Enter Venting Volume (SCF):                 (standard cubic feet)                                     (14.696 psia))


                                                                                   tpy
                                                                                                        Report Total VOC emissions
                                                            VOC emissions:       #DIV/0!                on Separator(s) tab.
                                                                  benzene        #DIV/0!
                                                                    toluene      #DIV/0!                Report HAP emissions on
                                                                                                        Separator(s) tab or HAP
                                                              ethylbenzene       #DIV/0!                speciation tab if the values are
                                                                                                        greater than or equal to 0.1
                                                                      xylene     #DIV/0!                tpy.
                                                               n-hexane (C6)     #DIV/0!
Condensate Storage Tank
     Gas condensate is defined as a liquid hydrocarbon with an API gravity greater than 40° at 60°F (and a specific gravity less

Barnett Shale Phase II Identification Information:
Company Name:                    Insert Company and/or site name here.
Condensate Tank#:
Company's Unique
Identification Number:



Tank emissions are made up of 3 different components, working, breathing and flash losses.

Using EPA TANKS 4.0 Software to calculate Working and Breathing losses

     Working and Breathing Losses

     EPA TANKS 4.0
     This software is available for download at www.epa.gov/ttn/chief/software/tanks/index.html




                                                 Working                                    Breathing


     VOCs, C3+
     Benzene
     Toluene
     E benzene
     Xylenes
     n-hexane
     2,2,4 - Trimethylpentane
     Any Additional HAP (if applicable):




Using E&P TANKS 4.0 Software to calculate Working and Breathing losses
     E&P Tanks (accounts for working, breathing and flash losses).
     This software can be purchased from www.global.ihs.com
     Component                         Controlled Emissions [ton/yr]

     VOCs, C3+
     Benzene
     Toluene
     E benzene
     Xylenes
     n-C6
     224Trimethylp
 at 60°F (and a specific gravity less than 0.8252).                       Back to Workbook Navigation Tab.

                                          Notes:
                                          ► Enter variables into blue boxes
                                          ► Emissions will be in green boxes




hing and flash losses.




            Flash losses                                                       Total Emissions
            Valid Methods for Condensate (Use one of the following
            accepted methods):
                  Direct Measurement of Emissions
                  Process Simulator Models
                  the gas/oil ratio (GOR) method

                    Flash losses


            VOCs, C3+                                                          VOCs, C3+                         0.0000
            Benzene                                                            Benzene                           0.0000
            Toluene                                                            Toluene                           0.0000
            E benzene                                                          E benzene                         0.0000
            Xylenes                                                            Xylenes                           0.0000
            n-hexane                                                           n-C6                              0.0000
            2,2,4 - Trimethylpentane                                           2,2,4 - Trimethylpentane          0.0000
            Any Additional HAP (if applicable):                                Any Additional HAP (if applicable):
                                                                                                                 0.0000
                                                                                                                 0.0000
                                                                                                                 0.0000
                                                                                                                 0.0000




                                                                               Annual Emissions           tons per year

                                                                               VOCs, C3+                        0.0000
                                                                               Benzene                          0.0000
                                                                               Toluene                          0.0000
                                                                               E benzene                        0.0000
                                                                               Xylenes                          0.0000
                                                                               n-C6                             0.0000
                                                                               2,2,4 - Trimethylpentane         0.0000
Report VOC emissions on
Condensate Tank(s) Tab.




Report HAP emissions on
Condensate Tank(s) tab or
HAP speciation tab if the
values are greater than or
equal to 0.1 tpy.




Report VOC emissions on
Condensate Tank(s) Tab.



Report HAP emissions on
Condensate Tank(s) tab or
HAP speciation tab if the
values are greater than or
equal to 0.1 tpy.
Crude Oil Storage Tank
          Crude oil is defined as heavy, low volatility oil approximated by a GOR less than 1,750 cubic feet per barrel and an A


Barnett Shale Phase II Identification Information:
Company Name:                         Insert Company and/or site name here.
Crude Oil Tank#:
Company's Unique Identification
Number:



Tank emissions are made up of 3 different components, working, breathing and flash losses.

Using EPA TANKS 4.0 Software to calculate Working and Breathing losses

          Working and Breathing Losses

          EPA TANKS 4.0
          This software is available for download at www.epa.gov/ttn/chief/software/tanks/index.html




                                                       Working                                     Breathing


          VOCs, C3+
          Benzene
          Toluene
          E benzene
          Xylenes
          n-hexane
          2,2,4 - Trimethylpentane
          Any Additional HAP (if applicable):




Using E&P TANKS 4.0 Software to calculate Working and Breathing losses
          E&P Tanks (accounts for working, breathing and flash losses).
          This software can be purchased from www.global.ihs.com
          Component                        Controlled Emissions [ton/yr]

          VOCs, C3+
          Benzene
          Toluene
          E benzene
          Xylenes
          n-C6
224Trimethylp
bic feet per barrel and an API gravity less than 40°.                                       Back to Workbook Navigation Tab.


                                           Notes:
                                           ► Enter variables into blue boxes
                                           ► Emissions will be in green boxes




nd flash losses.




            Flash losses                                                        Total Emissions
            Valid Methods for Crude Oil (Use one of the following
            accepted methods):
                  Direct Measurement of Emissions
                  Process Simulator Models
                  Vasquez-Beggs correlation
                  Rollins, McCain, and Creeger correlations
                  the gas/oil ratio (GOR) method

                     Flash losses


            VOCs, C3+                                                           VOCs, C3+
            Benzene                                                             Benzene
            Toluene                                                             Toluene
            E benzene                                                           E benzene
            Xylenes                                                             Xylenes
            n-hexane                                                            n-C6
            2,2,4 - Trimethylpentane                                            2,2,4 - Trimethylpentane
            Any Additional HAP (if applicable):                                 Any Additional HAP (if applicable):




                                                                                Annual Emissions

                                                                                VOCs, C3+
                                                                                Benzene
                                                                                Toluene
                                                                                E benzene
                                                                                Xylenes
                                                                                n-C6
2,2,4 - Trimethylpentane
ack to Workbook Navigation Tab.




                                  Report VOC emissions on Crude
                       0.0000     Oil Tank(s) Tab.
                       0.0000
                       0.0000
                       0.0000
                       0.0000
                       0.0000     Report HAP emissions on Crude
                                  Oil Tank(s) tab or HAP speciation
                       0.0000
                                  tab if the values are greater than
HAP (if applicable):              or equal to 0.1 tpy.
                       0.0000
                       0.0000
                       0.0000
                       0.0000




            tons per year
                                  Report VOC emissions on Crude
                       0.0000     Oil Tank(s) Tab.
                       0.0000
                       0.0000     Report HAP emissions on Crude
                       0.0000     Oil Tank(s) tab or HAP speciation
                       0.0000     tab if the values are greater than
                       0.0000     or equal to 0.1 tpy.
         Report HAP emissions on Crude
         Oil Tank(s) tab or HAP speciation
         tab if the values are greater than
         or equal to 0.1 tpy.
0.0000
Produced Water Storage Tank

Barnett Shale Phase II Identification Information:
Company Name:                                                          Insert Company and/or site name here.
Produced Water Tank#:
Company's Unique Identification Number:

Tank emissions are made up of 3 different components, working, breathing and flash losses.

Using EPA TANKS 4.0 Software to calculate Working and Breathing losses
Working and Breathing Losses
EPA TANKS 4.0*
This software is available for download at www.epa.gov/ttn/chief/software/tanks/index.html



                                               Working                                       Breathing


VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-hexane
2,2,4 - Trimethylpentane
Any Additional HAP (if applicable):




*It is possible to create a mixture in the EPA TANKS program similar to the composition of the produced
water stored in the tanks (e.g., a mixture of 99% water and 1% condensate) to determine the emissions.

Using E&P TANKS 4.0 Software to calculate Working and Breathing losses
E&P Tanks (accounts for working, breathing and flash losses).
This software can be purchased from www.global.ihs.com
Component                         Controlled Emissions [ton/yr]


VOCs, C3+
Benzene
Toluene
E benzene
Xylenes
n-C6
224Trimethylp
                                                              Back to Workbook Navigation Tab.


                                                          Notes:
                                                          ► Enter variables into blue boxes
                                                          ► Emissions will be in green boxes

ing and flash losses.


                   Flash losses                                     Total Emissions
                        Direct Measurement of Emissions
                        Process Simulator Models
                        the gas/oil ratio (GOR) method
                        Vasquez-Beggs correlation
                        Flash losses


                   VOCs, C3+                                        VOCs, C3+
                   Benzene                                          Benzene
                   Toluene                                          Toluene
                   E benzene                                        E benzene
                   Xylenes                                          Xylenes
                   n-hexane                                         n-C6
                   2,2,4 - Trimethylpentane                         2,2,4 - Trimethylpentane
                   Any Additional HAP (if applicable):              Any Additional HAP (if applicable):




                                                                    Annual Emissions


                                                                    VOCs, C3+
                                                                    Benzene
                                                                    Toluene
                                                                    E benzene
                                                                    Xylenes
                                                                    n-C6
                                                                    2,2,4 - Trimethylpentane
avigation Tab.




                                Report VOC emissions on
                                Produced Water Tank(s)
                       0.0000   Tab.
                       0.0000
                       0.0000
                       0.0000
                       0.0000   Report HAP emissions on
                       0.0000   Produced Water Tank(s)
                       0.0000   tab or HAP speciation tab if
HAP (if applicable):            the values are greater than
                                or equal to 0.1 tpy.
                       0.0000
                       0.0000
                       0.0000
                       0.0000




             tons per year
                                Report VOC emissions on
                                Produced Water Tank(s)
                       0.0000   Tab.
                       0.0000
                       0.0000
                       0.0000   Report HAP emissions on
                                Produced Water Tank(s)
                       0.0000
                                tab or HAP speciation tab if
                       0.0000   the values are greater than
                       0.0000   or equal to 0.1 tpy.
Turbine Emission Calculations (fueled by natural gas)                                Back to Workbook Navigation Tab.

Barnett Shale Phase II Identification Information:                                          ►Input variables into the blue boxes
Company Name:                        Insert Company and/or site name here.                  ►Emissions will be in the green boxes.
Turbine #:
Company's Unique Identification
Number:



          Turbine rating (MMBtu/hr):
              Operating hours/year:

             pollutant                    emission factor (lb/MMBtu)*         tpy
               VOC                                  0.0021                   0.000
               NOX                                   0.32                    0.000

* Emission Factors from AP-42, Chapter 3, Tables 3.1-1 and 3.1-2a.
Non-Flare Combustive Devices
                                                                                                                                                                                      Back to Workbook Navigation Tab.


Barnett Shale Phase II Identification Information:                                                                                          Notes:

Company Name:                     Insert Company and/or site name here.                                                                     ►Input variables into the blue boxes
Other #:                                                                                                                                    ►Emissions will be in the green boxes.
Company's Unique
Identification Number:                                                                                                                      ► Instructions are shaded.


General Information                                                                                                      Emission Factors

(1) What kind of device is
this? Enter a short
description of the device                                                                                                Emission Factors from AP-42 Table 1.4-1 and 1.4-2                       Emission Factors from AP-42 Table 1.4-3
type.                                                                                                                    (lb/MMscf)                                                              (lb/MMscf)

                                  Emission Factors for Waste Gas Stream(s) (lb/MMscf)                                                       NOx                                 100              VOC                    5.5
                                                NOx              100                                                                        Other Vendor Factor                                  benzene           2.10E-03
                                                                                                                                                                                                 toluene           3.40E-03

(2) Is there one or more
continuous pilot streams?                 Yes
Pick Yes or No. Follow
instructions below.                                                                                                                                                                              ethylbenzene                  0 none listed
                                       Enter pilot stream information into the boxes in the column for
                                       Steam No. 1 below. If there is more than one continous pilot
                                             stream, please enter it as one combined stream.                                                                                                     xylene                         0 none listed
                                  Emission Factors for Pilot Stream (lb/MMscf)                                                                                                                   n-hexane                     1.8
                                                NOx                100


(3) Is there an added fuel
                                          Yes
stream? Pick Yes or No.
Follow instructions below.
                                      Enter added fuel stream information into the boxes in the column
                                                           for Steam No. 2 below.
                                  Emission Factors for Added Fuel Stream (lb/MMscf)
                                                NOx               100

(4) VOC percent
                                           98
destruction efficiency (%)

Stream Information

Stream Sent to Flare No.                   1              2          3              4             5              6               7                    8                    9              10            11               12       Total for all
                                                                                                                                                                                                                                  Streams
Enter Names of Each
Stream sent to the flare                            Added                                   ex: glycol     ex: amine     ex: glycol unit    ex: amine unit flash    ex: truck
Here →                            Pilot(s)          fuel        ex: oil tank ex: water tank unit vent      unit vent     flash tank         tank                    loading

Volumetric Flow Rate of
Stream (scf/yr)                                                                                                                                                                                                                                 0
Heat Value of Stream - from
program results or gas
analysis (Btu/scf)                                                                                                                                                                                                                              0

Uncontrolled VOC and HAP                                                                                                                                                                                                          Total for all
                                                        Added                                 ex: glycol    ex: amine     ex: glycol unit    ex: amine unit flash      ex: truck
Emissions for each of                   Pilot(s)                ex: oil tank ex: water tank                                                                                                                                       Streams
                                                         fuel                                 unit vent      unit vent      flash tank              tank                loading
these stream
Total VOC Annual Emissions        -                 -                                                                                                                                                                                           0
benzene Annual Emissions          -                 -                                                                                                                                                                                           0
toluene Annual Emissions          -                 -                                                                                                                                                                                           0
ethylbenzene Annual               -                 -                                                                                                                                                                                           0
xylene Annual Emissions (tpy)     -                 -                                                                                                                                                                                           0
n-hexane Annual Emissions         -                 -                                                                                                                                                                                           0
other HAP (fill in name) Annual   -                 -                                                                                                                                                                                           0
other HAP (fill in name) Annual   -                 -                                                                                                                                                                                           0

Other Combustion Device
Total Emissions
                                  Annual
                                  Emissions
                                  (tpy)
NOX                                     0.00
Total VOC                               0.00                    Report NOx and Total VOC on the "Other Source(s)" tab in the Phase II workbook.
benzene                                 0.00
toluene                                 0.00
ethylbenzene                            0.00
xylene                                  0.00                    Report Benzene, Ethylbenzene, Toluene, Xylene(s), and n-hexane and any other HAPs on the
n-hexane                                0.00                    Phase II workbook if they are ≥ 0.1 tpy on the "Other Source(s)" tab.
other HAP                               0.00
other HAP                               0.00
Flash Emission Calculation - Vasquez-Beggs Solution Gas/Oil Ratio Correlation Method
                                                                                                                                                           Back to Crude Oil Storage
                      (For Estimating VOC Flashing Emissions, Using Stock Tank Gas-Oil Ratios For Crude Oil Facilities)


Barnett Shale Phase II Identification Information:                                                                   Notes:
                                                                                                                                                            Back to Workbook Navigation Tab.
Company Name:         Insert Company and/or site name here.                                                          ► Enter variables into blue boxes
Tank#:                                                                                                               ► Emissions will be in green boxes
Company's Unique
Identification
Number:
                                                                                                                                                           Within Valid
INPUTS:                                                                                                   CONSTRAINTS:                                      Range?
                      Stock Tank API Gravity                                                 API             16      >API>         40            °API          No
                      Separator Pressure (psig)                                               P              50   > P+Patm >      5250          (psia)         No
                      Separator Temperature (°F)                                              Ti             70      > Ti >        295           (°F)          No
                      Separator Gas Gravity at Initial Condition                             SGi            0.56    > SGi >       1.18      (MW/28.97)         No
                      Stock Tank Barrels of Oil per day (BOPD)                                Q             None     >Q >         None        (BOPD)           Yes
                      Stock Tank Gas Molecular Weight                                        MW              18     > MW >         125      (lb/lb-mole)       No
                      Fraction VOC (C3+) of Stock Tank Gas                                  VOC              0.5    > VOC >       1.00        fraction         No
                      Atmospheric Pressure (psia)                                           Patm            None   > Patm >       None          (psia)         Yes

OUTPUTS:
                      SGx = Dissolved gas gravity at 100 psig = SGi [1.0+0.00005912*API*Ti*Log(Pi/114.7)]

                                  SGx =                  0.00

                      Rs = (C1 * SGx * Pi^C2) exp ((C3 * API) / (Ti + 460))

                      Where:                 Rs    Gas/Oil Ratio of liquid at pressure of interest
                                           SGx     Dissolved gas gravity at 100 psig
                                             Pi    Pressure of initial condition (psia)
                                            API    API Gravity of liquid hydrocarbon at final condition
                                              Ti   Temperature of initial condition (F)

                                                        Constants
                                                              °API Gravity
                                    °APTI ®           < 30     >= 30      Given °API
                                      C1              0.0362    0.0178         0.0362
                                      C2              1.0937     1.187         1.0937
                                      C3              25.724    23.931         25.724
                                                                                                          CONSTRAINTS:
                          Rs =             0.00 scf/bbl         for P + Patm =                        0     20      > Rs >         2070      (scf/STB)

                          THC = Rs * Q * MW * 1/385 scf/lb-mole * 365 D/Yr * 1 ton/2000 lbs

                                  THC              Total Hydrocarbon (tons/year)
                                  Rs               Solution Gas/Oil Ratio (scf/STB)
                                  Q                Oil Production Rate (bbl/day)
                                  MW               Molecular Weight of Stock Tank Gas (lb/lb-mole)
                                  385              Volume of 1 lb-mole of gas at 14.7 psia and 68 F (WAQS&R Std Cond)

                          THC =           0.000 TPY

                         VOC = THC * Frac. of C3+ in the Stock Tank Vapor

                         VOC* =      0.00     TPY        from "FLASHING" of oil from separator to tank press
*Before reporting these emissions, make sure to review the Within Valid Range section to verify this method is valid for your conditions.
GOR Method for Estimating Flash Emissions

Barnett Shale Phase II Identification Information:
Company Name:               Insert Company and/or site name here.
Tank#:
Company's Unique
Identification Number:
                                                                                                                             ► Enter variables into blue boxes
                                                                                                                             ► Emissions will be in green boxes

                                     Gas Oil Ratio:                      in standard cubic feet of flash gas per barrel (SCF/bbl) of oil/condensate produced
             Barrels of Oil or Condensate per day:

This information is based on an analysis submitted by the applicant.                                                                     Flash Gas MW =

Flash Gas Speciation:

                                                      molecular weight     grams per 100
                                    mole %             (grams/mole)         moles of gas          weight %                                      Total gas emitted:
Nitrogen                                                 28.01348                          0       #DIV/0!                                             tpy:
CO2                                                       44.0095                          0       #DIV/0!
H2S                                                      34.08188                          0       #DIV/0!
methane (C1)                                             16.04246                          0       #DIV/0!                                  VOC wt% =
ethane (C2)                                              30.06904                          0       #DIV/0!                            Benzene weight% =
propane (C3)                                             44.09562                          0       #DIV/0!                            Toluene weight% =
i-butane (C4)                                             58.1222                          0       #DIV/0!                       Ethylbenzene weight% =
n-butane (C4)                                             58.1222                          0       #DIV/0!                             Xylene weight% =
i-pentane (C5)                                           72.14878                          0       #DIV/0!                           n-hexane weight% =
n-pentane (C5)                                           72.14878                          0       #DIV/0!
hexanes (C6)                                                86.18                          0       #DIV/0!
heptanes (C7+)*                                              100                           0       #DIV/0!
octane (C8+)*                                              114.23                          0       #DIV/0!
nonane (C9+)*                                              128.26                          0       #DIV/0!
decane (C10+)*                                             142.29                          0       #DIV/0!                   Contaminant          TPY
benzene                                                     78.11                          0       #DIV/0!                        Total VOC      #DIV/0!
toluene                                                     92.14                          0       #DIV/0!                          benzene      #DIV/0!
ethylbenzene                                               106.16                          0       #DIV/0!                            toluene    #DIV/0!
xylenes (M, P, O)                                          106.16                          0       #DIV/0!                      ethylbenzene     #DIV/0!
undecanes (C11+)*                                        156.31                          0      #DIV/0!                             xylene    #DIV/0!
                    TOTALS:          0.0000                                              0      #DIV/0!                      n-hexane (C6)    #DIV/0!


* If MW of heptanes plus is given, you can change the value in the table above.
* If the MW of the total sample is given, you can adjust the MW of heptanes+ until the "Flash Gas MW" value above equals the value on the lab report.
                                       Back to Workbook Navigation Tab.




es into blue boxes
ill be in green boxes

sate produced


                          0




  Total gas emitted:
                          0


                #DIV/0!
                #DIV/0!
                #DIV/0!
                #DIV/0!
                #DIV/0!
                #DIV/0!




                              Report Total VOC emissions on the
                              appropriate tank tab.

                              Report HAP emissions on the
                              appropriate tank tab or HAP
                              speciation tab if the values are
                              greater than or equal to 0.1 tpy.
Report HAP emissions on the
appropriate tank tab or HAP
speciation tab if the values are
greater than or equal to 0.1 tpy.
Example First page of a GRI-GLYCalc Report:




Controlled Regenerator with Flash Tank
Controlled Regenerator Emissions section example:
                                                      Report these emissions as
                                                      the uncontrolled/controlled
                                                      regenerator emissions




                                                      Total VOC is 1.2836 tpy for
                                                      this example for the
                                                      uncontrolled /controlled
                                                      regenerator emissions.
Flash Gas Emissions section example:




                                                      Report these emissions as
                                                      the flash tank emissions.




                                                      Total VOC is 0.0168 tpy for
                                                      the flash tank emissions for
                                                      this example.




Uncontrolled Regenerator with Flash Tank
Uncontrolled Regenerator Emissions section example:
                                                          Report these emissions as
                                                          the "uncontrolled/controlled
                                                          regenerator emissions".


                                                          Total VOC is 2.1251 tpy for
                                                          this example for the
                                                          uncontrolled /controlled
                                                          regenerator emissions.
Flash Gas Emissions section example:




                                                          Report these emissions as
                                                          the flash tank emissions.




                                                          Total VOC is 0.0168 tpy for
                                                          the flash tank emissions for
                                                          this example.




Uncontrolled Regenerator with Flash Tank with recycle/recompression option
Uncontrolled Regenerator Emissions section example:




                                                          Report these emissions as
                                                          the "uncontrolled/controlled
                                                          regenerator emissions".
                                            Total VOC is 2.1251 tpy for
                                            this example for the
                                            uncontrolled /controlled
                                            regenerator emissions.
Flash Gas Emissions section example:

                                       No emissions to report for flash
                                       tank that is
                                       recycled/recompressed. You may
                                       leave this section blank or enter
                                       zeros.
Back to Glycol Dehydrator Tab.




                     Back to Glycol Dehydrator Tab.
Back to Glycol Dehydrator Tab.
Back to Glycol Dehydrator Tab.
E&P Tank Example
                                                     Back to Condensate Tanks Tab.
Look for the "Calculation Results" Section of
the E&P Tank printout for emissions data.
                                                        Back to Crude Tanks Tab.



                                                    Back to Produced Water Tanks Tab.
From the "Controlled [ton/yr]" column, read
the VOCs, C3+ emissions. This is your Total
VOC emissions. (For this example 74.897                  Back to Frac Tanks Tab.
tpy)




Report the Benzene through 2,2,4 Trimethylpentane
emissions.
                             IC Engines List of Types
                             2 Stroke Lean
                             4 Stroke Lean
                             4 Stroke Rich



                             2 Stroke Lean               4 Stroke Lean 4 Stroke Rich
Nox (90-105% Load)                                3.17              4.08         2.21
Nox (<90% Load)                                   1.94             0.847         2.27
CO (90-105 Load)                                 0.386             0.317         3.72
CO (<90% Load)                                   0.353             0.557         3.51
SO2                                          0.000588          0.000588     0.000588

VOC total                                         0.12            0.118       0.0296
PM total                                      0.04831         0.009987       0.01941
For Error Finding Only:
TOC                                               1.64             1.47         0.358
PM filterable                                  0.0384       0.0000771         0.0095
PM condensable                                0.00991          0.00991       0.00991

VOC Speciation C or better   2 Stroke Lean               4 Stroke Lean 4 Stroke Rich BOILERS turbines
1,1,2,2-Tetrachloroethane                    6.63E-05                       2.53E-05
1,1,2-Trichloroethane                        5.27E-05
1,1-Dichoroethane                            3.91E-05
1,2,4-Trimethylbenzene                       1.11E-04         1.43E-05
1,2-Dichloropropane                          4.46E-05
1,3-Dichloropropene                          4.38E-05
2-Methylnapththalene                         2.14E-05         3.32E-05
Acenaphthene                                 1.33E-06         1.25E-06
2,2,4-trimethlypentane                       8.46E-04         2.50E-04
Acenaphthylene                               3.17E-06         5.53E-06
Acetaldehyde                                 7.76E-03         8.36E-03      2.79E-03               4.00E-05
Acrolein                                     7.78E-03         5.14E-03      2.63E-03               6.40E-06
Anthracene                                   7.18E-07
Benz(a)anthracene                            3.36E-07
Benzene                                      1.94E-03         4.40E-04      1.58E-03    2.10E-03   1.20E-05
Biphenyl                                     3.95E-06
Butane                                       4.75E-03
Butyr/isobutyaldehyde                        4.37E-04         1.01E-04
Carbon Tetrachloride                         6.07E-05
Chlorobenze                                  4.44E-05
Chloroform                                   4.71E-05
Chrysene                                     6.72E-07         6.93E-07
Cyclohexane                                  3.08E-04
cyclopentane                                 9.47E-05         2.27E-04
Ethylbenzene                                 1.08E-04         3.97E-05                             3.20E-05
Ethylene Dibromide                           7.34E-05
Fluoranthene                                 3.61E-07         1.11E-06
Fluorene                                     1.37E-06         5.67E-06
Formaldehyde                                 5.52E-02         5.28E-02      2.05E-02    7.50E-02   7.10E-04
Isobutane            3.75E-03
Methanol             2.48E-03   2.50E-03
Methycyclohexane     3.38E-04   1.23E-03
Methylene Chloride   1.47E-04   2.00E-05   4.12E-05
n-Hexane             4.45E-04   1.11E-03
n-Nonane             3.08E-05   1.10E-04
n-Octane             7.44E-05   3.51E-04
n-Pentane            1.53E-03   2.60E-03
Naphthalene          9.63E-05   7.44E-05                         1.30E-06
Phenanthrene         3.53E-06
Phenol               4.21E-05
Propane              2.87E-02   4.19E-02
Pyrene               5.84E-07   1.36E-06
Styrene              5.48E-05
Toluene              9.63E-04   4.08E-04   5.58E-04   3.40E-03
Vinyl Chloride       2.47E-05   1.49E-05
Xylene-u             2.68E-04   1.84E-04   1.95E-04
BOILER
                                                 NOX                         CO
                                                  100
Large Wall Fired (>100 MMBtu/hr) - Controlled - Flue Gas Recirculation        84
                                                  140
Large Wall Fired (>100 MMBtu/hr) - Controlled Low Nox Burners                 84
                                                  190
Large Wall Fired (>100 MMBtu/hr) - Uncontrolled (Post - NSPS)                 84
                                                  280
Large Wall Fired (>100 MMBtu/hr) - Uncontrolled (Pre - NSPS)                  84
Residential Furnaces - (< 0.3) Uncontrolled        94                         40
                                                   50
Small Boilers (<100 MMBtu/hr) - Controlled - Low Nox Burners                  84
                                                   32                         84
Small Boilers (<100 MMBtu/hr) - Controlled - Low Nox burners/Flue Gas Recirculation
Small Boilers (<100 MMBtu/hr) - Uncontrolled      100                         84
                                                   76
Tangential Fired Boilers (All) - Low Nox burners/Flue gas recirculation       98
Tangential Fired Boilers (All) Uncontrolled       170                         24

Digester Gas - Uncontrolled

Distillate Oil - Uncontrolled
Distillate Oil - Water-Steam Injection
Landfill Gas - Uncontrolled
Natural Gas - Lean Premix
Natural Gas - Uncontrolled
Natural Gas - Water-Steam Injection


TURBINES                             Digester Gas - Uncontrolled Distillate Oil - Uncontrolled
Nox                                                      1.60E-01                      8.80E-01
CO                                                       1.70E-02                      3.30E-03
SO2                                                      6.50E-03                      3.30E-02
VOC total                                                5.80E-03                      4.10E-04
PM total                                                 1.20E-02                      1.20E-02
For Error Finding Only:
PM filterable                                                                         1.20E-02
PM condensable
1,1,2,2-Tetrachloroethane
1,1,2-Trichloroethane
1,1-Dichoroethane
1,2,4-Trimethylbenzene
1,2-Dichloropropane
1,3-Dichloropropene
2-Methylnapththalene
Acenaphthene
2,2,4-trimethlypentane
Acenaphthylene
Acetaldehyde
Acrolein
Anthracene
Benz(a)anthracene
Benzene                                                                               5.50E-05
Biphenyl
Butane
Butyr/isobutyaldehyde
Carbon Tetrachloride
Chlorobenze
Chloroform
Chrysene
Cyclohexane
cyclopentane
Ethylbenzene
Ethylene Dibromide
Fluoranthene
Fluorene
Formaldehyde         2.80E-04
Isobutane
Methanol
Methylcyclohexane
Methylene Chloride
n-Hexane
n-Nonane
n-Octane
n-Pentane
Naphthalene          3.50E-05
Phenanthrene
Phenol
Propane
Pyrene
Styrene
Toluene
Vinyl Chloride
Xylene-u
                                  Landfill Gas - Uncontrolled
Distillate Oil - Water-Steam Injection
                         2.40E-01                               1.40E-01
                         7.60E-02                               4.40E-01
                                                                4.50E-02
                       4.10E-04                                 1.30E-02
                       1.20E-02                                 2.30E-02

                       1.20E-02




                       5.50E-05                                 2.10E-05
2.80E-04




3.50E-05




           1.10E-04

           3.10E-05
Natural Gas - Lean Premix    Natural Gas - Uncontrolled Natural Gas - Water-Steam Injection
                    9.90E-02                    3.20E-01          1.30E-01
                    1.50E-02                    8.20E-02          3.00E-02
                                                3.40E-03
                    2.10E-03                    2.10E-03          2.10E-03
                    6.60E-03                    6.60E-03          6.60E-03

                   1.90E-03                    1.90E-03            1.90E-03




                   4.00E-05                    4.00E-05            4.00E-05
                   6.40E-06                    6.40E-06            6.40E-06


                   1.20E-05                    1.20E-05            1.20E-05
3.20E-05   3.20E-05   3.20E-05



7.10E-04   7.10E-04   7.10E-04




1.30E-06   1.30E-06   1.30E-06




1.30E-04   1.30E-04   1.30E-04

6.40E-05   6.40E-05   6.40E-05

				
DOCUMENT INFO
Shared By:
Categories:
Tags:
Stats:
views:19
posted:8/29/2011
language:English
pages:56