CONTENT Sinopec Russia ru

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CONTENT Sinopec Russia ru Powered By Docstoc
					EXPORT PRODUCT
      CATALOGUE


(CATALYSTS, WHITE OIL, PETROLEUM

          COKE & WAX)




REFINERY & CHEMICAL PRODUCT EXPORT
             DIVISION
MARCH, 2010




              1
                                                           CONTENT

1. Oil Refining Catalyst................................................................ 5
  (1) Catalytic Cracking Catalyst ....................................................................................................... 5
        Residue Cracking Catalyst ...................................................................................................... 5
        Maximum Diesel Catalyst ....................................................................................................... 8
        Olefin-Reducing Catalyst ................................................................................................................. 9
        Special Catalyst for MGD Process .................................................................................................... 11
        Special Catalyst forARGG Process................................................................................................... 12
        Special Catalyst for DCC Process ..................................................................................................... 12
        Special Catalyst for MIP-CGPProcess............................................................................................... 13
  (2) Catalytic CrackingAdditive ................................................................................................................ 14
        Catalytic Cracking DesulphurizationAdditive ...................................................................................... 14
        Catalytic Cracking Gas-IncreasingAdditive......................................................................................... 15
  (3) Catalytic Reforming Catalyst............................................................................................................... 15
        Semi-Regeneration Reforming Catalyst ............................................................................................. 15
  (4) Hydroprocessing Catalyst .................................................................................................................. 17
        Hydrorefining Catalyst .................................................................................................................. 17
        Hydrorefining Catalyst for Clean Gasoline .......................................................................................... 18
        Catalytic Cracking Gasoline Selective Hydrodesulphurization................................................................... 18
        Hydrorefining Catalyst for Clean Diesel.............................................................................................. 19
        Diesel Ultra Deep Desulphurization Catalyst........................................................................................ 19
        Aviation Kerosene Hydroprocessing Catalyst....................................................................................... 20
        Lube Hydrorefining Catalyst ........................................................................................................... 20
        Lubricant Hydro-dewaxing Catalyst.................................................................................................. 21
        Paraffin Hydrorefining Catalyst........................................................................................................ 21
        Diene Selective Hydroprocessing Catalyst........................................................................................... 22
        White Oil Hydroprocessing Catalyst.................................................................................................. 22
        Hydrocracking Catalyst ................................................................................................................. 22
        Residue Hydro-demetallization Catalyst ............................................................................................. 23
        Residue Hydrodemetallization & Hydrodesuphurization Catalyst .............................................................. 24
        Residue Hydro-demetallization and Hydrodenitrogenation Catalyst............................................................ 24
        Reforming Prehydroprocessing Catalyst............................................................................................. 24
        Guard Catalyst ............................................................................................................................ 25

2. Polyolefin Catalyst .................................................................27
  (1) PE Catalyst – Gas Phase Process .......................................................................................................... 27
  (2) PE Catalyst – Borealis Process............................................................................................................. 29

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   (3) PE Catalyst – Slurry Process ............................................................................................................... 30
   (4) PPCatalyst – Granular Shape .............................................................................................................. 31
   (5) PPCatalyst – Spherical Shape.............................................................................................................. 33

3. Catalysts for Basic Organic Materials .................................34
   (1) Catalysts for Toluene Disproportionation and Transalkylation........................................................................ 34
   (2) VinylAcetate Catalyst ....................................................................................................................... 34
   (3)Acrylonitrile Catalyst......................................................................................................................... 35
   (4) Pd/C Catalyst for Hydropurification of TerephthalicAcid............................................................................. 35
   (5) Silver Catalyst for EO/EG .................................................................................................................. 35
   (6) Benzene and Ethylene Liquid PhaseAlkylating Catalyst ............................................................................. 36
   (7) Ethylbenzene Dehydrogenation Catalyst ................................................................................................ 36
   (8) Catalyst for Liquid-phase Selective Hydrogenation of Propyne and Propadiene in C3 Fractions............................... 36
   (9)Catalyst for Gas-phase Selective Hydrogenation ofAcetylene in C2 Fractions.................................................... 37
   (10)Catalyst for Selective Hydrogenation ofAcetylene and MAPD in front-end process ........................................... 37
   (11) Hydrogenation of Pyrolysis Gasoline ................................................................................................... 38

4. Other Catalysts .......................................................................39
   (1) PX Sorbent.................................................................................................................................... 39
   (2) Non-crystalAlloy Hydrorefining Catalyst ............................................................................................... 39
   (3) Special Molecular Sieve Catalyst.......................................................................................................... 39
   (4)Adhesive-Free 5ASmall Spherical Molecular Sieve .................................................................................. 40
   (5) C5/C6 Isomerization Catalyst.............................................................................................................. 40
   (6) High-Temperature De-sulfurization Catalyst ............................................................................................ 40
   (7) De-Chlorination Catalyst.................................................................................................................... 40
   (8): PACatalyst ................................................................................................................................... 41


Lube Base Oil ................................................................................................................ 42
White Oil........................................................................................................................ 44
Petroleum Coke ............................................................................................................. 51
Paraffin Wax ................................................................................................................. 52
  Liquid Paraffin Wax .................................................................................................... 52
  Fully Refined Paraffin Wax ........................................................................................ 53
  Semi-Refined Paraffin Wax ........................................................................................ 54
  Microcrystalline Wax .................................................................................................. 55
  Specialty Wax ............................................................................................................. 56
  Chewing Gum Special-Purpose Wax .......................................................................... 57




                                                                                                                                                            3
                                        Sinopec Catalyst Manual


Sinopec is the largest domestic producer and supplier of catalyst for oil refining and chemical purpose. Its main
products include: oil refining catalyst, polyolefin catalyst, basic organic material catalyst and other catalyst etc.
Besides meeting demands of domestic markets, products of Sinopec Catalyst are also exported to European,
American,Asian,African and other international markets.
Sinopec advocates the construction of an enterprise team in type of Service, Study and Intelligence. It pursues the
managerial philosophy of Quality the First and Service the Best and the enterprise spirit of Always Creative and
Forever Vigorous. It will put into effect the competition strategy of product innovation, production efficiency,
product diversity and producer development, in order to provide high-quality products and satisfying services for its
vast customers. Sinopec is willing to establish long-term strategic partnership with its vast customers home and
abroad, and to realize mutual progress and development.




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1. Oil Refining Catalyst
(1) Catalytic Cracking Catalyst
Residue Cracking Catalyst
ORBIT Series
Main purpose of ORBIT-3000 catalyst is to increase yield of gasoline and diesel oil in goal product. The following
technological measures are taken in preparation process of this catalyst: adopting composite molecular sieve to
endow this catalyst with both excellent coke selectivity and good activity stability; in production of ultra-stabilized
molecular sieve, through modifying technology and exploiting middle holes of molecular sieve, the catalyst is
suitable for cracking heavy oil macromolecules. With improved molecular sieve quality, it is effective to enforce
macromolecule-cracking ability by means of modifying carrier into active alumina.
Based on basic performances of ORBIT-3000 catalyst (high cracking activity of macromolecules, good coke
selectivity, suitable for heavy oil processing), ORBIT-3300 is a new-type RFCC catalyst successfully developed
through replacing active components. This catalyst is suitable for RFCC plants with large processing capacity but
low catalyst/oil ratio. Within flexible working range of the fractionator, debutanizer and gas compressor system, this
catalyst can be used without any revamp on the plant. Through adjustment of active components in preparation
process of ORBIT-3300, metal tolerance of the product has been improved for worse feedstock and uncertainties.
Aiming at processing high-vanadium feedstock from the Middle East and increasing total liquid yield, based on
ORBIT-3300, ORBIT-3600 catalyst is a new type RFCC catalyst successfully developed through optimizing
active components and modifying carrier. While improving performance of molecular sieve in preparation process,
carrier is also modified, components with heavy metal resistance are also added, thus heavy metal resistance
performance (especially vanadium) is effectively promoted; shape-selective zeolite component is also added to
increase LPG yield appropriately.
ORBIT-3600B catalyst is a kind of anti-vanadium olefin-reducing catalyst based on anti-vanadium catalyst
ORBIT-3600. Commercial results reveal that the catalyst has strong heavy oil cracking ability, high yield of light oil,
high octane number of gasoline, strong olefin-reducing ability etc.
In order to realize the objective of reducing olefin content in gasoline on the basis of anti-vanadium heavy oil
cracking catalyst ORBIT-3600, ORBIT-3600B has the following characters: through modification of Y-type
molecular sieve and blending with active components, on the premise of maintaining heavy oil cracking activity,
hydrogen transfer activity is strengthened to reach the goal of reducing olefin content in gasoline; acid distribution of
catalyst is also adjusted reasonably to reduce the generation of coke and dry gas.


ZC Series

On the basis of successfully developed new ―one exchange, one calcination‖ preparation technology and increased
crystallinity of ultra-stable molecular sieve, ZC series catalyst has been developed through modifying active
components, adjusting hole structure of carrier and gradient distribution of active catalyst components. Due to the
above modifying technologies, ZC series catalysts are of high activity and stability, excellent coke selectivity, strong
residue oil macromolecule cracking ability, high heavy metal resistance performance, high yield of high-value
product and low unit cost of catalyst etc.
ZC-7000 catalyst is especially suitable for heavy oil cracking installations that use VRDS residue oil and residue oil

                                                                                                                       5
as feedstock, where it is difficult for catalyst of high bulk density to fluidize. With this catalyst, material resources can
be extended; meanwhile yield of light oil can be increased.
ZC-7300 catalyst has higher activity than ZC-7000 catalyst, and is suitable for heavy oil cracking installations
using VRDS residue oil that is hard to be cracked. For installation of low catalyst/oil ratio, ideal product distribution
can also be achieved.
ZC-7000B is developed on the basis of ZC-7000, through treating with modification technology, olefin-reducing
ability is strengthened, and olefin content in gasoline can be reduced by 5~6 units.


DVR Series

DVR-1 RFCC catalyst is a specially formulated catalyst for catalytic cracking installations that use entire vacuum
residue oil as feedstock (abbreviated as VRFCC technology). VRFCC technology can further increase blending
ratio of residue oil in catalytic cracking process, and increase economic benefit of oil refining enterprises to the full
extent.
In order to meet the demand for blending various vacuum residue oils by large scale, the following technological
measures are mainly taken in the preparation process of DVR-1 catalyst: treating ultra-stable molecular sieve with
modification technology and exploiting large and middle holes of ultra-stable molecular sieve, which enables
DVR-1 catalyst to crack heavy oil macromolecules; treating carrier with activation technology to improve acid
distribution and hole distribution of carrier, so that cracking ability of carrier to residue oil macromolecule can be
enhanced effectively. Additive technology is adopted to improve heavy metal resistance performance (especially
nickel). Through optimization of production technology and post-treatment, regeneration activity and stability of
catalyst is improved. For most domestic existing cracking installations, without the need to revamp plants, this
catalyst has very broad spreading and application prospect in oil refining with large blending ratio of various residue
oils.
To meet the demand for improving product distribution and reducing olefin content in FCC gasoline, DVR-2
catalyst is a product suitable for VRFCC process, while maintaining olefin-reducing performance. Results of
industrial application reveal that on the premise of maintaining various performances of DVR-1 catalyst, DVR-2
catalyst can reduce olefin content in FCC gasoline as well.


CC-15 Series

CC-15 catalyst adopts REUSY molecular sieve as its main active component. The carrier has certain cracking
activity, middle bulk density, high strength and certain heavy oil cracking ability. It can be used in catalytic cracking
installations which use entire VGO or oil blended with less than 15% VR as feedstock. CC-15 can also be used in
RFCC installations fed with entirely paraffin based ATB, or with small amount of poor-quality CGO or DAO. It
has been commercially applied in nearly thirty domestic catalytic cracking installations, including FCC installations
fed with blended VTB and RFCC installations with entire ATB. CC-15 (M) catalyst can also increase octane
number of gasoline.
CHZ-4
CHZ-4 catalyst adopts new generation ultra-stable SRY molecular sieve as its main active component, which is
prepared by withdrawing aluminum and replenishing silicon with ―hydrothermal + chemical‖ method. SRY
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molecular sieve integrates advantages of molecular sieves prepared with hydrothermal and chemical method,
possesses excellent thermal and hydrothermal stability, more secondary pore and strong heavy oil cracking ability. It
has little non-framework aluminum inside with cleaning channels, therefore non-selective cracking reaction is
avoided to the most extent, and coke selectivity is especially excellent. SRY molecular sieve is a new generation
ultra-stable molecular sieve with international advanced level developed in the middle 1990s.
In order to meet the demand of nickel and vanadium resistance, and further enhance conversion ability to heavy oil,
kaolin earth with fine particle, large specific surface area and high activity is adopted as carrier, which is blended
with active alumina to enhance cracking ability of heavy oil. CHZ-4 catalyst has been widely used in ten sets of
domestic catalytic cracking installations of heavy oil. Under high blending ratio of residue oil, product distribution is
still very good.
CHN-1
CHN-1 is of excellent anti-alkali nitrogen performance, which has been specially developed for high content of
alkali nitrogen feedstock inside Sinopec.
CHN-1 catalyst also adopts new generation ultra-stable SRY molecular sieve as main active component, which is
prepared by withdrawing aluminum and replenishing silicon with ―hydrothermal + chemical‖ method. In order to
meet the demand of alkali nitrogen resistance and further enhance conversion ability to heavy oil, kaolin with fine
particle, large specific surface area and high activity is adopted as carrier, which is blended with active alumina to
enhance cracking ability to heavy oil.


CHV Series

CHV series catalyst adopts new generation ultra-stable SRY molecular sieve as main active component, which is
prepared by withdrawing aluminum and replenishing silicon with ―hydrothermal + chemical‖ method. SRY
molecular sieve has high silicon/aluminum ratio, little non-framework aluminum and good hydrothermal stability.
Meanwhile, it has excellent coke selectivity, isomerization performance and strong cracking ability to heavy oil.
Core technology of anti-vanadium catalyst is the setting of vanadium trap, and amount of traps is determined by the
vanadium content in processed feedstock. In order to improve cracking ability to heavy oil and anti-contamination
ability from heavy metal, active alumina is also introduced. Other special components can also be added if there is
need to increase yield of LPG or octane value. Under normal catalyst consumption, this catalyst can be used in
catalytic cracking installations of heavy oil containing 4000~10000 ppm vanadium on E-cat. Series of
anti-vanadium catalysts can be produced, and special catalyst can be tailored according to the practical situation of
customer’s installation.


DOCP, DOCR

This series of heavy oil cracking catalyst is mainly designed for various heavy oil catalytic cracking installations
where gasoline octane number is needed to upgrade. With such catalyst, 90# or higher grade gasoline can be
produced directly. It is especially suitable for heavy oil catalytic cracking installations which process paraffin based
feedstock.
ZRP-3 (RPSA) shape selective molecular sieve is introduced in DOCR catalyst as kernel active component, which
has high thermal and hydrothermal stability, C3= and C4= increasing ability and isomerization ability. Octane value
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of gasoline and yield of LPG can both be increased.
ZRP-5 shape selective molecular sieve is introduced in DOCP catalyst as kernel active component, which has stronger isomerization
ability than RPSA, and can transform straight chain gasoline into branch chain. So, octane value of gasoline can be increased, while yield
of light oil and LPG is basically not influenced.

While obtaining perfect products distribution, at the same time, improving FCC gasoline octane number, the series
catalysts are all applicable for processing blended heavy oil.


Maximum Diesel Catalyst

MLC-500, MLC-500ZA

MLC-500 heavy oil catalytic cracking catalyst is of high hydrothermal stability, strong anti-contamination ability
from heavy metal, high remaining activity, high mechanical strength and strong cracking ability under rigorous
conditions, and has prominent effect in increasing diesel/gasoline ratio. In commercial application, this catalyst can
process heavy feedstock well and increase yield of light oil. In conjunction with corresponding technology, yield of
diesel oil can be increased. With MLC-500 catalyst, by adopting multi-section feeding and selective cracking
technology, product quality can be improved, and octane value of gasoline can be increased.
Main design thought of MLC-500 heavy oil catalytic cracking catalyst is to enhance cracking ability for heavy oil,
to limit further cracking of intermediate fractions, and to make reasonable adjustment on matrix/zeolite ratio and
acid distribution. Main technological measures include: increase surface cracking activity of large and middle pores
and control activity of small pores; strengthen cracking ability to heavy oil through increasing conversion activity
and selectivity of the matrix; adopt ultra-stable Y molecular sieve and adjust its acid distribution to make full use of
its macromolecule cracking characteristic and limit its cracking function to intermediate fractions.
MLC-500ZA is a tailor made large bulk density catalyst specially developed for a 3 million t/a FCC plant of
Zhenhai Petrochemicals Branch. Feedstock of the installation is mainly VGO blended with about 10% coker gas
oil. On the premise of blending more residue oil, the product series can increase yield of diesel oil and octane value
of gasoline. MLC-500ZAcatalyst has high selectivity of LPG and gasoline with high octane value.


CC-20D Series

CC-20D is a maximum diesel FCC catalyst with high activity and coke selectivity etc. On the premise of ensuring
conversion ability to heavy oil, activity of large pores of carrier is increased, and high yield of light oil is achieved.
CC-20D series catalyst adopts complex molecular sieve preparation technology, varieties and ratio of PSRY                ,
REUSY and SRCY molecular sieves are adjusted, selective RPSA or ZRP-5 zeolite with different Si/Al ratio is
                                                                                      ,
also adopted. On customer’s demand, maximum diesel catalyst considering LPG octane value and anti-vanadium
ability can be produced.
CC-20DV is a maximum diesel catalyst considering anti-vanadium ability.
CC-20DF is a catalyst product specially designed for double-riser technology.
CC-200D
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                                                                                    ,
CC-200D is a kind of diesel oriented catalyst with mid bulk density. Yield of LPG anti-contamination from
vanadium and blending with residue oil are taken into consideration simultaneously.


   Olefin-Reducing Catalyst

GOR-C, GRV-C

                                                                                 ,
GOR-C olefin-reducing catalyst adopts modified Y molecular sieve, MOY as its main active component, which is
modified with unique oxide and endowed with excellent hydrogen transfer activity, fine coke selectivity and
excellent cracking ability to heavy oil. The catalyst has high activity and strength, which can realize selective
hydrogen transfer reaction and ensure effective utilization of hydrogen resource in feedstock and reasonable
distribution in product. This catalyst also has the ability to reduce olefin in FCC gasoline prominently by 10~15V%.
Combined with operation techniques, olefin content in FCC gasoline can be steadily controlled under 35V%, while
content of isomerized alkane and aromatics can be increased and yield of LPG keeps at a high level.
GRV-C is a kind of new type high-efficiency anti-vanadium olefin-reducing catalyst. This catalyst is composed of
active components and carrier with high cracking activity to heavy oil and good coke selectivity, which are specially
developed toward intermediate feedstock. Semi-synthesized carrier bonded with alumina is adopted to improve
anti-contamination ability of catalyst from heavy metal. PTI preparation technology of catalyst is developed to
improve interfacial adhesion between carrier and molecular sieve, and further increase anti-abrasion strength.
Cracking activity and hydrogen transfer activity are adjusted and appropriately matched to endow the catalyst with
both olefin-reducing function and strong cracking ability to heavy oil. AEP matrix is also adopted to adjust acid
distribution and pore distribution of catalyst to achieve good coke selectivity.


CDC

CDC is a brand-new chemically designed catalyst with gradient pore distribution and gradient acid center, which
makes it possible for heavy oil macromolecule to access active center and being of excellent desorbing/diffusing
ability. CDC catalyst possesses excellent activity and stability, profound conversion ability to heavy oil and high
hydrogen transfer activity. Coke can be reduced at the same time. Through formulation adjustment, it can increase
propylene content in product.As a new type FCC catalyst, it can meet various demands of oil refiners.


COR Series

                                                                                        ,
This series of olefin-reducing catalysts adopt modified Y molecular sieve, MOY as its main active component,
which is modified with unique oxide and endowed with excellent hydrogen transfer activity, fine coke selectivity
and excellent cracking ability to heavy oil. The catalyst has high activity and strength, which can realize selective
hydrogen transfer reaction and ensure effective utilization of hydrogen resource in feedstock and reasonable
distribution in product. This catalyst also has the ability to reduce olefin in FCC gasoline prominently by 10~15V%.
Combined with operation techniques, olefin content in FCC gasoline can be steadily controlled under 35V%, while
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content of isomerized alkane and aromatic hydrocarbon can be increased.
COR-C catalyst is suitable for catalytic cracking installation with non-paraffin based feedstock.
CORV is suitable for catalytic cracking installation with feedstock of heavy metal, especially vanadium.
CORH has excellent anti-contamination performance from metal.
CORS is of high yield of diesel oil and high octane value of gasoline.


DOCO

DOCO olefin-reducing catalyst is good for selective hydrogen transfer reaction, which can control the coke and dry
gas yield effectively and ensure liquid yield. This catalyst has the ability to reduce olefin in gasoline prominently by
10~11V% at the same time, and olefin content can be steadily controlled under 35V%, which can meet the
demand of new standard gasoline. This catalyst also has strong isomerization ability, and isomerization index
(isobutane to isobutene ratio in LPG) can be increased by 1.02~1.05%, isoalkane in gasoline can be increased by
8.09%, aromatic can be increased by 1.89%, which is very important to keep octane number.


GOR-II

Based on industrial applications of the first generation olefin-reducing catalyst, GOR-II is developed to meet the
demand of oil refining plants to improve product distribution and further enhance cracking ability to heavy oil.
GOR-II catalyst has the following characters. Effective match of selective hydrogen transfer activity and cracking
activity is ensured through performance improvement and blending of active components. Good selective
hydrogen transfer activity can ensure olefin-reducing effect to gasoline, while high cracking activity can increase
conversion with heavy oil. New type matrix is adopted to control pore distribution and increase medium pore
proportion to enhance heavy oil cracking ability, increase yield of diesel oil, and restrain coking at the same time.
Acid distribution of catalyst is adjusted properly to reduce coke and dry gas.


GOR-III

The third generation olefin-reducing catalyst, GOR-III, is developed to further improve olefin-reduction
performance. Through further modification of main active components, selective molecular sieve and matrix,
olefin-reducing margin and cracking ability is further enhanced, hydrothermal stability of catalyst is elevated, coke
selectivity and product distribution is improved. Industrial application result reveals: in comparison with the second
generation olefin-reducing catalyst, E-cat activity of GOR-III can be decreased by 3% more and octane value of
gasoline is elevated slightly.


RMS-8

In order to meet the increasingly diversifying demands of customers for product distribution, RMS-8 catalyst is a
new type residue FCC catalyst developed to increase gasoline yield and reduce olefin of gasoline. Commercial
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application result reveals that RMS-8 has strong cracking ability to heavy oil macromolecule, high gasoline yield,
good anti-contamination ability from heavy metal, and appropriate olefin reducing ability etc.


   Special Catalyst for MGD Process

RGD-1

RGD-1 is a catalyst of excellent cracking ability to heavy oil macromolecule. It can selectively restrain further
cracking of intermediate fractions and enhance secondary cracking of gasoline fraction, so that yield of diesel oil
and LPG in catalytic cracking installation can be raised at the same time. By adjusting density and strength of
molecular sieve active centers, hydrogen transfer reaction is increased appropriately, and olefin content in gasoline is
lowered. In its preparation process, the following measures are taken: through modification of kaolin, pores bigger
than 100 Å and smaller than 5 Å are increased to make carrier have good pore distribution gradient. Moderate
weak-acid big pores can crack macromolecule hydrocarbon, restrain secondary cracking of intermediate fractions,
                                                                                               .
and reduce coking. Moderate strong-acid small pores can further crack gasoline into LPG Introduction of metal
components in active centers adjusts acid strength properly, and enhances cracking degree of gasoline into LPG         .
Meanwhile hydrogen transfer ability in gasoline is elevated, which is favorable for reducing olefin content in
gasoline. Adoption of modified selective molecular sieve is favorable for increasing yield of LPG and octane value
of gasoline.


RGD-C

RGD-C catalyst has good industrial application effect on increasing yield of LPG and diesel oil. Modified and
composite ultra-stable molecular sieve is adopted in RGD-C catalyst, appropriate selective molecular sieve and
trapping components for metal contaminations are added, and content of middle-pore active components are
increased. This catalyst has strong conversion ability to heavy oil, strong anti-contamination ability from heavy
metal, good coke and dry gas selectivity. Less coke and dry gas can be achieved in reaction of gasoline under
rigorous condition. RGD-C can selectively crack gasoline to LPG with high yield of LPG and diesel oil.


CMOD Series

CMOD catalyst adopts multiple high-performance molecular sieves (ultra-stable Y molecular sieve, RPSA
molecular sieve etc) as its active components. It is produced with high solid content technology. With high activity
                                                                                              .
and strength, CMOD catalyst has prominent effect in increasing yield of diesel oil and LPG When yield of LPG
reaches 15~20m%, yield of diesel oil is basically maintained. CMOD catalyst has good vanadium resistance.
CMOD catalyst also has good basic nitrogen resistance, where large proportion coking gas oil can be processed.
CMOD-100 can tolerate vanadium over 10,000 ppm on E-cat.
CMOD-200 catalyst can tolerate vanadium 5,000~10,000 ppm on E-cat.

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   Special Catalyst for ARGG Process

RAG Series

RAG-1 catalyst is specially designed for ARGG technology. It is especially suitable for processing feedstock
blended with high content of residue oil, such as entire ATB, VGO blended with high proportion of ATB, VTB or
de-asphalt oil. In preparation process of RAG-1 catalyst, performance of carrier is specially improved to make its
                                                                                          TB
distribution of secondary pores more perfect according to the characters of A feedstock. Meanwhile
coordination and match between molecular sieve component and carrier performance are optimized. As a result,
RAG-1 catalyst has stronger conversion ability to heavy oil, better product selectivity and heavy metal resistance. Its
main characters are: stable structure, good pore distribution gradient, which makes molecules of various sizes,
especially macromolecules contact and react with active centers selectively and thoroughly. Macromolecules can
contain deposit of heavy metal. With high activity and good selectivity, its conversion ability to heavy oil and
anti-contamination ability from heavy metal nickel is very strong.
RAG-6 catalyst is also specially designed for ARGG technology, with performance of strong conversion ability to
heavy oil and heavy metal resistance. Its main characters are: It has stable structure, good pore distribution gradient,
which makes molecules of various sizes, especially macromolecule contact and react with active centers selectively
and thoroughly, meanwhile macromolecules can contain deposit of heavy metal. It has high activity, good
selectivity, especially strong conversion ability to heavy oil and anti-contamination ability from heavy metal nickel.
In comparison with RAG-1 catalyst, RAG-6 catalyst has larger pore size, higher activity and better heavy metal
(especially nickel) resistance. In addition, by adopting of new type selective molecular sieve in preparation process,
better selectivity is achieved.
RAG-7A is a catalyst with large bulk density, which is specially designed for the 600,000 t/a ARGG installation of
Gaoqiao Refinery where 50% vacuum residue oil is blended in. Besides possessing inherent high activity and
stability of RAG series catalyst, RAG-7A has high yield of LPG (especially propylene) and 90# gasoline with high
octane value.


   Special Catalyst for DCC Process

MMC-2, CIP-2

In order to meet the growing demand for propylene in market, based on special catalyst of original DCC-I
technology, MMC-2 is a new generation catalytic pyrolysis catalyst developed through modification of active
components, with which a higher yield of propylene and cracking ability to heavy oil can be achieved.
CIP-2 is a special catalyst for DCC-II catalytic pyrolysis technology. To meet the demand of high light olefin yield
with residue oil as blended feedstock, CIP-2 must possess high activity for heavy oil and restrain activity for
hydrogen transfer reaction. In preparation process of CIP-2, multi-function active components and other
modification technology are applied to endow CIP-2 catalytic pyrolysis catalyst with high cracking activity, high
stability, good olefin selectivity, high octane value of gasoline and strong anti-abrasion performance.
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Special Catalyst for CPP Process


CD002

Combining catalytic pyrolysis process (CPP) with matched catalyst CD002, under the reaction temperature of
560~650 ℃ light olefin, dominant in ethylene and propylene, can be produced with heavy petroleum hydrocarbon
            ,
as feedstock. Furthermore, by controlling reaction condition, yield ratio of ethylene to propylene can also be
adjusted to meet the demand change with flexibility. CD002 catalyst contributes to both high yield of light olefin
and high hydrothermal activity and stability. It can meet rigorous operation demand of catalytic pyrolysis
technology.
Special Catalyst for MIP Process


CR022

MIP is an FCC process that directly produces gasoline with low olefin content and high octane value. Its kernel
technology is to revamp existing FCC riser reaction system appropriately, and divide conventional single reaction
section into two reaction sections with different reaction temperature and reaction time. MIP technology makes
catalytic cracking reaction proceed in each reaction section controllably and selectively, and realizes the goal to
produce maximum isomerized alkane and FCC gasoline with low olefin content and high octane value directly.
CR022 catalyst is specialized for MIP technology. Industrial application result reveals that it has high heavy oil
cracking performance, good coke selectivity, high yield of light oil and prominent olefin-reducing function.


CRMI-2

CRMI-2 catalyst is specialized for MIP technology,which possesses the characters of high activity, high thermal
and hydrothermal stability and good coke selectivity. In conjunction with MIP technology, it can reduce olefin
content in gasoline, and maintain RON at the same time. CRMI series catalyst adopts preparation technology of
composite molecular sieves, variety and ratio of molecular sieves (PSRY or REUSY) are adjusted, and selective
molecular sieves (RPSA or ZRP-5) with different Si/Al ratio are adopted to increase yield of propylene on the
premise of maintaining heavy oil conversion and total liquid yield.


   Special Catalyst for MIP-CGP Process

CGP-1

MIP-CGP is an FCC technology with maximum isomerized alkane, higher yield of propylene and lower olefin
content in gasoline. CGP series catalyst is a special designed catalyst for the process. Considering practical condition
in specific Refinery and in conjunction with MIP-CGP technology, CGP-1 catalysts can guarantee olefin content in
                                                                                                                     13
catalytic gasoline to meet Europe II or Europe III emission standard, on the premise of maintaining the same
capacity of original installation, while octane value of gasoline is not lowered; yield of propylene (relative to
material oil) is over 7~8m%.




(2) Catalytic Cracking Additive

   Catalytic Cracking Desulphurization Additive

MS011

FCC gasoline is the main blending component of vehicle gasoline. To reduce sulfur content in catalytic gasoline is
one of the effective measures to meet new international gasoline standard. Sulfur-reducing additive MS011 can
effectively reduce sulfur content by 15~20m% in FCC gasoline, while not influencing distribution of products.
Catalytic Cracking Propylene-IncreasingAdditive


MP031

MP031 is developed to increase the propylene content in LPG aiming at the increasingly growing demand for
propylene in current market. Industrial application result reveals that under the same operating condition, with a
proportion of 4~8m% additive, yield of propylene (relative to feedstock) can increase by 0.5~0.8m% on the
premise of small increase in yield of LPG.


CHPA Series

CHPA is a kind of FCC additive to obtain high yield of propylene developed by RIPP. This additive adopts metal
modified ZSM-5 molecular sieve as active components, and is prepared with particular carrier technology. The
product has certain MAT activity without any influence to activity of the main catalyst. It can increase propylene
content in LPG (i.e. yield of propylene) while maintaining conversion rate and total liquid yield.




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   Catalytic Cracking Gas-Increasing Additive

CA Series

CA series additive is jointly developed by RIPP and Sinopec Catalyst Changling Division. Main products include
CA-1 catalytic cracking LPG-increasing additive, CA-2 catalytic cracking gasoline octane value-increasing
additive, CA-100 high-efficiency catalytic cracking LPG-increasing additive, CA-3 catalytic cracking
LPG-increasing additive of middle bulk density, CA-200 high-efficiency catalytic cracking gasoline octane
value-increasing additive etc. CA series catalytic cracking additives contain MFI shape selective zeolite and other
various molecular sieves as active components with strong cracking ability to heavy oil, strong isomerization ability,
good coke selectivity and heavy metal resistance. In catalytic cracking installation, it can be used together with
catalytic cracking catalyst at any ratio. It is an ideal catalytic cracking additive considering high yield of diesel oil and
gas olefins or production of gasoline with high octane value.




 (3) Catalytic Reforming Catalyst

   Semi-Regeneration Reforming Catalyst

CB Series

CB series catalyst is made of high-purity Al(OH)3 powder, by molding and sintering to make spherical or strip
γ-Al2O3 carrier, then infused with Pt and Re active components to get the catalyst product. Catalyst product is
available either in oxidative state or in reductive state. Reductive state catalyst can lessen unit start-up time.
Among CB series catalyst, CB-6, CB-7, CB-9, CB-60 and CB-70 are semi-regeneration reforming catalysts
developed by RIPP and produced by Sinopec Catalyst Changling Division. CB-6, CB-7, CB-9 catalysts have
spherical shape, and CB-60, CB-70 catalysts have strip shape. Re-to-Pt ratio of CB-6, CB-60 catalysts is 1, and
Re-to-Pt ratio of CB-7, CB-70 catalysts is higher than 1. The catalysts, such as CB-6/CB-7, CB-60/CB-70 adopt
two-section filling process in commercial application. In comparison with CB-6, content of precious metal Pt in
CB-7 catalyst is lowered by 30% while content of precious metal Pt in CB-60 catalyst is lowered by 20%. Reaction
performance evaluation and commercial application result reveal that CB series catalysts performance has
exceeded the level of imported reference catalyst with the characters of simple start-up procedure, short start-up
time, low hydrogen consumption etc. Catalyst can be adjusted to water and chlorine balance quickly and effectively
in normal running process. Regeneration is easy and safe by adopting a ―dry method‖ pressurized process, which
simplifies coke burning procedure, shortens coke burning time, lessens surface area loss and chlorine loss. Catalyst
performance can be recovered very well after regeneration. Catalyst can be regenerated either on-site or off-site, and
                                                                                                                          15
off-site regeneration has more advantage. CB series catalyst has been used more than sixty plants not only by
domestic customers, but also by overseas customers.


PRT Series

PRT-A, PRT-B, PRT-C, PRT-D are new generation strip multi-metal semi-regeneration catalytic reforming
catalysts developed by RIPP and produced by Changling Division. They have the characters of high carrier purity,
proper pore distribution, high strength and chlorine-holding ability. Selectivity and stability are further improved,
and carbon deposit velocity is decreased.
PRT-A and PRT-C are multi-metal catalysts of which Re-to-Pt ratio is 1, and PRT-B and PRT-D are multi-metal
catalysts of which Re-to-Pt ratio is higher than 1. Two-section filling process is adopted in commercial application,
for example, PRT-A and PRT-B are filled together, PRT-C and PRT-D are filled together. PRT-A/ PRT-B have the
same performance with PRT-C/ PRT-D basically. In comparison with CB-60/ CB-70 catalysts, conversion rate of
aromatic with PRT-A/ PRT-B and PRT-C/ PRT-D can be increased by over 5%, liquid yield can be increased by
over 1%, while carbon deposit can be decreased by over 18% under the same reaction condition. Catalysts activity,
selectivity and stability have all reached international advanced level with good regeneration performance and feed
adaptability, and excellent processing ability even for lean naphthenic straight-run oil and secondary processing oil.
In commercial application, continuous running time of PRT-A/PRT-B and PRT-C/PRT-D reached thirty months
and twenty-nine months respectively in the first period. PRT series catalyst keeps the characters of CB series for
applied process. Presently, PRT series catalyst has already been applied in ten plants.
Continuous Reforming Catalyst


GCR Series

GCR series catalyst is a new generation continuous reforming catalyst with high activity and hydrothermal stability
developed by RIPP.
The obvious characteristic of the new generation GCR series continuous reforming catalyst is its improved activity.
It is increased by 6 to 8 degrees centigrade in comparison with previous generation reforming catalyst applied
widely in the domestic units. At the same time, due to the adoption of new type catalytic materials, the ability of
anti-high temperature hydrothermal treating is improved significantly, the surface area decreasing rate is slowed,
and its life time is prolonged double times more than previous generation, which improves the economics sharply.
Moreover, the chlorine-holding ability is increased, and the injected chlorine quantity can be reduced to half, which
can inhibit the chloride corrosion of downstream process obviously. The mechanical strength of the product is
improved, with better anti-abrasion performance and less dust from circulation and transportation.
Within GCR series, GCR-100 is an economic catalyst with low Pt content, while GCR-100A has a slightly higher
Pt content. GCR series catalyst product is in reductive state with small sphere diameter of 1.4~2.0 mm.
The new generation GCR series continuous reforming catalyst is suitable for the reforming process aiming at
high-octane number gasoline, aromatic, and hydrogen with feedstock of straight-run naphtha, hydrocracking heavy
naphtha, pyrolysis gasoline, coking gasoline, catalytic gasoline, condensed oil etc.


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RC Series

RC series is a one of the newest generation, high selective and low carbon-depositing rate catalyst developed by
RIPP in recent years. RC011(PS-VI) was applied successfully in Zhenhai Refinery Branch. RC011 is an
economic catalyst with lower Pt content, and Pt content, while RC031(PS-VII)has a slightly higher Pt content.
RC series continuous reforming catalyst has obvious characteristics as follows: It has good selectiveness, with high
C5+ liquid yield, and increased aromatic and hydrogen yield. Carbon-depositing rate decreases obviously for more
than 20% under the same rigorous reacting condition. At the same time, good hydrothermal stability,
chlorine-holding ability and excellent mechanical strength are kept.
The newest RC series continuous reforming catalyst is suitable for the reforming process aiming at high-octane
number gasoline, aromatic, and hydrogen with feedstock of straight-run naphtha, hydrocracking heavy naphtha,
pyrolysis gasoline, coking gasoline, catalytic gasoline, condensed oil etc. Because of the low carbon-depositing rate,
it makes special sense for the capacity expanding and revamping, especially for the continuous reforming plants
with a constrained regeneration ability.




(4) Hydroprocessing Catalyst

   Hydrorefining Catalyst

RN Series

RN-1 catalyst has high hydro-denitrogen, hydro-desulfur and hydro-dearomatics activity, high activity stability and
wide adaptability to various feedstock with active component of Ni-W. It possesses high mechanical strength, low
bed pressure drop and good regeneration performance. In April 1987, the first industrial application of this catalyst
was carried out in Guangzhou Petrochemical Company, and great success was achieved. Its performance has
reached international advanced level.
It is applicable for hydrorefining of straight-run fraction of high-nitrogen and high-sulfur content, such as gasoline,
reforming feedstock, kerosene, jet fuel, straight-run diesel, vacuum gas oil, and lube oil.
It is applicable for hydrorefining of secondary processing fraction of high-nitrogen and high-sulfur crude, such as
viscosity-breaking gasoline, catalytic cracking diesel, coking diesel, coking gas oil, mixture of coking gas oil and
straight gas oil.
It is applicable for moderate and high pressure hydrocraking of high-nitrogen and high-sulfur crude, and
hydrodenitrogenation and aromatic saturating of feedstock, also applicable for moderate pressure hydro-upgrading
processing for refining section feedstock, such as hydrodenitrogenation of vacuum gas oil, residue catalytic
cracking diesel, feedstock from atmospheric line 3 and vacuum line 1.
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RN-2 is a trilobe-shape catalyst with active component of Ni-W. Besides possessing all the properties of RN-1,
RN-2 catalyst increases HDN activity by 15% in comparison with RN-1. In August 1993, RN-2 was industrially
applied in Changling Refinery.
RN-2 can be applied within all the range of RN-1, besides, it is especially suitable for hydrotreating of inferior
feedstock (such as vacuum gas oil, coking gas oil), and pre-refining of feedstock for moderate-pressure and
high-pressure hydrocracking.
RN-10 is a trilobe-shape catalyst with active component of Ni-W. RN-10 is an updated and substituted product for
RN-1, with higher hydro-denitrogen, hydro-desulfur and hydro-dearomatics activity. In April 1997, the first
industrial application of RN-10 was carried out in diesel hydroprocessing plant of Guangzhou Petrochemical
Company, and great success was achieved.
RN-10 can be applied within all the range of RN-1, besides, it is especially suitable for processing imported
high-sulfur fraction and domestic high-nitrogen fraction. It also give technical support to production enhancing.
RN-10B is a butterfly-shape catalyst with active component of Ni-W with high hydro-denitrogen, hydro-desulfur,
hydro-dearomatics activity, high anti-crush strength and bed porosity, and dramatically decreased bed pressure drop.
RN-10B can be applied with diversified feedstock as well.
RN-10B catalyst was applied in the diesel hydroprocessing plants of Sinopec Jingmen Branch and Sinopec Ji’nan
Branch successfully.
RN-10B catalyst can be applied to straight-run fraction (such as gasoline, kerosene, straight-run diesel etc.) and
secondary processing fraction (such as coking gasoline, coking diesel, coking gas oil, catalytic cracking diesel etc.).
RN-10B is especially suitable for the production expanding plants that need to decrease pressure drop, and the new
and old plants that need to improve the product quality.
RN-32 (including RN-32V) is a new generation high-performance hydrorefining catalyst developed by RIPP after
complete optimization with very high de-nitrogen and de-sulfur activity. Compared with RN-2 catalyst, under
reaction temperature of 375~385 ℃ hydrogen pressure of 8.0 Mpa and volume space velocity of 1.0 h-1,
                                        ,
de-nitrogen activity is increased by 20~28%, de-sulfur activity is increased by 82~136%, while maintaining good
activity stability. RN-32V catalyst has already been applied in Sinopec Ji’nan Branch, Sinopec Changling Branch
and Sinopec Jingmen Branch successfully.
RN-32 catalyst is suitable for preprocessing of hydrocracking feedstock, hydrotreating of gas oil, and catalytic
cracking feedstock. RN-32 (including RN-32V) can not only solve the processing problem of high-nitrogen oil, but
also give technical support to production expanding.


   Hydrorefining Catalyst for Clean Gasoline

   Catalytic Cracking Gasoline Selective Hydrodesulphurization

RSDS Series

RSDS series catalysts include RGO-2 guard catalyst and RSDS-1 selective hydro-desulfur catalyst, which can
meet clean gasoline specification of Europe-III and Europe-IV emission standard for sulfur content. RSDS series
catalysts have characteristics as follows: GRO-2 guard catalyst has weak acidity, high operation space velocity,
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strong low-temperature de-diene ability etc. In hydro-treating process of FCC gasoline, it can be used for long term
operation, with main catalyst protected. RSDS-1 selective hydro-desulfur catalyst has high hydro-desulfur activity,
low olefin and aromatics saturating activity, strong octane-holding ability, with good activity stability.
It is applicable for low-sulfur gasoline production with low octane loss when hydroprocessing high-sulfur content
catalytic cracking gasoline.
Catalytic Cracking Gasoline Hydro-isomerization Desulphurization & Olefin-reduction


RIDOS Series

Catalytic Cracking Gasoline hydro-desulfur olefin-reducing technology (abbreviated as RIDOS technology), uses
olefin-rich FCC gasoline as its feed, and separates gasoline into two fractions, light fraction and heavy fraction
according to product objective and feed property. Light fraction is extracted and refined with alkali to remove thiol,
while heavy fraction is hydro-desulfurized and olefin reduced and finally light fraction and heavy fraction are
blended to get full-fraction gasoline product. This technology can be utilized in production of clean gasoline with
sulfur content lower than 200 ppm, olefin content lower than 20 V%, and loss of anti-explosion index less than 2
units. It is recognized that RIDOS technology has reached advanced level in international like technologies.
Catalysts applied in RIDOS technology include RGO-2 guard catalyst, RS-1A hydro-refining catalyst and
RIDOS-1 hydro-isomerization catalyst. Characters of RIDOS series catalysts are proper shape with strength
increase and diffusion resistance decrease, high diene saturating performance, high hydro-desulfurization, olefin
saturating and isomerization activity, efficient coke restrain and long-term operation. Its desulfurization rate is over
90%, olefin saturating rate over 60%, with minor loss of octane value. RIDOS technology was applied on the
220,000ton/a hydro-treating process of FCC gasoline successfully in Yanshan Branch.
It is applicable for deep desulfurization and olefin-decreasing of olefin-rich FCC gasoline, and object product is
clean gasoline with low octane number loss.


   Hydrorefining Catalyst for Clean Diesel

   Diesel Ultra Deep Desulphurization Catalyst

RS-1000

RS-1000 is a new generation high-performance diesel ultra deep desulphurization catalyst developed by RIPP with
complete optimization. The active component of RS-1000 is Ni-W. It has excellent hydrodesulphurization and
hydrodenitrogenation activity, and hydrodesulphurization performance has reached international advanced level of
similar catalysts. Not only Europe III standard, but also Europe IV standard can be met when RS-1000 is used to
produce diesel by refineries, and diesel with 50 g/g or 10 g/g ultra low sulfur content is available under the
hydrorefining condition of 3.2~6.4MPa hydrogen pressure. RS-1000 was industrially applied in Sinopec Jingmen
Branch in 2005, and the product clean diesel met Europe III standard. Because there is great potential demand for
ultra low sulfur clean diesel in China, RS-1000 has broad application prospect.
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This catalyst can be used either in hydrotreating of diesel oil under high space velocity for low-sulfur diesel oil
meeting Europe III standard, or under normal hydro-refining condition for low-sulfur diesel oil meeting Europe IV
standard with good adaptability to various diesel oil, including high-sulfur and high-nitrogen diesel oil.
Inferior Diesel Deep Hydrotreating Catalyst


RIC Series

Developed by RIPP, containing metal components (Ni and W) and molecular sieve, RIC-1/RIC-2 catalysts are
used to raise cetane value and decrease density of diesel oil from FCC process with residue oil blended feedstock.
These catalysts have high saturating activity to aromatics, high cracking activity, good selectivity, high activity to
remove sulfur and nitrogen. They can improve cetane value by more than 8~12 units, decrease diesel oil density by
more than 0.035 g/cm3, and diesel yield is more than 95%. Clean diesel with less than 50ppm sulfur content can be
obtained, and the quality of inferior diesel oil such as FCC diesel oil can be upgraded.
RIC-1/RIC-2 catalysts are mainly used to upgrade the quality of inferior diesel such as FCC diesel. RIC-1/RIC-2
catalysts can either act as hydrotreating catalysts in the single catalyst and single section process, or act as
hydrocracking catalysts in the double catalysts and double sections process.


   Aviation Kerosene Hydroprocessing Catalyst

RSS-1A

Aiming at the character of straight-run aviation kerosene, RIPP developed a jet fuel hydro-dethiol patent technology
(RHSS technology) with a whole package of new hydro-dethiol RSS-1A catalyst and matched mild technological
process. Industrial application result reveals that, under mild technological condition (reaction temperature of
235~247 ℃ reaction pressure of 0.7~1.3 Mpa, volume space velocity of 4.0 h-1, and hydrogen/oil ratio of 30~55
             ,
V/V), RHSS technology has good de-thiol and de-acid effect, certain function to remove sulfur, raise smoking point
and upgrade color of product, and product performances meet the quality standard of 3# jet fuel. RSS-1A catalyst
has stable performance, and can meet the industrial demand for long-period operation. RSS-1A catalyst and RHSS
technology were applied in the jet fuel hydroprocessing plants of Shanghai Petrochemical Company and Zhenhai
Refinery etc.
RSS-1A catalyst is mainly used in the hydrorefining process of straight-run aviation kerosene, also it can be used in
olefin saturating of reformate raffinate aiming at solvent oil.


   Lube Hydrorefining Catalyst

RL-1

Lubricant hydrogenation RL-1 catalyst has excellent balance between hydrogenation function and acid cracking
                                                                                                                   20
function, and it has the function to improve viscosity-temperature performance of lubricant fraction effectively and
increase its viscosity index. The catalyst has high aromatics saturating activity, high de-sulfur and de-nitrogen
activity and certain isomerization ability. The catalyst has good activity stability, and its integral performance has
reached current international level. RL-1, a trilobe-shape strip catalyst, takes Ni-W as its active component. It has
wide adaptability to lubricant fractions from various feedstock. Experiment result reveals that RL-1 has good effect
in hydrogenation of lubricant fraction under both high and moderate pressure. RL-1 catalyst has been industrially
applied in Kelamayi Petrochemical Plant and Sinopec Jingmen Branch. From lubricant fraction of different feed,
API,AP II, orAP III base oil, 120~150BS bright oil, rubber filling oil and white oil etc. can be produced.
It is applicable for hydrogenation process under both high and moderate pressure, top grade lube base oil can be
produced from lubricant fraction of different feed.


   Lubricant Hydro-dewaxing Catalyst

RDW-1

RDW-1 lubricant hydro-dewaxing catalyst is a high-performance catalyst developed by RIPP and produced by
Sinopec Catalyst Changling Division. This catalyst is a selective cracking catalyst with shape selective molecular
sieve as its main component, and is applied in hydro-dewaxing of lubricant oil. It can crack high solidifying point
hydrocarbon into little molecular ones and separate them from oil, so as to decrease solidifying point. RDW-1, a
trilobe-shape strip catalyst, adopts shape selective molecular sieve with high crystallization degree, complex
co-extruding agent developed by RIPP, as well as particular preparation technology, which make cracking activity
of catalyst be adjusted elaborately. RDW-1 catalyst has the characters of high activity, high strength, long hydrogen
activating period. Compared with reference catalysts, RDW-1 catalyst can be used under higher space velocity.
Industrial result reveals that RDW-1 has good stability and good regeneration performance. RDW-1 catalyst has
been industrially applied in Kelamayi Petrochemical Company, 32# and 46# refrigerating machine oil, 45#
transformer oil, rubber filling oil and 150BS bright oil can be produced from Kelamayi section-9 thick oil.
It is applicable for hydro-dewaxing of diesel and lube fraction.


   Paraffin Hydrorefining Catalyst

RJW Series

RJW-1 is a trilobe-shape strip catalyst with Ni-W as its active component. It is suitable for hydrorefining of paraffin.
RJW-1 paraffin hydro-refining catalyst is of high hydrogenation and aromatics saturating activity, weak cracking
ability, proper pore structure, small diffusion resistance, favorable for distribution of gas and liquid in reactor. In 1992,
RJW-1 paraffin hydro-refining catalyst was applied on the 100,000 t/a paraffin hydro-refining plant of Jingmen
Petrochemical Company.
RJW-2 is jointly developed by RIPP and Sinopec Jingmen Branch, it is a trilobe-shape strip catalyst with Ni-W as
active component and suitable for hydrorefining of micro-crystalline paraffin. In 1994, it realized industrial
                                                                                                                         21
production in Changling Division, and was applied on the 50,000 t/a paraffin hydro-refining plant of Jingmen
Petrochemical Company in May 1995.
It is applicable for hydrorefining of diversified paraffin and micro-crystalline paraffin aiming at food grade product,
also suitable for hydrorefining of lube to improve the invariability of base oil.


   Diene Selective Hydroprocessing Catalyst

RDD-1

Considering the process and feedstock condition of PetroChina Liaoyang Company, RDD-1 catalyst is a
diene-selective hydrogenation catalyst developed by RIPP and produced by Changling Division, with
non-precious metal Ni as its active component. Industrial application result reveals that its activity and stability is
superior to imported products. Fast activity-losing problem of Ni based catalyst is solved. It has been under steady
operation for more than one and a half years on Liaoyang Synthetic Fiber Company’s 70,000 t/a pyrolytic gasoline
hydrogenation plant with maleic anhydride value in first-section product steadily under 10 mg/g.
Selective hydroprocessing technology (including its catalyst) can be applied not only in the refining of steam
pyrolytic gasoline, but also in the refining of other chemical feedstock widely, for example, the refining of catalytic
pyrolytic gasoline feedstock aiming at low-carbon olefin, the refining of high octane number component feedstock
aiming at aether such as MTBE, TAME etc., getting rid of diene from feedstock as the above so as to protect the
catalysts in the downstream process and prolong the catalysts lives.


   White Oil Hydroprocessing Catalyst

RLF-10W

RLF-10W is a kind of precious metal catalyst used in hydrogenation of white oil. It has excellent hydrogenation and
aromatics saturating performance, weak cracking performance, small diffusion resistance, proper shape and
strength. RLF-10 W is mainly used in section-2 hydrogenation in white oil production with two-section
hydrogenation technology. It is also used in process that has high demand for aromatic saturating performance.
It is applicable for producing food grade white oil of diversified viscosity grade.


   Hydrocracking Catalyst

RT Series

Main components of trilobe-shape strip RT-1 catalyst are Ni, W, and Y molecular sieve. RT-1 catalyst has certain
hydro-desulphurization, hydro-denitrogenation and aromatics saturating ability with good cracking selectivity and
                                                                                                                    22
anti-nitrogen stability. It has been successfully applied on industrial plants.
RT-1 catalyst can also be used in middle-pressure hydrocracking technology of heavy vacuum gas oil (RMC).
Main components of trilobe-shape strip RT-5 moderate-pressure hydrocracking catalyst are W, Ni, and Y molecular
sieve.
RT-5 catalyst has very strong hydrocracking activity and good anti-nitrogen stability with certain
hydro-desulphurization, hydro-denitrogenation and aromatics saturating ability. It has been successfully applied in
many domestic hydrocracking plants. Moderate-pressure hydrogenation upgrading technology combining RN-1
hydrorefining catalyst and RT-5 hydrocracking catalyst is regarded as one of the three great updated technologies in
the world for producing diesel oil with low sulfur and aromatics content byAmerican Oil & Gas magazine.
RT-5 catalyst can also be used in moderate-pressure hydrocracking technology of heavy vacuum gas oil (RMC).
RT-5 can be used in moderate-pressure hydrocracking technology of heavy vacuum gas oil (RMC), also it can be
used in high-pressure hydrocracking process.


RHC-1

RHC-1 catalyst was developed by RIPP with characters of high hydrogenation activity and high selective
ring-opening performance. It can decrease BMCI of product tail oil, and is especially suitable for the production of
top grade chemical feedstock under moderate pressure condition (trim pyrolysis feedstock of low BMCI and
reforming feedstock with high latent aromatics), and hydrocracking process of top grade transportation fuel with
ultra-low sulfur content. RHC-1 catalyst was applied in the 1.3 million ton/a hydrocracking plant of Sinopec
Yanshan Branch. The result revealed BMCI of tail oil decreased by about two units, which increased ethylene yield
of downstream steamed cracking ethylene process.


   Residue Hydro-demetallization Catalyst

RDM Series

RDM-1/RDM-2 are butterfly shape residue hydro-demetallization catalyst with Ni-Mo/Alumina as its
components.
RDM-1/RDM-2 has larger pore volume and size with higher hydro-demetallization (Ni, V) activity and excellent
active stability and certain de-sulfur and de-carbon residue ability at the same time. They can tolerate metal more
than 80% weight of themselves. These catalysts have already been applied in industrial plants successfully.
They are applicable for residue hydrotreating (RHT) process filled behind guard catalyst. The main function is to
remove Ni and V from residue and protect downstream catalysts.




                                                                                                                 23
   Residue Hydrodemetallization & Hydrodesuphurization Catalyst

RMS-1

RMS-1 is a butterfly shape residue hydro-demetallization and desulphurization catalyst with Co-Mo/Alumina as
components.
RMS-1 has larger pore volume, proper pore size and concentrated pore distribution, proper acidity and density etc,
with excellent hydro-desulphurization activity, hydro-demetallization (Ni, V) activity, higher metal containing ability,
higher de-nitrogenation and de-carbon residue ability at the same time. The catalyst has already been applied in
industrial plants successfully (running period reached eight months).
It is applicable in residue hydrotreating (RHT) process filled behind demetallization catalyst. The main function is to
remove sulfur, metal, carbon residue and nitrogen from residue.


   Residue Hydro-demetallization and Hydrodenitrogenation Catalyst

RSN-1

RSN-1 is a butterfly shape residue hydro-demetallization and denitrogenation catalyst with Ni-W/Alumina as
components.
RSN-1 has proper pore volume and concentrated pore distribution, proper acidity and density, and contain certain
quality of B-acid etc, with excellent hydro-denitrogenation, de-carbon residue, and de-sulphurization activity. The
catalyst has already been applied in industrial plants successfully (running period reached eight months).
It is applicable in residue hydrotreating (RHT) process filled behind demetallization and desulfurization catalyst.
The main function is to remove nitrogen, carbon residue and sulfur from residue.


   Reforming Prehydroprocessing Catalyst

RS Series

RS-1 is a kind of high-activity hydrorefining catalyst for naphtha under high space velocity. Due to its good
hydrogenation performance, high activity in sulfur and nitrogen removal and low aromatic hydrocarbon saturating
activity, RS-1 is especially adaptable for pre-hydrogenation of reforming feedstock under high space velocity. RS-1
is a trilobe strip shape catalyst based on Ni-W system and mixed with other additives with unique composition
structure. In industrial installation under high space velocity, this catalyst shows high hydro-desulfurization activity,
good activity stability and high mechanical strength.
With RS-1, straight-run gasoline can be processed to produce reforming feedstock under condition of 8~10 h-1high
space velocity and low hydrogen/oil ratio; naphtha with 25% coking gasoline content can be processed to produce
                                                                                                                      24
reforming feedstock under condition of 4~6 h-1high space velocity. Under the pressure (2.0 MPa) of reforming
pre-hydrogenation, hydrogenation of diversified feedstock from inside and outside of China like high-sulfur content
feedstock from Middle East, and pre-hydrogenation of nitrogenous feedstock (N<5 ppm) mixed with secondary
processing gasoline can both be realized to produce refined oil (S<0.5 ppm, N<0.5 ppm).
Aiming at the furious market competition, RIPP developed a higher activity reforming feedstock
pre-hydrogenation catalyst, RS-30, under high space velocity. It adopts alumina as carrier, Ni-W and other additives
as active components. It is a butterfly shape catalyst with unique composition structure and optimized preparation
technology. RS-30 has high activity in sulfur and nitrogen removal, low aromatic saturating activity, and high
mechanical strength. It is especially adaptable for pre-hydrogenation of reforming feedstock under high space
velocity, with strong market competence and broad industrial application prospect.
They are applicable for pre-hydrorefining of reforming feedstock.


   Guard Catalyst

RG Series

As crude oil is becoming heavier, feedstock quality in hydrogenation process is also becoming worse. Life of
hydrogen catalyst and operation period of installation is also shortened. RG-1 protector is just developed to solve the
above problem by RIPP.
In hydrogenation procedure of residue oil, large amount of impurities are found in the feedstock such as Fe, Ca and
coke-producing material. These impurities will deposit on the high-activity de-metal catalyst rapidly. As a result, the
bed pressure-drop will rise quickly. In order to delay the bed pressure-drop rising, a protective layer that can
accommodate large amount of Fe and coke should be placed on top of the de-metal catalyst layer. High activity is
not demanded for protective catalyst, because impurity atoms (such as Fe etc) are very easy to be removed. What is
needed is large space enough (including the porosity of bed layer of protective catalyst) to accommodate deposits.
Meanwhile the protector should have enough crushing resistance. Protector RG-10 series catalyst is a special-shape
catalyst with high strength and large pore volume, which is specially developed to solve the above problem. This
catalyst series include RG-10, RG-10A, RG-10B and RG-10C. They can be used individually or in combination
according to particular situation, and can be used as protector in other hydrogenation processes.
RG-10 is an inert guard catalyst with seven-hole ball shape filled on the top of reactor. The function is to block and
capture granule from residue, improve stream status of liquid and decrease pressure drop of bed.
RG-10A/B are Raschig ring shape guard catalysts with Ni-Mo/Alumina as components. Outside diameter of
RG-10A is about 6.0mm, while RG-10B is about 3.5 mm. The main function is to remove impurities such as Fe,
Ca and Na, as well as Ni and V to a certain extent from feedstock. RG-10A/B are filled after RG-10 usually.
From RG-10 to RG-10A, RG-10B, the activity increases from naught to existence, and granular reduces from big
to small. RG-10, RG-10A and RG-10B have excellent activity and granular combination to protect the main
catalyst.
The three guard catalysts have already been applied in industrial plants successfully.
They are applicable in hydrotreating process of inferior feedstock (heavy oil), and be filled on the top of reactor
subsection by subsection. The main function is to remove granule and impurities such as Fe, Ca and Na from
feedstock.
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RP-1

RP-1 is a kind of active support developed by RIPP. It is trilobe-shape strip and mainly contains W, Ni and alumina.
When a secondary processing oil (such as thermal processing gasoline, diesel oil and other gas oil etc.) is processed,
such oil is easy to produce coke under high temperature on the top of bed layer causing the bed pressure-drop to rise
rapidly because there are considerable alkene and diene in the oil products. If a layer of catalyst with low activity is
placed on top of the catalyst layer, diene can be hydrogenated rapidly and the top coking can be avoided. On
demand of the above hydrogenation technology, RP-1 active support is designed. RP-1 has excellent diene
saturating performance and certain hydro-desulfurization ability and de-nitrification ability. It also has high
mechanical strength with low price.




                                                                                                                     26
Polyolefin Catalyst
(1) PE Catalyst – Gas Phase Process

BCG Series

BCG (BCG-I and BCG-II) catalyst is a kind of Ziegler-Natta type high-efficiency PE catalyst with SiO2 as its
support. It is invented by BRICI. It is suitable for ethylene polymerization or co-polymerization in gas-phase
fluidized bed technology, especially those of Unipol technology. Its technological characters are listed below.
It has high activity, which is larger than 5 kgPE/gCat (Unipol industrial installation). It has very good fluidity. It has
good response to hydrogen regulation. It has good co-polymerization performance. The polymer produced has
high bulk density, which is larger than 0.35 g/cm3 (Unipol industrial installation). The polymer produced has good
particle shape, narrow particle size distribution and contains little fines.


SCG-1 Series

The SCG-1 catalyst is a new type of high-efficiency product used for gas-phase polyethylene plant with the Unipol process. The SCG-1
                                                                                                                        )
catalyst is a powder catalyst based on TiCl4-Mg Cl2 system. The SCG-1 series catalyst contains three types: SCG-1(Ⅰ , SCG-1(Ⅱ      ),
            ),
SCG-1(Ⅲ and can be used for producing full range density PE resin (from low to high). It means that the resin product of all low, all
medium and partial high densities ( HDPE with MI2.16≥8) can be produced by SCG-1(Ⅰ or SCG-1(Ⅱ SCG-1(Ⅲ is only used for all
                                                                                        )              ).          )
high density and narrow MWD PE product. The operating condition of reactor is the same as the original patent designing. The main
properties of SCG-1 are listed below.

It operates smoothly in the gas-phase fluidized reactor, the reaction is easy to control, and electrostatic sheeting and violent polymerization
caused by catalyst can thus be avoided. It is high in activity. It is quick in action and termination, better adapted to reactor at high load and
condensed mode running. The SCG-1 catalyst is sensitive to hydrogen adjustment, and its hydrogen response is superior to that of same
kind catalysts. The SCG-1 catalyst is high in copolymerizing power, and its response to copolymerizing monomers is superior to that of
same kind catalyst.

Compared with the imported catalyst, the SCG-1catalyst particles are better shaped, the particle size distribution is a
little narrower, and it has a suitable strength of bursting, no gathering, and adhesion of the particles, which manifest
good free-flowing property and easy to feed in the catalyst feeder.


SLC-G

The SLC-G is developed on the base of catalyst formulation. The commercial technology including special facilities and process/quality
control were self-exploited by Shanghai Leader, and the catalyst is made with technology magnified by Shanghai Leader. The SLC-G
catalyst is Ziegler -Natta polyethylene catalyst based on special silica. It can be used in ethylene co-polymerization and

                                                                                                                                             27
homopolymerization of gas-phase fluidized-bed. The technical characteristics of the catalyst are listed below.

It has high productivity, which is about 8-12 kgPE/gCat. It has very good response to hydrogen regulation. It has good response to
co-monomer. It has high settle bulk density on resin, which is larger than 0.35 g/cm3. With good free-flowing property, it can be applied in
intrinsic feeder system and software system of Unipol process. There is very good particle shape of resin, narrow particle size distribution
and few fines.


SCG-3/4/5 Series

The SCG-3 catalyst is used in Unipol process. SCG-3 catalyst is chrome-based, with medium molecular weight distribution
(MFR=50-90), used in the production of HDPE, and its properties, uses and method of use are the same as those of the imported B-300
(F-3) catalyst, however, because of improvement on the support and electron donor, its properties are somewhat improved.

The SCG-4 catalyst is used in Unipol process. SCG-4 catalyst is chrome-based, with medium molecular weight distribution
(MFR=50-90), used in the production of LLDPE, and its properties, uses and method of use are the same as those of the imported
B-400(F-4) catalyst.And, because of improvement on the support and electron donor, its properties are somewhat improved.

The SCG-5 catalyst is used for production of broad molecular weight distribution(MFR=75-150 ) HDPE in Unipol process, just the
same as the traditional imported G-300 (S-2) catalyst. Its performance indices and uses are exactly the same as those of the imported
G-300 (S-2) catalyst. It is a chromium (Cr) based catalyst for the production of all the brands of HDPE made with the original G-300
catalyst.


BCS Series

BCS Series (BCS01, BCS02) catalysts are a kind of slurry catalysts which are applicable to ethylene
polymerization with Unipol process and BP process. They can be used to produce a variety of PE grades, including
injection molding, extrusion molding and flow molding.
They have high activity within the range of 15~30kgPE/gCat in industrial process. The polymer produced has high
bulk density which is larger than 0.32g/cm3. They have excellent copolymerization performance and hydrogen
response. The melt flow index of polymer produced is adjustable between 0.2~80 g/10min.. The polymer
produced has good morphology and contains few fines.
The difference is that BCS01 catalyst adopts MgCl2 as its support and that BCS01 catalyst adopts SiO2 as its
support.


SLC-S

The SLC-S is developed on the base of catalyst formulation from bench-scale with autonomous intellectual property. The commercial
technology including special facilities and process/quality control were self-exploited by Shanghai Leader, and the catalyst is made with
technology magnified by Shanghai Leader.

The SLC-S is a slurry catalyst with some solids in the special mineral oil. It is a non-silica supported Mg/Ti catalyst and is designed to
replace traditional powder catalyst. SLC-S is used for producing narrow LLDPE, MDPE and HDPE on gas-phase fluidized-bed

                                                                                                                                        28
polyethylene process. Its main properties are shown below.

It has a high productivity, which can reach 25-38 kgPE/gCat. The chemistry and polymerization behavior are similar to those of powder
catalyst, but are not identical. SLC-S and powder catalyst require same C4=/C2= or C6=/C2=ratio for a given density, but the activity of
SLC-S is higher with comonomer and it has lower hexane extraction ratio. Lower SLC-S catalyst is required in reactor for same Al/Ti
ratio. Hydrogen response of SLC-S is 30% better than powder catalyst for same MI. Lower T2 is required by the reactor, and T2 level in
the reactor is 75% lower than powder catalyst. Moreover, there is less ash in the product and FAR is better.


SLC-i Series

The SLC-i catalyst is a new type of high-efficiency product used for gas-phase polyethylene plant of Innovene process. The SLC-i
catalyst is a powder catalyst based on TiCl4-Mg system.

The SLC-i series catalyst contains two types: SLC-i (LD) and SLC-i(HD), and can be used for producing full range of density PE resin
(from low to high). It means that the resin product of all low, all medium can be produced by SLC-i (LD). SLC-i(HD) is only used for all
high density and narrow MWD PE product. The operating condition of reactor is the same as Innovene original patent designing. The
main properties of SLC-i are listed below.

The SLC-i catalyst operates smoothly in the gas-phase fluidized reactor, the reaction is easy to control, and electrostatic sheeting and
violent polymerization caused by catalyst can thus be avoided. It is high in activity, about 6-8.5 kgPE/gCat. It is quick in action and
termination, better adapted to reactor at high load and condensed mode running. The SLC-i catalyst is sensitive to hydrogen adjustment,
and its hydrogen response selectivity is superior to that of same kind catalysts. It is high in copolymerizing power, and its response to
copolymerizing monomers is superior to that of same kind catalyst.

Compared with the imported catalyst, the SLC-i catalyst particles are better shaped, the particle size distribution is a
little narrower, and it has a suitable strength of bursting, no gathering, and adhesion of the particles, which manifest
good free-flowing property and easy to feed in the catalyst feeder.




(2) PE Catalyst – Borealis Process

SLC-B

SLC-B is a newly developed catalyst by Shanghai Leader. This catalyst can be used to produce PE product with bimodal MW
distribution in PE plant.

SLC-B catalyst can produce film, pipe, etc. Its activity is ≥15 kgPE/gCat. The average particle size is around 35-40 m. The settle bulk
density is about 0.38-0.46 g/cm3.




                                                                                                                                     29
PE Catalyst – Slurry Process

BCH Catalyst

BCH catalyst is a kind of high-efficiency PE catalyst applicable to stirred tank type slurry PE process. It is used in almost all the Mitsui
technology PE installations in China. It was invented by BRICI, and suitable to produce HDPE product.

It operates easily in the PE installations because of its smooth kinetic curve and its good hydrogen response property. It has high activity,
which is larger than 25 kgPE/gCat.. The catalyst has good co-polymerization performance. The polymer produced has good
morphology, narrow particle size distribution and contains few fines.




BCE Catalyst

BCE catalyst is a new kind of high-efficiency PE catalyst aimed to produce high grade PE product in slurry process. It can be used to
produce a variety of HDPE and MDPE products including the pipe material of PE80, PE100.

      It has high activity, which is larger than 25 kgPE/gCat.. It has good co-polymerization performance with less oligomer. The
hydrogen response property is good and the bulk density of polymer is larger than 0.38 g/cm3 , which is much higher than that of the
same kind of catalyst. Thus the load of the reactor can be enhanced easily. The polymer produced has good morphology, narrow particle
size distribution and contains few fines.All properties of BCE have exceeded or reached the level of imported catalyst.




NT-1

NT-1 catalyst is a new kind high efficiency supported catalyst. Its activity is larger than 600 kgPE/gTi. The bulk
density of the polymer produced is larger than 0.30g/cm3. It has good particle shape and good co-polymerization
performance etc. It is suitable for co-polymerization of ethylene with hexene and other α-olefins, and it shows
excellent co-polymerization performance. The catalyst has very good response toward hydrogen regulation.




                                                                                                                                         30
  PP Catalyst – Granular Shape

N Series

N series (N-I, N-II, N-III) catalyst are new generation high-efficiency polypropylene catalysts developed by BRICI.
They are widely used in Hypol process, Spheripol Process, successive gas-phase process and batch bulk process.
Several brands can meet demands of various customers. The technological characters are listed below.
                                                                                                        ,
They have high activity, which is larger than 50 kgPP/gCat (liquid phase bulk polymerization, 70℃ two hours).
They have good response towards hydrogen regulation, and the melt flow index of polymer produced with it is
adjustable between 0.2~40 g/10min. They have adjustable stereo-specific ability, and the polymer produced with it
has high and adjustable isotacticity. They have good co-polymerization performance. The polymer produced with it
has high bulk density, which is larger than 0.46 g/ cm3. The polymer produced with it has good particle shape, good
fluidity, and contains few fines. The polymer powder produced with this catalyst has good stability (aging and
radiation resistance). The PP resin produced with it has excellent mechanical property.


NG

NG catalyst is particularly designed for the Innovene process. And the PP resin of various brands can be produced. It has been applied on
several industrial installations successfully. Its main technological characters are listed below.

                                                                                                 ,
It has high activity, which is larger than 55 kgPP/gCat (liquid phase bulk polymerization, 70℃ two hours). It has good response towards
hydrogen regulation, and the melt flow index of polymer produced with it is adjustable between 0.2~40 g/10min. It has high
stereo-specific ability, and the polymer produced with it has high isotacticity. It has good co-polymerization performance. The polymer
produced with it has high bulk density, which is larger than 0.46 g/ cm3. The polymer produced with it has good particle shape, good
fluidity. The PPresin produced with it has excellent mechanical performance.




NA

NAcatalyst is a new kind of granular PP catalyst. It has high activity and high impurity resistance. It has good morphology, high specific
surface area. It has adjustable stereo-specific ability. It has high sensitivity to hydrogen regulation, stable release of activity and good
co-polymerization performance. There are few fines in the catalyst and the polymer produced with it. The catalyst can be used in
production of impact-resistant co-polymer. It has already been used in producing high-speed BOPP resins and impact-resistance
copolymers in the Hypol process. The main properties of NAcatalyst are shown below.

                                                                                                  ,
    It has high activity, which is larger than 45 kgPP/gCat (liquid phase bulk polymerization, 70℃ two hours). It has good response
towards hydrogen regulation, and the melt flow index of polymer produced with it is adjustable between 0.2~40 g/10min. It has
                                                                                                                                        31
adjustable stereo-specific ability, and the polymer produced with it has an adjustable isotacticity. It has good co-polymerization
performance. The polymer produced with it has high bulk density, which is larger than 0.46 g/ cm3. The polymer produced with it has
good particle shape, good fluidity. The PP resin produced with it has excellent mechanical performance.


ND Catalyst

ND catalyst is a new kind of PP catalyst with new internal electron donor. It has excellent properties and can be used in a variety of PP
installations. It has super high activity which is about 30% higher than that of the same kind of catalyst. The isotacticity index is easy to
adjust. The hydrogen response performs variously. Series inner donors correspond to series hydrogen responses, from low to high, to
meet different conditions. The distribution of molecular weight of polymer is broad and the polymer produced has both a good
mechanical property and a good manufacturing property. The polymer produced has good morphology and contains few fines.




YS Series

YS 841/842 polypropylene catalyst is gray brown crystal powder. Its activity is larger than 40 kgPP/gCat. It has
good particle shape and cavity structure. It has excellent polymerization kinetic behavior, which is favorable for the
operation and control of industrial polymerization process. It is suitable for PP installations of slurry process, Hypol
process and batch bulk process. The polymer produced with it shows a bulk density about 0.42~0.45 g/cm3. The
main technological indexes of the catalyst have reached the international standard of the similar catalysts.




                                                                                                                                         32
  PP Catalyst – Spherical Shape

DQ Series

DQ catalyst is a new generation spherical high-efficiency catalyst developed by BRICI.. It is suitable for production
of mono-polymer, random co-polymer and impact co-polymer. The result of industrial application of it
proves its excellent performances. It can be used in production of co-polymer with high ethylene content,
the ethylene content can reach 15wt.% easily. The impact co-polymer SP179 produced with it has high impact
strength.. It is widely used in Spheripol Process, Hypol Process and batch bulk polymerization process.
It has high activity, which is larger than 50 kgPP/gCat (liquid phase bulk polymerization). It has longer life of active
centers, which is larger than 6hours. It is sensitive to hydrogen regulation, and the melt index of polymer produced
with it is adjustable between 0.2~150 g/10min. The polymer produced with it has high and adjustable isotacticity.
The polymer produced with it has high bulk density, which is larger than 0.47 g/cm3. The catalyst and the polymer
produced with it are all in the spherical shape, and the particle size can be adjusted appropriately on demands. The
polymer produced with it has excellent performances.
The catalyst has many brands, and demands of various customers can be met. DQ-Ⅲ can be used to produce
common impact co-polymer and that DQ-V-01 is used to produce high ethylene content and super high
impact production such as SP179 in Spheripol Process. DQ-Ⅳ is usually used to produce mono-polymer, its
small particle size is helpful to improve the load of production. DQ-V-02 is used to produce the production with
high melt flow rate.




HDC

      HDC is Ziegler-Natta carrier-type high-efficiency catalyst which belongs to the fourth generation. It has the characters of high
activity, long life and high impurity resistance etc. The catalyst has good co-polymerization performance. The polymer produced with it
has a high isotacticity. The average particle size of the polymer produced with it is around 0.8~5.0 mm, and the polymer particle is in the
spherical shape. There are few fines contained in the products.




                                                                                                                                       33
3. Catalysts for Basic Organic Materials
(1) Catalysts for Toluene Disproportionation and Transalkylation

HAT-095, HAT-096, HLD-001

The catalysts have been mainly used in the process for disproportionation & transalkylation of toluene and C9
                                          T
aromatics to benzene and mixed xylenes. HA series catalysts have exhibited the following advantages.
It has high space velocity, low initial reaction temperature, high activity and good stability. It is capable
of processing high C10 with a content up to 10% in the combined feed. This offers the flexibility to
process feedstock and also makes heavy aromatics efficiently converted to xylenes. The addition of C10A
into the feed restrains indane formation. As a result, the first cycle lengths of the catalysts commercially
reach 4 years. Thus, the catalyst service life remains longer. The above advantages have allowed our
clients to utilize low value aromatics available to maximize benzene and mixed xylenes.




Vinyl Acetate Catalyst

CTV Series

They are the palladium-based catalysts used for the gas phase acetoxylation of ethylene to vinyl acetate. The
highlights of CTV series catalysts are listed below.
It has high activity(8-10 t/m3•d). It has high selectivity. It has long service lifetime (more than 2 years). It can be
used as a drop-in catalyst in the existing industrial plant.




                                                                                                                    34
(3) Acrylonitrile Catalyst

MB-98, CTA-6, SAC-2000,SANC-05, SANC-06,, SANC-08,

The catalyst is mainly used in ammoxidation of propylene to acrylonitrile. The technical features of the catalysts are
listed below.
A single pass yield of AN ≥80%. Good adaptability, which makes it possible to use the catalyst as a drop-in one
with no equipment revamp. The catalyst can operate at high WWH (about 0.070~0.088 h-1), C3H3:NH3:Air
(mol)=1:1.15~1.20:9.2~9.8 and temperatures 425~440 ℃ And it has good stability.
                                                       .



 (4) Pd/C Catalyst for Hydropurification of Terephthalic Acid

CTP Series

CTP series catalysts are the carbon supported palladium (Pd/C) catalysts used for hydropurification of terephthalic
acid. Various physical specifications of CTP series Pd/C catalyst are similar to those of the counterpart catalysts in
the market. Their processing capacity can be 40 kgPTA/gCat.
CTP-IV Pd/C catalyst adopts more advanced preparation technology. The distribution and dispersion of active
components are more reasonable.



 (5) Silver Catalyst for EO/EG

YS Series

The integrated carrier production, catalyst preparation, analysis testing, the production plant of the catalyst with
capacity of 400 t/a were constructed through many years research and development in Beijing Yanshan. The
performance indexes of the catalyst have reached international advanced level in its high activity. It has been widely
used in EO/EG plants.
It has high initial selectivity. The initial selectivity is between 80-83% depending on the plants operation. It has high
activity. The initial temperature is around 220-230 ℃depending on production load. The space-time yield can reach
maximum 280 gEO/h.l, which makes it one of the best catalysts in commercial application. It shows extraordinary
stability. It is quite stable with slow declined speed in selectivity and slow decay in activity. And it can be used for
                                                                                                                      35
2-5 years in commercial plant application. The selectivity in later stage is normally over 78%.


 (6) Benzene and Ethylene Liquid Phase Alkylating Catalyst

AEB-2

AEB-2 alkylate catalyst possesses the characteristics of high activity, good selectivity in ethyl-benzene and stability.
This catalyst not only can be used in alkylating reaction of benzene and multi-ethylbenzene in liquid phase, but also
be used in alkyl transfer reaction of benzene and multi-ethylbenzene in liquid phase.
AEB-6
AEB-6 can be used for alkylating benzene and ethylene in liquid phase. It possesses excellent alkylating activity,
good ethyl-benzene selectivity and long time activated stability. It’s properties have reached advanced level in the
world. AEB-6 adopts compound material of nanometer molecular sieve as main activated composition to improve
catalyst activity. And the catalyst usage amount is greatly reduced. When the temperature is 250 ℃ the pressure is
                                                                                                       ,
                                            -1
4.0 Mpa, liquid benzene space rate is 3 h , and the molecular ratio of benzene/ethylene is 12, good result can be
achieved with AEB-6. The ethyl-benzene selectivity was ≥92%, ethylation selectivity was ≥99%, and ethylene
translation ratio was 100%.




 (7) Ethylbenzene Dehydrogenation Catalyst

GS-08, GS-10

The catalyst is mainly used in dehydrogenation of ethylbenzene to styrene. It can also be used in dehydrogenation
of diethyl benzene to divinylbenzene. GS dehydrogenation catalysts have the following features.
It offers high activity at low reaction temperature. It provides high selectivity (the styrene selectivity≥96.5%). It has
long service lifetime, stability and adaptability.



 (8) Catalyst for Liquid-phase Selective Hydrogenation of
Propyne and Propadiene in C3 Fractions

BC-L-83

With the catalyst, propyne and propadiene in C3fractions can be effectively removed to meet the requirements of
                                                                                                                      36
ethylene units, with slight increase in propylene yield. By now the process and catalyst have been already applied to
more than 10 units in China, as well as a number of overseas ethylene units each of a capacity of over 600 thousand
MTA.
It offershigh activity, selectivity, and stability, while less polymers formed. It gives us longer regeneration cycle,10
months above under normal operational conditions. Catalyst life time longer than 5 years. It offers advanced
single-stage liquid-phase hydrogenation process, featuring less equipment, lower investment and more operation
convenience, as compared with the conventional two-stage process. It has high liquid space velocity, hence low
consumption of catalyst. It gets low consumption of energy. As the inlet temperature of the reactor ranges from 25℃
to 45℃,no propylene refrigeration is necessary.
Its physical properties are listed below. It has an appearance of yellowish gray granules of Φ2.5-5mm. Its bulk
density is 0.8-0.9g/ml. Its composition is Pd/Al2O3. Its crushing strength is about 50-100N/granule.




(9)Catalyst for Gas-phase Selective Hydrogenation of Acetylene
in C2 Fractions

BC-H-20A/B

Hydrogenation catalyst is one of the keys for preparing high purity ethylene. The catalyst for gas-phase
hydrogenation of acetylene in C2fractions, has been spreading for use in the country’s large and medium ethylene
units, with satisfactory result.
Its features is listed below. BC-H-20A/B catalyst allows a wide range of operating conditions, with high space
velocity, high selectivity, little green oil produced and adhesion to the catalyst. It also ensures a longer cycle of
operation. The catalyst can be successfully used in single-stage, two-stage or three-stage fixed bed reactor. The
catalyst is suitable for the removal of acetylene in C2 fractions in ethylene units, as well as for the further purification
of ethylene in polyethylene units.
Its appearance is yellowish gray granules of Φ2.5-5mm. Its composition is Pd-Promoter/Al2O3. Its bulk density is
about 0.6-0.9g/ml. Its crushing strength is >40N/granule. Its regeneration cycle is 6-12months. Its life time is
≥5years.




 (10)Catalyst for Selective Hydrogenation of Acetylene and
MAPD in front-end process

BC-H-21B

Hydrogenation catalyst is one of the keys for preparing high purity ethylene. The BC-H-21 is a catalyst for
gas-phase hydrogenation of acetylene and MAPD in front-end process. It has been spreading for use in the
                                                                                                                         37
country’s large and medium ethylene units, with satisfactory result.
BC-H-21B catalyst allows a wide range of operating conditions, with high space velocity, high selectivity, little
green oil produced and adhesion to the catalyst. It also ensures a longer cycle of operation.
Its appearance is yellowish gray granules of Φ4-5mm. Its composition is Pd-Promoter/Al2O3. Its bulk density is
around 0.6-0.9 g/ml. Its crushing strength is >40 N/granule. Its regeneration cycle is >3 years. Its life time is ≥5
years.




 (11) Hydrogenation of Pyrolysis Gasoline
Pyrolysis gasoline from steam-cracking ethylene plants cannot be utilized directly. The first stage hydrogenation is
for converting diolefins and alkenyl aromatics to monoolefins and alkyl aromatics and the second stage
hydrogenation is for olefins saturation and hydrodesulfurization, the catalysts play a key role in this process. We
have SHP catalyst series for raw pyrolysis gasoline upgrading, whch have been commercially approved.
SHP-01 and SHP-01F catalysts are designed for first stage hydrogenation of middle fraction and full range
pygas respectively. Meanwhile, SHP-02 and SHP-02F catalysts showed their combined advantages in the
second stage stacked bed reactor in terms of olefins hydrogenation and hydrodesulfurization. These catalysts have
already delivered the benefits to our clients’ plants, such as capacity expansion with no instrument modification,
longer catalyst cycle length or service life, lower reactor inlet temperature, energy saving and lower aromatics loss.




                                                                                                                   38
Other Catalysts
(1) PX Sorbent

RAX-2000A

It is a kind of solid molecular sieve sorbent developed by RIPP. It is used in the simulating remotion-bed process to
separate the high purity xylene product from the xylene mixture containing C8 non-aromatic compounds, ethyl
benzene (EB), Paraxylene(PX), mata-xylene(MX) and OX. It is an ideal selection for replacement of aromatic PX
sorbent in separation unit. It has been used in the domestic Parex commercial plant designed by UOP successfully.
Industrial result reveals that the purity of PX is 99.8%, and the yield of PX is over 98%.


(2) Non-crystal Alloy Hydrorefining Catalyst

SRNA-4

SRNA-4 is developed by RIPP. It is widely used in hydrogenation fields of petrochemicals, fine chemical, oil
refining, pharmaceutical and pesticide industries etc.
The activity, selectivity, stability and hydrogenation conversion rate of the product are all prominently superior to the
conventional catalysts of Ni-framework normally produced and used. Made with ultra-quenching technology, the
catalyst has unique crystal phase structure. It has long life and low unit consumption.


(3) Special Molecular Sieve Catalyst

HTS

HTS has similar MFI structure to ZSM-5 molecular sieve, and it has unique hollow channel structure. Ti content in
molecular framework is very high, which endows it with excellent thermal stability, sensitivity resistance, high
catalytic activity and selectivity. With dilute aqueous solution of H2O2 as oxidant, it can selectively catalyze
epoxidization of alkene, oxidization of alcohol, oxidization of alkane, hydroxylation of phenol to prepare bisphenol
and ammoxidation of cyclohexanone to prepare cyclohexanone oxime under mild conditions. Compared with the
conventional catalytic oxidizing catalyst, HTS makes oxidizing process simpler. The reaction condition is moderate
as it can proceed under normal pressure and low temperature (20~100 ℃ The catalytic oxidizing activity is
                                                                               ).

                                                                                                                      39
improved. The yield and selectivity of the final oxidization products are raised. It is also an environment protecting
product since the pollution is prominently reduced.


(4) Adhesive-Free 5A Small Spherical Molecular Sieve

NWA-IIB

NWA-IIB is a new adhesive-free spherical A-type molecular sieve. Based on its particular production process and
preparation technology, diffusion resistance of n-alkane in large and micro holes of the absorbent is effectively
lowered, so it has the characters of large absorption capacity and high absorption/desorption rate etc. It is mainly
used in MOLEX technology and variable-pressure absorption etc.


(5) C5/C6 Isomerization Catalyst

NNI-1

C5/C6 isomerization catalyst is a moderate-temperature molecular sieve catalyst. It is the first molecular sieve
catalyst carrying Pd that has realized industrial application in the world. The catalyst is mainly used in isomerization
of alkane to transform C5/C6 n-alkane in light naphtha into corresponding branch alkane, so that the front-end
octane value of gasoline fraction can be raised, and the gasoline is provided with uniform anti-explosion
performance.


(6) High-Temperature De-sulfurization Catalyst

TS-III

TS-III developed by Sinopec Catalyst Nanjing Division is a kind of high-efficiency ZnO desulfurization catalyst. It
is mainly used in H2S removal from hydrogen-making light oil feedstock (naphtha, dry gas) under high
temperature. It is also used in desulfurization of hydrogen, synthesis gas, and liquefied gas. The product has the
characters of high sulfur capacity, high crushing resistance, long life and low dust content etc.


(7) De-Chlorination Catalyst

TL

The TL de-chlorination catalyst includes low-temperature type and high-temperature type. The low-temperature
                                                                                                                     40
de-chlorination catalyst is mainly used in de-chlorination of cycle hydrogen in catalytic reforming installation. The
high-temperature de-chlorination catalyst is mainly used in de-chlorination of various mixing gases (carbon dioxide,
carbon monoxide, hydrocarbon etc) in hydrogen-making installation, or used in de-chlorination of
pre-hydrogenation feedstock in catalytic reforming installation. The product can effectively remove the chlorine ion
in cycle hydrogen and can prolong the application life and the maintenance period of facilities.


(8): PA Catalyst

Catalyst for Maleic Anhydride production from Oxidation of Benzene

(BC-118B)

BC-118B developed by BRICI is a catalyst for production of maleic anhydride from selective oxidation of benzene. This is a new type
lanthanon V2O5-MoO3 series catalyst. The active components are holding on the inert cricoid carrier. The catalyst has been used in
more than thirty units in China, such as Kaifeng organic chemical plant, Taiyuan Qiaoyou, Shanxi Taiming, Changzhou Shuguang,
Shanghai Changfeng, etc.

Performance:
◎High catalytic activity

◎High single translation ratio of benzene (98%~100%)

◎High selectivity and high yield the mass yield of maleic anhydride is (90-93%)

◎Low reaction temperature

◎Good stability (~480℃)

◎Long life time (more than 24 months)



Catalyst for Phthalic Anhydride production from oxidation of o-xylene (BC-239Ⅲ)
The ―BC-239Ⅲ‖ catalyst developed by BRICI, which is a V2O5-TiO2 supported catalyst used for the
―70-90 gram process‖ fixed bed oxidation of o-xylene to produce Phthalic Anhydride. The reactor is
filled with different kinds of catalyst in two, three or four parts, which are of different activity and
selectivity. The catalyst has been used in the Phthalic Anhydride production units in Jinling and Qilu
petrochemical company of SINOPEC.
Performance:
◎ High concentration of o-xylene: ~70-90g/Nm3
◎ Low reaction temperature:Salt Bath Temperature: 350~370℃
◎ Short induction period: the concentration of o-xylene can reach more than 80g/Nm3 in 45~75 days
◎ High space velocity and high yield: Yield of PA: ~113wt%
◎ High quality PA: the content of PTLD in crude PA≤0.15wt%
◎ Without adding SO2

                                                                                                                                41
Lube Base Oil




                42
43
 White oil


White oil industrial grade




Outline of product :
This product is the white-colored oil finely prepared through two-stage high-pressure phdrogenation of
the distillation cut of petroleum lubrication oil.
Characteristice:
Mineral oil industrial grade is a colorless, transparent, odourless , tasteless and oily liquid and free from
fluorescence, It can dissolve in ether, chloroform, gasoline and benzene, not in water or alcohol.
Main index (Standard: SH0006-98)


                Grade                                    Salable product

               Model                          7                  10                 15

kinetic viscosity ( 40       ) , mm2/s    6.1 7.5            9.0 11.0           13.5 16.5

   flash point(open) ,          >=           130                140                150

        pour point ,           <=            +3                  +3                 +2

            color ,     >=                   +20                +20                +24

          vitriol color test                 pass               pass               pass


Uses:
It severs as lubricant, solvent or coolant for spinning and weaving in chemical or synthetic fibre industry
in order to soften and brighten textiles. Also it is used as wetting agent, solvent or lubricant in the
industries of synthetic resin and plastic processing.

Packing : 200L in metal pail or special tanker
Note :
1 . The standard is following the SH0164.
2 . Stored in cool airiness place, not mixed with moisture and impurity.




                                                                                                            44
White oil food grade




Outline of product :
This product is a colorlss, odorless, tasteless, fluorescence-free, and clear oily liquid. This is the white-colored oil finely
prepared throuth two-stage high-pressure hy-drogenation of the distillation cut of petroleum lubrication oil and it excludes
the white mineral oils mixed with additives for processing purpose.
Uses:
It is suitable for gloss setting, adhesion privention, bubble removing, sealing and polishing of food. Also it is used for
anti-corrosion and lubrication of food machinery, Operating appliances and pharmaceutical machinery. Besides, it can
prolong the shelflife of liquor,vinegar, fruits vegetables and canned food.


Model
10# , 15# , 26# , 36#


Standard GB4853-94


                                                                                                Specifications
                                Items
                                                                            10                 15               26               36

                Kinematic Viscosity(40       ).mm2/s                  7.6        12.4   12.5        17.5   24        28   32.5        39.5

     Flash point ,                                        Min               145            165              165              165

                          Saybolt colority                               +30               +30              +30              +30

                        Soluble acid or alkali                           None             None             None             None

                 Mechanical Impurity , %(m/m)                            None             None             None             None

                          Water , %(m/m)                                 None             None             None             None

                Arsenic , mg/kg                  Max                         1                 1                1                1

                 Heavy metal mg/kg               Max                        10                 10               10               10

                     Plumbum , mg/kg         Max                             1                 1                1                1

                Readily carbonizable substances                          Pass              Pass             Pass             Pass

                           Solid Paraffin                                Pass              Pass             Pass             Pass

    Uv absorbance(at wave length 260         420nm)       Max               0.1            0.1              0.1              0.1




                                                                                                                                         45
     Packing : 200L in metal pail


Note :
1 . In assordance with the stipulaton Method 1 and the Dry Podzolization Method shallbe used.
2 . In accordance with the stipulation the dry digestion procedure spercified in the method shall be used.
3 . The wavelength detection range specified in GB/T11081 shall be extended to 420nm.




Food grade high viscosity white oil

Outline of product :
This product is a colorlss, odorless, tasteless, fluorescence-free, and clear oily liquid. This is the white-colored oil finely
prepared throuth two-stage high-pressure hy-drogenation of the distillation cut of petroleum lubrication oil.


User:
This product can be used in most of polystyrene and polypropylene products.
It can increase the flexibility of plastic. It has inner lubrication and demolding capacity. It has fine transparency and
stability. It has fine effects in the injection mould of Polystyrene.


Model
70#, 90#


Main index


                                                                                     70#                        90#

                  kinematic viscosity ( 40      ) , mm2/s                          65   75                 75     100

                       flash point ( open ) ,     >=                                 230                        235

                               Chroma     >=                                         +30                        +30

                           easy charring matter                                     pass                     pass

                     coefficient of refraction , nD20                          1.470    1.485           1.470     1.485

                           UV absorbance /cm
                                                                                     0.1                        0.1
                            (260    420nm) <=

                initial boiling point ,   ( 10mmHg ), >=                             230                        240
                              2.5% point, >=                                         255                        260


                                                                                                                                  46
                       density ( 20      ) , kg/m3                           859   880   860   880
Packing : 200L in metal pail or tanker


Note :
1 . The standard is following the SH0164.
2 . Store in cool, well-ventilated place, away from moisture and impurity.




                                                                                                     47
Injection white oil ( light white oil )

Outline of product :
It is made from petroleum. It used in vaccine injections for animals.


Main index ( standard : China animal remedy standard 2001 )

                       Relative density                                      0.818        0.880

           Kinematic viscosity ( 40        ), mm2/s                            11         13

                           Acidity                                            neutrality

                  Heavy metal , ppm       <=                                         10

                       Lead , ppm    <=                                              1

                       As , ppm      <=                                              1

                  UV absorbency/cm <=                                            0.1

                        Solid paraffin                                           pass

                    Easy charring matter                                         pass




     Packing : 200L in metal pail


Note :
1 . The standard is following the SH0164.
2 . Store in cool, well-ventilated place, away from moisture and impurity.




                                                                                                  48
White oil cosmetic grade

Outline of product :
This product is the white-colored oil finely prepared through hydrogenation of the distillation cut of
petroleum lubrication oil. It is classified by the viscosity into four calsses:No.10, 15, 26 and 36.

Characteristics :

Mineral oil cosmetic grade is a colorless, transparent, odorless, tasteless and oily liquid. It can be
dissolved in ether, chloroform gasoline and benzene, not in water or alcohol. Moreover, it has high
purity and possesses excellent antioxidant and chemical stability.

Uses :
It is used as the raw material of cosmetic for making hair-cream, face-cream, lipstick or vanishing cream.
In addition, it is also used as lubricate oil for light machinery and precision instruments.

Standard SH0007-90(98)


                      Items                                              Specifications

                     Grade                                                  Excellent

                     Brand                             10             15              26               36

          Kinetic viscosity(40 )mm2/s              7.6 12.4       12.5 17.5          24 28      32.5 39.5

                Flash point Min                        140            150             160           160

         UV absorbence (at wave length
                                                                               0.1
                260-350mm)Max

              Soluble acid or alkali                                        Neutral

         Readily carbonizable Substances                                      Pass

                     Suffide                                                  Pass

           Heavy metal ppm Max                                                 30

              Arsenic ppm      Max                                              2

                 Solid paraffin                                               Pass

                      water                                                  None

              Mechanical impurity                                            None

                                                                                                            49
                                              Colorless, transparent, odorless, tasteless and oily
               Appearance
                                                       liquid and free from fluorescence


Note :
1. If 10 ml of this product added with 10ml neutral alcohol is boiled and then stands-still ,
the reaction of the alcohol layer to the wet litmus paper shall keep neutral.
2. Package, marks and transportation
This product shall be packed, marked, stored, transported, delivered and accepted in
accordance with SH0164.
3. Sampling
Sample of 2L shall be taken in accordance with GB/T47756 for the inspection and as the
reserved sample.




                                                                                                     50
Petroleum Coke

SPECIFICATION

                 FIRST                                                     High      TEST
    ITEMS                  1#A     1#B        2#A       2#B   3#A   3#B
                 GRADE                                                    Sulphur   METHOD
  Sulphur,%
                    0.5    0.5     0.8         1        1.5    2     3      ≥3      GB/T 387
     Max.
                                                                                     SH/T
Volatile Max,%      12     12            14             17    18    20      20
                                                                                      0026
                                                                                     SH/T
Ash,Max %           0.3    0.3                0.5             0.8   1.2     1.2
                                                                                      0029
                                                                                     SH/T
Moisture Max,%                                      8
                                                                                      0032
                 2.08~                                                               SH/T
 Density g/cm3            Report                        -                    -
                  2.13                                                                0033




ITEMS                                          FIGURE
Sulphur,%                                      1-7
Volatile Max, %                                14
Ash Max,%                                      0.5
Moisture Max,%                                 8.0

Packing : In bulk




                                                                                             51
Paraffin Wax




Liquid Paraffin Wax

Application:
Used in making synthetic detergent, emulsifying agent of pesticide and plasticizer, etc.
Packing:
Bulk in Chemical Tanker
Precautions:
Kept in shady, dry stores and protected from direct sunshine, dust, water and chemical
substances during storage and transportation.
Specification
                                            LIMITS
ITEMS
                                       52#SR         54#SR         54#FR         56#SR         56#FR   58#FR   60#FR

                                Min    52            54            54            56            56      58      60
Melting point, ℃
                                Max    54            56            56            58            58      60      62
Oil content, wt%   Max                 1.0           1.5           0.6           1.5           0.5     0.5     0.5
Color, Saybolt   Min                   +25           +17           +28           +17           +28     +28     +28
                   (100g,25℃),1/10mm
Penetration                            22            20            17            20            17      18      18
                   Max
Odor, number Max                       2             2             1             2             1       1       1
Water-soluble acid or alkali           Nil           Nil           Nil           Nil           Nil     Nil     Nil
Mechanical impurity and water          Nil           Nil           Nil           Nil           Nil     Nil     Nil
Light Stability , number Max                         6                           6
Total Solvent Content (For Benzene
                                       Report        Report        Report        Report                Max.2   Max.2
&Toluene),ppm
FDA UV Absorbance 280-289 nm           Report        Report        Report        Report
290-299 nm                             Report        Report        Report        Report
300-359nm                              Report        Report        Report        Report                Pass    Pass
                                            Repo
360-400nm                                                 Report        Report        Report
                                            rt


Illustration: SR means semi-fully refined wax; FR means fully refined wax.

                                                                                                                   52
  Fully Refined Paraffin Wax

  Application:
  Used in production of high frequency porcelain, carbon paper, precision casting, cold cream
  and food wrapper, etc.
  Packing:
  Packed in PP woven bag with inner PE film bag and kraft paper bag, 50kg net each
  Precautions:
  Protected from direct sunlight or rain, and kept away from heat or fire sources.

  Specification
                                                                       LIMITS
            ITEMS                            TOP GRADE                               FIRST GRADE
                                 NO.54       NO.56       NO.58       NO.60   NO.54       NO.56       NO.58       NO.60
Melting       Min                  54         56          58          60      54          56          58          60
point, ℃      Max                  56         58          60          62      56          58          60          62
Oil content, wt% Max                               0.5                                         0.8
Color,Saybolt Min                       +28                    +25                 +25                     +22
Light stability, number   Max            4                       5                   4                       5
Penetration(25℃,100g),1/10mm
                                         18                      16                19                      17
Max

Kinetic viscosity (100℃)mm2/s                   Report                                      Report

Odor, number Max                                     2                                           2
Water-soluble acid or alkali                       Nil                                         Nil
Mechanical impurity and water                      Nil                                         Nil




                                                                                                                  53
Semi-Refined Paraffin Wax

Application:
Used in making illuminating candles, artistic candles, wax pencils, stencil paper,
equipments or materials for telecommunication and raw materials for chemical industry as
well.
Packing:
Packed in PP woven bag with inner PE film bag and kraft paper bag, 50kg net each
Precautions:
Protected from direct sunlight or rain, and kept away from heat or fire sources.
Specification

                                                  LIMITS                         TEST
                ITEMS
                                                                                METHOD
                                    NO.54       NO.56       NO.58       NO.60
                          Min         54         56          58          60
Melting point, ℃                                                                GB/T 2539
                          Max         56         58          60          62
Oil content, wt% Max                                  1.8                       GB/T 3554
Color, Saybolt Min                                    +17                       GB/T3555
Light stability, number   Max               6                       7           SH/T 0404
              (100g,25℃),1/10mm
                                                      23
Penetration Max                                                                 GB/T 4985
              (100g,35℃),1/10mm                    Report
Kinetic viscosity (100℃)mm2/s                      Report                        GB/T 265
Odor, number Max                                        2                        SH/T 0414
                                                                                  SH/T
Water-soluble acid or alkali                          Nil
                                                                                0407
Mechanical impurity and water                         Nil                            -




                                                                                        54
    Microcrystalline Wax


    Application:
    Used in water proof, anti-corrosion, adhesives, polishes, desensitizers, fine casting,
    insulation, rubber anti-ozonants, medicine, cosmetics, food-stuff and food packaging, etc.
    Packing:
    Packed in PP woven bag with inner PE film bag and kraft paper bag, 50kg net each
    Precautions:
    Kept from direct sun-shine during storage for keeping color stability; prevented from over
    heating in melting and mingling with water and impurities during storage and
    transportation.

    Specification

                                     70#                        80#                                85#           TEST
            ITEMS                                                                                                MET
                            Grade      Food       regular       Grade    Food    regular       Grade     Food
                                                                                                                 HOD
                             A         grade      grade          A       grade   grade          A        grade
  Melting            Max                                                                                         GB/T8
                                67         67          77           77    77          82            82     82
  Point ℃                                                                                                         026
                     Min
                                72         72          82           82    82          87            87     87

Penetration (100g, 25℃)                                                                                          GB/T4
                            30         30         20            20       16      18            18        14
1/10mm, Max                                                                                                       958
                                                                                                                 SH/T0
Oil Content wt%, Max        3          1.0        5             3        1.0     5             3         1.0
                                                                                                                 638
                                                                                                                 GB/T6
Color, Saybolt Min          2.5        1.0        4.5           2.5      1.0     4.5           2.5       1.0
                                                                                                                 540
Kinetic viscosity      ,
                 (100℃) m                                       10—2     10—     10—2                    10—2    GB/T2
                            <6         <6         10—20                                        10—20
㎡/s,                                                            0        20      0                       0       65
              280-289mm
                                           0.15                           0.15                            0.15
              Max
              290-299mm
                                           0.12                           0.12                            0.12
 FDA UV       Max                                                                                                GB/T7
                                  -                         -                              -
Absorbance    300-359mm                                                                                           363
                                           0.08                           0.08                            0.08
              Max
              360-400mm
                                           0.02                           0.02                            0.02
              Max

                                                                                                                 55
Specialty Wax

There are more than 100 kinds of specialty wax products in SINOPEC, applied in food
packing, painting, rubber protecting, sealing of bottle-made handcraft and best roof
materials for the marble, etc.
SPECIALTY WAX TYPES
Series of Precise Founding Wax
Rubber Protection Wax
Domestic Fowl Feather-Puwing Wax
Soft Microcrystalline Wax
Polishing Bride Smudge-proof Wax
Soft Paraffin Wax
Preventing Rust Wax
Compound Wax for Emulsified Explosive
Specialty Wax for Phase Change Energy-Storing Material
Bottle-made Handcraft Seal Wax




                                                                                  56
Chewing Gum Special-Purpose Wax

Application:
Used in food and the chewing gum.
Precautions:
Kept in the good condition in storage and transporting, stored up in dry and ventilated
environment and where temperature is lower than 50℃, prevented from fire and burning
things.
Packing:
Packed in bag, 600 kg net each

Specification


           ITEMS                        INDEX                     TEST METHOD

    Outward appearance              Cream color solid             Visual estimation

    Drop melting point, ℃                88-102                      GB/T8026

Penetration,25℃,1/10mm,Max                4-10                       GB/T4985

      Oil content, wt%                    <3                         SH/T0638

      FDA examination                   Through                      GB/T7363
Illustration: This product has good flexibility, agglutination, water resistance and oxidation
resistance, pure white outward appearance and good stability, conforming to FDA172.886
examination standards.




                                                                                            57

				
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