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Biofuel

Biofuel
Globally, biofuels are most commonly used to power vehicles, heat homes, and for cooking. Biofuel industries are expanding in Europe, Asia and the Americas. Recent technology developed at Los Alamos National Lab even allows for the conversion of pollution into renewable bio fuel.[1] Agrofuels are biofuels which are produced from specific crops, rather than from waste processes such as landfill off-gassing or recycled vegetable oil.[2] There are two common strategies of producing liquid and gaseous agrofuels. One is to grow crops high in sugar (sugar cane, sugar beet, and sweet sorghum[3]) or starch (corn/maize), and then use yeast fermentation to produce ethyl alcohol (ethanol). The second is to grow plants that contain high amounts of vegetable oil, such as oil palm, soybean, algae, jatropha, or pongamia pinnata. When these oils are heated, their viscosity is reduced, and they can be burned directly in a diesel engine, or they can be chemically processed to produce fuels such as biodiesel. Wood and its byproducts can also be converted into biofuels such as woodgas, methanol or ethanol fuel[4]. It is also possible to make cellulosic ethanol from non-edible plant parts, but this can be difficult to accomplish economically.[5].

The 2005 Volvo FlexiFuel S40 was one of the first E85 flexible fuel cars produced by a Swedish automaker. The Volvo FlexiFuel is now offered on the European market.

Biomass
E95 trial bus operating in São Paulo, Brazil.
Renewable energy

Biofuel Biomass Geothermal Hydropower Solar power Tidal power Wave power Wind power

Sugar cane can be used as a biofuel or food. Biomass or biofuel is material derived from recently living organisms. This includes plants, animals and their by-products. For example, manure, garden waste and crop residues are all sources of biomass. It is a renewable energy source based on the carbon cycle, unlike other natural resources such as petroleum, coal, and nuclear fuels. It is used to produce power, heat & steam and fuel, through a number of different processes. Although

Biofuel is defined as solid, liquid or gaseous fuel obtained from relatively recently lifeless or living biological material and is different from fossil fuels, which are derived from long dead biological material. Also, various plants and plant-derived materials are used for biofuel manufacturing.

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renewable, biomass often involves a burning process that produces emissions such as Sulphur Dioxide (SO2), Nitrogen Oxides (NOx) and Carbon Dioxide (CO2), but fortunately in quantities far less than those emitted by coal plants. However, proponents of coal plants feel that their way of doing it is a lot cheaper and there is a lot of dispute over this. Biomass is one of the few forms of energy that can be used in a carbon negative manner. When biomass is combusted to produce heat, it releases less carbon than was absorbed by the plant material during the plant’s lifecycle. This is because (1) approximately one third of the carbon absorbed by the plant during its life is sequestered in its roots, which are left in the soil to rot and fertilize nearby plant life, and (2) combustion of biomass produces 1-10% solid ash (depending on type of plant used), which is extremely high in carbon (this ash is commonly used as fertilizer). Animal waste is a persistent and unavoidable pollutant produced primarily by the animals housed in industrial-size farms. Researchers from Washington University have figured out a way to turn manure into biomass. In April 2008 with the help of imaging technology they noticed that vigorous mixing helps microorganisms turn farm waste into alternative energy, providing farmers with a simple way to treat their waste and convert it into energy.[6] There are also agricultural products specifically grown for biofuel production including corn, switchgrass, and soybeans, primarily in the United States; rapeseed, wheat and sugar beet primarily in Europe; sugar cane in Brazil; palm oil and miscanthus in SouthEast Asia; sorghum and cassava in China; and jatropha and pongamia pinnata in India; pongamia pinnata in Australia and the tropics. Hemp has also been proven to work as a biofuel. Biodegradable outputs from industry, agriculture, forestry and households can be used for biofuel production, either using anaerobic digestion to produce biogas, or using second generation biofuels; examples include straw, timber, manure, rice husks, sewage, and food waste. Biomass can come from waste plant material. The use of biomass fuels can therefore contribute to waste management as well as fuel security and help to prevent global warming, though alone they are not a comprehensive solution to these problems.

Biofuel

Energy from bio waste
Using waste biomass to produce energy can reduce the use of fossil fuels, reduce greenhouse gas emissions and reduce pollution and waste management problems. A recent publication by the European Union highlighted the potential for waste-derived bioenergy to contribute to the reduction of global warming. The report concluded that the equivalent of 19 million tons of oil is available from biomass by 2020, 46% from bio-wastes: municipal

Filtered waste vegetable oil. solid waste (MSW), agricultural residues, farm waste and other biodegradable waste streams.[7][8] Landfill sites generate gases as the waste buried in them undergoes anaerobic digestion. These gases are known collectively as landfill gas (LFG). This is considered a source of renewable energy, even though landfill disposal is often non-sustainable. Landfill gas can be burned either directly for heat or to generate electricity

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for public consumption. Landfill gas contains approximately 50% methane, the gas found in natural gas. Land fill gas can be easily purified and then fed into the Natural Gas grid. If landfill gas is not harvested, it escapes into the atmosphere: this is undesirable because methane is a greenhouse gas with much more global warming potential than carbon dioxide.[9][10] Over a time span of 100 years, one ton of methane produces the same greenhouse gas (GHG) effect as 21 tons of CO2.[11] When methane burns, it produces carbon dioxide in the ratio 1:1 -CH4 + 2O2 = CO2 + 2H2O. So, by harvesting and burning landfill gas, its global warming potential is reduced a factor of 23, in addition to providing energy for heat and power. It was recently discovered that living plants also produce methane.[12] The amount is 10 to 100 times greater than that produced by dead plants in an aerobic environment but does not increase global warming because of the carbon cycle.[13] Anaerobic digestion can be used as a waste management strategy to reduce the amount of waste sent to landfill and generate methane, or biogas. Any form of biomass can be used in anaerobic digestion and will break down to produce methane, which can be harvested and burned to generate heat, power or to power certain automotive vehicles. A current project for a 1.6 MW landfill power plant is projected to provide power for 880 homes.[14] It is estimated that this will eliminate 3,187 tons of methane and directly eliminate 8.756 tons of carbon dioxide release per year. This is the same as removing 12,576 cars from the road, or planting 15,606 trees, or not using 359 rail cars of coal per year.

Biofuel

In some countries biodiesel is less expensive than conventional diesel. technology.[15] The basic feedstocks for the production of first generation biofuels are often seeds or grains such as wheat, which yields starch that is fermented into bioethanol, or sunflower seeds, which are pressed to yield vegetable oil that can be used in biodiesel. These feedstocks could instead enter the animal or human food chain, and as the global population has risen their use in producing biofuels has been criticised for diverting food away from the human food chain, leading to food shortages and price rises. The most common first generation biofuels are listed below.

Liquid fuels for transportation
Most transportation fuels are liquids, because vehicles usually require high energy density, as occurs in liquids and solids. Vehicles usually need high power density as can be provided most inexpensively by an internal combustion engine. These engines require clean burning fuels, in order to keep the engine clean and minimize air pollution. The fuels that are easier to burn cleanly are typically liquids and gases. Thus liquids (and gases that can be stored in liquid form) meet the requirements of being both portable and clean burning. Also, liquids and gases can be pumped, which means handling is easily mechanized, and thus less laborious.

Vegetable oil
Edible vegetable oil is generally not used as fuel, but lower quality oil can be used for this purpose. Used vegetable oil is increasingly being processed into biodiesel, or (more rarely) cleaned of water and particulates and used as a fuel. To ensure that the fuel injectors atomize the fuel in the correct pattern for efficient combustion, vegetable oil fuel must be heated to reduce its viscosity to that of diesel, either by electric coils or heat exchangers. This is easier in warm or temperate climates. MAN B&W Diesel, Wartsila and Deutz AG offer engines

Types
First generation biofuels
’First-generation biofuels’ are biofuels made from sugar, starch, vegetable oil, or animal fats using conventional

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that are compatible with straight vegetable oil, without the need for after-market modifications. Vegetable oil can also be used in many older diesel engines that do not use common rail or unit injection electronic diesel injection systems. Due to the design of the combustion chambers in indirect injection engines, these are the best engines for use with vegetable oil. This system allows the relatively larger oil molecules more time to burn. However, a handful of drivers have experienced limited success with earlier pre-"pumped use" VW TDI engines and other similar engines with direct injection.

Biofuel
old deposits in the fuel tank and pipes. It also effectively cleans the engine combustion chamber of carbon deposits, helping to maintain efficiency. In many European countries, a 5% biodiesel blend is widely used and is available at thousands of gas stations.[16][17] Biodiesel is also an oxygenated fuel, meaning that it contains a reduced amount of carbon and higher hydrogen and oxygen content than fossil diesel. This improves the combustion of fossil diesel and reduces the particulate emissions from un-burnt carbon. Biodiesel is safe to handle and transport because it is as biodegradable as sugar, 10 times less toxic than table salt, and has a high flashpoint of about 300 F compared to petroleum diesel fuel, which has a flash point of 125 F.[18]. In the USA, more than 80% of commercial trucks and city buses run on diesel. The emerging US biodiesel market is estimated to have grown 200% from 2004 to 2005. "By the end of 2006 biodiesel production was estimated to increase fourfold [from 2004] to more than 1 billion gallons,".[19]

Biodiesel
Biodiesel is the most common biofuel in Europe. It is produced from oils or fats using transesterification and is a liquid similar in composition to fossil/mineral diesel. Its chemical name is fatty acid methyl (or ethyl) ester (FAME). Oils are mixed with sodium hydroxide and methanol (or ethanol) and the chemical reaction produces biodiesel (FAME) and glycerol. One part glycerol is produced for every 10 parts biodiesel. Feedstocks for biodiesel include animal fats, vegetable oils, soy, rapeseed, jatropha, mahua, mustard, flax, sunflower, palm oil, hemp, field pennycress, pongamia pinnata and algae. Pure biodiesel (B100) is by far the lowest emission diesel fuel. Although liquefied petroleum gas and hydrogen have cleaner combustion, they are used to fuel much less efficient petrol engines and are not as widely available. Biodiesel can be used in any diesel engine when mixed with mineral diesel. The majority of vehicle manufacturers limit their recommendations to 15% biodiesel blended with mineral diesel. In some countries manufacturers cover their diesel engines under warranty for B100 use, although Volkswagen of Germany, for example, asks drivers to check by telephone with the VW environmental services department before switching to B100. B100 may become more viscous at lower temperatures, depending on the feedstock used, requiring vehicles to have fuel line heaters. In most cases, biodiesel is compatible with diesel engines from 1994 onwards, which use ’Viton’ (by DuPont) synthetic rubber in their mechanical injection systems. Electronically controlled ’common rail’ and ’pump duse’ type systems from the late 1990s onwards may only use biodiesel blended with conventional diesel fuel. These engines have finely metered and atomized multi-stage injection systems are very sensitive to the viscosity of the fuel. Many current generation diesel engines are made so that they can run on B100 without altering the engine itself, although this depends on the fuel rail design. NExBTL is suitable for all diesel engines in the world since it overperforms DIN EN 590 standards. Since biodiesel is an effective solvent and cleans residues deposited by mineral diesel, engine filters may need to be replaced more often, as the biofuel dissolves

Bioalcohols

Information on a pump in California.

The Koenigsegg CCXR Edition at the 2008 Geneva Motor Show. This is an "environmentally-friendly" version of the CCX, which can use E85 and E100.

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Biologically produced alcohols, most commonly ethanol, and less commonly propanol and butanol, are produced by the action of microorganisms and enzymes through the fermentation of sugars or starches (easiest), or cellulose (which is more difficult). Biobutanol (also called biogasoline) is often claimed to provide a direct replacement for gasoline, because it can be used directly in a gasoline engine (in a similar way to biodiesel in diesel engines). Butanol is formed by ABE fermentation (acetone, butanol, ethanol) and experimental modifications of the process show potentially high net energy gains with butanol as the only liquid product. Butanol will produce more energy and allegedly can be burned "straight" in existing gasoline engines (without modification to the engine or car),[20] and is less corrosive and less water soluble than ethanol, and could be distributed via existing infrastructures. DuPont and BP are working together to help develop Butanol. E. coli have also been successfully engineered to produce Butanol by hijacking their amino acid metabolism[21]. Ethanol fuel is the most common biofuel worldwide, particularly in Brazil. Alcohol fuels are produced by fermentation of sugars derived from wheat, corn, sugar beets, sugar cane, molasses and any sugar or starch that alcoholic beverages can be made from (like potato and fruit waste, etc.). The ethanol production methods used are enzyme digestion (to release sugars from stored starches), fermentation of the sugars, distillation and drying. The distillation process requires significant energy input for heat (often unsustainable natural gas fossil fuel, but cellulosic biomass such as bagasse, the waste left after sugar cane is pressed to extract its juice, can also be used more sustainably). Ethanol can be used in petrol engines as a replacement for gasoline; it can be mixed with gasoline to any percentage. Most existing automobile petrol engines can run on blends of up to 15% bioethanol with petroleum/ gasoline. Gasoline with ethanol added has higher octane, which means that your engine can typically burn hotter and more efficiently. In high altitude (thin air) locations, some states mandate a mix of gasoline and ethanol as a winter oxidizer to reduce atmospheric pollution emissions. Ethanol fuel has less BTU energy content, which means it takes more fuel (volume and mass) to produce the same amount of work. An advantage of ethanol is that is has a higher octane rating than ethanol-free gasoline available at roadside gas stations and ethanol’s higher octane rating allows an increase of an engine’s compression ratio for increased thermal efficiency.. Very-expensive aviation gasoline (Avgas) is 100 octane made from 100% petroleum with toxic tetra-ethyl lead added to raise the octane number. The high price of zero-ethanol Avgas does not include federal-and-state road-use taxes.

Biofuel
Ethanol is very corrosive to fuel systems, rubber hoses and gaskets, aluminum, and combustion chambers. Therefore, it is illegal to use fuels containing alcohol in aircraft (although at least one model of ethanolpowered aircraft has been developed, the Embraer EMB 202 Ipanema). Ethanol also corrodes fiberglass fuel tanks such as used in marine engines. For higher ethanol percentage blends, and 100% ethanol vehicles, engine modifications are required. It is the hygroscopic (water loving) nature of relatively polar ethanol that can promote corrosion of existing pipelines and older fuel delivery systems. To characterize ethanol itself as a corrosive chemical is somewhat misleading and the context in which it can be indirectly corrosive, somewhat narrow; i.e., limited to effects upon existing pipelines designed for petroleum transport. Corrosive ethanol cannot be transported in petroleum pipelines, so more-expensive over-the-road stainless-steel tank trucks increase the cost and energy consumption required to deliver ethanol to the customer at the pump. In the current alcohol-from-corn production model in the United States, considering the total energy consumed by farm equipment, cultivation, planting, fertilizers, pesticides, herbicides, and fungicides made from petroleum, irrigation systems, harvesting, transport of feedstock to processing plants, fermentation, distillation, drying, transport to fuel terminals and retail pumps, and lower ethanol fuel energy content, the net energy content value added and delivered to consumers is very small. And, the net benefit (all things considered) does little to reduce un-sustainable imported oil and fossil fuels required to produce the ethanol.[22] Although ethanol-from-corn and other food stocks has implications both in terms of world food prices and limited, yet positive energy yield (in terms of energy delivered to customer/fossil fuels used), the technology has lead to the development of cellulosic ethanol. According to a joint research agenda conducted through the U.S. Department of Energy,[23] the fossil energy ratios (FER) for cellulosic ethanol, corn ethanol, and gasoline are 10.3, 1.36, and 0.81, respectively.[24][25][26] Many car manufacturers are now producing flexiblefuel vehicles (FFV’s), which can safely run on any combination of bioethanol and petrol, up to 100% bioethanol. They dynamically sense exhaust oxygen content, and adjust the engine’s computer systems, spark, and fuel injection accordingly. This adds initial cost and ongoing increased vehicle maintenance. Efficiency falls and pollution emissions increase when FFV system maintenance is needed (regardless of the fuel mix being used), but not performed (as with all vehicles). FFV internal combustion engines are becoming increasingly complex, as are multiple-propulsion-system FFV hybrid vehicles, which impacts cost, maintenance, reliability, and useful lifetime longevity.

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Alcohol mixes with both petroleum and with water, so ethanol fuels are often diluted after the drying process by absorbing environmental moisture from the atmosphere. Water in alcohol-mix fuels reduces efficiency, makes engines harder to start, causes intermittent operation (sputtering), and oxidizes aluminum (carburetors) and steel components (rust). Even dry ethanol has roughly one-third lower energy content per unit of volume compared to gasoline, so larger / heavier fuel tanks are required to travel the same distance, or more fuel stops are required. With large current un-sustainable, non-scalable subsidies, ethanol fuel still costs much more per distance traveled than current high gasoline prices in the United States.[27] Methanol is currently produced from natural gas, a non-renewable fossil fuel. It can also be produced from biomass as biomethanol. The methanol economy is an interesting alternative to the hydrogen economy, compared to today’s hydrogen produced from natural gas, but not hydrogen production directly from water and state-of-the-art clean solar thermal energy processes.[28]

Biofuel

Bioethers
Bio ethers (also referred to as fuel ethers or fuel oxygenates) are cost-effective compounds that act as octane enhancers. They also enhance engine performance, whilst significantly reducing engine wear and toxic exhaust emissions. Greatly reducing the amount of ground-level ozone, they contribute to the quality of the air we breathe.[29] [30] [31] Pipes carrying biogas gases and produce biofuels such as biodiesel, biogas and a dry fuel comparable to coal.[33]

Syngas
Syngas, a mixture of carbon monoxide and hydrogen, is produced by partial combustion of biomass, that is, combustion with an amount of oxygen that is not sufficient to convert the biomass completely to carbon dioxide and water.[34] Before partial combustion the biomass is dried, and sometimes pyrolysed. The resulting gas mixture, syngas, is itself a fuel. Using the syngas is more efficient than direct combustion of the original biofuel; more of the energy contained in the fuel is extracted. Syngas may be burned directly in internal combustion engines or turbines. The wood gas generator is a wood-fueled gasification reactor mounted on an internal combustion engine. Syngas can be used to produce methanol and hydrogen, or converted via the FischerTropsch process to produce a synthetic diesel substitute, or a mixture of alcohols that can be blended into gasoline. Gasification normally relies on temperatures >700°C. Lower temperature gasification is desirable when coproducing biochar but results in a Syngas polluted with tar.

Biogas
Biogas is produced by the process of anaerobic digestion of organic material by anaerobes.[32] It can be produced either from biodegradable waste materials or by the use of energy crops fed into anaerobic digesters to supplement gas yields. The solid byproduct, digestate, can be used as a biofuel or a fertilizer. In the UK, the National Coal Board experimented with microorganisms that digested coal in situ converting it directly to gases such as methane. Biogas contains methane and can be recovered from industrial anaerobic digesters and mechanical biological treatment systems. Landfill gas is a less clean form of biogas which is produced in landfills through naturally occurring anaerobic digestion. If it escapes into the atmosphere it is a potent greenhouse gas. Oils and gases can be produced from various biological wastes: • Thermal depolymerization of waste can extract methane and other oils similar to petroleum. • GreenFuel Technologies Corporation developed a patented bioreactor system that uses nontoxic photosynthetic algae to take in smokestacks flue

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Biofuel
enzyme catalysts that efficiently break down cellulose into sugars at high temperatures", adding to the 10 previously known.[39] In addition, research conducted at TU Delft by Jack Pronk has shown that elephant yeast, when slightly modified can also create ethanol from non-edible ground sources (eg straw).[40][41] The recent discovery of the fungus Gliocladium roseum points toward the production of so-called mycodiesel from cellulose. This organism was recently discovered in the rainforests of northern Patagonia and has the unique capability of converting cellulose into medium length hydrocarbons typically found in diesel fuel.[42] Scientists also work on experimental recombinant DNA genetic engineering organisms that could increase biofuel potential.

Solid biofuels
Examples include wood, sawdust, grass cuttings, domestic refuse, charcoal, agricultural waste, non-food energy crops (see picture), and dried manure. When raw biomass is already in a suitable form (such as firewood), it can burn directly in a stove or furnace to provide heat or raise steam. When raw biomass is in an inconvenient form (such as sawdust, wood chips, grass, agricultural wastes), another option is to pelletize the biomass with a pellet mill. The resulting fuel pellets are easier to burn in a pellet stove. A problem with the combustion of raw biomass is that it emits considerable amounts of pollutants such as particulates and PAHs (polycyclic aromatic hydrocarbons). Even modern pellet boilers generates much more pollutants than oil or natural gas boilers. Pellets made from agricultural residues are usually worse than wood pellets, producing much larger emissions of dioxins and chlorophenols.[35] Another solid biofuel is biochar, which is produced by biomass pyrolysis. Biochar pellets made from agricultural waste can substitute for wood charcoal. In countries where charcoal stoves are popular, this can reduce deforestation.

Third generation biofuels
Algae fuel, also called oilgae or third generation biofuel, is a biofuel from algae. Algae are low-input, high-yield feedstocks to produce biofuels. It produces 30 times more energy per acre than land crops such as soybeans.[43] With the higher prices of fossil fuels (petroleum), there is much interest in algaculture (farming algae). One advantage of many biofuels over most other fuel types is that they are biodegradable, and so relatively harmless to the environment if [44][45][46] spilled. The United States Department of Energy estimates that if algae fuel replaced all the petroleum fuel in the United States, it would require 15,000 square miles (38,849 square kilometers), which is roughly the size of Maryland.[43] Second and third generation biofuels are also called advanced biofuels. Algae, such as Botryococcus braunii and Chlorella vulgaris, are relatively easy to grow, [2] but the algal oil is hard to extract. There are several approaches, some of which work better than others. See: Prospects for the Biodiesel Industry. [3]

Second generation biofuels
Supporters of biofuels claim that a more viable solution is to increase political and industrial support for, and rapidity of, second-generation biofuel implementation from non food crops, including cellulosic biofuels.[36] Second-generation biofuel production processes can use a variety of non food crops. These include waste biomass, the stalks of wheat, corn, wood, and specialenergy-or-biomass crops (e.g. Miscanthus). Second generation (2G) biofuels use biomass to liquid technology[37], including cellulosic biofuels from non food crops.[38] Many second generation biofuels are under development such as biohydrogen, biomethanol, DMF, BioDME, Fischer-Tropsch diesel, biohydrogen diesel, mixed alcohols and wood diesel. Cellulosic ethanol production uses non food crops or inedible waste products and does not divert food away from the animal or human food chain. Lignocellulose is the "woody" structural material of plants. This feedstock is abundant and diverse, and in some cases (like citrus peels or sawdust) it is a significant disposal problem. Producing ethanol from cellulose is a difficult technical problem to solve. In nature, ruminant livestock (like cattle) eats grass and then use slow enzymatic digestive processes to break it into glucose (sugar). In cellulosic ethanol laboratories, various experimental processes are being developed to do the same thing, and then the sugars released can be fermented to make ethanol fuel. In 2009 scientists reported developing, using "synthetic biology", "15 new highly stable fungal

Ethanol from living algae
Most biofuel production comes from harvesting organic matter and then converting it to fuel but an alternative approach relies on the fact that some algae naturally produce ethanol and this can be collected without killing the algae. The ethanol evaporates and then can be condensed and collected. The company Algenol is trying to commercialize this process.

Biofuels by region
Recognizing the importance of implementing bioenergy, there are international organizations such as IEA Bioenergy,[47] established in 1978 by the OECD International

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Energy Agency (IEA), with the aim of improving cooperation and information exchange between countries that have national programs in bioenergy research, development and deployment. The U.N. International Biofuels Forum is formed by Brazil, China, India, South Africa, the United States and the European Commission.[48] The world leaders in biofuel development and use are Brazil, United States, France, Sweden and Germany. See also: Biodiesel around the world

Biofuel

References
[1] [2] [3] [4] lanl.gov, Green Freedom: Out of Thin Air Call for a moratorium on EU agrofuel incentives Transnational Institute- 1 July 2007 ICRISAT: Sweet sorghum balances food and fuel needs Pu, Yunqiao; Dongcheng Zhang, Preet M. Singh and Arthur J. Ragauskas (December 19, 2007). "The new forestry biofuels sector". Biofuels, Bioproducts and Biorefining (BioFPR) 2 (1): 58–73. doi:10.1002/bbb.48. http://www.biofpr.com. Oliver R. Inderwildi, David A. King (2009). "Quo Vadis Biofuels". Energy & Environmental Science 2: 343. doi:10.1039/b822951c. New study advances method to make energy from farm waste, [1], 4/17/2008. European Environment Agency (2006) How much bioenergy can Europe produce without harming the environment? EEA Report no. 7 Marshall, A. T. (2007) Bioenergy from Waste: A Growing Source of Power, Waste Management World Magazine, April, p34-37 IPCC Third Assessment Report, accessed August 31, 2007. Non-CO2 Gases Economic Analysis and Inventory: Global Warming Potentials and Atmospheric Lifetimes, U.S. Environmental Protection Agency, accessed August 31, 2007 http://unfccc.int/ghg_data/items/3825.php Frank Keppler, John T. G. Hamilton, Marc Bra, and Thomas Röckmann (2006). "Methane emissions from terrestrial plants under aerobic conditions". Nature 439: 187–191. doi:10.1038/nature04420. http://biofuel.org.uk/biofuel-from-waste.html Construction of landfill power plant has begun By MARLA TONCRAY, News Editor (Friday, October 10, 2008 12:57 AM EDT) The Ledger Independent Maysville, Kentucky UN biofuels report ADM Biodiesel: Hamburg, Leer, Mainz Welcome to Biodiesel Filling Stations http://www.hempcar.org/biofacts.shtml THE FUTURIST, Will Thurmond. July-August 2007 ButylFuel,LLC Main Page Evans, Jon (14 January 2008). "Biofuels aim higher". Biofuels, Bioproducts and Biorefining (BioFPR). http://www.biofpr.com/details/feature/102347/ Biofuels_aim_higher.html. Retrieved on 2008-12-03. Andrew Bounds (2007-09-10). ""OECD warns against biofuels subsidies"". Financial Times. http://www.ft.com/cms/s/0/e780d216-5fd5-11dcb0fe-0000779fd2ac.html. Retrieved on 2008-03-07. see "Breaking the Biological Barriers to Cellulosic Ethanol")

Issues with biofuel production and use
There are various current issues with biofuel production and use, which are presently being discussed in the popular media and scientific journals. These include: the effect of moderating oil prices, the "food vs fuel" debate, carbon emissions levels, sustainable biofuel production, deforestation and soil erosion, impact on water resources, human rights issues, poverty reduction potential, biofuel prices, energy balance and efficiency, and centralised versus decentralised production models.

[5]

[6] [7]

[8]

See also
• Agroecology • Algaculture and algology • Anaerobic digestion • Bioalcohol • Biobutanol, a direct biofuel that replaces gasoline. • Biodiesel • Bioenergy • BioEthanol for Sustainable Transport • Biofuelwatch • Biogas and Biogas powerplant • Bioheat, a biofuel blended with heating oil. • Biohydrogen • Biomass briquettes • Biomass to liquid biooil • Carbon based fuel • Energy crop • Energy density • Energy forestry • Energy security • Ecological sanitation and biogas. • Energy content of biofuel • Ethanol fuel • Gasification • Green crude • Green Earth Technologies • Hybrid vehicle • IRENA • Life cycle assessment • List of emerging technologies • List of vegetable oils section on oils used as biodiesel • Low-carbon economy • Straight vegetable oil • Table of biofuel crop yields • United Nations Environment Programme • Vegetable oil economy • Waste vegetable oil

[9] [10]

[11] [12]

[13] [14]

[15] [16] [17] [18] [19] [20] [21]

[22]

[23]

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From Wikipedia, the free encyclopedia
[24] Brinkman, N. et al., "Well-to-Wheels Analysis of Advanced/Vehicle Systems", 2005. [25] Farrell, A.E. et al. (2006) "Ethanol can Contribute to Energy and Environmental Goals", Science, 311, 506-8. [26] Hammerschlag, R. 2006. "Ethanol’s Energy Return on Investment: A Survey of the Literature 1999-Present", Environ. Sci. Technol., 40, 1744-50. [27] "With only 2/3 the energy of gasoline, ethanol costs more per mile". zFacts.com. 2007-04-27. http://zfacts.com/p/ 436.html. Retrieved on 2008-03-07. [28] Hydrogen Solar home [29] http://eur-lex.europa.eu/LexUriServ/ LexUriServ.do?uri=CELEX:31985L0536:EN:HTML, Council Directive 85/536/EEC of 5 December 1985 on crude-oil savings through the use of substitute fuel components in petrol [30] http://circa.europa.eu/Public/irc/env/ fuel_quality/library?l=/stakeholder_october/ presentations/copert_brusselsppt/_EN_1.0_&a=d COPERT Study: An assessment of the impact of ethanol-blended petrol [31] http://www.europarl.europa.eu/registre/ docs_autres_institutions/ commission_europeenne/sec/2007/0055/ COM_SEC(2007)0055_EN.pdf Fuel Quality Directive Impact Assessment [32] Redman, G., The Andersons Centre. "Assessment of on-farm AD in the UK", National Non-Food Crops Centre, 2008-06-09. Retrieved on 2009-05-11. [33] greenfuelonline.com [34] Evans, G. "Liquid Transport Biofuels - Technology Status Report", National Non-Food Crops Centre, 2008-04-14. Retrieved on 2009-05-11. [35] Cedric Briens, Jan Piskorz and Franco Berruti, "Biomass Valorization for Fuel and Chemicals Production -- A Review," 2008. International Journal of Chemical Reactor Engineering, 6, R2 [36] http://www.renewable-energy-world.com/ articles/print_screen.cfm?ARTICLE_ID=308325 [37] Oliver R. Inderwildi, David A. King (2009). "Quo Vadis Biofuels". Energy & Environmental Science 2: 343. doi:10.1039/b822951c. [38] Chris Somerville. ""Development of Cellulosic Biofuels"" (PDF). U.S. Dept. of Agriculture. http://www.usda.gov/ oce/forum/2007%20Speeches/PDF%20PPT/ CSomerville.pdf. Retrieved on 2008-01-15. [39] EurekAlert. (2009). 15 new highly stable fungal enzyme catalysts that efficiently break down cellulose into sugars at high temperatures. [40] Jack Pronk’s elephant yeast Retrieved from "http://en.wikipedia.org/wiki/Biofuel"

Biofuel
[41] Straw to ethanol plant in Sas van Gent [42] ""Fill her up please, and make it myco-diesel"". AFP. http://afp.google.com/article/ ALeqM5gz4TxqoKipVTNNcSTylCrzgb0IAg. Retrieved on 2008-11-04. [43] ^ Eviana Hartman (2008-01-06). ""A Promising Oil Alternative: Algae Energy"". Washington Post. http://www.washingtonpost.com/wp-dyn/content/ article/2008/01/03/AR2008010303907.html. Retrieved on 2008-01-15. [44] Globeco biodegradable bio-diesel [45] Friends of Ethanol.com biodegradable ethanol [46] Low Cost Algae Production System Introduced [47] IEA bioenergy [48] "Press Conference Launching International Biofuels Forum". United Nations Department of Public Information. 2007-03-02. http://www.un.org/News/ briefings/docs/2007/070302_Biofuels.doc.htm. Retrieved on 2008-01-15.

Further reading
• Caye Drapcho, Nhuan Phú Nghiêm, Terry Walker (August 2008). Biofuels Engineering Process Technology. [McGrawHill]. ISBN 0071487492; 9780071487498. http://www.mhprofessional.com/ product.php?isbn=0071487492. • Fuel Quality Directive Impact Assessment

External links
• Alternative Fueling Station Locator (EERE). • Biofuels guidance for businesses, including permits and licences required on NetRegs.gov.uk • How Much Water Does It Take to Make Electricity? -Natural gas requires the least water to produce energy, some biofuels the most, according to a new study. • International Conference on Biofuels Standards European Union Biofuels Standardization • International Energy Agency: Biofuels for Transport - An International Perspective • Steel City Biofuels - A program of the Pennsylvania State University dedicated to the dissemination of high-quality educational resources. • Biofuels from Biomass: Technology and Policy Considerations Thorough overview from MIT

Categories: Alternative propulsion, Anaerobic digestion, Biodegradable waste management, Bioenergy, Biofuels, Sustainable technologies, Fuels

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Biofuel

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