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Material Safety Data Sheet Section 1. Chemical Product and Company Identification Common Name Macrosorb K2A Pierce Chemical Company P.O. Box 117 Rockford, IL 61105 United States 815.968.0747 Not available. Not available. Not available. Pierce Chemical Company P.O. Box 117 Rockford, IL 61105 United States 815.968.0747 Code Supplier MSDS# Validation Date 0027531 0027532 0027561 0027562 1883700 375 9/17/98 Synonym Trade name Material Uses Manufacturer Print Date 9/17/98 Responsible Name Company In Case of Emergency CALL CHEMTREC: 800.424.9300 OUTSIDE US: 202.483.7616 Section 2. Composition and Information on Ingredients Name CAS # % by Weight Exposure Limits 1) Ethanol 64-17-5 20 TWA: 1000 (ppm) TWA: 1900 (mg/m3) Section 3. Hazards Identification Physical State and Appearance Emergency Overview Liquid. (Suspension.) WARNING! HIGHLY FLAMMABLE LIQUID AND VAPOR, VAPOR MAY CAUSE FLASH FIRE. BIRTH DEFECT HAZARD CONTAINS MATERIAL WHICH CAN CAUSE BIRTH DEFECT. CONTAINS MATERIAL WHICH MAY CAUSE BLOOD, KIDNEYS, LIVER, HEART DAMAGE. MAY CAUSE EYE IRRITATION. MAY CAUSE SKIN IRRITATION. MAY CAUSE RESPIRATORY TRACT IRRITATION Keep away from heat, sparks and flame. Avoid contact with eyes Avoid breathing vapors or spray mists. Avoid contact with skin and clothing. Keep container closed. Use only with adequate ventilation. Avoid exposure during pregnancy. Wash thoroughly after handling. Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion. Routes of Entry Potential Acute Health Effects Eyes Hazardous in case of eye contact (irritant). Skin Sensitization of the product: Not available. Hazardous in case of skin contact (irritant). Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Inhalation Hazardous in case of inhalation (lung irritant). Ingestion Hazardous in case of ingestion. Potential Chronic Health Effects CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Ethanol]. MUTAGENIC EFFECTS: Classified PROVEN for human [Ethanol]. TERATOGENIC EFFECTS: Classified PROVEN for human [Ethanol]. Medical Conditions Repeated exposure to an highly toxic material may produce general deterioration of health by an Aggravated by Overexposure accumulation in one or many human organs. Continued on Next Page Macrosorb K2A Overexposure Not available. /Signs/Symptoms See Toxicological Information (section 11) Page: 2/6 Section 4. First Aid Measures Eye Contact Skin Contact Check for and remove any contact lenses. Do not use an eye ointment. Seek medical attention. After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Wash contaminated clothing before reusing. Allow the victim to rest in a well ventilated area. Seek immediate medical attention. Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention. Not available. Inhalation Ingestion Notes to Physician Section 5. Fire Fighting Measures Flammability of the Product Auto-ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances Explosion Hazards in Presence of Various Substances Fire Fighting Media and Instructions Protective Clothing (Fire) Special Remarks on Fire Hazards Special Remarks on Explosion Hazards Flammable. The lowest known value is 363°C (685.4°F) (Ethanol). The lowest known value is OPEN CUP: 13°C (55.4°F). (Ethanol) Not available. These products are carbon oxides (CO, CO2). Highly flammable in presence of open flames and sparks, of heat. Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. Flammable liquid, insoluble in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray or fog. Be sure to use an approved/certified respirator or equivalent. Not available. Not available. Section 6. Accidental Release Measures Small Spill and Leak Large Spill and Leak Absorb with an inert material and put the spilled material in an appropriate waste disposal. Flammable liquid, insoluble in water. Keep away from heat Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Do not touch spilled material. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities. Continued on Next Page Macrosorb K2A Section 7. Handling and Storage Handling Page: 3/6 To avoid fire or explosion, dissipate static electricity during transfer by grounding and bonding containers and equipment before transferring material. Use explosion-proof electrical (ventilating, lighting and material handling) equipment. Carcinogenic, teratogenic or mutagenic materials should be stored in a separate locked safety storage cabinet or room. Storage Section 8. Exposure Controls/Personal Protection Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Eyes Splash goggles. Body Lab coat. Personal Protection Respiratory Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Hands Gloves. Feet Not applicable. Protective Clothing (Pictograms) Personal Protection in Case of Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be a Large Spill sufficient; consult a specialist BEFORE handling this product. Product Name 1) Ethanol Exposure Limits TWA: 1000 (ppm) TWA: 1900 (mg/m3) Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical State and Appearance Molecular Weight Molecular Formula pH (1% Soln/Water) Boiling/Condensation Point Melting/Freezing Point Critical Temperature Specific Gravity Vapor Pressure Vapor Density Volatility Odor Threshold Evaporation Rate Liquid. (Suspension.) Not applicable. Not applicable. Not applicable. Odor Taste Color Not available. Not available. Not available. The lowest known value is 78.4°C (173.1°F) (Ethanol). May start to solidify at -114.1°C (-173.4°F) based on data for: Ethanol. Not available. The only known value is 0.789 (Water = 1) (Ethanol). Not available. The highest known value is 1.6 (Air = 1) (Ethanol). Not available. The highest known value is 180 ppm (Ethanol) Not available. Continued on Next Page Macrosorb K2A VOC Viscosity LogKow Ionicity (in Water) Dispersion Properties Solubility Page: 4/6 Not available. Not available. Not available. Not available. Not available. Insoluble in cold water, hot water. Physical Chemical Comments Not available. Section 10. Stability and Reactivity Stability and Reactivity Conditions of Instability The product is stable. Not available. Incompatibility with Various Slightly reactive to reactive with oxidizing agents. Substances Hazardous Decomposition Products Hazardous Polymerization Not available. No. Section 11. Toxicological Information Toxicity to Animals WARNING: THE LC50 VALUES HEREUNDER ARE ESTIMATED ON THE BASIS OF A 4-HOUR EXPOSURE. Acute oral toxicity (LD50): 3450 mg/kg [Mouse]. (Ethanol). Acute toxicity of the vapor (LC50): 20697.9 ppm 4 hour(s) [Mouse]. (Ethanol). Chronic Effects on Humans CARCINOGENIC EFFECTS: Classified 3 (Not classifiable for human.) by IARC [Ethanol]. MUTAGENIC EFFECTS: Classified PROVEN for human [Ethanol]. TERATOGENIC EFFECTS: Classified PROVEN for human [Ethanol]. DEVELOPMENTAL TOXICITY: Classified Development toxin [PROVEN] [Ethanol]. The substance is toxic to blood, kidneys, liver, heart. Other Toxic Effects on Humans Hazardous in case of skin contact (irritant), of ingestion, of inhalation (lung irritant). Special Remarks on Toxicity Not available. to Animals Special Remarks on Chronic Effects on Humans Special Remarks on Other Toxic Effects on Humans Not available. To the best of our knowledge, the toxicological properties of this product have not been thoroughly investigated. Section 12. Ecological Information Ecotoxicity BOD5 and COD Biodegradable/OECD Mobility Not available. Not available. Not available. Not available. Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation Special Remarks on the Products of Biodegradation The product itself and its products of degradation are not toxic. Not available. Continued on Next Page Macrosorb K2A Section 13. Disposal Considerations Waste Information Waste Stream Page: 5/6 Not available. Not available. Consult your local or regional authorities. Section 14. Transport Information DOT Classification Class 3: Flammable liquid. Flammable liquids n.o.s. (Ethanol) UN1993 Not available. Marine Pollutant Not available. Hazardous Substances Reportable Quantity Special Provisions for Transport TDG Classification ADR/RID Classification IMO/IMDG Classification ICAO/IATA Classification Not available. Not available. Class 3: Flammable liquid. Class 3: Flammable liquid A. Class 3.2: Flammable liquid (Intermediate flashpoint group of liquids having a flashpoint of -18°C (0°F) up to, but not including, 23°C (73°F) c.c.). Class 3: Flammable liquid. Section 15. Regulatory Information HCS Classification U.S. Federal Regulations Class: Combustible liquid having a flash point between 37.8°C (100°F) and 93.3°C (200°F). TSCA 8(b) inventory: Ethanol SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: No products were found. SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were found. SARA 313 toxic chemical notification and release reporting: No products were found. Clean water act (CWA) 307: No products were found. Clean water act (CWA) 311: No products were found. Clean air act (CAA) 112 accidental release prevention: No products were found. Clean air act (CAA) 112 regulated flammable substances: No products were found. Clean air act (CAA) 112 regulated toxic substances: No products were found. Class B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). Class D-2A: Material causing other toxic effects (VERY TOXIC). CEPA DSL: Ethanol International Regulations WHMIS (Canada) EINECS DSCL (EEC) Not available. R11- Highly flammable. R36- Irritating to eyes. R46- May cause heritable genetic damage. R61- May cause harm to the unborn child. No products were found. International Lists Continued on Next Page Macrosorb K2A State Regulations Page: 6/6 Florida: Ethanol Massachusetts RTK: Ethanol New Jersey: Ethanol California prop. 65: This product contains the following ingredients for which the State of California has found to cause birth defects which would require a warning under the statute: Ethanol Section 16. Other Information Label requirements HIGHLY FLAMMABLE LIQUID AND VAPOR, VAPOR MAY CAUSE FLASH FIRE. BIRTH DEFECT HAZARD CONTAINS MATERIAL WHICH CAN CAUSE BIRTH DEFECT. CONTAINS MATERIAL WHICH MAY CAUSE BLOOD, KIDNEYS, LIVER, HEART DAMAGE. MAY CAUSE EYE IRRITATION. MAY CAUSE SKIN IRRITATION. MAY CAUSE RESPIRATORY TRACT IRRITATION Health Fire Hazard Reactivity Personal Protection Hazardous Material Information System (U.S.A.) * 0 National Fire 2 Protection 0 Association (U.S.A.) h 2 Health Fire Hazard 0 0 Reactivity Specific Hazard References Other Special Considerations Not available. Not available. Verified by Company. Printed 9/17/98. Validated by Company on 9/17/98. CALL CHEMTREC: 800.424.9300 OUTSIDE US: 202.483.7616 Notice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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