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					19201, ave Clark Graham Baie D'Urfé Qc H9X 3P5 Tél: 514−457−3628 Fax: 514−457− 9773

IRON OXIDE RED: 124, 125, 127, 132, 132G, 137, 139, 145, 185, J3103Z, 3107, 3113, 3109, 3136, 3140, J1000, J3140, 1121, 3186, J3110, J3122
Prod: SLC2182

Section 1: MANUFACTURER INFORMATION MANUFACTURER/SUPPLIER: ROCKWOOD PIGMENTS 7011 MUIRKIRK ROAD BELTSVILLE, MD 20705. SUPPLIER 24 HOUR PHONE EMERGENCY: CHEMTREC 1−800−424−9300. NUMBER: CHEMICAL FAMILY: INORGANIC METAL OXIDE. PRODUCT USES: PIGMENT. REVISIONS: NEW MSDS. ISSUE #: 001 REVISION DATE: 2006/08/02. HAZARD RATING HEALTH: 0 FIRE: 0 REACTIVITY: 0 Section 2: HAZARDOUS INGREDIENTS
Ingredient Name IRON OXIDE − FE2O3 SILICON DIOXIDE CONCENTRATION % 95−99 <1 T.L.V. 5 MG/M3 NOT AVAILABLE C.A.S. 1309−37−1 7631−86−9 LD/50 NOT AVAILABLE NOT AVAILABLE LC/50 NOT AVAILABLE NOT AVAILABLE

Section 2A: ADDITIONAL INGREDIENT INFORMATION NOTE: EXPOSURE TO IRON OXIDE FUMES MAY OCCUR DURING WELDING PROCEDURES.

IRON OXIDE RED: 124, 125, 127, 132, 132G, 137, 139

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Section 3: PHYSICAL DATA PHYSICAL STATE: SOLID APPEARANCE & ODOR: RED LITTLE OR NO ODOUR. DRY POWDER. ODOR THRESHOLD (PPM): NOT APPLICABLE. PH (AS IS): 4−8 (50 g/l WATER). SPECIFIC GRAVITY 4.5−5.0 @ 20°C. (WATER=1) @ 20OC: BOILING POINT °C: NOT APPLICABLE. VAPOUR PRESSURE (MM HG): NOT APPLICABLE. VAPOUR DENSITY (AIR=1): NOT APPLICABLE. FREEZING POINT: 1000 DEG C. EVAPORATION RATE NOT APPLICABLE. (BUTYL ACETATE = 1): MELTING POINT °C: > 1000 DEG C. VOLATILES BY VOLUME: NOT APPLICABLE. SOLUBILITY IN WATER (%): INSOLUBLE. COEFFICIENT OF WATER/OIL NOT AVAILABLE. DISTRIBUTION: VOC: 0 Section 4: FIRE & EXPLOSION DATA FLAMMABILITY: NOT FLAMMABLE. CONDITIONS OF SURROUNDING FIRE. FLAMMABILITY: EXTINGUISHING MEDIA: CARBON DIOXIDE, DRY CHEMICAL, FOAM. WATER SPRAY. USE EXTINGUISHING MEDIA FOR SURROUNDING FIRE. SPECIAL PROCEDURES: FIREFIGHTERS SHOULD WEAR THE USUAL PROTECTIVE GEAR. USE SELF CONTAINED BREATHING APPARATUS. FLASH POINT (C), METHOD: WILL NOT FLASH. AUTOIGNITION NOT AVAILABLE. TEMPERATURE: UPPER FLAMMABLE LIMIT NOT APPLICABLE. (% VOL): LOWER FLAMMABLE LIMIT NOT APPLICABLE. (% VOL): SENSITIVITY TO STATIC NOT APPLICABLE. DISCHARGE:

IRON OXIDE RED: 124, 125, 127, 132, 132G, 137, 139

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SENSITIVITY TO IMPACT: NOT APPLICABLE. RATE OF BURNING: NOT APPLICABLE. EXPLOSIVE POWER: NOT APPLICABLE. HAZARDOUS COMBUSTION SMOKE PRODUCTS: IRRITATING & TOXIC FUMES AT ELEVATED TEMPERATURES. T.D.G. FLAMMABILITY NOT APPLICABLE. CLASS: Section 5: REACTIVITY DATA CHEMICAL STABILITY: PRODUCT IS STABLE IN NORMAL HANDLING AND STORAGE CONDITIONS. CONDITIONS OF NONE KNOWN. INSTABILITY: HAZARDOUS WILL NOT OCCUR. POLYMERIZATION: INCOMPATIBLE NONE KNOWN. SUBSTANCES: REACTIVITY, UNDER WHICH NONE KNOWN. CONDITIONS?: HAZARDOUS PRODUCTS OF SEE HAZARDOUS PRODUCTS OF COMBUSTION SECTION 4. DECOMPOSITION: Section 6: TOXICOLOGICAL PROPERTIES ROUTE OF ENTRY: INHALATION. EYE CONTACT, SKIN CONTACT. EFFECTS OF ACUTE EXPOSURE EYE CONTACT: EXCESSIVE EXPOSURE TO AIRBORNE DUST MAY REDUCE VISIBILITY AND/OR CAUSE UNPLEASANT DEPOSITS IN THE EYES. SKIN CONTACT: INJURY TO THE SKIN CAN OCCUR BY DIRECT MECHANICAL ACTION OR BY RIGOROUS SKIN CLEANING NECESSARY FOR REMOVAL OF DUST. SKIN ABSORPTION: NO HAZARD KNOWN. INHALATION: MAY CAUSE RESPIRATORY IRRITATION. CAN CAUSE COUGHING AND SNEEZING. EXCESSIVE EXPOSURE TO AIRBORNE DUST MAY CAUSE UNPLEASANT DEPOSITS IN THE EARS AND NOSE. INJURY TO THE MUCOUS MEMBRANES CAN OCCUR BY DIRECT MECHANICAL ACTION. INGESTION: NO HAZARD IN NORMAL INDUSTRIAL USE. EFFECTS OF CHRONIC PROLONGED INHALATION (6 TO 10 YEARS) OF IRON OXIDE FUME HAS EXPOSURE: BEEN REPORTED TO PRODUCE CHANGES IN LUNG X−RAYS OF EXPOSED INDIVIDUALS. THIS CONDITION, SIDEROSIS, IS CONSIDERED TO BE A BENIGN PNEUMONIOCOSIS THAT EXHIBITS NO ADVERSE HEALTH EFFECTS. SIDEROSIS HAS BEEN OBSERVED AMONG OCCUPATIONS SUCH AS ARC−WELDERS WHERE IRON OXIDE FUMES ARE PRESENT. AS PER MANUFACTURER, THIS CONDITION HAS NOT BEEN OBSERVED AFTER PROLONGED EXPOSURE TO IRON OXIDE PIGMENTS.

IRON OXIDE RED: 124, 125, 127, 132, 132G, 137, 139

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LD 50 OF MATERIAL, SPECIES > 500 mg/kg RAT ORAL. & ROUTE: LC 50 OF MATERIAL, SPECIES NOT AVAILABLE. & ROUTE: EXPOSURE LIMIT OF RECOMMENDED. MATERIAL: 10 mg/m3 TOTAL DUST. IRRITANCY OF MATERIAL: NON−IRRITANT TO THE EYES OF A RABBIT. NON−IRRITANT TO THE SKIN OF A RABBIT. SENSITIZING CAPABILITY OF NOT AVAILABLE. MATERIAL: CARCINOGENIC EFFECTS: NOT LISTED AS A CARCINOGEN. REPRODUCTIVE EFFECTS: NOT AVAILABLE. TERATOGENICITY: NOT AVAILABLE. MUTAGENICITY: NOT AVAILABLE. SYNERGISTIC MATERIALS: NOT AVAILABLE. Section 7: PREVENTATIVE MEASURES PERSONAL PROTECTION GLOVES/TYPE: RUBBER, CLOTH OR PLASTIC GLOVES. IF APPROPRIATE FOR JOB CONDITIONS. RESPIRATORY/TYPE: WEAR NIOSH APPROVED RESPIRATOR FOR NUISANCE DUST WHEN DUST LEVELS EXCEED THE RECOMMENDED EXPOSURE LIMIT. EYE/TYPE: SAFETY GLASSES. FOOTWEAR/TYPE: SAFETY BOOTS PER LOCAL REGULATIONS. CLOTHING/TYPE: WEAR ADEQUATE PROTECTIVE CLOTHING. OTHER/TYPE: EYE WASH FACILITY SHOULD BE IN CLOSE PROXIMITY. EMERGENCY SHOWER SHOULD BE IN CLOSE PROXIMITY. VENTILATION PROVIDE ADEQUATE VENTILATION. REQUIREMENTS: LEAK/SPILL: PREVENT RUNOFF INTO DRAINS, SEWERS, AND OTHER WATERWAYS. AVOID DUST ACCUMULATION. VENTILATE AREA. WEAR PROTECTIVE EQUIPMENT. SCOOP UP OR VACUUM SPILLAGE. PUT IN APPROPRIATE LABELLED CONTAINER FOR DISPOSAL. WASTE DISPOSAL: IN ACCORDANCE WITH MUNICIPAL, PROVINCIAL AND FEDERAL REGULATIONS. FOLLOW COMPANY POLICIES AND PROCEDURES. HANDLING PROCEDURES USE ADEQUATE VENTILATION. AND EQUIPMENT: AVOID BREATHING DUST. WASH CONTAMINATED CLOTHING BEFORE REUSE. WEAR PROTECTIVE CLOTHING. AVOID DUST ACCUMULATIONS. AVOID EYE AND SKIN CONTACT. WASH THOROUGHLY AFTER USING, PARTICULARLY BEFORE EATING OR SMOKING.

IRON OXIDE RED: 124, 125, 127, 132, 132G, 137, 139

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STORAGE NEEDS: STORE IN A DRY PLACE. STORE AT AMBIENT TEMPERATURES. STORE AWAY FROM EXCESSIVE HEAT. STORE AWAY FROM OXIDIZERS. STORE AWAY FROM FOOD AND BEVERAGES. PROTECT FROM MOISTURE. SPECIAL SHIPPING NOT REGULATED. INSTRUCTIONS: Section 8: FIRST AID MEASURES SKIN CONTACT: REMOVE CONTAMINATED CLOTHING − WASH AFFECTED AREA WITH WARM WATER AND SOAP − SEEK MEDICAL ATTENTION IF IRRITATION OCCURS OR PERSISTS. EYE CONTACT: FLUSH EYES WITH WATER FOR AT LEAST 15 MINUTES. REMOVE CONTACT LENSES IF WORN. LIFT EYELIDS OCCASIONALLY TO FACILITATE IRRIGATION. CONSULT A PHYSICIAN IF IRRITATION PERSISTS. INHALATION: REMOVE VICTIM TO FRESH AIR − IF NOT BREATHING QUALIFIED PERSONNEL SHOULD ADMINISTER ARTIFICIAL RESPIRATION − GET MEDICAL ATTENTION. IF BREATHING IS DIFFICULT, ADMINISTER OXYGEN. INGESTION: GET MEDICAL ATTENTION. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. DO NOT INDUCE VOMITING. DRINK TWO GLASSES OF WATER. ADDITIONAL INFORMATION: NOT APPLICABLE. Section 9: ADDITIONAL INFORMATION CAS NOMENCLATURE: IRON OXIDE (FE2O3). C.A.S. REGISTRATION 1309−37−1. NUMBER: DOMESTIC SUBSTANCE LIST: THIS PRODUCT APPEARS ON THE DOMESTIC SUBSTANCE LIST. APPEARS ON THE U.S. TSCA INVENTORY. W.H.M.I.S.: CLASSIFICATION: NOT CONTROLLED. T.D.G.R.: PROPER SHIPPING NAME: NOT REGULATED. UN/PIN #: NOT APPLICABLE. CLASS: NOT APPLICABLE. PACKING GROUP: NOT APPLICABLE. REPORTING QUANTITY: NOT APPLICABLE. I.M.O. CLASSIFICATION: REFER TO TRANSPORTER. ICAO (AIR) CLASS: REFER TO AIRLINE.

IRON OXIDE RED: 124, 125, 127, 132, 132G, 137, 139

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QUANTITY PERMITTED ON REFER TO AIRLINE. PASSENGER AIR CRAFT: QUANTITY PERMITTED ON REFER TO AIRLINE. CARGO AIR CRAFT: SPECIAL SHIPPING IN CASE OF EMERGENCY CONTACT CANUTEC 1−613−996−6666. INSTRUCTIONS: ESSENTIAL INFORMATION: THE INFORMATION CONTAINED HEREIN IS BASED UPON PUBLICLY AVAILABLE INFORMATION AND IS CONSIDERED TRUE AND ACCURATE. THIS COMPANY MAKES NO WARRANTIES EXPRESS OR IMPLIED AS TO THE ACCURACY OR ADEQUACY OF THIS INFORMATION. THIS INFORMATION IS OFFERED SOLEY FOR THE USER'S CONSIDERATION, INVESTIGATION AND VERIFICATION. IT IS THE USER'S RESPONSIBILITY WHETHER ANY USE OF THIS INFORMATION AND DATA IS IN ACCORDANCE WITH APPLICABLE FEDERAL, PROVINCIAL/STATE OR LOCAL LAWS AND REGULATIONS. THE MANUFACTURERS ORIGINAL MSDS IS AVAILABLE BY CONTACTING THE SALES ORDER DEPARTMENT. NATIONAL POLLUTANTS DOES NOT APPEAR. RELEASE INVENTORY (NPRI): REFERENCES: 1−"DANGEROUS GOODS GUIDE TO INITIAL EMERGENCY RESPONSE" − CANUTEC 1996. 2−"REGULATIONS RESPECTING THE HANDLING, OFFERING FOR TRANSPORT AND TRANSPORTATION OF DANGEROUS GOODS" − EXTRACT FROM THE CANADA GAZETTE PART II, 3−"CONTROLLED PRODUCTS REGULATIONS: HAZARDOUS PRODUCTS ACT" − EXTRACT FROM THE CANADA GAZETTE PART II. 4−"DOMESTIC SUBSTANCE LIST" − ENVIRONMENT CANADA 5−"1996 THRESHOLD LIMIT VALUES FOR CHEMICALS AND PHYSICAL AGENTS AND BIOLOGICAL EXPOSURE INDICES " − AMERICAN CONFERENCE OF GOVERNMENTAL INDUSTRIAL HYGIENISTS (ACGIH) 6−"CCINFO−DISK" CANADIAN CENTRE FOR OCCUPATIONAL HEALTH AND SAFETY. DATA PREPARED BY: CONFORM−ACTION DATA SYSTEMS A DIVISION OF 2843471 CANADA INC. 1804 TRANS−CANADA HWY., DORVAL, QUEBEC H9P 1H7 (514) 683−2060 (800) 990−5093 FAX (514) 683−1445.

IRON OXIDE RED: 124, 125, 127, 132, 132G, 137, 139

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posted:7/14/2009
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