SAFETY DATA SHEET
GRAFFITI WIPES Page 1 Issued: 13.11.08 Revision No: 3
1. IDENTIFICATION OF THE SUBSTANCE / PREPARATION AND OF THE COMPANY / UNDERTAKING
Product name: GRAFFITI WIPES Product code: 43128 Company name: ROCOL ROCOL House Swillington Leeds West Yorkshire LS26 8BS ENGLAND Tel: +44 (0) 113 232 2700 Fax: +44 (0) 113 232 2740 Emergency tel: +44 (0) 113 232 2600 Email: firstname.lastname@example.org
2. HAZARDS IDENTIFICATION
Main hazards: Flammable. Irritating to skin. May cause sensitisation by skin contact. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
3. COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous ingredients: D-LIMONENE 15-30% EINECS: 227-813-5 CAS: 5989-27-5 [-] R10; [Xi] R38; [Sens.] R43; [N] R50/53 • 1-METHOXY-2-PROPANOL 15-30% EINECS: 203-539-1 CAS: 107-98-2 [-] R10 • CYCLOHEXANONE 5-15% EINECS: 203-631-1 CAS: 108-94-1 [-] R10; [Xn] R20 • BRONOPOL (INN) <1% EINECS: 200-143-0 CAS: 52-51-7 [Xn] R21/22; [Xi] R37/38; [Xi] R41; [N] R50
4. FIRST AID MEASURES (SYMPTOMS)
Skin contact: Eye contact: Ingestion: Inhalation: There may be irritation and redness at the site of contact. There may be irritation and redness. The eyes may water profusely. There may be soreness and redness of the mouth and throat. May cause drowsiness. Exposure may cause coughing or wheezing.
4. FIRST AID MEASURES (ACTION)
Skin contact: Wash immediately with plenty of soap and water. Remove all contaminated clothes and footwear immediately unless stuck to skin. Eye contact: Bathe the eye with running water for 15 minutes. Obtain medical attention if soreness or redness persists. Ingestion: Wash out mouth with water. Do not induce vomiting. Consult a doctor. Inhalation: Remove casualty from exposure ensuring one's own safety whilst doing so. Seek medical attention if you feel unwell.
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5. FIRE-FIGHTING MEASURES
Extinguishing media: Carbon dioxide. Dry chemical powder. Exposure hazards: In combustion emits toxic fumes. Protection of fire-fighters: Wear self-contained breathing apparatus. Wear protective clothing to prevent contact with skin and eyes.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions: Refer to section 8 of SDS for personal protection details. Eliminate all sources of ignition. Environmental precautions: Do not discharge into drains or rivers.
7. HANDLING AND STORAGE
Handling requirements: Ensure there is sufficient ventilation of the area. Storage conditions: Store in cool, well ventilated area. Keep container tightly closed. Suitable packaging: Must only be kept in original packaging.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Hazardous ingredients: 1-METHOXY-2-PROPANOL WEL (8 hr TWA): 375 mg/m3 WEL (15 min STEL): 560 mg/m3 • CYCLOHEXANONE WEL (8 hr TWA): 10 ppm WEL (15 min STEL): 20 ppm Engineering measures: Ensure there is sufficient ventilation of the area. Respiratory protection: Respiratory protection not required. Hand protection: Protective gloves. Eye protection: Safety glasses with side-shields. Ensure eye bath is to hand. Skin protection: Protective clothing.
9. PHYSICAL AND CHEMICAL PROPERTIES
State: Colour: Odour: Boiling point/range°C: Flash point°C: pH: Liquid Grey Characteristic odour 120 45 4.9 - 5.9
10. STABILITY AND REACTIVITY
Stability: Conditions to avoid: Materials to avoid: Haz. decomp. products: Stable under normal conditions. Heat. Hot surfaces. Strong oxidising agents. Strong acids. In combustion emits toxic fumes.
11. TOXICOLOGICAL INFORMATION
Hazardous ingredients: D-LIMONENE ORL MUS LD50 5600 mg/kg ORL RAT LD50 4400 mg/kg SCU MUS LD50 3170 mg/kg • 1-METHOXY-2-PROPANOL IVN RAT LD50 4200 mg/kg ORL MUS LD50 11700 mg/kg ORL RAT LDLO 3739 mg/kg • CYCLOHEXANONE ORL MUS LD50 1400 mg/kg ORL RAT LD50 1620 µl/kg SCU RAT LD50 2170 mg/kg [cont...]
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• BRONOPOL (INN) ORL MUS LD50 270 mg/kg ORL RAT LD50 180 mg/kg SKN MUS LD50 4750 mg/kg SKN RAT LD50 1600 mg/kg Chronic toxicity: May cause sensitisation by skin contact. Routes of exposure: Refer to section 4 of SDS for routes of exposure and corresponding symptoms.
12. ECOLOGICAL INFORMATION
Persistence and degradability: No data available. Other adverse effects: Toxic to aquatic organisms.
13. DISPOSAL CONSIDERATIONS
NB: The user's attention is drawn to the possible existence of regional or national regulations regarding disposal.
14. TRANSPORT INFORMATION ADR / RID
UN no: Packing group: Shipping name: Labelling: 1263 III PAINT 3 ADR Class: 3 Classification code: F1 Hazard ID no: 30
IMDG / IMO
UN no: Packing group: Marine pollutant: Labelling: 1263 III . 3 Class: 3 EmS: F-E,S-E(ul)
IATA / ICAO
UN no: Packing group: Packing instructions: Labelling: 1263 III 309(P&CA); 310(CAO) 3 Class: 3
15. REGULATORY INFORMATION
Hazard symbols: Irritant. Dangerous for the environment.
Risk phrases: R10: Flammable. R38: Irritating to skin. R43: May cause sensitisation by skin contact. R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Safety phrases: S24: Avoid contact with skin. [cont...]
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S37: Wear suitable gloves. S51: Use only in well-ventilated areas. S35: This material and its container must be disposed of in a safe way. Haz. ingredients (label): D-LIMONENE Note: The regulatory information given above only indicates the principal regulations specifically applicable to the product described in the safety data sheet. The user's attention is drawn to the possible existence of additional provisions which complete these regulations. Refer to all applicable national, international and local regulations or provisions.
16. OTHER INFORMATION
Other information: EC Directive 1999/45/EC relating to the classification, packaging and labelling of dangerous preparations. EC Directive 91/155/EEC defining the laying down and detailed arrangements for the system of specific information relating to dangerous preparations. Risk phrases used in s.3: R10: Flammable. R38: Irritating to skin. R43: May cause sensitisation by skin contact. R50/53: Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R20: Harmful by inhalation. R21/22: Harmful in contact with skin and if swallowed. R37/38: Irritating to respiratory system and skin. R41: Risk of serious damage to eyes. R50: Very toxic to aquatic organisms. Legal disclaimer: The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a guide. This company shall not be held liable for any damage resulting from handling or from contact with the above product.