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Energy Role of Hydrogen and NETL

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Energy, Role of Hydrogen, and NETL West Virginia Energy Roadmap for Hydrogen Stonewall Resort Roanoke, WV November 19-20, 2003 Rita A. Bajura, Director National Energy Technology Laboratory Office of Fossil Energy Outline • Definition of hydrogen energy future • Drivers • Technology status • WV situation analysis • Closing comments Photo: NREL RAB 11/19/03 U.S. Energy Today Renewable 6% Nuclear 8% Coal 23% N. Gas 24% 34% Other 39% Electricity Petroleum 39% 27% Transportation End Use Primary Energy 2000 Data . DOE/EIA Annual Energy Outlook 2003 RAB 11/19/03 Hydrogen Energy Future: A Notional View 2050 Other Fuel Electricity Energy Mix TBD Conservation/ Efficiency Other Onsite H2 Use Electricity Transportation H2 Onsite H2 Fuel Cells H2 Fueled Vehicles RAB 11/19/03 Low Carbon Emission Primary Energy End Use Confluence of Drivers for H2 Energy Future Urban Pollution Worries Increasing Political Will Climate Change Concerns Energy Security – Oil Imports Fuel Cell Technology Maturing RAB 11/19/03 While Air Emissions Down Sharply, Pressure to Further Reduce 150% Growth and Emissions 164% 159% Gross Domestic Product Vehicle Miles Traveled 100% 42% 50% 38% Energy Consumption U.S. Population 0% - -48% - Aggregate Emissions (6 Pollutants) EPA Emission Trends RAB 11/19/03 70 80 90 95 96 97 98 99 00 01 02 Year CO2 From Energy Is Major Contributor to Anthropogenic Greenhouse Gas Emissions U.S. GHG Emissions Weighted by Global Warming Potential Other CO2 1.7% CO2 from 2 Energy 82% Methane 9.0% Nitrous Oxide 5.6% Other Gases 2.1% EIA Report #EIA/DOE-0573 “Emissions of Greenhouse Gases in the U.S. 1999,” Executive Summary (Oct. 2000) RAB 11/19/03 It Probably Doesn’t Matter ─ The Issue Is Here to Stay • Science unlikely to provide Global Climate Change: Fact or Fiction? unequivocal causality answer • Governments and markets likely to act on their perception of the science Portions based on Executive Action Brief No. 23, June 2002,The Conference Board RAB 11/19/03 Patchwork of State & Local GHG Programs Seattle, WA: Goal of zero net GHG emissions from electric; purchased reductions from OR Climate Trust OR: New power plants 17% CO2 below most efficient natural gas plant; purchase credits from OR Climate Trust or approved projects Portland, OR: 20% below 1988 CO2 emissions by 2010 CA: GHG registry being developed OK: Law allows OK to certify carbon sequestration from changes in farming practices WI: GHG registry being developed NH: 4P legislation requiring 3 power plants to reduce CO2 emissions to 1990 levels passed House; purchase credits from 11 NE states; GHG registry being developed MA: Law requiring 10% cut in CO2 emissions from 6 power plants; may purchase CO2 offsets; GHG registry being developed NY: GHG Task Force established; recommendations for federal 4P reductions NJ: GHG reduction target of 3.5% below 1990 levels by 2005; voluntary generation of GHG credits/banking in NJ credit registry Neil Cohn, Natsource Emissions Desk, April 30th, 2002 RAB 11/19/03 TX: GHG registry being developed States With Incentives for Renewables 38 states have one or more incentives: • State income tax credit • Renewable portfolio standard / goal • State / utility / local buydown program • State grant program Database of State Incentives for Renewable Energy, WWW.dsireusa.org RAB 11/19/03 Fuel Cell Technology Maturing Phosphoric Acid • IFC • 220 200-kW units • > Six “9’s” reliability Molten Carbonate • Fuel Cell Energy • 50 MW/year manufacturing plant • 10 million kWh generated RAB 11/19/03 Nothing Matches Fuel Cell Efficiency Transportation and Stationary Power 100 80 60 40 20 0 0.01 High-T Fuel Cells Low-T Fuel Cells High-T Hybrid Fuel Cells Gas Turbine Combined-Cycles Diesel Engines IGCC PC Gasoline Engines Gas Engines Micro and Adv Turbines Efficiency (% LHV) 0.1 1 10 100 1000 Power Output (MWe) Gas Engine - GRI Diesel Engine - California Advanced Reciprocating Internal Combustion Engines Collaborative, Workshop Proceedings, July 2001 RAB 11/19/03 Fuel Cells Are an Enabling Technology for Hydrogen Future Hydrogen Basically a battery with an external supply of fuel and oxidant Electron Flow Anode Electrolyte Electricity Cathode + Oxygen from Air Pure Water Cells stacked together for desired power Issue: Cost • Fuel cells cost $1,600 - $4,500 per kilowatt • Internal combustion engines cost = $35 per kilowatt RAB 11/19/03 3-10 kW Solid State Fuel Cells for Multiple Applications 2005 Beta Prototype • $800 / kW − Premium power − Auxiliary power in long-haul trucks − Military 2015 2010 Product • $400 / kW • Vision 21 power plants • Hybrid systems − Residential − Industrial CHP RAB 11/19/03 Six SECA Industry Teams General Electric Company FuelCell Energy, Inc. RAB 11/19/03 Energy Security: U.S. Oil Imports Rising 30 Actual Projected 25 Million BBLs/day Consumption 20 15 10 5 0 1970 68% Imports in 2025 55% Net Imports Today Domestic supply 1980 1990 2000 2010 2025 DOE/EIA Annual Energy Outlook 2003 RAB 11/19/03 Petroleum Supply, Consumption, and Imports 1970-2025 World Light Oil Supply Is Finite Pratt 1942 Weeks 1948 MacNaughton 1953 Weeks 1959 Shell 1968 Moody 1970 Moody 1972 Linden 1973 Adams & Kirby 1975 Folinsbee 1976 Nelson 1977 Nehring 1979 Meyerhoff 1979 Halbouty 1981 Nehring 1982 Martin 1984 Masters 1987 Bookout 1989 Campbell 1992 Masters 1994 Campbell 1995 USGS 95% 2000 USGS Mean 2000 USGS 5% 2002 Mean 2.25 Trillion Barrels Published Estimates World Oil Ultimate Recovery Trillions of Barrels 0 1 2 3 4 USGS and Colin Campbell RAB 11/19/03 Estimated Date of Peak Light Oil Production Billion BBLs / year 40 30 20 10 0 1950 2.2 2.6 Assumed World Oil Resource 1.8 Trillion BBLS 1970 1990 2010 2030 World Resources Institute RAB 11/19/03 Hydrogen Can Be Produced From Many Domestic Energy Sources Natural Gas Biomass Nuclear Power Future Hydrogen • Fusion • Thermochemical • Photochemical Coal Solar / Wind Biomass photo: NREL, Calvert Cliffs Nuclear Plant RAB 11/19/03 Increasing Political Will President Bush Launches Hydrogen and Related Initiatives • Hydrogen • FreedomCAR • FutureGen • Carbon Sequestration RAB 11/19/03 Beginnings of Hydrogen Infrastructure Exists • World annual production equivalent to 1.5% of primary energy • Most produced by major Refineries Methanol Other industrial gas suppliers: − − − − − Air Liquide Air Products BOC Linde Praxair Ammonia • Used principally as Space D. Hart, P. Freund and A. Smith, Hydrogen — Today and Tomorrow, IEA Greenhouse Gas R&D Programme, April 1999 RAB 11/19/03 industrial commodity Hydrogen Refueling Stations CTA Chicago, IL CaFCP Ford Dearborn, MI Sacramento, CA Erie, PA RAB 11/19/03 Hydrogen - Inherently Good But Economically Challenged • Not naturally occurring − Process derived • Low energy density • Safety challenged • Expensive to: − Produce − Store − Deliver − Transfer RAB 11/19/03 U.S. DOE Developing Hydrogen R&D Plans RAB 11/19/03 DOE’s Hydrogen Program Sets Goals for Infrastructure Development Storage Hydrogen Production Delivery Transfer Hydrogen Use Hydrogen Storage on Metal Hydrides RAB 11/19/03 Technology Can Enable Coal to Be Preferred Source for Future H2 Production U.S. Fossil Fuel Reserves / Production Ratio Years Supply at Current Production • Abundant reserves • Low and stable 300 246 200 Coal Oil Natural Gas prices • Technology improvements − Could enable nearzero emissions of air pollutants/GHGs 100 11.7 0 9.2 EIA- U.S. Crude Oil, Natural Gas, and Natural Gas Liquids Reserves: 2001 Annual Report, November 2002; Coal: BP Statistical Review, June 2002, World Energy Council RAB 11/19/03 FutureGen One billion dollar, 10-year demonstration project to create world’s first coal-based, zero-emission electricity and hydrogen plant President Bush, February 27, 2003 RAB 11/19/03 FutureGen Concept Hydrogen Pipeline Oil Pipeline E le c tric it y Refinery and / or Coal-Fired IGCC CO 2 Pipeline Enhanced Oil Recovery Geologic Sequestration RAB 11/19/03 Industry Group Announced Formation of FutureGen Consortium • American Electric Power • CINergy • PacifiCorp • Southern Company • TXU (Texas Utilities) • CONSOL • Kennecott Energy • North American Coal • Peabody Energy • RAG American Coal Holding Charter members represent ∼1/3 coalCharter members represent ∼1/3 coalfired utilities and ∼1/2 U.S. coal industry fired utilities and ∼1/2 U.S. coal industry RAB 11/19/03 FutureGen Uses Coal Gasification Technology IGCC in Early Commercialization • Wabash River −1996 Powerplant of Year Award* − Achieved 95% availability • Tampa Electric − 1997 Powerplant of Year Award* − First dispatch power generator *Power Magazine RAB 11/19/03 Significant Worldwide Gasification Capacity Cumulative Capacity GWth Syngas 70 60 50 40 30 20 10 0 1975 1985 1995 2005 Planned Real 130 Operating Gasification Plants • 400 gasifiers • 43,300 MWth of synthesis gas equivalent • 24,000 MWe IGCC Year DOE’s Worldwide Gasification Database, 2001 RAB 11/19/03 Why Integrated Gasification Combined Cycle? • Fuel and product flexibility • Environmentally superior • High efficiency • Sequestration ready Producing concentrated stream of CO2 at high pressure • Improves sequestration economics • Reduces efficiency penalty RAB 11/19/03 Approaches to Sequester Carbon Capture and Storage Enhance Natural Processes Unmineable Coal Seams Forestation Deep Ocean Injection Depleted Oil / Gas Wells, Saline Reservoirs Iron or Nitrogen Fertilization of Ocean Enhanced Photosynthesis RAB 11/19/03 Why Sequestration Is Important Sequestration Advantages One of Three Carbon Management Options • Switch to low- and • Compatible with existing energy infrastructures • May prove to be lowest no-carbon fuels • Increase energy cost option efficiency • Sequester carbon RAB 11/19/03 Large Potential Worldwide Storage Capacity 100,000 10,000 Potential Capacity Range Capacity (Gigatons) 6,000 5,000 4,000 3,000 2,000 1,000 0 Deep Saline Depleted Depleted Coal Ocean Reservoirs Oil Gas Seams Reservoirs Reservoirs Annual World Emissions 6.2 Gigatons Storage Option Storage Options: IEA Greenhouse Gas R&D Program; Advanced Resources International estimates for coal seams World Emissions: International Energy Outlook 2000, Table A10 RAB 11/19/03 One Million TPY CO2 Sequestration Projects Weyburn CO2 Project • Pan Canadian Resources • Enhanced oil recovery coupled with sequestration Sleipner North Sea Project • Statoil • Production of natural gas with high CO2 content • CO2 sequestered in saline reservoir under sea Sequestration Is Feasible RAB 11/19/03 DOE Sequestration Program Is Dynamic • Diverse research portfolio −70 projects • Strong industry support −40% cost share • $140M value of R&D portfolio RAB 11/19/03 National Energy Technology Laboratory • One of DOE’s 17 national labs • Sites in West Virginia, Pennsylvania, Oklahoma, Alaska • Implements DOE’s R&D programs in coal, oil, natural gas • 1,100 Federal and contractor employees • $750 million per year budget RAB 11/19/03 How Can WV Participate in Hydrogen Future? RAB 11/19/03 Many States Have Hydrogen Activities • Hawaii – State H2 Plan • California – Fuel Cell Partnership • North Dakota – Coal Gasification/Sequestration • Florida – Solar H2 Initiative • Michigan – FreedomCar/ Next Energy • Ohio – Fuel Cell Initiative • Montana – Montana Energy Futures Coalition Photo: NREL RAB 11/19/03 Canadian Hydrogen Experience Stakes are Large! • 2001-2002 −32 companies −$97 million revenue −$179 million R&D −1,772 jobs • Projected 2002-2003 growth −$165 million −$358 million R&D −2,639 jobs Photos: NREL RAB 11/19/03 Hydrogen Industries • Engineering • H2 production equipment • Testing equipment • Fuel cells • Power generators • H2 storage • H2 transportation • Distributed energy • Electrical components • Purification services • Engines • Safety products • NOx reduction • Fuel reformation • Gas sensors • Carbon sequestration • Coal gasification • Safety training • Many more to come equipment • Pressure devises • Pressure regulators • Evaluation and certification services RAB 11/19/03 Coal in West Virginia • 16,200 payroll jobs • 99% of electricity produced using coal − Average cost $0.05/kWh • 54 billion tons coal reserves − Produced 163 million tons in 2002 • Contributes 13% to State GDP • Coal and electricity industry pay 60% of WV’s business tax The Hydrogen Economy in WV: 2002, Alzate and Will, Bureau of Business and Economic Research, July 2003 RAB 11/19/03 U.S. CO2 Emissions From Fossil Fuel Combustion 2,500 2,000 1,500 Relative Contribution by Fuel Type Natural Gas Petroleum Coal Tg CO2 Eq. 1,000 500 0 Industrial Electric Residential Commercial U.S. Territories Transportation Table 2-3, EPA 430-R-02-003, April 2002 Inventory of U.S. Greenhouse Gas Emissions and Sinks: 1990-2000 RAB 11/19/03 West Virginia Situation Analysis • Coal critical to WV economy and potential target for carbon emission limits • Chemical industry has H2 production expertise • Research institutions have H2 production expertise • Potential H2 pipeline right-of- ways along pipelines/electric transmission lines centers • Near east coast population • Potential sites for geological sequestration RAB 11/19/03 WV Has Many Potential Geologic Sequestration Sites Legend: 1 to 2 Formations 3 to 4 Formations 5 to 6 Formations 7 to 8 Formations 9 to 10 Formations 11 to 12 Formations Appalachian Basin NETL, Curt White RAB 11/19/03 In Closing . . . Energy Industry Being Transformed as It Moves Toward a Hydrogen Future Electricity Sector Transportation Sector RAB 11/19/03 Coal Gasification/Carbon Sequestration Path Is Promising • U.S. has an abundance of coal — easily enough to get to 2100 • We have technology to gasify coal and sequester CO2 • Coal-based H2 and electricity production with near-zero carbon emissions appears less expensive than most other approaches Ray Smith, LLNL, Southwest Renewable Energy, Conference, Flagstaff, AZ, August 7, 2003 RAB 11/19/03 For West Virginia . . . Gasification plus carbon sequestration Gasification plus carbon sequestration provides opportunity for coal: provides opportunity for coal: To continue to be used for electric production To produce H2 and capture portions of transportation fuel market RAB 11/19/03 Where U.S. Could Be in 2050 Today Renewables 6% Natural Gas 24% Coal 23% Oil 39% 2050 Doubling of Energy Use Natural Gas 10% Hydrogen Fuels Coal 50% Near-Zero Emission Electricity Renewables 20% Oil 10% Nuclear 10% Nuclear 8% Total projection an extrapolation of EIA “Reference Case” (1999-2020) Based on Ray Smith, LLNL, Southwest Renewable Energy Conference, Flagstaff, AZ, August 7, 2003 RAB 11/19/03 Should There Be a WV Hydrogen Initiative? Should It Focus on CoalBased Hydrogen Production ? RAB 11/19/03

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