Material Safety Data Sheet
Revision Date: 07/21/2005 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Product name: HYSOL CB064 6OZ LS ENCAP AMKOR Product type: Encapsulant Company address: Henkel Corporation 15051 East Don Julian Road Industry, California 91746
Issue date: 07/21/2005
Item No. : FP4653-A77A2 / IDH No. 1168959 Region: United States Contact Information: Telephone: 626.968.6511 Emergency Telephone: 860.571.5100 Internet: www.electronics.henkel.us
This product contains epoxy resin CAS number 27610-48-6 that is covered by a USEPA Significant New Use Rule (SNUR) that limits its use to binding fibers in aerospace composites or for encapsulating electronic devices. It is a violation of the SNUR to use this product for any other application. Contains one or more components for which a Toxic Substances Control Act Low Volume Exemption (LVE) applies. Quantities of import and/or manufacturer of the component within this product are limited to the LVE submittor.
2. COMPOSITION/INFORMATION ON INGREDIENTS
Hazardous components Silica, amorphous, fused 60676-86-0 Silica, amorphous (fumed) 7631-86-9 Methylhexahydro phthalic anhydride 25550-51-0 Oxirane, 2,2`-[1,6naphthalenediylbis(oxymethylene)]bi s27610-48-6 % 60-100 ACGIH TLV 0.1 mg/m³ TWA respirable fraction 6 mg/m TWA
OSHA PEL None
10 mg/m TWA
3 mg/m TWA respirable dust
3. HAZARDS IDENTIFICATION EMERGENCY OVERVIEW
HMIS: Physical state: Color: Odor: Liquid Black Odorless HEALTH: FLAMMABILITY: PHYSICAL HAZARD: Personal Protection: 3* 1 0 See Section 8
CAUSES EYE AND SKIN IRRITATION. MAY CAUSE CANCER AND REPRODUCTIVE EFFECTS. MAY CAUSE ALLERGIC SKIN AND RESPIRATORY REACTION. MAY CAUSE RESPIRATORY TRACT IRRITATION.
Skin, Inhalation, Eyes, Ingestion
Relevant routes of exposure: Potential Health Effects Inhalation: Skin contact: Eye contact: Ingestion: Existing conditions aggravated by exposure: Item No. :
May cause respiratory tract irritation. May cause allergic respiratory reaction. Coughing. Causes skin irritation. May cause allergic skin reaction. Repeated or prolonged exposure may cause skin burns. May cause severe eye irritation. Prolonged contact may cause eye burns and corneal injury. Blurred vision. Pain and discomfort. Excess tearing. Redness. May cause irritation to the gastrointestinal tract, mouth and mucous membranes. Eye, skin, and respiratory disorders. Pre-existing skin or lung allergies may increase the chance of developing exaggerated allergic symptoms from exposure to this product. Product name: HYSOL CB064 6OZ LS ENCAP AMKOR 1 of 5
FP4653-A77A2 / IDH No. 1168959
See Section 11 for additional toxicological information.
4. FIRST AID MEASURES
Remove to fresh air. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. If symptoms develop and persist, get medical attention. Remove contaminated clothing and shoes. Immediately flush skin with plenty of water (using soap, if available). Get medical attention if symptoms develop and persist. Wash clothing before reuse. Thoroughly clean shoes before reuse. Check for and remove any contact lenses. Immediately flush eyes with plenty of water for at least 15 minutes. Get medical attention. DO NOT induce vomiting unless directed to do so by medical personnel. Give a conscious person several glasses of water. Never give anything by mouth to an unconscious person. Get medical attention if symptoms develop and persist.
5. FIRE-FIGHTING MEASURES
Flash point: Autoignition temperature: Flammable/Explosive limits-lower %: Flammable/Explosive limits-upper %: Extinguishing media: Special fire fighting procedures: Greater than 121.11ºC (250ºF) Not available Not available Not available Water spray (fog), foam, dry chemical or carbon dioxide. Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear. Use water spray to keep fire exposed containers cool. None Oxides of carbon. Oxides of nitrogen. Hydrocarbons. Cleveland open cup
Unusual fire or explosion hazards: Hazardous combustion products:
6. ACCIDENTAL RELEASE MEASURES
Environmental precautions: Releases of this product may not be made into U.S. waters without primary and secondary wastewater treatment. Evacuate and ventilate spill area; dike spill to prevent entry into water system; wear full protective equipment during clean-up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Scrape up as much material as possible. Store in a closed container until ready for disposal.
7. HANDLING AND STORAGE
Handling: Use only with adequate ventilation. Avoid contact with eyes, skin and clothing. Do not taste or swallow. Do not breathe mist or vapors. Keep container closed. Wash thoroughly after handling. Keep in a cool, well ventilated area away from heat, sparks and open flame. Keep container tightly closed until ready for use. Refer to Section 10. For information on product shelf life contact Henkel Customer Service at (626) 968-6511
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering controls: Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination below occupational exposure limits.
Respiratory protection: Use NIOSH approved respirator if there is potential to exceed exposure limit(s). Item No. : FP4653-A77A2 / IDH No. 1168959 Product name: HYSOL CB064 6OZ LS ENCAP AMKOR 2 of 5
Use chemical resistant, impermeable clothing including gloves and either an apron or body suit to prevent skin contact. 4H gloves. Chemical splash goggles or safety glasses with side shields. Full face protection should be used if the potential for splashing or spraying of product exists. See Section 2 for exposure limits.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state: Color: Odor: Vapor pressure: pH: Boiling point/range: Melting point/range: Specific gravity: Vapor density: Evaporation rate: Solubility in water: Partition coefficient (n-octanol/water): VOC content: Liquid Black Odorless Not available Not applicable Not available Not available 1.9 Not available Not available Insoluble Not available Not available
10. STABILITY AND REACTIVITY
Stability: Hazardous polymerization: Hazardous decomposition products: Incompatability: Conditions to avoid: Stable at normal conditions None under normal processing. Oxides of carbon. Oxides of nitrogen. Hydrocarbons. Strong oxidizing agents. Strong acids and strong bases. Water. Alcohols. Storage with incompatible materials. Heat, flames, sparks and other sources of ignition. Exposure to moisture.
11. TOXICOLOGICAL INFORMATION
Product toxicity data: The U.S. Environmental Protection Agency (EPA) has identified certain substances that are structurally similar to the epoxy resin component with CAS # 27610-48-6. These analogues are phenylglycidylether and diglycidylether of resorcinol. Based on the results of animal bioassays on these analogues, the EPA finds that the epoxy resin component (CAS # 27610-48-6) may be carcinogenic and may cause reproductive effects. The epoxy resin is expected to be absorbed via all routes. Carcinogen Status Hazardous components Silica, amorphous, fused 60676-86-0 Silica, amorphous (fumed) 7631-86-9 Methylhexahydro phthalic anhydride 25550-51-0 Oxirane, 2,2`-[1,6naphthalenediylbis(oxymethylene)]bi s27610-48-6 NTP Carcinogen No No No No IARC Carcinogen No No No No OSHA Carcinogen No No No No
Literature Referenced Target Organ & Other Health Effects
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FP4653-A77A2 / IDH No. 1168959 3 of 5
Product name: HYSOL CB064 6OZ LS ENCAP AMKOR
Hazardous components Silica, amorphous, fused 60676-86-0 Silica, amorphous (fumed) 7631-86-9 Methylhexahydro phthalic anhydride 25550-51-0 Oxirane, 2,2`-[1,6naphthalenediylbis(oxymethylene)]bi s27610-48-6
Health Effects/Target Organs Nuisance dust Nuisance dust Allergen, Irritant, Respiratory Carcinogen, Reproductive
12. ECOLOGICAL INFORMATION
Ecological information: Not available
13. DISPOSAL CONSIDERATIONS
Information provided is for unused product only. Recommended method of disposal: EPA hazardous waste number: Product must be disposed of in a landfill or by incineration. Not a RCRA hazardous waste.
14. TRANSPORT INFORMATION
The shipping classifications in this section are for non-bulk packaging only (unless otherwise specified). Shipping classification may be different for bulk packaging. U.S. Department of Transportation Ground (49 CFR): Proper shipping name: Not regulated (Up to 6 oz when shipped as originally packaged by Henkel only) Hazard class or division: None Identification number: None Packing group: None International Air Transportation (ICAO/IATA): Proper shipping name: Not regulated (Up to 6 oz when shipped as originally packaged by Henkel only) Hazard class or division: None Identification number: None Packing group: None WaterTransportation (IMO/IMDG): Proper shipping name: Hazard class or division: Identification number: Packing group:
Not regulated (Up to 6 oz when shipped as originally packaged by Henkel only) None None None
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Product name: HYSOL CB064 6OZ LS ENCAP AMKOR
15. REGULATORY INFORMATION
United States Regulatory Information TSCA 8 (b) Inventory Status: Contains one or more component(s) for which a Toxic Substances Control Act Low Volume Exemption (LVE) applies. Quantities of import and/or manufacturer of the component within this product are limited to the LVE submittor. This product contains an ingredient for which a Significant New Use Rule (SNUR) has been promulgated by the USEPA under the Toxic Substances Control Act (TSCA) section 5(a)(2). This SNUR (40CFR 721.5192) limits its use to binding fibers in aerospace composites or for encapsulating electronic devices. It is in violation of the SNUR to use this product for any other application. Manufacture, import, distribution, use and disposition of this product is restricted to the requirements listed in 40 CFR. Oxirane, 2,2`-[1,6-naphthalenediylbis(oxymethylene)]bis- (CAS# 27610-48-6). None. Immediate Health Hazard, Delayed Health Hazard None above reporting de minimus. This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm.
TSCA 5 (a) (2) SNUR:
TSCA 12 (b) Export Notification: CERCLA/SARA Section 302 EHS: CERCLA/SARA Section 311/312: CERCLA/SARA 313: California Proposition 65:
Canada Regulatory Information CEPA DSL/NDSL Status: WHMIS hazard class: One or more components are not listed on, and are not exempt from listing on either the Domestic Substances List or the Non-Domestic Substances List. D.2.A, D.2.B
16. OTHER INFORMATION
This material safety data sheet contains changes from the previous version in sections: New Material Safety Data Sheet format. Updated HMIS rating in Section 3. New information added in section(s): 1 - 16 Prepared by: Melissa Frisby, Product Safety and Regulatory Affairs Specialist For Safety and Regulatory Information contact: Product Safety and Regulatory Affairs, Rocky Hill, CT. 860-571-5204
DISCLAIMER: The data contained herein are furnished for information only and are believed to be reliable. However, Henkel Corporation does not assume responsibility for any results obtained by persons over whose methods Henkel Corporation has no control. It is the user's responsibility to determine the suitability of Henkel's products or any production methods mentioned herein for a particular purpose, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of any of Henkel Corporation's products. In light of the foregoing, Henkel Corporation specifically disclaims all warranties, express or implied, including warranties of merchantability and fitness for a particular purpose, arising from sale or use of Henkel Corporation's products. Henkel Corporation further disclaims any liability for consequential or incidental damages of any kind, including lost profits.
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Product name: HYSOL CB064 6OZ LS ENCAP AMKOR