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MATERIAL SAFETY DATA SHEET SECTION 1 X CHEMICAL PRODUCTS AND COMPANY IDENTIFICATION FOR EMERGENCY SOURCE INFORMATION CONTACT: • (918) 687 - 5427 • CHEMTREC: Schrader-Bridgeport International, Inc. 500 South (800) 424-9300 (24 hour contact) • CANUTEC: 45th Street E. Muskogee, Oklahoma 74403 (918) (613) 996-6666 • SETIQ: 91-800-00214 687 - 5427 MATERIAL NAME: Mist Coolant PRODUCT IDENTIFICATION TRADE NAMES/SYNONYMS: #273 Mist Coolant 273 273-4 CHEMICAL FAMILY: Not Applicable (N.A.) SECTION 2 W COMPOSITION/INFORMATION OF INGREDIENTS INGREDIENT CAS NUMBER PERCENTAGE (%) Diethanolamine 111-42-2 2.0-3.0 Dodecyldioicacid 693-23-2 1.0-2.0 Polyalkaleneglycol N.A. 3.0-5.0 1,3,5 Tris(2-Hydroxyethyl-s-Trizine) 4719-04-4 2.0-5.0 Sodium 2 Pyridinethiol-1-Oxide 3511-73-2 1.0-2.0 Water 7732-18-5 93.7-89.3 SECTION 3 ; HAZARDS IDENTIFICATION ))))))))))))))))EMERGENCY OVERVIEW)))))))))))))))) • Blue liquid with a pleasant odor • May cause eye and skin irritation • Target Organs: None )))))))))))))))))))))))))))))))))))))))))))) ACUTE GETTING IT IN YOUR EYE... • Causes eye irritation GETTING IT ON YOUR SKIN... • May cause skin irritation • Prolonged and/or repeated contact may cause dermatitis . SWALLOWING IT... • May cause gastrointestinal irritation with nausea and vomiting BREATHING IT... • Inhalation may cause respiratory tract irritation SYSTEMIC EFFECTS: • No data available. CHRONIC • Prolonged or repeated skin contact may cause dermatitis CANCER, REPRODUCTIVE AND GENETIC EFFECTS • No data available See Toxicological Information (Section 11) For More Information SECTION 4 _ FIRST AID MEASURES EYES: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower lids; do not let allow victim to rub or keep eyes closed. Get Medical Aid SKIN: Quickly remove contaminated clothing and immediately flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Get Medical Aid INGESTION: Do not induce vomiting. Get Medical Aid INHALATION: Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid. NOTE TO PHYSICIAN: TREAT SYMPTOMATICALLY AND SUPPORTIVELY SECTION 5 FIRE FIGHTING MEASURES • Product is nonflammable; use agent most appropriate to extinguish surrounding fire FLASH POINT: (Method Used) N.A. FLAMMABLE LIMITS: LEL: N.A. UEL: N.A. EXPLOSION SEVERITY: N.A.. IGNITION SEVERITY: N.A. MINIMUM EXPLOSION CONCENTRATION: N.A.. AUTOIGNITION TEMPERATURE: N.A. EXTINGUISHING MEDIA: Use dry chemical or Carbon Dioxide (CO2). SPECIAL INSTRUCTIONS: Approach fire from upwind. As in any fire, wear self contained breathing apparatus pressure demand (NIOSH approved) and full protective gear. SECTION 6 ACCIDENTAL RELEASE MEASURES • Evacuate as necessary • Absorb spill using an absorbent, noncombustible materials such as earth, sand or vermiculite • Ventilate the area of spill or leak • Wear appropriate protective equipment as specified in Section 8 SECTION 7 HANDLING AND STORAGE Prior to working with this product workers should be trained on its proper handling and storage • Wash thoroughly after handling • Remove contaminated clothing and wash before reuse • Use with adequate ventilation • Store in tightly closed container • Store in a cool, dry, well ventilated area away from oxidizers and other incompatible substances SECTION 8 EXPOSURE CONTROLS / PERSONAL PROTECTION ENGINEERING CONTROLS: Local exhaust ventilation may be necessary to control any air contaminants to within there exposure limits (see below) during the use of this product EXPOSURE LIMITS TLV (2002) REL DIETHANOLAMINE TWA TWA 2 mg/M3 (skin) 3 ppm PEL TWA N.A. CANADA TWA 3 ppm STEL 6 ppm NO DATA AVAILABLE FOR OTHER INGREDIENTS PERSONAL PROTECTIVE EQUIPMENT • EYES: Wear safety glasses or chemical goggles when handling this product (ANSI Z87.1 approved) • SKIN: Where contact is likely wear chemical resistant gloves • RESPIRATORY PROTECTION: A NIOSH approved air purifying respirator (APR) with properly selected cartridges may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits. Protection provided by APRs is limited. Use a positive pressure air supplied respirator if there is any potential for an uncontrolled release, exposure levels are not known, or any other circumstances where APRs may not provide adequate protection. SECTION 9 PHYSICAL AND CHEMICAL PROPERTIES BOILING POINT (760 MM HG): 212 °F (100°C) PERCENT VOLATILE BY VOLUME: 90 MELTING POINT: N.A. SPECIFIC GRAVITY (H2O = 1): 1.03 EVAPORATION RATE (BuAc = 1): 1 VAPOR DENSITY (AIR =1): 0.64 SOLUBILITY IN WATER: Very Soluble VAPOR PRESSURE AT 68 °F: 22 mm Hg APPEARANCE AND ODOR: Blue liquid with a pleasant odor SECTION 10 conditions STABILITY AND REACTIVITY CHEMICAL STABILITY: Stable at room temperature in closed containers under normal storage and handling CONDITIONS TO AVOID: Incompatible materials. MATERIAL TO AVOID: Avoid strong oxidizing materials HAZARDOUS DECOMPOSITION PRODUCTS: Carbon monoxide, carbon dioxide and other toxics HAZARDOUS POLYMERIZATION: Has not been reported SECTION 11 TOXICOLOGICAL INFORMATION DIETHANOLAMINE Moderately toxic by ingestion, intraperotineal and subcutaneous routes. Mildly toxic by skin contact TOXICITY Type Of Dose LD50(oral) SKIN IRRITATION: rabbit 500 mg/24 hour MLD IARC Not listed NTP Not listed Specie Rat Result 710 mg/kg EYE IRRITATION: Rabbit 5500 mg SEV ACGIH Not listed OSHA Not listed CARCINOGENICITY California(Prop 65) Not listed NIOSH Not listed MUTAGENICITY, TERATOGENICITY AND REPRODUCTIVE EFFECTS • No data available NO DATA AVAILABLE FOR OTHER INGREDIENTS SECTION 12 M ECOLOGICAL INFORMATION No Data Available SECTION 13 ( DISPOSAL CONSIDERATIONS When disposing of the unused contents, the preferred options are to send to licensed reclaimer, or to a permitted incinerator. Any disposal practice must be in compliance with local, state, and federal laws and regulations. SECTION 14 2 TRANSPORTATION INFORMATION NOT MEANT TO BE ALL INCLUSIVE - CHECK LOCAL, STATE, AND FEDERAL LAWS AND REGULATIONS Agency Shipping Name Packing Group Hazard Class UN/NA # U.S. DOT N.A. N.A. N.A. N.A. SECTION 15 REGULATORY INFORMATION TSCA: Diethanolamine is listed on the TSCA inventory. None of the ingredients are listed under Chemical Test Rules, Section 12B, or Significant New Use Rules CERCLA RQ’s(40 CFR Part 302) SARA (40 CFR Part 355) TPQ’s SARA Title III Section 313 RCRA Clean Air Act - Hazardous Air Pollutants Clean Air Act - Ozone Depleting List California’s Prop 65 OSHA Canada’s DSL/NDSL List Canada’s Ingredient Disclosure List NFPA 704 LABEL: 0 0 1 Diethanolamine 1+ pound None of the ingredients are listed Diethanolamine is listed None of the ingredients are listed Diethanolamine and Dodecyldioicacid are listed None of the ingredients are listed as Class 1 or 2 ozone depletors None of the ingredients are listed None of the ingredients are listed Diethanolamine is listed Diethanolamine is listed HMIS LABEL N.A. SECTION 16 E OTHER INFORMATION MSDS REVISIONS: Section 8 MSDS CREATION DATE: 1/9/95 REVISION #2: 3/9/03 Reviewed 3/27/06 DISCLAIMER The information above is believed to be accurate and represents the best information currently available to the Manufacturer and MSDS developer. However, we make no warranty of merchantability or any other warrant, express or implied, with respect to such information, and we assume no liability resulting from its use. User should make their own investigation to determine the suitability of the information for their particular purposes. In no way shall the Manufacturer or MSDS developer be liable for any claims, losses, or damage of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if the Manufacturer or MSDS developer has been advised of the possibility of such damages. MSDS DEVELOPER: Cass Willard, CIH DATE: 03/09/03
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