853

1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 B Source Description Phase II ID No. EPA ID No. Facility Name Facility Location City State Unit ID Name/No. Other Sister Facilities Number of Sister Facilities Combustor Class Combustor Type Combustor Characteristics Capacity (MMBtu/hr) Soot Blowing APCS Detailed Acronym APCS General Class APCS Characteristics 853 LAD001890367 Dupont Dow Elastomers LaPlace LA HCl Recovery Unit None 0 HCl Production Furnace C T-Thermal, liquid injection, down fired, 48 MMBtu/hr, dual parallel units with common APCS 48 WQ/3STGHClABS/S/CWS WQ, LEWS Water spray quench, 3 stage HCl absorbers, vent scrubber, Dynawave caustic scrubber. Water used in 3-stage HCl and vent scrubbers; caustic used in Dynawave scrubber Liq Chlorinated liq. wastes Natural gas Nat gas used during start up and shutdown, but not during normal operations 1.5 120 20.5 90 HAF operation; Tier III for Cr, HCl, Cl2; Tier I for other metals 19 20 Hazardous Wastes 21 Haz Waste Description 22 Supplemental Fuel 23 24 Stack Characteristics Diameter (ft) 25 Height (ft) 26 Gas Velocity (ft/sec) 27 Gas Temperature (°F) 28 29 30 Permitting Status HWC Burn Status (Date if 31 Terminated) 1, source, 853 B 1 Cond Description 2 3 853C10 4 Report Name/Date 5 Report Prepare 6 Testing Firm 7 Testing Dates 8 Cond Dates 9 Cond Description 10 Content 11 12 13 853C11 14 Report Name/Date 15 16 17 18 19 20 C Source Emissions Survey of DuPont Dow Elastomers, HCl Recovery Unit Stack Risk Burn, April 1997, File Number 97-17A METCO Environmental METCO Environmental April 23-24, 1997 Apr-97 Risk burn, normal operating cond PM, metals, CO, D/F Report Prepare Testing Firm Testing Dates Cond Dates Cond Description Content 21 22 23 853C12 24 Report Name/Date 25 26 27 28 29 30 31 Source Emissions Survey of DuPont Dow Elastomers, HCl Recovery Unit Stack Permit Burn, April 1997, File Number 97-17 METCO Environmental METCO Environmental April 25-26, 1997 Apr-97 Trial burn test DRE, PM, Cr (HCl/Cl2 testing performed, but results later considered invalid due to analytical difficulties) Report Prepare Testing Firm Testing Dates Cond Dates Cond Description Content Source Emissions Survey of DuPont Dow Elastomers Halogen Acid Furnace Stack, September 1997, File Number 97-240A METCO Environmental METCO Environmental September 2-3, 1997 Sep-97 Supplemental trial burn test PM, HCl/Cl2 2, cond, 853 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 59 60 61 62 63 64 65 66 67 68 B Stack Gas Emissions C D E F G H I J K L M Comments Units 853C10 PM Antimony Arsenic Barium Beryllium Cadmium Chromium Lead Mercury Silver Thallium Sampling Train Stack Gas Flowrate O2 Moisture Temperature Antimony Arsenic Barium Beryllium Cadmium Chromium Lead Mercury Silver Thallium SVM LVM Particle Size Distribution 0.5-1 1-1.5 1.5-2 2-2.5 2.5-5 5-7.5 7.5-10 10-12.5 853C11 PM CO (RA) CO (MHRA) Chromium Chromium (Hex) Sampling Train Stack Gas Flowrate O2 Moisture Temperature Sampling Train Stack Gas Flowrate O2 Moisture Temperature Chromium E1 E1 E1 gr/dscf ppmv ppmv µg/dscm µg/dscm E1 gr/dscf µg/dscm µg/dscm µg/dscm µg/dscm µg/dscm µg/dscm µg/dscm µg/dscm µg/dscm µg/dscm 7% O2 R1 y n n n n n n n n n n 0.0031 9.47 0.303 4.5 0.016 0.352 10.18 6.4 0.29 0.436 21.5 R2 0.0046 8.24 0.255 23.75 0.017 0.09 24.8 3.2 0.27 0.78 16.9 R3 0.0036 9.6 0.36 3.43 0.02 0.11 21.4 3.4 0.41 0.42 17.5 Cond Avg 0.0038 nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd PM/metals E1 dscfm % % °F E1 E1 E1 E1 E1 E1 E1 E1 E1 E1 E1 E1 in microns % wt % wt % wt % wt % wt % wt % wt % wt µg/dscm µg/dscm µg/dscm µg/dscm µg/dscm µg/dscm µg/dscm µg/dscm µg/dscm µg/dscm µg/dscm µg/dscm y y y y y y y y y y y y nd nd nd nd nd nd nd nd 100 3 7980 4.5 4.6 90 8.0 0.3 3.8 0.0 0.3 8.6 5.4 0.2 0.4 18.2 5.7 8.9 nd nd nd nd nd nd nd nd 100 1.08 8426 4.5 4.3 89 7.0 0.2 20.2 0.0 0.1 21.0 2.7 0.2 0.7 14.3 2.8 21.3 nd nd nd nd nd nd nd nd 100 1.7 8287 4.3 4.4 89 8.0 0.3 2.9 0.0 0.1 17.9 2.9 0.3 0.4 14.7 2.9 18.3 100 8231 4.4 4.4 89.3 7.7 0.3 8.9 0.0 0.2 15.9 3.7 0.3 0.5 15.8 3.8 16.1 100 100 100 100 100 100 100 1.7 0.6 0.3 1.7 1 23.8 14.6 6.7 51.3 R1 y y y n n 0.0075 14 15.46 256.9 57.31 R2 0.0107 18.5 18.9 492.6 72.52 R3 0.0079 12.2 13.34 264.97 97.19 Cond Avg 0.0087 14.9 15.9 PM/chlorineE1 dscfm % % °F Chromium E2 dscfm % % °F E2 µg/dscm y 3, emiss, 853 8680 6.8 4.64 89 8948 6.7 4.95 90 8337 5.8 4.68 89 8655 6.4 8879 6.8 4.58 92 253.3 8560 6.7 4.53 93 482.3 8824 5.8 4.61 88 244.1 326.5 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 B Chromium (Hex) LVM POHC DRE Feedrate Emission Rate DRE POHC DRE Feedrate Emission Rate DRE POHC DRE Feedrate Emission Rate DRE 853C12 PM CO (RA) CO (MHRA) HCl Cl2 Sampling Train Stack Gas Flowrate O2 Moisture Temperature HCl Cl2 Total Chlorine C E2 E2 D µg/dscm µg/dscm E y y F G 56.5 253.3 H I 71.0 482.3 J K 89.5 244.1 L M 72.3 326.5 1,4-dichloro-2-butene lb/hr E1 lb/hr E1 % Carbon Tetrachloride lb/hr E1 lb/hr E1 % Chlorobenzene lb/hr E1 lb/hr E1 % > 197.14 0 99.999 > 202.3 0 99.999 > 223.78 0 99.999 > 587.5 0.004 99.999 > 588.4 0.003 99.999 > 643.1 0.003 99.999 > 190.9 2.65E-04 99.999 R1 > 186.3 4.94E-04 nd 99.999 > R2 0.0435 21.25 22.01 505.5 1.9 192.9 2.53E-04 99.999 R3 0.0384 19.99 20.74 504.3 1.7 Cond Avg 0.0431 26.2 28.8 E1 E1 E1 gr/dscf ppmv ppmv ppmv ppmv y y y n n 0.0474 37.39 43.57 529.6 2.2 PM/chlorineE1 dscfm % % °F E1 E1 E1 ppmv ppmv ppmv y y y 8470 6.1 8.4 107 497.6 2.1 501.7 8528 6.5 7.93 108 488.1 1.8 491.7 8556 6.6 7.5 107 490.3 1.7 493.6 8518.0 6.4 492.0 1.9 495.7 4, emiss, 853 B C D E F G H I J K L M N O P Q R S Feedstreams R1 F2 Total Total Total Total F2 Total Total F2 Total Total Total R2 R3 Cond Avg R1 R2 R3 853C10 Risk burn 48.36 50.63 50.07 nd nd nd Feedstream Number Feed Class Feed Class 2 Feedstream Description Total Feedrate Density Heat Content Thermal Feedrate Viscosity Ash Chlorine Antimony Arsenic Barium Beryllium Cadmium Chromium Lead Mercury Silver Thallium Selenium Nickel nd nd nd nd nd nd nd nd nd nd nd 7980 4.5 8426 4.5 8287 4.3 8231.0 4.4 nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd lb/hr kg/l Btu/lb MMBtu/hr cst % wt % wt ppmw ppmw ppmw ppmw ppmw ppmw ppmw ppmw ppmw ppmw ppmw ppmw F1 Liq HW HW Liq organic waste 4331.0 1.109 11167 48.36 6 0.0176 39.3 1.5 0.12 0.18 0.01 0.02 1.3 1.6 0.03 0.24 8.2 2.8 11.8 F1 Liq HW HW Liquid organic waste 4331.0 1.127 11690 50.63 6 0.0246 44.2 1.4 0.12 0.18 0.01 0.02 1.4 1.6 0.03 0.24 8.1 2.8 13.6 F1 Liq HW HW Liquid organic waste 4331.0 1.026 11560 50.07 6 0.0289 36.8 1.4 0.12 0.18 0.01 0.02 0.59 1.6 0.02 0.24 8.1 2.8 0.69 F1 Liq HW HW Liquid organic waste 4331.0 1.1 11140 48.25 6 0.0237 40.1 1.4 0.12 0.18 0.01 0.02 1.1 1.6 0.03 0.24 8.1 2.8 8.7 Gas Flowrate Oxygen dscfm % Feedrate MTEC Calculations Ash Chlorine Antimony Arsenic Barium Beryllium Cadmium Chromium Lead Mercury Silver Thallium Selenium Nickel SVM LVM 100 100 100 100 100 100 100 100 100 100 100 100 9 100 100 100 100 100 100 100 8 100 100 100 100 100 100 100 18 21.7 48388271 184.7 14.8 22.2 1.2 2.5 160.1 197.0 3.7 29.6 1009.6 344.8 1452.9 199.5 176.1 100 100 100 100 100 100 100 100 100 100 28.7 51540812 163.3 14.0 21.0 1.2 2.3 163.3 186.6 3.5 28.0 944.5 326.5 1585.9 188.9 178.4 33.9 43109044 164.0 14.1 21.1 1.2 2.3 69.1 187.4 2.3 28.1 948.9 328.0 80.8 189.8 84.3 100 100 100 100 100 100 100 100 100 100 100 100 11 mg/dscm ug/dscm ug/dscm ug/dscm ug/dscm ug/dscm ug/dscm ug/dscm ug/dscm ug/dscm ug/dscm ug/dscm ug/dscm ug/dscm ug/dscm ug/dscm 28.1 47679376 170.6 14.3 21.4 1.2 2.4 130.8 190.3 3.2 28.6 967.7 333.1 1039.9 192.7 146.3 100 100 100 100 100 100 100 100 100 100 100 100 9 21.7 48388271 92.3 7.4 11.1 0.6 1.2 160.1 98.5 1.8 14.8 504.8 172.4 726.4 199.5 176.1 100 100 100 100 100 100 100 100 100 100 100 100 8 28.7 51540812 81.6 7.0 10.5 0.6 1.2 163.3 93.3 1.7 14.0 472.3 163.3 792.9 188.9 178.4 100 100 100 100 100 100 100 100 100 100 100 100 18 33.9 43109044 82.0 7.0 10.5 0.6 1.2 69.1 93.7 1.2 14.1 474.4 164.0 40.4 189.8 84.3 100 100 100 100 100 100 100 100 100 100 100 100 11 853C11 Trial burn R1 R2 R3 Cond Avg R1 F2 Spike Spike Spike R2 F2 Spike Spike Spike R3 F2 Spike Spike Spike 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 F1 Liq HW HW Liquid organic waste 4895.4 F1 Liq HW HW Liquid organic waste 4903.6 F1 Liq HW HW Liquid organic waste 4947.0 5, feed, 853 F1 Liq HW HW Liquid organic waste 4877.5 Feedstream Number Feed Class Feed Class 2 Feedstream Description Feed Rate lb/hr T U V W X Y Z AA AB Cond Avg F2 Total Total Total 48.25 28.1 47679376 170.6 14.3 21.4 1.2 2.4 130.8 190.3 3.2 28.6 967.7 333.1 1039.9 192.7 146.3 Cond Avg F2 Spike Spike Spike R1 F3 Total Total Total R2 F3 Total Total Total R3 F3 Total Total Total Cond Avg F3 Total Total Total 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 42 43 44 45 46 47 48 49 50 51 52 53 54 55 56 57 58 6, feed, 853 B 9550 nd 9568 8773 9297 C E F G H I J K L M N O P Q R S Heat Content D Btu/lb nd nd nd nd nd 72.0 nd nd nd nd 8680 6.8 46.8 8948 6.7 46.9 8337 5.8 43.4 8655 6.4 45.3 8680 6.8 1.5 0.05 0.23 7.9 nd nd nd nd 1.6 0.01 0.24 8.2 nd nd nd nd 1.6 0.01 0.24 8.1 1.6 0.02 0.24 8.1 8948 6.7 72.7 6 0.041 910.43 51.8 1150256.6 1.4 0.12 0.17 0.01 0.02 1.3 nd nd nd nd nd nd nd nd nd nd 6 0.039 867.47 47.7 1060978.2 1.5 0.12 0.18 0.01 0.02 1 6 0.045 1009.78 48.4 1086074.1 1.4 0.12 0.18 0.01 0.02 0.95 6 0.042 929.23 49.3 1099103 1.4 0.12 0.18 0.01 0.02 1.1 72.8 Viscosity Ash Ash Chlorine Chlorine Antimony Arsenic Barium Beryllium Cadmium Chromium Chromium Lead Mercury Silver Thallium cst % wt g/hr % wt g/hr ppmw ppmw ppmw ppmw ppmw ppmw g/hr ppmw ppmw ppmw ppmw Gas Flowrate Oxygen Thermal Feedrate dscfm % MMBtu/hr 8337 5.8 100 100 100 100 100 100 100 100 100 100 9 226.0 220.0 100 11 232.4 100 170.7 11 236.7 166.6 100 100 100 100 100 100 100 100 100 100 100 100 100 10 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 Feedrate MTEC Calculations Ash Chlorine Antimony Arsenic Barium Beryllium Cadmium Chromium Lead Mercury Silver Thallium 60.90 76944399 208.1 17.8 25.3 1.5 3.0 193.3 223.0 7.4 34.2 1174.5 55.90 68365154 215.2 17.2 25.8 1.4 2.9 143.5 229.5 1.4 34.4 1176.3 65.70 70663707 204.6 17.5 26.3 1.5 2.9 138.8 233.8 1.5 35.1 1183.6 61 71991087 209 18 26 1 3 159 229 3 35 1178 232 186 mg/dscm ug/dscm ug/dscm ug/dscm ug/dscm ug/dscm ug/dscm ug/dscm ug/dscm ug/dscm ug/dscm ug/dscm 4817.7 4683.4 4735.1 SVM LVM ug/dscm ug/dscm 4817.7 4683.4 4735.1 853C12 R1 R2 R3 Cond Avg F2 Total Total R1 F2 Total Total Total R2 F2 Total Total Total R3 Total Feedstream Number Feed Class Feed Class 2 Feedstream Description Feed Rate Heat Content Viscosity Ash Ash Chlorine Chlorine nd 8470 6.1 423.0 8528 6.5 41.3 g/hr Btu/lb cst % wt g/hr % wt g/hr F1 Liq HW HW Liquid organic waste 22225906 8640 6 0.29 912.6 54.8 1153019.3 F1 Liq HW HW Liquid organic waste 2216789 8460 6 0.32 864.5 55.6 1057408.1 F1 Liq HW HW Liquid organic waste 2236928 9660 6 0.35 1006.6 49.3 1082673.3 8556 6.6 47.6 7, feed, 853 F1 Liq HW HW Liquid organic waste 2200000 8920 6 0.32 927.9 53.2 1097700.2 8518 6.4 43.2 59 60 61 62 63 64 65 66 67 68 69 70 71 72 73 74 75 76 77 78 79 80 81 82 83 84 85 86 87 88 89 90 91 92 93 94 95 96 97 98 99 100 101 102 103 104 105 106 107 108 109 110 111 112 113 114 115 116 423.0 41.3 47.6 Gas Flowrate Oxygen Thermal Feedrate dscfm % MMBtu/hr U V W X Y Z AA AB 46.8 46.9 43.4 45.3 100 100 100 100 100 100 100 100 100 100 226.0 100 5037.7 232.4 100 4854.2 100 100 100 100 100 100 100 100 100 100 100 100 236.7 100 4901.7 60.9 76944399.4 208.1 17.8 25.3 1.5 3.0 5011.0 223.0 7.4 34.2 1174.5 100 100 100 100 100 100 100 100 100 100 100 100 100 100 100 55.9 68365154.2 215.2 17.2 25.8 1.4 2.9 4826.9 229.5 1.4 34.4 1176.3 65.7 70663707.1 204.6 17.5 26.3 1.5 2.9 4873.9 233.8 1.5 35.1 1183.6 60.8 71991086.9 209.3 17.5 25.8 1.5 2.9 4903.9 228.8 3.4 34.6 1178.1 231.7 4931.2 T 59 60 61 62 63 64 65 66 67 68 69 70 71 72.5 72 73 74 75 76 77 8655 78 6.4 79 80 81 82 83 84 85 86 87 88 89 4739.6 90 91 92 93 94 95 96 4739.6 97 98 99 Cond Avg 100 101 102 F2 103 Total 104 Total Total 105 106 107 108 109 110 111 112 113 114 115 43.2 116 8, feed, 853 C D E F G H I J K L M N O P Q R S B 117 118 Feedrate MTEC Calculations 119 Ash 120 Chlorine 59.6 75328141 57.6 70504655 67.4 72452689 61.5 72775235 59.6 75328141 57.6 70504655 67.4 72452689 mg/dscm ug/dscm 9, feed, 853 T 117 118 119 120 61.5 72775235 U V W X Y Z AA AB 10, feed, 853 1 2 3 4 5 6 7 8 9 A Process Information B Units C Cond Avg 853C11 Combustion Temp Dynawave Scrubber pH Blowdown/feed C 1450 2.07 0.117 gal/lb 11, process, 853 A B PCDD/PCDF N Facility Name and ID: Condition ID: Condition/Test Date: DuPont LaPlace HAF 853C10 Risk burn, normal operating cond, April 23, 1997 I-TEF Wght Fact TEQ 1/2 ND 0.0035 nd 0.0110 nd 0.0045 nd 0.0058 nd 0.0108 nd 0.0037 nd 0.0005 0.0030 nd 0.0019 nd 0.0420 nd 0.0260 0.0094 0.0174 0.0008 nd 0.0042 0.0003 nd 0.0001 nd 4.50 0.1228 76.8 0.045 0.017 0.035 0.075 0.032 0.032 0.015 0.0075 0.0032 0.0032 0.0015 0.0005 0.0002 0.0000 4.60 0.0530 0.045 0.047 0.0023 0.0235 0.0225 0.0235 0.0750 0.0320 0.0320 0.0075 0.0450 0.0085 0.0175 0.057 0.047 0.0001 0.0047 0.0570 0.0235 0.03 0.0003 0.0150 0.0002 nd 0.0001 nd 0.0024 nd 0.0011 nd 0.0118 nd 0.0075 nd 0.0032 0.0032 nd 0.0008 nd 0.0005 nd 0.0001 nd 0.0000 nd 4.60 0.0326 96.4 0.015 0.012 0.015 0.0015 0.0012 0.0015 0.0075 0.0060 0.0075 0.0008 nd 0.0006 nd 0.0008 nd 0.014 0.012 0.01 0.012 0.027 0.043 0.031 0.039 0.056 0.019 0.024 0.012 0.019 0.014 0.019 0.012 0.0060 0.0060 0.0030 nd 0.01 0.005 0.0050 0.0025 0.0025 nd 0.007 0.0070 0.0050 0.0014 0.0012 0.0010 0.0001 0.0000 0.0043 0.0016 0.0195 0.0056 0.0019 0.0024 0.0012 0.0002 0.0001 0.0000 4.30 0.0441 TEQ 1/2 ND Total Full ND TEQ Full ND Run 1 Total TEQ Total Full ND Full ND 1/2 ND nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd nd 4.50 100.0 0.059 0.2455 0.1950 0.0002 0.0975 0.8410 0.0670 0.0084 0.0007 0.4205 0.0335 0.5200 0.1870 0.3480 0.0150 0.0520 0.0187 0.0348 0.0015 0.2600 0.0935 0.1740 0.0075 0.0760 0.1680 0.0038 0.0840 0.0380 0.0840 0.9690 0.0590 0.0010 0.0059 0.4845 0.0295 0.7450 0.0075 0.3725 0.0890 0.1160 0.2150 0.0089 0.0116 0.0215 0.0445 0.0580 0.1075 0.0440 0.0220 0.0220 0.0070 0.0070 0.0035 Run 2 Total TEQ Total Full ND Full ND 1/2 ND Run 3 Total 1/2 ND 0.0035 0.0050 0.0070 0.0060 0.0050 0.0060 0.0135 0.0215 0.0155 0.0195 0.0280 0.0190 0.0120 0.0060 0.0095 0.0070 0.0095 C D E F G H I J K L M N O P Q R TEQ 1/2 ND 0.0035 0.0025 0.0007 0.0006 0.0005 0.0001 0.0000 0.0022 0.0008 0.0098 0.0028 0.0019 0.0012 0.0006 0.0001 0.0001 0.0000 4.30 0.0228 Detected in train (ng/dscm) 2,3,7,8-TCDD TCDD Other 1,2,3,7,8-PCDD PCDD Other 1,2,3,4,7,8-HxCDD 1,2,3,6,7,8-HxCDD 1,2,3,7,8,9-HxCDD HxCDD Other 1,2,3,4,6,7,8-HpCDD HpCDD Other OCDD 2,3,7,8-TCDF TCDF Other 1,2,3,7,8-PCDF 2,3,4,7,8-PCDF PCDF Other 1,2,3,4,7,8-HxCDF 1,2,3,6,7,8-HxCDF 2,3,4,6,7,8-HxCDF 1,2,3,7,8,9-HxCDF HxCDF Other 1,2,3,4,6,7,8-HpCDF 1,2,3,4,7,8,9-HpCDF HpCDF Other OCDF 1 0 0.5 0 0.1 0.1 0.1 0 0.01 0 0.001 0.1 0 0.05 0.5 0 0.1 0.1 0.1 0.1 0 0.01 0.01 0 0.001 O2 (%) PCDD/PCDF (ng/dscm @ 7% O2) 1 2 3 4 5 6 7 8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24 25 26 27 28 29 30 31 32 33 34 35 36 37 38 39 40 41 TEQ Cond Avg 12, df c10, 853