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Asbestos

Asbestos

Asbestos

Fibrous asbestos on muscovite

Blue asbestos (crocidolite) from Wittenoom, Western Australia. The ruler is 1 cm.

Asbestos Asbestos is a naturally occurring silicate mineral with long, thin fibrous crystals. The word asbestos (ασβεστος) is derived from a Greek adjective meaning inextinguishable. The Greeks termed asbestos the miracle mineral because of its soft and pliant properties, as well as its ability to withstand heat. Asbestos is toxic. The inhalation of asbestos fibers can cause serious illnesses, including malignant mesothelioma, lung cancer, and asbestosis (a type of pneumoconiosis). Since the mid 1980s, many uses of asbestos have been banned in several countries.

Blue asbestos showing the fibrous nature of the mineral Asbestos became increasingly popular among manufacturers and builders in the late 19th century because of its resistance to

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heat, electricity and chemical damage, its sound absorption and tensile strength. When asbestos is used for its resistance to fire or heat, the fibers are often mixed with cement or woven into fabric or mats. Asbestos was used in some products for its heat resistance, and in the past was used on electric oven and hotplate wiring for its electrical insulation at elevated temperature, and in buildings for its flame-retardant and insulating properties, tensile strength, flexibility, and resistance to chemicals.

Asbestos
throughout the world. Its idealized chemical formula is Mg3(Si2O5)(OH)4. Chrysotile fibers are curly as opposed to fibers from amosite, crocidolite, tremolite, actinolite, and anthophyllite which are needlelike.[1] Chrysotile, along with other types of asbestos, has been banned in dozens of countries and is only allowed in the United States and Europe in very limited circumstances. Chrysotile has been used more than any other type and accounts for about 95% of the asbestos found in buildings in America.[2] Applications where chrysotile might be used include the use of joint compound. It is more flexible than amphibole types of asbestos; it can be spun and woven into fabric. The most common use is within corrugated asbestos cement roof sheets typically used for outbuildings, warehouses and garages. It is also found as flat sheets used for ceilings and sometimes for walls and floors. Numerous other items have been made containing chrysotile including brake linings, cloth behind fuses (for fire protection), pipe insulation, floor tiles, and rope seals for boilers.

Types and associated fibres

Brown
Amosite, CAS No. 12172-73-5, is a trade name for the amphiboles belonging to the Cummingtonite - Grunerite solid solution series, commonly from Africa, named as an acronym from Asbestos Mines of South Africa. One formula given for amosite is Fe7Si8O22(OH)2. It is found most frequently as a fire retardant in thermal insulation products and ceiling tiles.[2]

Chrysotile asbestos

Blue
Crocidolite, CAS No. 12001-28-4 is an amphibole found primarily in southern Africa, but also in Australia. It is the fibrous form of the amphibole riebeckite. One formula given for crocidolite is 2+3Fe3+2Si8O22(OH)2. Notes: chrysoNa2Fe tile commonly occurs as soft friable fibers. Asbestiform amphibole may also occur as soft friable fibers but some varieties such as amosite are commonly straighter. All forms of asbestos are fibrillar in that they are composed of fibers with widths less than 1 micrometer that occur in bundles and have very long lengths. Asbestos with particularly fine fibers is also referred to as "amianthus". Amphiboles such as tremolite have a crystal structure containing strongly bonded

Asbestos fibers Six minerals are defined as "asbestos" including: chrysotile, amosite, crocidolite, tremolite, anthophyllite and actinolite.

White
Chrysotile, CAS No. 12001-29-5, is obtained from serpentine rocks which are common

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ribbonlike silicate anion polymers that extend the length of the crystal. Serpentine (chrysotile) has a sheetlike silicate anion which is curved and which rolls up like a carpet to form the fiber.[3]

Asbestos

Historic usage
Asbestos was named by the ancient Greeks, although the naming of minerals was not very consistent yet at that time (the modern Greek word ἀσβεστος stands for lime, not for the material known as asbestos in English). The ancients already recognized certain hazards of the material. The Greek geographer Strabo and the Roman naturalist Pliny the Elder noted that the material damaged lungs of slaves who wove it into [5]Charlemagne, the first Holy Roman cloth. Emperor, is said to have had a tablecloth made of asbestos.[6][7] Wealthy Persians, who bought asbestos imported over the Hindu Kush, amazed guests by cleaning the cloth by simply exposing it to fire. According to Biruni in his book of Gems, any cloths made of asbestos (Persian: ‫ ,تسشرذآ‬āzarshast or Persian: ‫,بشرذآ‬ āzarshab) were called (Persian: ‫ )هكتسش‬shastakeh[8]. Some of the Persians believed the fiber was fur from an animal (named samandar, Persian: ‫ )ردنمس‬that lived in fire and died when exposed to water.[9][10] While traveling to China, Marco Polo described observing miraculous garments that were cleaned by being placed in fires. These garments were without a doubt made from asbestos. Some archeologists believe that ancients made shrouds of asbestos, wherein they burned the bodies of their kings, in order to preserve only their ashes, and prevent their being mixed with those of wood or other combustible materials commonly used in funeral pyres.[11] Others assert that the ancients used asbestos to make perpetual wicks for sepulchral or other lamps.[7][9] In more recent centuries, asbestos was indeed used for this purpose. Although asbestos causes skin to itch upon contact, ancient literature indicates that it was prescribed for diseases of the skin, and particularly for the itch. It is possible that they used the term asbestos for alumen plumosum, because the two terms have often been confused throughout history.[11] Asbestos became more widespread during the industrial revolution; in the 1860s it was used as insulation in the U.S. and Canada. Development of the first commercial asbestos mine began in 1879 in the Appalachian foothills of Quebec.[12] By the mid 20th century uses included fire retardant coatings, concrete, bricks, pipes and fireplace cement,

Other materials
Other regulated asbestos minerals, such as tremolite asbestos, CAS No. 77536-68-6, Ca2Mg5Si8O22(OH)2; actinolite asbestos (or smaragdite), CAS No. 77536-66-4, Ca2(Mg, Fe)5(Si8O22)(OH)2; and anthophyllite asbestos, CAS No. 77536-67-5, (Mg, Fe)7Si8O22(OH)2; are less commonly used industrially but can still be found in a variety of construction materials and insulation materials and have been reported in the past to occur in a few consumer products. Other natural and not currently regulated asbestiform minerals, such as richterite, Na(CaNa)(Mg, Fe++)5(Si8O22)(OH)2, and winchite, (CaNa)Mg4(Al, Fe3+)(Si8O22)(OH)2, may be found as a contaminant in products such as the vermiculite containing zonolite insulation manufactured by W.R. Grace and Company. These minerals are thought to be no less harmful than tremolite, amosite, or crocidolite, but since they are not regulated, they are referred to as "asbestiform" rather than asbestos although may still be related to diseases and hazardous.

Nations Producing Asbestos

Asbestos output in 2005 In 2006, 2.3 million tons of asbestos were mined worldwide, in 11 or 12 countries. Russia was the largest producer with about 40% world share followed by China, Kazakhstan, and Canada (the last of which produces 10% of the world’s asbestos).[4]

Uses
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heat, fire, and acid resistant gaskets, pipe insulation, ceiling insulation, fireproof drywall, flooring, roofing, lawn furniture, and drywall joint compound.[7] Approximately 100,000 people in the United States have died, or will die, from asbestos exposure related to ship building. In the Hampton Roads area, a shipbuilding center, mesothelioma occurrence is seven times the national rate.[13] Thousands of metric tons of asbestos were used in World War II ships to wrap the pipes, line the boilers, and cover engine and turbine parts. There were approximately 4.3 million shipyard workers in the United States during WWII; for every thousand workers about fourteen died of mesothelioma and an unknown number died from asbestosis.[12] Asbestos fibers were once used in automobile brake pads and shoes. Since the mid-1990s, a majority of brake pads, new or replacement, have been manufactured instead with linings made of ceramic, carbon, metallic and Aramid fiber (Twaron or Kevlar—the same material used in bulletproof vests). Kent, the first filtered cigarette on the market, used crocidolite asbestos in its "Micronite" filter from 1952 to 1956.[14] The first documented death related to asbestos was in 1906. In the early 1900s researchers began to notice a large number of early deaths and lung problems in asbestos mining towns. The first diagnosis of asbestosis was made in England in 1924. By the 1930s, England regulated ventilation and made asbestosis an excusable work related disease, about ten years sooner than the U.S. [1] The term Mesothelioma was not used in medical literature until 1931, and was not associated with asbestos until sometime in the 1940s. The United States government and asbestos industry have been criticized for not acting quickly enough to inform the public of dangers, and to reduce public exposure. In the late 1970s court documents proved that asbestos industry officials knew of asbestos dangers and tried to conceal them.[12] In Japan, particularly after World War II, asbestos was used in the manufacture of ammonium sulfate for purposes of rice production, sprayed upon the ceilings, iron skeletons, and walls of railroad cars and buildings (during the 1960s), and used for energy efficiency reasons as well. Production of

Asbestos
asbestos in Japan peaked in 1974 and went through ups and downs until about 1990, when production began to drop severely.[15]

Specific products
Serpentine group
Serpentine minerals have a sheet or layered structure. Chrysotile is the only asbestos mineral in the serpentine group. In the United States, chrysotile has been the most commonly used type of asbestos. According to the U.S. EPA Asbestos Building Inspectors Manual, chrysotile accounts for approximately 95% of asbestos found in buildings in the United States. Chrysotile is often present in a wide variety of materials, including: • joint compound • mud and texture coats • vinyl floor tiles, sheeting, adhesives • roofing tars, felts, siding, and shingles • "transite" panels, siding, countertops, and pipes • fireproofing • caulk • gaskets • brake pads and shoes • clutch plates • stage curtains • fire blankets • interior fire doors • fireproof clothing for firefighters • thermal pipe insulation In the European Union and Australia it has recently been banned as a potential health hazard[16] and is not used at all. Japan is moving in the same direction, but more slowly. Revelations that hundreds of workers had died in Japan over the previous few decades from diseases related to asbestos sparked a scandal in mid-2005.[17] Tokyo had, in 1971, ordered companies handling asbestos to install ventilators and check health on a regular basis; however, the Japanese government did not ban crocidolite and amosite until 1995, and a full-fledged ban on asbestos was implemented in October 2004.[17]

Amphibole group
Five types of asbestos are found in the amphibole group: amosite, crocidolite, anthophyllite, tremolite, and actinolite. Amosite, the second most likely type to be found in buildings, according to the U.S. EPA

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Asbestos
asbestos, like all asbestos, is hazardous. Amosite is the most hazardous of the asbestos minerals because of its hollow straight fiber structure that can stay airborne for up to 72 hours. It also does not get trapped by water as easily as the serpentine fibers do of chrysotile. Tremolite often contaminates chrysotile asbestos, thus creating an additional hazard. Asbestos exposure becomes a health concern when high concentrations of asbestos fibers are inhaled over a long time period.[18] People who become ill from asbestos are almost always those who are exposed on a dayto-day basis in a job where they work directly with the material. As a person’s exposure to fibers increases, either by breathing more fibers or by breathing fibers for a longer time, that person’s risk of disease also increases. Disease is very unlikely to result from a single, high-level exposure, or from a short period of exposure to lower levels.[18]

Other asbestos-related diseases
A household heat spreader for cooking on gas stoves, made of asbestos (probably 1950s; "Amiante pur" is French for "Pure Asbestos") Asbestos Building Inspectors Guide, is the "brown" asbestos. Amosite and crocidolite were formerly used in many products until the early 1980s. The use of all types of asbestos in the amphibole group was banned in much of the Western world by the mid-1980s, and by Japan in 1995. These products were mainly: • Low density insulation board and ceiling tiles • Asbestos-cement sheets and pipes for construction, casing for water and electrical/telecommunication services • Thermal and chemical insulation (i.e., fire rated doors, limpet spray, lagging and gaskets) • – caused when the sharp fibers lodge in the skin and are overgrown causing benign callus-like growths. • – discrete fibrous or partially calcified thickened area which can be seen on Xrays of individuals exposed to asbestos. They do not become malignant or cause other lung impairment. • – similar to above and can sometimes be associated with asbestosis. Usually no symptoms shown but if exposure is extensive, it can cause lung impairment.

Asbestos as a contaminant
Most respirable asbestos fibers are invisible to the unaided human eye because their size is about 3.0-20.0 µm in length and can be as thin as 0.01 µm. Human hair ranges in size from 17 to 181 µm in width.[19] Fibers ultimately form because when these minerals originally cooled and crystallized, they formed by the polymeric molecules lining up parallel with each other and forming oriented crystal lattices. These crystals thus have three cleavage planes, just as other minerals and gemstones have. But in their case, there are two cleavage planes that are much weaker than the third direction. When sufficient force is applied, they tend to break along their weakest directions, resulting in a linear fragmentation pattern and hence a fibrous

Health issues
Chrysotile asbestos, like all other forms of industrial asbestos, has produced tumors in animals. Mesotheliomas have been observed in people who were occupationally exposed to chrysotile, family members of the occupationally exposed, and residents who lived close to asbestos factories and mines.[1] Brown

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Asbestos
exposure from NOA. Many populated areas are in proximity to shallow, natural deposits which occur in 50 of 58 California counties and in 19 other U.S. states. In one study, data was collected from 3,000 mesothelioma patients in California and 890 men with prostate cancer, a malignancy not known to be related to asbestos. The study found a correlation between the incidence of mesotheliomas and the distance a patient lived from known deposits of rock likely to include asbestos, the correlation was not present when the incidence of prostate cancer was compared with the same distances. According to the study, risk of mesothelioma declined by 6 percent for every 10 kilometers that an individual had lived away from a likely asbestos source.[22] Portions of El Dorado County, California are known to contain natural asbestos formations near the surface.[23][22] The USGS studied amphiboles in rock and soil in the area in response to an EPA sampling study and subsequent criticism of the EPA study. The study found that many amphibole particles in the area meet the counting rule criteria used by the EPA for chemical and morphological limits, but do not meet morphological requirements for commercial-grade-asbestos. The executive summary pointed out that even particles that do not meet requirements for commercial-grade-asbestos may be a health threat and suggested a collaborative research effort to assess health risks associated with "Naturally Occurring Asbestos".[24] Large portions of Fairfax County, Virginia were also found to be underlain with tremolite. The county monitored air quality at construction sites, controlled soil taken from affected areas, and required freshly developed sites to lay 6 inches (150 mm) of clean, stable material over the ground.[22]

Asbestos fibres (SEM micrograph) form. This fracture process can keep occurring and one larger asbestos fiber can ultimately become the source of hundreds of much thinner and smaller fibers. As asbestos fibers get smaller and lighter, they more easily become airborne and human respiratory exposures can result. Fibers will eventually settle but may be re-suspended by air currents or other movement. Friability of a product containing asbestos means that it is so soft and weak in structure that it can be broken with simple finger crushing pressure. Friable materials are of the most initial concern because of their ease of damage. The forces or conditions of usage that come into intimate contact with most non-friable materials containing asbestos are substantially higher than finger pressure.

Environmental asbestos
Asbestos can be found naturally in the air outdoors and in some drinkable water, including water from natural sources.[20] Studies have shown that members of general (non-occupationally exposed) population have tens of thousands to hundreds of thousands of asbestos fibers in each gram of dry lung tissue, which translates into millions of fibers and tens of thousands of asbestos bodies in every person’s lungs.[21] Asbestos from natural geologic deposits is known as "Naturally Occurring Asbestos" (NOA). Health risks associated with exposure to NOA are not yet fully understood, and current US federal regulations do not address

History of health concerns and regulation
Prior to 1900
By the first century AD, Greeks and Romans had already observed, at least in passing, that slaves involved in the weaving of asbestos cloth were afflicted with a sickness of the lungs. [25] Early concern in the modern era on the health effects of asbestos exposure can be

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found in several sources. Among the earliest were reports in Britain. The annual reports of the Chief Inspector of Factories reported as early as 1898 that asbestos had ’easily demonstrated’ health risks.[26] At about the same time, what was probably the first study of mortality among asbestos workers was reported in France. [27] While the study describes the cause of death as chalicosis, a generalized pneumoconiosis, the circumstances of the employment of the fifty workers whose death prompted the study suggest that the root cause was asbestos or mixed asbestos-cotton dust exposure.

Asbestos
manufactured have long suspected the dust to be the cause of chronic bronchitis and fibrosis...[30]." Dr. Cooke then went on to report on a case in 1927 involving a 33-year old male worker who was the only survivor out of ten workers in an asbestos carding room. In the report he named the disease "asbestosis[31]." Dr. Cooke’s second case report was followed, in the late 1920s, by a large public health investigation (now known as the Merewether report after one of its two authors) that examined some 360 asbestos-textile workers (reported to be about 15% of the total comparable employment in Britain at the time) and found that about a quarter of them suffered from pulmonary fibrosis [32]. This investigation resulted in improved regulation of the manufacturing of asbestos-containing products in the early 1930s. Regulations included industrial hygiene standards, medical examinations, and inclusion of the asbestos industry into the British Workers’ Compensation Act [33]. The first known US workers’ compensation claim for asbestos disease was in 1927[34]. In 1930, the first reported autopsy of an asbestosis sufferer was conducted in the United states and later presented by a doctor at the Mayo Clinic, although in this case the exposure involved mining activities somewhere in South America[35]. In 1930, the major asbestos company Johns-Manville produced a report, for internal company use only, about medical reports of asbestos worker fatalities.[36] In 1932, A letter from U.S. Bureau of Mines to asbestos manufacturer Eagle-Picher stated, in relevant part, "It is now known that asbestos dust is one of the most dangerous dusts to which man is exposed".[37] In 1933, Metropolitan Life Insurance Co. doctors found that 29% of workers in a Johns-Manville plant had asbestosis.[36] Likewise, in 1933, Johns-Manville officials settled lawsuits by 11 employees with asbestosis on the condition that the employees’ lawyer agree to never again "directly or indirectly participate in the bringing of new actions against the Corporation."[37] In 1934, officials of two large asbestos companies, Johns-Manville and RaybestosManhattan, edited an article about the diseases of asbestos workers written by a Metropolitan Life Insurance Company doctor. The changes downplayed the danger of asbestos dust.[37] In 1935, officials of Johns-

1900s–1910s
Further awareness of asbestos-related diseases can be found in the early 1900s, when London doctor H. Montague Murray conducted a post mortem exam on a young asbestos factory worker who died in 1899. Dr. Murray gave testimony on this death in connection with an industrial disease compensation hearing. The post-mortem confirmed the presence of asbestos in the lung tissue, prompting Dr. Murray to express as an expert opinion his belief that the inhalation of asbestos dust had at least contributed to, if not actually caused, the death of the worker[28]. The record in the United States was similar. Early observations were largely anecdotal in nature and did not definitively link the occupation with the disease, followed by more compelling and larger studies that strengthened the association. One such study, published in 1918, noted: All of these processes unquestionably involve a considerable dust hazard, but the hygienic aspects of the industry have not been reported upon. It may be said, in conclusion, that in the practice of American and Canadian life insurance companies, asbestos workers are generally declined on account of the assumed health-injurious conditions of the industry [29].

1920s and 1930s
Widespread recognition of the occupational risks of asbestos in Britain was reported in 1924 by a Dr. Cooke, a pathologist, who introduced a case description of a 33-year old female asbestos worker with the following: ’Medical men in areas where asbestos is

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Manville and Raybestos-Manhattan instructed the editor of Asbestos magazine to publish nothing about asbestosis.[37] In 1936, a group of asbestos companies agreed to sponsor research on the health effects of asbestos dust, but required that the companies maintain complete control over the disclosure of the results.[36]

Asbestos

1960s–early 1980s
Through the 1970s, asbestos was used to fireproof roofing and flooring, for heat insulation, and for a variety of other purposes

Modern regulation
United States
In 1989 the United States Environmental Protection Agency (EPA) issued the Asbestos Ban and Phase Out Rule which was subsequently overturned in the case of Corrosion Proof Fittings v. U.S. Environmental Protection Agency, 1991. This ruling leaves many consumer products that can still legally contain trace amounts of asbestos. For a clarification of products which legally contain asbestos read the EPA’s clarification statement.[42] The EPA has proposed a concentration limit of seven million fibers per liter of drinking water for long fibers (lengths greater than or equal to 5 µm). The Occupational Safety and Health Administration (OSHA), has set limits of 100,000 fibers with lengths greater than or equal to 5 µm per cubic meter of workplace air for 8-hour shifts and 40-hour work weeks.[43]

1940s
In 1942, an internal Owens-Corning corporate memo referred to "medical literature on asbestosis . . . . scores of publications in which the lung and skin hazards of asbestos are discussed."[36] Either in 1942 or 1943, the president of Johns-Manville, Lewis H. Brown, said that the managers of another asbestos company were "a bunch of fools for notifying employees who had asbestosis." When one of the managers asked, "do you mean to tell me you would let them work until they dropped dead?" the response is reported to have been, "Yes. We save a lot of money that way."[38] In 1944, a Metropolitan Life Insurance Company report found 42 cases of asbestosis among 195 asbestos miners.[36]

1950s
In 1951, asbestos companies removed all references to cancer before allowing publication of research they sponsored.[39] In 1952, Dr. Kenneth Smith, Johns-Manville medical director, recommended (unsuccessfully) that warning labels be attached to products containing asbestos. Later, Smith testified: "It was a business decision as far as I could understand . . . the corporation is in business to provide jobs for people and make money for stockholders and they had to take into consideration the effects of everything they did and if the application of a caution label identifying a product as hazardous would cut into sales, there would be serious financial implications."[40] In 1953, National Gypsum’s safety director wrote to the Indiana Division of Industrial Hygiene, recommending that acoustic plaster mixers wear respirators "because of the asbestos used in the product." Another company official noted that the letter was "full of dynamite" and urged that it be retrieved before reaching its destination. A memo in the files noted that the company "succeeded in stopping" the letter, which "will be modified."[41]

New Zealand
In 1984, the import of raw amphibole (blue and brown) asbestos into New Zealand was banned. In 2002 the import of chrysotile (white) asbestos was banned[44].

Australia
A complete ban on asbestos containing material in Australia was introduced in 1991 although some building materials in storage were still being used in the years that followed. Queensland began regulation of asbestos removal and disposal in 2005. Handlers of asbestos materials must have a BClass license for bonded asbestos and an AClass license for friable asbestos. The town of Wittenoom, in Western Australia was built around a (blue) asbestos mine. The town has since been closed, and is contaminated. However one couple remains there, refusing to leave the area and refusing to believe in current medical advice.

Contamination of other products
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Asbestos
Safety and Health Administration found asbestos in all four talc samples that it tested in 2000.[50]

Asbestos and vermiculite
Vermiculite is a hydrated laminar magnesium-aluminum-iron silicate which resembles mica. It can be used for many industrial applications and has been used as a replacement for asbestos. Some ore bodies of vermiculite have been found to contain small amounts of asbestos.[45] One vermiculite mine operated by W. R. Grace and Company in Libby, Montana exposed workers and community residents to danger by mining contaminated vermiculite, in 1999 the EPA began cleanup efforts and now the area is a superfund cleanup area.[46] The EPA has determined that harmful asbestos is released from the mine as well as through other activities that disturb soil in the area.[47]

Asbestos in construction
Asbestos construction in developed countries
The use of asbestos in new construction projects has been banned for health and safety reasons in many developed countries, including the European Union, Australia, Japan, and New Zealand. A notable exception is the United States, where asbestos continues to be used in construction such as cement asbestos pipes. Until the mid-1980s, white asbestos was used in the manufacture of Artex a decorative stipple finish.[52] Prior to the ban, asbestos was widely used in the construction industry. Many older buildings contain asbestos. In the United States, there is a minimum standard for asbestos surveys as described by ASTM Standard E 2356-04. The U.S. Environmental Protection Agency includes some but not all asbestos-contaminated facilities on the Superfund National Priorities list (NPL). Renovation and demolition of asbestos contaminated buildings is subject to EPA NESHAP and OSHA Regulations. Asbestos is not a material covered under CERCLA’s innocent purchaser defense. In the UK, the removal and disposal of asbestos and of substances containing it are covered by the Control of Asbestos Regulations 2006[53]

Asbestos and talc
Talc is sometimes contaminated with asbestos.[48] In 2000, tests in a certified asbestostesting laboratory found the tremolite form of amphibole asbestos in three out of eight major brands of children’s crayons (oil pastels) that are made partly from talc — Crayola, Prang, and Rose Art.[49] In Crayola crayons, the tests found asbestos levels from 0.05% in Carnation Pink to 2.86% in Orchid; in Prang crayons, the range was from 0.3% in Periwinkle to 0.54% in Yellow; in Rose Art crayons, it was from 0.03% in Brown to 1.20% in Orange. Overall, 32 different types of crayons from these brands contained more than trace amounts of asbestos, and eight others contained trace amounts. The Art and Creative Materials Institute, a trade association which tests the safety of crayons on behalf of the makers, initially insisted the test results must be incorrect, although they later said they do not test for asbestos.[49] In May 2000, Crayola said tests by a materials analyst, Richard Lee, of two of its crayons were negative for asbestos, although it later emerged that Lee had testified in lawsuits over 250 times on behalf of the asbestos industry, which paid him US$7 million.[50] In June 2000, Binney & Smith, the maker of Crayola, and the other makers agreed to stop using talc in their products, and changed their product formulations in the United States.[50] The mining company, R T Vanderbilt Co of Gouverneur, New York, which supplied the talc to the crayon makers, insists there is no asbestos in its talc "to the best of our knowledge and belief",[51] but tests by the United States Mine

Asbestos construction in developing countries
Some developing countries, such as India and China, have continued widespread use of asbestos. The most common is corrugated asbestos-cement sheets or "A/C Sheets" for roofing and for side walls. Millions of homes, factories, schools or sheds and shelters continue to use asbestos. Cutting these sheets to size and drilling holes to receive ’J’ bolts to help secure the sheets to roof framing is done on site. There has been no significant change in production and use of A/C Sheets in developing countries following the widespread restrictions in developed nations.

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Asbestos
1999 saw the introduction of the Fairness in Asbestos Compensation Act[60]. This Act was used as a tool in order to determine which of the numerous federal cases were true, and if the plaintiff’s were actually suffering from asbestos related illness. This process was necessary as thousands of false insurance claims were costing companies billions and ultimately many companies were forced to file for bankruptcy. While companies filed for bankruptcy, this limited payouts to those who were actually affected by the material. What the 1999 Act ultimately determined was “a judgment that those resources should be spent on delivering full and prompt compensation to those who are, and will become, impaired by asbestos disease, and not dissipated on payments to those who are not sick and may never become sick, on punitive damages that seek retribution for the decisions of long-dead executives for conduct that took place decades ago and on the extraordinary transaction costs (Professor Christopher Edley, Jr.).” [60] With this litigation, it was recommended by many that the framework of the Act was set in a manner that was fair towards most parties. There is no effective way to allocate funding to every claimant with the fair treatment of companies in question. Although a majority of companies involved with numerous asbestos cases are household names, they are also at the highest risk while faced with workers health concerns. The 1999 Act has effectively helped save time, money and aggravation for both sides of every asbestos case. There are fewer cases of bankruptcy and fewer cases of fraudulent medical concerns. Notable concerns with bankruptcy include the fact that once a company is forced to divide funding amongst its workers, it has a limited budget which lags on the economy and ultimately cannot contribute back the way it once was.[60] This was a main reason for the hesitation of any strict enforcement policy. However, the Act of 1999 helps to alleviate exuberant payouts to unqualified claimants, all while safely and legally protecting those who were, are and will be affected by asbestos related illnesses. Litigation exists outside the United States in England, Scotland, Ireland, the Netherlands, France, Australia, and Japan among other nations. See the companion article for further information.

Litigation
Asbestos litigation is the longest, most expensive mass tort in U.S. history, involving more than 8,400 defendants and 730,000 claimants as of 2002 according to the RAND Corporation[54], and at least one defendant reported claim counts in excess of 800,000 in 2006[55]. Current trends indicate that the worldwide rate at which people are diagnosed with asbestos-related diseases will likely increase through the next decade[56]. Analysts have estimated that the total costs of asbestos litigation in the USA alone is over $250 billion.[57] The Federal legal system in the United States has been faced with numerous counts of asbestos related suits, which often included multiple plaintiffs with similar symptoms. The concern with these court cases are the staggering numbers, which in 1999 recorded 200,000 cases pending in the Federal court system of the United States [58]. Further, it is estimated that within the next 40 years, cases may balloon to seven hundred thousand cases. These numbers help explain how there are thousands of current pending cases. Litigation of asbestos materials has been a difficult entity to muster because of the multiple factors which play a role in every case. The company that often is being exposed for their negligence of working conditions and the worker or in many cases, workers who were exposed to asbestos and did not know that they were, or knew and now fear future medical problems, have current symptoms or were upset for the negligence of the company. Companies sometimes counter saying that health issues do not currently appear in their worker or workers, or sometimes are settled out of court[59]. The Research and Development (RAND) think-tank has appropriated certain legal information which is readily available for proclaimed victims of natural resource accidents. This information, although sometimes deemed radical, has helped many workers, regardless of health condition, earn compensation through companies. RAND, along with the Institute for Civil Justice (ICJ) have been proponents of the organization of past cases in order to determine one aspect of fair compensation for workers.

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The volume of the asbestos liability has concerned manufacturers and insurers and reinsurers[61]. The amounts and method of allocating compensation have been the source of many court cases, and government attempts at resolution of existing and future cases.

Asbestos
replacements to asbestos are inferior. An example is the suggestion by Dixy Lee Ray and others that the shuttle Challenger exploded because the maker of O-ring putty was pressured by the EPA into ceasing production of asbestos-laden putty.[66][67] However, scientists point out that the putty used in Challenger’s final flight did contain asbestos, and failures in the putty were not responsible for the failure of the O-ring that led to loss of the shuttle.[67][68] Asbestos was used in the first forty floors of the World Trade Center towers causing an airborne contamination among lower Manhattan after the towers collapsed in the attacks on September 11th, 2001.[69] Steven Milloy suggests that the World Trade Center towers could still be standing or at least would have stood longer had a 1971 ban not stopped the completion of the asbestos coating above the 64th floor [70]. This was not mentioned in the National Institute of Standards and Technology’s report on the towers’ collapse. All fireproofing materials, regardless of what they are made of are required to obtain a fire-resistance rating prior to installation. All fibre-based lightweight commercial spray fireproofing materials are vulnerable to kinetic energy impacts that are outside of the fire testing upon which their ratings are based, including asbestos-based materials, and would have been removed in large areas by the impact of the planes.[71][72][73]

Critics of safety regulations
EU-Canada dispute
According to Natural Resources Canada, chrysotile asbestos is not as dangerous as once thought. According to their fact sheet, "...current knowledge and modern technology can successfully control the potential for health and environmental harm posed by chrysotile".[62] In May 1998, Canada requested consultations before the WTO with the European Commission concerning France’s 1996 prohibition of the importation and sale of asbestos.[63] Canada claimed that the French measures contravened provisions of the Agreements on Sanitary and Phytosanitary Measures and on Technical Barriers to Trade, and the GATT 1994.[63] The EC said that substitute materials had been developed in place of asbestos, which are safer to human health. It stressed that the French measures were not discriminatory, and were fully justified for public health reasons. The EC said that in the July consultations, it had tried to convince Canada that the measures were justified, and that just as Canada broke off consultations, it was in the process of submitting substantial scientific data in favour of the asbestos ban.[63] Critics of Canada’s support of the use of chrysotile asbestos argue that Canada is ignoring the risks associated with the material. The CFMEU pointed out that selling asbestos is illegal in Canada, but it is exported and most exports go to developing countries. Canada has pressured countries, including Chile, and the UN to avoid asbestos bans.[64]

Substitutes for asbestos in construction
Fiberglass insulation was invented in 1938 and is now the most commonly used type of insulation material. The safety of this material is also being called into question, as research shows that the composition of this material causes similar toxicity as asbestos.[74] In Europe stone- and glasswool are the main insulators in houses. Many companies that produced asbestoscement products that were reinforced with asbestos fibres have developed products incorporating organic fibres. One such product was known as Eternit and another "Everite" now use "Nutec" fibres which consist of organic fibres, portland cement and silica. Cement-bonded wood fiber is another substitute. Stonefibres are used in gaskets and friction materials.

Other criticism
Asbestos regulation critics include Junkscience.com author and Fox News columnist Steven Milloy and the asbestos industry.[65] Critics sometimes argue that increased regulation does more harm than good and that

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From Wikipedia, the free encyclopedia
Another potential fiber is polybenzimidazole or PBI fiber. Polybenzimidazole fiber is a synthetic fiber with high melting point of 760 °C that also does not ignite. Because of its exceptional thermal and chemical stability, it is often used by fire departments and space agencies.

Asbestos

Other asbestos-related topics
• Adequately wet • Adswood tip (in Greater Manchester in England) • Ambler, Pennsylvania • Artex • Asbestos abatement • Asbestos and the law • Asbestos fibers • Asbestos-Ceramic • Asbestosis • Asbestos, Quebec • Avondale Landfill (in Polmont in Scotland) • Brominated flame-retardant • Cemesto • Eternit • Fibro • Fireproofing • Hunt v. T&N plc • Turner & Newall • Wittenoom, former asbestos mining town • Medical geology • Mesothelioma

Old Wailuku Post Office sealed off for Asbestos Removal. Asbestos alternatives for industial use include sleeves, rope, tape, fabric and insulation batt materials made from fiberglass and silica. These products, including firesleeve, are available to protect wiring, cables, hoses, lines and pipe from AB Technology Group. (http://www.firesleeveandtape.com).

References
[1] ^ American Cancer Society [2] ^ Wisconsin Department of Natural Resources [3] WA Deer, RA Howie, J Zussman (1992). An Introduction to the Rock-Forming Minerals (2nd ed.). Longman. [4] "World Mineral Production 2002-2006" (PDF). British Geological Survey. http://nora.nerc.ac.uk/3260/2/ FINAL_WMP_2002_2006_COMPLETE_WEB.pdf. Retrieved on 2009-01-01. [5] History of Asbestos [6] Time Magazine [7] ^ Understanding Asbestos Mesothelioma Applied Research Center [8] Dehkhoda Persian Dictionary [9] ^ University of Calgary [10] A Brief History of Asbestos Use and Associated Health Risks EnvironmentalChemistry.com website [11] ^ History of science This article incorporates content from the 1728 Cyclopaedia, a publication in the public domain. [12] ^ Shipyards, a Crucible for Tragedy [13] Horrible Toll Could Have Been Avoided [14] Cancer Research [15] Asbestos in Japan

Recycling and disposal
In most developed countries, asbestos is typically disposed of as hazardous waste in landfill sites. Asbestos can also be recycled by transforming it into harmless silicate glass. A process of thermal decomposition at 1000-1250 °C produces a mixture of non-hazardous silicate phases, and at temperatures above 1250 °C it produces silicate glass.[75] Microwave thermal treatment can be used in an industrial manufacturing process to transform asbestos and asbestos-containing waste into porcelain stoneware tiles, porous singlefired wall tiles, and ceramic bricks.[76]

See also
Mineralogy
• Asbestine • List of minerals

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From Wikipedia, the free encyclopedia
[16] Australian prohibition on use of chrysotile asbestos [17] ^ Asbestos deaths just the tip of the iceberg Japan Times Online [18] ^ 2001.09.16: (Fact Sheet) Asbestos [19] Ley, Brian (1999). "Diameter of a Human Hair". The Physics Factbook. http://hypertextbook.com/facts/1999/ BrianLey.shtml. [20] Centre for disease control article on asbestos [21] Medscape article on asbestos [22] ^ Raloff, Janet (July 8, 2006) ( – Scholar search), Dirty Little Secret, http://www.sciencenews.org/articles/ 20060708/bob9.asp [23] "Not in Their Back Yard", Mother Jones, May/June 2007. [24] Meeker, G.P.; Lowers, H.A.; Swayze, G.A.; Van Gosen, B.S. (December, 2006), Mineralogy and Morphology of Amphiboles Observed in Soils and Rocks in El Dorado Hills, California, http://pubs.usgs.gov/of/2006/1362/ [25] P. Brodeur, "Annals of Law, The Asbestos Industry on Trial, 1-A Failure to Warn, The New Yorker, June 10, 1985, pp 57 [26] Chief Inspector of Factories and Workshops, "Annual Report of the Chief Inspector of Factories and Workshops for the Year 1898", 1899, cited in Tweedale referenced below [27] D. Auribault, "Note sur l’Hygiène et la Sécurité des Ouvriers dans les Filatures et Tissages d’Amianté (On hygiene and security of the workers in the spinning and weaving of asbestos)" in Le Bulletin de l’Inspection du Travail, 1906, pp 120 132. This summary was given by Broduer and roughly confirmed by Merewether & Price in the report cited below. [28] H. M. Murray, testimony before the Departmental Committee on Compensation for Industrial Diseases "Minutes of Evidence, Appendices and Index", 1907. pg 127 cited and summarized in Merewether & Price referenced below [29] F. L. Hoffman, "Mortality from Respiratory Diseases in Dusty Trades", Bulletin of the US Bureau of Labor Statistics, Vol. 231, pp 176 - 180. Mr. Hoffman was a professional statistician, employed by Prudential with an international reputation on public health matters

Asbestos
[30] W. E. Cooke, "Fibrosis of the Lungs Due to the Inhalation of Asbestos Dust," British Medical Journal, 1927, pg. 487 [31] W. E. Cooke, "Pulmonary Asbestosis," British Medical Journal, 1927, pp. 1024 1025, cited in G. Peters & B. Peters, Sourcebook on Asbestos Diseases, Volume 1, 1980, pg. G1 [32] E.R.A. Merewether & C. W. Price, "Report on Effects of Asbestos Dust on the Lung" H.M. Stationery Office, 1930 [33] Geoffrey Tweedale, Magic Mineral to Killer Dust, Turner & Newall and the Asbestos Hazard, Oxford University Press, 2001, page 21 ISBN 0199243999 [34] Broduer, pp 59 - 60 [35] R. G. Mills, "Pulmonary Asbestosis: Report of a Case", Minnesota Medicine, July 1930, pp 495 - 499 [36] ^ Barry I. Castleman, Asbestos: Medical and Legal Aspects, 4th edition, Aspen Law and Business, Englewood Cliffs, NJ 1996, p.195 [37] ^ Paul Brodeur (1985). Outrageous Misconduct: The Asbestos Industry on Trial (1st ed.). Pantheon Books. ISBN 0-394-53320-8. [38] Testimony of Charles H. Roemer, Deposition taken April 25, 1984, JohnsManville Corp., et al. v. the United States of America, U.S. Claims Court Civ. No. 465-83C, cited in Barry I. Castleman, Asbestos: Medical and Legal Aspects, 4th edition, Aspen Law and Business, Englewood Cliffs, NJ 1996, p.581 [39] Barry I. Castleman, Asbestos: Medical and Legal Aspects, 4th edition, Aspen Law and Business, Englewood Cliffs, NJ 1996, p.71 [40] Barry I. Castleman, Asbestos: Medical and Legal Aspects, 4th edition, Aspen Law and Business, Englewood Cliffs, NJ 1996, p.666 [41] Barry I. Castleman, Asbestos: Medical and Legal Aspects, 4th edition, Aspen Law and Business, Englewood Cliffs, NJ 1996, p.669-70 [42] EPA clarification statement on asbestos (PDF format) [43] Agency for toxic substances and disease registry article on asbestos [44] Journal of the New Zealand Medical Association, 05-November-2004, Vol 117 No 1205 [45] EPA Asbestos Contamination In Vermiculite

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From Wikipedia, the free encyclopedia
[46] Libby Asbestos - US EPA Region 8 [47] Risk Assessment - US EPA [48] A USGS Study of Talc Deposits and Associated Amphibole Asbestos Within Mined Deposits of the Southern Death Valley Region, California [49] ^ "Major brands of kids’ crayons contain asbestos, tests show". Seattle PostIntelligencer. 2000-05-23. http://seattlepi.nwsource.com/national/ cray23.shtml. Retrieved on 2007-11-21. [50] ^ "Crayon firms agree to stop using talc". Seattle Post-Intelligencer. 2000-06-13. http://seattlepi.nwsource.com/national/ cray13.shtml. Retrieved on 2007-11-21. [51] "Old dispute rekindled over content of mine’s talc". Seattle Post-Intelligencer. 2000-05-30. http://seattlepi.nwsource.com/national/ cra30.shtml. Retrieved on 2007-11-21. [52] Where can asbestos be found, Asbestos Surveying Ltd, Birmingham, UK, 02-08-2008.Accessed: 12-29-2008. [53] Control of Asbestos Regulations 2006, Health and Safety Exceutive, London, UK, Undated.Accessed: 12-29-2008. [54] RAND 2002 [55] Enpro Public Filings [56] Bianchi and Bianchi, "Malignant Mesothelioma: Global Incidence and Relationship with Asbestos, Industrial Health 2007, 45. 379-387. This article identifies sources for data in 37 countries including the US. Most of these sources are inadequate to directly measure mesothelioma incidence over time, but it is clear that rates vary, and are influenced by the amount of asbestos used, how it was used, and when it was last used. See also Peto, Decarli, LaVecchia, Levi, and Negri "The European Mesothelioma Epidemic" British Journal of Cancer (1999), 79 (3/ 4), 666-672 which projects mesothelioma incidence in six countries in Europe (France, Germany, Britain, Italy, Netherlands, and Switzerland) as modified in Pelucci, Malvezzi, LaVecchia, Levi, Decarli and Negri, "The Mesothelioma Epidemic in Western Europe: an Update" Brit. J. of Cancer (2004) 90, 1022-1024 [57] The Economist, January 26, 2005

Asbestos

[58] United States. Cong. Hearing: Asbestos Litigation. 107th Cong., 2nd sess. HRG.107-993. Washington: GPO, 2002. [59] Carroll, Stephen J., Deborah Hensler, Allan Abrahamse, Jennifer Gross, Michelle White, Scott Ashwood, and Elizabeth Sloss. Asbestos Litigation Costs and Compensation. Santa Monica,CA: RAND, 2002. [60] ^ United States. Cong. Senate. Finding Solutions to the Asbestos Litigation Problem: the Fairness in Asbestos Compensation Act of 1999. 106nd Cong., 1st sess. S.758. Washington: GPO, 1999. [61] American Academy of Acturaries’ Mass Torts Subcomittee, "Overview of Asbestos Claims Issues and Trends, August 2007 pp 7 - 8 [62] Chrysolite Asbsetos Fact Sheet [63] ^ EC measures affecting asbestos products World Trade Organization [64] Stop Canada’s Export Of Asbestos CFMEU [65] Multinational Monitor article on Corporate junk science, retrieved December 16th, 2006 [66] Lehr, Jay H., editor (1992). Rational Readings on Environmental Concerns. Van Nostrand Reinhold. ISBN 0-442-01146-6. http://books.google.com/ books?id=LsXmMHOT8VsC&pg=PA119&ots=umUm U0TgY-TiA. [67] ^ Asbestos and Challenger Disaster [68] MSNBC article on myths of the Challenger disaster, retrieved December 16th, 2006 [69] The Junkman’s Answer to Terrorism: Use More Asbestos, retrieved July 16th, 2007 [70] Fox News - Asbestos Fireproofing Might Have Prevented World Trade Center Collapse, retrieved July 27th, 2007 [71] Asbestos and the WTC collapse, retrieved December 16th, 2006 [72] Center for Fire Research PDF, retrieved December 16th, 2006 [73] Why Did the World Trade Center Collapse? Science, Engineering, and Speculation, retrieved December 16th, 2006 [74] "Fiber Glass: A Carcinogen That’s Everywhere". Rachel’s News (Environmental Research Foundation). 1995-05-31. http://www.rachel.org/en/ node/3999. Retrieved on 2008-10-30. [75] A F Gualtieri and A Tartaglia (August 2000). "Thermal decomposition of

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From Wikipedia, the free encyclopedia

Asbestos

asbestos and recycling in traditional • Control of Asbestos in Singapore ceramics". Journal of the European Ceramic Society 20 (9): 1409–1418. Mineral and mining links doi:10.1016/S0955-2219(99)00290-3. • Parachrysotile (asbestos) at the http://www.sciencedirect.com/ webmineral.com Mineral Database science?_ob=ArticleURL&_udi=B6TX0-40NFSHM- of Minn.: Asbestos • Univ. W&_user=10&_coverDate=08%2F31%2F2000&_rdoc=1&_fmt=&_orig=search&_sort=d&view=c&_a • Asbestos Newspaper Articles Archive Retrieved on 2007-11-20. • White Gold Pioneers: Asbestos [76] C Leonelli, P Veronesi, D N Boccaccini, Mining—The origins of asbestos mining, M R Rivasi, L Barbieri, F Andreola, I illustrated with many early photographs Lancellotti, D Rabitti, and G C Pellacani (2006-07-31). "Microwave thermal Health and the environment inertisation of asbestos containing waste • About Your House — General Series — and its recycling in traditional ceramics". Asbestos Journal of Hazardous Materials 135 • Hazards magazine’s comprehensive (1-3): 149–155. doi:10.1016/ asbestos resource pages j.jhazmat.2005.11.035. • The Miracle Mineral Fiber - Asbestos • CBC Digital Archives - Asbestos: Magic mineral or deadly dust? • An article on the health impact of asbestos • George B. Guthrie and Brooke T. from Liverpool’s ’Nerve’ magazine Mossman, editors, Health Effects of • The Wittenoom Tragedy, Asbestos Mineral Dusts, Mineralogical Society of Diseases Society of Australia. America Reviews in Mineralogy v. 28, 584 • Health and Safety - Asbestosis (TUC pages (1993) ISBN 0-939950-33-2 Resources, UK) • International Asbestos Victims Memorial • About Asbestos European Agency for Safety and Health at Work (OSHA) • Asbestos contamination near abandoned Regulatory and government mine links • Asbestos Health Risk Assessment • U.S. EPA Asbestos Home Page • A USGS map of "Naturally Occurring • ATSDR Case Studies in Environmental Asbestos" in Eastern America Medicine: Asbestos Toxicity U.S. • Shipbuilding’s Deadly Legacy (series of Department of Health and Human articles from a Newspaper local to Services Hampton Roads, VA) • Asbestos and Occupational Health in the • EPA refused to warn of asbestos dangers World • Asbestos Danger: Do You Have Zonolite In • British Government Health and Safety Your Attic? Executive (HSE) • A guide to asbestos in the home (From • National Institute for Occupational Safety The Wrekin Housing Trust) and Health - Asbestos Page

Additional reading

External links

Retrieved from "http://en.wikipedia.org/wiki/Asbestos" Categories: Asbestos, Fibers, Hazardous air pollutants, Occupational safety and health, IARC Group 1 carcinogens This page was last modified on 22 May 2009, at 18:50 (UTC). All text is available under the terms of the GNU Free Documentation License. (See Copyrights for details.) Wikipedia® is a registered trademark of the Wikimedia Foundation, Inc., a U.S. registered 501(c)(3) taxdeductible nonprofit charity. Privacy policy About Wikipedia Disclaimers

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