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Material Safety Data Sheet Section 1. Chemical Product and Company Identification Common Name Supplier Camphorquinone-10-Sulfonic Acid Pierce Chemical Company P.O. Box 117 Rockford, IL 61105 United States 815.968.0747 Not available. Not available. Not available. Pierce Chemical Company P.O. Box 117 Rockford, IL 61105 United States 815.968.0747 Code MSDS# Validation Date 0020249 1876260 94 9/9/98 Synonym Trade name Material Uses Manufacturer Print Date Responsible Name In Case of Emergency 9/9/98 Company CALL CHEMTREC: 800.424.9300 OUTSIDE US: 202.483.7616 Section 2. Composition and Information on Ingredients Name 1) Camphorquinone-10-Sulfonic Acid CAS # 73413-79-3 % by Weight 100 Not available. Exposure Limits Section 3. Hazards Identification Physical State and Appearance Emergency Overview Solid. (Crystals solid.) DANGER! CAUSES SEVERE SKIN BURNS. CAUSES SEVERE EYE BURNS. CAUSES SEVERE RESPIRATORY TRACT BURNS. Avoid breathing dust. Do not breathe dust Do not get on skin or clothing. Do not get in eyes. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Routes of Entry Potential Acute Health Effects Absorbed through skin. Dermal contact. Eye contact. Inhalation. Ingestion. Eyes Hazardous in case of eye contact (corrosive). Eye contact can result in corneal damage or blindness. Skin Hazardous in case of skin contact (corrosive). The amount of tissue damage depends on length of contact. Skin contact can produce inflammation and blistering. Skin contact may produce burns. Inhalation Hazardous in case of inhalation (lung corrosive). Inhalation of dust will produce irritation to gastro-intestinal or respiratory tract, characterized by burning, sneezing and coughing. Over-exposure by inhalation may cause respiratory irritation. Ingestion May be fatal if swallowed. May cause burns to mouth, throat and stomach. Potential Chronic Health Effects Medical Conditions Aggravated by Overexposure CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS : Not available. TERATOGENIC EFFECTS: Not available. Repeated exposure of the eyes to a low level of dust can produce eye irritation. Repeated skin exposure can produce local skin destruction, or dermatitis. Repeated inhalation of dust can produce varying degree of respiratory irritation or lung damage. Not available. Overexposure /Signs/Symptoms See Toxicological Information (section 11) Continued on Next Page Camphorquinone-10-Sulfonic Acid Section 4. First Aid Measures Eye Contact Skin Contact Page: 2/6 Check for and remove any contact lenses. Immediately flush eyes with running water for at least 15 minutes, keeping eyelids open. Cold water may be used. Do not use an eye ointment. Seek medical attention. If the chemical got onto the clothed portion of the body, remove the contaminated clothes as quickly as possible, protecting your own hands and body. Place the victim under a deluge shower. If the chemical got on the victim's exposed skin, such as the hands : Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cold water may be used. If irritation persists, seek medical attention. Wash contaminated clothing before reusing. Allow the victim to rest in a well ventilated area. Seek immediate medical attention. Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention. Not available. Inhalation Ingestion Notes to Physician Section 5. Fire Fighting Measures Flammability of the Product Auto-ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances May be combustible at high temperature. Not available. Not available. Not available. Not available. Not available. Explosion Hazards in Presence Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. of Various Substances Fire Fighting Media and Instructions Protective Clothing (Fire) Special Remarks on Fire Hazards SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray, fog or foam. Do not use water jet. Be sure to use an approved/certified respirator or equivalent. Not available. Special Remarks on Explosion Not available. Hazards Section 6. Accidental Release Measures Small Spill and Leak Use appropriate tools to put the spilled solid in a convenient waste disposal container. Finish cleaning by spreading water on the contaminated surface and dispose of according to local and regional authority requirements. Corrosive solid. Stop leak if without risk. Do not get water inside container. Do not touch spilled material. Use water spray to reduce vapors. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal. Finish cleaning by spreading water on the contaminated surface and allow to evacuate through the sanitary system. Large Spill and Leak Continued on Next Page Camphorquinone-10-Sulfonic Acid Section 7. Handling and Storage Handling Storage Page: 3/6 Avoid breathing dust. Do not breathe dust Do not get on skin or clothing. Do not get in eyes. Keep container closed. Use only with adequate ventilation. Wash thoroughly after handling. Keep container dry. Keep in a cool place. Ground all equipment containing material. Corrosive materials should be stored in a separate safety storage cabinet or room. Section 8. Exposure Controls/Personal Protection Engineering Controls Use process enclosures, local exhaust ventilation, or other engineering controls to keep airborne levels below recommended exposure limits. If user operations generate dust, fume or mist, use ventilation to keep exposure to airborne contaminants below the exposure limit. Personal Protection Eyes Splash goggles. Body Lab coat. Respiratory Vapor and dust respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Hands Gloves. Feet Not applicable. Protective Clothing (Pictograms) Personal Protection in Case of Splash goggles. Full suit. Vapor and dust respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; a Large Spill consult a specialist BEFORE handling this product. Product Name 1) Camphorquinone-10-Sulfonic Acid Exposure Limits Not available. Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical State and Appearance Solid. (Crystals solid.) Molecular Weight Molecular Formula pH (1% Soln/Water) Boiling/Condensation Point Melting/Freezing Point Critical Temperature Specific Gravity Vapor Pressure Vapor Density Volatility Odor Threshold Evaporation Rate VOC 246.3 g/mole Not available. Not available. Decomposes. (156 to 157°C or 312.8 to 314.6°F) Not available. Not available. Not available. Not applicable. Not available. Not available. Not available. Not available. Not available. Odor Taste Color Not available. Not available. Yellow. Continued on Next Page Camphorquinone-10-Sulfonic Acid Viscosity LogKow Ionicity (in Water) Dispersion Properties Solubility Physical Chemical Comments Not available. Not available. Not available. See solubility in water. Partially soluble in cold water, hot water. Not available. Page: 4/6 Section 10. Stability and Reactivity Stability and Reactivity Conditions of Instability Incompatibility with Various Substances Hazardous Decomposition Products Hazardous Polymerization The product is stable. Not available. Reactive with oxidizing agents. Not available. Yes. Section 11. Toxicological Information Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans Special Remarks on Toxicity to Animals Special Remarks on Chronic Effects on Humans Special Remarks on Other Toxic Effects on Humans LD50: Not available. LC50: Not available. Not available. Hazardous in case of skin contact (corrosive), of eye contact (corrosive), of ingestion, of inhalation (lung corrosive). Not available. Not available. To the best of our knowledge, the toxicological properties of this product have not been thoroughly investigated. Section 12. Ecological Information Ecotoxicity BOD5 and COD Biodegradable/OECD Mobility Not available. Not available. Not available. Not available. Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation Special Remarks on the Products of Biodegradation Not available. Not available. Continued on Next Page Camphorquinone-10-Sulfonic Acid Section 13. Disposal Considerations Waste Information Waste Stream Not available. Not available. Page: 5/6 Consult your local or regional authorities. Section 14. Transport Information DOT Classification Not a DOT controlled material (United States). Not applicable. Not applicable. Not applicable. Marine Pollutant Not available. Hazardous Substances Reportable Quantity Special Provisions for Transport TDG Classification ADR/RID Classification IMO/IMDG Classification ICAO/IATA Classification Not available. Not applicable. Not controlled under TDG (Canada). Not controlled under ADR (Europe). Not controlled under IMDG. Not controlled under IATA. Section 15. Regulatory Information HCS Classification U.S. Federal Regulations Class: Corrosive solid. TSCA: No products were found. SARA 302/304/311/312 extremely hazardous substances: No products were found. SARA 302/304 emergency planning and notification: No products were found. SARA 302/304/311/312 hazardous chemicals: No products were found. SARA 311/312 MSDS distribution - chemical inventory - hazard identification: No products were found. SARA 313 toxic chemical notification and release reporting: No products were found. Clean water act (CWA) 307: No products were found. Clean water act (CWA) 311: No products were found. Clean air act (CAA) 112 accidental release prevention: No products were found. Clean air act (CAA) 112 regulated flammable substances: No products were found. Clean air act (CAA) 112 regulated toxic substances: No products were found. International Regulations WHMIS (Canada) Class D-2B: Material causing other toxic effects (TOXIC). No products were found. EINECS DSCL (EEC) International Lists State Regulations Not available. R37/38- Irritating to respiratory system and skin. R41- Risk of serious damage to eyes. No products were found. No products were found. California prop. 65: No products were found. Continued on Next Page Camphorquinone-10-Sulfonic Acid Section 16. Other Information Label requirements CAUSES SEVERE SKIN BURNS. CAUSES SEVERE EYE BURNS. CAUSES SEVERE RESPIRATORY TRACT BURNS. Health Fire Hazard Reactivity Personal Protection Page: 6/6 Hazardous Material Information System (U.S.A.) 3 National Fire 1 Protection Association 0 (U.S.A.) j 1 Health Fire Hazard Reactivity Specific Hazard 3 COR 0 References Other Special Considerations Not available. Not available. Validated by Company on 9/9/98. CALL CHEMTREC: 800.424.9300 OUTSIDE US: 202.483.7616 Notice to Reader Verified by Company. Printed 9/9/98. To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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