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Material Safety Data Sheet A

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Material Safety Data Sheet A Powered By Docstoc
					                                                                        Material Safety Data Sheet

OCEAN ACLOX® FILM
                                                                                     Date of Issue : June 11, 2010
                                                                                                      Page 1of 4

1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
Identification of the Product
1.1. OCEAN ACLOX® FILM
     ACX-G-W (Gloss White) / ACX-M-W (Matte White)
1.2. Usage of the Product
     Unplasticized Flexible Butyl-Acrylate-Vinyl chloride copolymer Sheet
1.3. Company
     Taiyo Chemical Industry Co., Ltd.
     Office/Plant
     3-4-28, Imazu-minami, Tsurumi-ku, Osaka 538-0043, Japan
     Tel. +81-6-6961-0856
     Emergency telephone
     +81-6-6961-5561


2.   COMPOSITION / INFORMATION ON INGREDIENTS
2.1. Chemical Composition
                     Component                        Wt%                          CAS No.
Butyl-Acrylate-Vinyl chloride copolymer               55-65    Non-application
Ba-Zn Stabilizer                                       1-3     Nothing to mention particularly
UV absorber                                           0.5-1    Nothing to mention particularly
Titanium dioxide                                       4-12    13463-67-7
Antimony trioxide                                      1-3     1309-64-4
Calcium carbonate                                      2-4     471-34-1
Other additives                                       20-30    Nothing to mention particularly



3.   HAZARDS IDENTIFICATION
Classified as non-dangerous product.
3.1 Emergency Overview
    In case of emergency such as thermal decomposition, general first aid procedures applied for toxic gasses
     are suitable. Avoid processing vapors, especially hydrogen chloride, which will cause irritation of eyes
     or respiratory tract.
3.2 Repeated or prolonged
    Extended exposure to skin can cause slight irritation.


4.   FIRST AID MEASURES
4.1. Skin contact
     Rinse with plenty of water (15 minutes), then wash area with mild soap and water. Get medical attention if
     irritation should occur or persist.
                                                                        Material Safety Data Sheet

OCEAN ACLOX® FILM
                                                                                       Date of Issue : June 11, 2010
                                                                                                        Page 2of 4


4.2. Eye contact
     Rinse immediately with water (15 minutes), occasionally lift upper and lower lids, until no evidence of
     product remains. Get medical attention.
4.3. Inhalation
      Move affected person to fresh air. Get medical attention.
4.4. Ingestion
      Induce vomiting. Get medical attention.


5.   FIRE FIGHTING MEASURES
5.1. Suitable extinguishing media
     Form water, dry chemical agent (ABC) type, CO2, foam. At extinction, avoid the scattering of burning
     material and avoid creating dust hazard: do not use stick water jets.
5.2. Unsuitable extinguishing media
     Avoid spraying with stick water jet due to the danger of potential spreading.
5.3. Exposure hazards
     CO and CO2 gas, HCl and chlorinated hydrocarbons (small amounts), and aromatic aliphatic hydrocarbons
     may arise in a fire.
5.4. Special protecting equipment for fire-fighters
     Wear full protective clothing. Wear self-contained breathing apparatus.


6.   ACCIDENTAL RELEASE MEASURES
6.1. Personal precautions
     Do not breathe dust when dust is raised. Avoid ignition source. Avoid contact with eyes and skin. Use dust
     mask, gloves made from antistatic material and protecting glasses when dust is raised. Wash hands at the
     end of working.
6.2. Environmental precautions
     Prevent contamination of soil, drains, foodstuffs, drinks, animal feeds and surface waters.
6.3. Methods for cleaning
     Take up mechanically by brush and dustpan or by suction or vacuum equipment. Avoid dust generation
     and ignition source.


7.   HANDLING AND STORAGE
7.1. Handling
     In high temperature processing, handle with care. Wear personal protective equipment. Handle in
     accordance with industrial hygiene and safty practice. Ensure good ventilation. Do not smoke, eat or drink
     at the workplace.
7.2. Storage
     Store in a dry area, avoiding high temperature, sunlight and exposure to water.
                                                                       Material Safety Data Sheet

OCEAN ACLOX® FILM
                                                                                    Date of Issue : June 11, 2010
                                                                                                        Page 3of 4


8.    EXPOSURE CONTROLS / PERSONAL PROTECTION
8.1. Engineering Controls;Processes which generate vapours, dust or fumes should be performed with
       adequate ventilation. If necessary, use NIOSH approved chemical cartridge respirator.
8.2. Exposure controls
8.2.1. Occupational exposure control
8.2.1.1. Respiratory protection: Use dust mask, if necessary.
8.2.1.2. Hand protection: Not necessary in normal use. But use heavy cotton or insulated gloves to handle
         hot sheet.
8.2.1.3. Eye protection: Wear suitable safety glasses.
8.2.2.    Environmental exposure controls: Keep emissions to the atmosphere within local authority
          prescriptions for dust.
8.3. Exposure limits
         Ingredient                    Percent                  ACGIH TLV                      OSHA PEL
Ba-Zn Stabilizer                         1-3
     Ba rium stearate                                           0.5mg/m3(Ba)                   0.5mg/m3(Ba)
     Zn stearate                                                   10mg/m3                        10mg/m3
Titanium dioxide                         4-12                     10mg/m3                           -
Antimony trioxide                        1-3                    0.5mg/m3(Sb)                        -
Calcium carbonate                        2-4                      10mg/m3                           -


9.    PHYSICAL AND CHEMICAL PROPERTIES
       Appearance                          : White sheet/film
       Odor                                : Not available
       Melting point                       : Not available
       Boiling point                       : Not applicable
       Oxidizing properties                : Not applicable
       Density                             : 1.24~1.44 g/cm³
       Flashpoint                          : Not available
       Ignition temperature                : > 250°C
       Solubility in water                 : Not soluble
       Vapour pressure                     : Not applicable
       PH value                            : Not applicable
       Partition coefficient               : Not applicable
       Viscosity                           : Not applicable

10. STABILITY AND REACTIVITY
10.1.     Conditions to avoid: static discharges, dust generation. Please take care not to hold sheet in
          machine for a long time at elevated temperatures in order to avoid decomposition. During long
          exposures to high temperatures, the degradation temperature decreases.
           Avoid to inhale dust and processing vapours, especially hydrogen chloride, which will cause
           irritation of eyes or respiratory tract.
                                                                       Material Safety Data Sheet

OCEAN ACLOX® FILM
                                                                                   Date of Issue : June 11, 2010
                                                                                                     Page 4of 4

10.2.   Materials to avoid: oxidizers.
10.3.   Hazardous decomposition products: when burning or during thermal decomposition, combustion
        gases may result; eg CO, CO2, HCl and chlorinated hydrocarbons (small amounts), and aromatic
        aliphatic hydrocarbons.
11. TOXICOLOGICAL INFORMATION
   No data available for Ocean ACLOX White sheet.
12. ECOLOGICAL INFORMATION
   No data available for Ocean ACLOX White sheet.
13. DISPOSAL CONSIDERATIONS
   Incineration or landfill in accordance with local regulations. The cleaned packaging can be recycled or
   treated together with household refuse. Local regulations may impose specific requirements for treatment
   and/or reporting of the packaging wastes (e.g. as based upon EU packaging waste directive).

14. TRANSPORT INFORMATION
  Carefully load not fall and drop the product when transporting. Take any measures to prevent injury due to
  collapse of cargo piles.

15. REGULATORY INFORMATION
*Japanese Regulations
 PRTR(Pollutant Release and Transfer Register) Law
          Chemical Substances       :    Antimony and its compounds         (I-No31)
*European/International Regulations
 European Labeling in Accordance with EC Directives (data for Sb2O3)
 Hazard Symbols : XN
 Risk Phrases : R 40 Limited evidence of a carcinogenic effect.
 Safety Phrases : S22 Do not breathe dust.
                : S36/37 Wear suitable protective clothing and gloves.

16. OTHER INFORMATION
The information set forth herein has been gathered from standard reference materials and/or Taiyo Chemical
Industry Co., Ltd. test data. The information containing herein is based on the present state of our knowledge
and is intended to describe our product from the view of safety requirements. It should not therefore be
construed as guaranteeing specific properties.
This product should be stored, handled and used in accordance with good industrial hygiene practices and in
conformity with any legal regulation. Safe handling and use remain the responsibility of the customer.