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Material Safety Data Sheet Section 1. Chemical Product and Company Identification Common Name Supplier Acetic Acid Butyl Ester Pierce Chemical Company P.O. Box 117 Rockford, IL 61105 815.968.0747 N-Butyl Acetate Sequanal Grade 1-Butyl Acetate Not available. Not available. Pierce Chemical Company P.O. Box 117 Rockford, IL 61105 815.968.0747 Code MSDS# Validation Date 0020160 1870350 76 8/18/98 Synonym Trade name Material Uses Manufacturer Print Date 8/19/98 Responsible Name Company In Case of Emergency CALL CHEMTREC: 800.424.9300 OUTSIDE US: 202.483.7616 Section 2. Composition and Information on Ingredients Name CAS # % by Weight Exposure Limits 1) Acetic Acid Butyl Ester 100 Section 3. Hazards Identification Physical State and Appearance Emergency Overview Liquid. HIGHLY FLAMMABLE LIQUID AND VAPOR, VAPOR MAY CAUSE FLASH FIRE. HARMFUL IF SWALLOWED. MAY CAUSE SKIN IRRITATION. HIGHLY FLAMMABLE LIQUID AND VAPOR, VAPOR MAY CAUSE FLASH FIRE. HARMFUL IF SWALLOWED. MAY CAUSE SKIN IRRITATION. Absorbed through skin. Eye contact. Inhalation. Ingestion. Routes of Entry Potential Acute Health Effects Eyes Irritation of the product in case of eye contact: Not available. Skin Sensitization of the product: Not available. Hazardous in case of skin contact (irritant). Severe over-exposure can result in death. Skin inflammation is characterized by itching, scaling, reddening, or, occasionally, blistering. Inhalation Slightly hazardous in case of inhalation. May be fatal if inhaled. Ingestion Slightly hazardous in case of ingestion. May be fatal if swallowed. Potential Chronic Health Effects CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. Medical Conditions Repeated exposure to an highly toxic material may produce general deterioration of health by an Aggravated by Overexposure accumulation in one or many human organs. Overexposure Not available. /Signs/Symptoms See Toxicological Information (section 11) Continued on Next Page Acetic Acid Butyl Ester Section 4. First Aid Measures Eye Contact Skin Contact Page: 2/6 IMMEDIATELY flush eyes with running water for at least 15 minutes, keeping eyelids open. COLD water may be used. After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. COLD water may be used. Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Wash contaminated clothing before reusing. Allow the victim to rest in a well ventilated area. Seek immediate medical attention. DO NOT induce vomiting. Examine the lips and mouth to ascertain whether the tissues are damaged, a possible indication that the toxic material was ingested; the absence of such signs, however, is not conclusive. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention. Not available. Inhalation Ingestion Notes to Physician Section 5. Fire Fighting Measures Flammability of the Product Auto-ignition Temperature Flash Points Flammable Limits Products of Combustion Fire Hazards in Presence of Various Substances Explosion Hazards in Presence of Various Substances Fire Fighting Media and Instructions Protective Clothing (Fire) Flammable. 425.3°C (797.5°F) CLOSED CUP: 29°C (84.2°F). LOWER: 1.4% UPPER: 7.5% These products are carbon oxides (CO, CO2). Flammable in presence of open flames and sparks. Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. No specific information is available in our database regarding the product's risks of explosion in the presence of various materials. Flammable liquid, soluble or dispersed in water. SMALL FIRE: Use DRY chemicals, CO2, alcohol foam or water spray. LARGE FIRE: Use alcohol foam, water spray or fog. Wear MSHA/NIOSH approved self-contained breathing apparatus or equivalent and full protective gear. No additional remark. No additional remark. Special Remarks on Fire Hazards Special Remarks on Explosion Hazards Section 6. Accidental Release Measures Small Spill and Leak Large Spill and Leak Dilute with water and mop up, or absorb with an inert DRY material and place in an appropriate waste disposal container. Flammable liquid. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. DO NOT touch spilled material. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all sources of ignition. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities. Continued on Next Page Acetic Acid Butyl Ester Section 7. Handling and Storage Handling Storage Page: 3/6 Keep container tightly closed. Keep in a cool, well-ventilated place. Highly toxic or infectious materials should be stored in a separate locked safety storage cabinet or room. Section 8. Exposure Controls/Personal Protection Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Eyes Safety glasses. Body Lab coat. Personal Protection Respiratory Wear appropriate respirator when ventilation is inadequate. Hands Gloves. Feet Not applicable. Protective Clothing (Pictograms) Personal Protection in Case of Splash goggles. Full suit. Boots. Gloves. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. a Large Spill Product Name 1) Acetic Acid Butyl Ester Exposure Limits Consult local authorities for acceptable exposure limits. Section 9. Physical and Chemical Properties Physical State and Appearance Molecular Weight Molecular Formula pH (1% Soln/Water) Boiling/Condensation Point Melting/Freezing Point Critical Temperature Specific Gravity Vapor Pressure Vapor Density Volatility Odor Threshold Evaporation Rate VOC Viscosity Liquid. 116.16 g/mole C6 H12 O2 Not available. 126°C (258.8°F) -73.5°C (-100.3°F) 305.9°C (582.6°F) 0.875 (Water = 1) Not available. Not available. Not available. Not available. Not available. Not available. Not available. Odor Taste Color Fruity. Not available. Colorless. Continued on Next Page Acetic Acid Butyl Ester LogKow Ionicity (in Water) Dispersion Properties Solubility Page: 4/6 Not available. Not available. See solubility in water. Soluble in cold water, hot water. Physical Chemical Comments No additional remark. Section 10. Stability and Reactivity Stability and Reactivity Conditions of Instability The product is stable. No additional remark. Incompatibility with Various Reactive with oxidizing agents, acids, alkalis. Slightly reactive to reactive with moisture. Substances Hazardous Decomposition Products Hazardous Polymerization Not available. No. Section 11. Toxicological Information Toxicity to Animals Chronic Effects on Humans Other Toxic Effects on Humans Acute oral toxicity (LD50): 10768 mg/kg [Rat]. Acute dermal toxicity (LD50): >17600 mg/kg [Rabbit]. CARCINOGENIC EFFECTS: A4 (Not classifiable for human or animal.) by ACGIH. Hazardous in case of skin contact (irritant). Slightly hazardous in case of ingestion, of inhalation. Special Remarks on Toxicity No additional remark. to Animals Special Remarks on Chronic Effects on Humans Special Remarks on Other Toxic Effects on Humans No additional remark. To the best of our knowledge, the toxicological properties of this product have not been thoroughly investigated. Section 12. Ecological Information Ecotoxicity BOD5 and COD Biodegradable/OECD Mobility Not available. Not available. Not available. Not available. Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation Special Remarks on the Products of Biodegradation The products of degradation are less toxic than the product itself. No additional remark. Continued on Next Page Acetic Acid Butyl Ester Section 13. Disposal Considerations Waste Information Waste Stream Page: 5/6 Not available. Not available. Consult your local or regional authorities. Section 14. Transport Information DOT Classification DOT CLASS 3: Flammable liquid. Flammable liquids n.o.s. UN1993 Not available. Marine Pollutant Not available. Hazardous Substances Reportable Quantity Special Provisions for Transport TDG Classification ADR/RID Classification IMO/IMDG Classification ICAO/IATA Classification 2270 No additional remark. TDG CLASS 3: Flammable liquid. ADR CLASS 3: Flammable liquid A. IMDG CLASS 3.1: Flammable liquid (Low flash point). IATA CLASS 3: Flammable liquid. Section 15. Regulatory Information HCS Classification U.S. Federal Regulations HCS CLASS: Toxic. HCS CLASS: Irritating substance. TSCA inventory: Acetic Acid Butyl Ester TSCA 5(e) substance consent order: Acetic Acid Butyl Ester TSCA 8(d) H and S data reporting: Acetic Acid Butyl Ester TSCA 12(b) annual export notification: Acetic Acid Butyl Ester Clean water act (CWA) 307: No products were found. Clean water act (CWA) 311: No products were found. Clean air act (CAA) 112 accidental release prevention: No products were found. Clean air act (CAA) 112 regulated flammable substances: No products were found. Clean air act (CAA) 112 regulated toxic substances: No products were found. International Regulations WHMIS (Canada) WHMIS CLASS B-2: Flammable liquid with a flash point lower than 37.8°C (100°F). No products were found. EINECS DSCL (EEC) Not available. R11- Highly flammable. R25- Toxic if swallowed. R38- Irritating to skin. No products were found. No products were found. International Lists State Regulations Continued on Next Page Acetic Acid Butyl Ester Page: 6/6 California prop. 65: This product contains the following ingredients for which the State of California has found to cause cancer, birth defects or other reproductive harm, which would require a warning under the statute: No products were found. Section 16. Other Information Label requirements HIGHLY FLAMMABLE LIQUID AND VAPOR, VAPOR MAY CAUSE FLASH FIRE. HARMFUL IF SWALLOWED. MAY CAUSE SKIN IRRITATION. Health Fire Hazard Reactivity Personal Protection Hazardous Material Information System (U.S.A.) 1 National Fire 3 Protection 0 Association (U.S.A.) a 3 Health Fire Hazard 1 0 Reactivity Specific Hazard References Other Special Considerations Not available. No additional remark. Verified by Company. Printed 8/19/98. Validated by Company on 8/18/98. CALL CHEMTREC: 800.424.9300 OUTSIDE US: 202.483.7616 Notice to Reader To the best of our knowledge, the information contained herein is accurate. However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist.
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