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Chemical Manufacturing Co. Ltd.
C.O.S.H.H. PACK
CONTENTS:
1. DAMP PROOFING AND REPLASTERING.
2. TIMBER PRESERVATION AND REPAIR.
3. STRUCTURAL WATERPROOFING.
4. PROTECTIVE COATINGS.
5. STRUCTURAL REPAIR.
SECTION 1 :
DAMPROOFING AND REPLASTERING.
DAMPROOFING.
- TRI-CREAM
- TRI-GEL
- TRIJECT-RAPID DPC
- TRIJECT 3 DPC
- TRIJECT 2 SOLVENT DPC
REPLASTERING.
- TRITON RENOVATING PLASTER
- TRIMIX 1
- TRI-REND
TRI-CREAM Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: Publication date Revision date
TR 01/09/2006
1.PRODUCT NAME: TRI-CREAM (Advanced D.P.C Injection System)
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
White Mineral Oil 92062-35-6 50<75% Xn
Siloxane & Alkylalkoxysilane 15% Xi, N
3. HAZARD IDENTIFICATION
This product is not classified under the Chemicals Hazard
Information and Packaging Regulations 2002
4.FIRST AID
CONTACT WITH SKIN Remove contaminated clothing. Wash affected skin with soap
and plenty of water.
CONTACT WITH EYES Wash copiously with water or eye wash for at least 15
minutes. If symptoms persist seek medical attention.
INGESTION Rinse out mouth and then drink plenty of water. Consult
doctor as soon as possible. Keep the person affected quiet.
INHALATION Remove to fresh air.
OTHER INFORMATION
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA Water mist, alcohol foam, carbon dioxide or dry chemical.
SPECIFIC HAZARDS None
CLEAN-UP PROCEDURES Collect contaminated fire fighting water separately. It must not
enter drains. Dispose of fire debris and contaminated fire
fighting water in accordance with official regulations.
Material Safety Data Sheet According to 93/112EC TRI-CREAM
6.HANDLING AND STORAGE
HANDLING PRECAUTIONS Wear rubber gloves and safety glasses or goggles. .
STORAGE INFORMATION Keep containers sealed and store above 5ºC
7.EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear goggles or face shield, PVC or synthetic rubber gloves,
protective footwear, and overalls.
It is advisable to wear a suitable head covering and to apply a
barrier cream (water-resistant type).
Use only in well ventilated areas.
Respiratory protection: Not normally required.
8. SPILL OR LEAK PROCEDURES
Do not allow to enter drains or sewers. Contain and absorb onto
earth or sand and sweep up. Dispose of in accordance with local
regulations.
.PHYSICAL AND CHEMICAL PROPERTIES
Appearance White Cream Odour None
PH - Boiling Point -
Melting Point - Flash Point > 100º C
Self-inflammability Product is not self igniting Autoignition Temp. -
Oxidising Properties - Solubility in Water Fully Miscible
Relative Density @ 20ºC 0.86 g/cm³ Vapour Pressure -
10.STABILITY/REACTIVITY
CONDITIONS TO AVOID Avoid working in confined spaces with poor ventilation.
MATERIALS TO AVOID Avoid any strong acids and strong bases.
HAZARDOUS DECOMPOSITION PRODUCTS: None if used properly.
None if stored properly.
In the long term ethanol is formed by hydrolysis.
11.TOXICOLOGICAL INFORMATION
INHALATION Alkoxy silane: Do not inhale aerosol mist because of the
risk of lung damage.
SKIN CONTACT No irritating effect.
SKIN ABSORPTION - (Cont’d)
TRI-CREAM Material Safety Data Sheet According to 93/112EC
11.TOXICOLOGICAL INFORMATION (cont’d)
EYE CONTACT No irritating effect.
INGESTION No acute oral data available
ACUTE OVEREXPOSURE -
CHRONIC OVEREXPOSURE -
12.ECOLOGICAL INFORMATION
BIODEGRADABILITY Product hydrolyses to ethanol, silanol and/or siloxanol
compounds.
AQUATIC TOXICITY Considered to be a weak water pollutant.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Disposal through an authorised contractor to an
incinerator site. In accordance with the Control of
Pollution Act 1974. Control of pollution (Special
Waste) Regulations 1980 apply. Hazardous waste as
defined by EC Council Directive 91/689/EEC.
Disposal outside the UK in accordance with local
regulations governing hazardous liquid and solid
wastes.
14. TRANSPORT INFORMATION
PACKAGING 5 litre Tub.
Not classified as hazardous for transport purposes.
15. REGULATORY INFORMATION
The COSHH Regulations 2002 may apply to the use of this product at work.
16.OTHER INFORMATION
BWPDA DP6: Safety in damp proofing
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRI-GEL Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: Publication date Revision date
TR 30/4/2003
1.PRODUCT NAME: TRI-GEL (Ready to use waterbased d.p.c gel)
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Potassium methylsiliconate 031795-24-1 250-807-9 10-25 C, Corrosive R35
Potassium hydroxide 001310-58-3 215-181-3 5-10 C, Corrosive R35
3. HAZARD IDENTIFICATION
Corrosive – causes severe burns
Highly alkaline, avoid contact with acids.
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water. Remove contaminated clothing,
shoes or boots.
CONTACT WITH EYES Wash out with water for at least 15 minutes. Seek medical advice.
INGESTION Rinse the mouth (do not swallow), Seek medical advice.
DO NOT INDUCE VOMITING.
INHALATION Remove to fresh air.
OTHER INFORMATION
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA As appropriate to surrounding fire
SPECIFIC HAZARDS Following evaporation of water, the residue may burn: Toxic
gases are released. Hazardous dust is released.
SPECIAL PROTECTIVE EQUIPMENT Full protective clothing.
Material Safety Data Sheet According to 93/112EC TRI-GEL
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount
involved, which may include eye/face protection and PVC or
synthetic rubber gloves, protective footwear, overalls.
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbent and shovel into
a suitable closed container for disposal according to item 13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Material should only be handled by trained personnel.
Wear suitable protective clothing according to item 8.
STORAGE INFORMATION Protect from frost. Keep containers tightly closed in a cool
place. Do not mix or store in galvanised or light metal
containers. Avoid contact with acids.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear goggles or face shield, PVC or synthetic rubber gloves, protective footwear,
and overalls.
It is advisable to wear a suitable head covering and to apply a barrier cream
(water-resistant type).
Wash before meals; shower or bathe after work. Do not smoke whilst handling
the product.
Do not wear contaminated clothing.
EXPOSURE LIMITS Potassium hydroxide: OES: 2mg/m³ - (short-term
exposure limit – 15minute reference period)
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Colourless to Yellowish Gel Oxidising properties None
Odour Sweetish Vapour pressure 2.3 Kpa @ 20°c
PH 12 - 13 Relative density 1.17 (15ºC)
Boiling point Not Relevant Bulk density Not relevant
Melting point May crystallise at low temperature Viscosity thixotropic gel
Flash point None Solubility Miscible with water
Flammablity/autoflammability Not Relevant Partition coefficient No data
Explosive properties Not explosive Other data Slowly attacks light metals
TRI-GEL Material Safety Data Sheet According to 93/112EC
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID The product is a strong alkali which reacts violently with acids.
MATERIALS TO AVOID Zinc, aluminium (slowly liberates hydrogen). Ammonium salts
(ammonia).
11.TOXICOLOGICAL INFORMATION
Acute toxicity: no data known.
The high alkalinity of the preparation renders it corrosive. It causes severe burns.
Ingestion may cause nausea and extreme discomfort.
12.ECOLOGICAL INFORMATION
MOBILITY The water-miscibility of the product suggests that it is likely to leach
from soil into groundwater. There is no available data on
sorption/desorption.
DEGRADABILITY Biotic and abiotic degradation are likely to be slow. No data on
persistence.
ACCUMULATION There is no evidence for bioaccumlation or biomagnification.
ECOTOXICITY No data.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Chemical residues are normally regarded as Special Waste. Dispose of
in accordance with local and national regulations.
DISPOSAL OF PACKAGING Uncleaned packaging should be treated as for the product. If
thoroughly rinsed, it may be treated as general waste for recycling,
incineration or landfill, according to regulations.
14. TRANSPORT INFORMATION
INTERNATIONAL REGULATIONS
RAIL/ROAD (RID/ADR): UN No: 3267
Class: 8
Item No: 56b
Hazard identification No: 80
Labelling: 8 Corrosive
Packaging Group: II
Proper Shipping Name: Caustic Alkali liquid, NOS.
Contains Potassium methylsiliconate/Potassium
Hydroxide.
Marine pollutant: No.
Material Safety Data Sheet According to 93/112EC TRI-GEL
15. REGULATORY INFORMATION
CLASSIFICATION Corrosive (C)
LABEL INFORMATION
CONTAINS POTASSIUM HYDROXIDE, POTASSIUM METHYL SILICONATE.
R35: CAUSES SEVERE BURNS.
S26: IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY with plenty of water and seek medical
advice.
S35: THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF IN A SAFE WAY.
S36/37/39: WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE PROTECTION.
S45: IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL seek medical advice immediately (show the label
where possible).
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), the Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
USES: Damp-proofing for buildings (For further information, refer to the product technical data sheet).
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIJECT-RAPID DPC Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: Publication date Revision date
TR219
1.PRODUCT NAME: TRIJECT-RAPID DPC
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Potassium methylsiliconate 031795-24-1 47 C, Corrosive R35
Potassium hydroxide 001310-58-3 215-181-3 19 C, Corrosive R35
3. HAZARD IDENTIFICATION
Corrosive – causes severe burns
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of water or soap and water. Immediately remove
contaminated clothing.
CONTACT WITH EYES Wash out with water for several minutes. Seek medical advice.
INGESTION Rinse the mouth (do not swallow), and give copious fluids to drink.
DO NOT INDUCE VOMITING.
INHALATION Remove to fresh air.
OTHER INFORMATION Advice to doctor: Allow cortisone spray inhalation at the earliest
opportunity.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA As appropriate to surrounding fire
SPECIAL PROTECTIVE EQUIPMENT Full protective clothing.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount
involved, which may include eye/face protection and PVC or
synthetic rubber gloves, protective footwear, overalls.
(Contd.)
Material Safety Data Sheet According to 93/112EC TRIJECT-RAPID DPC
6.ACCIDENTAL RELEASE MEASURES (contd.)
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbent and shovel into
a suitable closed container for disposal according to item 13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Material should only be handled by trained personnel.
Wear suitable protective clothing according to item 8.
STORAGE INFORMATION Protect from frost. Keep containers tightly closed in a cool
place. Do not mix or store in galvanised or light metal
containers.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear goggles or face shield, PVC or synthetic rubber gloves, protective footwear,
and overalls.
It is advisable to wear a suitable head covering and to apply a barrier cream
(water-resistant type).
Wash before meals, shower or bathe after work. Do not smoke whilst handling the
product.
Do not wear contaminated clothing.
EXPOSURE LIMITS None assigned in EH40
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Colourless liquid Oxidising properties None
Odour None Vapour pressure Not relevant
pH 14 Relative density 1.030 – 1.34 (15ºC)
Boiling point Not Relevant Bulk density Not relevant
Melting point May crystallise at low temperature Viscosity 12cS (25°C)
Flash point None Solubility Miscible with water
Flammablity/autoflammability Not Relevant Partition coefficient No data
Explosive properties Not explosive Other data Slowly attacks light metals
TRIJECT-RAPID DPC Material Safety Data Sheet According to 93/112EC
10.STABILITY/REACTIVITY
STABILITY Stable
CONDITIONS TO AVOID No special requirements
MATERIALS TO AVOID Zinc, aluminium (slowly liberates hydrogen). Ammonium salts (ammonia).ACIDS
11.TOXICOLOGICAL INFORMATION
Acute toxicity: no data known.
The high alkalinity of the preparation renders it corrosive. It causes severe burns.
Ingestion may cause nausea and extreme discomfort.
12.ECOLOGICAL INFORMATION
MOBILITY The water-miscibility of the product suggests that it is likely to leach
from soil into groundwater. There is no available data on
sorption/desorption.
DEGRADABILITY Biotic and abiotic degradation are likely to be slow. No data on
persistence.
ACCUMULATION There is no evidence for bioaccumlation or biomagnification.
ECOTOXICITY No data.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Chemical residues are normally regarded as Special Waste. Dispose of
in accordance with local and national regulations.
DISPOSAL OF PACKAGING Uncleaned packaging should be treated as for the product. If
thoroughly rinsed, it may be treated as general waste for recycling,
incineration or landfill, according to regulations.
14. TRANSPORT INFORMATION
UN NO. 1814
PROPER SHIPPING NAME Caustic Alkali Liquid, NOS. Contains Potassium
methylsiliconate/Potassium hydroxide
EMERGENCY ACTION CODE 2X
ADR/RID Class 8. Item 42(b)
IMCO Class 8. IMDG Code page 8136
MFAG Table No. 705
EmS No. 8-06
ICAO/IATO Class 8. Passenger aircraft: packing 809, max.1 litre nett. Cargo:
packing 813, max. 30 litres nett.
PACKING GROUP 2
LABEL Corrosive
Material Safety Data Sheet According to 93/112EC TRIJECT-RAPID DPC
15. REGULATORY INFORMATION
CLASSIFICATION Corrosive (C)
LABEL INFORMATION
CONTAINS POTASSIUM HYDROXIDE.
R35: CAUSES SEVERE BURNS.
S1/2: KEEP LOCKED UP AND OUT OF REACH OF CHILDREN.
S23: DO NOT BREATHE SPRAY.
S26: IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY with plenty of water and seek medical
advice.
S36/37/39: WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE PROTECTION.
S45: IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL seek medical advice immediately (show the label
where possible).
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), the Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIJECT 3 Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: Publication date Revision date
TR204 20/02/97
1.PRODUCT NAME: TRIJECT 3
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Potassium methylsiliconate 031795-24-1 35 C, Corrosive R35
Potassium hydroxide 001310-58-3 215-181-3 14 C, Corrosive R35
3. HAZARD IDENTIFICATION
Corrosive – causes severe burns
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water.
CONTACT WITH EYES Wash out with water for several minutes. Seek medical advice.
INGESTION Rinse the mouth (do not swallow), and give copious fluids to drink.
DO NOT INDUCE VOMITING.
INHALATION Remove to fresh air.
OTHER INFORMATION Advice to doctor: Allow cortisone spray inhalation at the earliest
opportunity.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA As appropriate to surrounding fire
SPECIAL PROTECTIVE EQUIPMENT Full protective clothing.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount
involved, which may include eye/face protection and PVC or
synthetic rubber gloves, protective footwear, overalls.
(Contd.)
Material Safety Data Sheet According to 93/112EC TRIJECT 3
6.ACCIDENTAL RELEASE MEASURES (contd.)
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbent and shovel into
a suitable closed container for disposal according to item 13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Material should only be handled by trained personnel.
Wear suitable protective clothing according to item 8.
STORAGE INFORMATION Protect from frost. Keep containers tightly closed in a cool
place. Do not mix or store in galvanised or light metal
containers.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear goggles or face shield, PVC or synthetic rubber gloves, protective footwear,
and overalls.
It is advisable to wear a suitable head covering and to apply a barrier cream
(water-resistant type).
Wash before meals; shower or bathe after work. Do not smoke whilst handling
the product.
Do not wear contaminated clothing.
EXPOSURE LIMITS None assigned in EH40
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Colourless liquid Oxidising properties None
Odour None Vapour pressure Not relevant
PH 12 - 13 Relative density 1.24 (15ºC)
Boiling point Not Relevant Bulk density Not relevant
Melting point May crystallise at low temperature Viscosity 6-9cS (25°C)
Flash point None Solubility Miscible with water
Flammablity/autoflammability Not Relevant Partition coefficient No data
Explosive properties Not explosive Other data Slowly attacks light metals
10.STABILITY/REACTIVITY
STABILITY Stable
CONDITIONS TO AVOID No special requirements
MATERIALS TO AVOID Zinc, aluminium (slowly liberates hydrogen). Ammonium salts (ammonia).
TRIJECT 3 Material Safety Data Sheet According to 93/112EC
11.TOXICOLOGICAL INFORMATION
Acute toxicity: no data known.
The high alkalinity of the preparation renders it corrosive. It causes severe burns.
Ingestion may cause nausea and extreme discomfort.
12.ECOLOGICAL INFORMATION
MOBILITY The water-miscibility of the product suggests that it is likely to leach
from soil into groundwater. There is no available data on
sorption/desorption.
DEGRADABILITY Biotic and abiotic degradation are likely to be slow. No data on
persistence.
ACCUMULATION There is no evidence for bioaccumlation or biomagnification.
ECOTOXICITY No data.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Chemical residues are normally regarded as Special Waste. Dispose of
in accordance with local and national regulations.
DISPOSAL OF PACKAGING Uncleaned packaging should be treated as for the product. If
thoroughly rinsed, it may be treated as general waste for recycling,
incineration or landfill, according to regulations.
14. TRANSPORT INFORMATION
UN NO. 1719
PROPER SHIPPING NAME Caustic Alkali Liquid, NOS. Contains Potassium
methylsiliconate/Potassium hydroxide
EMERGENCY ACTION CODE 2X
ADR/RID Class 8. Item 42(b)
IMCO Class 8. IMDG Code page 8136
MFAG Table No. 705
EmS No. 8-06
ICAO/IATO Class 8. Passenger aircraft: packing 809, max.1 litre nett. Cargo:
packing 813, max. 30 litres nett.
PACKING GROUP 3
LABEL Corrosive
Material Safety Data Sheet According to 93/112EC TRIJECT 3
15. REGULATORY INFORMATION
CLASSIFICATION Corrosive (C)
LABEL INFORMATION
CONTAINS POTASSIUM HYDROXIDE.
R35: CAUSES SEVERE BURNS.
S1/2: KEEP LOCKED UP AND OUT OF REACH OF CHILDREN.
S23: DO NOT BREATHE SPRAY.
S26: IN CASE OF CONTACT WITH EYES, RINSE IMMEDIATELY with plenty of water and seek medical
advice.
S36/37/39: WEAR SUITABLE PROTECTIVE CLOTHING, GLOVES AND EYE/FACE PROTECTION.
S45: IN CASE OF ACCIDENT OR IF YOU FEEL UNWELL seek medical advice immediately (show the label
where possible).
S51: USE ONLY IN WELL VENTILATED AREAS.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), the Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIJECT 2 Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: Publication date Revision date
TR201 02/03/97 11/03/2004
HARMFUL
1.PRODUCT NAME: TRIJECT 2
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
De-aromatised white spirit 64742-48-9 265-150-3 96 Xn R10, R65, R66
Silicone Resin 4 R10, R52, R53
3. HAZARD IDENTIFICATION
Flammable
Harmful: May cause lung damage if swallowed
Repeated exposure may cause skin drying and cracking
HARMFUL
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water.
CONTACT WITH EYES Wash out with water for several minutes. If redness and/or irritation
persists, seek medical advice.
INGESTION Rinse the mouth (do not swallow), and give water or milk to drink.
Seek medical advice. DO NOT INDUCE VOMITING.
INHALATION Remove to fresh air if fumes cause irritation of nose or throat.
OTHER INFORMATION Treat symptomatically
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA Dry powder or foam. For small fires use CO . Never use water
²
jet.
Flash point 40°C.
SPECIAL PROTECTIVE EQUIPMENT For fires in confined spaces, use breathing apparatus.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount
involved, which may include eye/face protection, PVC or
synthetic rubber gloves, protective footwear, overalls.
(Contd.)
Material Safety Data Sheet According to 93/112EC TRIJECT 2
6.ACCIDENTAL RELEASE MEASURES (contd.)
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbent and shovel into
a suitable closed container for disposal according to item 13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Observe good hygiene standards and minimise skin contact.
Wear suitable protective clothing according to item 8.
STORAGE INFORMATION Keep containers tightly closed in a cool place, out of direct
sunlight. Keep stored well ventilated.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Where prolonged or repeated exposure is likely, protective clothing should be worn,
including eye protection and PVC or synthetic rubber gloves.
Wash hands and exposed skin before meals and after work. Do not eat, drink or smoke
whilst handling the product.
Do not wear contaminated clothing. Ventilate confined spaces thoroughly.
EXPOSURE LIMITS LTEL for solvent: 1000 mg/m³ (8hr. TWA)
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear, colourless liquid Oxidising properties None
Odour Paraffinic Vapour pressure < 10 mbar @ 37.8°C
PH Not relevant Relative density 0.775 – 0.785 (15ºC)
Boiling point 160º to 200°C Bulk density Not relevant
Melting point Not Relevant Viscosity 1.24cS @ 20°C
Flash point 40ºC Solubility Insoluble in water
Autoignition temperature 230°C Partition coefficient No data
Flammability limits LEL 0.6%,UEL 8.0% Other data Aromatic content 0.4% vol, typically
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.(Protect from heat and ignition
source
CONDITIONS TO AVOID High temperatures (flash point 40°C)
MATERIALS TO AVOID Strong oxidising agents, strong acids/alkalis and halogens.
TRIJECT 2 Material Safety Data Sheet According to 93/112EC
11.TOXICOLOGICAL INFORMATION
Toxicity following a single exposure to high levels of the solvent component is of a low order. Prolonged
and repeated contact may cause drying of the skin and possibly dermatitis. Prolonged inhalation of spray
mist may cause inflammation of the lungs. The major hazard is lung damage from aspiration – medical
supervision for 24-48 hours is recommended if aspiration could have occurred.
The Permethrin may cause a stinging or burning sensation on the skin (without lesions).
LD50 oral (rat) > 5g/kg LD50 dermal (rabbit) > 5g/kg.
12.ECOLOGICAL INFORMATION
MOBILITY The solvent is volatile, and the active ingredient decomposes in contact
with water, becoming fixed in the soil.
DEGRADABILITY Biodegrades slowly. If admitted with care into adapted bio-treatment
plants, no adverse effects on the live sludge are to be expected.
ACCUMULATION Has the potential to bioaccumulate. Log Pow = 4.07
ECOTOXICITY Solvent is classed as non-toxic.
Silicone is moderately toxic.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Chemical residues are normally regarded as Special Waste. Dispose of
in accordance with local and national regulations. Can be burned in
domestic refuse incinerators in accordance with local regulations.
DISPOSAL OF PACKAGING Uncleaned packaging should be treated as for the product. If
thoroughly rinsed, it may be treated as general waste for incineration or
landfill, according to regulations.
14. TRANSPORT INFORMATION
UN NO. 1993
PROPER SHIPPING NAME FLAMMABLE LIQUID, NOS. Triject 2, contains 96% white spirit
EMERGENCY ACTION CODE 3Y
ADR/RID Class 3. Item 31(c)
IMCO Class 3.3 IMDG Code page
MFAG Table No.
EmS No.
ICAO/IATO Class 3.2
PACKING GROUP 3
LABEL Flammable
Material Safety Data Sheet According to 93/112EC TRIJECT 2
15. REGULATORY INFORMATION
CLASSIFICATION Harmful: may cause lung damage if swallowed
Flammable
Repeated exposure may cause skin cracking and drying
LABEL INFORMATION
PRECAUTIONS
Keep out of the reach of children
Do not breathe vapour/spray
Avoid contact with skin
In case of fire use foam/dry powder/CO . Do not use water
Avoid release to the environment
²
If swallowed, do not induce vomiting, seek medical advice immediately and show the container or label.
Use only in well-ventilated areas.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRITON RENOVATING PLASTER Material Safety Data Sheet According to 93/112EC
Triton Chemical Manufacturing Co. Ltd.
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS REF: Publication Date Revision Date
10/11/2005
1. PRODUCT NAME: TRITON RENOVATING PLASTER HSE No.
2. COMPOSITION/INFORMATION ON INGREDIENTS
Controlled blends of ordinary Portland cement, expanded perlite aggregate,
limestone flour and hydrated lime.
3. HAZARD IDENTIFICATION
Respirable dust inhaled over a prolonged period of time could constitute a
health hazard.
Irritaring to eyes and skin.
Risk of serious damage to eyes.
May cause burns in the presence of moisture due to generation of strong
alkaline solutions of calcium hydroxide.
May cause allergic dermatitis due to the sensitivity of an individuals skin to
hexavelent chromium salts in the presence of moisture
4. FIRST AID MEASURES
CONTACT WITH SKIN An irritant, may cause burns in the presence of moisture. Remove
contaminated clothing. Wash immediately with plenty of water.
CONTACT WITH EYES Causes painful irritation and may cause serious damage to eyes unless
immediate treatment is given. Speed is essential. Remove particles with cotton
wool bud, irrigate with eyewash or clean water until medical help is obtained.
Obtain medical attention as soon as possible.
INGESTION Unlikely to cause any reactions. Larger doses may irritate gastrointestinal
tract. Do not induce vomiting, wash out mouth with water and give copious
quantities of water to drink.
INHALATION Irritating to the respiratory tract in high concentration. Remove from exposure
and keep warm and at rest. Irrigate nose and throat with water for at least 20
minutes.
FURTHER TREATMENT Symptomatic, if necessary. No known delay effects. Prolonged or repeated
contact with skin may result in more severe irritation or dermatitis. Prolonged
repeated inhalation of high dust concentractions may cause ulceration and
perforation of the nasal septum and pneumonitis. It is advisable to ensure that
eyewash facilities are readily available where Portland cement may be
handled.
Material Safety Data Sheet TRITON RENOVATING PLASTER
5. FIRE FIGHTING MEASURES
Non combustible and inhibits the spread of flame. No special fire fighting procedure, extinguisher media or
explosion hazard is identified.
6. ACCIDENTAL RELEASE MEASURES
SPILLAGES Contain spillage and keep dry if possible. Use vacuum suction unit, or shovel
into bags (using appropriate protective clothing (See section 8). Cover or
enclose area if possible to avoid unnecessary dust hazard. The material can be
slurried by the addition of water (see Hazardous ingredient, section 2) but will
subsequently set as a hard material. Avoid contamination of drains and
watercourses. Spillage into watercourses must be alerted to the Environment
Agency or other appropriate regulatory body.
7. HANDLING AND STORAGE
Assess manual handling requirements which may need two man lifting
techniques. The product should be handled to minimise the creation of airborne
dust particles. Approved goggles and dust masks should be worn as well as
long sleeved garments, full length trousers, Wellington boots and gloves.
Avoid saturating clothing with mix water, which is alkaline and may lead to
skin burns.
STORAGE Bags should be palletised and kept dry. Bulk products should be stored in silos
and kept dry. Dust collection system should be utilised to minimise the
creation of dust.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
OCCUPATION EXPOSURE STANDARD: Respirable dust – 4mg/m³ (8hr TWA)
Total inhalable dust – 10mg/m³ (8hr TWA)
Handling systems should preferably be enclosed, or suitable ventilation installed to maintain atmospheric
dust below OES. Wear suitable respiratory protection equipment if exposure to atmospheric dust levels
above occupational exposure standard is likely. Use approved dust respirators to EN149 category FFP3,
or air-stream helmet for heavy exposure. Rubber, leather or fabric/composite gloves provide suitable
hand protection. Wide vision full goggles to BS2092 grade 1 impact, with anti-mist for eye protection.
Long sleeved overalls, close fitting at openings. Boots that resist dust penetration.
9. PHYSICAL & CHEMICAL PROPERTIES
APPEARANCE: Coarse Powder SOLUBILITY IN WATER: Insoluble
ODOUR: None SOLUBILITY IN SOLVENT: Insoluble
PH: Highly Alkaline PARTITION COEFFICIENT: N/A
BOILING POINT: N/A FLASH POINT: N/A
MELTING POINT: N/A AUTO IGNITION: N/A
EXPLOSIVE PROPERTIES: N/A OXIDISING PROPERTIES: N/A
VAPOUR PRESSURE: N/A DENSITY: 1.7
TRITON RENOVATING PLASTER Material Safety Data Sheet According to 93/112EC
10. STABILITY AND REACTIVITY
MATERIALS TO AVOID: None
50
CONDITIONS TO AVOID: Water/Moisture (not controlled)
HAZARDOUS DECOMPOSITION
PRODUCTS None. The addition of water produced alkali by-products.
11. TOXICOLOGICAL INFORMATION
INHALATION: High concentration of dust may be irritating to the respiratory tract.
INDIGESTION: May cause irritation of the gastrointestinal tract.
SKIN: Irritant in the presence of moisture. May cause burns.
EYES: Painful irritant, with risk of severe and permanent damage to eyes.
LONG TERM EXPOSURE: Prolonged and repeated skin contact may cause irritant contact
dermatitis and/or allergic (chromium) dermatitis. Allergic dermatitis
more commonly arises through contact with cement/water mixture than
dry cement.
12. ECOLOGICAL INFORMATION
ECOTOXICITY: The product is considered to be non toxic. Harmful to aquatic
organisms in prolonged contact times.
MOBILITY: Sparingly soluble in water to form alkaline solution. Low mobility in
most ground conditions.
PERSISTENCE & DEGRADATION Non bio-degradable – reacts with atmospheric and ground moisture
and carbon dioxide to form a hard crystalline gel of calcium
silicate/aluminate hydrates.
13. DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Disposal should be in accordance with current local and national
legislation. Portland cement can normally be disposed only to licensed
waste facilities.
DISPOSAL OF PACKAGING Contaminated packaging can be incinerated.
14. TRANSPORT INFORMATION
Not classified as hazardous for transport
IMDG (Sea) Not classified
ADR (Road) Not classified
RID (Rail) Not classified
IATA (Air) Not classified
Material Safety Data Sheet TRITON RENOVATING PLASTER
15. REGULATORY INFORMATION
The Chemicals (Hazard Information and Packaging for Supply) Regulations 2002. Statutory Instrument 2002
No. 1689.
Classification for conveyance: None
Classification for supply: Irritant
LABEL INFORMATION
R38: Irritating to skin
R41: Risk of serious damage to eyes
S26: In case of contact with eyes, rinse immediately with water and seek medical advice.
S37,S39: Wear suitable gloves and eye/face protection.
S2: Keep out of reach of children
SAFETY PHRASES
15.2 – Occupational Exposure Limits 2002 – HSE Guidance Note EH40/02
OES Inhalable dust – 10mg/m³ (8hr TWA)
Respirable dust – 4mg/m³ (8hr TWA)
16. OTHER INFORMATION
Training advice: Wear and use of PPE
Recommended Uses and Restrictions: DIY and industrial applications
Sources of Key Data Used to Compile Data Sheet: EH40, P.P.E. Regulations 1992
Other: EH44 “Dust in the Workplace”
The information contained in this data sheet is to the best of our knowledge accurate at the date of
publication, but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the
technical data sheet for the product.
Abbreviations: OES - occupational exposure standard. STEL - short-term exposure limit. LTEL – long term
exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIMIX 1 Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
205 20/02/97
1.PRODUCT NAME: TRIMIX 1
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Potassium oleate 11 None None assigned
3. HAZARD IDENTIFICATION
Not hazardous under normal conditions of use.
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of water.
CONTACT WITH EYES Wash out with water. Seek medical advice if irritation persists.
INGESTION Rinse the mouth (do not swallow), and give copious fluids to drink.
DO NOT INDUCE VOMITING.
INHALATION Remove to fresh air.
OTHER INFORMATION Treat symptomatically
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA As appropriate to surrounding fire
SPECIAL PROTECTIVE EQUIPMENT No special requirements.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing including eye/face protection
and PVC or synthetic rubber gloves.
(Contd.)
Material Safety Data Sheet According to 93/112EC TRIMIX 1
6.ACCIDENTAL RELEASE MEASURES (contd.)
ENVIRONMENTAL PRECAUTIONS Do not allow to enter watercourses.
Discharge of small amounts to public sewers is normally permissable.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbent and shovel into
a suitable closed container for disposal according to item 13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS If large amounts are to be handled, wear suitable protective
clothing according to item 8.
STORAGE INFORMATION Protect from frost. Keep containers tightly closed in a cool
place.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
No special requirements for exposure control – observe normal industrial hygiene
practices.
If large quantities are handled, it is advisable to wear eye protection and PVC or
rubber gloves.
EXPOSURE LIMITS None assigned in EH40
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Pale Blue liquid Oxidising properties None
Odour Slight fatty odour Vapour pressure Not relevant
pH 9 Relative density 0.99 – 1.01 (15ºC)
Boiling point 102ºC Bulk density Not relevant
Melting point May separate at low temperature Viscosity As for water
Flash point None Solubility Miscible with water
Flammability/autoflammability Not relevant Partition coefficient No data
Explosive properties No explosive Other data
10.STABILITY/REACTIVITY
STABILITY Stable
CONDITIONS TO AVOID No special requirements
MATERIALS TO AVOID No special requirements
TRIMIX 1 Material Safety Data Sheet According to 93/112EC
11.TOXICOLOGICAL INFORMATION
Potassium oleate is not toxic and is a recognised food additive.
12.ECOLOGICAL INFORMATION
MOBILITY The water-miscibility of the product suggests that it is likely to leach
from soil into groundwater. There is no available data on
sorption/desorption.
DEGRADABILITY Readily biodegrades in the soil or in sewage treatment works.
ACCUMULATION There is no evidence for bioaccumlation or biomagnification.
ECOTOXICITY There is no evidence that the product is ecotoxic.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Chemical residues are normally regarded as Special Waste. Dispose of
in accordance with local and national regulations.
DISPOSAL OF PACKAGING Uncleaned packaging should be treated as for the product. If
thoroughly rinsed, it may be treated as general waste for incineration or
landfill, according to regulations.
14. TRANSPORT INFORMATION
UN NO. None assigned
PROPER SHIPPING NAME
EMERGENCY ACTION CODE
ADR/RID Not classified as hazardous
IMCO Not classified as hazardous
MFAG Table No.
EmS No.
ICAO/IATA Not classified as hazardous
PACKING GROUP
LABEL None
Material Safety Data Sheet According to 93/112EC TRIMIX 1
15. REGULATORY INFORMATION
CLASSIFICATION Not classified as hazardous for supply
LABEL INFORMATION
No precautionary information is given on the label.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRI-REND Material Safety Data Sheet According to 93/112EC
Triton Chemical Manufacturing Co Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: Publication date Revision date
TR205 01/08/2001
1. PRODUCT NAME TRI-REND
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Sodium Metasilicate 6843-92-0 229-912-9 5.0 C, Corrosive R34
Sodium Hydroxide 1310-72-2 215-185-5H <1.0 C, Corrosive R34
3. HAZARD IDENTIFICATION
Irritating to eyes and skin.
4. FIRST AID
CONTACT WITH SKIN Wash with plenty of water.
CONTACT WITH EYES Wash out with water. Seek medical advice if irritation persists.
INGESTION Rinse the mouth (do not swallow), and give copious fluids to drink.
DO NOT INDUCE VOMITING
INHALATION Remove to fresh air.
OTHER INFORMATION Treat Symptomatically.
5. FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA As appropriate to surrounding fire.
SPECIAL PROTECTIVE EQUIPMENT No special requirements.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing including eye/face protection and
PVC or synthetic rubber gloves.
ENVIRONMENTAL PRECAUTIONS Do not allow to enter watercourses.
Discharge of small amounts to public sewers is normally
permissible.
CLEAN UP PROCEDURES Absorb in dry sand or earth or similar absorbent and shovel into a
suitable closed container for disposal according to item 13.
Material Safety Data Sheet According to 93/112EC TRI-REND
7. HANDLING AND STORAGE
HANDLING PRECAUTIONS If large amounts are to be handled, wear suitable protective
clothing according to item 8.
STORAGE INFORMATION Protect from frost. Keep containers tightly closed in a cool
place.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
No special requirements for exposure control – observe normal industrial hygiene practices.
If large quantities are handled, it is advisable to wear eye protection and PVC or rubber gloves.
EXPOSURE LIMITS None assigned in EH40
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Pale Yellow Liquid Oxidising properties: None
Odour: Slight Fatty Odour Vapour pressure: Not relevant
pH: 11 Relative density: 1.01 – 1.03
Boiling Point: 102°C Bulk density: Not relevant
Melting Point: May separate at low temperature Solubility: Miscible with water
Flash Point: None Partition coefficient: No data
Flammability/Automobility: Not relevant Other data:
Explosive properties: Not explosive
10. STABILITY/REACTIVITY
STABILITY Stable
CONDITIONS TO AVOID Storage in metal containers
MATERIALS TO AVOID Strong acids
11. TOXICOLOGICAL INFORMATION
ACUTE TOXICITY: No data known
12. ECOLOGICAL INFORMATION
MOBILITY The water-miscibility of the product suggests that it is likely to
leach from soil into groundwater. There is no available data on
sorption/desorption. (Contd.)
TRI-REND Material Safety Data Sheet According to 93/112EC
13. ECOLOGICAL INFORMATION (contd.)
DEGRADABILITY Readily biodegrades in the soil or in sewage treatment works.
ACCUMULATION There is no evidence for bioaccumulation or biomagnification.
ECOTOXICITY There is no evidence that the product is ecotoxic.
14. DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Chemical residues are normally regarded as Special Waste.
DISPOSAL OF PACKAGING Uncleaned packaging should be treated as for the product. If
thoroughly rinsed, it may be treated as general waste for
incineration or landfill, according to regulations.
15. TRANSPORT INFORMATION
UN No. None assigned
PROPER SHIPPING NAME
EMERGENCY ACTION CODE
ADR/RID Not classified as hazardous
IMCO Not classified as hazardous
MFAG Table No.
EmS No.
ICAO/IATA Not classified as hazardous
PACKING GROUP
LABEL None
16. REGULATORY INFORMATION
CLASSIFICATION: Irritant
LABEL INFORMATION:
IRRITATING TO EYES AND SKIN
INCASE OF CONTACT WITH EYES, Rinse immediately with plenty of water and seek medical advice.
WEAR SUITABLE GLOVES AND EYE/FACE PROTECTION
KEEP OUT OF REACH OF CHILDREN
17. OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication, but we cannot
accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical data sheet for the
product.
Abbreviations: OES – Occupational exposure standard. STEL – short-term exposure limit. LTEL – long term exposure limit.
TWA – time weighted (8 hour) average. LEL – Lower explosive limit. UEL – Upper explosive limit.
SECTION 2 :
TIMBER PRESERVATION AND REPAIR.
PRESERVATION.
- TRIBOR PLUS
- TRIBOR 10
- TRIBOR 20
- TRIBOR GEL
- TRITEC 120
- TRITEC 120 PLUS
- TRITEC 121
- TRITEC 121 PLUS
- TRIMETHRIN OS PLUS
- TRISOL 23
- TRIPASTE PB
REPAIR.
- TRIMOL 15, 34, 35, 36, 40, 41 – Resin
- TRIMOL 15, 34, 35, 36 – Hardener
- TRIMOL 35 & 36 – Filler
- TRIMOL 54 - Hardener
- TRIMOL 54 - Resin
TRIBOR PLUS Material Safety Data Sheet According to 93/112EC
Triton Chemical Manufacturing Co. Ltd.
129 Felixstowe Road, Abbey Wood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
HARMFUL
MSDS Ref: TR Publication date Revision date
20/12/02 17/02/04
1. PRODUCT NAME: TRIBOR PLUS HSE No. 7549
2. COMPOSITION
Hazardous ingredient CAS No. Weight % Symbols Risk Phrases
Disodium Octoborate Tetrahydrate 12280-03-04 20 None None
1,2-Propanediol 57-55-6 27.1 None None
Ethylene Glycol and other inert materials 107-21-1 45 Xn,Harmful R22
Permethrin 52645-53-1 0.4 Xn, Harmful R22
Isononyl Phenyl Ethoxylate 37205-87-1 4.0 Xn, Harmful R22-41-53
3.HAZARD IDENTIFICATION
Irritating to eyes and skin.
Harmful if swallowed
HARMFUL
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of water or soap and water.
CONTACT WITH EYES Wash out with water for several minutes. Seek medical advice.
INGESTION Wash out mouth with water and give water to drink. Do not induce
vomiting. If patient feels unwell, seek medical attention.
INHALATION Remove to fresh air.
OTHER INFORMATION
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA As appropriate to surrounding fire
SPECIAL PROTECTIVE EQUIPMENT No particular requirements
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear respiratory protection if large amounts of dust are generated.
ENVIRONMENTAL PRECAUTIONS No environment hazard.
CLEAN-UP PROCEDURES Sweep up and place in container for re-use or disposal to landfill.
Material Safety Data Sheet According to 93/112EC TRIBOR PLUS
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Observe normal industrial hygiene methods.
STORAGE INFORMATION Store in a cool, dry place.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear suitable gloves, (neoprene/PVC or synthetic rubber). Eye/face protection to BS2092 for chemical
resistance and coveralls. If spraying wear suitable respiratory protection, either an air-fed mask or cartridge
type respirator fitted with P2 or P3 cartridge.
Engineering controls of operator exposure may replace PPE if it provides equal or a higher degree of
protection (ie. Local exhaust ventilation, non-atomising spray etc.).
Wash hands and skin before and after work. Do not apply to surfaces where food is prepared, stored or
eaten. Remove or cover all foodstuffs before application. Do not apply to hot surfaces or unprotected
electrical equipment or naked flames. Keep unprotected persons and animals away from treated surfaces for
48 hours or until surfaces are dry or covered. Avoid excessive contamination of coveralls and launder
regularly.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Cloudy, pale gel Oxidising properties None
Odour None Vapour pressure 30Pa (25°C)
pH 9 (1% in water) Relative density 1200kg/m³
Boiling point >190°C Bulk density Not Relevant
Melting point Not Relevant Viscosity No Data
Flash point >100°C Solubility Soluble in water
Autoignition temperature >370°C Partition coefficient No data
Explosive properties LEL s.6%, UEL 12.5% Other data
10.STABILITY/REACTIVITY
STABILITY Stable
CONDITIONS TO AVOID Protect from moisture (product is hygroscopic)
MATERIALS TO AVOID Strong oxidising agents
11.TOXICOLOGICAL INFORMATION
Low acute oral toxicity LD50 (by calculation) >5000mg/kg
TRIBOR PLUS Material Safety Data Sheet According to 93/112EC
12.ECOLOGICAL INFORMATION
MOBILITY Mobile in the soil.
DEGRADABILITY Not biodegradable
ACCUMULATION There is a likelihood of bioaccumulation or biomagnification.
ECTOTOXICITY Boron is an essential micronutrient for plant life, but phytotoxic in large
amounts.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT: Dispose of by landfill in a commercial site, in accordance with local
and national regulations.
DISPOSAL OF PACKAGING: As for product.
14. TRANSPORT INFORMATION
Not regulated for transport by road, rail, sea or air.
15.REGULATORY INFORMATION
CLASSIFICATION Harmful if swallowed.
This product is approved under the control of pesticides regulations 1986 for use by Professional Operators
as directed. HSE No. 7549.
The information contained in this safety data sheet does not constitute the user’s own assessment of
workplace risk as required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of
publication, but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the
technical data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIBOR 10 Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co.Ltd.
129 Felixstowe Rd, Abbey Wood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
213 13/07/99 17/02/04
1.PRODUCT NAME: TRIBOR 10 HSE NO. 7915
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Disodium octaborate tetrahydrate 12280-03-04 10%
Ethylene glycol 107-21-1 20% Xn, Harmful R22
Benzalkonium Chloride 61789-71-9 2% Xn, Harmful R22,R34
3.HAZARD IDENTIFICATION
Irritant – irritating to eyes and skin
4.FIRST AID
SWALLOWING Rinse mouth and administer 1 pint warm water (cold if not available).
Do not induce vomiting-seek medical attention immediately. Never
admininster anything by mouth to an unconscious person. See also
section 11.
EYES Flush with plenty of water for at least 15 minutes. Seek medical
attention if irritation persists.
INHALATION Remove patient to fresh air, keep warm and at rest. Seek medical
attention immediately.
SKIN Remove contaminated clothing and wash affected areas with soap and
water. Launder contaminated clothing before re-use. If irritation
persists, consult a doctor.
5.FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA Product is non-combustible. Essentially an aqueous solution.
PPE: FIRE Neoprene/PVC or synthetic gloves, chemical resistant boots and
clothing. Breathing apparatus in the event of smoke inhalation.
(Contd.)
Material Safety Data Sheet According to 93/112EC TRIBOR 10
5. FIRE FIGHTING MEASURES (cont'd)
PRODUCTS OF COMBUSTION Exposure to extreme heat may liberate water vapour with trace
quantities of Hydrogen
Chloride and Oxides of Nitrogen and Carbon.
PPE: SPILLAGE Neoprene/PVC or synthetic rubber gloves and eye/face
protection and chemical resistant boots.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Where possible shut off or remove source of leak. Absorb
spillage with sand/sawdust or vermiculite and place into
suitable HDPE/plastic drum. Seal and mark with contents to
await disposal. Wash down with copious water.
If product has entered watercourses or ditches inform Police or
Fire Brigade.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Wear suitable gloves, overalls and eye/face protection. Keep
out of reach of children.
When using, do not eat, drink or smoke.
STORAGE INFORMATION Store in safe, cool, dry conditions, away from food, drink and
animal foodstuffs. Store only in original container, tightly
closed.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear suitable gloves, (neoprene/PVC or synthetic rubber). Eye/face protection to BS2092 for chemical
resistance and coveralls. If spraying wear suitable respiratory protection, either an air-fed mask or cartridge
type respirator fitted with P2 or P3 cartridge.
Engineering controls of operator exposure may replace PPE if it provides equal or a higher degree of
protection (ie. Local exhaust ventilation, non-atomising spray etc.).
Wash hands and skin before and after work. Do not apply to surfaces where food is prepared, stored or
eaten. Remove or cover all foodstuffs before application. Do not apply to hot surfaces or unprotected
electrical equipment or naked flames. Keep unprotected persons and animals away from treated surfaces for
48 hours or until surfaces are dry or covered. Avoid excessive contamination of coveralls and launder
regularly.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear/Amber liquid
Odour Slight (Cont'd).
TRIBOR 10 Material Safety Data Sheet According to 93/112EC
9. PHYSICAL AND CHEMICAL PROPERTIES (Cont'd).
pH 8 Flash Point >100ºC
Boiling Point 100ºC Auto Ignition Not Known
Melting Point N/A Oxidising properties None
Explosives Properties None Density 1.08-1.10g/cm³
Vapour Pressure N/A (Specify Solvent)
Solubility in water Soluble n-Octanol/Water
Solubility in solvent Insoluble
Partition Coefficient N/A
10.STABILITY/REACTIVITY
Stable and non-reactive under normal conditions of handling and storage.
INCOMPATIBLE SUBSTANCES
Strong Oxidising Agents
11.TOXICOLOGICAL INFORMATION
LD (50) 15,000 mg/kg (Wistar Rat Scantox)
EFFECTS OF ACUTE (OVER) EXPOSURE
SKIN: Reddening at the site of contact possible accompanied by itching/stinging.
EYES: Watering, soreness and severe irritation
INHALATION: Due to the low volatility of the product there should be no hazard associated with
inhalation under normal conditions of use. Excessive inhalation of spray mist may
cause irritation of nasal passages and mucous membranes, cough, confusion or
dizziness.
INGESTION: *Abdominal pains, nausea, vomiting, possible reddening of the mouth and gastric
tract.
NB: This product contains 1,2 Ethandiol which can be dangerous in high doses. To
block the Toxic Aldehyde administer Ethanol orally.
Medical Personnel should contact their nearest Poisons Unit for further advice.
12.ECOLOGICAL INFORMATION
Do not allow product, waste or empty container to contaminate ponds, waterways, ditches, drains or water
storage tanks.
Toxic to aquatic life. Possible phytotoxic – avoid contact with plant life. All ingredients potentially
biodegradable.
Do not use on or near bees or bee keeping equipment including hives.
Material Safety Data Sheet According to 93/112EC TRIBOR 10
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT: Disposal of Waste in accordance with the Environmental Protection
Act 1990. Preferably by high temperature incineration at a site
approved and licensed by the Local Authority, operated by a
competent approved and licensed Waste Disposal Contractor.
DISPOSAL OF PACKAGING: Cleaned and empty containers may be disposed of as inert waste
(remove the label). Duty of Care Waste Transfer Form should specify
Pesticide Product.
14. TRANSPORT INFORMATION
Not regulated for transport by road, rail, sea or air.
15.REGULATORY INFORMATION
CLASSIFICATION Irritating to eyes and skin
This product is approved under the Control of Pesticides Regulations 1986 for use by Professional Operators
as directed. HSE No. 6286
The control of Substances Hazardous to Health Regulations 1988 will relate to this product when used at
work.
16.OTHER INFORMATION
Recommended uses and restrictions: Use only as directed
NOTICE TO CUSTOMER:-
ENSURE ALL POTENTIAL USERS OF THIS PRODUCT ARE AWARE OF THIS SDS PRIOR TO
USING THE PRODUCT.
KEEP SDS IN A SAFE PLACE READILY LOCATABLE IN CASE OF FUTURE REQUIREMENT.
READ THIS SDS IN CONJUNCTION WITH THE LABEL AND DIRECTIONS FOR USE ON THE
PRODUCT CONTAINER.
DESTROY ALL OBSOLETE COPIES RELATING TO THIS PRODUCT
THIS SDS RELATES ONLY TO THE PRODUCT SPECIFIED.
COPIES OF THIS DOCUMENT ARE AVAILABLE ON REQUEST.
THIS SAFETY DATA SHEET IS BASED ON THE BEST OF CURRENT INFORMATION AND
ADVICE AVAILABLE TO US AND IS BELIEVED TO BE TRUE AND ACCURATE. NO
LIABILITY CAN BE ACCEPTED FOR LOSS, DAMAGE OR INJURY AS CONDITIONS OF USE
ARE OUTSIDE OUR CONTROL. THIS IS NOT A TECHNICAL SPECIFICATION.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIBOR 20 Material Safety Data Sheet According to 93/112EC
Triton Chemical Manufacturing Co. Ltd.
129 Felixstowe Road, Abbey Wood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
HARMFUL 211 18/4/97 16/02/04
1.PRODUCT NAME: TRIBOR 20 HSE No. 6242
2. COMPOSITION
Hazardous ingredient CAS No. Weight % Symbols Risk Phrases
Disodium Octoborate Tetrahydrate 12280-03-04 20 None None
1,2-Propanediol 28 None None
Ethylene Glycol and other inert materials 107-21-1 52 Xn,Harmful R22
3.HAZARD IDENTIFICATION
Irritating to eyes and skin.
Harmful if swallowed
HARMFUL
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of water or soap and water.
CONTACT WITH EYES Wash out with water for several minutes. Seek medical advice.
INGESTION Wash out mouth with water and give water to drink. Do not induce
vomiting. If patient feels unwell, seek medical attention.
INHALATION Remove to fresh air.
OTHER INFORMATION
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA As appropriate to surrounding fire
SPECIAL PROTECTIVE EQUIPMENT No particular requirements
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear respiratory protection if large amounts of dust are generated.
ENVIRONMENTAL PRECAUTIONS No environment hazard.
CLEAN-UP PROCEDURES Sweep up and place in container for re-use or disposal to landfill.
Material Safety Data Sheet According to 93/112EC TRIBOR 20
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Observe normal industrial hygiene methods.
STORAGE INFORMATION Store in a cool, dry place.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear suitable gloves, (neoprene/PVC or synthetic rubber). Eye/face protection to BS2092 for chemical
resistance and coveralls. If spraying wear suitable respiratory protection, either an air-fed mask or cartridge
type respirator fitted with P2 or P3 cartridge.
Engineering controls of operator exposure may replace PPE if it provides equal or a higher degree of
protection (ie. Local exhaust ventilation, non-atomising spray etc.).
Wash hands and skin before and after work. Do not apply to surfaces where food is prepared, stored or
eaten. Remove or cover all foodstuffs before application. Do not apply to hot surfaces or unprotected
electrical equipment or naked flames. Keep unprotected persons and animals away from treated surfaces for
48 hours or until surfaces are dry or covered. Avoid excessive contamination of coveralls and launder
regularly.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear, pale liquid Oxidising properties None
Odour None Vapour pressure 30Pa (25°C)
pH 9 (1% in water) Relative density 1.18 – 1.20
Boiling point >190°C Bulk density Not Relevant
Melting point Not Relevant Viscosity No Data
Flash point >100°C Solubility Soluble in water
Autoignition temperature >370°C Partition coefficient No data
Explosive properties LEL s.6%, UEL 12.5% Other data
10.STABILITY/REACTIVITY
STABILITY Stable
CONDITIONS TO AVOID Protect from moisture (product is hygroscopic)
MATERIELS TO AVOID Strong oxidising agents
11.TOXICOLOGICAL INFORMATION
Low acute oral toxicity LD50 (by calculation) >5000mg/kg
TRIBOR 20 Material Safety Data Sheet According to 93/112EC
12.ECOLOGICAL INFORMATION
MOBILITY Mobile in the soil.
DEGRADABILITY Not biodegradable
ACCUMULATION There is a likelihood of bioaccumulation or biomagnification.
ECTOTOXICITY Boron is an essential micronutrient for plant life, but phytotoxic in large
amounts.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT: Dispose of by landfill in a commercial site, in accordance with local
and national regulations.
DISPOSAL OF PACKAGING: As for product.
14. TRANSPORT INFORMATION
Not regulated for transport by road, rail, sea or air.
15.REGULATORY INFORMATION
CLASSIFICATION Harmful if swallowed.
This product is approved under the control of pesticides regulations 1986 for use by Professional Operators
as directed. HSE No. 6242.
The information contained in this safety data sheet does not constitute the user’s own assessment of
workplace risk as required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of
publication, but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the
technical data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIBOR GEL Material Safety Data Sheet According to 93/112EC
Triton Chemical Manufacturing Co. Ltd.
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
Non-hazardous 211 18/4/97 18/03/2003
1.PRODUCT NAME: TRIBOR GEL HSE No. 6099
2. COMPOSITION
Hazardous ingredient CAS No. Weight % Symbols Risk Phrases
Disodium Octoborate Tetrahydrate 12230-03-04 46 None None
1,2-Propanediol 57-55-6
3.HAZARD IDENTIFICATION
May cause eye irritation, and mild skin irritation on prolonged contact.
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of water or soap and water.
CONTACT WITH EYES Wash out with water for several minutes. Seek medical advice.
INGESTION Wash out mouth with water and give water to drink. Do not induce
vomiting. If patient feels unwell, seek medical attention.
INHALATION Remove to fresh air.
OTHER INFORMATION
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA As appropriate to surrounding fire
SPECIAL PROTECTIVE EQUIPMENT No particular requirements
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear respiratory protection if large amounts of dust are generated.
ENVIRONMENTAL PRECAUTIONS No environment hazard.
CLEAN-UP PROCEDURES Sweep up and place in container for re-use or disposal to landfill.
Material Safety Data Sheet According to 93/112EC TRIBOR GEL
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Observe normal industrial hygiene methods.
STORAGE INFORMATION Store in a cool, dry place.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Use PVC or synthetic/rubber gloves and eye/face protection when applying the product.
EXPOSURE LIMITS None assigned in EH40
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Colourless gel Oxidising properties None
Odour None Vapour pressure 30Pa (25°C)
pH 9 (1% in water) Relative density 1200kg/m³
Boiling point >190°C Bulk density Not Relevant
Melting point Not Relevant Viscosity No Data
Flash point >100°C Solubility Soluble in water
Autoignition temperature >370°C Partition coefficient No data
Explosive properties LEL s.6%, UEL 12.5% Other data
10.STABILITY/REACTIVITY
STABILITY Stable
CONDITIONS TO AVOID Protect from moisture (product is hygroscopic)
MATERIELS TO AVOID Strong oxidising agents
11.TOXICOLOGICAL INFORMATION
Low acute oral toxicity LD50 (by calculation) >5000mg/kg
12.ECOLOGICAL INFORMATION
MOBILITY Mobile in the soil.
DEGRADABILITY Not biodegradable
ACCUMULATION There is a likelihood of bioaccumulation or biomagnification.
ECTOTOXICITY Boron is an essential micronutrient for plant life, but phytotoxic in large
amounts.
TRIBOR GEL Material Safety Data Sheet According to 93/112EC
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT: Dispose of by landfill in a commercial site, in accordance with local
and national regulations.
DISPOSAL OF PACKAGING: As for product.
14. TRANSPORT INFORMATION
Not regulated for transport by road, rail, sea or air.
15.REGULATORY INFORMATION
CLASSIFICATION Not classified as hazardous.
This product is approved under the control of pesticides regulations 1986 for use by Professional Operators
as directed. HSE No. 6099
The information contained in this safety data sheet does not constitute the user’s own assessment of
workplace risk as required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of
publication, but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the
technical data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRITEC 120 Material Safety Data Sheet According to93/112EC
Triton
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
208 02/04/97 03/03/04
1.PRODUCT NAME: TRITEC 120 HSE NO. 6539
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Permethrin 52645-53-1 258—067-9 4.6 Xn,Harmful R22
Fatty alcohol ethoxylate 68439-46-3 28-32 Xi R41
3. HAZARD IDENTIFICATION
Irritant – irritating to eyes and skin
Risk of serious damage to eyes
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water for at least 5 minutes.
CONTACT WITH EYES Wash out with water for several minutes. Seek medical advice.
INGESTION Rinse the mouth (do not swallow), and give copious fluids to drink.
DO NOT INDUCE VOMITING. Obtain medical attention.
INHALATION Remove to fresh air. Keep warm and at rest.
OTHER INFORMATION Treat symptomatically
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA As appropriate to surrounding fire
SPECIAL PROTECTIVE EQUIPMENT Wear breathing apparatus in confined spaces.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing including eye/face protection
and PVC or synthetic rubber gloves, protective footwear,
overalls. (Contd.)
Material Safety Data Sheet According to 93/112EC TRITEC 120
6.ACCIDENTAL RELEASE MEASURES (contd.)
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbent and shovel into
a suitable closed container for disposal according to item 13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Material should only be handled by trained personnel.
Wear suitable protective clothing according to item 8.
STORAGE INFORMATION Protect from frost. Keep containers tightly closed in a cool
place.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear goggles or face shield, PVC or synthetic rubber gloves, protective footwear and
overalls.
If spraying wear suitable respiratory protection, either an air-fed mask or cartridge
type respirator fitted with a P2 or P3 cartridge.
Wash hands and exposed skin before meals and after use. Do not eat, drink or smoke
whilst handling the product.
Do not wear contaminated clothing.
EXPOSURE LIMITS None assigned in EH40
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear liquid Oxidising properties None
Odour Very slight odour Vapour pressure No data
pH Neutral Relative density 1.01 – 1.03 (15ºC)
Boiling point >100ºC Bulk density Not relevant
Melting point Below 0ºC Viscosity Similar to water
Flash point Above 93ºC Solubility Miscible with water
Flammability/autoflammability No data Partition coefficient No data
Explosive properties No data Other data
10.STABILITY/REACTIVITY
STABILITY Stable
CONDITIONS TO AVOID No special requirements
MATERIALS TO AVOID
TRITEC 120 Material Safety Data Sheet According to 93/112EC
11.TOXICOLOGICAL INFORMATION
Acute Toxicity: LD50 > 10,000mg/Kg, by calculation. May produce a transient burning or stinging sensation
(without lesions) on exposed skin.
12.ECOLOGICAL INFORMATION
MOBILITY The water-miscibility of the product suggests that it is likely to leach
from soil into groundwater. There is no available data on
sorption/desorption.
DEGRADABILITY Biodegradable in natural media. No data on persistence
ACCUMULATION There is no evidence for bioaccumlation or biomagnification.
ECOTOXICITY Extremely toxic to fish (Permethrin LC 96h (trout) 0.009mg/l)
50
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Chemical residues are normally regarded as Special Waste. Dispose of
in accordance with local and national regulations (most likely to be
incineration).
DISPOSAL OF PACKAGING Uncleaned packaging should be treated as for the product. If
thoroughly rinsed, it may be treated as general waste for incineration or
landfill, according to regulations.
14. TRANSPORT INFORMATION
UN NO. None assigned
PROPER SHIPPING NAME
EMERGENCY ACTION CODE
ADR/RID Not regulated
IMCO Not classified as hazardous for carriage by sea
MFAG Table No.
EmS No.
ICAO/IATA --
PACKING GROUP None assigned
LABEL Marine pollutant
15. REGULATION INFORMATION
CLASSIFICATION Irritating to eyes and skin.
Risk of serious damage to eyes
SAFETY PHRASES Keep away from food, drink and animal feeding stuffs.
Keep out of reach of children.
Keep only in the original container.
Keep container tightly closed.
KEEP IN A SAFE PLACE.
ENSURE ADEQUATE VENTILATION before reoccupation.
WASH ANY CONTAMINATION from exposed skin and eyes immediately.
WASH HANDS AND EXPOSED SKIN before meals and after use
In case of contact with eyes, rinse immediately with plenty of water and
seek medical advice. (CONT’D)
Material Safety Data Sheet According to 93/112EC TRITEC 120
15.REGULATORY INFORMATION (CONT’D)
THIS PRODUCT IS APPROVED UNDER THE CONTROL OF PESTICIDES REGULATIONS 1986
FOR USE AS DIRECTED, HSE No. 6539.
To avoid risks to man and the environment, comply with the instructions for use.
LABEL INFORMATION
FOR USE ONLY AS A WOOD PRESERVATIVE
FOR USE ONLY BY PROFESSIONAL OPERATORS
READ ALL PRECAUTIONS BEFORE USE
The (COSHH) Control of Substances Hazardous to Health Regulations 1994 may apply to the use of this product at
work.
FOR USE ONLY BY PROFESSIONAL OPERATORS.
Engineering control of operator exposure must be used where reasonably practicable in addition to the following items
of personal protective equipment.
Wear suitable protective clothing, gloves and eye/face protection.
AVOID EXCESSIVE CONTAMINATION OF COVERALLS AND LAUNDER REGULARLY.
Do not breathe spray. Otherwise wear respiratory protective equipment and eye protection (see HSE Guidance
Booklet HS(G)53, “The Selection, Use and Maintenance of Respiratory Protective Equipment – A Practical Guide”).
However, engineering controls may replace personal protective equipment if a COSHH assessment shows they
provide an equal or higher standard of protection.
DO NOT CONTAMINATE FOODSTUFFS, EATING UTENSILS OR FOOD CONTACT SURFACES.
WHEN USING DO NOT EAT, DRINK OR SMOKE
THIS MATERIAL AND ITS CONTAINER must be disposed of in a safe way.
EXCLUDE ALL UNPROTECTED PERSONS AND ANIMALS DURING TREATMENT AND FOR AT LEAST 1
HOUR AFTER TREATMENT IS COMPLETED.
ENSURE THERE IS A PHYSICAL BARRIER TO PREVENT CONTACT BY UNPROTECTED
PERSONS AND ANIMALS UNTIL TREATED SURFACES ARE VISIBLY DRY.
EXTREMELY DANGEROUS TO FISH AND OTHER AQUATIC LIFE.
REMOVE OR COVER FISH TANKS AND BOWLS before application.
Do not contaminate ground, waterbodies or watercourses with chemicals or used container.
COVER WATER STORAGE TANKS before application.
ALL BATS ARE PROTECTED UNDER THE WILDLIFE AND COUNTRYSIDE ACT 1981. BEFORE
TREATING ANY STRUCTURE USED BY BATS, CONSULT ENGLISH NATURE, SCOTTISH NATURAL
HERITAGE OR THE COUNTRYSIDE COUNCIL FOR WALES. READ ALL PRECAUTIONS BEFORE USE
HSE No. 6539
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRITEC 120 Plus Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref. TR Publication date Revision date
215 13/07/98 03/03/04
1.PRODUCT NAME: TRITEC 120 PLUS HSE NO. 6537
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Permethrin 52645-53-1 258—067-9 2.3 Xn,Harmful R22
Propiconazole 60207-90-1 9.8 Xn, Harmful R22, R50/53
N, Dangerous for
the environment.
Fatty alcohol ethoxylate 68439-46-3 28-32 Xi R41
3. HAZARD IDENTIFICATION
Irritant – irritating to eyes and skin
Risk of serious damage to eyes.
May cause sensitisation by skin contact.
Dangerous for the environment
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water for at least 5 minutes.
CONTACT WITH EYES Wash out with water for several minutes. Seek medical advice.
INGESTION Rinse the mouth (do not swallow), and give copious fluids to drink.
DO NOT INDUCE VOMITING. Obtain medical attention.
INHALATION Remove to fresh air. Keep warm and at rest.
OTHER INFORMATION Treat symptomatically
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA As appropriate to surrounding fire
SPECIAL PROTECTIVE EQUIPMENT Wear breathing apparatus in confined spaces.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing including eye/face protection
and PVC or synthetic rubber gloves, protective footwear,
overalls.
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbent and shovel into a
suitable closed container for disposal according to item 13.
Material Safety Data Sheet According to 93/112EC TRITEC 120 Plus
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Material should only be handled by trained personnel.
Wear suitable protective clothing according to item 8.
STORAGE INFORMATION Protect from frost. Keep containers tightly closed in a cool
place.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear goggles or face shield, PVC or synthetic rubber gloves, protective footwear and
overalls
If spraying wear suitable respiratory protection, either an air-fed mask or cartridge
type respirator fitted with a P2 or P3 cartridge.
Wash hands and exposed skin before meals and after use. Do not eat, drink or smoke
whilst handling the product.
Do not wear contaminated clothing.
EXPOSURE LIMITS None assigned in EH40
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear liquid Oxidising properties None
Odour Very slight odour Vapour pressure No data
pH Neutral Relative density 1.02 – 1.04 (15ºC)
Boiling point >100ºC Bulk density Not relevant
Melting point Below 0ºC Viscosity Similar to water
Flash point Above 93ºC Solubility Miscible with water
Flammability/autoflammability No data Partition coefficient No data
Explosive properties No data Other data
10.STABILITY/REACTIVITY
STABILITY Stable
CONDITIONS TO AVOID No special requirements
MATERIALS TO AVOID
11.TOXICOLOGICAL INFORMATION
Acute Toxicity: LD50 > 10,000mg/Kg, by calculation. May produce a transient burning or stinging
sensation
(without lesions) on exposed skin.
TRITEC 120 Plus Material Safety Data Sheet According to 93/112EC
12.ECOLOGICAL INFORMATION
MOBILITY The water-miscibility of the product suggests that it is likely to leach
from soil into groundwater. There is no available data on
sorption/desorption.
DEGRADABILITY Biodegradable in natural media. No data on persistence
ACCUMULATION There is no evidence for bioaccumlation or biomagnification.
ECOTOXICITY Extremely toxic to fish (Permethrin LC 96h (trout) 0.009mg/l)
50
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Chemical residues are normally regarded as Special Waste. Dispose of in
accordance with local and national regulations (most likely to be
incineration).
DISPOSAL OF PACKAGING Uncleaned packaging should be treated as for the product. If thoroughly
rinsed, it may be treated as general waste for incineration or landfill,
according to regulations.
14. TRANSPORT INFORMATION
UN NO. None assigned
PROPER SHIPPING NAME
EMERGENCY ACTION CODE
ADR/RID Not regulated
IMCO Not classified as hazardous for carriage by sea
MFAG Table No.
EmS No.
ICAO/IATA --
PACKING GROUP None assigned
LABEL Marine pollutant
15. REGULATION INFORMATION
CLASSIFICATION Irritating to eyes and skin
Risk of serious damage to eyes
May cause sensitisation by skin contact
Dangerous for the environment.
SAFETY PHRASES Keep away from food, drink and animal feeding stuffs.
Keep out of reach of children.
Keep only in original container.
Keep container tightly closed.
KEEP IN A SAFE PLACE.
ENSURE ADEQUATE VENTILATION before re-occupation.
WASH ANY CONTAMINATION from skin or eyes immediately.
WASH HANDS AND EXPOSED SKIN before meals and after use.
IRRITATING TO EYES AND SKIN.
In case of contact with eyes, rinse immediately with plenty of water
and seek medical advice.
MAY CAUSE SENSITISATION BY SKIN CONTACT.
DANGEROUS FOR THE ENVIRONMENT.
TOXIC TO AQUATIC ORGANISMS. (CONTD.)
Material Safety Data Sheet According to 93/112EC TRITEC 120 Plus
15.REGULATORY INFORMATION (CONT’D)
MAY CAUSE LONGTERM ADVERSE EFFECTS IN THE
AQUATIC ENVIRONMENT.
THIS PRODUCT IS APPROVED UNDER THE CONTROL OF PESTICIDES REGULATIONS 1986
FOR USE AS DIRECTED. HSE No. 6537.
To avoid risks to man and the environment, comply with the instructions for use.
LABEL INFORMATION:
WOOD PRESERVATIVE FOR PROFESSIONAL USE AGAINST WOOD ROTTING FUNGI AND WOOD
DESTROYING INSECTS.
FOR USE ON WOOD OUT OF GROUND CONTACT OR SURFACE WATER CONTACT.
READ ALL PRECAUTIONS BEFORE USE
The (COSHH) Control of Substances Hazardous to Health Regulations 1994 may apply to the use of this product at
work.
FOR USE ONLY BY PROFESSIONAL OPERATORS.
Engineering control of operator exposure must be used where reasonably practicable in addition to the following items
of personal protective equipment.
Wear suitable protective clothing, gloves and eye/face protection.
AVOID EXCESSIVE CONTAMINATION OF COVERALLS AND LAUNDER REGULARLY.
Do not breathe spray. Otherwise wear respiratory protective equipment and eye protection (see HSE Guidance
Booklet HS(G)53: “The Selection, Use and Maintenance of Respiratory Equipment – A Practical Guide”).
However engineering controls may replace personal protective equipment if a COSHH assessment shows they provide
an equal or higher standard of protection.
DO NOT CONTAMINATE FOODSTUFFS, EATING UTENSILS OR FOOD CONTACT SURFACES.
WHEN USING, DO NO EAT, DRINK OR SMOKE.
THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF IN A SAFE WAY.
EXCLUDE ALL UNPROTECTED PERSONS AND ANIMALS DURING TREATMENT AND FOR AT LEAST 1
HOUR AFTER TREATMENT IS COMPLETED.
ENSURE THERE IS A PHYSICAL BARRIER TO PREVENT CONTACT BY UNPROTECTED PERSONS AND
ANAIMALS UNTIL TREATED SURFACS ARE VISIBLY DRY.
EXTREMELY DANGEROUS TO FISH AND OTHER AQUATIC LIFE.
REMOVE OR COVER ALL FISH TANKS AND BOWLS before application.
Do not contaminate ground, waterbodies or watercourses with chemicals or used container.
COVER WATER STORAGE TANKS before application.
ALL BATS ARE PROTECTED UNDER THE WILDLIFE AND COUNTRYSIDE ACT 1981. BEFORE
TREATING ANY STRUCTURE USED BY BATS, CONSULT ENGLISH NATURE, SCOTTISH NATURL
HERITAGE OR THE COUNTRYSIDE COUNCIL FOR WALES.
READ ALL PRECAUTIONS BEFORE USE., HSE No. 6537.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication, but we cannot
accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical data sheet for the
product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long term
exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper explosive limit.
TRITEC 121 Material Safety Data Sheet According to 93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
217 13/07/98 03/03/04
1. PRODUCT NAME: TRITEC 121 HSE NO. 6541
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Permethrin 52645-53-1 258—067-9 4.6 Xn,Harmful R22
Fatty alcohol ethoxylate 68439-46-3 28-32 Xi R41
3.HAZARD IDENTIFICATION
Irritant – irritating to eyes and skin
Risk of serious damage to eyes
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water for at least 5 minutes
CONTACT WITH EYES Wash out with water for several minutes. Seek medical advice
INGESTION Rinse the mouth (do not swallow), and give copious fluids to drink.
DO NOT INDUCE VOMITING. Obtain medical attention.
INHALATION Remove to fresh air. Keep warm and at rest.
OTHER INFORMATION Treat symptomatically
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA As appropriate to surrounding fire
SPECIAL PROTECTIVE EQUIPMENT Wear breathing apparatus in confined spaces.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing including eye/face protection
and PVC or synthetic rubber gloves, protective footwear,
overalls. (Contd.)
Material Safety Data Sheet According to 93/112EC TRITEC 121
6.ACCIDENTAL RELEASE MEASURES (contd.)
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbent and shovel into
a suitable closed container for disposal according to item 13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Material should only be handled by trained personnel.
Wear suitable protective clothing according to item 8.
STORAGE INFORMATION Protect from frost. Keep containers tightly closed in a cool
place.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear goggles or face shield, PVC or synthetic rubber gloves, protective footwear, and overalls
If spraying wear suitable respiratory protection, either an air-fed mask or cartridge type respirator fitted with
a P2 or P3 cartridge.
Wash hands and exposed skin before meals and after use. Do not eat, drink or smoke whilst
Handling the product.
Do not wear contaminated clothing.
EXPOSURE LIMITS None assigned in EH40
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear liquid Oxidising properties None
Odour Very slight odour Vapour pressure No data
pH Neutral Relative density 1.01 – 1.03 (15ºC)
Boiling point >100ºC Bulk density Not relevant
Melting point Below 0ºC Viscosity Similar to water
Flash point Above 93ºC Solubility Miscible with water
Flammability/autoflammability No data Partition coefficient No data
Explosive properties No data Other data
10.STABILITY/REACTIVITY
STABILITY Stable
CONDITIONS TO AVOID No special requirements
MATERIALS TO AVOID
TRITEC 121 Material Safety Data Sheet According to 93/112EC
11.TOXICOLOGICAL INFORMATION
Acute Toxicity: LD > 10,000mg/Kg, by calculation. May produce a transient burning or stinging sensation
(without lesions) on exposed skin.
12.ECOLOGICAL INFORMATION
MOBILITY The water-miscibility of the product suggests that it is likely
to leach from soil into groundwater. There is no available data on
sorption/desorption.
DEGRADABILITY Biodegradable in natural media. No data on persistence
ACCUMULATION There is no evidence for bioaccumlation or biomagnification.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Chemical residues are normally regarded as Special Waste. Dispose of
in accordance with local and national regulations (most likely to be
incineration).
DISPOSAL OF PACKAGING Uncleaned packaging should be treated as for the product. If
thoroughly rinsed, it may be treated as general waste for incineration or
landfill, according to regulations.
14. TRANSPORT INFORMATION
UN NO. None assigned
PROPER SHIPPING NAME
EMERGENCY ACTION CODE
ADR/RID Not regulated
IMCO Not classified as hazardous for carriage by sea
MFAG Table No.
EmS No.
ICAO/IATA --
PACKING GROUP None assigned
LABEL Marine pollutant
15.REGULATORY INFORMATION
CLASSIFICATION Irritating to eyes and skin
Risk of serious damage to eyes
SAFETY PHRASES Keep away from food, drink and animal feeding stuffs.
Keep out of reach of children.
Keep only in the original container.
Keep container tightly closed.
KEEP IN A SAFE PLACE.
ENSURE ADEQUATE VENTILATION before reoccupation.
WASH ANY CONTAMINATION from exposed skin and eyes immediately.
WASH HANDS AND EXPOSED SKIN before meals and after use
In case of contact with eyes, rinse immediately with plenty of water
and seek medical advice. (CONT’D)
Material Safety Data Sheet According to 93/112EC TRITEC 121
15.REGULATORY INFORMATION (CONT’D)
THIS PRODUCT IS APPROVED UNDER THE CONTROL OF PESTICIDES REGULATIONS 1986
FOR USE AS DIRECTED, HSE No. 6539.
To avoid risks to man and the environment, comply with the instructions for use.
LABEL INFORMATION
FOR USE ONLY AS A WOOD PRESERVATIVE
FOR USE ONLY BY PROFESSIONAL OPERATORS
READ ALL PRECAUTIONS BEFORE USE
The (COSHH) Control of Substances Hazardous to Health Regulations 1994 may apply to the use of this product at
work.
FOR USE ONLY BY PROFESSIONAL OPERATORS.
Engineering control of operator exposure must be used where reasonably practicable in addition to the following items
of personal protective equipment.
Wear suitable protective clothing, gloves and eye/face protection.
AVOID EXCESSIVE CONTAMINATION OF COVERALLS AND LAUNDER REGULARLY.
Do not breathe spray. Otherwise wear respiratory protective equipment and eye protection (see HSE Guidance
Booklet HS(G)53, “The Selection, Use and Maintenance of Respiratory Protective Equipment – A Practical Guide”).
However, engineering controls may replace personal protective equipment if a COSHH assessment shows they
provide an equal or higher standard of protection.
DO NOT CONTAMINATE FOODSTUFFS, EATING UTENSILS OR FOOD CONTACT SURFACES.
WHEN USING DO NOT EAT, DRINK OR SMOKE
THIS MATERIAL AND ITS CONTAINER must be disposed of in a safe way.
EXCLUDE ALL UNPROTECTED PERSONS AND ANIMALS DURING TREATMENT AND FOR AT LEAST 1
HOUR AFTER TREATMENT IS COMPLETED.
ENSURE THERE IS A PHYSICAL BARRIER TO PREVENT CONTACT BY UNPROTECTED
PERSONS AND ANIMALS UNTIL TREATED SURFACES ARE VISIBLY DRY.
EXTREMELY DANGEROUS TO FISH AND OTHER AQUATIC LIFE.
REMOVE OR COVER FISH TANKS AND BOWLS before application.
Do not contaminate ground, waterbodies or watercourses with chemicals or used container.
COVER WATER STORAGE TANKS before application.
ALL BATS ARE PROTECTED UNDER THE WILDLIFE AND COUNTRYSIDE ACT 1981. BEFORE
TREATING ANY STRUCTURE USED BY BATS, CONSULT ENGLISH NATURE, SCOTTISH NATURAL
HERITAGE OR THE COUNTRYSIDE COUNCIL FOR WALES. READ ALL PRECAUTIONS BEFORE USE
HSE No. 6539
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of
publication, but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the
technical data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRITEC 121 PLUS Material Safety Data Sheet Accordingto93/112EC
Triton Chemical Manufacturing Co.Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
218 13/07/98 04/03/04
1. PRODUCT NAME: TRITEC 121 PLUS HSE NO. 6538
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Permethrin 52645-53-1 258—067-9 4.6 Xn,Harmful R22
Propiconazole 60207-90-1 9.8 Xn, Harmful R22, R50/53
N, Dangerous
for environment
Fatty alcohol ethoxylate 68439-46-3 28-32 Xi R41
3. HAZARD IDENTIFICATION
Irritant – irritating to eyes and skin
May cause sensitisation by skin contact.
Dangerous for the environment.
Risk of serious damage to eyes
4. FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water for at least 5 minutes
CONTACT WITH EYES Wash out with water for several minutes. Seek medical advice
INGESTION Rinse the mouth (do not swallow), and give copious fluids to drink.
DO NOT INDUCE VOMITING. Obtain medical attention.
INHALATION Remove to fresh air. Keep warm and at rest.
OTHER INFORMATION Treat symptomatically
5. FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA As appropriate to surrounding fire
SPECIAL PROTECTIVE EQUIPMENT Wear breathing apparatus in confined spaces.
6. ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing including eye/face protection
and PVC or synthetic rubber gloves, protective footwear, overalls.
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbent and shovel into a suitable
closed container for disposal according to item 13.
Material Safety Data Sheet According to 93/112EC TRITEC 121 PLUS
7. HANDLING AND STORAGE
HANDLING PRECAUTIONS Material should only be handled by trained personnel.
Wear suitable protective clothing according to item 8.
STORAGE INFORMATION Protect from frost. Keep containers tightly closed in a cool
place.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear goggles or face shield, PVC or synthetic rubber gloves, protective footwear, and overalls
If spraying wear suitable respiratory protection, either an air-fed mask or cartridge type respirator fitted with
a P2 or P3 cartridge.
Wash hands and exposed skin before meals and after use. Do not eat, drink or smoke whilst
Handling the product.
Do not wear contaminated clothing.
EXPOSURE LIMITS None assigned in EH40
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear liquid Oxidising properties None
Odour Very slight odour Vapour pressure No data
pH Neutral Relative density 1.02 – 1.04 (15ºC)
Boiling point >100ºC Bulk density Not relevant
Melting point Below 0ºC Viscosity Similar to water
Flash point Above 93ºC Solubility Miscible with water
Flammability/autoflammability No data Partition coefficient No data
Explosive properties No data Other data
10. STABILITY/REACTIVITY
STABILITY Stable
CONDITIONS TO AVOID No special requirements
MATERIALS TO AVOID
11. TOXICOLOGICAL INFORMATION
Acute Toxicity: LD > 10,000mg/Kg, by calculation. May produce a transient burning or stinging sensation
(without lesions) on exposed skin.
TRITEC 121 PLUS Material Safety Data Sheet According to 93/112EC
12. ECOLOGICAL INFORMATION
MOBILITY The water-miscibility of the product suggests that it is likely
to leach from soil into groundwater. There is no available data on
sorption/desorption.
DEGRADABILITY Biodegradable in natural media. No data on persistence
ACCUMULATION There is no evidence for bioaccumlation or biomagnification.
13. DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Chemical residues are normally regarded as Special Waste. Dispose of in
accordance with local and national regulations (most likely to be
incineration).
DISPOSAL OF PACKAGING Uncleaned packaging should be treated as for the product. If thoroughly
rinsed, it may be treated as general waste for incineration or landfill,
according to regulations.
14. TRANSPORT INFORMATION
UN NO. None assigned
PROPER SHIPPING NAME
EMERGENCY ACTION CODE
ADR/RID Not regulated
IMCO Not classified as hazardous for carriage by sea
MFAG Table No.
EmS No.
ICAO/IATA --
PACKING GROUP None assigned
LABEL Marine pollutant
15. REGULATION INFORMATION
CLASSIFICATION Irritating to eyes and skin
Risk of serious damage to eyes
May cause sensitisation by skin contact
Dangerous for the environment.
SAFETY PHRASES Keep away from food, drink and animal feeding stuffs.
Keep out of reach of children.
Keep only in original container.
Keep container tightly closed.
KEEP IN A SAFE PLACE.
ENSURE ADEQUATE VENTILATION before re-occupation.
WASH ANY CONTAMINATION from skin or eyes immediately.
WASH HANDS AND EXPOSED SKIN before meals and after use.
IRRITATING TO EYES AND SKIN.
In case of contact with eyes, rinse immediately with plenty of water
and seek medical advice.
MAY CAUSE SENSITISATION BY SKIN CONTACT.
DANGEROUS FOR THE ENVIRONMENT.
TOXIC TO AQUATIC ORGANISMS
MAY CAUSE LONGTERM ADVERSE EFFECTS IN THE
AQUATIC ENVIRONMENT. (CONTD.)
Material Safety Data Sheet According to 93/112EC TRITEC 121 PLUS
15. REGULATORY INFORMATION (CONT’D)
THIS PRODUCT IS APPROVED UNDER THE CONTROL OF PESTICIDES REGULATIONS 1986
FOR USE AS DIRECTED. HSE No. 6538.
To avoid risks to man and the environment, comply with the instructions for use.
LABEL INFORMATION:
WOOD PRESERVATIVE FOR PROFESSIONAL USE AGAINST WOOD ROTTING FUNGI AND WOOD
DESTROYING INSECTS.
FOR USE ON WOOD OUT OF GROUND CONTACT OR SURFACE WATER CONTACT.
READ ALL PRECAUTIONS BEFORE USE
The (COSHH) Control of Substances Hazardous to Health Regulations 1994 may apply to the use of this product at
work.
FOR USE ONLY BY PROFESSIONAL OPERATORS.
Engineering control of operator exposure must be used where reasonably practicable in addition to the following items
of personal protective equipment.
Wear suitable protective clothing, gloves and eye/face protection.
AVOID EXCESSIVE CONTAMINATION OF COVERALLS AND LAUNDER REGULARLY.
Do not breathe spray. Otherwise wear respiratory protective equipment and eye protection (see HSE Guidance
Booklet HS(G)53: “The Selection, Use and Maintenance of Respiratory Equipment – A Practical Guide”).
However engineering controls may replace personal protective equipment if a COSHH assessment shows they provide
an equal or higher standard of protection.
DO NOT CONTAMINATE FOODSTUFFS, EATING UTENSILS OR FOOD CONTACT SURFACES.
WHEN USING, DO NO EAT, DRINK OR SMOKE.
THIS MATERIAL AND ITS CONTAINER MUST BE DISPOSED OF IN A SAFE WAY.
EXCLUDE ALL UNPROTECTED PERSONS AND ANIMALS DURING TREATMENT AND FOR AT LEAST 1
HOUR AFTER TREATMENT IS COMPLETED.
ENSURE THERE IS A PHYSICAL BARRIER TO PREVENT CONTACT BY UNPROTECTED PERSONS AND
ANAIMALS UNTIL TREATED SURFACS ARE VISIBLY DRY.
EXTREMELY DANGEROUS TO FISH AND OTHER AQUATIC LIFE.
REMOVE OR COVER ALL FISH TANKS AND BOWLS before application.
Do not contaminate ground, waterbodies or watercourses with chemicals or used container.
COVER WATER STORAGE TANKS before application.
ALL BATS ARE PROTECTED UNDER THE WILDLIFE AND COUNTRYSIDE ACT 1981. BEFORE
TREATING ANY STRUCTURE USED BY BATS, CONSULT ENGLISH NATURE, SCOTTISH NATURL
HERITAGE OR THE COUNTRYSIDE COUNCIL FOR WALES.
READ ALL PRECAUTIONS BEFORE USE., HSE No. 6538.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
16. OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of
publication, but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the
technical data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIMETHRIN OS Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: Publication date Revision date
TR206 27/03/97 17/02/04
1.PRODUCT NAME: TRIMETHRIN 2 OS HSE NO. 4621
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Permethrin 52645-53-1 258-067-9 0.2 Irritant R22
Odourless Kerosene 64742-47-8 265-149-8 99.8 Harmful R22
3. HAZARD IDENTIFICATION
Irritant – irritating to eyes and skin
Flammable (flash point 77°C)
Harmful if swallowed
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water for at least 5 minutes.
CONTACT WITH EYES Wash out with water for several minutes. If redness and/or irritation
persists, seek medical advice.
INGESTION Rinse the mouth (do not swallow), and give water or milk to drink.
Seek medical advice. DO NOT INDUCE VOMITING.
INHALATION Remove to fresh air if fumes cause irritation of nose or throat.
OTHER INFORMATION Treat symptomatically
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA Dry powder or foam. For small fires use CO . Never use water
²
jet.
Flash point 77°C.
SPECIAL PROTECTIVE EQUIPMENT For fires in confined spaces, use breathing apparatus.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount
involved, which may include eye/face protection, PVC or
synthetic rubber gloves, protective footwear, overalls.
(Contd.)
Material Safety Data Sheet According to 93/112EC TRIMETHRIN OS
6.ACCIDENTAL RELEASE MEASURES (contd.)
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbent and shovel into
a suitable closed container for disposal according to item 13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Observe good hygiene standards and minimise skin contact.
Wear suitable protective clothing according to item 8.
STORAGE INFORMATION Keep containers tightly closed in a cool place, out of direct
sunlight. Keep stored well ventilated.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Where prolonged or repeated exposure is likely, protective clothing should be worn,
including eye protection and PVC or synthetic rubber gloves.
If spraying wear suitable respiratory protection, either an air-fed mask or cartridge type
respirator fitted with a suitable cartridge.
Wash hands and exposed skin before meals and after work. Do not eat, drink or smoke
whilst handling the product.
Do not wear contaminated clothing. Ventilate confined spaces thoroughly.
EXPOSURE LIMITS LTEL for solvent: 1000mg/m³
(8 hr. TWA)
OES 5mg/m³ oil mist
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear, colourless liquid Oxidising properties None
Odour Paraffinic Vapour pressure No data
PH Not relevant Relative density 0.81 (15ºC)
Boiling point 200º to 260°C Bulk density Not relevant
Melting point Not Relevant Viscosity 2.25cS @ 20°C
Flash point 77ºC Solubility Insoluble in water
Autoignition temperature 230°C Partition coefficient No data
Explosive properties LEL 0.6%,UEL 7.0% Other data
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID High temperatures (flash point 77°C)
MATERIALS TO AVOID Strong oxidising agents.
TRIMETHRIN OS Material Safety Data Sheet According to 93/112EC
11.TOXICOLOGICAL INFORMATION
Toxicity following a single exposure to high levels of the solvent component is of a low order. Prolonged
and repeated contact may cause drying of the skin and possibly dermatitis. Prolonged inhalation of spray
mist may cause inflammation of the lungs. The major hazard is lung damage from aspiration – medical
supervision for 24-48 hours is recommended if aspiration could have occurred.
The Permethrin may cause a stinging or burning sensation on the skin (without lesions).
LD50 oral (rat) > 10,000mg/kg (by calculation)
12.ECOLOGICAL INFORMATION
MOBILITY Likely to be mobile in the soil. Take care to avoid contamination of
groundwater.
DEGRADABILITY Biodegrades slowly.
ACCUMULATION There is no evidence for bioaccumlation or biomagnification.
ECOTOXICITY Highly toxic to fish. Marine pollutant (IMDG code)
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Chemical residues are normally regarded as Special Waste. Dispose of
in accordance with local and national regulations. Can be burned in
domestic refuse incinerators in accordance with local regulations.
DISPOSAL OF PACKAGING Uncleaned packaging should be treated as for the product. If
thoroughly rinsed, it may be treated as general waste for incineration or
landfill, according to regulations.
14. TRANSPORT INFORMATION
UN NO. None assigned
PROPER SHIPPING NAME
EMERGENCY ACTION CODE 3[Z] (suggested)
ADR/RID Not classified as hazardous
IMCO Not classified as hazardous
MFAG Table No.
EmS No.
ICAO/IATO Not classified as hazardous
PACKING GROUP
LABEL Marine pollutant
Material Safety Data Sheet According to 93/112EC TRIMETHRIN OS
15. REGULATORY INFORMATION
CLASSIFICATION Irritant
LABEL INFORMATION
PRECAUTIONS
FLAMMABLE. DO NOT APPLY in the presence of naked flames, hot surfaces or unprotected electrical equip-
ment.
ENSURE ADEQUATE VENTILATION when applying.
WEAR SUITABLE PROTECTIVE CLOTHING, NAMELY OVERALLS AND SYNTHETIC/PVC GLOVES
when handling.
AVOID WORKING IN SPRAY MIST or wear suitable respiratory equipment and eye protection.
WHEN USING, DO NOT EAT, DRINK OR SMOKE.
WASH HANDS AND EXPOSED SKIN before meals and after work.
COVER ALL FOODSTUFFS BEFORE APPLICATION.
DO NOT APPLY TO SURFACES on which food is prepared.
CHILDREN AND PETS SHOULD BE KEPT AWAY FROM TREATED AREAS FOR 48 HOURS OR UNTIL
DRY.
VENTILATE CONFINED SPACES THOROUGHLY.
EXTREMELY DANGEROUS TO FISH. Do not contaminate ponds, waterways or ditches with chemical or used
container.
REMOVE FISH TANKS before applying.
DO NOT USE ON BEEHIVES OR BEEKEEPING EQUIPMENT.
KEEP OUT OF THE REACH OF CHILDREN.
KEEP IN ORIGINAL CONTAINER, tightly closed and in a safe place.
THIS MATERIAL AND ITS CONTAINER must be disposed of in a safe way.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRISOL 23 Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: Publication date Revision date
HARMFUL TR212 11/02/98 25/02/04
1.PRODUCT NAME: TRISOL 23 HSE NO. 6274
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
3-lodo-2-propynyl-butyl carbamate 55406-53-6 259-627-5 5 Xn, N R20/22, 41,50
Fatty Alcohol ethoxylate 22 Xn R22, 41
3.HAZARD IDENTIFICATION
Harmful if swallowed
Risk of serious damage to eyes
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water for at least 5 minutes. If irritation
or redness develop, seek medical attention.
CONTACT WITH EYES Wash out with water for several minutes. Seek medical advice.
INGESTION Rinse the mouth (do not swallow), and give copious fluids to drink,
preferably milk. DO NOT INDUCE VOMITING.
INHALATION May cause respiratory irritation. Remove to fresh air, keep warm and
at rest.
OTHER INFORMATION Information for doctor: May cause severe eye irritation and possible
corneal injury unless washed from eyes promptly.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA As appropriate to surrounding fire
SPECIAL PROTECTIVE EQUIPMENT Full protective clothing. May produce toxic and irritant iodine
vapour
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing including eye/face protection
and PVC or synthetic rubber gloves, protective footwear, and
overalls.
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
(Cont’d)
Material Safety Data Sheet According to 93/112EC TRISOL 23
6.ACCIDENTAL RELEASE MEASURES (Cont’d)
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbent and shovel into
a suitable closed container for disposal according to item 13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Avoid contact with eyes or skin. Do not breathe spray.
Wear suitable protective clothing according to item 8.
STORAGE INFORMATION Protect from frost. Keep containers tightly closed in a cool place.
Do not mix or store in galvanised or light metal containers.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear goggles or face shield, PVC or synthetic rubber gloves, protective
footwear, and overalls.
If spraying wear suitable respiratory protection, either an air-fed mask or
cartridge type respirator fitted with a suitable cartridge.
It is advisable to wear a suitable head covering and to apply a barrier
cream (water-resistant type).
Wash before meals; shower or bathe after work. Do not smoke whilst
handling the product.
Do not wear contaminated clothing.
EXPOSURE LIMITS None assigned in EH40
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear liquid Oxidising properties None
Odour Very slight odour Vapour pressure No data
pH Neutral Relative density 1.02 – 1.04 (15ºC)
Boiling point > 100° C Bulk density Not relevant
Melting point Below 0° C Viscosity Similar to water
Flash point > 93º C Solubility Miscible with water
Flammability/autoflammability: Not combustible Partition coefficient No data
Explosive properties Not explosive Other data
10.STABILITY/REACTIVITY
STABILITY Stable
CONDITIONS TO AVOID No special requirements
MATERIALS TO AVOID Strong acids and bases
TRISOL 23 Material Safety Data Sheet According to 93/112EC
11.TOXICOLOGICAL INFORMATION
3-lodo-2-propynyl-butyl carbamate (I.P.B.C.) is moderately toxic: LD 1470mg/kg (rat, acute, oral).
50
The calculated toxicity of TRISOL 23 is LD50 > 10,000mg/kg, based on dilution factors.
It causes severe eye irritation and is a skin irritant.
Ingestion may cause nausea, gastrointestinal irritation and vomiting.
Long-term exposure effects are unknown.
12.ECOLOGICAL INFORMATION
MOBILITY No specific information.
DEGRADABILITY COD = 1.148e mg/kg (day(s)) for I.P.B.C.
I.P.B.C. is not biodegradable
ACCUMULATION Bioconcentration factor for Carp: 3.3-4.5
ECOTOXICITY Acutely toxic to aquatic organisms.
LC50 (96hr) Blue gill 0.23mg a.i./L. LC 50 (48hr) Daphnia magna 0.696mg/L
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Chemical residues are normally regarded as Special Waste. Dispose of
in accordance with local and national regulations.
DISPOSAL OF PACKAGING Uncleaned packaging should be treated as for the product. If
thoroughly rinsed, it may be treated as general waste for incineration or
landfill, according to regulations.
14. TRANSPORT INFORMATION
UN NO. 3077
PROPER SHIPPING NAME ENVIRONMENTALLY HAZARDOUS SUBSTANCES, NOS.
Contains Iodocarb (5%)
ADR/RID Class 9. Item 12(c)
IMCO Class 9. IMDG Code page 9029
ICAO/IATO Class 9.
PACKING GROUP III
LABEL Harmful, Dangerous to the environment (as 100% I.P.B.C)
15. REGULATORY INFORMATION
CLASSIFICATION Harmful if swallowed
Risk of serious damage to eyes
LABEL INFORMATION:
FOR USE ONLY AS A SURFACE BIOCIDE
FOR USE ONLY BY PROFESSIONAL OPERATORS
SAFETY PHRASES
INCASE OF ACCIDENT OR IF YOU FEEL UNWELL seek medical advice immediately. (Show the label where
possible).
To avoid risks to man and the environment, comply with the instructions for use. (Cont’d)
Material Safety Data Sheet According to 93/112EC TRISOL 23
15. REGULATORY INFORMATION (Cont’d)
SAFETY PHRASES (Cont’d)
WASH HANDS AND EXPOSED SKIN before meals and after use.
WASH ANY CONTAMINATION from skin or eyes immediately.
In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
Keep only in the original container.
Keep container tightly closed.
KEEP IN A SAFE PLACE.
KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDING STUFFS.
Keep out of the reach of children.
PRECAUTIONS
The (COSHH) Control of Substances Hazardous to Health Regulations 1994 may apply to the use of this
product at work.
FOR USE ONLY BY PROFESSIONAL OPERATORS.
Engineering control of operator exposure must be used where reasonably practicable in addition to the
following items of personal protective equipment.
Wear suitable protective clothing, gloves and eye/face protection.
AVOID EXCESSIVE CONTAMINATION OF COVERALLS AND LAUNDER REGULARLY.
Do not breathe spray. Otherwise wear respiratory protective equipment and eye protection (see HSE Guidance
Booklet HS(G) 53: “The Selection – A Practical Guide”.
However engineering controls may replace personal protective equipment if a COSHH assessment shows they
provide an equal or higher standard of protection.
COVER FOOD, FOOD PREPARING EQUIPMENT AND EATING UTENSILS before application.
THIS MATERIAL AND ITS CONTAINER must by disposed of in a safe way.
DO NOT APPLY TO SURFACES on which food or feed is stored, prepared or eaten.
UNPROTECTED PERSONS AND ANIMALS SHOULD BE KEPT AWAY FROM TREATED AREAS FOR 48
HOURS OR UNTIL SURFACES ARE DRY.
COVER WATER STORAGE TANKS before application.
Do not empty into drains.
DO NOT USE NEAR DRAINS, PREVENT ANY SURFACE RUN-OFF FROM ENTERING DRAINS.
DANGEROUS TO FISH AND OTHER AQUATIC LIFE.
This product contains substances which are known to be hazardous to the environment.
Do not contaminate ground, waterbodies or watercourses with chemical or used container.
REMOVE OR COVER ALL FISH TANKS AND BOWLS before application.
AVOID ALL CONTACT WITH PLANT LIFE.
WHEN USING DO NOT EAT, DRINK OR SMOKE.
READ ALL PRECAUTIONS BEFORE USE. HSE No. 6274
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
This product is for use only by professional operators as a masonry fungicide.
This product is approved under the control of pesticides regulations 1986 (as amended) for use as directed. HS No. 6274
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication, but we cannot
accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical data sheet for the
product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long term exposure limit.
TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper explosive limit.
TRIPASTE PB Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: Publication date Revision date
TR214 18/4/97 27/6/97 (side lined)
1.PRODUCT NAME: TRIPASTE PB HSE NO. 6080
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Permethrin 52645-53-1 258-067-9 0.2 Xn (Harmful) R22
Trihexyleneglycol biborate 3.3 Xn (Harmful)
blend with hydrocarbon solvent
3. HAZARD IDENTIFICATION
Irritant
Irritating to eyes and skin
Mist/fume may irritate nose or throat on prolonged exposure.
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water. If irritation persists, seek medical
advice.
CONTACT WITH EYES Wash out with water for several minutes and seek medical advice.
INGESTION Do not induce vomiting. Keep at rest and seek medical attention.
INHALATION Remove to fresh air. Keep warm and at rest. Seek medical advice if
necessary.
OTHER INFORMATION
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA Water spray, dry powder, CO or foam. Never use water jet.
²
SPECIAL PROTECTIVE EQUIPMENT For fires in confined spaces, use breathing apparatus.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount
involved, which may include eye/face protection, PVC or
synthetic rubber gloves, protective footwear, overalls.
(Contd.)
Material Safety Data Sheet According to 93/112EC TRIPASTE PB
6.ACCIDENTAL RELEASE MEASURES (contd.)
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbent and shovel into
a suitable closed container for disposal according to item 13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Observe good hygiene standards and minimise skin contact.
Provide adequate ventilation in work spaces.
STORAGE INFORMATION Keep containers tightly closed in a cool place, out of direct
sunlight. Keep stored well ventilated.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Where prolonged or repeated exposure is likely, protective clothing should be worn,
including eye protection and PVC or synthetic rubber gloves.
Wash hands and exposed skin before meals and after work. Do not eat, drink or smoke
whilst handling the product.
Do not wear contaminated clothing. Ventilate confined spaces thoroughly.
EXPOSURE LIMITS None prescribed in EH40
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance White or green paste Oxidising properties None
Odour Mild solvent odour Vapour pressure <0.1Pa (20°C)
pH 5.0 – 6.5 Relative density 0.98 (20ºC)
Boiling point 100º to 220°C Bulk density Not relevant
Melting point Not Relevant Viscosity No data
Flash point >60ºC Solubility Partially soluble in water
Autoignition temperature No data Partition coefficient No data
Explosive properties No data Other data
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID High temperatures
MATERIALS TO AVOID Strong oxidising agents.
TRIPASTE PB Material Safety Data Sheet According to 93/112EC
11.TOXICOLOGICAL INFORMATION
Acute toxicity LD50 (rat, oral) > 4000mg/kg. May cause irritation or burning sensation (without lesions).
12.ECOLOGICAL INFORMATION
MOBILITY Avoid subsoil penetration.
DEGRADABILITY Biodegradable.
ACCUMULATION There is potential for bioaccumlation. Biomagnification is unlikely.
ECOTOXICITY Toxic to aquatic organisms. Permethrin LC50 (trout): 0.009mg/l
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Chemical residues are normally regarded as Special Waste. Incinerate
in compliance with Environment Protection Act 1990 (Process
Guidance Note IPR5/1).
DISPOSAL OF PACKAGING Uncleaned packaging should be treated as for the product. Cleaned
packaging may be land-filled.
14. TRANSPORT INFORMATION
UN NO. None assigned
ADR/RID Not classified as hazardous
PROPER SHIPPING NAME
IMCO Not classified as hazardous
IATA/IACO Not classified as hazardous
PACKING GROUP
LABEL No hazard label
15. REGULATORY INFORMATION
CLASSIFICATION Irritant
LABEL INFORMATION
R36/38: Irritating to eyes and skin.
S51: Use only in well ventilated areas.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
Required by health and safety legislation.
Material Safety Data Sheet According to 93/112EC TRIPASTE PB
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIMOL RESINS (15, 34, 35, 36, 40, 41) Material Safety Data Sheet According to 93/112EC
Triton Chemical Manufacturing Co. Ltd.
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
300 4/4/97
1.PRODUCT NAME: TRIMOL RESINS 15, 34, 35, 36, 40, 41
2. COMPOSITION
Hazardous ingredient CAS Nos. Weight, % Symbols Risk Phrases
Bisphenol A and F epoxy 25068-38-6, 68609-97-2, 100 Xi (Irritant) R36/38,43,51/53
Resins, diglycidyl ethers 28064-14-4
3.HAZARD IDENTIFICATION
Irritant
Irritating to skin and eyes
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water.
CONTACT WITH EYES Wash out with water for several minutes and seek medical advice.
INGESTION Seek medical advice in the event of discomfort.
INHALATION Remove to fresh air if fumes cause irritation of nose or throat.
OTHER INFORMATION May aggravate existing respiratory problems.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA Dry powder or foam. For small fires use CO² . Never use water
jet.
SPECIAL PROTECTIVE EQUIPMENT For fires in confined spaces, use breathing apparatus.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount
involved, which may include eye/face protection, PVC or
synthetic rubber gloves, protective footwear and overalls.
(Contd.).
Material Safety Data Sheet According to 93/112EC TRIMOL RESINS (15,34,35,36,40,41)
6.ACCIDENTAL RELEASE MEASURES (contd.)
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbents and shovel
into a suitable closed container for disposal according to item
13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Observe good hygiene standards and minimise skin contact.
Wear suitable protective clothing according to item 8.
STORAGE INFORMATION Keep containers tightly closed in a cool place, out of direct
sunlight. Keep stored well ventilated.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Where prolonged or repeated exposure is likely, protective clothing should be
worn, including eye protection, boots and PVC or synthetic rubber gloves.
Wash hands and exposed skin before meals and after work. Do not eat, drink
or smoke whilst handling the product.
Do not wear contaminated clothing. Ventilate confined spaces thoroughly.
EXPOSURE LIMITS None prescribed in EH40.
Slight irritant, not considered hazardous.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear, golden liquid Oxidising properties None
Odour Faint Vapour pressure 1Pa (20°C)
pH 7 (50% suspension in water) Relative density 1.2-1.13 (15°C)
Boiling point Decomposes Bulk density Not Relevant
Melting point Not Relevant Viscosity No data
Flash point >150°C Solubility Insoluble in water
Autoignition temperature No data Partition coefficient No data
Explosive properties No data Other data
TRIMOL RESINS (15, 34, 35, 36, 40,41) Material Safety Data Sheet According to 93/112EC
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID High temperatures (degrades resin).
MATERIALS TO AVOID Strong oxidising agents, acids and bases.
Excess of hardener (uncontrolled polymerisation reaction).
11.TOXICOLOGICAL INFORMATION
Not available data on acute toxicity. Irritating to eyes. A mild skin irritant and mild sensitising agent.
12.ECOLOGICAL INFORMATION
MOBILITY Low soil absorption.
DEGRADABILITY Not easily biodegradable
ACCUMULATION There is potential for bioaccumulation. Biomagnification is unlikely.
ECTOTOXICITY Toxic to aquatic organisms:
(TLm96: fish 1.2mg/litre, Daphnia 2.7 mg/litre, algae 9.4mg/litre)
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT: Chemical residues are normally regarded as Special Waste. Dispose of
in accordance with local and national regulations (incinerate or
landfill).
DISPOSAL OF PACKAGING: Uncleaned packaging should be treated as for the product.
14. TRANSPORT INFORMATION
UN No. None assigned
PROPER SHIPPING NAME Liquid epoxy resin
ADR/RID Not classified as hazardous
IMCO Not classified as hazardous
MFAG Table No.
EmS No.
IATA/IACO Not classified as hazardous
PACKING GROUP
LABEL No hazard label
Material Safety Data Sheet According to 93/112EC TRIMOL RESINS (15, 34, 35, 36, 40, 41)
15.REGULATORY INFORMATION
CLASSIFICATION Irritant
LABEL INFORMATION
S24: Irritating to eyes and skin.
S26: May cause sensitisation by skin contact.
S28: After contact with skin, wash immediately with plenty of water.
S37/39: Wear suitable gloves and eye/face protection.
Refer to other relevant legislation such as Health and Safety at Work etc Act (HSWA), the Control of
Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of
Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of
workplace risk as required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of
publication, but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the
technical data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIMOL HARDENER (15, 34, 35, 36) Material Safety Data Sheet According to 93/112EC
Triton Chemical Manufacturing Co. Ltd.
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
301 4/4/97 18/06/04
1.PRODUCT NAME: TRIMOL HARDENER 15, 34, 35, 36
2. COMPOSITION
Hazardous ingredient CAS Nos. EC No. Weight, % Symbols Risk Phrases
Trimethylhexamethylene diamine 25620-58-0 247-134-8 100 C (Corrosive) R22,34,43,52/53
3.HAZARD IDENTIFICATION
Corrosive – Causes burns
Harmful if swallowed
May cause sensitisation by skin contact
Harmful to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water. If irritation persists, obtain
medical advice.
CONTACT WITH EYES Wash out with water for several minutes and seek medical advice.
INGESTION Give plenty of water – if possible, charcoal slurry. Do not induce
vomiting.
INHALATION Remove to fresh air. If symptoms persist, seek medial advice.
OTHER INFORMATION Treat symptomatically.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA Dry powder or foam. For small fires use CO ² . Never use water
jet.
SPECIAL PROTECTIVE EQUIPMENT Full protective equipment. Toxic and irritant fumes may be
produced.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing which may include eye/face
protection, PVC or synthetic rubber gloves, protective footwear
and overalls. Avoid contact with skin, eyes and clothing.
Material Safety Data Sheet According to 93/112EC TRIMOL HARDENER (15, 34, 35, 36)
6.ACCIDENTAL RELEASE MEASURES (contd.)
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbents and shovel
into a suitable closed container for disposal according to item
13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Ensure adequate ventilation in work areas. Keep away from
sources of ignition – no smoking. Handle and open container
with care
STORAGE INFORMATION Keep containers tightly closed in a cool place, out of direct
sunlight. Keep store well ventilated. Keep away from food and
feeding stuffs.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear protective clothing, including eye protection, boots and PVC or
synthetic rubber gloves. In case of insufficient ventilation, wear suitable
respiratory protective equipment.
Wash hands and exposed skin before meals and after work. Do not eat, drink
or smoke whilst handling the product.
EXPOSURE LIMITS None prescribed in EH40.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear, colourless liquid Oxidising properties None
Odour Amine-like Vapour pressure 6Pa (20°C)
pH 11.3 (50% in water) Relative density 0.86-0.87 (20°C)
Boiling point >200°C Bulk density Not Relevant
Melting point Not Relevant Viscosity 5mPa.s (25°)
Flash point >108°C (CC) Solubility Miscible with water
Autoignition temperature No data Partition coefficient No data
Explosive properties No data Other data
TRIMOL HARDENER (15, 34, 35, 36) Material Safety Data Sheet According to 93/112EC
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID High temperatures, formation of aerosols, static discharges.
MATERIALS TO AVOID Strong oxidising agents, acids and bases.
11.TOXICOLOGICAL INFORMATION
LD50 (rat, oral): 910mg/kg. Eye irritation (rabbit): corrosive. Skin irritation (rabbit): corrosive.
Dermal sensitisation (guinea pig): sensitiser.
12.ECOLOGICAL INFORMATION
MOBILITY Avoid subsoil penetration
DEGRADABILITY Not easily biodegradable
ACCUMULATION There is potential for bioaccumulation. Biomagnification is unlikely.
ECTOTOXICITY Toxic to aquatic organisms.
(LC 50 (fish) 96h:1000mg/litre, EC50 (daphnia) 24h: 31.5mg/litre
EC50 (algae) 72h: 29.5mg/litre), IC50 (bacteria) 3h: 100mg/litre.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT: Chemical residues are normally regarded as Special Waste. Incinerate
in compliance with the Environmental Protection Act 1990 (Process
Guidance Note IPR5/1)
DISPOSAL OF PACKAGING: Uncleaned packaging should be treated as for the product. After
cleaning, can be landfilled.
14. TRANSPORT INFORMATION
UN No. 2327
PROPER SHIPPING NAME Trimethylhexamethhylene diamines, solution
ADR/RID Class 8. Item 53(c).
IMCO Class 8. IMDG Code page 08243
MFAG Table No. 320
EmS No. 8.05
IATA/IACO Class 8
PACKING GROUP 3
LABEL Corrosive
Material Safety Data Sheet According to 93/112EC TRIMOL HARDENER (15, 34, 35, 36)
15.REGULATORY INFORMATION
CLASSIFICATION Corrosive
LABEL INFORMATION
R34:Causes burns
R22: Harmful if swallowed.
R43: May cause sensitisation by skin contact.
R52/53: Harmful to aquatic organisms, may cause long-term adverse affects in the aquatic environment.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S45: In case of accident or if you feel unwell, seek medical advice (show the label where possible).
Refer to other relevant legislation such as Health and Safety at Work etc Act (HSWA), the Control of
Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of
Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of
workplace risk as required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of
publication, but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the
technical data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIMOL FILLERS 35 AND 36 Material Safety Data Sheet According to 93/112EC
Triton Chemical Manufacturing Co. Ltd.
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
308 15/4/97
1.PRODUCT NAME: TRIMOL FILLERS 35 AND 36
2. COMPOSITION
An inert, inorganic filler consisting of a mixture of silica sand and silica flour.
3.HAZARD IDENTIFICATION
Contains respirable fraction silica – harmful by inhalation.
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water.
CONTACT WITH EYES Wash out with water for several minutes. Seek medical advice.
INGESTION Not likely to cause any adverse affects in the amounts which could be
taken.
INHALATION Remove to fresh air. Keep warm and at rest.
OTHER INFORMATION
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA As appropriate to surrounding fire.
SPECIAL PROTECTIVE EQUIPMENT No particular requirements.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear respiratory protection if dust is generated.
ENVIRONMENTAL PRECAUTIONS No environmental hazard.
CLEAN-UP PROCEDURES Avoid dry sweeping and generation of dust. Damp down before
shovelling into a suitable container for disposal by landfill.
Material Safety Data Sheet According to 93/112EC TRIMOL FILLER 35 AND 36
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Keep and mix in original container. If necessary, wear suitable
protective clothing according to item 8.
STORAGE INFORMATION No particular storage requirements. Keep dry to avoid
deterioration.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear dust masks or the equivalent to BS2091 Type B, and provide dust
extraction where dust is produced.
EXPOSURE LIMITS Refer to HSE Guidance Note EH40 for current
critical silica concentrations.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance White to buff-coloured powder/granules Oxidising properties None
Odour None Vapour pressure Not relevant
pH Not relevant Relative density Not relevant
Boiling point Not relevant Bulk density 2700kg/m³
Melting point >2000°C Viscosity Not relevant
Flash point Not combustible Solubility Insoluble in water
Autoignition temperature Not relevant Partition coefficient Not relevant
Explosive properties Not explosive Other data
10.STABILITY/REACTIVITY
STABILITY Stable.
CONDITIONS TO AVOID No special requirements.
MATERIALS TO AVOID None
TRIMOL FILLER 35 AND 36 Material Safety Data Sheet According to 93/112EC
11.TOXICOLOGICAL INFORMATION
Inert, insoluble and non-toxic. The main health hazard is inhalation of the respirable fraction silica.
12.ECOLOGICAL INFORMATION
MOBILITY Not mobile in soil.
DEGRADABILITY Inert and not biodegradable
ACCUMULATION There is no likelihood of bioaccumulation or Biomagnification
ECTOTOXICITY Not ecotoxic
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT: Dispose of by landfill in a commercial site, in accordance with local
and national regulations.
DISPOSAL OF PACKAGING: As for product.
14. TRANSPORT INFORMATION
Not regulated by road, rail, sea or air.
15.REGULATORY INFORMATION
CLASSIFICATION Not classified as hazardous.
LABEL INFORMATION None
Refer to other relevant legislation such as Health and Safety at Work etc Act (HSWA), the Control of
Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of
Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of
workplace risk as required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of
publication, but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the
technical data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIMOL 54 HARDENER Material Safety Data Sheet According to 93/112EC
Triton Chemical Manufacturing Co. Ltd.
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
310 18/4/97 29/01/03
1.PRODUCT NAME: TRIMOL 54 HARDENER
2. COMPOSITION
Hazardous ingredient CAS Nos. EC No. Weight, % Symbols Risk Phrases
Tetraethylenepentamine 112-57-2 203-986-2 1 – 10 C (N) R36/38,43,S26,S37/38
4,4 –Isopropylidenediphenol 80-05-7 201-245-8 1 – 5 Xi R36/37/38 R43
3.HAZARD IDENTIFICATION
Irritating to skin and eyes
May cause sensitisation by skin contact.
Harmful to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water. If irritation persists, obtain
medical advice.
CONTACT WITH EYES Wash out with water for at least 15 minutes and seek medical advice.
INGESTION Give plenty of water if possible, charcoal slurry. Do not induce
vomiting. Obtain medical attention.
INHALATION Remove to fresh air. If symptoms persist, seek medical advice.
OTHER INFORMATION Treat symptomatically.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA Water spray, dry powder, CO ². or foam. Never use water jet.
SPECIAL PROTECTIVE EQUIPMENT Full protective equipment. Toxic and irritant fumes may be
produced.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing which may include eye/face
protection, PVC or synthetic rubber gloves, protective footwear
and overalls. Avoid contact with skin, eyes and clothing.
(Contd.).
Material Safety Data Sheet According to 93/112EC TRIMOL 54 HARDENER
6.ACCIDENTAL RELEASE MEASURES (contd.)
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbents and shovel
into a suitable closed container for disposal according to item
13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Ensure adequate ventilation in work areas.
Handle and open container with care.
Avoid formation of aerosol.
STORAGE INFORMATION Keep containers tightly closed in a cool place, out of direct
sunlight. Keep stored well ventilated. Keep away from food
and feeding stuffs.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear protective clothing, including eye protection, boots and PVC or
synthetic rubber gloves. In case of insufficient ventilation, wear suitable
respiratory protective equipment.
Wash hands and exposed skin before meals and after work. Do not eat, drink
or smoke whilst handling the product.
EXPOSURE LIMITS None prescribed in EH40.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Dark brown paste Oxidising properties None
Odour Amine-like Vapour pressure 0.006Pa (25°C)
pH 11 (50% in water) Relative density 0.6g/cm³ (25°C)
Boiling point Decomposes above 200° Bulk density Not Relevant
Melting point Not relevant Viscosity Paste
Flash point 170°C (CC) Solubility Partially miscible with water
Autoignition temperature No data Partition coefficient No data
Explosive properties No data Other data
TRIMOL 54 HARDENER Material Safety Data Sheet According to 93/112EC
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID High temperatures, static discharges.
MATERIALS TO AVOID Strong oxidising agents, acids and bases.
11.TOXICOLOGICAL INFORMATION
LD50(rat, oral): >5000 mg/kg. Eye irritation (rabbit): irritating. Skin irritation (rabbit): irritating.
Dermal sensitisation (guinea pig): sensitiser
12.ECOLOGICAL INFORMATION
MOBILITY Avoid subsoil penetration.
DEGRADABILITY Not easily biodegradable
ACCUMULATION There is potential for bioaccumulation. Biomagnification is unlikely.
ECTOTOXICITY Toxic to aquatic organisms.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT: Chemical residues are normally regarded as Special Waste. Incinerate
in compliance with Environment Protection Act 1990 (Process
Guidance Note IPR5/1). Waste Key Number: 070204
DISPOSAL OF PACKAGING: Uncleaned packaging should be treated as for the product. Cleaned
packaging may be land-filled.
14. TRANSPORT INFORMATION
UN No. None assigned
PROPER SHIPPING NAME
ADR/RID Not classified as hazardous
IMCO Not classified as hazardous
MFAG Table No.
Ems No.
IATA/IACO Not classified as hazardous
PACKING GROUP
LABEL No hazard label
Material Safety Data Sheet According to 93/112EC TRIMOL 54 HARDENER
15.REGULATORY INFORMATION
CLASSIFICATION Xi Irritant
LABEL INFORMATION
R36/38: Irritating to eyes and skin.
R43: May cause sensitisation by skin contact.
R52/53: Harmful to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39: Wear suitable gloves and eye/face protection.
S61: Avoid release to the environment. Refer to special instructions/Safety data sheets.
Hazardous components which must be listed on the label: Tetraethylenepentamine
4, 4’ - Isopropylidenediphenol
Refer to other relevant legislation such as Health and Safety at Work etc Act (HSWA), the Control of
Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of
Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of
workplace risk as required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of
publication, but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the
technical data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIMOL 54 RESIN Material Safety Data Sheet According to 93/112EC
Triton Chemical Manufacturing Co. Ltd.
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
309 27/09/2002 29/01/2003
1.PRODUCT NAME: TRIMOL 54 RESIN
2. COMPOSITION
Hazardous ingredient CAS Nos. EC No. Weight, % Symbols Risk Phrases
Bisphenol A /epichlorhydrin 25068-38-6 70 – 82 Xi N R36/38,43, 51/53
epoxy resin (average molecular weight < 700)
3.HAZARD IDENTIFICATION
Irritant
Irritating to skin and eyes
May cause sensitisation by skin contact.
Dangerous Toxic to aquatic organisms, may cause long term adverse effects in
to the
Environment the aquatic environment.
4. FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water. If irritation persists, seek medical
advice.
CONTACT WITH EYES Wash out with water for several minutes and seek medical advice.
INGESTION Give plenty of water (charcoal slurry, if possible). Do not induce
vomiting. Obtain medical attention.
INHALATION Remove to fresh air. Keep warm and at rest.
OTHER INFORMATION May aggravate existing respiratory problems.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA Water spray, dry powder, CO ². or foam. Never use water jet.
SPECIAL PROTECTIVE EQUIPMENT For fires in confined spaces, use breathing apparatus.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount
involved, which may include eye/face protection, PVC or
synthetic rubber gloves, protective footwear and overalls.
(Contd.).
Material Safety Data Sheet According to 93/112EC TRIMOL 54 RESIN
6.ACCIDENTAL RELEASE MEASURES (contd.)
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbents and shovel
into a suitable closed container for disposal according to item
13.
7.HANDLING AND STORAGE
HANDLING
ADVICE ON SAFE HANDLING Provide sufficient air exchange and/or exhaust in work rooms.
Ensure adequate ventilation.
Hold and open container with care
Observe good hygiene standards and minimise skin contact.
Wear suitable protective clothing according to item 8.
STORAGE Keep containers tightly closed in a cool place, out of direct
sunlight. Keep stored well ventilated.
Keep away from food, drink and animal feeding stuffs.
STORAGE HAZARD CLASS: Storage class 10, environmentally hazardous liquids.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Where prolonged or repeated exposure is likely, protective clothing should be
worn, including eye protection, boots and PVC or synthetic rubber gloves.
Wash hands and exposed skin before meals and after work. Do not eat, drink
or smoke whilst handling the product.
Do not wear contaminated clothing. Ventilate confined spaces thoroughly.
EXPOSURE LIMITS None prescribed in EH40.
Slight irritant, not considered hazardous.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Brown paste Oxidising properties None
Odour Faint Vapour pressure <0.1Pa (20°C)
pH 10 (50% suspension in water) Relative density 0.6 (25°C)
Boiling point Decomposes above 200° Bulk density Not Relevant
Melting point Not relevant Viscosity No data
Flash point >200°C Water Solubility Insoluble at 20°C
Autoignition temperature No data Miscibility in water Immiscible at 20°C
Explosive properties No data Partition coefficient No data
Other data
TRIMOL 54 RESIN Material Safety Data Sheet According to 93/112EC
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID High temperatures (degrades resin).
MATERIALS TO AVOID Strong oxidising agents, acids and bases.
Excess of hardener (uncontrolled polymerisation reaction).
11.TOXICOLOGICAL INFORMATION
Acute toxicity. LD (rat, oral) >5000 mg/kg. Irritating to eyes. A mild skin irritant and mild sensitising
50
agent.
12.ECOLOGICAL INFORMATION
MOBILITY Prevent product from entering drains. Avoid subsoil penetration. Do
not contaminate surface water.
BIO DEGRADABILITY Not easily biodegradable
ACCUMULATION There is potential for bioaccumulation. Biomagnification is unlikely.
ECTOTOXICITY Toxic to aquatic organisms.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT: Chemical residues are normally regarded as Special Waste. Incinerate
in compliance with Environment Protection Act 1990 (Process
Guidance Note IPR5/1) Waste Key Number 070208.
DISPOSAL OF PACKAGING: Uncleaned packaging should be treated as for the product. Cleaned
packaging may be land-filled.
14. TRANSPORT INFORMATION
UN No. 3082
ADR/RID Class 9
PROPER SHIPPING NAME Environmentally Hazardous Substance, Liquid, N.O.S. – Bisphenol A
epoxy resin.
IATA/DGR See: Proper Shipping Name
PACKING GROUP III
PACKING INSTRUCTION
(Cargo Aircraft) 914
ADR/RID LABEL 9
Material Safety Data Sheet According to 93/112EC TRIMOL 54 RESIN
15.REGULATORY INFORMATION
CLASSIFICATION Irritant (Xi)
Dangerous to the Environment (N)
LABEL INFORMATION
R36/38: Irritating to eyes and skin.
R43: May cause sensitisation by skin contact.
R51/53: Toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment.
S28: After contact with skin, wash immediately with plenty of water.
S37/39: Wear suitable gloves and eye/face protection.
S61: Avoid release to the environment. Refer to special instructions (Safety data sheets).
Refer to other relevant legislation such as Health and Safety at Work etc Act (HSWA), the Control of
Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of
Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of
workplace risk as required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of
publication, but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the
technical data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
SECTION 3 :
STRUCTURAL WATERPROOFING.
CEMENTITOUS.
- T.T55 SLURRY
- FILLET SEAL
- T.T.M.E. ELASTIFIER
- QUICK SET
- TRITON SBR
EPOXY.
- TRISEAL
- TRIMOL 41
BITUMEN.
- BITUMEN EMULSION
CONCRETE WATERPROOFING SYSTEMS
- TT SUPER
- TT SUPER ADMIX
- TT WATERSTOP
- TT SWELL MASTIC
- TT VAPOUR MEMBRANE
TRITON TT55 Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
312 05/09/97 17/02/04
1.PRODUCT NAME: TRITON TT55 Tanking Slurry
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Ordinary Portland cement 65997-15-1 53 Xi (Irritant) See section 15
Also contains silica flour, silica sand and other additives
3. HAZARD IDENTIFICATION
Irritating to the skin
Risk of serious damage to eyes
May cause sensitisation by skin contact
4.FIRST AID
CONTACT WITH SKIN Wash off with plenty of soap and water. Remove contaminated
clothing.
CONTACT WITH EYES Wash out with water for at least 15 minutes and seek medical advice
without delay.
INGESTION Wash out mouth with water and give plenty of water to drink.
DO NOT INDUCE VOMITING.
INHALATION Remove to fresh air. If nose or airways become inflamed, seek medical
advice.
OTHER INFORMATION Until the mixture has set, may cause both irritant and allergic contact
dermatitis.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA As appropriate to surrounding fire
SPECIAL PROTECTIVE EQUIPMENT No particular requirement
Material Safety Data Sheet According to 93/112EC TRITON TT55
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount
involved which may include eye/face protection, PVC or synthetic
rubber gloves, protective footwear and overalls, particularly
during mixing operations.
ENVIRONMENTAL PRECAUTIONS Contain the spillage and keep children away from the area.
CLEAN-UP PROCEDURES Recover the spilt material in a dry state if possible.
Minimise generation of airborne dust.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Observe good hygiene standards and minimise skin contact.
Wear suitable protective clothing according to item 8.
STORAGE INFORMATION Keep containers tightly closed in a cool place.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
When handling or mixing the product, protective clothing should be worn, including
eye protection and PVC or synthetic rubber gloves.
Wash hands and exposed skin before meals and after work.
Do not wear contaminated clothing.
EXPOSURE LIMITS Occupational exposure standard (8h TWA):
10mg/m³ total inhalable dust, 5mg/m³ respirable dust
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Grey powder Oxidising properties None
Odour None Vapour pressure Not relevant
pH 11, when wet. Relative density Not relevant
Boiling point Not relevant Bulk density 1300 kg/m³
Melting point Not relevant Viscosity Not relevant
Flash point None Solubility Very slightly soluble in water
Autoignition temperature Not combustible Partition coefficient Not relevant
Explosive properties None Other data
TRITON TT55 Material Safety Data Sheet According to 93/112EC
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID Damp (degrades product).
MATERIALS TO AVOID No particular requirements.
11.TOXICOLOGICAL INFORMATION
Severe eye irritant. Irritating to skin – the powder or its mixture with water may cause irritant dermatitis or
burns, and traces of hexavalent chromium in the product may cause allergic dermatitis. Ingestion of small
amounts is unlikely to cause any significant reaction, but large doses may result in irritation to the gastro
intestinal tract.
12.ECOLOGICAL INFORMATION
MOBILITY Not mobile in soil.
DEGRADABILITY Relatively inert.
ACCUMULATION No potential for bioaccumlation or biomagnification.
ECOTOXICITY Addition of cement-based products to water may cause the pH to rise,
and they may therefore be toxic to aquatic life in some circumstances.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Dispose of in accordance with local and national regulations (normally
landfill), or to any place authorised to accept builders waste.
DISPOSAL OF PACKAGING Packaging should be treated as for the product, or may be incinerated.
14. TRANSPORT INFORMATION
UN NO. None assigned
PROPER SHIPPING NAME Portland cement mixture
ADR/RID Not classified as hazardous
IMCO Not classified as hazardous
ICAO/IATA Not classified as hazardous
PACKING GROUP
LABEL No hazard label
Material Safety Data Sheet According to 93/112EC TRITON TT55
15. REGULATION INFORMATION
CLASSIFICATION Irritant
LABEL INFORMATION:
IRRITATING TO THE SKIN
RISK OF SERIOUS DAMAGE TO THE EYES
MAY CAUSE SENSITISATION BY SKIN CONTACT
DO NOT BREATHE DUST
AVOID CONTACT WITH THE SKIN
READ ALL PRECAUTIONS BEFORE USE
The (COSHH) Control of Substances Hazardous to Health Regulations 1988 may apply to the use of this product
at work. Engineering control of operator exposure must be used where reasonably practicable in addition to the
following items of personal protective equipment.
WEAR SUITABLE PROTECTIVE CLOTHING, gloves and eye/face protection.
IN CASE OF CONTACT WITH EYES rinse immediately with plenty of water and seek medical advice.
AFTER CONTACT WITH SKIN, wash immediately with plenty of clean water.
KEEP OUT OF REACH OF CHILDREN.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRITON FILLET SEAL Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
313 30/09/2002 17/02/04
1.PRODUCT NAME: TRITON FILLET SEAL
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Ordinary Portland cement 65997-15-1 25 Xi (Irritant) See section 15
Also contains silica flour, silica sand and other additives
3. HAZARD IDENTIFICATION
Irritating to the skin
Risk of serious damage to eyes
May cause sensitisation by skin contact
4.FIRST AID
CONTACT WITH SKIN Wash off with plenty of soap and water. Remove contaminated
clothing.
CONTACT WITH EYES Wash out with water for at least 15 minutes and seek medical advice
without delay.
INGESTION Wash out mouth with water and give plenty of water to drink.
DO NOT INDUCE VOMITING.
INHALATION Remove to fresh air. If nose or airways become inflamed, seek medical
advice.
OTHER INFORMATION Until the mixture has set, may cause both irritant and allergic contact
dermatitis.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA As appropriate to surrounding fire
SPECIAL PROTECTIVE EQUIPMENT No particular requirement
Material Safety Data Sheet According to 93/112EC TRITON FILLET SEAL
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount
involved which may include eye/face protection, PVC or synthetic
rubber gloves, protective footwear and overalls, particularly
during mixing operations.
ENVIRONMENTAL PRECAUTIONS Contain the spillage and keep children away from the area.
CLEAN-UP PROCEDURES Recover the spilt material in a dry state if possible.
Minimise generation of airborne dust.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Observe good hygiene standards and minimise skin contact.
Wear suitable protective clothing according to item 8.
STORAGE INFORMATION Keep containers tightly closed in a cool place.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
When handling or mixing the product, protective clothing should be worn, including
eye protection and PVC or synthetic rubber gloves.
Wash hands and exposed skin before meals and after work.
Do not wear contaminated clothing.
EXPOSURE LIMITS Occupational exposure standard (8h TWA):
10mg/m³ total inhalable dust, 5mg/m³ respirable dust
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Grey powder Oxidising properties None
Odour None Vapour pressure Not relevant
pH 11, when wet. Relative density Not relevant
Boiling point Not relevant Bulk density 1300 kg/m³
Melting point Not relevant Viscosity Not relevant
Flash point None Solubility Very slightly soluble in water
Autoignition temperature Not combustible Partition coefficient Not relevant
Explosive properties None Other data
TRITON FILLET SEAL Material Safety Data Sheet According to 93/112EC
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID Damp (degrades product).
MATERIALS TO AVOID No particular requirements.
11.TOXICOLOGICAL INFORMATION
Severe eye irritant. Irritating to skin – the powder or its mixture with water may cause irritant dermatitis or
burns, and traces of hexavalent chromium in the product may cause allergic dermatitis. Ingestion of small
amounts is unlikely to cause any significant reaction, but large doses may result in irritation to the gastro
intestinal tract.
12.ECOLOGICAL INFORMATION
MOBILITY Not mobile in soil.
DEGRADABILITY Relatively inert.
ACCUMULATION No potential for bioaccumlation or biomagnification.
ECOTOXICITY Addition of cement-based products to water may cause the pH to rise,
and they may therefore be toxic to aquatic life in some circumstances.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Dispose of in accordance with local and national regulations (normally
landfill), or to any place authorised to accept builders waste.
DISPOSAL OF PACKAGING Packaging should be treated as for the product, or may be incinerated.
14. TRANSPORT INFORMATION
UN NO. None assigned
PROPER SHIPPING NAME Portland cement mixture
ADR/RID Not classified as hazardous
IMCO Not classified as hazardous
ICAO/IATA Not classified as hazardous
PACKING GROUP
LABEL No hazard label
Material Safety Data Sheet According to 93/112EC TRITON FILLET SEAL
15. REGULATION INFORMATION
CLASSIFICATION Irritant
LABEL INFORMATION:
IRRITATING TO THE SKIN
RISK OF SERIOUS DAMAGE TO THE EYES
MAY CAUSE SENSITISATION BY SKIN CONTACT
DO NOT BREATHE DUST
AVOID CONTACT WITH THE SKIN
READ ALL PRECAUTIONS BEFORE USE
The (COSHH) Control of Substances Hazardous to Health Regulations 1988 may apply to the use of this product
at work. Engineering control of operator exposure must be used where reasonably practicable in addition to the
following items of personal protective equipment.
WEAR SUITABLE PROTECTIVE CLOTHING, gloves and eye/face protection.
IN CASE OF CONTACT WITH EYES rinse immediately with plenty of water and seek medical advice.
AFTER CONTACT WITH SKIN, wash immediately with plenty of clean water.
KEEP OUT OF REACH OF CHILDREN.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TTME Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
Not classified as 313 05/09/97
hazardous
1.PRODUCT NAME: TTME (TRITON TANKING MIX ELASTIFIER)
2. COMPOSITION
An approximately 50% aqueous dispersion of n-butyl acrylate/styrene copolymer
3. HAZARD IDENTIFICATION
Not classified as hazardous for supply or transport
4.FIRST AID
CONTACT WITH SKIN Wash off with plenty of soap and water. Remove contaminated
clothing.
CONTACT WITH EYES Wash out with water for at least 15 minutes and seek medical advice.
INGESTION Wash out mouth with water and give plenty of water to drink. Seek
medical advice.
INHALATION Remove to fresh air. Keep warm and at rest.
OTHER INFORMATION
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA As appropriate to surrounding fire
SPECIAL PROTECTIVE EQUIPMENT No particular requirement
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount
involved which may include eye/face protection and PVC or
synthetic rubber gloves.
ENVIRONMENTAL PRECAUTIONS Contain the spillage. Avoid large amounts entering water
courses. (cont’d)
Material Safety Data Sheet According to 93/112EC TTME
6. ACCIDENTAL RELEASE MEASURES (cont’d.)
CLEAN-UP PROCEDURES Large spillages should be pumped into containers, soak up
remainder with dry sand or earth. Small spillages may be
washed down with water, if waste water is disposed of
correctly.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Observe normal industrial hygiene standards.
STORAGE INFORMATION Keep containers tightly closed in a cool place. Protect from
frost.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
When handling or mixing the product, protective clothing should be worn, including
eye protection and PVC or synthetic rubber gloves.
Wash hands and exposed skin before meals and after work.
Do not wear contaminated clothing.
EXPOSURE LIMITS Refer to the current edition of HSE Guidance Note EH40
(Occupational exposure limits). The following may be present in the product:
n-butyl acrylate [141-32-2], stryrene [100-42-5], ethylbenzene [100-41-4], acrylamide
[79-06-1] and formaldehyde [50-00-0].
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance White liquid Oxidising properties None
Odour Faint Vapour pressure 23 mbar (water)
pH 8 Relative density 1.03 at 20°C
Boiling point About 100°C (water) Bulk density Not relevant
Melting point About 0°C (water) Viscosity 200mPa at 23°C
Flash point None Solubility Miscible with water
Autoignition temperature Not combustible Partition coefficient Not relevant
Explosive properties None Other data
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID Frost.
MATERIALS TO AVOID No particular requirements.
TTME Material Safety Data Sheet According to 93/112EC
11.TOXICOLOGICAL INFORMATION
Not harmful to health if handled correctly according to the given recommendations.
12.ECOLOGICAL INFORMATION
MOBILITY Low mobility in the soil – binds to soil particles.
DEGRADABILITY Eliminated from water by abiotic processes, eg adsorption onto
activated sludge
ACCUMULATION No potential for bioaccumlation or biomagnification.
ECOTOXICITY Do not discharge to natural waters without pretreatment.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Dispose of in accordance with local and national regulations (normally
by incineration).
DISPOSAL OF PACKAGING Packaging should be treated as for the product.
14. TRANSPORT INFORMATION
UN NO. None assigned
PROPER SHIPPING NAME Aqueous copolymer suspension
ADR/RID Not classified as hazardous
IMCO Not classified as hazardous
ICAO/IATA Not classified as hazardous
PACKING GROUP
LABEL No hazard label
15. REGULATION INFORMATION
CLASSIFICATION Not classified as hazardous
LABEL INFORMATION:
WEAR GLOVES AND EYE PROTECTION. WASH HANDS AND EXPOSED SKIN AFTER USE.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
Material Safety Data Sheet According to 93/112EC TTME
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRITON T.Q.S Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
314 23/02/01 17/02/04
1.PRODUCT NAME: TRITON QUICK SET (T.Q.S)
2. COMPOSITION
Hazardous ingredient CAS No. Weight % Symbols Risk Phrases
Rapid Hardening Portland cement <50 Xi (Irritant) See section 15
Calcium Aluminate Cement <30 Xi (Irritant)
Also contains silica sand and other additives
3. HAZARD IDENTIFICATION
Irritating to the skin
Risk of serious damage to eyes
May cause sensitisation by skin contact
4.FIRST AID
CONTACT WITH SKIN Wash off with plenty of soap and water. Remove contaminated
clothing.
CONTACT WITH EYES Wash out with water for at least 15 minutes and seek medical advice
without delay.
INGESTION Wash out mouth with water and give plenty of water to drink.
DO NOT INDUCE VOMITING.
INHALATION Remove to fresh air. If nose or airways become inflamed, seek medical
advice.
OTHER INFORMATION Until the mixture has set, may cause both irritant and allergic contact
dermatitis.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA As appropriate to surrounding fire
SPECIAL PROTECTIVE EQUIPMENT No particular requirement
Material Safety Data Sheet According to 93/112EC TRITON T.Q.S
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount
involved which may include eye/face protection, PVC or synthetic
rubber gloves, protective footwear and overalls, particularly
during mixing operations.
ENVIRONMENTAL PRECAUTIONS Contain the spillage and keep children away from the area.
CLEAN-UP PROCEDURES Recover the spilt material in a dry state if possible.
Minimise generation of airborne dust.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Observe good hygiene standards and minimise skin contact.
Wear suitable protective clothing according to item 8.
STORAGE INFORMATION Keep containers tightly closed in a cool place.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
When handling or mixing the product, protective clothing should be worn, including
eye protection and PVC or synthetic rubber gloves.
Wash hands and exposed skin before meals and after work.
Do not wear contaminated clothing.
EXPOSURE LIMITS Occupational exposure standard (8h TWA):
10mg/m³ total inhalable dust, 5mg/m³ respirable dust
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Grey powder Oxidising properties None
Odour None Vapour pressure Not relevant
pH 11, when wet. Relative density Not relevant
Boiling point Not relevant Bulk density 1300 kg/m³
Melting point Not relevant Viscosity Not relevant
Flash point None Solubility Very slightly soluble in water
Autoignition temperature Not combustible Partition coefficient Not relevant
Explosive properties None Other data
TRITON T.Q.S Material Safety Data Sheet According to 93/112EC
10.STABILITY/REACTIVITY
REACTIVITY Sets rapidly when mixed with water, large amounts will also heat up
after mixing
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID Damp (degrades product).
MATERIALS TO AVOID No particular requirements.
11.TOXICOLOGICAL INFORMATION
Severe eye irritant. Irritating to skin – the powder or its mixture with water may cause irritant dermatitis or
burns, and traces of hexavalent chromium in the product may cause allergic dermatitis. Ingestion of small
amounts is unlikely to cause any significant reaction, but large doses may result in irritation to the gastro
intestinal tract.
12.ECOLOGICAL INFORMATION
MOBILITY Not mobile in soil.
DEGRADABILITY Relatively inert.
ACCUMULATION No potential for bioaccumlation or biomagnification.
ECOTOXICITY Addition of cement-based products to water may cause the pH to rise,
and they may therefore be toxic to aquatic life in some circumstances.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Dispose of in accordance with local and national regulations (normally
landfill), or to any place authorised to accept builders waste.
DISPOSAL OF PACKAGING Packaging should be treated as for the product, or may be incinerated.
14. TRANSPORT INFORMATION
UN NO. None assigned
PROPER SHIPPING NAME Portland cement mixture
ADR/RID Not classified as hazardous
IMCO Not classified as hazardous
ICAO/IATA Not classified as hazardous
PACKING GROUP
LABEL No hazard label
Material Safety Data Sheet According to 93/112EC TRITON T.Q.S
15. REGULATION INFORMATION
CLASSIFICATION Irritant
LABEL INFORMATION:
IRRITATING TO THE SKIN
RISK OF SERIOUS DAMAGE TO THE EYES
MAY CAUSE SENSITISATION BY SKIN CONTACT
DO NOT BREATHE DUST
AVOID CONTACT WITH THE SKIN
READ ALL PRECAUTIONS BEFORE USE
The (COSHH) Control of Substances Hazardous to Health Regulations 1988 may apply to the use of this product
at work. Engineering control of operator exposure must be used where reasonably practicable in addition to the
following items of personal protective equipment.
WEAR SUITABLE PROTECTIVE CLOTHING, gloves and eye/face protection.
IN CASE OF CONTACT WITH EYES rinse immediately with plenty of water and seek medical advice.
AFTER CONTACT WITH SKIN, wash immediately with plenty of clean water.
KEEP OUT OF REACH OF CHILDREN.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRITON SBR Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co.Ltd.
129 Felixstowe Rd, Abbey Wood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
Not Classified MSDS Ref: TR Publication date Revision date
as Hazardous 02/07/2001
1.PRODUCT NAME: TRITON SBR
2. COMPOSITION Styrene/butadiene polymer dispersion in water
3.HAZARD IDENTIFICATION This product is not hazardous according to EEC criteria.
4.FIRST AID MEASURES
Never give fluids or induce vomiting if patient is unconscious or is having convulsions.
SWALLOWING No adverse effects anticipated by this route of exposure
incidental to proper industrial handling.
EYES Irrigate immediately with water for at least 5 minutes,
INHALATION No adverse effects anticipated by this route of
exposure.
SKIN Wash off in flowing water or shower.
5.FIRE-FIGHTING MEASURES
This product is an aqueous dispersion, unless dried it will not burn.
EXTINGUISHING MEDIA Water fog, Carbon Dioxide, Foam, Dry Chemicals.
HAZARDOUS COMBUSTION PRODUCTS Upon burning, the dry product generates dense black
smoke.
PROTECTION OF FIREFIGHTERS Wear positive-pressure self-contained breathing
apparatus and protective fire fighting clothing,
(includes fire fighting helmet, coat, pants, boots and
gloves).
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear adequate personal protective equipment. See
Section 8, Exposure Controls/Personal Protection.
ENVIRONMENTAL PRECAUTIONS Prevent contamination of surface and groundwater.
METHODS OF CLEANING UP Small spills may be flushed away with large quantities
of water. Large spills should be contained and
recovered if possible; if not possible divert spill to
pond and allow to dry.
Material Safety Data Sheet According to 93/112EC TRITON SBR
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Good general ventilation should be sufficient for most
conditions.
STORAGE INFORMATION This product must be protected from freezing and
exposure to temperatures exceeding 40 deg C. Store at
room temperature. Product may develop bacterial
odours upon long-term storage.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
EXPOSURE GUIDELINES None established.
ENGINEERING CONTROL Good general ventilation should be sufficient for most
conditions.
PERSONAL PROTECTIVE EQUIPMENT
RESPIRATORY PROTECTION For most conditions, no respiratory protection should be
needed however, in misty atmospheres, use an approved
mist respirator.
SKIN PROTECTION No precautions other than clean body-covering clothing
should be needed. Use impervious gloves when
prolonged or frequently repeated contact could occur.
EYE/FACE PROTECTION Use safety glasses.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Emulsion Freezing point/range 0 deg.C (water)
Colour Milky White Boiling point/range 100 deg.C (water)
Odour Practically odourless Water Solubility miscible in all proportions
Solid content 45% (approx) Flash point not applicable
pH 10.5 Flammability not applicable
Rel. density (water=1) 0.98-1.04 Auto-ignition temp not applicable
10.STABILITY/REACTIVITY
CHEMICAL STABILITY Stable under normal handling and storage conditions.
CONDITIONS TO AVOID May coagulate if frozen (0 deg.C) The dry resin is
combustible.
MATERIALS TO AVOID Addition of chemicals, such as acids or multivalent
metal salts, may cause coagulation.
11.TOXICOLOGICAL INFORMATION
INGESTION Single dose oral toxicity is low. The oral LD50 for rats is >2000 mg/kg. No
hazards anticipated from swallowing small amounts incidental to normal
industrial handling.
(Cont’d)
TRITON SBR Material Safety Data Sheet According to 93/112EC
11.TOXICOLOGICAL INFORMATION (cont’d)
SKIN CONTACT The LD50 for skin absorption in rats is >2000 mg/kg. Short single exposure is not
likely to cause significant skin irritation. Prolonged or repeated exposure may
cause skin irritation. Skin absorption is unlikely due to physical properties.
INHALATION No adverse effects are anticipated from inhalation .
EYE CONTACT May cause slight transient (temporary) eye irritation. Corneal injury is unlikely.
12.ECOLOGICAL INFORMATION
DEGRADATION Biodegradation reached in the Closed Bottle Test (OECD Test No. 301 D) after
28 days: <10 % Latex dispersions will colour waters to a milky white.
AQUATIC TOXICITY Acute LC50 for rainbow trout (Onchorynchus mykiss) is >100 mg/L.
Acute EC50 for water flea (Daphnia magna) is 10-100 mg/L.
13.DISPOSAL CONSIDERATIONS
Dispose of according to local and national regulations.
14. TRANSPORT INFORMATION
Product is not classified for any mode of transportation.
15.REGULATORY INFORMATION
EEC Classification and User Label Information
This product does not require classification according to the criteria of the Commission of the European
Communities.
16.OTHER INFORMATION
No other information
NOTICE TO CUSTOMER:-
ENSURE ALL POTENTIAL USERS OF THIS PRODUCT ARE AWARE OF THIS SDS PRIOR TO USING
THE PRODUCT.
KEEP SDS IN A SAFE PLACE READILY LOCATABLE IN CASE OF FUTURE REQUIREMENT.
READ THIS SDS IN CONJUNCTION WITH THE LABEL AND DIRECTIONS FOR USE ON THE
PRODUCT CONTAINER.
DESTROY ALL OBSOLETE COPIES RELATING TO THIS PRODUCT
THIS SDS RELATES ONLY TO THE PRODUCT SPECIFIED.
COPIES OF THIS DOCUMENT ARE AVAILABLE ON REQUEST.
THIS SAFETY DATA SHEET IS BASED ON THE BEST OF CURRENT INFORMATION AND ADVICE
AVAILABLE TO US AND IS BELIEVED TO BE TRUE AND ACCURATE. NO LIABILITY CAN BE
ACCEPTED FOR LOSS, DAMAGE OR INJURY AS CONDITIONS OF USE ARE OUTSIDE OUR
CONTROL. THIS IS NOT A TECHNICAL SPECIFICATION.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long term
exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper explosive limit.
TRISEAL - RESIN (Part 1) Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: Publication date Revision date
26/02/2002
1.PRODUCT NAME: TRISEAL - RESIN (Part 1)
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Bisphenol A and F epoxy 25068-38-6 <60% Xi (Irritant) R36/38,43
Resins 54208-63-8 {
Alkylglycidylether 68081-84-5 2683582 <15% Xi (Irritant) R36/38,R43,R51/53
3. HAZARD IDENTIFICATION
Irritant
Irritating to skin and eyes.
May cause sensitisation by skin contact.
Toxic to aquatic organisms, may cause long term adverse effects in the
aquatic environment.
4. FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water.
CONTACT WITH EYES Wash out with water for several minutes and seek medical advice.
INGESTION Seek medical advice in the event of discomfort.
INHALATION Remove to fresh air if fumes cause irritation of nose or throat.
OTHER INFORMATION May aggravate existing respiratory problems.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA Dry powder or foam. For small fires use CO . Never use water jet.
²
SPECIAL PROTECTIVE EQUIPMENT For fires in confined spaces, use breathing apparatus.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount
involved, which may include eye/face protection, PVC or
synthetic rubber gloves, protective footwear, overalls.
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
(Contd.)
Material Safety Data Sheet According to 93/112EC TRISEAL – RESIN (Part 1)
6.ACCIDENTAL RELEASE MEASURES (contd.)
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbent and shovel into
a suitable closed container for disposal according to item 13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Observe good hygiene standards and minimise skin contact.
Wear suitable protective clothing according to item 8.
Avoid open flames and sources of ignition.
STORAGE INFORMATION Keep containers tightly closed in a cool place, out of direct
sunlight. Keep stored well ventilated.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Where prolonged or repeated exposure is likely, protective clothing should be worn,
including eye protection and PVC or synthetic rubber gloves.
Wash hands and exposed skin before meals and after work. Do not eat, drink or smoke
whilst handling the product.
Do not wear contaminated clothing. Ventilate confined spaces thoroughly.
EXPOSURE LIMITS None prescribed in EH40
Slight irritant, not considered hazardous.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Red liquid Oxidising properties None
Odour Faint Vapour pressure No data
pH N/A Relative density 1.13 (25ºC)
Boiling point >200°c Bulk density Not relevant
Melting point Not Relevant Viscosity No data
Flash point >150C Solubility Insoluble in water
Autoignition temperature No data Partition coefficient No data
Explosive properties No data Other data
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID High temperatures (degrades resin).
MATERIALS TO AVOID Strong oxidising agents, strong acids and bases.
TRISEAL - RESIN (Part 1) Material Safety Data Sheet According to 93/112EC
11.TOXICOLOGICAL INFORMATION
No available data on acute toxicity. Irritating to eyes. A mild skin irritant and mild sensitising agent.
12.ECOLOGICAL INFORMATION
MOBILITY Low soil absorption
DEGRADABILITY Not easily biodegradable.
ACCUMULATION There is potential for bioaccumlation. Biomagnification is unlikely.
ECOTOXICITY Toxic to aquatic organisms.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Chemical residues are normally regarded as Special Waste. Dispose of
in accordance with local and national regulations (incinerate or
landfill).
DISPOSAL OF PACKAGING Uncleaned packaging should be treated as for the product.
14. TRANSPORT INFORMATION
UN NO. 3082
PROPER SHIPPING NAME Liquid epoxy resin
ADR/RID Class 9 No/letter:11-C
IMCO
MFAG Table No.
EmS No.
IATA/IACO Class 9 Environmentally hazardous substance, liquid, n.o.s.
PACKING GROUP III
LABEL No hazard label
15. REGULATORY INFORMATION
CLASSIFICATION Irritant
LABEL INFORMATION
R36/38: Irritating to eyes and skin.
R43: May cause sensitisation by skin contact.
S28: After contact with skin, wash immediately with plenty of water.
S37/39: Wear suitable gloves and eye/face protection.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S61: Avoid release to the environment. Refer to special instructions/Safety data sheets.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE
Control of Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act
and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
Required by health and safety legislation.
Material Safety Data Sheet According to 93/112EC TRISEAL - RESIN (Part 1)
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRISEAL–HARDENER (Part 2) Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: Publication date Revision date
TR 26/02/2002
1.PRODUCT NAME: TRISEAL – HARDENER (Part 2)
2. COMPOSITION
Hazardous ingredient CAS No. Weight % Symbols Risk Phrases
Tris-2,4,6(Dimethyl amino methyl) phenol 90-72-2 <5.0% Xn R22-36/38
Bis(Dimethyl amino methyl) phenol 71074-89-0 <1.0% Xn R22-36/38
Alkylated polyamine adduct <90% C (Corrosive) R21/22,34, 42/43
3. HAZARD IDENTIFICATION
Corrosive – Causes burns.
Harmful if swallowed.
May cause sensitisation by skin contact.
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water. If irritation persists, obtain
medical advice.
CONTACT WITH EYES Wash out with water for several minutes and seek medical advice.
INGESTION Give plenty of water – if possible, charcoal slurry. Do not induce
vomiting.
INHALATION Remove to fresh air. If symptoms persist, seek medical advice.
OTHER INFORMATION Treat symptomatically.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA Dry powder, fog or foam. For small fires use CO² . DO NOT
use high pressure water jet.
SPECIAL PROTECTIVE EQUIPMENT Full protective equipment. Toxic and irritant fumes may be
produced.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount involved,
which may include eye/face protection, PVC or synthetic rubber
gloves, protective footwear, overalls. Avoid contact with eyes and
skin.
Material Safety Data Sheet According to 93/112EC TRISEAL - HARDENER (Part 2)
6.ACCIDENTAL RELEASE MEASURES (contd.)
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbent and shovel into a
suitable closed container for disposal according to item 13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Ensure adequate ventilation in work areas. Keep away from
sources of ignition – no smoking. Avoid contact with eyes and
skin. Avoid inhaling vapour, ensure good ventilation.
STORAGE INFORMATION Keep containers tightly closed in a cool place, out of direct
sunlight. Keep stored well ventilated. Keep away from food
and feeding stuffs.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear protective clothing, including eye protection and PVC or synthetic/rubber gloves.
Wash hands and exposed skin before meals and after work. Do not eat, drink or smoke
whilst handling the product.
EXPOSURE LIMITS None prescribed in EH40
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Brown Liquid Oxidising properties None
Odour Amine-like Vapour pressure < 8 hpa @ 25°c
pH >7 (in water) Relative density 1.01 (25ºC)
Boiling point Decomposes Bulk density Not relevant
Melting point Not Relevant Viscosity No data
Flash point >100°C (CC) Solubility Partially miscible with water
Autoignition temperature No data Partition coefficient No data
Explosive properties No data Other data Avoid contact with strong
acids and oxidizers.
TRISEAL – HARDENER(PART 2) Material Safety Data SheetAccording to 93/112EC
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID High Temperatures, formation of aerosols, static discharges.
MATERIALS TO AVOID Strong oxidising agents, acids and bases.
11.TOXICOLOGICAL INFORMATION
LD50 (rat, oral): > 5000mg/kg (by calculation). Eye irritation (rabbit): corrosive. Skin irritation (rabbit): corrosive.
Dermal sensitisation (guinea pig): sensitiser
12.ECOLOGICAL INFORMATION
MOBILITY Likely to be mobile in soil.
DEGRADABILITY Readily biodegradable.
ACCUMULATION There is little potential for bioaccumlation. Biomagnification is
unlikely.
ECOTOXICITY Harmful to aquatic organisms:
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Chemical residues are normally regarded as Special Waste. Incinerate
in compliance with the Environmental Protection Act 1990 (Process
Guidance Note IPR5/1)
DISPOSAL OF PACKAGING As for the product.
14. TRANSPORT INFORMATION
UN NO. 2735
PROPER SHIPPING NAME
ADR/RID Class 8. Item 53(b)
IMCO Class 8. IMDG Code page
MFAG Table No. 320
EmS No. 8-05
IATA/IACO Class 8
PACKING GROUP 3
LABEL Corrosive
Material Safety Data Sheet According to 93/112EC TRISEAL – HARDENER (Part 2)
15. REGULATORY INFORMATION
CLASSIFICATION Corrosive
LABEL INFORMATION
R34: Causes burns.
R21/22: Harmful in contact with skin and if swallowed.
R42/43: May cause sensitisation by inhalation and skin contact.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S28: After contact with skin, wash immediately with plenty of water and mild soap.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE
Control of Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act
and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of
workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIMOL RESINS (15, 34, 35, 36, 40, 41) Material Safety Data Sheet According to 93/112EC
Triton Chemical Manufacturing Co. Ltd.
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
300 4/4/97
1.PRODUCT NAME: TRIMOL RESINS 15, 34, 35, 36, 40, 41
2. COMPOSITION
Hazardous ingredient CAS Nos. Weight, % Symbols Risk Phrases
Bisphenol A and F epoxy 25068-38-6, 68609-97-2, 100 Xi (Irritant) R36/38,43,51/53
Resins, diglycidyl ethers 28064-14-4
3.HAZARD IDENTIFICATION
Irritant
Irritating to skin and eyes
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water.
CONTACT WITH EYES Wash out with water for several minutes and seek medical advice.
INGESTION Seek medical advice in the event of discomfort.
INHALATION Remove to fresh air if fumes cause irritation of nose or throat.
OTHER INFORMATION May aggravate existing respiratory problems.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA Dry powder or foam. For small fires use CO² . Never use water
jet.
SPECIAL PROTECTIVE EQUIPMENT For fires in confined spaces, use breathing apparatus.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount
involved, which may include eye/face protection, PVC or
synthetic rubber gloves, protective footwear and overalls.
(Contd.).
Material Safety Data Sheet According to 93/112EC TRIMOL RESINS (15,34,35,36,40,41)
6.ACCIDENTAL RELEASE MEASURES (contd.)
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbents and shovel
into a suitable closed container for disposal according to item
13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Observe good hygiene standards and minimise skin contact.
Wear suitable protective clothing according to item 8.
STORAGE INFORMATION Keep containers tightly closed in a cool place, out of direct
sunlight. Keep stored well ventilated.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Where prolonged or repeated exposure is likely, protective clothing should be
worn, including eye protection, boots and PVC or synthetic rubber gloves.
Wash hands and exposed skin before meals and after work. Do not eat, drink
or smoke whilst handling the product.
Do not wear contaminated clothing. Ventilate confined spaces thoroughly.
EXPOSURE LIMITS None prescribed in EH40.
Slight irritant, not considered hazardous.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear, golden liquid Oxidising properties None
Odour Faint Vapour pressure 1Pa (20°C)
pH 7 (50% suspension in water) Relative density 1.2-1.13 (15°C)
Boiling point Decomposes Bulk density Not Relevant
Melting point Not Relevant Viscosity No data
Flash point >150°C Solubility Insoluble in water
Autoignition temperature No data Partition coefficient No data
Explosive properties No data Other data
TRIMOL RESINS (15, 34, 35, 36, 40,41) Material Safety Data Sheet According to 93/112EC
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID High temperatures (degrades resin).
MATERIALS TO AVOID Strong oxidising agents, acids and bases.
Excess of hardener (uncontrolled polymerisation reaction).
11.TOXICOLOGICAL INFORMATION
Not available data on acute toxicity. Irritating to eyes. A mild skin irritant and mild sensitising agent.
12.ECOLOGICAL INFORMATION
MOBILITY Low soil absorption.
DEGRADABILITY Not easily biodegradable
ACCUMULATION There is potential for bioaccumulation. Biomagnification is unlikely.
ECTOTOXICITY Toxic to aquatic organisms:
(TLm96: fish 1.2mg/litre, Daphnia 2.7 mg/litre, algae 9.4mg/litre)
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT: Chemical residues are normally regarded as Special Waste. Dispose of
in accordance with local and national regulations (incinerate or
landfill).
DISPOSAL OF PACKAGING: Uncleaned packaging should be treated as for the product.
14. TRANSPORT INFORMATION
UN No. None assigned
PROPER SHIPPING NAME Liquid epoxy resin
ADR/RID Not classified as hazardous
IMCO Not classified as hazardous
MFAG Table No.
EmS No.
IATA/IACO Not classified as hazardous
PACKING GROUP
LABEL No hazard label
Material Safety Data Sheet According to 93/112EC TRIMOL RESINS (15, 34, 35, 36, 40, 41)
15.REGULATORY INFORMATION
CLASSIFICATION Irritant
LABEL INFORMATION
S24: Irritating to eyes and skin.
S26: May cause sensitisation by skin contact.
S28: After contact with skin, wash immediately with plenty of water.
S37/39: Wear suitable gloves and eye/face protection.
Refer to other relevant legislation such as Health and Safety at Work etc Act (HSWA), the Control of
Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of
Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of
workplace risk as required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of
publication, but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the
technical data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIMOL 41 FILLER Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
315 05/09/97
1.PRODUCT NAME: TRIMOL 41 FILLER
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Ordinary Portland cement 65997-15-1 71 Xi (Irritant) See section 15
Also contains silica sand and other additives
3. HAZARD IDENTIFICATION
Irritant
Irritating to skin and eyes
4.FIRST AID
CONTACT WITH SKIN Wash off with plenty of soap and water. Remove contaminated
clothing.
CONTACT WITH EYES Wash out with water for at least 15 minutes and seek medical advice
without delay.
INGESTION Wash out mouth with water and give plenty of water to drink.
DO NOT INDUCE VOMITING.
INHALATION Remove to fresh air. If nose or airways become inflamed, seek medical
advice.
OTHER INFORMATION Until the mixture has set, may cause both irritant and allergic contact
dermatitis.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA As appropriate to surrounding fire
SPECIAL PROTECTIVE EQUIPMENT No particular requirement
Material Safety Data Sheet According to 93/112EC TRIMOL 41 FILLER
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount
involved which may include eye/face protection, PVC or synthetic
rubber gloves, protective footwear and overalls, particularly
during mixing operations.
ENVIRONMENTAL PRECAUTIONS Contain the spillage and keep children away from the area.
CLEAN-UP PROCEDURES Recover the spilt material in a dry state if possible.
Minimise generation of airborne dust.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Observe good hygiene standards and minimise skin contact.
Wear suitable protective clothing according to item 8.
STORAGE INFORMATION Keep containers tightly closed in a cool place.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
When handling or mixing the product, protective clothing should be worn, including
eye protection and PVC or synthetic rubber gloves.
Wash hands and exposed skin before meals and after work.
Do not wear contaminated clothing.
EXPOSURE LIMITS Occupational exposure standard (8h TWA):
10mg/m³ total inhalable dust, 5mg/m³ respirable dust
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Grey powder Oxidising properties None
Odour None Vapour pressure Not relevant
pH 11, when wet. Relative density Not relevant
Boiling point Not relevant Bulk density 1300 kg/m³
Melting point Not relevant Viscosity Not relevant
Flash point None Solubility Very slightly soluble in water
Autoignition temperature Not combustible Partition coefficient Not relevant
Explosive properties None Other data
TRIMOL 41 FILLER Material Safety Data Sheet According to 93/112EC
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID Damp (degrades product).
MATERIALS TO AVOID No particular requirements.
11.TOXICOLOGICAL INFORMATION
Severe eye irritant. Irritating to skin – the powder or its mixture with water may cause irritant dermatitis or
burns, and traces of hexavalent chromium in the product may cause allergic dermatitis. Ingestion of small
amounts is unlikely to cause any significant reaction, but large doses may result in irritation to the gastro
intestinal tract.
12.ECOLOGICAL INFORMATION
MOBILITY Not mobile in soil.
DEGRADABILITY Relatively inert.
ACCUMULATION No potential for bioaccumlation or biomagnification.
ECOTOXICITY Addition of cement-based products to water may cause the pH to rise,
and they may therefore be toxic to aquatic life in some circumstances.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Dispose of in accordance with local and national regulations (normally
landfill), or to any place authorised to accept builders waste.
DISPOSAL OF PACKAGING Packaging should be treated as for the product, or may be incinerated.
14. TRANSPORT INFORMATION
UN NO. None assigned
PROPER SHIPPING NAME Portland cement mixture
ADR/RID Not classified as hazardous
IMCO Not classified as hazardous
ICAO/IATA Not classified as hazardous
PACKING GROUP
LABEL No hazard label
Material Safety Data Sheet According to 93/112EC TRIMOL 41 FILLER
15. REGULATION INFORMATION
CLASSIFICATION Irritant
LABEL INFORMATION:
CONTACT WITH WET MORTAR MAY CAUSE IRRITATION, DERMATITIS OR BURNS.
CONTACT BETWEEN THE POWDER AND BODY FLUIDS (eg Sweat or Eye Fluid) MAY ALSO CAUSE
IRRITATION, DERMATITIS OR BURNS.
RISK OF SERIOUS DAMAGE TO EYES.
READ ALL PRECAUTIONS BEFORE USE
The (COSHH) Control of Substances Hazardous to Health Regulations 1988 may apply to the use of this product
at work. Engineering control of operator exposure must be used where reasonably practicable in addition to the
following items of personal protective equipment.
WEAR SUITABLE PROTECTIVE CLOTHING, gloves and eye/face protection.
IN CASE OF CONTACT WITH EYES rinse immediately with plenty of water and seek medical advice.
AFTER CONTACT WITH SKIN, wash immediately with plenty of clean water.
KEEP OUT OF REACH OF CHILDREN.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIMOL 41 HARDENER Material Safety Data Sheet According to 93/112EC
Triton Chemical Manufacturing Co. Ltd.
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
Irritant
MSDS Ref: TR Publication date Revision date
304 11/4/97
1.PRODUCT NAME: TRIMOL 41 HARDENER
2. COMPOSITION
Hazardous ingredient CAS Nos. EC No. Weight, % Symbols Risk Phrases
Amine-epoxy resin adduct polymer 20 Xi (Irritant) R22, 36/38
3.HAZARD IDENTIFICATION
Harmful
Harmful if swallowed
Irritating to skin and eyes
Irritant
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water. Seek medical advice if irritation
develops.
CONTACT WITH EYES Wash out with water for several minutes and seek medical advice.
INGESTION Give plenty of water to drink. Do not induce vomiting. Seek medical
advice.
INHALATION Remove to fresh air. Keep warm and at rest. Seek medical advice after
significant exposure.
OTHER INFORMATION Treat symptomatically.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA Dry powder or foam. For small fires use CO² .
SPECIAL PROTECTIVE EQUIPMENT For fires in confined spaces, use breathing apparatus.
Toxic and irritant fumes of oxides of nitrogen may be
produced.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount
involved, which may include eye/face protection, PVC or
synthetic rubber gloves, protective footwear and overalls.
(Contd.).
Material Safety Data Sheet According to 93/112EC TRIMOL 41 HARDENER
6.ACCIDENTAL RELEASE MEASURES (contd.)
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbents and shovel
into a suitable closed container for disposal according to item
13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Observe good hygiene standards and minimise skin contact.
Wear suitable protective clothing according to item 8.
STORAGE INFORMATION Keep containers tightly closed in a cool place, out of direct
sunlight. Keep stored well ventilated.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Where prolonged or repeated exposure is likely, protective clothing should be
worn, including eye protection, boots and PVC or synthetic rubber gloves.
Wash hands and exposed skin before meals and after work. Do not eat, drink
or smoke whilst handling the product.
Do not wear contaminated clothing. Ventilate confined spaces thoroughly.
EXPOSURE LIMITS None prescribed in EH40.
Slight irritant, not considered hazardous.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Viscous liquid Oxidising properties None
Odour Slight, ammonia-like Vapour pressure 2000Pa (20°C)
pH 9 (50% suspension in water) Relative density 1.04 (15°C)
Boiling point 100°C Bulk density Not Relevant
Melting point Solid below 0°C Viscosity Thixotropic
Flash point No data Solubility Partially soluble in water
Autoignition temperature No data Partition coefficient No data
Explosive properties No data Other data
TRIMOL 41 HARDENER Material Safety Data Sheet According to 93/112EC
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID Protect from frost.
MATERIALS TO AVOID Strong oxidising agents, acids.
11.TOXICOLOGICAL INFORMATION
Not available data on acute toxicity. Expected value from structurally related products:
LD50 (acute, oral) 1000-4000 mg/kg.
Irritating to eyes.
12.ECOLOGICAL INFORMATION
MOBILITY Mobile – avoid subsoil penetration.
DEGRADABILITY Not easily biodegradable
ACCUMULATION No evidence for bioaccumulation. Biomagnification is unlikely.
ECTOTOXICITY No data
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT: Chemical residues are normally regarded as Special Waste. Dispose of
in accordance with local and national regulations (incinerate or
landfill).
DISPOSAL OF PACKAGING: Uncleaned packaging should be treated as for the product.
14. TRANSPORT INFORMATION
UN No. None assigned
PROPER SHIPPING NAME
ADR/RID Not classified as hazardous
IMCO Not classified as hazardous
MFAG Table No.
EmS No.
IATA/IACO Not classified as hazardous
PACKING GROUP
LABEL No hazard label
Material Safety Data Sheet According to 93/112EC TRIMOL 41 HARDENER
15.REGULATORY INFORMATION
CLASSIFICATION Irritant
LABEL INFORMATION
R22: Harmful if swallowed.
R36/38: Irritating to eyes and skin.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S37/39: Wear suitable gloves and eye/face protection.
Refer to other relevant legislation such as Health and Safety at Work etc Act (HSWA), the Control of
Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of
Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of
workplace risk as required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of
publication, but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the
technical data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
FILLED BITUMEN EMULSION Material Safety Data Sheet According to 93/112EC
Triton Chemical Manufacturing Co. Ltd.
129 Felixstowe Road, Abbey Wood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
Jan 2005
1. PRODUCT NAME: FILLED BITUMEN EMULSION
2. COMPOSITION
Hazardous ingredient CAS No. Weight % Symbols Risk Phrases
Bitumen 84742-83-4 50-60 None None
Caustic Potash 1310-58-3 <1 C R35
Potassium Carbonate 584-08-7 <1 Xi R35/37/38
Description Triton Filled Bitumen Emulsion is a rubberised anionic bitumen
emulsion, which dries to provide a thick, black, flexible coating.
Other information The material should be stored at temperatures between 5°C - 40°C.
3.HAZARD IDENTIFICATION
MAIN HAZARDS The product is a viscous black, non-flammable liquid.
The dried film is combustible and on combustion yields oxides of
carbon in common with other carbonaceous materials.
Causes irritation to eyes and skin.
4.FIRST AID
GENERAL ADVICE The use of protective clothing and gloves is recommended as the
basis of good industrial hygiene practice.
CONTACT WITH SKIN Wash immediately with soap and water. If material has dried on
skin, use proprietary skin cleansers, followed by soap and water.
CONTACT WITH EYES Wash copiously with clean water. Seek medical advice/attention.
INGESTION Do not induce vomiting. See medical advice immediately.
INHALATION In the event of inhalation remove patient to fresh air.
Keep patient at rest and seek immediate medical advice.
OTHER INFORMATION Where aspiration into lungs is suspected due to involuntary
vomiting. Seek immediate medical advice.
5.FIRE-FIGHTING MEASURES
The product is non-flammable as supplied
For the dried film the products of combustion are those normal for carbonaceous materials.
SPECIAL PROTECTIVE EQUIPMENT Use self-contained breathing apparatus and full protective
clothing, especially in confined locations.
All hydrocarbons produce carbon oxides on combustion.
Material Safety Data Sheet According to 93/112EC FILLED BITUMEN EMULSION
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear protective clothing, gloves and goggles if any possibility
of eye contact. Practice good industrial hygiene.
ENVIRONMENTAL PRECAUTIONS Prevent entry into drains and watercourses.
CLEAN-UP PROCEDURES Contain and recover any spillage, using inert absorbent
materials. Dispose of resulting waste material according to
local authority waste disposal regulations.
ADDITIONAL ADVICE Advise appropriate authorities if spillages enter drains or
watercourses.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Always ensure good ventilation when in use. Avoid skin contact, and
if eye contact is likely use eye protection.
STORAGE INFORMATION Store at temperatures between 5°C - 40°C. Always protect from frost
to prevent breakdown of emulsion. Examine condition of containers
regularly.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
ENGINEERING CONTROL MEASURES None normally necessary
GENERAL PROTECTION AND
HYGIENE MEASURES Use of protective clothing recommended.
RESPIRATORY PROTECTION None normally required.
HAND PROTECTION Use P.V.C. gloves
EYE PROTECTION Use suitable eye protection only if eye contact is likely.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Viscous liquid Colour Brown/black, dried film is black
Odour Slight ammoniacal pH 10.0 – 11.5
Boiling point Not Relevant Flash point Above 200°C
Solubility Insoluble. Disperses in water. Flammability Non-flammable: dried film is
Combustible.
10.STABILITY/REACTIVITY
CONDITIONS TO AVOID Frost. Conditions at or near 100°C.
MATERIALS TO AVOID Unstable in contact with cationic material.
HAZARDOUS DECOMPOSITION PRODUCTS None
FILLED BITUMEN EMULSION Material Safety Data Sheet According to 93/112EC
11.TOXICOLOGICAL INFORMATION
The material is essentially non-toxic.
12.ECOLOGICAL INFORMATION
PERSISTENCE AND DEGRADATION No Information available.
MOBILITY AND BIO-ACCUMULATION
POTENTIAL No information available
OTHER INFORMATION Spillage into water courses may be harmful to aquatic organisms.
13.DISPOSAL CONSIDERATIONS
RECOMMENDATIONS ON PRODUCT
DISPOSAL Dispose of any waste material in accordance with local waste
disposal regulations.
14. TRANSPORT INFORMATION
The material is classified as non-hazardous.
15.REGULATORY INFORMATION
Not classified as hazardous for supply.
No statutory label required.
16.OTHER INFORMATION
ADVICE TO USERS Irritating to eyes and skin. Avoid contact if possible.
Keep out of reach of children.
Do not empty into drains.
The information contained in this data sheet is to the best of our knowledge accurate at the date of
publication, but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the
technical data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRITON TT SUPER/SUPER WHITE Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: Publication date Revision date
22/06/2007
1.PRODUCT NAME: TRITON TT SUPER/SUPER WHITE
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Ordinary Portland cement 65997-15-1 Xi (Irritant) 36/37/38
Also contains graded silica sands or crushed limestone
aggregates together with small quantities of other additives
3. HAZARD IDENTIFICATION
Mixing with water or contact of powder with body fluids
produces a strong alkaline solution. This may cause serious
burns and ulceration both to skin and eyes.
4.FIRST AID
CONTACT WITH SKIN Wash the affected area thoroughly with soap and water. If
irritation continues seek medical advice. Clothing contaminated
with wet product should be removed and washed thoroughly
before re-use.
CONTACT WITH EYES Wash eyes immediately with plenty of clean water for at least
15 minutes and seek medical advice without delay.
INGESTION If swallowing has occurred, do not induce vomiting. Give
person plenty of water to drink. Seek medial attention.
INHALATION Move affected person to fresh air. If nose or airways become
inflamed seek medical attention.
5.FIRE-FIGHTING MEASURES
Cement based products are not flammable and will not facilitate combustion of other materials.
EXPOSURE HAZARDS Do not release water contaminated with cement-based products
into surface drains.
Material Safety Data Sheet According to 93/11 TRITON TT SUPER/SUPER WHITE
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Avoid contact with skin, eyes and clothing. Avoid breathing dust.
ENVIRONMENTAL PRECAUTIONS Prevent contamination of surface water.
CLEAN-UP PROCEDURES Recover spillage in dry state if possible. Minimise generation
of airborne dust. The product can be slurried with water. Keep
children away from clean-up operations. Dispose to a place
authorised to accept builders’ water. Small quantities can be
disposed of as normal household waste.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS When handling bags of cement-based products most of which
weigh 25kg, due regard should be paid to Manual Handling
Regulations 1992. Some bags may have a small amount of
cement dust on their outer surface. Appropriate personal
protection should be used whilst handling.
STORAGE INFORMATION Bags should be stacked in a safe and stable manner. Store in
dry conditions.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
TECHNICAL PROTECTIVE MEASURES No special measures required.
EXPOSURE LIMITS Occupational exposure standard (8h TWA):
10mg/m³ total inhalable dust, 5mg/m³ respirable dust
All Triton cement based products contain powders which if handled carelessly can raise dust.
The personal exposure to such dusts (cement, silica sand, crushed limestone etc.) must be kept below
10mg/m³ 8 hour TWA total inhalable dust and 5mg/m³respirable dust. Some of the cement based products
contain microsilica form of silica. The personal exposure level to amorphous silica must be kept below
6mg/m³ 8 hour TWA total inhalable dust and 3mg/m³ respirable dust.
Some sands and other fillers may contain small quantities of respirable silica for which the personal
exposure must be kept below 0.4mg/m³ 8 hour TWA.
If care is taken not to raise dust and the exposure levels for nuisance dusts are not exceeded, the levels for
respirable silica should be very low.
Applying Occupational Exposure Standards EH40/95 Sections 40 and 4.1. Also see Dust: General Principles
of Protection HSE Guidance Note EH44 Rev 1991.
• Occupational Exposure Standards Limits – 8 hour TWA, reference period from Guidance Note
EH40/95, Table 2.
AMORPHOUSE SILICA: Total inhalable dust: 6mg/m³
Respirable dust: 3mg/m³
PORTLAND CEMENT: Total inhalable dust: 10mg/m³
Respirable dust: 5mg/m³
TRITON TT SUPER/SUPER WHITE Material Safety Data Sheet According to 93/112EC
8.EXPOSURE CONTROLS/PERSONAL PROTECTION (Cont’d)
Suitable respiratory protection should be worn to ensure that
personal OES is not exceeded. If care is taken not to raise dust
during handling, the use of respirators is not normally necessary.
Wear suitable gloves.
Suitable goggles or face protection should be worn wherever
there is a risk of product powder or product/water mixture
entering the eye.
Wear overalls and closed footwear.
9.PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE Particulate
PARTICLE SIZE 5 – 6000 pm
pH of wet cement 12 - 14
10. STABILITY AND REACTIVITY
Stable under normal room temperature storage conditions
Bags will set solid if continually soaked with water.
11.TOXICOLOGICAL INFORMATION
EYE CONTACT Cement constituent is severe eye irritant. Mild exposures can
cause soreness. Gross exposures or untreated mild exposures can
lead to chemical burning and ulceration of the eye.
SKIN CONTACT The powder or product/water mixture may cause irritation,
contact dermatitis or allergic dermatitis and/or burns.
INHALATION Inhalation of the powder may cause inflammation of mucous
membranes.
INGESTION The swallowing of small amounts of product or product/water
mixtures is unlikely to cause any significant reaction. Larger
doses may result in irritation to the gastro intestinal tract.
12.ECOLOGICAL INFORMATION
AQUATIC TOXICITY RATING LC50 aquatic toxicity rating has not been determined. The
addition of any cement based product to water may, however,
cause the pH to rise and therefore may be toxic to aquatic life in
some circumstances. No other specific information available.
Material Safety Data Sheet According to 93/112EC TRITON TT SUPER/SUPER WHITE
13.DISPOSAL CONSIDERATIONS
Dispose of empty bags or surplus product to a place authorised to accept builders’ waste. Keep out of reach
of children. Small numbers of bags can be disposed of as normal household wastes.
14. TRANSPORT INFORMATION
Classification for transport not required.
15. REGULATION INFORMATION
SYMBOLS: Xi Irritant
RISK PHRASES
R36/37/38: Irritating to eyes, respiratory systems and skin.
SAFETY PHRASES
S22 Do not breathe dust.
S28 After contact with skin, wash immediately with plenty of soap and water.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical attention.
S24/25 Avoid contact with skin and eyes.
S37/39 Wear suitable gloves and eye/face protection. Keep out of reach of children.
READ ALL PRECAUTIONS BEFORE USE
The (COSHH) Control of Substances Hazardous to Health Regulations 1988 may apply to the use of this product
at work. Engineering control of operator exposure must be used where reasonably practicable in addition to the
following items of personal protective equipment.
WEAR SUITABLE PROTECTIVE CLOTHING, gloves and eye/face protection.
IN CASE OF CONTACT WITH EYES rinse immediately with plenty of water and seek medical advice.
AFTER CONTACT WITH SKIN, wash immediately with plenty of clean water.
KEEP OUT OF REACH OF CHILDREN.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRITON TT SUPER ADMIX Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co.Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: Publication date Revision date
01/02/2003 22/06/2007
1.PRODUCT NAME: TRITON TT SUPER ADMIX
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Ordinary Portland cement 65997-15-1 Xi (Irritant) 36/37/38
Also contains graded silica sands or crushed limestone
aggregates together with small quantities of other additives
3. HAZARD IDENTIFICATION
Mixing with water or contact of powder with body fluids
produces a strong alkaline solution. This may cause serious
burns and ulceration both to skin and eyes.
4.FIRST AID
CONTACT WITH SKIN Wash the affected area thoroughly with soap and water. If
irritation continues seek medical advice. Clothing contaminated
with wet product should be removed and washed thoroughly
before re-use.
CONTACT WITH EYES Wash eyes immediately with plenty of clean water for at least
15 minutes and seek medical advice without delay.
INGESTION If swallowing has occurred, do not induce vomiting. Give
person plenty of water to drink. Seek medial attention.
INHALATION Move affected person to fresh air. If nose or airways become
inflamed seek medical attention.
5.FIRE-FIGHTING MEASURES
Cement based products are not flammable and will not facilitate combustion of other materials.
EXPOSURE HAZARDS Do not release water contaminated with cement-based products
into surface drains.
Material Safety Data Sheet According to 93/11 TRITON TT SUPER ADMIX
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Avoid contact with skin, eyes and clothing. Avoid breathing dust.
ENVIRONMENTAL PRECAUTIONS Prevent contamination of surface water.
CLEAN-UP PROCEDURES Recover spillage in dry state if possible. Minimise generation
of airborne dust. The product can be slurred with water. Keep
children away from clean-up operations. Dispose to a place
authorised to accept builders’ water. Small quantities can be
disposed of as normal household waste.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS When handling bags of cement-based products most of which
weigh 25kg, due regard should be paid to Manual Handling
Regulations 1992. Some bags may have a small amount of
cement dust on their outer surface. Appropriate personal
protection should be used whilst handling.
STORAGE INFORMATION Bags should be stacked in a safe and stable manner. Store in
dry conditions.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
TECHNICAL PROTECTIVE MEASURES No special measures required.
EXPOSURE LIMITS Occupational Exposure Standard (OES) Limits 8 hour TWA
(According to EH40/95).
All Triton cement based products contain powders, which if handled carelessly can raise dust.
The personal exposure to such dusts (cement, silica sand, crushed limestone etc.) must be kept below
10mg/m³ 8 hour TWA total inhalable dust and 5mg/m³respirable dust. Some of the cement based products
contain microsilica form of silica. The personal exposure level to amorphous silica must be kept below
6mg/m³ 8 hour TWA total inhalable dust and 3mg/m³ respirable dust.
Some sands and other fillers may contain small quantities of respirable silica for which the personal
exposure must be kept below 0.4mg/m³ 8 hour TWA.
If care is taken not to raise dust and the exposure levels for nuisance dusts are not exceeded, the levels for
respirable silica should be very low.
Applying Occupational Exposure Standards EH40/95 Sections 40 and 4.1. Also see Dust: General Principles
of Protection HSE Guidance Note EH44 Rev 1991.
• Occupational Exposure Standards Limits – 8 hour TWA, reference period from Guidance Note
EH40/95, Table 2.
AMORPHOUS SILICA: Total inhalable dust: 6mg/m³
Respirable dust: 3mg/m³
PORTLAND CEMENT: Total inhalable dust: 10mg/m³
Respirable dust: 5mg/m³
TRITON TT SUPER ADMIX Material Safety Data Sheet According to 93/112EC
8.EXPOSURE CONTROLS/PERSONAL PROTECTION (Cont’d)
Suitable respiratory protection should be worn to ensure that
personal OES is not exceeded. If care is taken not to raise dust
during handling, the use of respirators is not normally necessary.
Wear suitable gloves.
Suitable goggles or face protection should be worn wherever
there is a risk of product powder or product/water mixture
entering the eye.
Wear overalls and closed footwear.
9.PHYSICAL AND CHEMICAL PROPERTIES
PHYSICAL STATE Particulate
PARTICLE SIZE 5 – 6000 pm
pH of wet cement 12 - 14
10. STABILITY AND REACTIVITY
Stable under normal room temperature storage conditions
Bags will set solid if continually soaked with water.
11.TOXICOLOGICAL INFORMATION
EYE CONTACT Cement constituent is severe eye irritant. Mild exposures can
cause soreness. Gross exposures or untreated mild exposures can
lead to chemical burning and ulceration of the eye.
SKIN CONTACT The powder or product/water mixture may cause irritation,
contact dermatitis or allergic dermatitis and/or burns.
INHALATION Inhalation of the powder may cause inflammation of mucous
membranes.
INGESTION The swallowing of small amounts of product or product/water
mixtures is unlikely to cause any significant reaction. Larger
doses may result in irritation to the gastro intestinal tract.
12.ECOLOGICAL INFORMATION
AQUATIC TOXICITY RATING LC50 aquatic toxicity rating has not been determined. The
addition of any cement based product to water may, however,
cause the pH to rise and therefore may be toxic to aquatic life in
some circumstances. No other specific information available.
Material Safety Data Sheet According to 93/112EC TRITON TT SUPER ADMIX
13.DISPOSAL CONSIDERATIONS
Dispose of empty bags or surplus product to a place authorised to accept builders’ waste. Keep out of reach
of children. Small numbers of bags can be disposed of as normal household wastes.
14. TRANSPORT INFORMATION
Classification for transport not required.
15. REGULATION INFORMATION
SYMBOLS: Xi Irritant
RISK PHRASES
R36/37/38: Irritating to eyes, respiratory systems and skin.
SAFETY PHRASES
S22 Do not breathe dust.
S28 After contact with skin, wash immediately with plenty of soap and water.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical attention.
S24/25 Avoid contact with skin and eyes.
S37/39 Wear suitable gloves and eye/face protection. Keep out of reach of children.
READ ALL PRECAUTIONS BEFORE USE
The (COSHH) Control of Substances Hazardous to Health Regulations 1988 may apply to the use of this product
at work. Engineering control of operator exposure must be used where reasonably practicable in addition to the
following items of personal protective equipment.
WEAR SUITABLE PROTECTIVE CLOTHING, gloves and eye/face protection.
IN CASE OF CONTACT WITH EYES rinse immediately with plenty of water and seek medical advice.
AFTER CONTACT WITH SKIN, wash immediately with plenty of clean water.
KEEP OUT OF REACH OF CHILDREN.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRITON TT WATERSTOP Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: Publication date Revision date
07/2007
1.PRODUCT NAME: TRITON TT WATERSTOP
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Bentonite 1302-78-9 65%
Isobutylene Isprene 9010-85-9 20%
Polybutylene 9003-28-5 15%
3. HAZARD IDENTIFICATION
Do not ingest.
No dangers known.
4.FIRST AID
In all cases of doubt or when symptoms persist, always seek
medical attention.
5.FIRE-FIGHTING MEASURES
EXTINGUISHING MEDIA Water, foam, CO2, dry powder to extinguish.
UNSUITABLE EXTINGUISHING MEDIA No limitation known.
EXPOSURE RISKS Keep away from fire. Do not inhale the liberated gas.
PROTECTIVE EQUIPMENT Suitable oxygen breathing equipment.
6.ACCIDENTAL RELEASE MEASURES
ENVIRONMENTAL PRECAUTIONS No precaution required.
7.HANDLING AND STORAGE
STORAGE Storage temperature limits are 5° C to 45° C.
HANDLING No protective equipment required.
FIREPROOF MEASURES No particular precaution required (See exposure risks)
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
No special protective equipment required.
Material Safety Data Sheet According to 93/11 TRITON TT WATERSTOP
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Solid Strips Colour Black
Odour Not applicable Explosion Danger Not applicable
Boiling point Not applicable Steam pressure Not applicable
Density 1.45 Ignition Temperature >250°C
Solubility in water Not applicable Solubility in Solvent Insoluble
Viscosity Not applicable
10. STABILITY AND REACTIVITY
SITUATIONS TO AVOID No dangerous situation known
MATERIALS TO AVOID No dangerous situation known.
DANGEROUS DECOMPOSITION No dangerous situation known
PRODUCTS
11.TOXICOLOGICAL INFORMATION
ACUTE TOXICITY No animal testing has been made. On the basis of the single
components values, the following value of LD50 > 200,000mg/kg is
presumed.
PRIMARY IRRITANT EFFECT A prolonged contact might cause light irritations
SENSIBILITY EFFECTS No sensibility effects known
CHRONIC TOXICITY No data available
12.ECOLOGICAL INFORMATION
DEGRADABILITY The product is hardly degradable
WATER TOXICITY Not tested
ECOLOGICAL TOXICITY Not tested
13.DISPOSAL CONSIDERATIONS
PRODUCT Return goods to the manufacturer in the original packaging or
deliver (following the area regulations) to an authorised waste
material collector.
WASTE MATERIAL CODE Solid product, Hydrophilic Rubber products.
PACKAGING Discharge following the area regulations.
TRITON TT VAPOUR MEMBRANE Material Safety Data Sheet According to 93/112EC
14. TRANSPORT INFORMATION
ROAD TRANSPORT GGVE/GGVS Not a dangerous goods in terms of national and international
transport regulations.
MARITIME TRANSPORT IMDG Not a dangerous goods in terms of national and international
transport regulations.
AIR TRANSPORT ICAO/IATA Not a dangerous goods in terms of national and international
transport regulations.
15. REGULATION INFORMATION
READ ALL PRECAUTIONS BEFORE USE
The (COSHH) Control of Substances Hazardous to Health Regulations 1988 may apply to the use of this product at
work. Engineering control of operator exposure must be used where reasonably practicable in addition to the
following items of personal protective equipment.
WEAR SUITABLE PROTECTIVE CLOTHING, gloves and eye/face protection.
IN CASE OF CONTACT WITH EYES rinse immediately with plenty of water and seek medical advice.
AFTER CONTACT WITH SKIN, wash immediately with plenty of clean water.
KEEP OUT OF REACH OF CHILDREN.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication, but we cannot
accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical data sheet for the
product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long term exposure limit.
TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper explosive limit.
TRITON TT SWELL MASTIC Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: Publication date Revision date
22/06/2007
1.PRODUCT NAME: TRITON TT SWELL MASTIC
2. COMPOSITION
CONTENTS Polyisocyanate (Prepolymers) of Diphenylmethanediisocyanate &
Methylphenylenediisocyanate, fillers and auxiliaries.
CAS No. Does not apply (polymer, without Monomer)
EG No. Does not apply (polymer, without Monomer)
3. HAZARD IDENTIFICATION
Harmful to swallow.
Irritating to eyes, respiratory organs and skin.
4.FIRST AID
GENERAL DIRECTIONS Immediately change product-stained clothes.
CONTACT WITH SKIN Remove mechanically, wash immediately with soap and water and rinse
will.
CONTACT WITH EYES Wash with eye-lid open, rinse with running water. Seek medical
attention.
INGESTION Drink plenty of water. Go in the fresh air. Seek medial attention. By no
means induce vomiting.
INHALATION Seek medical attention.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHER MEDIA: Carbon dioxide, powder or water jet. In a larger fire, use water spray or
foam.
SPECIAL PROTECTIVE EQUIPMENT Use breathing apparatus with independent air supply essential.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL ENVIRONMENT Do not allow in drainage or groundwater.
ENVIRONMENTAL PROCEDURE
FOR CLEANING AND REMOVAL Remove with liquid-absorbing materials (Kieselguhr, sawdust, oil
binder). Place in disposal bins. Do not close – Carbon Dioxide
development – Danger of bursting. Leave in a safe place for a number
of days. The product reacts with water and sets.
Material Safety Data Sheet According to 93/11 TRITON TT SWELL MASTIC
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Keep containers dry and closed tightly. Avoid heating over 60°C and
cooling under 10°C. Ensure adequate ventilation or extraction of the
work place. protect from heat. In the event of fire, cool the containers
with water.
STORAGE INFORMATION Store in a cool place. Maximum storage temperature 60°C. Do not store
with oxidising materials.
FURTHER INFORMATION Do not store more than 6 months.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
COMPONENTS WITH WORKPLACE EXPOSURE LIMITS:
CAS No.
Description of material: Diisocyanate polymers on MDI and TDI basis.
%: Approx. 22
Form: Does not apply
Value: Does not apply
Standard: Does not apply
Additional Information: Basically the slits shown.
PERSONAL PROTECTION In accordance with the specification of the Association for joint
working.
Keep away from food, drinks and animal feeds. Immediately change
clothes soiled by the product. Wash hands before meals and at the end
of work.
Protective clothing should be worn, including eye protection and PVC
or synthetic rubber gloves.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Non-flowing paste Colour: Red, brown, blue or black
Odour: Typically faint Density: approx 1.3g/ml at 20°C
Vapour Pressure: 0.001 hPa at 20°C Water Solubility: Totally Miscible
(Product emulsifies)
Flash Point: 180°C Ignition Temperature: 250° C
Explosion Limits: No danger of explosion
10. STABILITY AND REACTIVITY
STABILITY Does to apply.
CONDITIONS TO AVOID No decomposition by correct handling and storage.
DANGEROUS REACTIONS Not Known.
DANGEROUS DECOMPOSITION
PRODUCTS Upon burning Carbon Monoxide, Nitric Oxide, Isocyanate vapour and traces
of Hydrogen Cyanide.
TRITON TT SWELL MASTIC Material Safety Data Sheet According to 93/112EC
11.TOXICOLOGICAL INFORMATION
ACUTE TOXICITY None by correct use. Over-exposure, especially inhalation of aerosol
vapours. Danger dependant on concentration. Irritation of the respiratory
organs in over-sensitive people – breathing difficulties, coughing, asthma.
PRIMARY IRRITATION EFFECT
OF THE SKIN: Can irritate the skin and mucous membrane.
PRIMARY IRRITATION EFFECT
OF THE EYES: Irritation
SENSITIVITY Possible with sensitive people on contact with skin.
12.ECOLOGICAL INFORMATION
WATER HARMFULNESS: Class 1 – slightly harmful to water (own classification, WKG, Germany)
GENERAL INSTRUCTIONS: Do not discharge into ground water, drainage or rivers.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Product reacts with water and sets to a physiologically harmless Polyurea
solid. The product can therefore be rendered inert by mixing with water and
can be disposed of in sold form like domestic refuse.
DISPOSAL OF PACKAGING Dispose according to local laws. Product can be rendered harmless by filling
with water in open bins.
RECOMMENDED CLEANING
MATERIAL Remove mechanically with sand, sawdust or oil binder or spray with water.
REFUSE KEY NUMBER 55905
14. TRANSPORT INFORMATION
ADR/RID & GGVS/GGVE None
E-Class None
Numbers/letters None
Mail Delivery Not allowed (in Germany)
Express goods
15. REGULATION INFORMATION
SYMBOLS: Xn, mildly toxic, contains prepolymers from 4,4 Diphenylmethane – (MDI) and
Methylphenylene – (TDI) – Diisocyanate.
RISK PHRASES
R20 Harmful to health on inhalation
R36/37/38 Irritates eyes, respiratory organs and skin
R42 Sensitivity possible through inhalation
Material Safety Data Sheet According to 93/112EC TRITON TT SWELL MASTIC
15. REGULATION INFORMATION (cont’d)
SAFETY PHRASES
S26 In case of contact with eyes, wash well with water and seek medical advice.
S28 In case of contact with skin, wash immediately with soap and water.
S28 Without adequate ventilation, wear breathing apparatus.
S45 In the event of an accident or feeling unwell, seek medical advice. If possible, present this safety
data sheet/label.
READ ALL PRECAUTIONS BEFORE USE
The (COSHH) Control of Substances Hazardous to Health Regulations 1988 may apply to the use of this product
at work. Engineering control of operator exposure must be used where reasonably practicable in addition to the
following items of personal protective equipment.
WEAR SUITABLE PROTECTIVE CLOTHING, gloves and eye/face protection.
IN CASE OF CONTACT WITH EYES rinse immediately with plenty of water and seek medical advice.
AFTER CONTACT WITH SKIN, wash immediately with plenty of clean water.
KEEP OUT OF REACH OF CHILDREN.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRITON TT VAPOUR MEMBRANE Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: Publication date Revision date
22/06/2007
1.PRODUCT NAME: TRITON TT VAPOUR MEMBRANE
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Ordinary Portland cement 65997-15-1 Xi (Irritant) 36/37/38
Also contains graded silica sands or crushed limestone aggregates together with small quantities of other additives
3. HAZARD IDENTIFICATION
Mixing with water or contact of powder with body fluids produces a
strong alkaline solution. This may cause serious burns and
ulceration both to skin and eyes.
4.FIRST AID
CONTACT WITH SKIN Wash the affected area thoroughly with soap and water. If irritation
continues seek medical advice. Clothing contaminated with wet
product should be removed and washed thoroughly before re-use.
CONTACT WITH EYES Wash eyes immediately with plenty of clean water for at least 15
minutes and seek medical advice without delay.
INGESTION If swallowing has occurred, do not induce vomiting. Give person
plenty of water to drink. Seek medial attention.
INHALATION Move affected person to fresh air. If nose or airways become
inflamed seek medical attention.
FIRST AID FACILITIES Eye wash fountains and/or water access should be easily accessible.
5.FIRE-FIGHTING MEASURES
Cement based products are not flammable and will not facilitate combustion of other materials.
EXPOSURE HAZARDS Do not release water contaminated with cement-based products into
surface drains.
FIRE/EXPLOS. HAZARD Product will not support combustion. Polymer will burn in a general
fire, once all the water has been driven off.
HAZARDOUS DECOMPOSITION Carbon Monoxide, carbon dioxide, oxides of nitrogen, fumes and
PRODUCTS smoke.
FIRE FIGHTING PROCEDURES Wear self-contained breathing apparatus.
FIRE FIGHTING PRECAUTIONS Water spray may be used to keep fire exposed containers cool.
EXTINGUISHING MEDIA Water spray or fog, foam, carbon dioxide or dry chemical.
HAZCHEM CODE None allocated.
Material Safety Data Sheet According to 93/11 TRITON TT VAPOUR MEMBRANE
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Avoid contact with skin, eyes and clothing. Avoid breathing dust.
ENVIRONMENTAL PRECAUTIONS Prevent contamination of surface water. Avoid contaminating
waterways.
CLEAN-UP PROCEDURES Recover spillage in dry state if possible. Minimise generation of
airborne dust. The product can be slurried with water. Keep children
away from clean-up operations. Dispose to a place authorised to
accept builders’ water. Small quantities can be disposed of as normal
household waste.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS When handling bags of cement-based products most of which weigh
25kg, due regard should be paid to Manual Handling Regulations
1992. Some bags may have a small amount of cement dust on their
outer surface. Appropriate personal protection should be used whilst
handling.
STORAGE INFORMATION Bags should be stacked in a safe and stable manner. Store in dry
conditions.
STORAGE PRECAUTIONS Store in a cool area to prolong storage life, best stored at room
temperature. Prevent from freezing.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
EXPOSURE LIMITS:
NAME STEL TWA
mg/m³ ppm mg/m³ ppm
Anionic bitumen 0.5
OTHER EXPOSURE INFO. Exposure standards not established for product, or other ingredients
ENGINEERING CONTROLS General ventilation is recommended during normal use. Local
ventilation may be required during certain operations to prevent
inhalation of vapours.
TECHNICAL PROTECTIVE MEASURES No special measures required.
EXPOSURE LIMITS Occupational exposure standard (8h TWA):
10mg/m³ total inhalable dust, 5mg/m³ respirable dust
All Triton cement based products contain powders, which if handled carelessly can raise dust.
The personal exposure to such dusts (cement, silica sand, crushed limestone etc.) must be kept below 10mg/m³ 8-hour
TWA total inhalable dust and 5mg/m³respirable dust. Some of the cement based products contain microsilica form of
silica. The personal exposure level to amorphous silica must be kept below 6mg/m³ 8 hour TWA total inhalable dust
and 3mg/m³ respirable dust.
Some sands and other fillers may contain small quantities of respirable silica for which the personal exposure must be
kept below 0.4mg/m³ 8 hour TWA.
If care is taken not to raise dust and the exposure levels for nuisance dusts are not exceeded, the levels for respirable
silica should be very low.
Applying Occupational Exposure Standards EH40/95 Sections 40 and 4.1. Also see Dust: General Principles of
Protection HSE Guidance Note EH44 Rev 1991.
• Occupational Exposure Standards Limits – 8 hour TWA, reference period from Guidance Note EH40/95, Table 2. Cont’d
TRITON TT VAPOUR MEMBRANE Material Safety Data Sheet According to 93/112EC
8.EXPOSURE CONTROLS/PERSONAL PROTECTION (Cont’d)
AMORPHOUSE SILICA: Total inhalable dust: 6mg/m³
Respirable dust: 3mg/m³
PORTLAND CEMENT: Total inhalable dust: 10mg/m³
Respirable dust: 5mg/m³
Respirator Type (AS1716) where concentrations in air may exceed the
recommended exposure limits, or work practice or other means of
exposure reduction are not adequate, approved respirator may be
necessary to prevent overexposure by inhalation.
Wear suitable Neoprene/rubber gloves.
Safety glasses as appropriate.
Wear overalls and closed footwear.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Dark brown/black thixotropic Oxidising properties None
Liquid/paste
Boiling point >100ºC approx. (water) Vapour pressure As for water
Specific Gravity 1.2kg/lt Flash Point Not Applicable
Flamm. Limit LEL Not Applicable Solubility in water Dilutable
Physical State Particulate Particle Size 5 – 6000 pm
pH of wet content 12 – 14
10. STABILITY AND REACTIVITY
Stable under normal room temperature storage conditions
Bags will set solid if continually soaked with water.
11.TOXICOLOGICAL INFORMATION
EYE CONTACT Acute – May be an eye irritant.
SKIN CONTACT Acute – Prolonged or repeated contact with skin may result in slight
skin irritation.
INHALATION Acute – Excessive exposure to vapours or spray mist may cause slight
irritation to eyes, nose and throat.
INGESTION Acute – No data supplied, but polymer is not expected to be harmful.
CHRONIC No data supplied, but polymer is not expected to be harmful.
12.ECOLOGICAL INFORMATION
AQUATIC TOXICITY RATING LC50 aquatic toxicity rating has not been determined. The addition of
any cement based product to water may, however, cause the pH to rise
and therefore may be toxic to aquatic life in some circumstances. No
other specific information available.
Material Safety Data Sheet According to 93/112EC TRITON TT VAPOUR MEMBRANE
13.DISPOSAL CONSIDERATIONS
SPILLS & DISPOSAL Do not contaminate streams, rivers, or watercourses. Do not flush down
drains and sewers. Inform local authority if liquid enters drains, sewers,
streams, etc. Dike and contain spill with sand or earth. Clean up before
the material dries. Absorb the liquid with sand, earth or other absorbent.
Place used absorbent in suitable, sealable labelled containers.
DISPOSAL Dispose of in accordance with Local, State and Federal regulations.
Dispose of empty backs or surplus product to a place authorised to
accept builders’ waste. Keep out of reach of children. Small numbers of
bags can be disposed of as normal household wastes.
14. TRANSPORT INFORMATION
Classification for transport not required.
15. REGULATION INFORMATION
SYMBOLS: Xi Irritant
RISK PHRASES
R36/37/38: Irritating to eyes, respiratory systems and skin.
SAFETY PHRASES
S22 Do not breathe dust.
S28 After contact with skin, wash immediately with plenty of soap and water.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical attention.
S24/25 Avoid contact with skin and eyes.
S37/39 Wear suitable gloves and eye/face protection. Keep out of reach of children.
READ ALL PRECAUTIONS BEFORE USE
The (COSHH) Control of Substances Hazardous to Health Regulations 1988 may apply to the use of this product at
work. Engineering control of operator exposure must be used where reasonably practicable in addition to the
following items of personal protective equipment.
WEAR SUITABLE PROTECTIVE CLOTHING, gloves and eye/face protection.
IN CASE OF CONTACT WITH EYES rinse immediately with plenty of water and seek medical advice.
AFTER CONTACT WITH SKIN, wash immediately with plenty of clean water.
KEEP OUT OF REACH OF CHILDREN.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication, but we cannot
accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical data sheet for the
product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long term exposure limit.
TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper explosive limit.
SECTION 5 :
STRUCTURAL REPAIR.
- TRIMOL 15
- TRIMOL 23
- TRIGROUT EXTRA
- TRIFIX ADHESIVE
TRIMOL RESINS (15, 34, 35, 36, 40, 41) Material Safety Data Sheet According to 93/112EC
Triton Chemical Manufacturing Co. Ltd.
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
300 4/4/97
1.PRODUCT NAME: TRIMOL RESINS 15, 34, 35, 36, 40, 41
2. COMPOSITION
Hazardous ingredient CAS Nos. Weight, % Symbols Risk Phrases
Bisphenol A and F epoxy 25068-38-6, 68609-97-2, 100 Xi (Irritant) R36/38,43,51/53
Resins, diglycidyl ethers 28064-14-4
3.HAZARD IDENTIFICATION
Irritant
Irritating to skin and eyes
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water.
CONTACT WITH EYES Wash out with water for several minutes and seek medical advice.
INGESTION Seek medical advice in the event of discomfort.
INHALATION Remove to fresh air if fumes cause irritation of nose or throat.
OTHER INFORMATION May aggravate existing respiratory problems.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA Dry powder or foam. For small fires use CO² . Never use water
jet.
SPECIAL PROTECTIVE EQUIPMENT For fires in confined spaces, use breathing apparatus.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount
involved, which may include eye/face protection, PVC or
synthetic rubber gloves, protective footwear and overalls.
(Contd.).
Material Safety Data Sheet According to 93/112EC TRIMOL RESINS (15,34,35,36,40,41)
6.ACCIDENTAL RELEASE MEASURES (contd.)
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbents and shovel
into a suitable closed container for disposal according to item
13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Observe good hygiene standards and minimise skin contact.
Wear suitable protective clothing according to item 8.
STORAGE INFORMATION Keep containers tightly closed in a cool place, out of direct
sunlight. Keep stored well ventilated.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Where prolonged or repeated exposure is likely, protective clothing should be
worn, including eye protection, boots and PVC or synthetic rubber gloves.
Wash hands and exposed skin before meals and after work. Do not eat, drink
or smoke whilst handling the product.
Do not wear contaminated clothing. Ventilate confined spaces thoroughly.
EXPOSURE LIMITS None prescribed in EH40.
Slight irritant, not considered hazardous.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear, golden liquid Oxidising properties None
Odour Faint Vapour pressure 1Pa (20°C)
pH 7 (50% suspension in water) Relative density 1.2-1.13 (15°C)
Boiling point Decomposes Bulk density Not Relevant
Melting point Not Relevant Viscosity No data
Flash point >150°C Solubility Insoluble in water
Autoignition temperature No data Partition coefficient No data
Explosive properties No data Other data
TRIMOL RESINS (15, 34, 35, 36, 40,41) Material Safety Data Sheet According to 93/112EC
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID High temperatures (degrades resin).
MATERIALS TO AVOID Strong oxidising agents, acids and bases.
Excess of hardener (uncontrolled polymerisation reaction).
11.TOXICOLOGICAL INFORMATION
Not available data on acute toxicity. Irritating to eyes. A mild skin irritant and mild sensitising agent.
12.ECOLOGICAL INFORMATION
MOBILITY Low soil absorption.
DEGRADABILITY Not easily biodegradable
ACCUMULATION There is potential for bioaccumulation. Biomagnification is unlikely.
ECTOTOXICITY Toxic to aquatic organisms:
(TLm96: fish 1.2mg/litre, Daphnia 2.7 mg/litre, algae 9.4mg/litre)
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT: Chemical residues are normally regarded as Special Waste. Dispose of
in accordance with local and national regulations (incinerate or
landfill).
DISPOSAL OF PACKAGING: Uncleaned packaging should be treated as for the product.
14. TRANSPORT INFORMATION
UN No. None assigned
PROPER SHIPPING NAME Liquid epoxy resin
ADR/RID Not classified as hazardous
IMCO Not classified as hazardous
MFAG Table No.
EmS No.
IATA/IACO Not classified as hazardous
PACKING GROUP
LABEL No hazard label
Material Safety Data Sheet According to 93/112EC TRIMOL RESINS (15, 34, 35, 36, 40, 41)
15.REGULATORY INFORMATION
CLASSIFICATION Irritant
LABEL INFORMATION
S24: Irritating to eyes and skin.
S26: May cause sensitisation by skin contact.
S28: After contact with skin, wash immediately with plenty of water.
S37/39: Wear suitable gloves and eye/face protection.
Refer to other relevant legislation such as Health and Safety at Work etc Act (HSWA), the Control of
Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of
Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of
workplace risk as required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of
publication, but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the
technical data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIMOL 15 FILLER Material Safety Data Sheet According to 93/112EC
Triton Chemical Manufacturing Co. Ltd.
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
Non-hazardous 307 15/4/97
1.PRODUCT NAME: TRIMOL 15 FILLER
2. COMPOSITION
An inert, light-weight inorganic filler consisting of aluminosilicate glass of particle size between 5 and 300
micrometres.
3.HAZARD IDENTIFICATION
There are no particular hazards associated with this product in normal
use.
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of water or soap and water.
CONTACT WITH EYES Wash out with water for several minutes. Seek medical advice.
INGESTION Not likely to cause any adverse effects in the amounts which could be
taken.
INHALATION Remove to fresh air.
OTHER INFORMATION
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA As appropriate to surrounding fire
SPECIAL PROTECTIVE EQUIPMENT No particular requirements
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear respiratory protection if large amounts of dust are generated.
ENVIRONMENTAL PRECAUTIONS No environment hazard.
CLEAN-UP PROCEDURES Sweep up and place in container for re-use or disposal to landfill.
Material Safety Data Sheet According to 93/112EC TRIMOL 15 FILLER
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Observe normal industrial hygiene methods.
STORAGE INFORMATION Store in a cool, dry place.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
The quantity of the Filler in the trimol 15 pack is not likely to present a risk in handling, but eye
protection and respiratory protection may be used if the filler is handled frequently or in large amounts.
EXPOSURE LIMITS OES: 10mg/m³ total respirable dust (EH40)
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Light grey or buff powder Oxidising properties None
Odour None Vapour pressure Not relevant
pH Not relevant Relative density No data
Boiling point Not relevant Bulk density 350kg/m³
Melting point 1350°C Viscosity Not relevant
Flash point Not combustible Solubility Insoluble in water
Autoignition temperature Not relevant Partition coefficient Not relevant
Explosive properties Not explosive Other data
10.STABILITY/REACTIVITY
STABILITY Stable
CONDITIONS TO AVOID No special requirements
MATERIALS TO AVOID None
11.TOXICOLOGICAL INFORMATION
Not toxic
TRIMOL 15 FILLER Material Safety Data Sheet According to 93/112EC
12.ECOLOGICAL INFORMATION
MOBILITY Not mobile in the soil.
DEGRADABILITY Inert, not biodegradable
ACCUMULATION There is no likelihood of bioaccumulation or biomagnification.
ECTOTOXICITY Not ecotoxic
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT: Dispose of by landfill in a commercial site, in accordance with local
and national regulations.
DISPOSAL OF PACKAGING: As for product.
14. TRANSPORT INFORMATION
Not regulated for transport by road, rail, sea or air.
15.REGULATORY INFORMATION
CLASSIFICATION Not classified as hazardous.
LABEL INFORMATION None
Refer to other relevant legislation such as Health and Safety at Work etc Act (HSWA), the Control of
Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of
Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of
workplace risk as required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of
publication, but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the
technical data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIMOL HARDENER (15, 34, 35, 36) Material Safety Data Sheet According to 93/112EC
Triton Chemical Manufacturing Co. Ltd.
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
301 4/4/97 18/06/04
1.PRODUCT NAME: TRIMOL HARDENER 15, 34, 35, 36
2. COMPOSITION
Hazardous ingredient CAS Nos. EC No. Weight, % Symbols Risk Phrases
Trimethylhexamethylene diamine 25620-58-0 247-134-8 100 C (Corrosive) R22,34,43,52/53
3.HAZARD IDENTIFICATION
Corrosive – Causes burns
Harmful if swallowed
May cause sensitisation by skin contact
Harmful to aquatic organisms, may cause long-term adverse effects in
the aquatic environment.
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water. If irritation persists, obtain
medical advice.
CONTACT WITH EYES Wash out with water for several minutes and seek medical advice.
INGESTION Give plenty of water – if possible, charcoal slurry. Do not induce
vomiting.
INHALATION Remove to fresh air. If symptoms persist, seek medial advice.
OTHER INFORMATION Treat symptomatically.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA Dry powder or foam. For small fires use CO ² . Never use water
jet.
SPECIAL PROTECTIVE EQUIPMENT Full protective equipment. Toxic and irritant fumes may be
produced.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing which may include eye/face
protection, PVC or synthetic rubber gloves, protective footwear
and overalls. Avoid contact with skin, eyes and clothing.
Material Safety Data Sheet According to 93/112EC TRIMOL HARDENER (15, 34, 35, 36)
6.ACCIDENTAL RELEASE MEASURES (contd.)
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbents and shovel
into a suitable closed container for disposal according to item
13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Ensure adequate ventilation in work areas. Keep away from
sources of ignition – no smoking. Handle and open container
with care
STORAGE INFORMATION Keep containers tightly closed in a cool place, out of direct
sunlight. Keep store well ventilated. Keep away from food and
feeding stuffs.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear protective clothing, including eye protection, boots and PVC or
synthetic rubber gloves. In case of insufficient ventilation, wear suitable
respiratory protective equipment.
Wash hands and exposed skin before meals and after work. Do not eat, drink
or smoke whilst handling the product.
EXPOSURE LIMITS None prescribed in EH40.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Clear, colourless liquid Oxidising properties None
Odour Amine-like Vapour pressure 6Pa (20°C)
pH 11.3 (50% in water) Relative density 0.86-0.87 (20°C)
Boiling point >200°C Bulk density Not Relevant
Melting point Not Relevant Viscosity 5mPa.s (25°)
Flash point >108°C (CC) Solubility Miscible with water
Autoignition temperature No data Partition coefficient No data
Explosive properties No data Other data
TRIMOL HARDENER (15, 34, 35, 36) Material Safety Data Sheet According to 93/112EC
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID High temperatures, formation of aerosols, static discharges.
MATERIALS TO AVOID Strong oxidising agents, acids and bases.
11.TOXICOLOGICAL INFORMATION
LD50 (rat, oral): 910mg/kg. Eye irritation (rabbit): corrosive. Skin irritation (rabbit): corrosive.
Dermal sensitisation (guinea pig): sensitiser.
12.ECOLOGICAL INFORMATION
MOBILITY Avoid subsoil penetration
DEGRADABILITY Not easily biodegradable
ACCUMULATION There is potential for bioaccumulation. Biomagnification is unlikely.
ECTOTOXICITY Toxic to aquatic organisms.
(LC 50 (fish) 96h:1000mg/litre, EC50 (daphnia) 24h: 31.5mg/litre
EC50 (algae) 72h: 29.5mg/litre), IC50 (bacteria) 3h: 100mg/litre.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT: Chemical residues are normally regarded as Special Waste. Incinerate
in compliance with the Environmental Protection Act 1990 (Process
Guidance Note IPR5/1)
DISPOSAL OF PACKAGING: Uncleaned packaging should be treated as for the product. After
cleaning, can be landfilled.
14. TRANSPORT INFORMATION
UN No. 2327
PROPER SHIPPING NAME Trimethylhexamethhylene diamines, solution
ADR/RID Class 8. Item 53(c).
IMCO Class 8. IMDG Code page 08243
MFAG Table No. 320
EmS No. 8.05
IATA/IACO Class 8
PACKING GROUP 3
LABEL Corrosive
Material Safety Data Sheet According to 93/112EC TRIMOL HARDENER (15, 34, 35, 36)
15.REGULATORY INFORMATION
CLASSIFICATION Corrosive
LABEL INFORMATION
R34:Causes burns
R22: Harmful if swallowed.
R43: May cause sensitisation by skin contact.
R52/53: Harmful to aquatic organisms, may cause long-term adverse affects in the aquatic environment.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S45: In case of accident or if you feel unwell, seek medical advice (show the label where possible).
Refer to other relevant legislation such as Health and Safety at Work etc Act (HSWA), the Control of
Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of
Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of
workplace risk as required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of
publication, but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the
technical data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIMOL 23 RESIN Material Safety Data Sheet According to 93/112EC
Triton Chemical Manufacturing Co. Ltd.
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
303 11/4/97
1.PRODUCT NAME: TRIMOL 23 RESIN
2. COMPOSITION
Hazardous ingredient CAS Nos. Weight, % Symbols Risk Phrases
Bisphenol A and F epoxy 25068-38-6, 68609-97-2 49 Xi (Irritant) R36/38,43, 51/53
Resins, diglycidyl ethers 28064-14-4
3.HAZARD IDENTIFICATION
Irritant
Irritating to skin and eyes
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water.
CONTACT WITH EYES Wash out with water for several minutes and seek medical advice.
INGESTION Seek medical advice in the event of discomfort.
INHALATION Remove to fresh air if fumes cause irritation of nose or throat.
OTHER INFORMATION May aggravate existing respiratory problems.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA Dry powder or foam. For small fires use CO² . Never use water
jet.
SPECIAL PROTECTIVE EQUIPMENT For fires in confined spaces, use breathing apparatus.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount
involved, which may include eye/face protection, PVC or
synthetic rubber gloves, protective footwear and overalls.
(Contd.).
Material Safety Data Sheet According to 93/112EC TRIMOL 23 RESIN
6.ACCIDENTAL RELEASE MEASURES (contd.)
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbents and shovel
into a suitable closed container for disposal according to item
13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Observe good hygiene standards and minimise skin contact.
Wear suitable protective clothing according to item 8.
STORAGE INFORMATION Keep containers tightly closed in a cool place, out of direct
sunlight. Keep stored well ventilated.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Where prolonged or repeated exposure is likely, protective clothing should be
worn, including eye protection, boots and PVC or synthetic rubber gloves.
Wash hands and exposed skin before meals and after work. Do not eat, drink
or smoke whilst handling the product.
Do not wear contaminated clothing. Ventilate confined spaces thoroughly.
EXPOSURE LIMITS None prescribed in EH40.
Slight irritant, not considered hazardous.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Black Paste Oxidising properties None
Odour Faint Vapour pressure 1Pa (20°C)
pH 7 (50% suspension in water) Relative density 1.6 (15°C)
Boiling point Decomposes Bulk density Not Relevant
Melting point Not Relevant Viscosity Thixotropic
Flash point >150°C Solubility Insoluble in water
Autoignition temperature No data Partition coefficient No data
Explosive properties No data Other data
TRIMOL 23 RESIN Material Safety Data Sheet According to 93/112EC
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID High temperatures (degrades resin).
MATERIALS TO AVOID Strong oxidising agents, acids and bases.
Excess of hardener (uncontrolled polymerisation reaction).
11.TOXICOLOGICAL INFORMATION
Not available data on acute toxicity. Irritating to eyes. A mild skin irritant and mild sensitising agent.
12.ECOLOGICAL INFORMATION
MOBILITY Low soil absorption.
DEGRADABILITY Not easily biodegradable
ACCUMULATION There is potential for bioaccumulation. Biomagnification is unlikely.
ECTOTOXICITY Toxic to aquatic organisms (data for 100% resin):
(TLm96: fish 1.2mg/litre, Daphnia 2.7 mg/litre, algae 9.4mg/litre)
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT: Chemical residues are normally regarded as Special Waste. Dispose of
in accordance with local and national regulations (incinerate or
landfill).
DISPOSAL OF PACKAGING: Uncleaned packaging should be treated as for the product.
14. TRANSPORT INFORMATION
UN No. None assigned
PROPER SHIPPING NAME Liquid epoxy resin
ADR/RID Not classified as hazardous
IMCO Not classified as hazardous
MFAG Table No.
EmS No.
IATA/IACO Not classified as hazardous
PACKING GROUP
LABEL No hazard label
Material Safety Data Sheet According to 93/112EC TRIMOL 23 RESIN
15.REGULATORY INFORMATION
CLASSIFICATION Irritant
LABEL INFORMATION
S24: Irritating to eyes and skin.
S26: May cause sensitisation by skin contact.
S28: After contact with skin, wash immediately with plenty of water.
S37/39: Wear suitable gloves and eye/face protection.
Refer to other relevant legislation such as Health and Safety at Work etc Act (HSWA), the Control of
Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of
Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of
workplace risk as required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of
publication, but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the
technical data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIMOL 23 HARDENER Material Safety Data Sheet According to 93/112EC
Triton Chemical Manufacturing Co. Ltd.
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
302 4/4/97
1.PRODUCT NAME: TRIMOL 23 HARDENER
2. COMPOSITION
Hazardous ingredient CAS Nos. EC No. Weight, % Symbols Risk Phrases
Trimethylhexamethylene diamine 25620-58-0 247-134-8 12 C (Corrosive) R22,34,43,52/53
3.HAZARD IDENTIFICATION
Corrosive – Causes burns
Harmful if swallowed
May cause sensitisation by skin contact
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water. If irritation persists, obtain
medical advice.
CONTACT WITH EYES Wash out with water for several minutes and seek medical advice.
INGESTION Give plenty of water – if possible, charcoal slurry. Do not induce
vomiting.
INHALATION Remove to fresh air. If symptoms persist, seek medial advice.
OTHER INFORMATION Treat symptomatically.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA Dry powder or foam. For small fires use CO ² . Never use water
jet.
SPECIAL PROTECTIVE EQUIPMENT Full protective equipment. Toxic and irritant fumes may be
produced.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount
involved, which may include eye/face protection, PVC or
synthetic rubber gloves, protective footwear and overalls.
Material Safety Data Sheet According to 93/112EC TRIMOL 23 HARDENER
6.ACCIDENTAL RELEASE MEASURES (contd.)
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbents and shovel
into a suitable closed container for disposal according to item
13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Ensure adequate ventilation in work areas. Keep away from
sources of ignition – no smoking. Handle and open container
with care
STORAGE INFORMATION Keep containers tightly closed in a cool place, out of direct
sunlight. Keep store well ventilated. Keep away from food and
feeding stuffs.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear protective clothing, including eye protection, boots and PVC or
synthetic rubber gloves. In case of insufficient ventilation, wear suitable
respiratory protective equipment.
Wash hands and exposed skin before meals and after work. Do not eat, drink
or smoke whilst handling the product.
EXPOSURE LIMITS None prescribed in EH40.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance White Paste Oxidising properties None
Odour Amine-like Vapour pressure 6Pa (20°C)
pH 11.3 (50% in water) Relative density 1.4 (20°C)
Boiling point Decomposes above 200°C Bulk density Not Relevant
Melting point Not Relevant Viscosity Thixotropic
Flash point >108°C (CC) Solubility Partially miscible with water
Autoignition temperature No data Partition coefficient No data
Explosive properties No data Other data
TRIMOL 23 HARDENER Material Safety Data Sheet According to 93/112EC
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID High temperatures, formation of aerosols, static discharges.
MATERIALS TO AVOID Strong oxidising agents, acids and bases.
11.TOXICOLOGICAL INFORMATION
LD50 (rat, oral): 7600mg/kg (by calculation). Eye irritation (rabbit): corrosive. Skin irritation (rabbit): corrosive.
Dermal sensitisation (guinea pig): sensitiser.
12.ECOLOGICAL INFORMATION
MOBILITY Avoid subsoil penetration
DEGRADABILITY Not easily biodegradable
ACCUMULATION There is potential for bioaccumulation. Biomagnification is unlikely.
ECTOTOXICITY Toxic to aquatic organisms. Data for 100% amine:
(LC 50 (fish) 96h:1000mg/litre, EC50 (daphnia) 24h: 31.5mg/litre
EC50 (algae) 72h: 29.5mg/litre), IC50 (bacteria) 3h: 100mg/litre.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT: Chemical residues are normally regarded as Special Waste. Incinerate
in compliance with the Environmental Protection Act 1990 (Process
Guidance Note IPR5/1)
DISPOSAL OF PACKAGING: Uncleaned packaging should be treated as for the product. After
cleaning, can be landfilled.
14. TRANSPORT INFORMATION
UN No. 2327
PROPER SHIPPING NAME Trimethylhexamethhylene diamines, solution
ADR/RID Class 8. Item 53(c).
IMCO Class 8. IMDG Code page 08243
MFAG Table No. 320
EmS No. 8.05
IATA/IACO Class 8
PACKING GROUP 3
LABEL Corrosive
Material Safety Data Sheet According to 93/112EC TRIMOL 23 HARDENER
15.REGULATORY INFORMATION
CLASSIFICATION Corrosive
LABEL INFORMATION
R34:Causes burns
R22: Harmful if swallowed.
R43: May cause sensitisation by skin contact.
R52/53: Harmful to aquatic organisms, may cause long-term adverse affects in the aquatic environment.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
S45: In case of accident or if you feel unwell, seek medical advice (show the label where possible).
Refer to other relevant legislation such as Health and Safety at Work etc Act (HSWA), the Control of
Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of
Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of
workplace risk as required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of
publication, but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the
technical data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRITON TRI-GROUT EXTRA Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: TR Publication date Revision date
316 06/11/2002
1.PRODUCT NAME: TRITON TRI-GROUT EXTRA
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Ordinary Portland cement 65997-15-1 <50 Xi (Irritant) See section 15
Also contains silica flour, silica sand and other additives
3. HAZARD IDENTIFICATION
Irritant
Irritating to skin and eyes
4.FIRST AID
CONTACT WITH SKIN Wash off with plenty of soap and water. Remove contaminated
clothing.
CONTACT WITH EYES Wash out with water for at least 15 minutes and seek medical advice
without delay.
INGESTION Wash out mouth with water and give plenty of water to drink.
DO NOT INDUCE VOMITING.
INHALATION Remove to fresh air. If nose or airways become inflamed, seek medical
advice.
OTHER INFORMATION Until the mixture has set, may cause both irritant and allergic contact
dermatitis.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA As appropriate to surrounding fire
SPECIAL PROTECTIVE EQUIPMENT No particular requirement
Material Safety Data Sheet According to 93/112EC TRITON TRI-GROUT EXTRA
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount
involved which may include eye/face protection, PVC or synthetic
rubber gloves, protective footwear and overalls, particularly
during mixing operations.
ENVIRONMENTAL PRECAUTIONS Contain the spillage and keep children away from the area.
CLEAN-UP PROCEDURES Recover the spilt material in a dry state if possible.
Minimise generation of airborne dust.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Observe good hygiene standards and minimise skin contact.
Wear suitable protective clothing according to item 8.
STORAGE INFORMATION Keep containers tightly closed in a cool place.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
When handling or mixing the product, protective clothing should be worn, including
eye protection and PVC or synthetic rubber gloves.
Wash hands and exposed skin before meals and after work.
Do not wear contaminated clothing.
EXPOSURE LIMITS Occupational exposure standard (8h TWA):
10mg/m³ total inhalable dust, 5mg/m³ respirable dust
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Grey powder Oxidising properties None
Odour None Vapour pressure Not relevant
pH 11, when wet. Relative density Not relevant
Boiling point Not relevant Bulk density 1300 kg/m³
Melting point Not relevant Viscosity Not relevant
Flash point None Solubility Very slightly soluble in water
Autoignition temperature Not combustible Partition coefficient Not relevant
Explosive properties None Other data
TRITON TRI-GROUT EXTRA Material Safety Data Sheet According to 93/112EC
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID Damp (degrades product).
MATERIALS TO AVOID No particular requirements.
11.TOXICOLOGICAL INFORMATION
Severe eye irritant. Irritating to skin – the powder or its mixture with water may cause irritant dermatitis or
burns, and traces of hexavalent chromium in the product may cause allergic dermatitis. Ingestion of small
amounts is unlikely to cause any significant reaction, but large doses may result in irritation to the gastro
intestinal tract.
12.ECOLOGICAL INFORMATION
MOBILITY Not mobile in soil.
DEGRADABILITY Relatively inert.
ACCUMULATION No potential for bioaccumlation or biomagnification.
ECOTOXICITY Addition of cement-based products to water may cause the pH to rise,
and they may therefore be toxic to aquatic life in some circumstances.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Dispose of in accordance with local and national regulations (normally
landfill), or to any place authorised to accept builders waste.
DISPOSAL OF PACKAGING Packaging should be treated as for the product, or may be incinerated.
14. TRANSPORT INFORMATION
UN NO. None assigned
PROPER SHIPPING NAME Portland cement mixture
ADR/RID Not classified as hazardous
IMCO Not classified as hazardous
ICAO/IATA Not classified as hazardous
PACKING GROUP
LABEL No hazard label
Material Safety Data Sheet According to 93/112EC TRITON TRI-GROUT EXTRA
15. REGULATION INFORMATION
CLASSIFICATION Irritant
LABEL INFORMATION:
CONTACT WITH WET MORTAR MAY CAUSE IRRITATION, DERMATITIS OR BURNS.
CONTACT BETWEEN THE POWDER AND BODY FLUIDS (eg Sweat or Eye Fluid) MAY ALSO CAUSE
IRRITATION, DERMATITIS OR BURNS.
RISK OF SERIOUS DAMAGE TO EYES.
READ ALL PRECAUTIONS BEFORE USE
The (COSHH) Control of Substances Hazardous to Health Regulations 1988 may apply to the use of this product
at work. Engineering control of operator exposure must be used where reasonably practicable in addition to the
following items of personal protective equipment.
WEAR SUITABLE PROTECTIVE CLOTHING, gloves and eye/face protection.
IN CASE OF CONTACT WITH EYES rinse immediately with plenty of water and seek medical advice.
AFTER CONTACT WITH SKIN, wash immediately with plenty of clean water.
KEEP OUT OF REACH OF CHILDREN.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE Control of Substances
Hazardous to Health Regulations (COSHH), the Environment Protection Act and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIFIX ADHESIVE – RESIN Material Safety Data Sheet According to 93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: Publication date Revision date
TR305 14/04/97
1.PRODUCT NAME: TRIFIX ADHESIVE - RESIN
2. COMPOSITION
Hazardous ingredient CAS No. Weight % Symbols Risk Phrases
Bisphenol A and F epoxy 25068-38-6, 68609-97-2 56 Xi (Irritant) S24,S26,S28,S37/39
Resins, diglycidyl 28064-14-4
3. HAZARD IDENTIFICATION
Irritant
Irritating to skin and eyes.
4. FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water.
CONTACT WITH EYES Wash out with water for several minutes and seek medical advice.
INGESTION Seek medical advice in the event of discomfort.
INHALATION Remove to fresh air if fumes cause irritation of nose or throat.
OTHER INFORMATION May aggravate existing respiratory problems.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA Dry powder or foam. For small fires use CO . Never use water jet.
²
SPECIAL PROTECTIVE EQUIPMENT For fires in confined spaces, use breathing apparatus.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount
involved, which may include eye/face protection, PVC or
synthetic rubber gloves, protective footwear, overalls.
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
(Contd.)
Material Safety Data Sheet According to 93/112EC TRIFIX ADHESIVE - RESIN
6.ACCIDENTAL RELEASE MEASURES (contd.)
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbent and shovel into
a suitable closed container for disposal according to item 13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Observe good hygiene standards and minimise skin contact.
Wear suitable protective clothing according to item 8.
Avoid open flames and sources of ignition.
STORAGE INFORMATION Keep containers tightly closed in a cool place, out of direct
sunlight. Keep stored well ventilated.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Where prolonged or repeated exposure is likely, protective clothing should be worn,
including eye protection and PVC or synthetic rubber gloves.
Wash hands and exposed skin before meals and after work. Do not eat, drink or smoke
whilst handling the product.
Do not wear contaminated clothing. Ventilate confined spaces thoroughly.
EXPOSURE LIMITS None prescribed in EH40
Slight irritant, not considered hazardous.
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Beige, thixotropic liquid Oxidising properties None
Odour Faint Vapour pressure 1Pa (20°C)
pH 7 (50% suspension in water) Relative density 1.7 (25ºC)
Boiling point Decomposes Bulk density Not relevant
Melting point Not Relevant Viscosity No data
Flash point >150C Solubility Insoluble in water
Autoignition temperature No data Partition coefficient No data
Explosive properties No data Other data
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID High temperatures (degrades resin).
MATERIALS TO AVOID Strong oxidising agents, strong acids and bases.
Excess of hardener (uncontrolled polymerisation reaction)
TRIFIX ADHESIVE – RESIN Material Safety Data Sheet According to 93/112EC
11.TOXICOLOGICAL INFORMATION
No available data on acute toxicity. Irritating to eyes. A mild skin irritant and mild sensitising agent.
12.ECOLOGICAL INFORMATION
MOBILITY Low soil absorption
DEGRADABILITY Not easily biodegradable.
ACCUMULATION There is potential for bioaccumlation. Biomagnification is unlikely.
ECOTOXICITY Toxic to aquatic organisms.
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Chemical residues are normally regarded as Special Waste. Dispose of
in accordance with local and national regulations (incinerate or
landfill).
DISPOSAL OF PACKAGING Uncleaned packaging should be treated as for the product.
14. TRANSPORT INFORMATION
UN NO. None assigned
PROPER SHIPPING NAME Liquid epoxy resin
ADR/RID Not classified as hazardous
IMCO Not classified as hazardous
MFAG Table No.
EmS No.
IATA/IACO Not classified as hazardous
PACKING GROUP
LABEL No hazard label
15. REGULATORY INFORMATION
CLASSIFICATION Irritant
LABEL INFORMATION
S24: Irritating to eyes and skin.
S26: May cause sensitisation by skin contact.
S28: After contact with skin, wash immediately with plenty of water.
S37/39: Wear suitable gloves and eye/face protection.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE
Control of Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act
and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of workplace risk as
Required by health and safety legislation.
Material Safety Data Sheet According to 93/112EC TRIFIX ADHESIVE - RESIN
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
TRIFIX ADHESIVE - HARDENER Material Safety Data Sheet According to93/112EC
Triton Chemical Manufacturing Co. Ltd
129 Felixstowe Road, Abbeywood, London SE2 9SG
Telephone: 020 8310 3929
Fax: 020 8312 0349
MSDS Ref: Publication date Revision date
TR306 14/04/97
1.PRODUCT NAME: TRIFIX ADHESIVE - HARDENER
2. COMPOSITION
Hazardous ingredient CAS No. EC No. Weight % Symbols Risk Phrases
Diethylene triamine 111-40-0 203-865-4 7.3 C (Corrosive) R21/22,34,43
Triphenyl phosphite 101-02-0 202-908-4 10.3 Xi (Irritant) R36/38
Alkylated polyamine adduct 30.6 C (Corrosive) R21/22,34,43
3. HAZARD IDENTIFICATION
Corrosive – Causes burns.
Harmful if swallowed.
May cause sensitisation by skin contact.
4.FIRST AID
CONTACT WITH SKIN Wash with plenty of soap and water. If irritation persists, obtain
medical advice.
CONTACT WITH EYES Wash out with water for several minutes and seek medical advice.
INGESTION Give plenty of water – if possible, charcoal slurry. Do not induce
vomiting.
INHALATION Remove to fresh air. If symptoms persist, seek medical advice.
OTHER INFORMATION Treat symptomatically.
5.FIRE-FIGHTING MEASURES
SUITABLE EXTINGUISHING MEDIA Dry powder, fog or foam. For small fires use CO² . DO NOT
use halones.
SPECIAL PROTECTIVE EQUIPMENT Full protective equipment. Toxic and irritant fumes may be
produced.
6.ACCIDENTAL RELEASE MEASURES
PERSONAL PRECAUTIONS Wear suitable protective clothing appropriate to the amount involved,
which may include eye/face protection, PVC or synthetic rubber
gloves, protective footwear, overalls
Material Safety Data Sheet According to 93/112EC TRIFIX ADHESIVE - HARDENER
6.ACCIDENTAL RELEASE MEASURES (contd.)
ENVIRONMENTAL PRECAUTIONS Do not allow to enter public sewers and watercourses.
If this cannot be avoided, inform the appropriate authority.
CLEAN-UP PROCEDURES Absorb in dry sand or earth or similar absorbent and shovel into a
suitable closed container for disposal according to item 13.
7.HANDLING AND STORAGE
HANDLING PRECAUTIONS Ensure adequate ventilation in work areas. Keep away from
sources of ignition – no smoking. Do not break open the
dispenser cartridge.
STORAGE INFORMATION Keep containers tightly closed in a cool place, out of direct
sunlight. Keep stored well ventilated. Keep away from food
and feeding stuffs.
8.EXPOSURE CONTROLS/PERSONAL PROTECTION
Wear protective clothing, including eye protection and PVC or synthetic/rubber gloves.
Wash hands and exposed skin before meals and after work. Do not eat, drink or smoke
whilst handling the product.
EXPOSURE LIMITS None prescribed in EH40
9.PHYSICAL AND CHEMICAL PROPERTIES
Appearance Red paste Oxidising properties None
Odour Amine-like Vapour pressure No data
pH >7 (in water) Relative density 1.2 (25ºC)
Boiling point Decomposes Bulk density Not relevant
Melting point Not Relevant Viscosity No data
Flash point >100°C (CC) Solubility Partially miscible with water
Autoignition temperature No data Partition coefficient No data
Explosive properties No data Other data
TRIFIX ADHESIVE – HARDENDER Material Safety Data Sheet According to 93/112EC
10.STABILITY/REACTIVITY
STABILITY Stable under normal conditions of use.
CONDITIONS TO AVOID High Temperatures, formation of aerosols, static discharges.
MATERIALS TO AVOID Strong oxidising agents, acids and bases.
11.TOXICOLOGICAL INFORMATION
LD50 (rat, oral): > 5000mg/kg (by calculation). Eye irritation (rabbit): corrosive. Skin irritation (rabbit): corrosive.
Dermal sensitisation (guinea pig): sensitiser
12.ECOLOGICAL INFORMATION
MOBILITY Likely to be mobile in soil.
DEGRADABILITY Readily biodegradable.
ACCUMULATION There is little potential for bioaccumlation. Biomagnification is
unlikely.
ECOTOXICITY Toxic to aquatic organisms:
13.DISPOSAL CONSIDERATIONS
DISPOSAL OF PRODUCT Chemical residues are normally regarded as Special Waste. Incinerate
in compliance with the Environmental Protection Act 1990 (Process
Guidance Note IPR5/1)
DISPOSAL OF PACKAGING As for the product.
14. TRANSPORT INFORMATION
UN NO. 2327
PROPER SHIPPING NAME
ADR/RID Class 8. Item 53(b)
IMCO Class 8. IMDG Code page
MFAG Table No. 320
EmS No. 8-05
IATA/IACO Class 8
PACKING GROUP 3
LABEL Corrosive
Material Safety Data Sheet According to 93/112EC TRIFIX ADHESIVE - HARDENER
15. REGULATORY INFORMATION
CLASSIFICATION Corrosive
LABEL INFORMATION
R34: Causes burns.
R22: Harmful if swallowed.
R43: May cause sensitisation by skin contact.
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36/37/39: Wear suitable protective clothing, gloves and eye/face protection.
Refer to other relevant legislation such as the Health and Safety at Work etc Act (HSWA), THE
Control of Substances Hazardous to Health Regulations (COSHH), the Environment Protection Act
and the Control of Pollution Act.
The information contained in this safety data sheet does not constitute the user’s own assessment of
workplace risk as
required by health and safety legislation.
16.OTHER INFORMATION
The information contained in this data sheet is to the best of our knowledge accurate at the date of publication,
but we cannot accept responsibility that it is sufficient or correct in all cases.
The data contained herein does not constitute a specification. Such information is available from the technical
data sheet for the product.
Abbreviations: OES – occupational exposure standard. STEL – short-term exposure limit. LTEL – long
term exposure limit. TWA – time weighted (8 hour) average. LEL – lower explosive limit. UEL – upper
explosive limit.
