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Report Date : 07/11/2008 1 / 5 SDS NO.: 11055 SAFETY DATA SHEET WICKES TRADITIONAL SHED & FENCE PRESERVER 1 IDENTIFICATION OF THE SUBSTANCE/PREPARATION AND OF THE COMPANY/UNDERTAKING PRODUCT NAME WICKES TRADITIONAL SHED & FENCE PRESERVER INTERNAL ID 170677/170678/170679/170680 APPLICATION Wood preservation for outdoor use. SUPPLIER Wickes Building Supplies Ltd, Wickes House, 120/138 Station Road, Harrow. HA1 2QB 0208 901 2000 0870 608 9001 (Customer Services) 0208 427 1645 2 HAZARDS IDENTIFICATION Flammable. Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Repeated exposure may cause skin dryness or cracking. Harmful: may cause lung damage if swallowed. CLASSIFICATION Xn;R65. N;R51/53. R10, R66. 3 COMPOSITION/INFORMATION ON INGREDIENTS Name EC No. CAS-No. Content Classification NAPHTHA (PETROLEUM), HYDROTREATED 265-150-3 64742-48-9 1-2.5% Xn;R65. R10,R66. HEAVY. PROPICONAZOLE 262-104-4 60207-90-1 < 1% Xn;R22. N;R50/53. R43. SOLVENT NAPHTHA 265-191-7 64742-88-7 2.5-10% Xn;R65. N;R51/53. R66. (PETROLEUM),MEDIUM ALIPH.,STRAIGHT RUN KEROSENE White Spirit 265-185-4 64742-82-1 50-100% Xn;R65. N;R51/53. R10,R66. The Full Text for all R-Phrases are Displayed in Section 16 4 FIRST-AID MEASURES GENERAL INFORMATION Remove affected person from source of contamination. Provide rest, warmth and fresh air. Place unconscious person on the side in the recovery position and ensure breathing can take place. Do not give victim anything to drink if they are unconscious. Get medical attention if any discomfort continues. INHALATION General first aid, rest, warmth and fresh air. Place unconscious person on the side in the recovery position and ensure breathing If breathing stops, provide artificial respiration. NEVER MAKE AN UNCONSCIOUS PERSON VOMIT OR DRINK FLUIDS! Get medical attention if any discomfort continues. INGESTION Provide rest, warmth and fresh air. DO NOT induce vomiting. Get medical attention immediately. SKIN CONTACT Remove contaminated clothing. Wash skin thoroughly with soap and water. Contact physician if irritation continues. EYE CONTACT Make sure to remove any contact lenses from the eyes before rinsing. Promptly wash eyes with plenty of water while lifting the eye lids. Continue to rinse for at least 15 minutes. Contact physician if irritation persists. Report Date : 07/11/2008 2 / 5 SDS NO.: 11055 WICKES TRADITIONAL SHED & FENCE PRESERVER 5 FIRE-FIGHTING MEASURES EXTINGUISHING MEDIA Fire can be extinguished using: Water spray, fog or mist. Alcohol resistant foam. Carbon dioxide (CO2). Do not use water jet as an extinguisher, as this will spread the fire. SPECIAL FIRE FIGHTING PROCEDURES Avoid breathing fire vapours. NOTE! Use air-supplied respirators to protect against gases\fumes. Cool containers exposed to flames with water until well after the fire is out. Move container from fire area if it can be done without risk. Keep run-off water out of sewers and water sources. Dike for water control. 6 ACCIDENTAL RELEASE MEASURES PERSONAL PRECAUTIONS Wear protective clothing as described in Section 8 of this safety data sheet. SPILL CLEAN UP METHODS Extinguish all ignition sources. Avoid sparks, flames, heat and smoking. Ventilate. When dealing with a spillage, please consult the section relating to suitable protective measures. Wear necessary protective equipment. Provide ventilation and confine spill. Do not allow runoff to sewer. Collect spillage in containers, seal securely and deliver for disposal according to local regulations. Wash thoroughly after dealing with a spillage. Inform Authorities if large amounts are involved. 7 HANDLING AND STORAGE USAGE PRECAUTIONS Keep away from heat, sparks and open flame. Avoid spilling, skin and eye contact. Avoid eating, drinking and smoking when using the product. Wear suitable protective clothing and suitable gloves Do not breathe spray. Otherwise wear respiratory protective equipment and eye protection (see HSE Guidance booklet HS (G) 53: "The Selection, Use and Maintenance of Respiratory Protective Equipment - A Practical Guide". This material and its container must be disposed of in a safe way. Do not empty into drains. Use only in well ventilated areas. Keep away from treated surfaces until dry. Do not contaminate ground, waterbodies or watercourses with chemical or used container. Cover water storage tanks before application. Remove and cover all fish tanks and bowls before application. Wash any contamination from skin and eyes immediately Wash hands and exposed skin before meals and after use. Ventilate treated areas thoroughly after application. For oudoor use only. Avoid all contact with plant life To avoid risks to man and the environment, comply with instructions for use. Until dry, treated areas can pose a fire risk. STORAGE PRECAUTIONS Observe the label precautions. Keep in a cool, dry, well ventilated place, away from sources of heat, ignition and direct sunlight. No smoking. Keep only in original container. Keep in a safe place. Keep container tightly closed. Keep out of reach of children. Keep away from food, drink and animal feedingstuffs. The principles contained in the HSE Guidance Note: Storage of Packaged Dangerous Substances, should be observed when storing this product. To avoid the risk of spillage, always store and transport in a secure and upright position. 8 EXPOSURE CONTROLS/PERSONAL PROTECTION Name Std LT - ppm LT - mg/m3 ST - ppm ST - mg/m3 NAPHTHA (PETROLEUM), HYDROTREATED SUP 1000 ppm No std. No std. HEAVY. SOLVENT NAPHTHA (PETROLEUM),MEDIUM SUP 100 ppm No std. No std. No std. ALIPH.,STRAIGHT RUN KEROSENE White Spirit SUP 350 mg/m3 INGREDIENT COMMENTS SUP = Supplier's recommendation. ENGINEERING MEASURES Provide adequate ventilation. Observe Workplace Exposure Limits and minimise the risk of inhalation of vapours. Must not be handled in confined space without sufficient ventilation. RESPIRATORY EQUIPMENT If ventilation is insufficient, suitable respiratory protection must be provided. HAND PROTECTION Protective gloves should be used if there is a risk of direct contact or splash. Barrier cream applied before work may make it easier to clean the skin after exposure, but does not prevent absorption through the skin. Report Date : 07/11/2008 3 / 5 SDS NO.: 11055 WICKES TRADITIONAL SHED & FENCE PRESERVER EYE PROTECTION Wear approved chemical safety goggles where eye exposure is reasonably probable. OTHER PROTECTION Wear appropriate clothing to prevent reasonably probable skin contact. Cotton or cotton/synthetic overalls or coveralls are normally suitable. Grossly contaminated clothing should be removed and the skin washed with soap and water or a proprietary skin cleaner. All personal protective equipment, including respiratory protective equipment, used to control exposure to hazardous substances must be selected to meet the requirements of the COSHH Regulations. HYGIENE MEASURES Wash any contamination from skin or eyes immediately. Wash hands and exposed slin before meals and after use. Use appropriate hand lotion to prevent defatting and cracking of skin. 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Low viscosity liquid. COLOUR Colour will vary dependent on individual shade. ODOUR Characteristic of solvents SOLUBILITY Immiscible with water FLASH POINT (°C) 43 CC (Closed cup). 10 STABILITY AND REACTIVITY STABILITY Stable under normal temperature conditions. No particular stability concerns. CONDITIONS TO AVOID Keep away from oxidising agents and strongly alkaline and strongly acidic materials. HAZARDOUS DECOMPOSITION PRODUCTS In a fire, hazardous decomposition products such as smoke, carbon monoxide, carbon dioxide and alcohols may be produced. 11 TOXICOLOGICAL INFORMATION TOXICOLOGICAL INFORMATION There is no data on the product itself. The product has been approved under the UK's Control of Pesticides Regulations and is classified for toxicological hazards accordingly. This takes into account, where known, delayed and immediate effects and also chronic effects of components from short-term and long-term exposure by oral, inhalation and dermal routes of exposure and eye contact. See Sections 3 and 15 for details of the resulting hazard classification. GENERAL INFORMATION Knowledge about health hazard is incomplete. Prolonged and repeated contact with solvents over a long period may lead to permanent health problems. INHALATION Vapours may cause headache, fatigue, dizziness and nausea. Contains organic solvents which in case of overexposure may depress the central nervous system causing dizziness and intoxication. Droplets of the product aspirated into the lungs through ingestion or vomiting may cause a serious chemical pneumonia. When working extensively on big surfaces in small and badly ventilated rooms, vapours may develop in concentrations which may cause malaise such as headache, dizziness and nausea. INGESTION Harmful: may cause lung damage if swallowed. If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label. SKIN CONTACT Product has a defatting effect on skin. May be absorbed through the skin. Prolonged contact may cause dryness of the skin. EYE CONTACT May cause temporary eye irritation. 12 ECOLOGICAL INFORMATION Report Date : 07/11/2008 4 / 5 SDS NO.: 11055 WICKES TRADITIONAL SHED & FENCE PRESERVER ECOTOXICITY The preparation is approved under the Control of Pesticides Regulations. This approval takes into account, where known, any effects on the environment resulting from the use of the product. Refer to Sections 3 and 15 for details of any environmental classification. Do not contaminate ground, waterbodies or watercourses with chemicals or used containers. All bats are protected under The Wildlife and Countryside Act 1981. Before treating any structure used by bats, consult Natural England, Scottish Natural Heritage or the Countryside Council for Wales. DEGRADABILITY There are no data on the degradability of this product. ACUTE FISH TOXICITY Dangerous to fish and aquatic life. Do not contaminate watercourses or ground. WATER HAZARD CLASSIFICATION The product should not be allowed to enter drains or watercourses, or be deposited where it can affect ground or surface waters. 13 DISPOSAL CONSIDERATIONS GENERAL INFORMATION This material and its container must be disposed of in a safe way DISPOSAL METHODS Do not allow runoff to sewer, waterway or ground. Dispose of waste and residues in accordance with local authority requirements. Contact specialist disposal companies. 14 TRANSPORT INFORMATION GENERAL Transport within user's premises: always transport in closed containers that are upright and secure. Ensure that person's transporting the product know what to do in an accident or spillage. Limited Quantity concessions may apply to the carriage of this product. PROPER SHIPPING NAME WOOD PRESERVATIVES, LIQUID UN NO. ROAD 1306 ADR CLASS Class 3: Flammable liquids. ADR PACK GROUP III UN NO. SEA 1306 IMDG CLASS 3 IMDG PACK GR. III EMS F-E; S-D MARINE POLLUTANT 15 REGULATORY INFORMATION LABELLING Harmful Dangerous for the environment CONTAINS White Spirit Report Date : 07/11/2008 5 / 5 SDS NO.: 11055 WICKES TRADITIONAL SHED & FENCE PRESERVER RISK PHRASES R10 Flammable. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R66 Repeated exposure may cause skin dryness or cracking. R65 Harmful: may cause lung damage if swallowed. SAFETY PHRASES S2 Keep out of the reach of children S13 Keep away from food, drink and animal feeding stuffs. S37 Wear suitable gloves. S46 If swallowed, seek medical advice immediately and show this container or label. S51 Use only in well-ventilated areas. S29/56 Do not empty into drains, dispose of this material and its container at hazardous or special waste collection point. S61 Avoid release to the environment. Refer to special instructions/safety data sheets. P14 Contains PROPICONAZOLE. May produce an allergic reaction. S16 Keep away from sources of ignition - No smoking. UK REGULATORY REFERENCES The information contained in this safety data sheet does not constitute the user's own assessment of workplace risks as required by other health and safety legislation. Chemicals (Hazard Information & Packaging) Regulations. The Control of Substances Hazardous to Health Regulations 1988. The Control of Pesticides Regulations 1986 HSE No 8774 EU DIRECTIVES Dangerous Substance Directive 67/548/EEC. Dangerous Preparations Directive 1999/45/EC. GUIDANCE NOTES Workplace Exposure Limits EH40. HSE Guidance Booklet HS (G) 53: "The Selection, Use and Maintenance of Respiratory Protective Equipment - A Practical Guide." 16 OTHER INFORMATION SDS NO. 11055/1 SAFETY DATA SHEET STATUS Approved. DATE 03-11-2008 RISK PHRASES IN FULL R10 Flammable. R22 Harmful if swallowed. R43 May cause sensitisation by skin contact. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R65 Harmful: may cause lung damage if swallowed. R66 Repeated exposure may cause skin dryness or cracking. DISCLAIMER This information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process. Such information is, to the best of the company's knowledge and belief, accurate and reliable as of the date indicated. However, no warranty guarantee or representation is made to its accuracy, reliability or completeness. It is the user's responsibility to satisfy himself as to the suitability of such information for his own particular use.
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