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					(45380) Crystal Violet 0.1 and 1.0% Solutions

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MATERIAL SAFETY DATA SHEET
Section 1 - Chemical Product and Company Identification Crystal Violet 0.1 and 1.0% Solutions MSDS Name: Catalog Numbers: S71261, S71262, S71262-1 Genetian Violet; Aizen Crystal Violet; C.I. Basic Violet 3, C.I. 42555; Gentiaverm; Analine Violet Synonyms: Company Identification: Fisher Scientific One Reagent Lane Fair Lawn, NJ 07410 201-796-7100 201-796-7100 800-424-9300

For information in the US, call: Emergency Number US: CHEMTREC Phone Number, US:

Section 2 - Composition, Information on Ingredients CAS# 532-32-1 548-62-9 7732-18-5 Chemical Name: Sodium benzoate C.I. Basic Violet 3 Water % EINECS# Hazard Symbols: Risk Phrases:

0.02-0.2 208-534-8 0.1-1.0 208-953-6 98.9-99.8 231-791-2

Text for R-phrases: see Section 16 Hazard Symbols: Risk Phrases:

None listed None listed Section 3 - Hazards Identification

EMERGENCY OVERVIEW Danger! Causes eye burns. Causes skin irritation. May cause allergic skin reaction. Harmful if swallowed. Target Organs: Respiratory system, eyes, skin. Potential Health Effects Contact with eyes may cause severe irritation, and possible eye burns. May cause conjunctivitis. This product contains a cationic dye. Similar dyes have caused permanent injury to the cornea and conjunctiva in documented exposure cases with human or rabbit eyes. May cause mild skin irritation. May cause skin sensitization, an allergic reaction, which becomes evident Skin: upon re-exposure to this material. Ingestion: Harmful if swallowed. May cause gastrointestinal irritation with nausea, vomiting and diarrhea. Inhalation: May cause respiratory tract irritation. Chronic: Prolonged or repeated skin contact may cause dermatitis. Eye: Section 4 - First Aid Measures Eyes: Skin: Ingestion: Inhalation: Notes to Physician: Section 5 - Fire Fighting Measures General Information: As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. Extinguishing Media: Use alcohol foam, carbon dioxide, or water spray when fighting fires involving this material. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately. Get medical aid if irritation develops or persists. Flush skin with plenty of soap and water. If victim is conscious and alert, give 2-4 cupfuls of milk or water. Never give anything by mouth to an unconscious person. Get medical aid. Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.

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Autoignition Temperature: Flash Point: Explosion Limits: Lower: Explosion Limits: Upper: NFPA Rating:

Not applicable. Not applicable. Not available Not available Not published Section 6 - Accidental Release Measures

General Information: Spills/Leaks:

Use proper personal protective equipment as indicated in Section 8. Absorb spill with inert material (e.g. vermiculite, sand or earth), then place in suitable container. Clean up spills immediately, observing precautions in the Protective Equipment section. Section 7 - Handling and Storage

Handling: Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Use with adequate ventilation. Storage: Store in a cool, dry place. Keep containers tightly closed. Section 8 - Exposure Controls, Personal Protection Engineering Controls: Use adequate ventilation to keep airborne concentrations low. Exposure Limits CAS# 532-32-1:

CAS# 548-62-9:

CAS# 7732-18-5:

Personal Protective Equipment Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face Eyes: protection regulations in 29 CFR 1910.133 or European Standard EN166. Wear appropriate protective gloves to prevent skin exposure. Skin: Wear appropriate protective clothing to prevent skin exposure. Clothing: Respirators: A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant respirator use. Section 9 - Physical and Chemical Properties Physical State: Color: Odor: pH: Vapor Pressure: Vapor Density: Evaporation Rate: Viscosity: Boiling Point: Freezing/Melting Point: Decomposition Temperature: Solubility in water: Specific Gravity/Density: Liquid violet odorless Not available 14 mm Hg 0.7 >1 Not available 100 deg C ( 212.00°F) 0 deg C ( 32.00°F) 137 deg C Soluble in water. 1.0

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Molecular Formula: Mixture Molecular Weight: 0 Section 10 - Stability and Reactivity Chemical Stability: Conditions to Avoid: Incompatibilities with Other Materials Hazardous Decomposition Products Hazardous Polymerization Stable under normal temperatures and pressures. Incompatible materials. Not available Nitrogen oxides, carbon monoxide, carbon dioxide. Will not occur.

Section 11 - Toxicological Information RTECS#: CAS# 532-32-1: DH6650000 CAS# 548-62-9: BO9000000 CAS# 7732-18-5: ZC0110000 CAS# 532-32-1: Oral, mouse: LD50 = 1600 mg/kg; Oral, rabbit: LD50 = 2 gm/kg; Oral, rat: LD50 = 4070 mg/kg; . CAS# 548-62-9: Oral, mouse: LD50 = 96 mg/kg; Oral, rabbit: LD50 = 150 mg/kg; Oral, rat: LD50 = 420 mg/kg; . CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg; . Sodium benzoate - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. C.I. Basic Violet 3 - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. Water - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop 65. See actual entry in RTECS for complete information. Section 12 - Ecological Information Not available Section 13 - Disposal Considerations Dispose of in a manner consistent with federal, state, and local regulations. Section 14 - Transport Information US DOT Shipping Name: Hazard Class: UN Number: Packing Group: Section 15 - Regulatory Information European/International Regulations European Labeling in Accordance with EC Directives Hazard Symbols:Not available Risk Phrases: Safety Phrases: WGK (Water Danger/Protection) CAS# 532-32-1: 1 CAS# 548-62-9: 2 Please contact Fisher Scientific for shipping information Canada TDG Not available

LD50/LC50:

Carcinogenicity:

Other:

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CAS# 7732-18-5: Not available Canada CAS# 532-32-1 is listed on Canada's DSL List CAS# 548-62-9 is listed on Canada's DSL List CAS# 7732-18-5 is listed on Canada's DSL List Canadian WHMIS Classifications: Not available This product has been classified in accordance with the hazard criteria of the Controlled Products Regulations and the MSDS contains all of the information required by those regulations. CAS# 532-32-1 is not listed on Canada's Ingredient Disclosure List. CAS# 548-62-9 is listed on Canada's Ingredient Disclosure List CAS# 7732-18-5 is not listed on Canada's Ingredient Disclosure List. US Federal TSCA CAS# 532-32-1 is listed on the TSCA Inventory. CAS# 548-62-9 is listed on the TSCA Inventory. CAS# 7732-18-5 is listed on the TSCA Inventory. Section 16 - Other Information MSDS Creation Date: 9/02/1997 Revision #3 Date 10/03/2005 The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantibility or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall the company be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential, or exemplary damages howsoever arising, even if the company has been advised of the possibility of such damages.

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