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									 Proceedings of the Fifth International Symposium on Refractories
                                                Contents


 INVITED REPORTS
Innovative Development of China’s Refractories
                                                                                                    1
ZHONG Xiangchong
Analysis and Forecast on Chinese Steel Market
                                                                                                    6
LI Shijun
Technology Development of High Temperature Industryand Progress of Refractories Industry in China
                                                                                                    22
LI Hongxia
Characteristics and Problem of Chrome-Containing Refractory
                                                                                                    28
Akira Yamaguchi
New Strategies for Advanced Testing Methods in the Field of Refractory Products
                                                                                                    31
Quirmbach Peter, Krause Olaf, Pötschke Jurgen
Development and Tendency of Refractories for Building Materials Industry in China
                                                                                                    34
ZENG Dafan, WANG Jiezeng
The Refractories Industry, Challenges and Developments
                                                                                                    37
Stefan Pirker
Evaluation of Carbon and Oxide Based Microstructures with Improved Thermal Shock
Performance due to Nanometer Particle Additions                                                     38
C.G. Aneziris, U. Klippel, W. Scharfl
Mineral and Matrix Engineering for Tailor Made Insulation in Steel Industry
                                                                                                    43
Octavian Anton, xVolker Krasselt, Glenn White et al.

 OVERVIEW
Energy Saving Direction of Refractory Production in China
                                                                                                    51
WEI Tong, WU Yunguang
Export and Import Situation of Refractories in China
                                                                                                    58
WANG Tiezheng, ZHANG Dejun, PAN Shangxin et al.
The Environment Problem and Pollution Prevention of Chrome Bearing Refractories
                                                                                                    62
XU Yanqing, FAN Zhihui, GENG Keming et al.
An Overview of MagnesiaHercynite Refractories for Cement Rotary Kilns
                                                                                                    65
GUO Zongqi, Josef Nievoll
Composition, Principle Damaged and Trends of Blast Furnace Taphole Clay
                                                                                                    72
LU Bing, FANG Changrong, WANG Zhoufu et al.
The Present Situation of Large BF Taphole Clay
                                                                                                    77
DONG Xiaochun,GUAN Shanji,LIU Miao

 STUDY ON THEORETICS, TECHNOLOGY AND APPLICATION
Effect of Bonds on Properties of Refractory Castables
                                                                                                    80
TIAN Shouxin
Investigation on Creep Resistance Magnesia Refractory
                                                                                                    86
SHI Gan, SUN Gengchen




                                                        I
Effects of Zirconia and Alumina on the Properties of Clay Bonded SiC Refractories
                                                                                                     90
A.A. Nourbakhsh, Z.A. Nemati, B. Amiri et al.
Burnout and Sintering of Gelcast Alumina-Spinel Parts
                                                                                                     97
LIU Kaiqi, LIU Yongfeng, WANG Bingjun et al.
Study on Numerical Simulation of Temperature Field and Optimization of Structure and
Properties of Permeable Brick                                                                       101
GU Huazhi, WANG Houzhi, ZHANG Meijie et al.
Research on Magnesite Heat-Dress Mechanism
                                                                                                    104
QU Dianli, ZHOU Xuliang, SHEN Xiaoyu et al.
Saving Potentials for the Production of Shaped Refractory Products: An Energy Efficiency Analysis
                                                                                                    108
Thorsten Tonnesen, Rainer Telle
Thermal Shock Resistance of Bauxite-Based β-Sialon Bonded Corundum/Silicon Carbide Composites
                                                                                                    112
ZHANG Haijun, HAN Bo
Analysis on Damage Reasons of Refractories Used in Rotary Kiln Producing Pellet
                                                                                                    116
XU Guotao, LV Yongjing, CHEN Huasheng et al.
Effect of Additives on the Densification of MgO Castable
                                                                                                    120
Z.X. Yang, K.H. Hwang, S.Y. Yoon et al.
Effects of Andalusite and Quartz on Properties of Mullite Based Castables
                                                                                                    124
HAN Bingqiang, WANG Peng, XU Yong et al.
Route of Steel Penetration in MgO-SiC Composites
                                                                                                    128
WEI Yaowu, LI Nan, CHEN Fangyu, XU Juliang
Synthesis of Magnesium Aluminum Oxynitride by Carbothermal Reduction and Nitridation
Process: Evolution of Morphology                                                                    131
DAI Wenbin, Akira Yamaguchi, LIN Wei et al.
Oxidation Protection of MgO-CaO-C Refractories by Addition of CaB6
                                                                                                    134
CHEN Min, SONG Yulong, YU Jingkun
Study on Relationship Between the Structure and Thermal Shock Resistance for Dense Structure
Refractories                                                                                        138
XIONG Xingyun, XIONG Yan
Study on Phase Transformation of Fe-Si3N4 System Material at High Temperature
                                                                                                    142
CHEN Junhong, WANG Fuming, SUN Jialin et al.
Investigation of Effective Parameters on Properties of Dolomite Bricks Containing Different
Bonding System                                                                                      145
S.Otroj, M. R. Nilforoushan
Optimization of Rheology and Mechanical Properties of LCC at Low and High Ambient
Temperature Based on Chinese Raw Materials                                                          148
LI Bin, SUN JiaLin, Benoit Valdelievre et al.
Reaction Between High-Grade Magnesia and Indian Chrome Ore During Firing
                                                                                                    155
LI Long, YU Jingkun, ZOU Zongshu
Effects of Heating Temperature and Addition Amount of La 2O3 on Synthesis of ZrO2-SiC
Composite                                                                                           158
MA Beiyue, TAN Cheng, YU Jingkun
Analyze Complex Phases of Slag-Tundish Plaster Reactions by XRD Ratio of Slopes Method
                                                                                                    161
A.Monshi, B. M. Moshtaghioun
Dynamics Research on SiAlON in situ Synthesis in Al2O3-Si-Al System
                                                                                                    169
WANG Li, ZHANG Xiaohui, JIANG Mingxue
Effect of Grain Size of ZrO2 Additive on Properties of MgO-CaO Refractories
                                                                                                    173
LU Caiyun, CHEN Min, YU Jingkun
Effect of B4C and SiC Addition on Properties of Alumina-Graphite Refractories
                                                                                                    177
SUN Yong, YU Jingkun
Effect of Various Additives on Properties of Al(O,N,C) in situ Reaction Reinforced Corundum
                                                                                                    180
Composite


                                                       II
YANG Ding’ao, YUAN Shouqian, JIANG Mingxue et al.


Effect of the Soaking ZrOCl2 Solution on the Slag Resistance of Magnesia Refractory
                                                                                                    184
HU Jingjing, YAN Zhengguo, YU Jingkun
Effects of Si-Al Powder Addition on the Properties, Phase Composition and Microstructure of
Corundum Material                                                                                   187
LIU Xinhong, YE Fangbao, ZHONG Xiangchong
Preparation of TiC Coating on Graphite Flakes Using Molten Salt Techniques
                                                                                                    191
LIU Xiaoguang, Zhang Shaowei
Effect of Addition of SiC-Al2O3 Composite on Resistance of Slag Corrosion and Slag Penetration of
Corundum Refractory                                                                                 192
ZHU Qiang, YU Jingkun, NIE Licheng
Characters of Modified Resins and Its Application in Al2O3-C Materials
                                                                                                    195
GUO Honglian, SHI Gan and XIA Yi
Research on Activity of Light-Burned Magnesia
                                                                                                    199
GUO Yuxiang, QU Dianli, SUN Yanfen
Study on Reason of Cold Crushing Strength Abnormally Changed After Thermal Shock Test for
Mullite Product                                                                                     201
LIU Xin, QU Dianli, LI Zhijian et al.
Slag Resistance of Reproductive Alumina-Magnesia-Carbon Bricks
                                                                                                    204
LI Xinjian, TANG Kun, Ke Changming et al.
Influence of Microsilica on Properties of Bauxite-based Castables
                                                                                                    208
PENG Hong, Bjørn Myhre and Jan-Olaf Roszinski
Effects of Pore Size Distribution and Composition on Slag Resistance of Porous Spinel
                                                                                                    215
YAN Wen, LI Nan
Electrokinetic Properties of Microsilica Slurries
                                                                                                    220
LI Xinwei, LI Zhijian, WU Feng et al.
Microstructure Study of α-Alumina Powder Derived from Aluminum Hydroxide
                                                                                                    223
CHEN Wei, YIN Zhoulan, LI Wangxing

 REFRACTORIES FOR METALLURGY INDUSTRY
Regenerating Research of Trough Castables
                                                                                                    227
YAO Jinfu, TIAN Shouxin, LIU Zhenjun,et al
Development and Research on Hot-blast Stove Regenerative Materials of Blast Furnace
                                                                                                    231
ZHANG Guodong, LIU Haixiao, YOU Jiegang, et al
Development of Al2O3-C Monolithic Stopper with High Wear Resistance
                                                                                                    235
LIU Guoqi, LI Hongxia, YANG Jinsong, et al
Application of Slide Gate Plates for Casting Ca-alloy Treated Special Steel
                                                                                                    238
J. Chaudhuri, S. Kumar, P. Bajoria, G. Banerjee
Magnesia Based Dry Vibrating Mix for Tundish
                                                                                                    242
LI Yousheng, YAO Xiaoyun, GUO Jianghua, et al
Study on the Corrosion Mechanism of MgO-MgAl2O4 Refractories by Molten Steel
                                                                                                    246
NIE Licheng, YAN Yongliang, YU Jingkun
Development of Magnesia-Carbon Quality Shaped Refractory for Tundish Impact Pad
                                                                                                    249
Rajeshwar Mishra, S. Mukhopadhyay, S.S.Das, et al
Effect of Additives on Grain Growth of Titanium Carbonitride in Carbothermal Reduction Process
of Titanium-Bearing Blast Furnace Slag                                                              252
LI Ciying, LI Yawei, GAO Yunming, et al
Refractories for RH Degassers
                                                                                                    256
John Damiano, Steve Giordanengo




                                                      III
Changes in Quality of Silica Bricks after 20 Years of Operational Exposure in a Heating Wall of
Coke Oven Battery                                                                                 259
Dvorak Stanislav
Technical Measure of Improving Permeable Stability and Service Life of Permeable Brick
                                                                                                  262
HE Jiamei, HU Chun’e, QI Tongrui, et al
Corrosion Resistance of MgO-Al2O3-TiO2 Refractories to Secondary Refining Slag
                                                                                                  267
ZOU Ming, JIANG Mingxue, LI Yong, et al
Study on Remove Inclusion of Molten Steel by Basic Refractory
                                                                                                  273
TIAN Lin, CHEN Shujiang, ZHANG Ling, et al
Smelting Reduction of Panzhihua Iron and Steel Co. BF Slag by Induction Furnace
                                                                                                  277
LI Youqi, KE Changming, HOU Shixi, et al
Effect of Fe-Si3N4 Addition on Properties of Alumina-Graphite Taphole Mix
                                                                                                  281
ZHOU Yongping, SUN Yong, YU Jingkun
Study on Influence of Iron Corrosion Resistance Properties That Aluminum Oxide to TKG
                                                                                                  284
MA Xiao’e, WANG Minli, GUO Hui, et al
Research on Effect of Materials on Property of Blast Furnace Injection Mix
                                                                                                  289
LI Zhihui, LI Zhijian, LI Xinwei, et al
Refractory Castables of Feed Wind Branch Pipe Lining on Blast Furnace
                                                                                                  292
FENG Li, XIONG Binsheng, LIN Liuzhu, et al

 REFRACTORIES FOR CEMENT, GLASS, CERAMIC& OTHER INDUSTRIES
The Research and Development of Special High Alumina Materials for the Smelt Aluminum Stove
                                                                                                  296
DONG Hongqin, SHEN Jianping, LI Shanshan
Medium-Cement Refractory Castables Suitable for the Application to Oil Refinery Unit Lining
                                                                                                  300
HU Zhihua, YAN Yun, LU ZhongYuan
Study on Refractory Castables of DN1100 Hot Blast Valve with Minimum Cooling
                                                                                                  305
XIONG Binsheng, FENG li, WANG Yinhe, et al
Alkali Vapor Corrosion on Mullite-Zircon Brick Used in Glass Tank Furnace
                                                                                                  309
HE Zhongyang, LIU Baikuan, SHI Xubo, et al
Influence and Strategy of Solid Waste Treatment on Refractory of Cement Kiln
                                                                                                  314
FENG Yunsheng, FAN Yong, TAO Guihua, et al
Development of High Alumina Ceramic Foams Fired Under Low Temperature
                                                                                                  321
WEN Kunpeng, MAO Zhongjia

 REFRACTORY RAW MATERIALS
Synthesizing Sulphides by a Temperature Gradient Method
                                                                                                  323
LIU Tao, CHANG Xiaoming, YU Jingkun
Study of MgO-CaO-ZrO2 Synthetic Clinker
                                                                                                  327
CHEN Shujiang, LI Guohua, ZHANG Ling, et al
Durandal 60: a Special Range of Andalusite for High Performance Refractories and Ceramics
                                                                                                  331
P. Hubert, E. Schmidt-Kluge, M.L Bouchetou
E-SY 1000 and E-SY 2000 – New Reactive Aluminas for Easy Workability of Castables
                                                                                                  336
LIU Xinyu, Gunter Buchel, Andreas Buhr
Study on CaZrO3 by Solid Phase Reaction
                                                                                                  341
WANG Jiandong, GE Changchun, SHEN Weiping
Tabular Alumina for High Purity Corundum Brick
                                                                                                  344
LIU Xinyu, XU Yanqing, GENG Keming,et al
Characteristics of Magnesia Obtained from Magnesite and Magnesium Hydrate
                                                                                                  349
LI Huan, YU Jingkun



                                                    IV
Research on Synthesis of Zirconium Boride by Using ZrOCl2, Al and H3BO3
YAN Zhengguo, Chen Wei, YU Jingkun                                                             352

ZrO2-Al2TiO5 Composite Material Prepared by Co-precipitation Method and Their Sintering
Properties                                                                                     355
ZHU Baoli, WANG Zhifa, ZHANG Lifang, et al
Synthesis and Some Characteristics of Al4O4C
                                                                                               359
ZHAO Jianli, LIN Wei, Akira Yamaguchi, et al

 OTHERS
Application of Apparent Specific Gravity on Refractory Research and Production
                                                                                               363
FENG Runtang, JIA Ting, DENG Yongchao, et al
Overall Quality Enhance in Refractory Plants:“Handling” Your Job with Industrial Robots
                                                                                               367
Andrea Grandi , Gianluca Alberti
The Design and Development of Non-Ball Mill for Superhard Refractories
                                                                                               370
LI Kunshan, MO Yimin
Improvement on Lining of Annular Shaft Kiln
                                                                                               375
ZHANG Deguo, WANG Xin, ZHOU Hong
Research About Testing Some Magnesia Refractories Apparent Porosity with Water as Medium
                                                                                               380
WANG Hongyong, LIU Hui, GAO Jianguo
The Prepare and Property Research of a New Cermets Self-Lubricant Coatings
                                                                                               382
XIAO Mingying, WANG Yinzhen, QIN Qingbin
Preparation Mesophase Pitch for Carbon Composite Refractories
LI Shiqiang, ZHAO Lei, LI Yawei, et al                                                         388

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