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Material Safety Data Sheet OCEAN ACLOX® FILM Date of Issue : June 11, 2010 Page 1of 4 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Identification of the Product 1.1. OCEAN ACLOX® FILM ACX-G-W (Gloss White) / ACX-M-W (Matte White) 1.2. Usage of the Product Unplasticized Flexible Butyl-Acrylate-Vinyl chloride copolymer Sheet 1.3. Company Taiyo Chemical Industry Co., Ltd. Office/Plant 3-4-28, Imazu-minami, Tsurumi-ku, Osaka 538-0043, Japan Tel. +81-6-6961-0856 Emergency telephone +81-6-6961-5561 2. COMPOSITION / INFORMATION ON INGREDIENTS 2.1. Chemical Composition Component Wt% CAS No. Butyl-Acrylate-Vinyl chloride copolymer 55-65 Non-application Ba-Zn Stabilizer 1-3 Nothing to mention particularly UV absorber 0.5-1 Nothing to mention particularly Titanium dioxide 4-12 13463-67-7 Antimony trioxide 1-3 1309-64-4 Calcium carbonate 2-4 471-34-1 Other additives 20-30 Nothing to mention particularly 3. HAZARDS IDENTIFICATION Classified as non-dangerous product. 3.1 Emergency Overview In case of emergency such as thermal decomposition, general first aid procedures applied for toxic gasses are suitable. Avoid processing vapors, especially hydrogen chloride, which will cause irritation of eyes or respiratory tract. 3.2 Repeated or prolonged Extended exposure to skin can cause slight irritation. 4. FIRST AID MEASURES 4.1. Skin contact Rinse with plenty of water (15 minutes), then wash area with mild soap and water. Get medical attention if irritation should occur or persist. Material Safety Data Sheet OCEAN ACLOX® FILM Date of Issue : June 11, 2010 Page 2of 4 4.2. Eye contact Rinse immediately with water (15 minutes), occasionally lift upper and lower lids, until no evidence of product remains. Get medical attention. 4.3. Inhalation Move affected person to fresh air. Get medical attention. 4.4. Ingestion Induce vomiting. Get medical attention. 5. FIRE FIGHTING MEASURES 5.1. Suitable extinguishing media Form water, dry chemical agent (ABC) type, CO2, foam. At extinction, avoid the scattering of burning material and avoid creating dust hazard: do not use stick water jets. 5.2. Unsuitable extinguishing media Avoid spraying with stick water jet due to the danger of potential spreading. 5.3. Exposure hazards CO and CO2 gas, HCl and chlorinated hydrocarbons (small amounts), and aromatic aliphatic hydrocarbons may arise in a fire. 5.4. Special protecting equipment for fire-fighters Wear full protective clothing. Wear self-contained breathing apparatus. 6. ACCIDENTAL RELEASE MEASURES 6.1. Personal precautions Do not breathe dust when dust is raised. Avoid ignition source. Avoid contact with eyes and skin. Use dust mask, gloves made from antistatic material and protecting glasses when dust is raised. Wash hands at the end of working. 6.2. Environmental precautions Prevent contamination of soil, drains, foodstuffs, drinks, animal feeds and surface waters. 6.3. Methods for cleaning Take up mechanically by brush and dustpan or by suction or vacuum equipment. Avoid dust generation and ignition source. 7. HANDLING AND STORAGE 7.1. Handling In high temperature processing, handle with care. Wear personal protective equipment. Handle in accordance with industrial hygiene and safty practice. Ensure good ventilation. Do not smoke, eat or drink at the workplace. 7.2. Storage Store in a dry area, avoiding high temperature, sunlight and exposure to water. Material Safety Data Sheet OCEAN ACLOX® FILM Date of Issue : June 11, 2010 Page 3of 4 8. EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1. Engineering Controls；Processes which generate vapours, dust or fumes should be performed with adequate ventilation. If necessary, use NIOSH approved chemical cartridge respirator. 8.2. Exposure controls 8.2.1. Occupational exposure control 18.104.22.168. Respiratory protection: Use dust mask, if necessary. 22.214.171.124. Hand protection: Not necessary in normal use. But use heavy cotton or insulated gloves to handle hot sheet. 126.96.36.199. Eye protection: Wear suitable safety glasses. 8.2.2. Environmental exposure controls: Keep emissions to the atmosphere within local authority prescriptions for dust. 8.3. Exposure limits Ingredient Percent ACGIH TLV OSHA PEL Ba-Zn Stabilizer 1-3 Ba rium stearate 0.5mg/m3(Ba) 0.5mg/m3(Ba) Zn stearate 10mg/m3 10mg/m3 Titanium dioxide 4-12 10mg/m3 - Antimony trioxide 1-3 0.5mg/m3(Sb) - Calcium carbonate 2-4 10mg/m3 - 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance : White sheet/film Odor : Not available Melting point : Not available Boiling point : Not applicable Oxidizing properties : Not applicable Density : 1.24～1.44 g/cm³ Flashpoint : Not available Ignition temperature : > 250°C Solubility in water : Not soluble Vapour pressure : Not applicable PH value : Not applicable Partition coefficient : Not applicable Viscosity : Not applicable 10. STABILITY AND REACTIVITY 10.1. Conditions to avoid: static discharges, dust generation. Please take care not to hold sheet in machine for a long time at elevated temperatures in order to avoid decomposition. During long exposures to high temperatures, the degradation temperature decreases. Avoid to inhale dust and processing vapours, especially hydrogen chloride, which will cause irritation of eyes or respiratory tract. Material Safety Data Sheet OCEAN ACLOX® FILM Date of Issue : June 11, 2010 Page 4of 4 10.2. Materials to avoid: oxidizers. 10.3. Hazardous decomposition products: when burning or during thermal decomposition, combustion gases may result; eg CO, CO2, HCl and chlorinated hydrocarbons (small amounts), and aromatic aliphatic hydrocarbons. 11. TOXICOLOGICAL INFORMATION No data available for Ocean ACLOX White sheet. 12. ECOLOGICAL INFORMATION No data available for Ocean ACLOX White sheet. 13. DISPOSAL CONSIDERATIONS Incineration or landfill in accordance with local regulations. The cleaned packaging can be recycled or treated together with household refuse. Local regulations may impose specific requirements for treatment and/or reporting of the packaging wastes (e.g. as based upon EU packaging waste directive). 14. TRANSPORT INFORMATION Carefully load not fall and drop the product when transporting. Take any measures to prevent injury due to collapse of cargo piles. 15. REGULATORY INFORMATION ＊Japanese Regulations PRTR(Pollutant Release and Transfer Register) Law Chemical Substances ： Antimony and its compounds (I-No31) ＊European/International Regulations European Labeling in Accordance with EC Directives (data for Sb2O3) Hazard Symbols : XN Risk Phrases : R 40 Limited evidence of a carcinogenic effect. Safety Phrases : S22 Do not breathe dust. : S36/37 Wear suitable protective clothing and gloves. 16. OTHER INFORMATION The information set forth herein has been gathered from standard reference materials and/or Taiyo Chemical Industry Co., Ltd. test data. The information containing herein is based on the present state of our knowledge and is intended to describe our product from the view of safety requirements. It should not therefore be construed as guaranteeing specific properties. This product should be stored, handled and used in accordance with good industrial hygiene practices and in conformity with any legal regulation. Safe handling and use remain the responsibility of the customer.
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