ADVANCED CLEANING
RODUCT FORMULATIONS
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ADVANCED
CLEANING
PRODUCT
FOR MULATlONS
Volume 5
Ernest W. Flick
NOYES PUBLICATIONS
WILLIAM ANDREW PUBLISHING, LLC
Nomich, New York, U.S.A.
Copyright 0 1999 by Ernest W. Flick
No part of this book may be reproduced or utilized in
any form or by any means, electronic or mechanical,
including photocopying, recording or by any informa-
tion storage and retrieval system, without permission
in writing from the Publisher.
Library of Congress Catalog Card Number: 89-30274
ISBN: 0-8155-1431-X
Printed in the United States
Published in the United States of America by
Noyes Publications/William Andrew Publishing, LLC
13 Faton Avenue, Norwich, New York 13815
10 9 8 7 6 5 4 3 2
Library of Congress Cataloging-in-Publication Data
(Revised for vol. 5)
Flick, Ernest W.
Advanced cleaning product formulations
Includes bibliographical references and index.
1. Cleaning compounds. I. Title
TP990.F56 1989 668'1 89-30274
ISBN 0-8155-1186-8 (v. 1)
ISBN 0-8155-1346-1 (v. 2)
ISBN 0-8155-1382-1 (v. 3)
ISBN 0-8155-1396-8 (v. 4)
ISBN 0-8155-1431-X (v. 5)
To
the late Ernie and Jeanne
and
Allyn and Barbara
and
Chris and Rachel
V
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reface
ohme 5) presents more than 423 up-to-date advanced cleaning
product formulations for household, industrial and automotive applications. It is
the result of information received from numerous industrial companies and other
organizations. The data represent selections made at no cost to, nor influence
from, the makers or distributors of these materials. Only the most recent
formulas have been included. All formulations are completely different than
those contained in Volumes 1, 2, 3 and 4 published earlier.
~ ~ in the cleaning product industry has gradually been~undergoing
~ ~ ~ a ~ o
significant change during the past years. Raw materials costs have risen and
manufacturers have been reluctant to pass along these increases. Environmental
considerations have also played a part. By changing formulations to improve
cost/performance characteristics, manufacturers have been able to control costs
but still enhance performance. This book presents manufacturers' suggested
formulations which might meet new performance criteria.
The formulations in this book are divided into the following sections and
chapters, with the number of formulations indicated in ( ):
H. Household and Industrial Cleaners and Polishes
1. Bathroom Cleaners (9)
2. Dairy, Food and General Industrial Cleaners (27)
3. Degreasers (9)
4. Dishwashing Detergents (34)
5. General Purpose Cleaners (31)
6. Glass CleanersPoiishes (12)
ard Surface Cleaners (21)
8. Laundry Products (55)
9. Metal Cleaners and Polishes (72)
10. Oven, Grill and Hot Plate Cleaners (9)
11. Polishes, Coatings and Finishes (6)
12. Rinse Aids (2)
13. Rug, Floor, Carpet, Upholstery Shampoos and Cleaners (33)
14. Miscellaneous (33)
vii
viii Preface
11. Transportation Cleaners and Polishes
15. Auto Cleaners and Polishes (6)
16. Car and Truck Wash Compounds (49)
17. Whitewall Tire Cleaners (3)
18. Miscellaneous (12)
Each formula is located in the chapter which is most applicable. The reader,
seeking a formula for a specific end use, should check each chapter which could
possibly apply. In addition to the above, there are two other sections which will
be helpful to the reader.
111. A chemical trademark section where each tradenamed raw material
included in the book is listed with a chemical description rand the
supplier's name. The specifications which each raw material meets are
included, if applicable.
IV. Main office addresses of the suppliers of trademarked raw materials.
Each formulation in the book lists the following information, as available, in the
manufacturer's own words:
Description of end use and most outstanding properties.
The percent by weight or volume of each raw material included i the
n
formula, rounded to a decimal figure.
Key properties of the formula, which are the features that the source
considers to be more outstanding than other formulations of the same
type.
The formula source, which is the company or organization that supplied
the formula. The secondary source may be the originating company andlor
the primary source's publication title, or both. A formula number is
included, if applicable.
The table of contents is organized in such a way as to serve as a subject index.
My fullest appreciation is expressed to the companies and organizations who
supplied the original starting formulations included in this book. I also thank the
suppliers of the raw materials included in these formulations, who furnished
information describing their trademarked raw materials.
Newburyport, Massachusetts Ernest W. Flick
July 1999
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NOTICE
To the best of our knowledge the information in this
publication is accurate; however, the Publisher does not assume
any responsibility or liability for the accuracy or completeness
of, or consequences arising from, such information. This book
is intended for informational purposes only. Mention of trade
names or commercial products does not constitute endorsement
or recommendation for use by the Publisher. Final
determination of the suitability of any information or product
for use contemplated by any user. We recommend that anyone
intending to rely on any recommendation of materials QB
procedures mentioned in this publication should satisfy himself
as to such suitability, and that he can meet all applicable safety
and health standards.
X
ntents and Subject Index
SECTION I
OUSEHOLD AND INDUSTRIAL
CLEANERS AND POLISHES
B OM CLEANERS: ............................... 2
Toilet Bowl Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
athroom Cleaner with Disinfectant . . . . . . . . . . . . . . . . . . . . . . . 4
Heavy Duty Acid Bathroom Cleaner . . . . . . . . . . . . . . . . . . . . . . . 4
Mildew Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5
~ o w ~ ~ ~ Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
l d e w 5
Tile Porcelain and Bathroom Cleaner. Acid . . . . . . . . . . . . . . . . . . 6
Tub and Tile Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
Hypochlorite Tub and Tile Cleaner and Mildew Stain Remover . . . 6
Toilet Bowl Cleaner with Bleach ......................... 7
2. .FOOD AND GENERAL INDUSTRIAL CLEANERS . . . . . 8
Acid Industrial and Household Cleaners
Oxalic Acid Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
ust Removal Jelly . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 9
Cleaners for Industrial Application
Desinfecting Cleaner. Acid . . . . . . . . . . . . . . . . . . . . . . . . . . 10
Dipping Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
Spray Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 10
Destainer
sphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
uced Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . 11
Zero phosphate. powder . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
Baking Pan Cleaner
phosphate. powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
Heavy Duty Cleaners
BBll Purpose-Food Process Plant . . . . . . . . . . . . . . . . . . . . . . 13
Hard Surface Spray Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 13
xi
xii Contents and Subject Index
High Foaming Alkaline Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . 14
Heavy Duty Alkaline Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . 44
Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 14
Industrial and High Pressure Cleaners
Cleaner, Strongly Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . 15
Cleaner. Weakly Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . . 15
Cleaner. Strongly Alkaline (Phosphate-Free) . . . . . . . . . . . . . 15
Cleaner. Weakly Alkaline (Phosphate-Free) . . . . . . . . . . . . . . 45
Metal Cleaner
(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
Food Industry Cleaner
(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 16
Milk Can Cleaner
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 17
Powdered Enzyme Presoaks
Economy Presoak . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
Premium Presoak . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 18
Enzyme Prespotter for Oily/Smutty Soils . . . . . . . . . . . . . . . . IS
Sanitizing Cleaner
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
Sanitizing Agent
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 19
.
3 DEGREASERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 20
Aqueous Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
Aqueous Degreaser
d-Limonene Microemulsion . . . . . . . . . . . . . . . . . . . . . . . . . 21
Water Based Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 21
Degreaser Concentrate (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . 22
Metal De-Oiling Liquid Concentrate (Liquid) . . . . . . . . . . . . . . . 22
Solvent Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 23
Solvent Based Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 24
Engine Cleaner and Degreaser . . . . . . . . . . . . . . . . . . . . . . . . . . 24
4. DISHWASHING DETERGENTS . . . . . . . . . . . . . . . . . . . . . . . . . 25
Automatic Dishwash Detergent-Consumer
(Zero Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . 26
Automatic Dishwash Detergent-Consumer
(Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . . . . . 26
Automatic Dishwash Detergent-Industrial & Institutional
(Phosphate. Solid Block . . . . . . . . . . . . . . . . . . . . . . . . . . . . 27
Automatic Dishwashing Detergent-Industrial & Institutional (Liquid~7
Contents and Subject Index xiii
Automatic Dishwash Detergent-Industrial & Institutional
(Zero.Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . 28
Automatic Dishwash Detergent-Industrial & Institutional
(Phosphate. Chlorine Free. Powder) . . . . . . . . . . . . . . . . . . . . 28
Automatic Dishwashing Gel with Chlorine Bleach . . . . . . . . . . . . 29
Clear. Colorless Manual Dish Wash . . . . . . . . . . . . . . . . . . . . . . 30
Powder Stainless Silverware Pre-Soak . . . . . . . . . . . . . . . . . . . . 30
Low Alkaline Warewashing Block . . . . . . . . . . . . . . . . . . . . . . . 30
Dish Washing Agents . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 31
sh w/Amine Oxide/LABS/SLES . . . . . . . . . . . . . . . . . . . 33
Dish Wash w l h i n e Oxide/LABS/ALES . . . . . . . . . . . . . . . . . . 33
Hand Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 33
Foam Booster: E-14-5 in Hand Dishwashing Liquids
Economy Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
Standard Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
90% Premium Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . 34
Rernium Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 34
Hand Dish Detergent Formulations
Clear Dishwash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35
Pearlescent Dishwash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 35
Hand Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 36
Rand Dishwashing Paste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 37
Light Duty Liquid. Premium Hand Dishwash . . . . . . . . . . . . . . . 38
Light Duty Liquid Low Cost Hand Dishwash . . . . . . . . . . . . . . . 38
Liquid Automatic Dishwasher Detergent . . . . . . . . . . . . . . . . . . . 39
Manual Dishwashing Gel . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 40
Manual Dishwashing Liquid . . . . . . . . . . . . . . . . . . . . . . . . . . . . 41
Now-Chlorinated Machine Dishwashing Compound. Liquid . . . . . 42
Chlorinated Machine Dishwashing Compound. Powder . . . . . . . . 42
Non-Chlorinated Machine Dishwashing Compound. Powder . . . . 42
Premium Hand Dishwashing Detergent . . . . . . . . . . . . . . . . . . . . 43
Dish Washing Agents for Manual Use . . . . . . . . . . . . . . . . . . . . 43
.
5 GEN LEANERS . . . . . . . . . . . . . . . . . . . . . . . 44
Abrasive Cleaner with Bleach . . . . . . . . . . . . . . . . . . . . . . . . . . 45
rasive Cleaner Without Bleach . . . . . . . . . . . . . . . . . . . . . . . . 46
Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 47
All Purpose Cleaner - No Rinse . . . . . . . . . . . . . . . . . . . . . . . . . 48
AB1-Purpose Disinfectant Cleaner . . . . . . . . . . . . . . . . . . . . . . . . 49
All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 49
&alp Purpose Cleaner w/Amide/€’hosphate Ester . . . . . . . . . . . . . . 50
A Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
1 50
xiv Contents and Subject Index
All Purpose Cleaner Concentrate
(Phosphate. Liquid. Foam . . . . . . . . . . . . . . . . . . . . . . . . . . . 51
All Purpose Concentrate
(Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 5%
Calcium Carbonate Abrasive Cleaner Without Bleach . . . . . . . . . 52
Citric Acid Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 53
General Purpose Cleaner
(Consumer Low Alkaline. Non-Phosphate Powder) . . . . . . . . 54
General Purpose Cleaner
(Consumer High Alkaline. Non-Phosphated Powder) . . . . . . . 54
General Purpose Spray & Wipe Cleaner . . . . . . . . . . . . . . . . . . . 55
General Purpose Spray & Wipe . . . . . . . . . . . . . . . . . . . . . . . . . 56
All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 56
Hypochlorite Vertical Surface Cleaner . . . . . . . . . . . . . . . . . . . . 57
Pump Spray All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . 57
Liquid Cleanser with Bleach . . . . . . . . . . . . . . . . . . . . . . . . . . . 58
All Purpose Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 58
Pine Oil Cleaner Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . 59
Disinfecting Cleaner. Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . 59
Sodium Bicarbonate Abrasive Cleaner Without Bleach . . . . . . . . 60
.
6 GLASS CLEANERS/POLISHES . . . . . . . . . . . . . . . . . . . . . . . . . . 61
Anti.Fogging. Anti-Static Glass Cleaner . . . . . . . . . . . . . . . . . . 62
Glass Cleaner. Ready to Use . . . . . . . . . . . . . . . . . . . . . . . . . . . 62
Glass Cleaner Concentrate (Non-Ammoniated) . . . . . . . . . . . . . . 63
Glass Cleaner Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63
Ammoniated Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 63
Glass and Window Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 64
Household Window Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65
Premium Household Window Cleaner . . . . . . . . . . . . . . . . . . . . . 65
Glass Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 65
Windows/Glass
Glass Cleaner (Concentrate) . . . . . . . . . . . . . . . . . . . . . . . . . 66
Windshield Washer Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . 66
Windshield Washer Concentrate (Low VOC) . . . . . . . . . . . . . . . . 66
.
7 HARD SURFACE CLEANERS . . . . . . . . . . . . . . . . . . . . . . . . . . . 67
Alkaline Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 58
Hard Surface Cleaner Concentrate (All Purpose Type) . . . . . . . . . 68
Concentrated Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . 69
Hard Surface Cleaner-Spray . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
Pine Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 69
Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 70
Contents and Subject Index xv
Bard Surface Cleaner w/Amphoteric . . . . . . . . . . . . . . . . . . . . . . 71
Hard Surface Cleaner Concentrate w/d’Limonene . . . . . . . . . . . . . 71
Bard Surface Cleaner Concentrate (Phosphate. Liquid) . . . . . . . . . 72
Hard Surface Spray Cleaner (Phosphate. Liquid) . . . . . . . . . . . . . 72
Hard Surface Cleaner Concentrate wmipentene . . . . . . . . . . . . . . 73
Alkaline Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 73
Liquid Abrasive Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74
Tile and Sanitary Cleaners . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 74
Liquid Hard Surface Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 74
Hard Surface Cleaner-All Purpose . . . . . . . . . . . . . . . . . . . . . . . 75
old and Mildew Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . 76
PRODUCTS ................................ 77
gent for Fine Fabrics-1 . . . . . . . . . . . . . . . . . . . . . . . . . . . 78
Detergent for Fine Fabrics-2 . . . . . . . . . . . . . . . . . . . . . . . . . . . 78
Heavy Duty Laundry . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 79
1 h 1 Liquid Laundry Detergent with Enzyme & Optical . . . . . . . 80
Surfactant Rich Detergent for Nursing Homes . . . . . . . . . . . . . . . 80
Powder for Automatic Dishwashing Machines . . . . . . . . . . . . . . . 80
dustrial Heavy Duty Laundry Liquid . . . . . . . . . . . . . . . . . . . . 81
Industrial Laundry Detergents
High Caustic Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . 82
Mixed Builder Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . 82
Washing Paste with Bleaching Agent . . . . . . . . . . . . . . . . . . . . . 82
Laundry Detergent-Consumer (Liquid) . . . . . . . . . . . . . . . . . . . . 83
Laundry Detergent-Consumer
(Zeolite Built. Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . 83
Laundry Detergent-Consumer
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 84
Laundry Detergent-Consumer
phosphate. Powder) ............................... 84
bundry Break-Industrial & Institutional
(Liquid. Phosphate) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
Laundry Break-Industrial & Institutional
(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 85
Laundry Detergent-Industrial & Institutional
(NTAJZeolite. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 86
Laundry Break-Industrial & Institutional
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 86
Laundry Detergent-Industrial & Institutional
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 87
Laundry Detergent-Industrial & Institutional
(Sodium Carbonate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . 87
mi Contents and Subject Index
Laundry Break-Industrial & Institutional
phosphate. Powder. High Alkalinity) . . . . . . . . . . . . . . . . . . 88
Laundry Break-Industrial & Institutional
(Zero Phosphate Powder. High Alkalinity . . . . . . . . . . . . . . . . 88
Laundry Detergent-Industrial & Institutional
(Reduced Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . 89
Laundry Detergent-Industrial & Institutional
(NTA, Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 89
Laundry Detergent-Industrial & Institutional
(Sodium Carbonate with Flow Aid. Powder) . . . . . . . . . . . . . . 90
Laundry Detergant-Industrial & Institutional
(Phosphate. Solid Block) . . . . . . . . . . . . . . . . . . . . . . . . . . . . 6
94
Laundry Detergent-Industrial and Institutional
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 91
Laundry Detergent-Industrial and Institutional
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . 1
91
Laundry Detergent-Industrial & Institutional
(Phosphate Built. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . 92
Laundry Detergent-Industrial & Institutional
(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 92
Laundry Builder-Industrial & Institutional
(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 93
Laundry Detergent-Industrial & Institutional
(Zeolite Built. Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . 93
Laundry Prespotter Sprayable Gel . . . . . . . . . . . . . . . . . . . . . . . . 94
Laundry Prespotter Sprayable Liquid . . . . . . . . . . . . . . . . . . . . . 95
Light Duty Liquid Detergent . . . . . . . . . . . . . . . . . . . . . . . . . . . 96
Calsoft LAS-99 Based . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 98
Dry Cleaner: Pre Spot-Water Soluble . . . . . . . . . . . . . . . . . . . . . 99
Wool Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 99
Two Part Industrial Laundry Detergents
Break Formulations Highly Alkaline Break . . . . . . . . . . . . . 5 0 10
Mixed Builder Break . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100
Detergent Additive . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 100
Ultra Liquid Laundry Detergent . . . . . . . . . . . . . . . . . . . . . . . . 101
Fine Fabric Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 61
14
.
9 METAL CLEANERS AND POLISHES . . . . . . . . . . . . . . . . . . . 802
Acid Metal Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . p03
Dipping Cleaner for Silver . . . . . . . . . . . . . . . . . . . . . . . . . . . . 103
Aluminum CleanerBrightener . . . . . . . . . . . . . . . . . . . . . . . . . 104
Powdered Metal Cleaning Concentrate . . . . . . . . . . . . . . . . . . . 104
Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 1104
Contents and Subject Index xvii
Aluminum Cleaner Concentrate F-498 . . . . . . . . . . . . . . . . . . . 105
Aluminum Wash F-499 . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 105
ffing Compound Remover . . . . . . . . . . . . . . . . . . . . . . . . . . 106
t Alkaline Paint Stripper Concentrate . . . . . . . . . . . . . . . . . . 106
Metal De-Oiling Liquid Concentrate (Liquid) . . . . . . . . . . . . . . 106
Cutting Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 107
Semi-synthetic Cutting Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . 109
Cutting Oil Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 109
General Purpose Machine Cleaner . . . . . . . . . . . . . . . . . . . . . . 110
Aircraft Cleaner Type I . . . . . . . . . . . . . . . . . . . . . . . . . . . . .
V 110
General Purpose Synthetic Fluid (A) . . . . . . . . . . . . . . . . . . . . . 111
General Purpose Synthetic Fluid (€3) . . . . . . . . . . . . . . . . . . . . . 111
Copper Machining Fluid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 111
General Purpose Synthetic Fluid (C) . . . . . . . . . . . . . . . . . . . . . 112
General Purpose Synthetic Fluid @) . . . . . . . . . . . . . . . . . . . . . 112
Metal Cleaner
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113
Aluminum Cleaner
phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 113
eta1 Cleaner
phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 114
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . 115
Non-Phosphorous Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . 116
Alkaline Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 116
Semi Synthetic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 117
Silver and Metal Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 119
Soluble Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 120
Soluble Oil Machining Fluid . . . . . . . . . . . . . . . . . . . . . . . . . . 122
Synthetic Machining Fluid . . . . . . . . . . . . . . . . . . . . . . . . . . . . 122
Synthetic . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 123
Synthetic DrawindStamping Fluid . . . . . . . . . . . . . . . . . . . . . . 124
Oil Based DrawindStamping Fluid . . . . . . . . . . . . . . . . . . . . . . 124
Spray Metal Cleaning Concentrate . . . . . . . . . . . . . . . . . . . . . . 124
Synthetic Formula . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 125
Synthetic Formulation . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 130
Universal Scouring Paste . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133
Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 133
Water Soluble Stamping Fluid . . . . . . . . . . . . . . . . . . . . . . . . . 134
-40 Type Lubricant Concentrate . . . . . . . . . . . . . . . . . . . . 134
Penetrating Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134
Burnishing Compound . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 134
xviii Contents and Subject Index
10. OVEN. GRILL AND HOT PLATE CLEANERS . . . . . . . . . . . 135
Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 136
Non-Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 3
B6
High Caustic Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . 137
Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138
Aerosol Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 138
Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139
Heavy Duty Oven Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 139
Oven Cleaner w/Amphoteric . . . . . . . . . . . . . . . . . . . . . . . . . . 4
10
Oven Cleaner wphosphate . . . . . . . . . . . . . . . . . . . . . . . . . . . . 140
.
1 POLISHES. COATINGS AND FINISHES . . . . . . . . . . . . . . . .
1 4
11
Furniture Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 142
LeatherPlastic Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 143
Marble Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144
Rust Removing Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 144
Scratched Wood Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 145
High Gloss. Detergent Resistant Polish . . . . . . . . . . . . . . . . . . . 145
12. RINSE AIDS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . .6
14
Rinse Aid. Acid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147
Rinse Aid . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 147
13. RUG. FLOOR, CARPET. UPHOLSTERY SHAMPOOS
AND CLEANERS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . n48
Carpet Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 4
19
Low Foam Carpet Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . 149
Steam Rug Cleaner-A . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149
Steam Rug Cleaner-B . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 149
Carpet Cleaners for the Spray-Extraction Process . . . . . . . . . . . 150
Carpet Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 150
(Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 11
15
Rug Steam Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 151
Carpet Shampoo. High Foam . . . . . . . . . . . . . . . . . . . . . . . . . . 152
Carpet Spot Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 12
15
Carpet & Upholstery Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 153
Vinyl Dressing (B) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 153
Carpet & Upholstery Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . 154
Liquid Steam Carpet Cleaner For Hard Water Systems . . . . . . . 154
Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155
Liquid Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 155
Heavy-Duty Floor Scrubber . . . . . . . . . . . . . . . . . . . . . . . . . . . 155
Household Carpet Freshenedhtistat . . . . . . . . . . . . . . . . . . . . 156
Contents and Subject Index xix
Pump Spray Carpet Antistat . . . . . . . . . . . . . . . . . . . . . . . . . . . 156
Liquid Leather. Vinyl. and Plastic Cleaner and Restorer . . . . . . . 157
Liquid Leather. Vinyl. and Plastic Cleaner . . . . . . . . . . . . . . . . 157
Low Cost Extraction Carpet Cleaner . . . . . . . . . . . . . . . . . . . . . 158
Premium. Medium Duty Steam Extraction Carpet Cleaner . . . . . 158
uty Steam Extraction Carpet Cleaner . . . . . . . . . . . . . . 158
aming Carpet Extractor Detergent . . . . . . . . . . . . . . . . . 159
m Cleaner (Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . 159
No Rinse Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160
Heavy Duty Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 160
No-Rinse Floor Cleaner Degreaser ...................... 160
Wax Stripper (A) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161
ax Stripper (B) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 161
Concentrated Wax Stripper . . . . . . . . . . . . . . . . . . . . . . . . . . . 161
CEELANEQUS ................................. 162
acteriostatic Concentrate w/Pine Oil . . . . . . . . . . . . . . . . . . . . 163
General Disinfectant Solution . . . . . . . . . . . . . . . . . . . . . . . . . . 163
Hospital Disinfectant . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 163
Cutting Oil Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164
Cutting Oil . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164
Concrete Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164
White Wall Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 164
d ' l h o n e n e Waterless Hand Cleaner . . . . . . . . . . . . . . . . . . . . . 165
Paste Nand Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 165
Dipentene Microemulsion Formulations
-alkaline Formulations . . . . . . . . . . . . . . . . . . . . . . . . . 166
line Formulations . . . . . . . . . . . . . . . . . . . . . . . . . . . . 167
Hydrocarbon Solvent Microemulsions
Emsol D-110 Formulations . . . . . . . . . . . . . . . . . . . . . . . . 168
Isopar M Formulations . . . . . . . . . . . . . . . . . . . . . . . . . . . . 169
h w Viscosity Silicone Emulsion Using Pemulen Resins . . . . . . 170
Luminizing Pet conditioner . . . . . . . . . . . . . . . . . . . . . . . . . . . 171
Pea Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 171
iao-Emulsions with d-Limonene ..................... 172
Micro-Emulsions with Pine Oil . . . . . . . . . . . . . . . . . . . . . . . . 173
Plastic Bottle Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174
Bottle Wash Formulations
w Foam . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174
oderate Foam . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 174
Terpene Microemulsions . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175
Concentrated Formula . . . . . . . . . . . . . . . . . . . . . . . . . . . . 175
Wax Emulsion Using Pemulen Resins . . . . . . . . . . . . . . . . . . . . 176
xx Contents and Subject Index
SECTION 11
TRANSPORATION CLEANERSl
AND POLISHES
.
15 AUTO CLEANERS AND POLISHES .................... 198
1’’
Chrome Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 7
19
Liquid Car Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 180
Liquid Spray Cleaner for Aluminum Trucks . . . . . . . . . . . . . . . 181
Aluminum Cleanermrightener . . . . . . . . . . . . . . . . . . . . . . . . . 181
Non-Phosphorous Aluminum Cleaner . . . . . . . . . . . . . . . . . . . . 11
18
Mild Abrasive Automobile Polish . . . . . . . . . . . . . . . . . . . . . . . 182
.
16 CAR AND TRUCK WASH COMPOUN S . . . . . . . . . . . . . . . . %83
Car Shampoo Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . . 184
Automobile Car Wash Concentrate . . . . . . . . . . . . . . . . . . . . . . 184
Car Wash (Calsoft LAS-99-Based) . . . . . . . . . . . . . . . . . . . . . 185
Car Wash (Calsuds A-Based) . . . . . . . . . . . . . . . . . . . . . . . . . 8
15
Car Wash (Calsoft T-60-Based) . . . . . . . . . . . . . . . . . . . . . . . 185
CarWash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186
Paste Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 186
Car Wash w/Amphoteric . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 187
Windshield Washer Concentrate . . . . . . . . . . . . . . . . . . . . . . . . 187
Windshield Washer Formulation . . . . . . . . . . . . . . . . . . . . . . . . 187
Car Wash Concentrate w/Alcohol Ethoxylate . . . . . . . . . . . . . . 133
Car and Truck Wash Formula . . . . . . . . . . . . . . . . . . . . . . . . . 189
Car Wash powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 189
Car Wash (Calsuds A-Based) . . . . . . . . . . . . . . . . . . . . . . . . . 189
Car Wash and Care
Car Shampoo with Water-Repellent Effect . . . . . . . . . . . . . 190
Rinse-off Agent (Water Repellent) . . . . . . . . . . . . . . . . . . . 9
10
Rinse-off Agent (Water-Repellent) Without Hydrocarbons . ~ 190
Windshield-Cleaner (Summer) . . . . . . . . . . . . . . . . . . . . . . 9
10
Windshield-Cleaner (Winter) . . . . . . . . . . . . . . . . . . . . . . . 9
1B
Insect Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191
Wheel Cleaner, Alkaline . . . . . . . . . . . . . . . . . . . . . . . . . . . 191
Tar Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 191
Car Wax . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 192
Auto Wipe & Shine Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . 192
Concentrated Traffic Film Removers . . . . . . . . . . . . . . . . . . . . 193
Foamy Brush Car Wash, Liquid . . . . . . . . . . . . . . . . . . . . . . . . 194
Low Cost Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 194
General Purpose Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . 195
Liquid Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 195
Contents and Subject Index xxi
Boat Wash & Car Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . 195
Heavy Duty Truck Wash. Liquid . . . . . . . . . . . . . . . . . . . . . . . 196
Heavy D t Truck Wash. Powder . . . . . . . . . . . . . . . . . . . . . . .
uy 196
Premium Car Wash Concentrate . . . . . . . . . . . . . . . . . . . . . . . . 197
Car Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 197
Auto Shampoo Concentrate . . . . . . . . . . . . . . . . . . . . . . . . . . . 197
Touchless Vehicle Wash Detergent
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . 198
Vehicle Wash Detergent (Low pH)
(Zero Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . 198
Tmck/Bus Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199
Economy Tnuck/Bus Wash . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199
Car Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 199
Car Wash and Wax Shampoo . . . . . . . . . . . . . . . . . . . . . . . . . . 199
Vehicle Wash Detergent
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200
(Liquid. low foam) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 200
Vehicle Wash Detergent (Low pH)
(Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . 201
Touchless Vehicle Wash Booster/Additive
(Zero Phosphate. Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . 201
ITEWALL TIRE CLEANERS . . . . . . . . . . . . . . . . . . . . . . 202
Mitewall Tire Cleaner
(Zero Phosphate Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . 203
phosphate Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 203
(Liquid) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 203
n SCEEUNEOUS . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 204
Aircraft Cleaner
(Reduced Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . 205
(Phosphate. Powder) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 205
Auto Care: Hnterior/Exterior Rubber & Vinyl Protectant . . . . . . . 206
Boat Polish . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 207
Concrete CIeanerDegreaser . . . . . . . . . . . . . . . . . . . . . . . . . . . 208
Garage Floor Cleaner . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 208
Acid Rust Remover . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 208
ConcreteDriveway Cleaners
For Other Stains . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 209
Heavy Duty Concrete Cleaner (Phosphate Free) Formula 1C . . . 209
Vinyl Dressing . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210
ressing (A) . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . . 210
xxii Contents and Subject Index
SECTION III: TRADEMARKED RAW MATE .
s . . . . . . . . . . 2nn
SECTION IV: SUPPLIERS' ADDRESSES . ... . . . . . . . . . . . . .
a ~ ~ 229
ection I
Household and Industrial
Cleaners and Polishes
1
1. Bathroom Cleaner
a
Bathroom Cleaners 3
A c i d i c Toilet Bowl C l e a n e r
Carbopol r e s i n s a r e used t o t h i c k e n t h i s a c i d i c t o i l e t bowl
c l e a n e r f o r m u l a t i o n . I n a d d i t i o n , t h e use o f t h e r e s i n p r o v i d e s
v e r t i c a l c l i n g t o increase t h e contact time o f t h e detergent
on t h e s o i l e d s u r f a c e and enhance consumer c o n v e n i e n c e .
I n s r e d ie n t : 5
DI Water 43.00
Carbopol 6 7 4 ( 1 ) 2.00
C i t r i c A c i d (50%) 50.00
A l k y l benzene s u l f o n i c a c i d 97%) ( 2 ) 2.00
Sodi u d o d e c y l d i p h e n y l o x i de d i s u l f o n a t e (45%) ( 3 )
m 3.00
B r o o k f ie l d v i s c o s i t y ( R V T 20 rpm): 4,000 cps
P r o d u c t pH: 1 .O-2.0
Product C l a r i t y : C l e a r
(1) BFGoodrich
i2j Stepan Co.: B i o s o f t 5-100
( 3 ) Dow Chemical Co.: Dowfax 2A1
Procedure:
1 . M i x t h e D I w a t e r and c i t r i c a c i d s o l u t i o n t o g e t h e r .
2 . U s i n g moderate a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d by a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
s c r e e n t h e Carbopol r e s i n i n t o t h e w a t e r / c i t r i c a c i d sol-
u t i o n . M i x t h e s l u r r y f o r a p p r o x i m a t e l y 30 m i n u t e s . The
p r o d u c t w i l l become i n c r e a s i n g l y t h i c k e r w i t h t i m e - h e a t i n g
t o 40-50C w i l l h a s t e n t h e p r o c e s s .
3 . Add t h e s u l f o n i c a c i d and t h e d i p h e n y l o x i d e d i s u l f o n a t e
surfactant.
4 . Add c o l o r and f r a g r a n c e , as d e s i r e d . Cool t h e p r o d u c t t o
room t e m p e r a t u r e .
Total Actives:
C i t r i c a c i d : 25.00
A l k y l benzene s u l f o n i c a c i d : 1.94
Dodecyl d i p h e n y l o x i d e d i s u l f o n a t e : 1.35
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-351
4 Advanced Cleaning Product Formulatioris
Bathroom Cleaner with Disinfectant
Inqredi ents: Wt .%*
A: Veegum T, Magnesium Aluminum Silicate 1 .oo
Rhodopol 23, Xanthan Gum 0.35
Deionized Water 86.65
B: Diatomaceous Earth (Super Floss) 5.00
Tetrasodium EDTA (Hampene 100) 2.75
Sodium o-Phenylphenate (Dowicide A) 0.25
Sodi um A1 kyl benzene Sul fonate (Cal soft L - 4 0 ) 3.00
Butyl Cellosolve 1 .oo
Procedure:
1 . Dry blend the Veegum T and Rhodopol 23 and add them to the
water while stirring with an homogenizer at 5000 rpm.
Continue mixing for 30 minutes.
2. Slowly add the Part 8 ingredients in the order shown, mixing
each for 5 minutes.
* A s received basis
SOURCE: R.T. Vanderbilt Co., Inc.: Formulation No. 363
Heavy Duty Acid Bathroom Cleaner
Inqredi ents: Wt%
Hydroxyacetic acid 5.0
Sulfamic acid 5.0
Ammonyx LO 10.0
Water, D.I. 80.0
Mixing Procedure:
Add ingredients to water in the order given and mix until
homogeneous.
Properties:
Appearance: Clear liquid
pH, as is: 1.0
Solids, %: 1 4 . 0
Density, lbs/gal: 8.7
Use Instructions:
Use as is o r dilute as needed. Do not use on natural marble
or polished aluminum. Use gloves. Do not mix with bleach.
Storage Stability:
Formulation is freeze/thaw stable through 3 cycles.
Formulation is stable for 3 weeks @ 50C.
SOURCE: Stepan Co.: Formulation No. 200
Bathroom Cleaners 5
M i 1dew Remover
Ingredients: Wt%*
Van Gel 0 3.00
D e i o n i z e d Water 85.55
Sodium H y d r o x i d e , 50% S o l u t i o n 0.45
Sodium H y p o c h l o r i t e , 10% S o l u t i o n ( H y p u r e N ) 10.00
Vanseal NALS-30 1.oo
Procedure:
4 . S l o w l y s p r i n k l e t h e Van Gel 0 i n t o w a t e r a t room t e m p e r a t u r e
w h i l e m i x i n g w i t h a homogenizer o r d i s p e n s e r o p e r a t i n g a t
5000 rpm. C o n t i n u e m i x i n g f o r 40 m i n u t e s .
2 . Add sodium h y d r o x i d e and m i x u n t i l u n i f o r m l y d i s s o l v e d .
Slow t h e m i x e r t o 1 0 0 0 rpm o r l e s s .
3 . Add t h e Vanseal NALS-30. A v o i d a i r e n t r a p m e n t . M i x u n t i l
uniform.
F o r m u l a t i o n No. 458
Bowl /Mi 1dew C 1 e a n e r
Ingredients:
A: Veegum T , Magnesium Aluminum S i l i c a t e 5.00
T e t r a s o d i u m P y r o p h o s p h a t e (TSPP) 0.25
Water 50.75
8 : Sodium H y p o c h l o r i t e , 5 . 2 5 % 34.00
Sodium M e t a s i l i c a t e , Anhydrous 10.00
Procedure:
1 . D r y b l e n d t h e Veegum T and TSPP. S l o w l y add t h e w a t e r w h i l e
a g i t a t i n g a t maximum a v a i l a b l e s h e a r . C o n t i n u e u n t i l smooth.
2 . Add P a r t B i n g r e d i e n t s s l o w l y i n t h e o r d e r shown, m i x i n g
a f t e r each a d d i t i o n u n t i l smooth and u n i f o r m .
F o r m u l a t i o n No. 424
*As r e c e i v e d b a s i s
SOURCE: R.T. V a n d e r b i l t Co., I n c . : Suggested F o r m u l a t i o n s
6 Advanced Cleaning Product Formulations
Tile, P o r c e l a i n a n d Bathroom C l e a n e r , A c i d
Ingredients:
Water, D . I . 75.5
Xanthan Gum 0.5
P e t r o BAF Powder 2.0
P h o s p h o r i c A c i d , 75% 12.0
H y d r o x y a c e t i c A c i d , 70% 10.0
Perfume, Dye q.s.
B l e n d i n g Procedure:
Add Xanthan Gum s l o w l y t o w a t e r w i t h h i g h speed m i x i n g . A l l o w
t o m i x u n t i l m a t e r i a l t h i c k e n s . Add r e m a i n i n g i n g r e d i e n t s i n
o r d e r l i s t e d . I f p r o b l e m s d e v e l o p a d d i n g Xanthan Gum t o w a t e r ,
p r e m i x t h e Xanthan Gum i n some i s o p r o p a n o l b e f o r e a d d i n g t o
water.
F o r m u l a 529
Tub and T i l e C l e a n e r
Ingredient:
Water, D . I . 67.4
P h o s p h o r i c A c i d , 86% 17.6
H y d r o c h l o r i c A c i d , 37% 13.5
R e w o t e r i c AM TEG 0.5
V a r o n i c T202 SR 1.o
Blending Procedure:
Add in g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .
T y p i c a l P r o p e r t ie s :
V i s c o s i t y , c p s : 293
S o l i d s : 16.3%
pH: 1 . 7
F o r m u l a 530
H y p o c h l o r i t e Tub and T i l e C l e a n e r a n d M i l * S t a i n Remoz
Ingredients:
Water, D . I . 44.9
Sodium H y d r o x i d e (30%) 1.o
Varox 365 1.5
Sodi urn H y p o c h l o r i t e ( 5 . 7 % ) 52.6
Blending Procedure:
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t io n .
Typical Properties:
V i s c o s i t y , cps: 4
S o l i d s : 3.8%
pH: 13.5
F o r m u l a 531
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Bathroom Cleaners 7
T o i l e t Bowl C l e a n e r w i t h B l e a c h
Carbopol r e s i n s a r e used t o t h i c k e n t h i s t o i l e t bowl w i t h
c h l o r i n e b l e a c h f o r m u l a t i o n . I n a d d i t i o n , t h e use o f t h e r e s i n
provides v e r t i c a l c l i n g t o increase the contact time of the
d e t e r g e n t on t h e s o i l e d s u r f a c e and enhance consumer c o n v e n i e n c e .
I n qr e di-w Wt%
D I Water 60.75
Carbopol 676 ( 1 ) 1.25
P o t a s s i um h y d r o x i d e ( 4 5 % ) 5.00
2 . l r P o t a s s i u m s i l i c a t e (39%) ( 2 ) 5.00
Potassium carbonate 5.00
Sodium h y p o c h l o r i t e ( 1 2 . 5 0 % ) 8.00
Amine O x i d e (30%) ( 3 ) 10.00
B r o o k f i e l d v i s c o s i t y (RVT-20rpm) : 2 , 5 0 0 c p s
P r o d u c t pH: 12-13
P r o d u c t c l a r i t y : Opaque
( 1 ) BFGoodri c h
( 2 ) PQ C o r p .
( 3 ) Lonza, I n c . : B a r l o x 12
Procedure:
1 . U s i n g m o d e r a t e a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d b y a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r
s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s ,
d i s p e r s e o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r .
M i x t h e s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e
s l u r r y i s homogeneous.
2 . W i t h c o n s t a n t a g i t a t i o n , add t h e p o t a s s i u m h y d r o x i d e and
t h e p o t a s s i u m s i l i c a t e . M i x u n t i l homogeneous.
3 . C o n t i n u e a g i t a t i o n and add t h e p o t a s s i u m c a r b o n a t e f o l l o w e d
by t h e b l e a c h .
4 . Add t h e amine o x i d e s u r f a c t a n t and m i x u n t i l homogeneous.
5 . Add c o l o r a n d f r a g r a n c e , a s d e s i r e d .
Total Actives:
S i l i c a t e (as Si02): 1.32
C a r b o n a t e ( a s Na2C03): 3 . 8 4
Available Chlorine: 1.OO
Amine O x i d e : 3 . 0 0
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-350
2. Dairy, Food and
General Industrial Cleaner
8
D a i q , Food and General Industrial Cleaners 9
A c i d I n d u s t r i a l and Household C l e a n e r s
O x a l i c A c i d Gel
Inqredients: W t .%*
Water 53.70
Van Gel B 2.50
Rhodopol 2 3 0.80
O x a l i c A c i d D i h y d r a t e , 12.59n Aqueous S o l u t i o n 40.00
P o l y s o r b a t e 40 (Tween 4 0 ) 3.00
Procedure:
1 . Dry b l e n d t h e Van Gel €3 and Rhodopol 2 3 and add them t o t h e
w a t e r w h i l e m i x i n g w i t h a p r o p e l l e r s t i r r e r a t 1800 rpm.
C o n t i n u e m i x i n g f o r 60 m i n u t e s .
2 . Reduce t h e s t i r r e r speed t o produce a s l i g h t v o r t e x and
s l o w l y add t h e o x a l i c a c i d s o l u t i o n .
3 . When a l l t h e a c i d has been added, add t h e P o l y s o r b a t e 40
and mix u n t i l u n i f o r m .
F o r m u l a t i o n N o . 466
Rust Removal J e l IY
Insredi ents: WtD/ou
Water 53.20
Van Gel B 3.00
Rhodopol 2 3 0.80
P h o s p h o r i c A c i d, 50% Aqueous Sol u t ion 40 0 0
Octoxynol-9 3 00
Procedure:
1 . D r y b l e n d t h e Van Gel 0 and Rhodopol 2 3 and add them t o he
w a t e r w h i l e m i x i n g w i t h a p r o p e l l e r s t i r r e r a t 1800 rpm.
C o n t i n u e m i x i n g f o r 60 m i n u t e s .
2 . Reduce t h e s t i r r e r speed t o produce a s l i g h t v o r t e x and
s l o w l y add t h e P h o s p h o r i c A c i d s o l u t i o n .
3 . A f t e r a l l t h e a c i d has been added, add t h e O c t o x y n o l - 9
and mix u n t i l u n i f o r m .
F o r m u l a t i o n No. 467
*As r e c e i v e d b a s i s
SOURCE: R . T . V a n d e r b i l t Co., I n c . : Suggested F o r m u l a t i o n s
10 Advanced Cleaning Product Formulations
Cleaners f o r I n d u s t r i a l A p p l i c a t i o n
D e s i n f e c t i n q Cleaner, A c i d
I n s ed ien t s : wts/,
water 48.0
P h o s p h o r i c a c i d (85Oh) 24.0
S u l p h u r i c a c i d (98%) 5.0
P r o p e t a l 241 3.0
Dodigen 226 20.0
F o r m u l a CT 06-06-01
D i ppi n q C1 e a n e r
I r ed i
n e-n-t-sL Wt%
itatger 75.5
Tetrapotassium pyrophosphate 10.0
C a u s t i c soda 1.5
D i p r o p y l e n e g l y c o l monomethyl ether 5.0
S u l f e t a l 4069 5.0
Zusol a t 1008/85 3.0
F o r m u l a CT 07-03-01
Spray C 1 e a n e r
Insredients: Q
Water 58.0
Cublen D50 3.0
T r i e t h a n o l ami ne 3.0
S u l f e t a l 4105 4.0
P r o p e t a l 241 2.0
Z u s o l a t l005/85 0.5
P h o s f e t a l 201 2.0
Butyl glycol 5.0
C i t r u s terpene 0.5
I n h i b i t o r 4000 22.0
F o r m u l a CT 07-06-01
Ingredients
water 86.0
Sul f e t a l 4105 6.0
P r o p e t a l 99 3.0
Zusolat 1005/85 0.5
Butyl glycol 4.0
Orange t e r p e n e 0.5
Formula CT 07-06-03
SOURCE: Zschimmer & Schwarz GmbH 8, C o . : General Formulations
Dairy, Food and General Industrial Cleaners I1
D e s t a in e r
(Phosphate, Powder)
S o i l - O r g a n i c s t a i n s : f o o d , mold and g r a s s
Surface-Cement, wood, p a i n t , p o l y m e r i c
A p p l i c a t i o n Method-Brush
Manufacture-Dry blend/Agglomeration
Compos i t to^ Wt%
*STPP 25.0
M e t s o Beads 2048 25.0
Sodium S u l f a t e 8.0
PQ Epsom S a l t 2.0
**Octylphenoxy Polyethoxyethanol, 9- 0 M o l e s EO 2.0
Sodium P e r b o r a t e , Monohydrate 38.0
Use D i l u t i o n : 2 . 3 - 4 . 5 % bw ( 3 - 6 oz/ga ion)
* FMC
** Rhone P o u l e n c I g e p a l C A - 6 3 0
Destai ner
(Reduced Phosphate, Powder)
S o i l - O r g a n i c s t a i n s : f o o d , mold and g r a s s
Surface-Cement, wood, p a i n t , p o l y m e r i c
A p p l i c a t i o n Methods-Brush
Manufacture-Dry blend/Agglomeration
Composi t i o :
n &
%
*STPP 10.0
M e t s o Beads 2048 25.0
Sodi um S u l f a t e 8.0
PQ Epsom S a l t 2.0
**Octylphenoxy Polyethoxyethanol, 9 - 1 0 Moles EO 2.0
V a l f o r 100 Z e o l i t e A 15.0
Sodium P e r b o r a t e , Monohydrate 38.0
Use L e v e l : 3-6 oz/gallon
* FMC
** Rhone-Poulenc I g e p a l CA-630
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
12 Advanced Cleaning Product Formulations
Eaa C l e a n e r
L x o phosphatS?,.powder)
S o i 1- P r o t e i n
S u r f a c e - E g g and egg h a n d l i n g e q u i p m e n t
A p p l i c a t i o n M e t h o d - H i g h p r e s s u r e s p r a y (700-1400 psi)
Manufacture-Dry blend
Composi t i o n : Wt%
Sodium C a r b o n a t e 30.0
M e t s o Beads 2048 20.0
Sodium S u l f a t e 12.0
V a l f o r 100 Z e o l i t e A 30.0
* S o d i urn D i c h l o r o i s o c y a n u r a t e 2H20 3.0
* * S o d i um A1 k y l a r y l S u l f o n a t e Powder ( 9 0 % ) 5.0
Use D i l u t i o n : 0 . 7 5 - 1 . 5 % bw ( 1 - 2 oz/gallon)
* O l i n Chemical
** Witco
B g k i - n g Pan C l e a n e r
(Phosphate,- Powder)
S o i l - A n i m a l f a t and g r e a s e , v e g e t a b l e o i l
S u r f a c e - A 1 umi num and s t e e l
A p p l i c a t i o n Method-Irnmersion/brush
Manufacture-Dry blend/Agglomeration
C O ~ ~t 1 o n :
S l Wt%
*Sodium C a r b o n a t e 35.0
*STPP 12.0
**Nonylphenoxy P o l y e t h o x y e t h a n o l , 9-10 M o l e s € 0 3.0
Metso Pentabead 2 0 50.0
Use D i l u t i o n . 1 . 5 % bw ( 2 o z / g a l l o n )
* FMC
** Rhone-Poulenc I g e p a l CO-630
SOURCE: PQ C o r p . . Detergent F o r m u l a t i o n Guide
Dairy, Food and General Industrial Cleaners 13
Heavv D u t v C l e a n e r s
A l l Purpose-Food P r o c e s s P l a n t
Ingredients: Weight%
Water 74.00
EDTA ( E t h y l e n e d i a m i n e t e t r a c e t i c A c i d ) 2.00
TKPP ( T e t r a P o t a s s i u m P y r o p h o s p h a t e ) 4.00
P i l o t SXS-40 5.00
KOH, 45% 10.00
Calamide C 5.00
Comments a b o u t t h i s f o r m u l a :
1 . Add i n g r e d i e n t s i n o r d e r l i s t e d .
2 . Water and EDTA g i v e a m i l k y w h i t e s o l u t i o n .
3 . Upon a d d i n g t h e o t h e r i n g r e d i e n t s t h e s o l u t i o n i s c l e a r .
4. EDTA can b e s u b s t i t u t e d w i t h Na4EDTA t o make a c l e a r f i n a l
solution.
5 . T h i s i s a heavy d u t y c l e a n e r f o r f o o d p r o c e s s i n g p l a n t s .
6 . Use l e v e l . 2-4 o z p e r g a l l o n .
F o r m u l a t i o n HDC-004-01
Hard S u r f a c e Spray Cleaner
- qredients:
In Weight%
Water 89.00
TKPP ( T e t r a P o t a s s i u m P y r o p h o s p h a t e ) 1.oo
E t h y l e n e G l y c o l Monobutyl E t h e r 3.00
C a l s u d s 81 4.00
NH40H, 28% 3.00
Comments a b o u t t h i s f o r m u l a :
1 . I n g r e d i e n t Water and TKPP when m i x e d a r e c l e a r .
2 . Hazy s o l u t i o n when E t h y l e n e G l y c o l M o n o b u t y l E t h e r i s added.
3 . W i t h t h e a d d i t i o n o f C a l s u d s 81 t h e s o l u t i o n t u r n s c l e a r and
has a pH o f 9.
4 . When iUH40H i s added, t h e pH i n c r e a s e s t o 1 2 .
F o r m u l a t i o n HDC-002-01
SOURCE: P i 1o t Chemical Co. : Suggested Formul a t i ons
14 Advanced Cleaning Product Formulations
H i qh Foaming A1 k a l ine C l e a n e r
M o n a t e r i c EH c o n t r i b u t e s t o d e t e r g e n c y and e f f e c t i v e l y con-
t r o l s b o t h t h e k r a f f t and c l o u d p o i n t i n t h i s h i g h foaming
formulation.
I n n r e d ie n t s : Wt9/o
Water 76.0
Sodium H y d r o x i d e (50%) 10.0
Sodium M e t a s i l i c a t e ( P e n t a h y d r a t e ) 2.0
Dodecyl benzenesul f o n i c a c i d 2.0
M o n a t e r i c EH 8.0
Nonoxynol -1 0 2.0
Procedure:
Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Package.
Recommened Use D i l u t i o n : 1 : 2 0 w i t h w a t e r
F o r m u l a t i o n F-768
Heavy D u t y A l k a l i n e Degreaser
M o n a t e r i c EH a i d s i n t h e removal o f o i l y s o i l s w i t h o u t emul-
s i f i c a t i o n . I t e a s i l y displaces o i l y s o i l s from hard surfaces
and keeps them f r o m r e d e p o s i t i n g .
Ingredients: Wt%
Water 65.0
Sodi u m H y d r o x i de ( 5 0 % ) 20.0
Sodium M e t a s i l i c a t e ( P e n t a h y d r a t e ) 3.0
M o n a t e r i c EH 10.0
Nonoxynol -1 0 2.0
Procedure:
Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Package.
Recommended Use D i l u t i o n : 1 : 2 0 w i t h w a t e r .
F o r m u l a t i o n F-769
Steam C1eaner
Mona NF-20 c o n t r i b u t e s t h e non-foaming and d e t e r g e n c y proper-
t i e s i n t h i s formulation.
I n a r e d ients: WtO/o
Water 65.00
m
Potassi u Hydroxide 3.00
Sodium M e t a s i l i c a t e (Anhydrous) 10.00
T e t r a p o t a s s i u Pyrophosphate
m 10.00
Mona NF-20 12.00
Procedure:
Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n .
Typical Properties:
Cloud P o i n t : 75C
K r a f f t Point: tOC
Recommended Use D i l u t i o n : 4-6 o z . / g a l .
F o r m u l a t i o n F-762
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
Dairy, Food and General Industrial Cleaners 15
I n d u s t r i a l and Hiqh Pressure Cleaners
C1
- eaner. Strong1 y A1 Kal i ne
Inqredients: w
y%
Water 76.5
Cublen D 50 1.o
Tetrapotassi um pyrophosphate 4.0
C a u s t i c soda 0.6
Sodi u m m e t a s i 1 i c a t e 4.9
S u l f e t a l 4105 4.0
Z u s o l a t 1008/85 2.0
P h o s f e t a l 201 2.0
Butyl glycol 5.0
F o r m u l a CT 06-13-01
C1 e a n e r , Weakly A1 k a l ine
Ingredients: Wt%
Water 80.4
Cublen D 50 1.o
Tetrapotassium pyrophosphate 2.0
T r i e t h a n o l ami ne 3.6
S u l f e t a l 4105 4.0
Z u s o l a t 1008/85 2.0
P h o s f e t a l 201 2.0
Butyl glycol 5.0
F o r m u l a CT 0 6 - 1 3 - 0 2
Cleaner, S t r o n q l y A1 k a l i n e (Phosphate-Free)
I n g r e d i e c Wt%
Water 80.5
Cublen D50 1. o
Sodi um m e t a s i 1 i c a t e 4.9
C a u s t i c soda 0.6
S u l f e t a l 4105 4.0
Z u s o l a t 1008/85 2.0
P h o s f e t a l 201 2.0
Butyl glycol 5.0
F o r m u l a CT 06-13-03
@1 eaner, Weak1 y A1 k a l ine ( Phosphate-Free1
Ingredients: Wt%
Water 80.4
C u b l e n D 50 1. o
T r i s o d i um c i t r a t e 2.0
S u l f e t a l 4105 4.0
Z u s o l a t 1008/85 2.0
P h o s f e t a l 201 2.0
Butyl glycol 5.0
T r i e t h a n o l ami n e 3.6
F o r m u l a CT 06-13-04
SOURCE: Zschimmer & Schwarz GmbH & C o . : General Formulations
16 Advanced Cleaning Product Formulations
Metal Cleaner
(m
S o i l - P e t r o l e u m and a n i m a l o i l and g r e a s e
Surface-Metal: Steel
A p p l ic a t i on Method-Immersi on
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composi t i on : w.t%
Water 65.6
S t a r Sodi um S i 1 ic a t e 15.6
Sodium H y d r o x i d e (50%) 6.3
*Phosphate E s t e r 5.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; 6 Moles EO) 7.5
Use D i l u t i o n : 2%-5% b v
* Rhone-Poulenc Rhodafac RE-610
** Rhone-Poulenc R h o d a s u r f 91-6
Food I n d u s t r y C l e a n e r
(W
S o i l - H e a v y f o o d g r e a s e , o i l and p r o t e i n
Surface-Metal, ceramic, polymeric, glass
A p p l i c a t i o n Method-Wipe, mop o r b r u s h
Manufacture-Mix t a n k w i t h p r o o e l l e r s t i r r e r
Composition: Wt%
Water 74.0
TKPP (60%) 3.0
N C l e a r Sodium S i l i c a t e 7.0
Sodi um H y d r o x i d e (50%) 3.5
*Phosphate E s t e r 2.5
**Ethylene Glycol n-Butyl Ether 5.0
* * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3; 6 . 5 Moles € 0 ) 5.0
Use D i l u t i o n : 6-12% bw ( 8 - 1 6 o z / g a l l o n )
* Rhone-Poulenc Rhodafac RE-600
** Dow C h e m i c a l , U n i o n C a r b i d e
*** Rhone-Poulenc R h o d a s u r f LA-7
SOURCE: PQ C o r p . : Detergent F o r m u l a t i o n Guide
Dairy, Food and General Industrial Cleaners 17
M i l k Can C l e a n e r
(Phosphat_e, Powder)
Sol 1 - F a t and p r o t e i n
Surface-Metal
A p p l i c a t i o n Method-Wipe o r b r u s h
Manufacture-Dry blend/Agglomeration
Compo_sition’ WX/,
*STPP 30.0
M e t s o Beads 2048 30.0
*Sod1 u m C a r b o n a t e 35.0
+*Sod1 um D i c h l o r o i s o c y a n u r a t e , 2H20 3.0
* * * S o d i u m A1 k y l a r y l S u l f o n a t e Powder, (90%) 2.0
Use D i l u t i o n 0.75-1 5% bw (1-2 o z / g a l l o n )
* FMC
** O l i n Chemical
*** w1 t c o
M i l k Can CLea-ner
(Zeco Phosphate, Powder)
S o l 1 - F a t and p r o t e i n
S u r f ace-Metal
A p p l i c a t i o n Method-Wipe o r b r u s h
Manufacture-Dry blend
Composi t i on : Wt%
Val f o r 100 Z e o l i t e A 20.0
Metso Pentabead 20 40.0
Sodium C a r b o n a t e 35.0
*Sodium D i c h l o r o i s o c y a n u r a t e , 2H20 3.0
**Sod1 um A 1 k y l a r y l S u l f o n a t e Powder, (90%) 2.0
Use L e v e l : 1 - 2 o z / g a l l o n
* O l i n Chemical
** Stepan, W i t c o
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
18 Advanced Cleaning Product Formulations
Powdered Enzyme Presoaks
Economy Presoak
Component: Wt%
Soda Ash 80.0
Sodium Metasilicate Pentahydrate 10.0
Sodium Dodecylbenzenesulfonate Powder 5.0
Burcosperse AP Powder 3.0
Burcotase EP-60 2.0
Premi um Presoak
Component: 5
Soda Ash 40.0
STPP 35. n
Neodol 25.7 5.0
Sodium Metasi 1 icate Pentahydrate 10.0
Sodium Dodecylbenzenesulfonate Powder 5.0
Burcosperse AP Powder 3.0
Burcotase EP-60 2.0
The recommended use concentration o f these products i s 1-4
g/1 in the presoak bath. F o r optimum results, the presoak
temperature should be 130-15OF.
Enzyme Prespotter f o r Oilv/Smuttv Soils
Component: wtD/,
Water 49.0
Propyl ene G1 ycol 10.0
Dodecyl benzenesul foni c Acid 10.0
TEA-85 20.0
Burco TME 5.0
Nonionic Surfactant* 5.0
Burcotase LL-100 1.o
*An HLB of 9 . 5 - 1 0 . 0 i s preferred. Alcohol ethoxylates are
preferred.
Add components in the order listed. Blend until uniform
between each addition. Cool before adding the enzyme.
SOURCE: Burlington Chemical G o . , Inc. : Suggested Formulations
Dairy,Food and General Industrial Cleaners 19
S a n i t i z i n s Cleaner
(Phosphate, Powder)
S o i l - H o s p i t a l s o i l : sebum, b l o o d , u r i n e , e t c .
Surface-Metal, ceramic, polymeric
A p p l i c a t i o n Method-Wipe o r b r u s h
Manufacture-Dry Blend
Composi t 1 1 0 ~ Wt%
Metso Beads 2048 20.0
*Sodium C a r b o n a t e 35.0
*STPP 30.0
**Sodi urn D i c h l o r o i s o c y a n u r a t e , 2H20 10.0
***Sod; um A1 k y l a r y l S u l f o n a t e Powder (99%) 5.0
Use D i l u t i o n : 0 . 7 5 - 1 . 5 % bw ( 1 - 2 oz/gallon)
* FMC
** 01 i n Chemical
*** witco
Sani t i z i na A a e n t
(Phosphate, Powder)_
S o i l - H o s p i t a l s o i l : sebum, b l o o d , u r i n e , etc.
Surface-Metal, ceramic, polymeric
A p p l i c a t i o n Method-Wipe, b r u s h
Manufacture-Dry blend/Agglomeration
Composi t i on : Wt%
*STPP 30.0
*Sodi um C a r b o n a t e 25.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl6; 12 M o l e s EO) 10.0
M e t s o Pentabead 20 30.0
Quaternary Germicide 5.0
Use D i l u t i o n : 0 . 7 5 - 1 . 5 % bw ( 1 - 2 oz/gallon)
* FMC
** Rhone-Poulenc R h o d a s u r f LA-12
SOURCE: PQ C o r p . : Detergent F o r m u l a r y Guide
3 Degreaser
.
20
Degreasers 21
Aqueous D e s r e a s e r
Ingredients: Wei q h t %
Water 60.80
NaOH, 50% 2.00
Cal s o f t LAS-99 9.40
P i l o t SXS-40 8.70
C a l o x y l a t e N-9 4.60
TKPP ( T e t r a P o t a s s i u m P y r o p h o s p h a t e ) 4.70
Sodium M e t a s i 1 i c a t e 6.60
E t h y l e n e G l y c o l Monobutyl Ether 3.20
Comments a b o u t t h i s f o r m u l a :
D i s s o l v e t h e s a l t s i n t h e water f i r s t .
F o r m u l a t i o n DEG-001-01
Aqueous D e q r e a s e r
d - L i monene M i c r o e m u l s i o n
Ingredients: Weight%
d - L i monene 9.90
C a l s u d s CD-6 9.80
C a l imu1 se PRS 2.44
Diethylene Glycol n-Butyl Ether 4.93
Water 73.00
Comments a b o u t t h i s f o r m u l a :
1 . A d d i t i o n a l C a l s u d s CD-6 may b e needed t o c l a r i f y t h e sample.
2 . Add t h e w a t e r s l o w l y .
F o r m u l a t i o n DEG-002-01
Water Based D e a r e a s e r
Ingredients: Weight%
Water 68.50
NaOH, 50% 2.00
Cal s o f t LAS-99 7.00
P i lot SXS-40 7.50
Na4EDTA 2.00
C a l o x y l a t e N-9 5.00
E t h y l e n e G l y c o l Monobutyl Ether 3.00
Sodi urn M e t a s i 1 ic a t e 5.00
Comments a b o u t t h i s f o r m u l a :
1 . T h e r e i s a p h o s p h a t e v e r s i o n where 3 . 5 % sodium t r i p h o s p h a t e
i s s u b s t i t u t e d f o r t h e sodium m e t a s i l i c a t e and Na4EDTA.
2 . Use w a t e r t o b a l a n c e i n g r e d i e n t s .
F o r m u l a t i o n DEG-006-01
SOURCE: P i l o t Chemical C o . : Suggested F o r m u l a t i o n s
22 Advanced Cleaning Product Formulatiorrs
m r e a s e r Concentrate
( L i q u i d)
Soil-Grease, o i l
Surface-Pai n t , polymeric, metal
A p p l i c a t i o n Method-Spray o r w i p e
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composi t i on : t/
w"o
Water 67.0
M e t s o Beads 2048 8.0
*Sodi urn P o l y a c r y l a t e (40%) 5.0
**Phosphate E s t e r 10.0
* * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 6 M o l e s EO) 5.0
* * * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 2 . 5 Moles EO) 5.0
Use D i l u t i o n : Normal Duty-1.5% bw ( 2 o z / g a l l o n )
Heavy D u t y - 3 . 0 % bw ( 4 o z / g a l l o n )
* Rhone-Poulenc C o l l o i d 226/35 P o l y a c r y l a t e (40%)
** Rhone-Poulenc Rhodafac R E - 6 1 0
*** Rhone-Poulenc R h o d a s u r f 91-6
**** Rhone-Poulenc R h o d a s u r f A-24
Metal De-Oiling L i q u i d Concentrate
( L i quid )
Soi 1 - P e t r o l e u m - b a s e d o i 1
S u r f a c e - M e t a l : S t e e l , c o p p e r , aluminum, e t c .
Appl i c a t i o n Method-Spray a n d / o r immersi on
Manufacture: Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composi t i on : W B
Water 42.0
S t a r s o Sodi urn S i 1 i c a t e 12.0
EDTA, T e t r a s o d i u m (37%) 16.0
Sodium X y l e n e S u l f o n a t e (40%) 20.0
* L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; 6 M o l e s EO) 3.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11 2 . 5 M o l e s EO) 7.0
Use D i l u t i o n : 2%-4% b v
* Rhone-Poulenc R h o d a s u r f 91-6
** Rhone-Poulenc R h o d a s u r f A-24
SOURCE: PQ Corp. : D e t e r g e n t F o r m u l a t on G u i d e
aegreasers 23
S o l v e n t Denreaser
Carbopol r e s i n s a r e used t o e m u l s i f y and s t a b i l i z e t h i s
d-limonene o i l based e m u l s i o n . I n a d d i t i o n , t h e use o f t h e
r e s i n provides v e r t i c a l c l i n g t o increase the contact time o f
t h e d e t e r g e n t on t h e s o i l e d s u r f a c e and enhance consumer
convenience.
I n q r e d ient : 9
D I Water 81.18
Carbopol ETD 2623 ( 1 ) 0.32
d-Limonene ( 2 ) 10.00
Propylene g l y c o l methyl e t h e r ( 3 ) 2.00
Alkylbenzene s u l f o n i c a c i d ( 4 ) 2.00
C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO ( 5 ) 1.50
Isopropanol 2.50
Sodium h y d r o x i d e (50%) 0.50
B r o o k f ie l d v i s c o s i t y (RVT-20 rpm) : 750 cps
P r o d u c t pH: 9 . 5 - 1 0
P r o d u c t C1 a r i t y : Opaque
(1) BFGoodrich
(2) A r y l e s s e n c e , I n c . : H-7892 d-limonene
(3) Dow Chemical : Dowanol PM
(4) Stepan C o . : B i o s o f t S-100
(5) S h e l l Chemical: Neodol 23-6.5
Procedure:
1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous.
2 . Add t h e d-limonene w i t h good a g i t a t i o n and mix u n t i l homogene-
ous.
3 . Reduce a g i t a t i o n and add t h e g l y c o l e t h e r , s u l f o n i c a c i d , and
alcohol ethoxyl ate.
4 . Add t h e i s o p r o p a n o l .
5 . Add t h e sodium h y d r o x i d e u n t i l t h e t a r g e t pH r a n g e i s
reached.
6 . Add c o l o r , as d e s i r e d .
T o t a l Actives:
d-limonene: 10.0
Propylene g l y c o l methyl e t h e r : 2.0
Sodium a1 k y l b e n z e n e s u l f o n a t e : 2.2
Psopropanol : 1.5
C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO: 2.5
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-330
24 Advanced Cleaning Product Formulations
S o l v e n t Based Deqreaser
Insredients: Wei ghP%
Kerosene 72.85
Aristonate M 3.00
Pine O i l 10.00
T a l l O i l F a t t y Acid 10.06
C a l o x y l a t e N-9 3.02
Hexyl ene G1 y c o l 1.06
Comments a b o u t t h i s f o r m u l a :
1 . Use a l o w o d o r g r a d e o f t a l l o i l f a t t y a c i d .
2 . Add i n g r e d i e n t s i n t h e o r d e r i n d i c a t e d .
3. A r i s t o n a t e L can be s u b s t i t u t e d f o r A r i s t o n a t e M~
F o r m u l a t i o n DEG-004-01
S o l v e n t Based Degreaser
Ingredients: W ig h t %
e
Aristonate M 5.10
T r i t o n X-45 5.00
T r i t o n N-101 2.99
Kerosene 86.93
Comments a b o u t t h i s f o r m u l a :
1 . Kerosene can be s u b s t i t u t e d w i t h A r o m a t i c Naphtha.
2 . A r i s t o n a t e M can be s u b s t i t u t e d w i t h A r i s t o n a t e L .
F o r m u l a t i o n DEG-003-01
E n q i n e C l e a n e r and Deqreaser
Ingredients: Weight%
Water 58.94
M I PA 20.33
C a l imu1s e PRS 5.08
Dowanol DPM 45.24
Na4EDTA 0.41
Comments a b o u t t h i s f o r m u l a :
Clear, p a l e y e l l o w product
F o r m u l a t i o n DEG-005-01
SOURCE: P i 1o t Chemi c a l Co. : Suggested Formul a t ions
lshwashing Detergents
25
26 Advanced Cleaning Product Formulations
A u t o m a t i c Dishwash Deteraent-Consumer
( Z e r o Phosohate. C h l o r i n e F r e e . Powder1
S o i l - F o o d g r e a s e , o i l and p r o t e i n
S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c
A p p l i c a t i o n Method-Dishwasher ( s p r a y )
Manufacture-Dry Blend/Agglomeration
Composi t i on :
Sodi urn C i t r a t e D i h y d r a t e 10.0
* B r i t e s i l H20 Hydrous P o l y s i l i c a t e 20.0
Sodi urn C a r b o n a t e 23.0
* * L i q u i d N o n i o n i c S u r f a c t a n t ( 3 moles EO) 3.0
* * * A c u s o l 445ND S o d i um P o l y a c r y l a t e ( 9 2 % sol id s ) 4.0
****Sodium P e r b o r a t e Monohydrate 10.0
V a l f o r 100 Z e o l i t e A 15.0
Sodium S u l f a t e 15.0
* 2 . 0 w e i g h t r a t i o powder w i t h 1 7 . 5 % w a t e r
** Rhone-Poulenc A n t a r o x BL-330
*** Rohm & Haas; o r use a c o m b i n a t i o n o f A c u s o l 445ND and A c u s o l
479ND ( 2 w t . % each)
**** O r use Sodium D i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r -
i n e ) a t 2 w t % . Balance w i t h s u l f a t e .
A u t o m a t i c Dishwash Detersent-Consumer
(Phosphate, C h l o r i n e F r e e , Powder)
S o i 1-Food g r e a s e , o i 1 and p r o t e i n
S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c
A p p l i c a t i o n Method-Dishwasher ( s p r a y )
Manufacture-Dry blend/Agglomeration
Composi t i on :
RU L i q u i d Sodium S i l i c a t e 15.0
*Sodium C a r b o n a t e 23.0
* * L i q u i d N o n i o n i c S u r f a c t a n t ( 3 moles EO) 3.0
* * * A c u s o l 445ND Sodi um P o l y a c r y l a t e (92% s o l id s ) 4.0
****Sodium P e r b o r a t e M o n o h y d r a t e 10.0
*STPP 30.0
Sodi um S u l f a t e 15.0
* FMC
** Rhone-Poulenc A n t a r o x BL-330
*** Rohm & Haas; O r u s e a c o m b i n a t i o n o f A c u s o l 445ND and
A c u s o l 479ND ( 2 w t . % each)
**** O r u s e Sodi u m D i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r -
i n e ) a t 2 w t %. B a l a n c e w i t h s u l f a t e .
SOURCE: PO C o r p . : Detergent F o r m u l a t i o n Guide
Dishwashing Detergents 27
A u t o m a t i c Dishwash D e t e r c i e n t - I n d u s t r i a l & I n s t i t u t i o n a l
(Phosphate, S o l i d B l o c k )
S o i l - F o o d g r e a s e , o i l and p r o t e i n
S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c
A p p l i c a t i o n Method-Dishwasher ( s p r a y )
Manufacture-Solid block
Composi t i on : Wt%
M e t s o Beads 2048 25.0
NaOH (50% S o l u t i o n ) 25.0
*STPP 35.0
*Sodi um C a r b o n a t e 12.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 M o l e s EO; C12-15) 3.0
* FMC
** Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r
S h e l l Chemical Neodol 25-7
A u t o m a t i c D i shwashi n g D e t e r g e n t - I n d u s t r i a1 & I n s t i t u t i o n a l
(L iquid)
S o i l - F o o d g r e a s e , o i l and p r o t e i n
S u r f a c e - M e t a l , c e r a m i c and g l a s s
A p p l i c a t i o n Method-Dishwasher ( s p r a y )
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composition : Wt%
Water 50.9
* A c r y s o l ASE 108 ( A c r y l i c P o l y m e r ) 6.9
* * T r i t o n DF-16 ( N o n i o n i c S u r f a c t a n t ) 3.0
P o t a s s i um H y d r o x i d e (45%) 1.2
TKPP (60%) 25.0
N C l e a r Sodium S i l i c a t e 13.0
Use D i l u t i o n : 0 . 1 5 - 0 . 3 0 % bw ( 0 . 2 - 0 . 4 oz/gallon)
* Rohm & Haas; o r Rhone-Poulenc C o l l o i d 226/35 P o l y a c r y l a t e ( 4 0 % )
** Rohm & Haas; o r Rhone-Poulenc A n t a r o x EL-330
SOURCE: PQ C o r p . : Detergent F o r m u l a t i o n Guide
28 Advarrced Clearring Product Formulatiorls
A u t o m a t i c D i s h w a s h D e t e r g e n t T I n d u s t r i a l - &- I n s t i ~ ! . ! t i g n ~ j
(Zero-Phosphate, C h l o r i n e F r e e , Powde_rj
S o i l - F o o d g r e a s e , oil and p r o t e i n
S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c
A p p l i c a t i o n Method-Dishwasher ( s p r a y )
Manuf a c t u r e - D r y B1 e n d / A g g l o m e r a t i on
Composi t io n : Wt%
M e t s o P e n t a b e a d 20 30.0
Sod1 um C a r b o n a t e 26.0
* L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 M o l e s € 0 ; C12-15) 3.0
* * A c u s o l 445ND Sodium P o l y a c r y l a t e ( 9 2 % s o l i d s ) 4.0
***Sodium P e r b o r a t e M o n o h y d r a t e B l e a c h 10.0
Val f o r 100 Z e o l i t e A 15.0
Sodium S u l f a t e 12.0
* Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r
S h e l l C h e m i c a l Neodol 25-7
** Rohm & Haas; O r u s e a c o m b i n a t i o n o f A c u s o l 445ND and A c u s o l
479ND ( 2 w t % e a c h ) .
*** O r use sodium d i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s c h l o r i n e )
a t 2 w t % . Balance w i t h s u l f a t e .
Stri-a 1 _&-Ins t_ii-tluti_ o?e_a_8
A u t o m . a t i c P ~ h w a ~ h _ D e t e ~ e _ n ~ . ~ I ~.d - u
LP h o s p h a t e _ , C h l _ o r i n e _Free- Pow_s1ec)
S o i l - F o o d g r e a s e , o i l and p r o t e i n
S u r f a c e - M e t a l , g l a s s , p l a s t i c and c e r a m i c
A p p l i c a t i o n Method-Dishwasher ( s p r a y )
Manufacture-Dry Blend/Agglomeration
Composition: Wt%
G t s o P e n t a b e a d 20 30.0
*STPP 25.0
* S o d i um C a r b o n a t e 28.0
* * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 M o l e s EO; C12-15) 3.0
* * * A c u s o l 445ND S o d i um P o l y a c r y l a t e ( 9 2 % sol i d s ) 4.0
****Sodium P e r b o r a t e Monohydrate B l e a c h 10.0
* FMC
** Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r
S h e l l C h e m i c a l Neodol 2 5 - 7
*** Rohm & Haas; O r u s e a c o m b i n a t i o n o f A c u s o l 445ND and
A c u s o l 479ND ( 2 w t % e a c h )
**** O r use sodium d i c h l o r o i s o c y a n u r a t e b l e a c h ( c o n t a i n s
c h l o r i n e ) a t 2 w t % . Balance w i t h s u l f a t e .
SOURCE: PP C o r p . : Detergent F o r m u l a t i o n Guide
Dishwashing Detergents 29
A u t o m a t i c D i s h w a s h i ng Gel w i tJ1_..Chlori n e B1 e a c h
Carbopol r e s i n s a r e used t o t h i c k e n t h e p r o d u c t t o reduce
s p l a s h i n g , p r o v i d e c u p r e t e n t i o n i n t h e d i s h w a s h e r , and c r e a t e a
s t a b l e suspension o f i n s o l u b l e s ( i . e . phosphate b u i l d e r s ) i n t h i s
AOL f o r m u l a t i o n c o n t a i n i n g c h l o r i n e b l e a c h .
Inqredient: Wt%
01 w a t e r 44.75
C a r b o p o l 672 ( 1 ) 1.25
P o t a s s i um h y d r o x i d e ( 4 5 % ) 5.00
2 . l r p o t a s s i u m s i l i c a t e (39%) ( 2 ) 15.00
P o t a s s i urn c a r b o n a t e ( 3 ) 5.00
Sodium t r i p o l y p h o s p h a t e ( 4 ) 20.00
S o d i um h y p o c h l o r i t e ( 1 2 . 5 C 0 h ) 8.00
Sodium n - d e c y l d i p h e n y l o x i d e d i s u l f o n a t e ( 4 5 % ) ( 5 ) 1.oo
B r o o k f i e l d v i s c o s i t y (RVT-20 rpm): 15,000 cps
P r o d u c t p H : 12-13
P r o d u c t c l a r i t y : Opaque
(1 BFGoodri c h
( 2 The P C o r p .
O
( 3 Armand
(4 FMC C o r p .
( 5 ) O o w C h e m i c a l : Dowfax 382
Procedure:
1 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an
i m p e l 1e r s u i t a b 1 e f o r g e n e r a l m i x i ng and b l e n d i n g o p e r a t i o n s .
Screen t h e Carbopol r e s i n i n t . 0 t h e v o r t e x o f t h e r a p i d l y
a g i t a t i n g w a t e r ( 8 0 0 r p m ) . A l l o w t o m i x u n t i l homogeneous
and f r e e o f p o l y m e r l u m p s .
2 . Add i n t h e p o t a s s i u m h y d r o x i d e a n d p o t a s s i u m s i l i c a t e . M i x
u n t i l homogeneous. The p r o d u c t w i l l become v e r y t h i c k a t t h i s
poi n-t.
3 . Add t h e p o t a s s i u m c a r b o n a t e and p h o s p h a t e . M i x u n t i l t h e r e
a r e no more p h o s p h a t e p a r t i c l e s . H e a t i n g t o 50-60C w i l l
speed t h i s p r o c e s s .
4 . Add t h e b l e a c h and t h e n t h e s u r f a c t a n t . M i x u n t i l homogeneous.
A d j u s t t h e pH t o 12-13 u s i n g KOH. 00 n o t u s e a c i d t o r e d u c e
t h e pH, e s p e c i a l l y a f t e r t h e a d d i t i o n o f t h e b l e a c h .
5 . Add c o l o r and f r a g r a n c e , a s d e s i r e d . Cool t h e p r o d u c t t o
b e l o w 30C t o a v o i d e x c e s s i v e b l e a c h d e c o m p o s i t i o n .
Total Actives:
Phosphorous c o n t e n t : 5.0
S i l i c a t e (as Si02): 3.9
C a r b o n a t e ( a s Na2CO3): 3.8
Ava i 1a b 1e c ti 1o r ine : 1.o
SOURCE: BFGoodrich S p e c i a l t y C h e m i c a l s : DET-100
30 Advanced Cleaning Product Formulations
Clear, C o l o r l e s s Manual - D i s h Wash
Insredients: Wt%
Water, D . I. 57.5
W i t c o l a t e ES-3 34.2
R e w o t e r i c AM 8-14 5.0
Ethanol 3.0
Sodium C h l o r i d e 3.3
B l e n d i n g Procedure:
Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d . D i s s o l v e c o m p l e t e l y
between each a d d i t i o n .
Comment:
R e w o t e r i c AM 8-14: Grease c u t t e r and foam b o o s t e r .
Formula 1 3 2
Powder S t a i n l e s s S i l v e r w a r e Pre-Soak
I n q r e d ie n t s : Wt%
Sodium Carbonate (Soda Ash) 67.0
P e t r o BAF Powder 5.0
DeSonic 1 1 N 11 . o
T r i sodi u m Phosphate, Anhydrous 2.0
C a u s t i c Soda Beads 25.0
61 e n d i ng P r o c e d u r e :
Blend i n g r e d i e n t s i n t h e o r d e r l i s t e d
Use D i 1u t u i on : 1 o z / g a l
Formula 1 2 7
Low A1 k a l ine Warewashi nq Block
I n q r e d ie n t s : W B
Water, D . I . 16.0
R.U. S i l i c a t e 29.0
DeSoni c LFD-97 2.0
Sodium Carbonate (Soda Ash) 23.0
Sodium T r i p o l y p h o s p h a t e Code 185 30.0
B l e n d i n g Procedure:
B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d . When s l u r r y i s
produced, p o u r i n t o molds and a l l o w t o harden.
Formula 1 2 9
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Dishwashing Detergents 31
Dish Washi nq Agents
clear, liquid, 25% W A S
alkanesulphonate:ethersulphate=4:l
Ingredi e m
A : H o s t a p u r SAS 6 0 33.30
Genapol Z R O l i q u i d 17.90
B: Water 48.50
Preservative 0.10
DY e
q.s.
Perfume 0.20
Tests:
v i s c o s i t y (rnPas) : 75
C l o u d p o i n t :
Deionized water 52.9
Dodecylbenzene s u l f o n a t e , sodium s a l t , ( 6 0 % s o l i d s ) 31 . 0 ( 1 8 )
L a u r y l a l c o h o l e t h e r s u l f a t e - 4 E 0 , (60% s o l i d s ) 10. l ( 6 )
Ethyl alcohol 1.5
Tomah E-14-5 3
Coco d i e t h a n o l ami de 3
90% Premi u m Formul a t ion
Inqredi ents: Wt.%
Deionized water 38.6
Dodecylbenzene s u l f o n a t e , sodium s a l t , (60% s o l i d s ) 38.8(22.5)
L a u r y i a l c o h o e t h e r s u l f a t e - 4 EO, (60% s o l i d s ) 12.6(7.5)
Ethyl alcohol 4
Tomah E-14-5 3
Coco d i e t h a n o ami de
Premi urn _ o r _ u l a t i o n
_ _ F m ~ - ~
I n q r e d i en& Wt.%
Deionized water 28.3
Dodecyl benzene s u l f o n a t e , s o d i um s a l t , (60% s o l i d s ) 46.6( 27)
L a u r y l a l c o h o l e t h e r s u l f a t e - 4 E 0 , (6O0h s o l i d s ) 15.1 (9)
Ethyl alcohol 4
Tomah E-14-5 3
Coco d i e t h a n o l ami de 3
SOURCE: Tomah P r o d u c t s , I n c . : Suggested F o r m u l a t i o n s
Dishwashing Detergents 35
Hand D i s h D e t e r a e n t F o r m u l a t i o n s
C l e a r D i shwash
IngredienPs 1 \N t %
Water 12.30
SXS (4O%j 8.00
C12 A i f a O i e f in s u i f o n a t e ( 2 8 . 7 5 % s o i i d s j 52.50
Lauryl e t h e r s u l f a t e - 3E0 (27.5% s o l i d s ) 18.20
Tomah AO-728 S p e c i a l 6.00
NaCl* 3.00
M i x i ng I n s t r u c t i o n s :
Add t h e i n g r e d i e n t s i n t h i s o r d e r .
M i x u n t i l homogeneous a f t e r each a d d i t i o n
SpG 2 0 / 2 0 C : 1 . 0 5
pH: 6
V i s c o s i t y : 505 c p s ( B r o o k f i e i d LVT 3 0 rpm s p i n d l e number 2)
NOTES: *Add more N a c l t o i n c r e a s e v i s c o s i t y .
__
P e a r i e s c e n t U i shwash
ingredients: WLL7O
Water 54.40
Dodecyibenzene s u i f o n a t e ( 6 0 % s o l i d s ) 25.00
C a u r y i e t h e r s u l f a t e - 4 E 0 (60% s o i i d s j 8 . 30
O p a c i f i e r L a t e x (4OWja 0.04
P e a r l i z i n g Agent ( 4 7 % j * * 2.30
Tomah A0-728 S p e c i a i 4.00
Tomah A m p h o t e r i c L 6.00
Mixing Instructions:
Add t h e i n g r e d i e n t s i n t h i s o r d e r .
M i x u n t i i homogeneous a f t e r each a d d i t i o n .
SpG 2 0 / 2 0 C : 1 . 0 3
PH: 6.5
V i s c o s i t y : 1363 c p s ( B r o o k f i e l d LVT, 12 rpm, s p i n d l e number
NOTES: * L y t r o n 295 Mortor! i n t e r n a t i o n a l
** E u p e r i a n PK-771, Henkei
SOURCE: Tomah P r o d u c t s , f n c . : Suggested F o r m u l a t i o n s
36 Advanced Cleaning Product Formulations
Hand D i s h w a s h i n g L i q u i d
C a r b o p o l r e s i n s c a n be used t o b u i l d r h e o l o g y i n p l a c e o f
u s i n g h i g h e r s u r f a c t a n t l e v e l s . T h i s w i l l improve t h e s k i n f e e l
and m i l d n e s s . A d d i t i o n a l l y , because o f t h e i r h i g h y i e l d v a l u e ,
t h e use o f Carbopol r e s i n s w i l l i n c r e a s e foam s t a b i l i t y .
Inqredient: Q
D I Water 38.11
Carbopol ETD 2623 ( 1 ) 0.70
5 8 0 0 MW p o l y a c r y l i c a c i d ( 2 ) 4.00
A l p h a s u l f o m e t h y l e s t e r (37%) ( 3 ) 27.03
TEA (99%) 5.50
Sodium l a u r y l e t h e r s u l f a t e (28%) ( 4 ) 17.86
Coconut d i e t h a n o l ami de ( 5 ) 2.00
B r o o k f i e l d v i s c o s i t y (RVT-20 rpm): 400-600 cps
P r o d u c t pH: 6 . 0 - 7 . 0
Product c l a r i t y : Clear
( 1 ) BFGoodrich
( 2 ) BFGoodrich: Good-Rite K-7058
( 3 ) Stepan Co.: A l p h a s t e p ML-40
( 4 ) Henkel C o r p . : S t a n d a p o l ES-3
( 5 ) Stepan C o . : N i n o l 11-CM
Procedure:
1 . Use a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an
i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s
P r e h e a t t h e w a t e r t o 40-5OC. Screen t h e Carbopol r e s i n i n t o
t h e v o r t e x o f t h e r a p i d l y a g i t a t i n g w a t e r (800 r p m ) . A l l o w
t o m i x f o r a t l e a s t 15 m i n u t e s o r u n t i l homogeneous and f r e e
o f p o l y m e r lumps.
2 . Add i n t h e l o w m o l e c u l a r w e i g h t p o l y a c r y l a t e w i t h c o n s t a n t
mixing.
3 . Add i n t h e ASME s u r f a c t a n t w i t h a l o w l e v e l o f a g i t a t i o n
t o a v o i d e x c e s s i v e foam g e n e r a t i o n .
4 . Add i n t h e TEA, l a u r y l e t h e r s u l f a t e , and c o c o n u t DEA.
5 . A d j u s t t h e pH u s i n g TEA t o r e a c h t h e t a r g e t r a n g e . Add c o l o r
and p e r f u m e , a s d e s i r e d . Cool b a t c h t o room t e m p e r a t u r e .
Total Actives:
Alpha s u l f o methyl e s t e r : 10.00
Sodium l a u r y l e t h e r s u l f a t e : 5.00
Coconut d i e t h a n o l a m i d e : 2.00
5 8 0 0 MW p o l y a c r y l i c a c i d : 2.00
SOURCE: BFGoodrich S p e c i a l t y C h e m i c a l s : DET-I10
Dishwashing Detergents 37
Hand Dishwashina P a s t e
Carbopol r e s i n s a r e used t o t h i c k e n and suspend i n s o l u b l e s i n
t h i s hand d i s h w a s h i n g p a s t e . A d d i t i o n a l l y , because o f t h e i r h i g h
y i e l d v a l u e , t h e use o f Carbopol r e s i n s w i l l i n c r e a s e t h e foam
s t a b i 1it y .
I n a r e d ient : Wt%
D I water 41.50
Carbopol 672 ( 1 ) 1 .oo
A l k y l b e n z e n e s u l f o n i c a c i d (9796) ( 2 ) 17.00
m
Sodi u h y d r o x i d e (50%) 5.00
2 . 4 r sodium s i l i c a t e (52%) ( 3 ) 7.50
Sodium t r i p o l y p h o s p h a t e ( 4 ) 15.00
Sodium c a r b o n a t e 5.00
Sodium o l e f i n s u l f o n a t e (40%) (5) 8.00
B r o o k f i e l d v i s c o s i t y (RVT-20 rpm) : 75,000 cps
P r o d u c t pH: 10-11
P r o d u c t c l a r i t y : Opaque
( 1) BFGoodri ch
(2) Stepan Co.: B i o s o f t S-100
(3) The PO Corp.
(4) M
F C Corp.
( 5 ) Stepan Go.: E i o t e r g e AS-40
Procedure:
1 . Use a L i g h t n i n ’ M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an
i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t o n s .
Screen t h e Carbopol r e s i n i n t o t h e v o r t e x o f t h e r a p i d l y
a g i t a t i n g w a t e r (800 r p m ) . A l l o w t o m i x u n t i l homogeneou
and f r e e o f polymer lumps.
2 . Add t h e s u l f o n i c a c i d w i t h c o n t i n u o u s a a i t a t i o n .
3 . Add t h e sodium h y d r o x i d e and sodium s i l i c a t e w i t h c o n t i n u o u s
a g i t a t i on. M i x u n t i1 homogeneous.
4 . S l o w l y , add t h e phosphate. M i x u n t i l homogeneous and f r e e o f
phosphate p a r t i c l e s . H e a t i n g t h e p r o d u c t t o 50-60C w i l l speed
up t h i s p r o c e s s .
5 . Add t h e sodium c a r b o n a t e and o l e f i n s u l f o n a t e . M i x u n t i l
homogeneous.
6 . A d d c o l o r and f r a g r a n c e , as d e s i r e d .
T o t a l A c t ives :
Phosphorous c o n t e n t : 3.7
S i l i c a t e (as Si02): 2.7
Carbonate ( a s Na2C03): 5.0
Sodium o l e f i n s u l f o n a t e : 3.2
Sodium a l k y l b e n z e n e s u l f o n a t e : 17.6
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-111
1
38 Advanced Cleaning Product Formulations
L i g h t Duty Liquid, Premium Hand D i s h w a s h
Ingredients: Wt%
Water, D . I . 30.2
W i t c o l a t e SE-5 21.7
W i t c o n a t e 1260 S l u r r y 36.7
W i t c a m i de 128T 5.0
P e t r o LBA L i q u i d 1.9
Sodium S u l f a t e 2.6
Ethanol 1.8
Formal i n 0.1
P e r f u m e , Dye 9,s.
81 e n d i n g P r o c e d u r e :
B l e n d i n g r e d i e n t s i n t h e o r d e r l i s t e d . A d j u s t pH t o 6 . 5 - 7 . 0
using C i t r i c Acid.
Typical Properties:
V i s c o s i t y , c p s : 230
A p p e a r a n c e : C1 e a r L i q u i d
F o r m u l a 113
L i g h t D u t y L i q u i d Low C o s t Hand D i s h w a s h
Ingredients:.
W a t e r , D . I. 81 . 5
W i t c o l a t e SE-5 5.5
W i t c o n a t e 1260 S l u r r y 9.2
W i t c a m i d e 128T 1.2
P e t r o LBA L i q u i d 0.5
Sodium C h l o r i d e 2.0
Formal i n 0.1
Perfume, Dye q.s.
Blending Procedure:
Blend i n g r e d i e n t s i n t h e order l i s t e d . A d j u s t pH=6.5-7.0
using C i t r i c Acid.
Typical Properties:
V i s c o s i t y , c p s : 170
Appearance: C l e a r L i q u i d
Formula 116
SOURCE: Witco Corp.: Suggested F o r m u l a t i o n s
Dishwashing Detergents 39
Liquid Automatic Dishwasher Deterqent
T h i s f o r m u l a t i o n f e a t u r e s Van Gel ES, magnesium aluminum
s i l i c a t e , as a s u s p e n d i n g a g e n t and r h e o l o g y m o d i f i e r . The
sodium h y p o c h l o r i t e f u n c t i o n s as a d i s i n f e c t a n t , c l e a n i n g a g e n t
and b l e a c h . Sodium m e t a s i l i c a t e a d j u s t s t h e f o r m u l a p H . The
p h o s p h a t e b l e n d p r o v i d e s d e t e r g e n c y and t h e s u r f a c t a n t s
contribute excellent r i n s a b i l i t y .
Inqredi ents: Wt%
A : Van Gel ES 4.00
D e i o n i z e d Water 53.00
B : T e t r a p o t a s s i u m P y r o p h o s p h a t e , t e c h n i c a l powder 10.00
Sodi um T r i p o l y p h o s p h a t e , t e c h n i c a l powder 20.00
C: Sodium M e t a a s i l i c a t e . Anhydrous 2.00
Sodium H y p o c h l o r i t e , 1 2 . 5 % s o l n . 8.00
D: Sodium X y l e n e s u l f o n a t e 2.25
Deceth-4-Phosphate 0.75
Procedure:
P r e h e a t t h e w a t e r t o 5 5 t o 60C. H y d r a t e t h e Van Gel ES
s l o w l y b y a d d i n g i t t o t h e a v a i l a b l e w a t e r u s i n g a h i g h speed
d i s p e r s e r . Preblend B i n g r e d i e n t s , Add B t o A s l o w l y w i t h
m i x i n g . M i x u n t i l u n i f o r m . Add C i n g r e d i e n t s i n t h e o r d e r
l i s t e d , mixing u n t i l dissolved. Continue mixing w h i l e c o o l i n g
r a p i d l y t o 25C. F i n a l l y , combine D i n g r e d i e n t s and add w h i l e
m i x i n g s l o w l y u n t i l smooth and u n i f o r m ( a v o i d i n c o r p o r a t i o n
of air).
C o n s i s t e n c y and pH:
Pumpable l i q u i d , V i s c o s i t y 1300-1800 c p s , B r o o k f i e l d Model
LVT, S p i n d l e 4 a t 60 rpm measured a t room t e m p e r a t u r e a f t e r
3 0 days a g i n g ; pH a p p r o x i m a t e l y 1 2 . 5 .
Suggested P a c k a g i n g : Squeeze b o t t l e o r pump.
SOURCE: R.T. V a n d e r b i l t Co., Inc.: F o r m u l a t i o n No. 438
40 Advanced Cleaning Product Formulations
Manual D i shwashi n q G e l
F u n c t i o n s & B e n e f i t s : C a r b o p o l EX-473:
* v i s c o s i t y m o d i f i e r f o r h i g h s u r f a c t a n t systems, independent
o f surfactant type
*provides high c l a r i t y across s u r f a c t a n t l e v e l
* i m p a r t s y i e l d v a l u e f o r s u s p e n s i o n o f , f o r i n s t a n c e , encap-
sulated actives
* a b i l i t y t o p o s t - t h i c k e n t r a d i t i o n a l s a l t - t h i c k e n e d systems
*easy-to-use, odorless, l i q u i d form
i n i r e d l ent : Wt%
DI w a t e r 37.50
C a r b o p o l EX-473 ( 3 0 % ) * 10.00
Sodium c i t r a t e 0.50
Sodium h y d r o x i d e ( 1 8 % ) 2.00
Ammonium l a u r y l s u l f a t e (30%)** 25.00
Sodium l a u r y l e t h e r s u l f a t e (30%)*** 25.00
* V i s c o s i t y modi f i e r : B F G o o d r i c h
* * A n i o n i c s u r f a c t a n t : Standapol A : Stepan Chemical
* * * A n i o n i c s u r f a c t a n t : S t a n d a p o l ES-3: S t e p a n C h e m i c a l
P h y s i c a l P r o p e r t i es :
B r o o k f i e l d RVT v i s c o s i t y - 2 0 rpm: 8 , 0 0 0 C P
P r o d u c t pH: 6 . 5 - 7 . 0
Product c l a r i t y : c l e a r
Procedure:
1 . U s i n g s l o w a g i t a t i o n ( 2 0 0 rpm) p r o v i d e d b y a L i g h - t n i n ' m i x e r
o r s i m i l a r v a r i a b l e speed u n - i t and an i m p e l l e r s u i t a b l e f o r
g e n e r a l m i x i n g and b l e n d i ng o p e r a t i o n s , add t h e C a r b o p o l
EX-473 r e s i n i n t o t h e D I w a t e r . M i x u n t i l u n i f o r m a n d
homogeneous.
2 . Add t h e sodium c i t r a t e . M i x u n t i l t h e sodium c i t r a t e i s
completely dissolved.
3 . A d j u s t t h e pH w i t h sodium h y d r o x i d e t o d e s i r e d pH.
4. Add t h e l a u r y l s u l f a t e and l a u r y l e t h e r s u l f a t e s u r f a c t a n t s
w i t h s l o w m i x i n g t o a v o i d e x c e s s i v e foam g e n e r a t i o n .
5 . Check pH, r e a d j u s t w i t h a d d i t i o n a l s o d i u m h y d r o x i d e i f
necessary.
6 . Add f r a g r a n c e and c o l o r , a s d e s i r e d .
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-130
Dishwashing Detergents 41
_ _ D i shwashi nq L i q u i d
Manual
F u n c t i o n s B B e n e f i t s : Carbopol EX-473:
* v i s c o s i t y m o d i f i e r f o r h i g h s u r f a c t a n t systems, i n d e p e n d e n t
o f surfactant type
*provides h i g h c l a r i t y across s u r f a c t a n t l e v e l
* i m p a r t s y i e l d v a l u e f o r s u s p e n s i o n o f , f o r i n s t a n c e , encap-
sulated actives
* a b i l i t y t o p o s t - t h i c k e n t r a d i t i o n a l s a l t - t h i c k e n e d systems
*easy-to-use, odorless, l i q u i d form
I n g r e d i en t . yt%
DI w a t e r 43.00
Carbopol EX-473 ( 3 0 % ) 5.50
Ammonium l a u r y l s u l f a t e (30%)* 25.00
Sodium l a u r y l e t h e r s u l f a t e ( 3 0 % ) * + 25.00
Sodium c i t r a t e 0.50
Sodium h y d r o x i d e (18%) I .oo
* A n i o n i c s u r f a c t a n t : S t a r i d a p o l A : Stepari Chemical
* * A n i o n i c s u r f a c t a n t : S t a n d a p o l ES-3: Stepan Chemical
Physical Properties:
B r o o k f i e l d R V T v i s c o s i t y - 2 0 rpm: 5 0 0 CP
Product pH: 6.5-7.0
Product c l a r i t y : Clear
Procedure:
1 . Using slow a g i t a t i o n (200 r p m ) provided by a L i g h t n i n ' Mixer
o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e f o r
g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , add t h e C a r b o p o l
E X - 4 7 3 r e s i n i n t o t h e D I w a t e r . M i x u n t i l u n i f o r m and
homogeneous.
2 . Add t h e l a u r y l s u l f a t e and l a u r y l e t h e r s u l f a t e s u r f a c t a n t s
w i t h s l o w m i x i n g t o a v o i d e x c e s s i v e foam g e n e r a t i o n .
3 . Add t h e sodium c i t r a t e , M i x u n t i l t h e sodium c i t i - a t e i s
completely dissolved.
4 . A d j u s t t h e p H w i t h sodium h y d r o x i d e .
5 . Add f r a g r a n c e and c o l o r , a s d e s i r e d .
SOURCE: BFGoodrich S p e c i a l t y C h e m i c a l s : DET-120
42 Advanced Cleaning Product Formulations
N o n - C h l o r i n a t e d M a c h i n e D i s h w a s h i n q Compound, Liquid
I n Q r e d ie n t s : \Mt%
Water, D . I . 79.5
Sodi um T r i p o l y p h o s p h a t e 2.0
Versene 2 2 0 , Powder 1 .o
Sodi um G1 u c o n a t e 1.o
Sodium M e t a s i l i c a t e , P e n t a h y d r a t e 7.0
C a u s t i c Soda 50% 8.5
P e t r o ULF L i q u i d 1 .o
81 e n d i ng P r o c e d u r e :
Add a l l components i n t h e o r d e r shown, m i x i n g w e l l between
a d d i t i ons.
F o r m u l a 109
C h l o r i n a t e d M a c h i n e D i shwashi n q Compound, Powder
Ingredients:
Sodi um C a r b o n a t e (Soda A s h ) , L i g h t D e n s i t y 30.0
Sodi um T r i p o l y p h o s p h a t e (STPP) , L i g h t D e n s i t y 25.0
DeSoni c LFD-97 1. o
Sodium M e t a s i l i c a t e , Anhydrous 30.0
C a u s t i c Soda Beads 10.0
CDB C l e a r o n 4.0
Blending Procedure:
Blend i n g r e d i e n t s i n t h e order l i s t e d , mixing thoroughly w i t h
each a d d i t i o n .
F o r m u l a 111
N o n - C h l o r i n a t e d M a c h i n e D i shwashi n g Compound. Powder
Inqredi ents: Wt%
Sodi um C a r b o n a t e (Soda A s h ) , L i g h t D e n s i t y 33.0
Sodium T r i p o l y p h o s p h a t e (STPP), L i g h t D e n s i t y 25.0
DeSoni c LFD-97 2.0
Sodium M e t a s i l i c a t e , Anhydrous 30.0
C a u s t i c Soda Beads 10.0
Blending Procedure:
Blend i n g r e d i e n t s i n t h e order l i s t e d , mixing thoroughly
w i t h each a d d i t i o n .
F o r m u l a 112
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Dishwashing Detergents 43
P r e m i um Hand D i shwashi ng D e t e r q e n t
Inqredients: Wt%
Water, D . I . 6.9
A1 p h a - S t e p MC-48 56.0
S t e o l CS-330 30.0
N i n o l 30-LL o r N i n o l 40-CO 5.6
Sodium C h l o r i d e 1.5
P r o p e r t i es :
Appearance: C l e a r y e l l o w l i q u i d
pH, as i s : 6 . 5 - 7 . 5
V i s c o s i t y @ 25 deg. C , c p s : 220
S o l i d s , % : 39-40
Density, l b s / g a l : 8 . 8
Freeze/thaw, 3 c y c l e s : Pass
C o l d s t o r a g e @ 4 deg. C . , 2 weeks: Pass
F l a s h p o i n t , deg. F: >200
M i x i n g Procedure:
CHarge w a t e r . Add MC-48 and CS-330 and m i x . Add 30-LL o r 40-CO
and m i x u n t i l homogeneous. S l o w l y add sodium c h l o r i d e t o t h i c k e n .
M i x u n t i l c l e a r . A d j u s t p H w i t h s u l f u r i c a c i d o r sodium h y d r o x i d e
as n e c e s s a r y .
Comment :
The s u r f a c t a n t s used i n t h i s f o r m u l a t i o n a r e d e r i v e d f r o m
o l e o c h e m i c a l r e s o u r c e s and a r e b i o d e g r a d a b l e .
SOURCE: Stepan C o . : F o r m u l a t i o n No. 173
D i s h Washina A q e n t s f o r Manual Use
Inqredi ents:
Water 79.0
Lumorol 4154 12.0
Z e t e s o l NL 6.0
Z u s o l a t 1008/85 1.o
Sodium c h l o r i d e approx. 2 . 0
F o r m u l a t i o n CT 02-01-04
m e d ien t s : Wt%
Water 76.5
Z e t e s o l 2056 20.0
Amphotensid B 4 2.0
Z u s o l a t 1008/85 1.o
P u r t o n CFD 0.5
F o r m u l a t i o n CT-02-01-05
SOURCE: Zschimmer & Schwarz GmbH & C o . : Suggested F o r m u l a t i o n s
5 General Purpose
.
44
General Purpose Cleaners 45
Abrasive Cleaner w i t h Bleach
Carbopol r e s i n s a r e used t o a c h i e v e a s t a b l e s u s p e n s i o n o f
t h e c a l c i u m carbonate a b r a s i v e o a r t i c l e s i n t h e presence o f
c h l o r i n e bleach
lnqredient : Wt%
DI[ Water 53.76
Carbopol 674 o r 691* 0.80
Good-Rite K-7058 (50%)** 2.00
m
Sodi u h y d r o x i d e (50%) 2.80
2 . 4 ~ sodium s i l i c a t e (52%) 2.50
Sodium h y p o c h l o r i t e (14%) 7.14
C a l c i urn c a r b o n a t e * * * 30.00
Sodium n - d e c y l d i p h e n y l o x i d e d i s u l f o n a t e (45% **** 1 .oo
*Suspension a i d : BFGoodrich
* * A n t i - r e d e p o s i t i o n : BFGoodrich
+ * + A b r a s i v e : W h i t e #8 ( G e o r g i a M a r b l e )
* * * * A n i o n i c s u r f a c t a n t : Dowfax 382 (Dow Chemi
Physi ea9 P r o p e r t i e s :
B r o o k f i e l d RVT v i s c o s i t y - 20 rpm: 3,960 c p
Product pH: 12-13
P r o d u c t c l a r i t y : Opaque
~ ~ ~ ~ ~ d ~ r ~
1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d by a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t -
a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous
2. Add t h e low m o l e c u l a r w e i g h t p o l y a c r y l a t e p o l y m e r f o l l o w e d
by t h e sodium h y d r o x i d e and sodium s i l i c a t e . M i x u n t i l
homogeneous.
3. Reduce a g i t a t i o n speed and add t h e sodium h y p o c h l o r i t e b l e a c h .
(The p r o d u c t w i l l d r o p i n v i s c o s i t y a t t h i s p o i n t . )
4. Add t h e c a l c i u m c a r b o n a t e and f i n a l l y t h e s u r f a c t a n t w i t h
c o n s t a n t a g i t a t i o n . M i x u n t i l homogeneous.
5. Add f r a g r a n c e , as d e s i r e d .
FGoedrich S p e c i a l t y Chemicals: DET-343
46 Advanced Cleaning Product Formulations
A b r a s i v e Cleaner W i t h o u t B1 each
Carbopol r e s i n s a r e used i n t h i s f o r m u l a t i o n t o a c h i e v e a
s t a b l e suspension o f t h e h i g h l o a d i n g o f c a l c i u m carbonate
abrasives .
Insredient: Wt%
D I Water 62.10
Ethanol 2.00
Carbopol 674 ( 1 ) 0.60
Sodium h y d r o x i d e (50%) 1 .00
Sodium b i c a r b o n a t e 1.20
Calcium carbonate ( 2 ) 30.00
C12-15 1in e a r a1 coho1 , 3 moles EO ( 3 ) 2.50
Coconut d i e t h a n o l ami de ( 4 ) 0.60
B r o o k f ie l d v i s c o s i t y (RVT-20 rpm) : 4,500 cps
P r o d u c t pH: 8-10
P r o d u c t c l a r i t y : Opaque
( 1 ) BFGoodr ich
( 2 ) G e o r g i a M a r b l e Co.: G e o r g i a M a r b l e W h i t e # 8
( 3 ) S h e l l Chemical: Neodol 25-3
( 4 ) Stepan Co.: N i n o l 11-CM
Procedure:
1 . Add t h e e t h a n o l t o t h e w a t e r - h o l d i n g back 10 p a r t s o f w a t e r
f o r s t e p #3.
2 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d by a L i g h t n i n ’
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r s c r e e n
t h e Carbopol r e s i n i n t o t h e D I w a t e r / e t h a n o l m i x t u r e . M i x t h e
s l u r r y for a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s
homogeneous.
3 . P r e p a r e a n e u t r a l i z i n g s o l u t i o n o f t h e 10 p a r t s o f w a t e r w i t h
t h e sodium h y d r o x i d e and sodium b i c a r b o n a t e . Add t h i s t o t h e
m i x t u r e formed above and m i x u n t i l homogeneous.
4 . Add t h e c a l c i u m c a r b o n a t e , a l c o h o l e t h o x y l a t e and coconut QEA.
M i x u n t i l homogeneous.
5 . Add f r a g r a n c e , as d e s i r e d .
Total Actives:
m
C a l c i u carbonate: 30.0
C12-15 l i n e a r a l c o h o l , 3 moles EO: 2.5
Coconut DEA: 0.6
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-340
General Purpose Cleaners 47
A l l Purpose C l e a n e r
Ingredients: Wei q h t %
Urea 2.00
Na4EOTA 2.00
Water 88.00
2990 Ammonia 1 .oo
C a l s o f t L-40 5.00
C a l o x y l a t e N-9 2.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n APC-001-01
A l l Purpose C l e a n e r
Ingredients: Wei q h t %
Na4EDTA 4.00
Water, Perfume 84.00
Dowanol DPnB 4.00
C a l s o f t L-40 8.00
Comments a b o u t t h i s f o r m u l a :
Compare t o M r . C l e a n , a t r a d e m a r k o f P r o c t o r & Gamble.
F o r m u l a t i o n APC-002-01
A l l Purpose C l e a n e r
Inqredi ent s : Wei q h t %
d - L i monene 40.00
Calamide C 4.00
Calamide C T W 4.00
Cal imu1 se PRS 10.00
Water 42.00
Comments a b o u t t h i s f o r m u l a :
1 . Add i n g r e d i e n t s f i r s t and m i x .
2 . Add w a t e r s l o w l y .
3 . M i x u n t i l homogeneous.
F o r m u l a t i o n APC-005-01
A l l Purpose C l e a n e r
Inqredi ents: Weight%
Water 85.00
Calamide C T
W 15.00
Comments a b o u t t h i s f o r m u l a :
Formula t h i c k e n s e f f e c t i v e l y .
F o r m u l a t i on APC-003-01
SOURCE: P i l o t Chemical C o . : Suggested F o r m u l a t i o n s
48 Advanced Cleaning Product Formulations
A l l Purpose C l e a n e r
Inqredients: Wei q h t %
Na4EDTA 5.00
Water 77.50
Calamide C 2.50
Calamide C T W 2.50
P i l o t SXS-40 2.50
Laurami ne O x i d e 10.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n APC-006-01
A l l Purpose C l e a n e r
Inqredients: Wei q h t %
Na4EDTA 5.00
Water 76.10
50% NaOH 0.80
Cal s o f t LAS-99 2.80
P i l o t SXS-40 5.30
Calamide C 5.00
Calamide C T W 5.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n APC-007-01
A l l Purpose C l e a n e r - No R i n s e
Inqredients: Weight%
Water 89.00
C a l f a x 1OL-45 3.00
Na4 EDTA 3.00
E t h y l e n e G l y c o l Monobutyl E t h e r 3.00
Calamide C T W 2.00
Comments a b o u t t h i s f o r m u l a :
Spray a s i s , t h e n w i p e w i t h a p a p e r t o w e l .
F o r m u l a t i o n APC-008-01
SOURCE: P i l o t Chemical Co.: Suggested F o r m u l a t i o n s
General Purpose Cleaners 49
A 1 1- P u r p o s e C 1 e a n e r
Composi t ion :
K e l z a n x a n t h a n gum 0.3
A1 ip a l CD-128 1.7
G a f a m i d e CDD 518 0.5
B u t y l C e l l o s o l ve 3.5
S o d i urn M e t a s i 1 ic a t e 1.7
T r i s o d i urn P h o s p h a t e 1.o
Water, Perfume 91.3
Procedure:
P r e p a r e w a t e r s o l u t i o n o f K e l z a n x a n t h a n gum b y a d d i n g t h e
powder s l o w l y t o t h e s i d e o f t h e v o r t e x w i t h c o n s t a n t a g i t a t i o n .
Add o t h e r i n g r e d i e n t s as i n d i c a t e d . F o r a e r o s o l u s e , c h a r g e w i t h
a p p r o x i m a t e l y 85 p e r c e n t c o n c e n t r a t i o n a n d 15 p e r c e n t G e n e t r o n
12.
A
-ll-Purpose D i s i n f e c t a n t Cleaner
Composi ti= Q
K e l z a n x a n t h a n gum 0.5
Makon 1 0 10.0
Sodium T r i p o l y p h o s p h a t e 3.0
V e r s e n e 100 3.0
Hyarnine 1 O X 1.o
Water 82.5
Procedure:
P r e p a r e w a t e r s o l u t i o n o f K e l z a n x a n t h a n gum b y a d d i n g t h e
powder s l o w l y t o t h e s i d e o f t h e v o r t e x w i t h c o n s t a n t a g i t a t i o n .
Add o t h e r i n g r e d i e n t s a s i n d i c a t e d . F o r a e r o s o l u s e , c h a r g e w i t h
a p p r o x i m a t e l y 85 p e r c e n t c o n c e n t r a t i o n and 15 p e r c e n t G e n e t r o n
12.
SOURCE: M o n s a n t o P e r f o r m a n c e M a t e r i a l s : K e l z a n S u g g e s t e d
Formulations
A l l Purpose C l e a n e r
l n q r e d i en& Wt%
R h o d a t e r g e SMC 10
STPP 2
Water 88
SOURCE: Rhone-Poulenc Surfactants & Specialties: Suggested
Formulations
50 Advanced Cleaning Product Formulations
A l l Purpose C l e a n e r w/Amide/Phosphate Ester
Innredi ents: Wt%
W a t e r , D.I. 83.0
Tetrapotassium Pyrophosphate 5.0
Varami de A-1 0 10.0
Emphos 5AP 2.0
81 e n d i ng P r o c e d u r e :
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .
Typical Properties:
V i s c o s i t y , c p s : 145
S o l i d s : 17.0%
pH: 8 . 8
Formula 514
A l l Purpose C l e a n e r
Ingredients: wto/,
Water 56.0
W i t c o n a t e 1 2 6 0 S1 u r r y 38.5
Witcamide 6445 5.5
Blending Procedure:
B1 end i n g r e d i e n t s i n t h e o r d e r 1 is t e d .
Typical Properties:
V i s c o s i t y , c p s : 670
Sol i d s : 33.0%
pH, as i s : 9 . 2
Formula 520
A1 1 Purpose C l e a n e r
Ingredients: W S
Water 90.0
Sodi um T r i p o l y p h o s p h a t e 2.0
C a u s t i c Soda, 50% 0.5
W i t c o 12988 2.0
W i t c a m i de 6 4 4 5 5.0
Perfume, Dye q.s.
Blending Procedure:
Blend i n g r e d i e n t s i n order l i s t e d .
T y p i c a l P r o p e r t ie s :
Speci f ic G r a v i t y : 1 . 0 2 0 6
Wt./Gal. l b s . : 8 . 5
pH, as i s : 9 . 1 2
V i s c o s i t y , c p s : 107
Color: Beige
Use D i l u t i o n : 1 - 2 o z . / G a l .
Formula 535
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
General Purpose Cleaners 51
A l l Purpose C l e a n e r C o n c e n t r e
(Phosphate, - L i q u i d , Foam)
S o i 1 - G r e a s e and o i 1
Surface-Paint, polymeric, metal
A p p l i c a t i o n Method-Spray
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composi t i n o : Wt%
Water 78.1
M e t s o Beads 2048 2.4
TKPP ( 6 0 % ) 3.0
*Phosphate E s t e r 3.0
* * D i p r o p y l e n e G l y c o l Monomethyl E t h e r 6.0
* * * O c t y l p h e n o x y P o l y e t h o x y e t h a n o l , 9-10 M o l e s E O 5.0
****Octylphenoxy P o l y e t h o x y e t h a n o l , 5 M o l e s EO 2.5
Use D i l u t i o n : Normal D u t y - 1 . 5 % bw ( 2 o z / g a l l o n )
Heavy D u t y - 2 . 5 % b w ( 3 . 3 o z / g a l 1on)
Tough D u t y - a s s u p p l i e d
* Rhone-Poulenc R h o d a f a c RE-610
**( Dow, A r c 0 C h e m i c a l
*** Rhone-Poulenc I g e p a l CA-630
**** Rhone-Poulenc I g e p a l CA-520
A l l Purpose C o n c e n t r a t e
(Phosphate, Liquid1
S o i 1 - G r e a s e and o i 1
Surface-Paint, polymeric, metal
A p p l i c a t i o n Method-Wipe o r b r u s h
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composi t i on : wto/,
Water 78.75
M e t s o Beads 2048 1 .oo
TKPP 3.00
Sodium X y l e n e S u l f o n a t e , 40% 3.50
*Ethylene Glycol n-Butyl Ether 6.00
Pine O i l 0.25
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl3, 6 . 5 M o l e s EO) 5.00
* * * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl5, 3 M o l e s EO) 2.50
Use D i 1u t i o n : 1 . 5 - 3 . 0 % bw ( 2 - 4 o z / g a l l o n )
* Dow C h e m i c a l , U n i o n C a r b i d e
*l Rhone-Poul enc R h o d a s u r f LA-7
*S* Rhone-Poulenc R h o d a s u r f A-24
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
52 Advanced Cleaning Product Formulations
Calcium Carbonate A b r a s i v e Cleaner W i t h o u t Bleach
Carbopol r e s i n s a r e used i n t h i s f o r m u l a t i o n t o a c h i e v e a
s t a b l e suspension o f t h e h i g h l o a d i n g o f c a l c i u m c a r b o n a t e
abrasives .
I n q r e d ie n t :
D I Water 62.10
Carbopol ETD 2623 ( 1 ) 0.25
Sodium h y d r o x i d e (50%) 0.20
C12-I5 l i n e a r a l c o h o l , 3 moles EO ( 2 ) 1.50
Sodium a l k y l benzene s u l f o n a t e ( 3 ) 0.50
Calcium carbonate ( 4 ) 30.00
P h y s i c a l P r o p e r t ies :
B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 7,500 c p
P r o d u c t pH: 8-10
P r o d u c t C l a r i t y : Opaque
Raw M a t e r i a l S u p p l i e r s :
( 1 ) BFGoodrich
( 2 ) S h e l l Chemical Co.: Neodol 25-3
( 3 ) Stepan Co. : Nacconol SQG
( 4 ) Georgia Marble C o . : Georgia Marble White #8
Procedure:
1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t -
a b l e f o r g e n e r a l m i x i ng and b l endi ng o p e r a t i o n s , d i s p e r s e
o r s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e
s l u r r y f o r a p p r o x i m a t e l y 15 m i n u t e s or u n t i l t h e s l u r r y
i s homogeneous.
2. Add t h e sodium h y d r o x i d e t o r e a c h t a r g e t pli. The p r o d u c t
w i l l become v e r y t h i c k a t t h i s p o i n t .
3 . Add t h e a l c o h o l e t h o x y l a t e and a l k y l b e n z e n e s u l f o n a t e s u r f -
a c t a n t s . M i x u n t i l homogeneous.
4 . Add t h e c a l c i u m c a r b o n a t e . M i x u n t i l homogeneous.
5. Add f r a g r a n c e , as d e s i r e d .
Total Actives:
Calcium carbonate: 30.00
C12-15 l i n e a r a l c o h o l , 3 moles EO: 1.50
Sodium a1 k y l b e n z e n e s u l f o n a t e : 0.50
SOURCE: BFGoodrich S p e c i a l t y Chemicals: BET-341
General Purpose Cleaners 53
C i t r i c A c i d Cleaner
F u n c t i a n e 8 B e n e f i t s : Carbopol ETD 2623:
* P r o v i d e s l o w p H t h i c k e n i n g v i a hydrogen b o n d i n g w i t h s u r f -
actant
* I m p a r t s y i e l d v a l u e f o r suspension o f a b r a s i v e p a r t i c l e s
*Provides v e r t i c a l c l i n g f o r increased s u r f a c e c o n t a c t t i m e
*Shear t h i n n i n g r h e o l o g y f o r easy d i s p e n s i n g t h r o u g h t r i g g e r
sprayer o r nozzle
* E a s y - t o - d i s p e r s e r e s i n f o r improved and e a s i e r f u l l - s c a l e
processing
Inqiredi e n t : Wt%
DI Water 78.40
Carbopo? ETD 2623 R e s i n * 0.10
C12-15 l i n e a r a l c o h o l , 3 moles EO** 5.00
C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO*** 2.50
Alkylbenzene s u l f o n i c acid**** 2.00
C i t r i c A c i d (50%) 12.00
*V iscos ity modi f ie r : BFGoodr ic h
s W o n i o n i c s u r f a c t a n t : Neodol 25-3: She1 1 Chemical
>N**Nonionic s u r f a c t a n t : Neodol 23-6.5: S h e l l Chemical
* * r * A n i o n i c s u r f a c t a n t : B i o s o f t 5-100: Stepan
P h y s i c a l P r o p e r t iee: S t o r a g e Temperature
25C
-. 5oc
B r o o k f i e l d RVT v i s c o s i t y - 2 0 rpm:
Initial: 50cP 50cP
Age-Up V i s c o s i t y : Week 2 : 170cP 400cP
Week 4 : 250cP 600cP
Week 6: 350cP 400cP
P r o d u c t pH: 1 . 4
Product c l a r i t y : T r a n s l u c e n t
Procedurw:
4. U s i n g J m a r i n e b l a d e p r o p e l l e r and r a p i d a g i t a t i o n (800 rpm)
p r o v i d e d by a L i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t ,
s p r i n k l e t h e Carbopol ETD 2623 r e s i n i n t o t h e v o r t e x . A l l o w
t o h y d r a t e f o r 15-20 m i n u t e s o r u n t i l no lumps a r e p r e s e n t .
Warming t h e d e i o n i z e d w a t e r t o 30C w i l l decrease t h e h y d r a t i o n
t i m e and i m p r o v e t h e d i s p e r s i b i l i t y o f t h e Carbopol powder.
2. M i x t h e Neodol 25-3 and Neodol 2 3 - 6 . 5 ( o r warm s l i g h t l y i f
needed) t o e n s u r e homogeneity. A d d w i t h moderate m i x i n g (300
r p m ) . A l l o w t o mix u n t i l u n i f o r m and smooth.
3. Add t h e B i o s o f t S-100 w i t h moderate (300 rpm) m i x i n g and
a l l o w t o m i x u n t i l u n i f o r m and smooth.
4. ~ Y
S ~ O W add t h e C i t r i c A c i d w i t h s l o w m i x i n g (200 r p m ) . M i x
u n t i l smooth and u n i f o r m .
5. Add f r a g r a n c e and c o l o r , a s d e s i r e d .
S O U R C E : B F G o o d r i c k S p e c i a l t y ChemicaJs: DET-352
54 Advanced Cleaning Product Formulations
G e n e r a l P u r p o s e C1 e a n e r
(Consumer Low Alkaline, Non-Phasphate Powder)
S o i l - F o o d ( f a t and p r o t e i n ) , p e t r o l e u m o i l and g r e a s e , c l a y
and p a r t i c u l a t e s o i l
Surface-Hard surface, i . e . , metal, p l a s t i c , ceramic, concrete,
and a s p h a l t
A p p l i c a t i on Method-Wi p e o r B r u s h
Manufacture-Dry blend/Agglomeration
Composi t i o n : Wt%
Sodi um C a r b o n a t e ( 1 i g h t d e n s i t y ) 30.0
* B r i t e s i 1 C20 Hydrous P o l y s i 1 i c a t e 10.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-Cl5; 9 M o l e s EO) 15.0
V a l f o r 100 Z e o l i t e A 30.0
* * * A c u s o l 445ND Sodium P o l y a c r y l a t e (92% S o l i d s ) 0.5
Sodi um S u l f a t e 14.5
Use L e v e l : 1-4 o z / g a l l o n
* 2 . 0 w e i g h t r a t i o s i l i c a t e powder, 82.5% s o l i d s
** Rhone-Poulenc R h o d a s u r f LA-9
*** Rohm & Haas
G e n e r a l Purpose C l e a n e r
(Consumer H i g h A 1 k a l ine, Non-Phosphated Powder1
S o i -Food ( f a t and p r o t e i n ) , p e t r o l e u m o i l and g r e a s e , c l a y
and p a r t i c u l a t e s o i l
Sur ace-Hard s u r f a c e , i . e . , m e t a l , p l a s t i c , c e r a m i c , c o n c r e t e ,
and a s p h a l t
App i c a t i o n Method-Wipe o r b r u s h
Manufacture-Dry blend/Agglomeration
Composi t i o n 1 Wt%
Sodium S u l f a t e 14.5
Sodi um C a r b o n a t e ( 1 ig h t d e n s i t y ) 30.0
* L i q u i d N o n i o n i c S u r f a c t a n t ( C 1 2 - C l 5 ; 9 M o l e s EO) 15.0
V a l f o r 100 Z e o l i t e A 30.0
M e t s o Beads 2048 10.0
* * A c u s o l 445ND Sodium P o l y a c r y l a t e (92% S o l i d s ) 0.5
Use L e v e l : 1-4 o z / g a l l o n
* Rhone-Poulenc R h o d a s u r f LA-9
** Rohm & Haas
SOURCE: PQ Corp. : D e t e r g e n t F o r m u l a t i o n Guide
General Purpose Cleaners 55
G e n e r a l P u r p o s e S p r a y & Wipe C l e a n e r
Carbopol r e s i n s a r e used t o i n c r e a s e t h e y i e l d v a l u e r e s u l t i n g
i n v e r t i c a l c l i n g when s p r a y e d on a v e r t i c a l s u r f a c e . T h i s
"no-drip" action w i l l increase the contact time o f t h e detergent
on t h e s o i l e d s u r f a c e a s w e l l a s enhance consumer c o n v e n i e n c e .
Ingredient: wto/,
D I Water 90.70
C a r b o p o l ETD 2 6 9 1 ( 1 ) 0.20
EDTA ( t e t r a s o d i u m s a l t ) 2.00
Sodium m e t a s i l i c a t e , a n h y d r o u s 2.30
P r o p y l ene g l y c o l m e t h y l e t h e r ( 2 ) 3.00
C12-15 l i n e a r a l c o h o l , 7 m o l e s EO ( 3 ) 1.50
B r o o k f i e l d v i s c o s i t y (RVT-20 rpm) : 120 c p s
P r o d u c t p H : 12-13
P r o d u c t C l a r i t y : C l e a r t o hazy
( 1 ) BFGoodri c h
( 2 ) Dow C h e m i c a l : Dowanol DPM
( 3 ) S h e l l C h e m i c a l : Neodol 25-7
Procedure:
1 . U s i n g m o d e r a t e a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d b y a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
screen t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 15 m i n u t e s or u n t i l t h e s l u r r y i s homogen-
eous.
2 . Under s l i g h t a g i t a t i o n , add t h e EDTA and M e t a s i l i c a t e .
3 . C o n t i n u e a g i t a t i o n and add t h e g l y c o l e t h e r and a l c o h o l
e t h o x y 1a t e .
4 . Add c o l o r and f r a g r a n c e , a s d e s i r e d .
T o t a l Actives:
Propylene g l y c o l methyl e t h e r : 3.0
C 1 2 - I 5 l i n e a r a l c o h o l , 7 m o l e s EO: 1.5
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-310
56 Advanced Cleaning Product Formulations
G e n e r a l P u r p o s e Spray & Wipe
Ingredients: Wt%
Water, D.I. 79.0
Sodi um C i t r a t e 2.0
A1 p h a - S t e p MC-48 10.0
S t e p a n o l WA-Extra 7.0
N i n o l 11-CM 2.0
M i x i n g Procedure:
Charge w a t e r and s u r f a c t a n t s and m i x . Add sodium c i t r a t e and
m i x u n t i 1 homogeneous.
T y p i c a l P r o p e r t i es :
Appearance: C l e a r c o l o r l e s s l i q u i d
pH, as i s : 9 . 4
3
V i s c o s i t y I 2 5 deg. C : V e r y t h i n
S o l i d s , %: 1 0 . 0
Density, l b s / g a l : 8.54
C o l d s t o r a g e @ 4 d e g . C, 1 d a y : p a s s
F r e e z e / t h a w , 3 c y c l e s : pass
Performance:
Gardner S t r a i g h t L i n e W a s h a b i l i t y T e s t :
Commercial P r o d u c t - 66% s o i l removed f r o m t i l e s
Above f o r m u l a t i o n - 82%' s o i l removed f r o m t i l e s
Above f o r m u l a t i o n p e r f o r m s b e t t e r t h a n c o m m e r c i a l
product.
Use I n s t r u c t i o n s : Use as i s
Comment :
The s u r f a c t a n t s used i n t h i s f o r m u l a t i o n a r e d e r i v e d f r o m
o l e o c h e m i c a l r e s o u r c e s and a r e b i o d e g r a d a b l e .
SOURCE: Stepan Co.: Suggested F o r m u l a t i o n No. 575
A1 1 -Purpose C1 e a n e r
Ingredients:
Water 82.0
Z e t e s o l 2056 14.0
Z u s o l a t 1008/85 4.0
SOURCE: Zschimmer & Schwarz GmbH & C o . : F o r m u l a t i o n CT 02-04-02
General Purpose Cleaners 57
H y p o c h l o r it e V e r t i c a l S u r f a c e C l e a n e r
M o n a t r o p e 1250 i s a h y p o c h l o r i t e s t a b l e s u r f a c t a n t t h a t
c o n t r i b u t e s t o w e t t i n g and f o a m i n g c h a r a c t e r i s t i c s .
In q r e d ie n t s : Wt%
M o n a t r o p e 1250 2.0
Sodium C14-17 A l k y l Sec S u l f o n a t e (60%) 2.0
Laurami ne O x i d e (30%) 10.0
P o t a s s i u m H y d r o x i d e (45%) 15.0
Sodi um T r i p o l y p h o s p h t e 5.0
Sodium H y p o c h l o r i t e 5 . 2 5 % ) 66.0
Procedure:
Add i n g r e d i e n t s w t h a g i t a t i o n .
Typical Properties:
Appearance: C l e a r y e l l o w l i q u i d
p H : 13
Recommended Use D i l u t i o n : 1:lO w i t h w a t e r
Formul a t i on F-783
Pump S p r a v A l l Purpose C l e a n e r
A f a s t a c t i o n s p r a y and w i p e f o r m u l a t i o n . Surfaces w i l l dry
streak-f ree.
Inqredients: Wt%
Water 94.0
M o n a t e r g e 779 (DEA-Laureth S u l f a t e ) 3.0
Propylene Glycol B u t y l Ether 3.0
Procedure:
Add i n g r e d i e n t s i n t h e o r d e r l i s t e d w i t h a g i t a t i o n . Package.
Typical Properties:
Appearance: C l e a r l i q u i d
Recommended Use D i 1 u t i o n : As i s
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
58 Advanced Cleaning Product Formulations
L i q u i d C 1 eanser w i t R B1 each
I n t h i s f o r m u l a Van Gel B i s used t o suspend t h e a b r a s i v e and
t o a d j u s t t h e v i s c o s i t y . The sodium c a r b o n a t e b u f f e r h e l p s
m a i n t a i n a pH o f a b o u t 1 1 , n e c e s s a r y f o r t h e s t a b i l i t y o f t h e
h y p o c h l o r i t e . T h i s l i q u i d c l e a n s e r o f f e r s t h e advantage o f m i l d -
ness i n u s e and g r e a t e r ease and e f f e c t i v e n e s s on v e r t i c a l
s u r f a c e s a s compared t o powders.
Ingredients:
A : Van Gel B 2.25
Water 62.25
6 : Diatomaceous E a r t h '10.00
Sodium c a r b o n a t e 4.50
Sodium h y p o c h l o r i t e , 5 . 2 5 % s o l n . 20.00
Sodium L a u r y l S u l f a t e , 29% s o l n . 1 .oo
Procedure:
S l o w l y add Van Gel B t o t h e w a t e r w h i l e a g i t a t i n g a t maximum
a v a i l a b l e s h e a r . C o n t i n u e m i x i n g u n t i l smooth. Add r e m a i n i n g
i n g r e d i e n t s i n o r d e r , m i x i n g w e l l a f t e r each a d d i t i o n .
Consistency: Medium v i s c o s i t y liquid.
Suggested Packaging: P l a s t i c squeeze b o t t l e .
SOURCE: R . T . V a n d e r b i l t Co., Inc.: F o r m u l a t i o n N o . 391
A l l Purpose C l e a n e r
Clear, liquid
Ingredients: Wt%
A : H o s t a p u r SAS 6 0 10.0-15.0
Genapol ZRO 1 iq u i d 0.0- 4.0
Genapol UD-080 1.0- 3 . 0
B : Water ad 1 0 0 . 0
Perfume 0.2
Preservative 0.1
Dye q.s.
Manufacturing:
Add one a f t e r a n o t h e r , t h e components o f B t o A .
Modern s t a n d a r d f o r m u l a t i o n s a r e based on a l k a n s u l p h o n a t e s and
noni oni c s .
E t h e r s u l p h a t e s a r e used i n r a r e cases.
Phosphates, sodium c a r b o n a t e and ammonia a r e n o t common any
1onger .
The above g u i d e f o r m u l a t i o n c o v e r s t h e common european p r o d u c t s .
SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n
General Purpose Cleaners 59
Pine O i l Cleaner Concentrate
Ingredients: g
Pine o i l 20.0
N i n o l 11-CM 9.0
Makon 12 5.0
Ammonyx LO 0.5
B i o - S o f t S-1 0 0 2.0
Isopropanol 10.0
Water, D . I . 53.5
M i x i ng Procedure:
Combine p i n e o i l , s u r f a c t a n t s and I P A . M i x u n t i l c l e a r . Add
water s l o w l y w h i l e under a g i t a t i o n . Mix u n t i l c l e a r .
Properties:
Appearance: C l e a r y e l l o w l i q u i d
Odor: P i n e
V i s c o s i t y @ 25C, c p s : 50
pH ( a s i s ) : 8 . 1
D e n s i t y 1b s / g a l : 8 . 0 6
Freeze/Thaw ( 3 c y c l e s ) : Pass
50 C oven ( 1 week): Pass
Use I n s t r u c t i o n s : D i l u t e 1-2 o z s i n t o one g a l l o n
Performance:
Gardner S t r a i g h t L i n e W a s h a b i l i t y T e s t :
Above f o r m u l a t i o n : 73.0% s o i l removed f r o m t i l e s
Commercial f o r m u l a t i o n : 5 5 . 5 % s o i l removed f r o m t i l e s
SOURCE: S t e p a n Co.: F o r m u l a t i o n No. 208
D i s i n f e c t i n g Cleaner, Alkaline
Ingredients: Wt%
Water 57.5
C i t r i c acid 2.0
Z u s o l a t 1008/85 3.5
Lumorol 4192 5.0
Trilon A liquid 7.0
Lonzabac-1230 25.0
Ingredients: Wt%
Water 69.0
Disodium t e t r a b o r a t e decahydrate 0.5
Sodi um b i c a r b o n a t e 1.0
Burdac-114 20.0
Z u s o l a t '1008/85 9.5
Ingredients: g
Water 57.5
Trilon A liquid 7.0
Citric acid 2.0
S u l f e t a l 4069 5.0
Z u s o l a t 1008/85 3.5
Lonrabac-1230 25.0
SOURCE: Zschimmer & Schwarz GmbH & Co.: F o r m u l a t i o n s CT 06-09-01,
CT 06-09-02, CT 06-09-03
60 Advanced Cleaning Product Formulatiorrs
Sodi urn B i c a r b o n a t e A b r a s i v e C l e a n e r W i t h o u t B l e a c h
Carbopol r e s i n s a r e used i n t h i s f o r m u l a t i o n t o a c h i e v e a
s t a b l e s u s p e n s i o n o f t h e h i g h l o a d i n g o r sodium b i c a r b o n a t e
abrasives.
-g r e d i e n t :
In wtsl,
D I Water 44.25
C a r b o p o l ETD 2691 ( 1 ) 0.50
A l k y l benzene s u l f o n i c a c i d ( 2 ) 0.75
C12-13 l i n e a r a l c o h o l , 6 . 5 m o l e s € 0 ( 3 ) 2.50
Sodium h y d r o x i d e ( 5 0 % ) 2.00
Sodium b i c a r b o n a t e ( 4 ) :
Grade 1 : 20.00
Grade 5 : 30.00
Physical Properties:
B r o o k f i e l d V i s c o s i t y (RVT-20 rprn): 6,000 c p
Product pH: 8.50
P r o d u c t C l a r i t y : Opaque
Raw M a t e r i a l S u p p l i e r s :
( 1 ) BFGoodrich
( 2 ) Stepan Co.: B i o s o f t 5-100
( 3 ) S h e l l C h e m i c a l C o . : Neodol 2 3 - 6 . 5
( 4 ) Church & Dwight
Procedure:
1 . U s i n g moderate a g i t a t i o n ( 8 0 0 r p m ) p r o v i d e d by a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
screen t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 1 5 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous.
2 . Add t h e a l k y l b e n z e n e s u l f o n i c a c i d f o l l o w e d b y t h e a l c o h o l
e t h o x y l a t e . M i x u n t i l homogeneous.
3 . Add t h e s o d i u m h y d r o x i d e . M i x u n t i l homogeneous. A d j u s t pH
t o 8.50 p r i o r t o t h e next step.
4 . W i t h m i n i m a l a g i t a t i o n , s l o w l y add t h e s o d i u m b i c a r b o n a t e .
M i x u n t i l smooth, homogeneous, and f r e e o f b i c a r b o n a t e l u m p s .
Re-check p H and a d j u s t , i f n e c e s s a r y .
5 . Add c o l o r a n d f r a g r a n c e , a s d e s i r e d .
T o t a l A c t iv e s :
S o d i um b i c a r b o n a t e : 50.00
C12-13 l i n e a r a l c o h o l , 6 . 5 m o l e s EO: 2.50
Sodium a1 k y l benzene s u l f o n a t e : 0.90
SOURCE: B F G o o d r i c h S p e c i a l t y C h e m i c a l s : DET-342
leaners/Polishes
61
62 Advanced Cleaning Product Formulations
A n t i -Foggi ng , A n t i -Stat ic G l a s s C l eaner
I gredients :
n MIBo/o
Water 90.0
Isopropyl Alcohol 9.0
Adogen 66 0.I
Varox 365 0.5
Emcol 4500 0.4
Blending Instructions:
Combine i n g r e d i e n t s i n t h e o r d e r shown and m i x t h o r o u g h l y .
I f p r o d u c t i s hazy, a d d i t i o n a l I s o p r o p y l Alcohol can be used
t o c l a r i f y t h e s o l u t i o n . G e n t l y h e a t i n g can b e used t o
f a c i l i t a t e m i x i n g o f t h e Emcol 4500.
Use I n s t r u c t i o n s :
A p p l y f i n i s h e d p r o d u c t t o a t o w e l l e t e (Kimwipe, e t c . ) and
wipe onto t h e glass. A l l o w t o d r y .
Product I n f o r m a t i o n :
Product: Benefit :
Varox 365 W e t t i n g a g e n t , d e g r e a s e r and d e t e r g e n t
Adogen 66 A n t i - s t a t i c agent
Emcol 4500 W e t t i n g a g e n t , c o u p l e r and d e t e r g e n t
T h i s f o r m u l a t i o n p r e s e n t s a t h i n b a r r i e r between t h e w a t e r
v a p o r ( f o g , steam, e t c . ) and t h e g l a s s w h i c h w i l l p r e v e n t
f o g g i n g . The a b i l i t y t o l o w e r t h e s u r f a c e t e n s i o n o f t h e w a t e r
prevents t h e c l i n g i n g o f i n d i v i d u a l water d r o p l e t s t o the glass;
t h e r e f o r e l i g h t i s n o t s c a t t e r e d as much a s i t i s when p a s s i n g
through i n d i v i d u a l d r o p l e t s .
F o r m u l a 708
Glass Cleaner, Ready t o Use
Ingredients:
Water, D . I . 84.9
P e t r o BAF L i q u i d 0.1
Isopropanol 10.0
E t h y l e n e G l y c o l Monobutyl E t h e r 5.0
Dye q.s.
B l e n d i ng P r o c e d u r e : B l e n d i n g r e d i e n t s i n t h e o r d e r 1is t e d .
F o r m u l a 705
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Glass CleanerslPolishes 63
G l a s s C l e a n e r C o n c e n t r a t e (Non-Ammoniated)
Ingredients: K%
W a t e r , D . I. 7.5
I s o p r o p a n o l , 99% 82.0
P e t r o LBA Powder 1.o
Monoethanol ami ne 0.5
Perfume, Dye q. s
B l e n d i n g Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d .
T h i s c o n c e n t r a t e s h o u l d be m i x e d w i t h n i n e p a r t s o f w a t e r
t o one p a r t c l e a n e r t o b e r e a d y t o u s e . T h i s p r o d u c t r e q u i r e s
a red label.
F o r m u l a 702
Glass Cleaner Concentrate
Inqredi ents: Wt%
Water, D . I . 77.0
P e t r o BAF L i q u i d 20.0
DeSonic 5 N 1.o
Ammonia, 29% 2.0
Dye q.s.
B l e n d i n g Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d .
Use D i l u t i o n : 1 p a r t c o n c e n t r a t e t o 50 p a r t s w a t e r .
F o r m u l a 703
Amrnoniated G l a s s C l e a n e r
m r e d ients: Wt%
Water 94.0
W i t c o l a t e 231 0 3.0
B u t y l C e l l o s o l ve 2.0
Aqua Ammonia, 26 B e ' 2.0
B l e n d i n g Procedure: Blend i n g r e d i e n t s i n t h e order l i s t e d .
F o r m u l a 704
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
64 Advanced Cleaning Product Formulations
G l a s s and Window C l e a n e r
Carbopol r e s i n s a r e used t o i n c r e a s e t h e y i e l d v a l u e r e s u l t i n g
i n v e r t i c a l c l i n g when s p r a y e d on a v e r t i c a l s u r f a c e . T h j s
"no-drip" a c t i o n w i l l increase the contact time o f t h e detergent
on t h e s o i l e d s u r f a c e as w e l l as enhance consumer c o n v e n i e n c e .
Inaredient: wel
D I Water 92 * 45
Carbopol ETD 2623 (4.10
Isopropanol 5.00
Ammonium h y d r o x i d e 0.20
A l k y l b e n z e n e s u l f o n i c a c i d (97%) ( 2 ) 0.25
Propylene g l y c o l methyl e t h e r (3) 2.00
Physical Properties:
B r o o k f ie l d V i s c o s i t y (RVT-20 rpm) : 200 c p
P r o d u c t pH: 9 . 5 - 1 0 . 0
Product C l a r i t y : Clear
Raw M a t e r i a1 Suppl ie r s :
( 1 ) BFGoodrich
( 2 ) Stepan Chemical: B i o s o f t 5-100
( 3 ) Dow Chemical: Dowanol PM
Procedure:
1 . U s i n g moderate a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d by a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous.
2 . Add t h e i s o p r o p a n o l .
3 . Add t h e ammonium h y d r o x i d e . M i x u n t i l homogeneous.
4 . Add t h e s u l f o n i c a c i d and g l y c o l e t h e r w i t h m i n i m a l a g i t a t i o n
t o a v o i d e x c e s s i v e foaming.
5 . Add a d d i t i o n a l ammonium h y d r o x i d e , i f necessary, t o r e a c h the
t a r g e t pH r a n g e .
6 . Add c o l o r and f r a g r a n c e , as d e s i r e d .
Total Actives:
Ammonium a l k y l b e n z e n e s u l f o n a t e : 0 . 3 0
Propylene g l y c o l methyl e t h e r : 2.00
Isopropanol: 5.00
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-300
Glass CleanerslPolishes 65
H o u s e h o l d Window C l e a n e r
Inqredients: Wt%
Water. D . I . 89.3
Isopropanol 10.0
Varox 365 0.7
Methylene Blue q.s.
Blending Procedure:
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .
T y p i c a l P r o p e r t ies:
V i s c o s i t y , cps: 4
S o l i d s : 0.2%
pH: 7 . 4
F o r m u l a 706
Bremi u m Household W i ndow C1 e a n e r
Ingredi ents: Q
Water, D . I . 89.4
Isopropanol 10.0
Varox 1770 0.6
Methylene Blue q. s
81 e n d i ng P r o c e d u r e :
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .
Typical Properties :
V i s c o s i t y , cps: 4
S o l i d s : 0.23%
pH: 6 . 2
F o r m u l a 707
GI ass @1e a n e r
Ingredients: Wt%
Water. D . I . q.s.
Isopropanol 6.0
Dowanol EB 4.0
R e w o t e r i c AM V 0.85
81 endi ng P r o c e d u r e :
B l e n d i n g r e d i e n t s i n t h e o r d e r shown, mixing thoroughly bet-
ween each a d d i t i o n .
F o r m u l a 709
SQURCE: W i t c o G o r p . : Suggested F o r m u l a t i o n s
66 Advanced Cleaning Product Formulations
W i n d o w s / G l ass
Gl-ass Cl g a n g r C C o n c e n t r a t e )
Ingredients: We i s h t YO
Water 10.04
Ethylene G l y c o l Monobutyl Ether 21.34
Isopropyl Alcohol 53.30
Ammonia, 2 9 . 4 % 2.35
C a l foam SLS-30 5.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d
F o r m u l a t i o n WIN-001-01
W i n-dzhield Washer C c n c e n t r a t e
Ingredients: Weigh_%
Water 47.66
Isopropyl Alcohol 47.30
C a l s u d s 81 5.10
Comments a b o u t t h i s f o r m u l a :
Use 4 0 2 . o f t h e c o n c e n t r a t e p e r g a l l o n .
F o r m u l a t i o n WIN-002-01
W i ndshjeld-pWashec C o n c e n t y a t e (Low VOC)
I r e d i-en t s :
ng W i gh ts/,
e
Water 62.20
P r o p y l ene G1 y c o l 33.80
Calsuds 81 4.02
Comments a b o u t t h i s f o r m u l a
Use l e v e l : 2-4 o z p e r g a l l o n .
F o r m u l a t i o n WIN-003-01
SOURCE: P i l o t C h e m i c a l C o . : Suggested F o r m u l a t i o n s
ard Surface Cleaners
67
68 Advanced Cleaning Product Formulations
A l k a l i n e Hard Surface Cleaner
n
I gredient s :
Water, D . I . 34.0
Sodi um M e t a s i 1 ic a t e 8.0
Varami de A-83 12.0
W i t c o n a t e 30DS 40.0
W i t c o n a t e SXS L i q u i d 8.0
81 e n d i n g P r o c e d u r e :
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t io n .
Typical Properties:
V i s c o s i t y , c p s : 205
S o l ids : 3 4 . 4 %
pH: 1 2 . 5
F o r m u l a 516
Hard Surface CleaEer Concentrate ( A l l P u r p o s e Type)
Ingredients: \Ne%
Water, D . I . 82.0
T e t r a s p o t a s s i u m P y r o p h o s p h a t e , Anhydrous 10.0
W i t c a m i de 1 PET 1.o
Emphos 5AP 4.0
W i t c o 1298S A 3.0
Blending Procedure:
Blend i n g r e d i e n t s i n order l i s t e d , m i x i n g w e l l a f t e r each
addition.
Typical Properties:
S p e c i f i c G r a v i t y : 1.085
Wt./Gal. l b s : 9.04
pH, a s i s : 7 . 5 7
V i s c o s i t y , c p s : 94
3 Freeze/Thaw c y c l e s : Passed
1 Week @ 52C: Passed
4 Weeks Room Temp: Passed
S o l i d s : 17.8%
Appearance: C 1 e a r L i q u i d
Use D i l u t i o n : 1-3 o z . / g a l .
F o r m u l a 540
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
Hand Surface Cleaners 69
Concentrated Hard Surface Cleaner
Ingredients: Wei q h t %
D e o d o r i z e d Kerosene 25.00
Calamide C T W 16.30
C a l o x y l a t e N-9 9.00
E t h y l e n e G l y c o l Monobutyl E t h e r 9.00
Water 41 .30
N a4 E DTA 0.40
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
Use 1-2 o z p e r g a l l o n .
F o r m u l a t i o n HSC-009-01
Hard Surface Cleaner-Spray
Inqredi ents: Wei q h t %
Water 86.50
Ammonia, 29% 3.00
Na4EDTA 0.50
Ethylene G l y c o l Monobutyl E t h e r 5.00
C a l s u d s 81 5.00
Comments a b o u t t h i s f o r m u l a :
1 . A f t e r a d d i t i o n o f E t h y l e n e G l y c o l Monobutyl E t h e r , t h e
mixture i s cloudy.
2 . It becomes c l e a r w i t h t h e a d d i t i o n o f C a l s u d s 8 1 .
F o r m u l a t i o n HSC-008-01
P i n e Cleaner
Inqredi ents : Weight%
Pine O i l 20.00
IPA 10.00
Calamide C T W 9.00
Cal o x y l a t e N-9 5.00
C a l s o f t LAS-99 2.00
Water 54.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
Use a t 1-2 o z p e r g a l l o n .
F o r m u l a t i o n HSC-004-01
P
-i n e Cleaner
Ingredients: Weight%
Pine O i l 15.00
C a l s u d s CD-6 10.00
C a l o x y l a t e N-9 8.00
IPA 10.00
Water 57.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n HSC-007-01
~~~~~~~ P i l o t Chemical Co. : Suggested F o r m u l a t i o n s
70 Advanced Cleatiing Product Formulations
H a r d S u r f a c e Cleanerc
Ingredients: weight%
Water 75.25
Sodi um M e t a s i 1 i c a t e 2.00
Na4EDTA 2.00
Dowanol PnB 6.00
P i l o t SXS-40 9.00
C a l o x y l a t e N-9 5.50
P i n e 01 1 0.25
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d
F o r m u l a t i o n HSC-001-01
Hard-Surface-C1 @anex
Ingredi ents : Wi q h t 9 6
Water 74.50
Sodi um M e t a s i 1 i c a t e 2.00
Na4EDTA 2.00
P i l o t SXS-40 7.00
Cal imu1 se PRS 3.00
Dowanol PnB 5.00
Cal o x y l a t e N-9 6.50
Comments s b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n HSC-002-01
H a r d S u r f a c e Cle&ne_r
Ingredisnts : Weisht_"L.
Water 79.30
Sodi um M e t a s i 1 i c a t e 5.20
Na4EDTA 2.50
P i l o t SXS-40 5.00
Calamide C T W 8.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
Use 1 - 4 o z p e r g a l l o n .
F o r m u l a t i o n HSC-005-01
eaner
Hardsu.!-33Cs~_ec1
Irns r e d i en t-s 1 e
W i_ph %
t
Water 58.50
Sodi um C i t r a t e 15.00
Soda Ash 5.00
Ammonia, 29% 3.50
P i l o t SXS-40 8.00
Calamide CWT 1O.DO
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
Use 2-4 o z p e r g a l l o n .
F o r m u l a t i o n HSC-006-01
SOURCE: P i l o t Chemical C o . : Suggested F o r m u l a t i o n s
Hand Sqface Cleaners 71
Hard Surface Cleaner w/Amphoteric
Inqredi ents: Wt%
Water, D . I . 75.0
Sodi um C a r b o n a t e 4.0
R e w o t e r i c AM KSF-40 10.0
Dowanol DPM 5.0
Versene 100 2.0
W i t c o n a t e SXS (40%) 4.0
Blending Procedure:
Add i n g r e d i e n t s in o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .
T y p i c a l P r o p e r t i es :
V i s c o s i t y , cps: 4
S o l i d s : 10.2%
pH: 10.8
F o r m u l a 507
H a r d S u r f a c e C l e a n e r C o n c e n t r a t e w/d'Limonene
Ingredients:
Phase I:
Isopropanol 10.0
Oleic A c i d 8.8
.Varoni c K205 5.0
d ' L i monene 12.0
Phase 11:
Water, D . I . 62.2
P o t a s s i u m H y d r o x i d e (87%) 2.0
B1 e n d i ng P r o c e d u r e :
Combine Phase I i n g r e d i e n t s and m i x t h o r o u g h l y . Combine Phase
I 1 i n g r e d i e n t s and m i x t h o r o u g h l y . W h i l e m i x i n g , add Phase I t o
Phase 11.
T y p i c a l P r o p e r t i es :
V i s c o s i t y , cps: 75
S o l i d s : 13.8%
pH: 1 0 . 2
F o r m u l a 508
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
72 Advanced Cleaning Product Formulations
Hard Surface Cleaner Concentrate
IPhosphate. L i q u i d )
S o i l - F o o d g r e a s e , o i l and p r o t e i n , p e t r o l e u m g r e a s e and o i l
Surface-Metal, ceramic, polymeric, g l a s s
A p p l i c a t i o n Method-Wipe, mop o r s p r a y ( d i l u t e d )
M a n u f a c t u r e - M i x t a n k w i t h p r o p e l 1e r s t i r r e r
ComDosition A:
Water 71.4
TSP 1.6
S t a r s o Sodium S i l i c a t e 14.0
Sodium H y d r o x i d e (50%) 4.0
*Phosphate E s t e r 5.0
* * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 6 Moles EO) 2.8
* * * L i q u i d N o n i o n i c S u r f a c t a n t (C9-C11; 2 . 5 Moles EO) 1 .2
Composition B: Wt%
Water 65.4
TSP 1.6
S t a r s o Sodi um S i 1 ic a t e 18.0
Sodium H y d r o x i d e (50%) 5.0
*Phosphate E s t e r 6.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C9-Cl1; 6 M o l e s EO) 2.8
* * * L i q u i d N o n i o n i c S u r f a c t a n t ( C 9 - C l l ; 2 . 5 Moles EO) 1.2
Use D i l u t i o n : 3-6% bw ( 4 - 8 oz/gallon)
* Rhone-Poulenc Rhodafac RE-600
** Rhone-Poulenc R h o d a s u r f 91-6
*** Rhone-Poulenc R h o d a s u r f A-24
Hard S u r f a c e Spray Cleaner
LPhosphate, L i q u i d )
S o i l - F o o d g r e a s e , o i l and p r o t e i n , p e t r o l e u m g r e a s e and o i l
Surface-Metal, ceramic, polymeric, g l a s s
A p p l i c a t i o n Method-Spray and w i p e
Manufacture-Mix tank w i t h p r o p e l l e r s t i r r e r
Composi t i on : Wt%
~-
Water 90.00
TKPP 2.00
N C l e a r Sodium S i l i c a t e 1.88
Sodium H y d r o x i d e (50%) 0.12
* D i p r o p y l ene G1 y c o l Monomethyl E t h e r 5.00
* * O c t y l p h e n o x y P o l y e t h o x y e t h a n o l , 12-13 M o l e s EO 1 .00
Use: As i s , spray
* Dow Chemical
** Rhone-Poulenc I g e p a l CA-720
SOURCE: PQ C o r p . : Detergent F o r m u l a t i o n Guide
Hand Surface Cleaners 73
Hard S u r f a c e C l e a n e r C o n c e n t r a t e w/Dipentene
I nnredi e n t s : Wt%
Phase I :
Isopropanol 10.0
Oleic Acid 8.8
V a r o n i c K205 5.0
D i pentene 12.0
Phase 11:
Water, D . I . 62.2
Potassium H y d r o x i d e (87%) 2.0
B l e n d i n g Procedure:
Combine Phase I i n g r e d i e n t s and m i x t h o r o u g h l y . Combine Phase
I 1 i n g r e d i e n t s and m i x t h o r o u g h l y . W h i l e m i x i n g , add Phase I t o
Phase X ~I
Typical Properties:
V i s c o s i t y , cps: 50
Solids: 13.8%
pH: 10.1
Formula 509
A 1 k a l ine Hard S u r f a c e C l e a n e r
I n q r e d ients: Wt%
Water, D . I . 62.7
Sodi u M e t a s i 1i c a t e
m 3.0
Varami de A-83 5.0
\Mi t c o n a t e 3 0 D S 6.8
W i t c o n a t e SXS L i q u i d 2.5
B l e n d i n g Procedure:
Add i n g r e d i e n t s i n o r d e r shown and d i s s o l v e c o m p l e t e l y between
each a d d i t i o n .
Typical Properties:
V i s c o s i t y , c p s : 32
S o l i d s : 1 1 .O%
pH: 12.0
Formula 515
SOURCE: W i t c o C o r p . : Suggested F o r m u l a t i o n s
74 Advanced Cleaning Product Formulations
L i q u i d A b r a s i v e C 1e a n s e r
Inqredients: Wt%
Water, t a p 48.5
C a l c i u m c a r b o n a t e , 100 mesh 42.5
Sodium t a l l o w soap, f l a k e s 2.0
A l p h a - S t e p MC-48 2.5
N i n o l 11-CM 2.0
Sodi um C h l o r i d e 2.5
M i x i ng P r o c e d u r e :
Charge warm w a t e r and add c a l c i u m c a r b o n a t e w h i l e m i x i n g .
Add soap and m i x u n t i l d i s p e r s e d . Add MC-48 and 11-CM and m i x
u n t i l homogeneous. Add sodium c h l o r i d e t o t h i c k e n .
P r o p e r t i es :
Appearance: Opaque, o f f - w h i t e creamy l i q u i d
pH, a s i s : 9 . 3
V i s c o s i t y @ 25 deg C . : t h i x o t r o p i c
s p i n d l e #3, 6 rpm, B r o o k f i e l d : 4520 c p s
s p i n d l e #3, 12 rpm, B r o o k f i e l d : 3840 c p s
s p i n d l e # 3 , 30 rpm, B r o o k f i e l d : 3060 c p s
S o l i d s , % : 50
D e n s i t y , l b s / g a l : 11.69
S t o r a g e a t a m b i e n t temp, 1 week: N o s e p a r a t i o n
Use I n s t r u c t i o n s : Use as i s
Performance:
C l e a n s g r e a s e p e n c i l , s c u f f marks and l i p s t i c k f r o m v i n y l
t i l e s s i m i 1 a r t o commerci a1 p r o d u c t s .
SOURCE: S t e p a n C o . : F o r m u l a t i o n No. 3 1 4
T i l e and Sani t a r v C l e a n e r s
Inqredi ents: Wt%
Z u s o l a t 1008/85 5.0
Water 79.6
Xanthan Gum 0.4
C i t r i c acid 15.0
Inqredients: Wt%
Amphotensid B 4 30.0
Water 60.0
Citric acid 10.0
SOURCE: Zschimmer & Schwarz GmbH & Co.: Suggested F o r m u l a t i o n s
CT 02-10-03 and CT 02-10-04
Hand Sutface Cleaners 75
L i q u i d Hard Surface Cleaner
Ingredients: Wt%*
A : Van Gel ES, Magnesium Aluminum S i l i c a t e 4.00
Rhodopol 23, Xanthan Gum 0.50
D e i o n i z e d Water 68.50
0 : Cocamide DEA (Monamid 150-ADD) 0.50
A1 k o x y l a t e d F a t t y A l c o h o l (P1 u r a f a c C-17) 2.50
T e t r a p o t a s s i um P y r o p h o s p h a t e 1.25
P o t a s s i u m Phosphate T r i b a s i c 0.75
D e i o n i z e d Water 21 .oo
C: Ammonium H y d r o x i d e , 28% 1 .oo
Procedure:
1 . D r y b l e n d t h e Van Gel ES and Rhodopol 23 and s l o w l y add them
t o t h e w a t e r w h i l e s t i r r i n g w i t h an homogenizer a t 5000 r p m .
C o n t i n u e m i x i n g f o r 40 m i n u t e s .
2. Combine t h e P a r t B i n g r e d i e n t s w i t h s l o w s t i r r i n g .
3 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o
produce a s l i g h t v o r t e x .
4 . Add P a r t I3 t o P a r t A, m i x f o r 5 m i n u t e s and t h e n add P a r t C
and m i x f o r 5 m i n u t e s .
F o r m u l a t i o n No. 303
Hard Surface C l e a n e r - A l l Purpose
Ingredients: W t .%*
A : Veegum, Magnesi um A1 umi num S i 1 i c a t e 1.20
Rhodopol 23, Xanthan Gum 0.40
D e i o n i z e d Water 48.40
B : Calcium Carbonate 40.00
C: C12-CI3 L i n e a r P r i m a r y A l c o h o l E t h o x y l a t e
(Neodol 23-6.5) 9.00
Cocamide DEA ( N i n o l 40-CO) 1 .oo
P r e s e r v a t i v e , Dye, F r a g r a n c e q.s.
Procedure:
1 . D r y b l e n d t h e Veegum and Rhodopol 23 and s l o w l y add t h e b l e n d
t o t h e w a t e r w h i l e s t i r r i n g w i t h an homogenizer a t 5000 rpm.
C o n t i n u e m i x i n g f o r 20 m i n u t e s .
2 . Add P a r t B and m i x f o r 10 m i n u t e s .
3 . Move t h e b a t c h t o a p r o p e l l e r m i x e r and a d j u s t t h e speed t o
produce a s l i g h t v o r t e x .
4 . Add t h e P a r t C i n g r e d i e n t s i n t h e o r d e r shown, m i x i n g f o r 5
m i n u t e s a f t e r each a d d i t i o n .
F o r m u l a t i o n f r o m S h e l l Chemical Co.
AS r e c e i v e d b a s i s
SOURCE: R . T . V a n d e r b i l t Co., I n c . : Van Gel and Veegum i n H a r d
S u r f a c e C l e a n e r s and P o l i s h e s : Suggested F o r m u l a t i o n s
76 Advanced Cleaning Product Formulations
M o l d and M i l d e w Remover
Carbopol r e s i n s a r e used t o reduce s p l a s h i n g and t o p r o v i d e
v e r t i c a l c l i n g when s p r a y e d on a v e r t i c a l surface. This
"no-drip" a c t i o n w i l l increase the contact time o f the deter-
g e n t on t h e s o i l e d s u r f a c e and enhance consumer c o n v e n i e n c e .
I n p r e d ie n t : \Rlt%
D I water 84.50
Carbopol 672 ( 1 ) 1 .00
Sodium h y d r o x i d e (50%) 2.00
Sodium m e t a s i l i c a t e , p e n t a h y d r a t e 0.50
P r i m a r y a l k a n e s u l f o n a t e (40%) ( 2 ) 5.00
Sodium h y p o c h l o r i t e (15.00%) 7.00
B r o o k f ie l d v i s c o s i t y (RVT-PO rpm) : 120 cps
P r o d u c t p H : 12-13
P r o d u c t c l a r i t y : Opaque
( 1 ) BFGoodrich
( 2 ) Stepan C o . : B i o - T e r g e PAS-8S
Procedure :
1 . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i ng and b l e n d i ng o p e r a t i o n s , d i s p e r s e o r
s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous.
2 . Under moderate a g i t a t i o n , add t h e sodium h y d r o x i d e and t h e
metasilicate.
3. Add t h e a l k a n e s u l f o n a t e .
4 . Under l o w a g i t a t i o n , add t h e sodium h y p o c h l o r i t e b l e a c h .
5 . Add c o l o r and f r a g r a n c e , as d e s i r e d .
Total Actives:
Primary alkane sulfonate: 2.0
Available chlorine: 1.0
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-320
Laundry Products
77
78 Advanced Cleaning Product Formulations
Detergent f o r Fine Fabrics-1
Powder
Inpredi ents: Q
Genapol OA-080 3.0
DDBS-Na* 15.0
Thermphos NW 25.0
T a l l o w soap, Powder 1 .O-3.0
Sodi um d i s i 1 i c a t e 3.0
S o k a l a n CP 5 1 .o
S o k a l a n HP 22 1 .o
A q u a m o l l i n BC Powder 0.5
Perfume q.s.
Sodi um s u l p h a t e ad 1 0 0 . 0
Manufacturing:
To b e p r e p a r e d by s p r a y m i x p r o c e s s . T h e r e f o r e DDBS-Na must
b e employed i n f o r m o f a s p r a y d r i e d powder. DDBS-Na p a s t e i s
not suitable.
*DDBS=Dodecyl Benzene S u l p h o n a t e
Detergent f o r Fine Fabrics-2
Powder
Inqredients: Wt%
Genapol OA-080 3.0
DDBS-Na* 15.0
Z e o l i t h A (Wessalith 20.0-25.0
T a l l o w soap, Powder 1.0- 3.0
Sodi um d i s i 1 ic a t e 3.0
S o k a l a n CP 5 2.0- 3.0
S o k a l a n HP 22 1 .o
Aquamoll i n BC Powder 0.5
Perfume q.s.
Sodium s u l p h a t e ad 100.0
Manufacturing:
To b e p r e p a r e d b y s p r a y m i x p r o c e s s . T h e r e f o r e DDBS-Na must
b e employed i n f o r m o f a s p r a y d r i e d powder. DDBS-Na p a s t e i s
not suitable.
*DDBS=Dodecyl Benzene S u l f o n a t e
SOURCE: H o e c h s t A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n s
Laundry Products 79
Heavy D u t y L a u n d r y
Ingredients: Wei q h t %
Water 28.90
Sodi um H y d r o x i d e , 50% 6.60
Calamide C 7.00
P i l o t SXS-40 12.50
Cal s o f t LAS-99 40.00
Cal o x y l a t e N - 9 5.00
Comments a b o u t t h i s f o r m u l a :
Add C a l o x y l a t e N - 9 a f t e r 50% o f LAS-99 has been n e u t r a l i z e d .
F o r m u l a t i o n HDL-001-01
Heavy D u t y L a u n d r y
Inqredients: Wei o h t %
Water 42.50
P i l o t SXS-40 22.50
Calamide C T W 4.00
Sodium S i l i c a t e ( S o l i d ) 3.01
C a l s o f t L-60 18.00
EDTA (Ethylenediaminetetraacetic A c i d ) 2.50
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n HDL-006-01
Heavv D u t y L a u n d r y
I n q r e d ie n t s : Weight%
Water 78.50
C a l f a x DB-45 7.00
C a l o x y l a t e N-9 7.00
P r o p y l ene G1 y c o l 2.50
TKPP ( T e t r a P o t a s s i um Pyrophosphate) 5.00
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
F o r m u l a t i o n HDL-007-01
Heavv D u t y L a u n d r y
Inqredients: Wei q h t %
Water 42.00
TKPP ( T e t r a P o t a s s i u m P y r o p h o s p h a t e ) 15.00
Sodium S i l i c a t e ( S o l i d ) 10.00
C a l s o f t L-60 18.00
P i l o t SXS-40 10.00
Calamide C T W 5.00
Comments a b o u t t h i s f o r m u l a :
May need t o be h e a t e d t o s o l u b i l i z e t h e s u r f a c t a n t .
F o r m u l a t i o n HDL-008-01
SOURCE: P i 1o t Chemical Co. : Suggested Formul a t i ons
80 Advanced Cleaning Product Formulations
I & I L i q u i d Laundrv Detergent
w i t h Enzyme & O p t i c a l
Components: % by Weisht
Water 50.00
T r i e t h a n o l ami ne 85% 3.25
D i e t h y l ene G1 y c o l 20.00
B u r c o l 117 10.00
B u r c o l LAF-6 10.00
Burcowi t e BBH-PO 1.25
B u r c o t a s e SL-160 0.50
B u r c o LAF-6 i s used t o c o n t r o l foam as w e l l a s t o p r o v i d e
w e t t i n g and d e t e r g e n c y .
Procedure:
Charge 1 / 2 o f w a t e r I3 120F. Add 1 , 2 , 3 , & 4 and b l e n d . Add
r e m a i n i n g w a t e r . Cool t o 1OOF. Add 5 and 6 . B l e n d u n t i l u n i f o r m .
1% pH: 9 . 5
% s o l i d s : 26
Lbs/gal : 8.66
S u r f a c t a n t R i c h D e t e r g e n t f o r N u r s i n o Homes
Ingredients: % bv W e i q h t
Water 30
TKPP 5
Sodium M e t a s i l i c a t e P e n t a h y d r a t e 5
B u r c o t e r g e DG-40 40
B u r c o NPS-876 10
SXS-40% 10
6-8 ounces p e r 100 pounds o f l a u n d r y . Heavy s o i l s may r e q u i r e
s l i g h t l y higher levels.
SOURCE: B u r l i n g t o n Chemical Co.: Suggested F o r m u l a t i o n s
Powder f o r A u t o m a t i c D i s h w a s h i n n M a c h i n e s
Ingredients: YO by W e i q h t
A Genapol 2908 1 .oo
B Sodium m e t a s i 1 i c a t e x 5H20 52.00
C Sodium c a r b o n a t e 10.00
Sodi um d i c h l o r o i s o c y a n u r a t e 2.00
Thermphos N W 35.00
Manufacturing:
I Spray A on B .
I 1 One a f t e r a n o t h e r , t h e components o f C a r e added t o 1
A p p l i c a t i o n : 1-29 d e t e r g e n t / L d i s h w a s h i n g l i q u o r
SOURCE: Hoechst A k t i e n g e s e l l s c h a f t : Suggested F o r m u l a t i o n
Laundry Products 81
IndustriaT Heavy Duty Laundry L i q u i d
Carbopol ETD 2691 is t o p r o v i d e p r o d u c t phase s t a b i l i z a t i o n i n
t h i s high a l k a l i n i t y i n d u s t r i a l strength cleaner.
I nsredient : Wt%
D I water 49.00
Carbopol ETD 2691 ( 1 ) 0.50
612-15 l i n e a r a l c o h o l , 7 moles EO ( 2 ) 18.00
Sodium a l k y l b e n z e n e s u l f o n a t e (60%) ( 3 ) 5.50
Potassium h y d r o x i d e (45%) 2.00
Sodium m e t a s i l i c a t e , anhydrous 5.00
T e t r a p o t a s s i u m pyrophosphate 20.00
P h y s i c a l Pi-opert ie s :
B r o o k f i e l d V i s c o s i t y (RVT-20 rpm): 900
P r o d u c t pH: 14
P r o d u c t C l a r i t y : Opaque
Raw M a t e r i a l S u p p l i e r s :
( 1 ) BFGoodrich
( 2 ) S h e l l Chemical C o . : Neodol 25-7
( 3 ) Stepan Co.: B i o s o f t D-62
PP.0cedure:
I . Use a b i g h t n i n ' M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an
i m p e l l e r s u i t a b l e f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s .
Screen t h e Carbopol r e s i n i n t o t h e v o r t e x o f t h e r a p i d l y
a g i t a t i n g w a t e r (800 rpm). A l l o w t o mix u n t i l homogeneous
and f r e e o f polymer lumps.
2. W i t h s l o w m i x i n g , add i n t h e a l c o h o l e t h o x y l a t e and a l k y l -
benzene s u l f o n a t e s u r f a c t a n t s .
3. C o n t i n u e a g i t a t i n g and add t h e p o t a s s i u m h y d r o x i d e and meta-
s i li c a t e .
4. Add i n t h e pyrophosphate w i t h minimal a g i t a t i o n t o a v o i d a i r
entrapment.
5. Add dyes and f r a g r a n c e , as d e s i r e d .
Total Wcti ves :
Sodi u a1 k y l benzene sul f o n a t e :
m 3.30
C12-15 l i n e a r a l c o h o l , 7 moles EO: 18.00
T e t r a p o t a s s i u m pyrophosphate: 20.00
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-201
82 Advanced Cleaning Product Formulatioris
I n d u s t r i a l Laundry D e t e r a e n t s
H i g h C a u s t i c Formula-
Components: % bv Weiaht
Burco NPS-816 15.0
Burcosperse LP 10.0
B u r c o l i t e BSGH-255 5.0
Dequest 2000 5.0
50% NaOH 65.0
Procedure:
B l e n d a l l components e x c e p t 50% NaOH. S l o w l y add NaOH w i t h
a g i t a t i o n . Keep t e m p e r a t u r e below 1 6 0 F d u r i n g t h e e n t i r e
agitation.
Mixed B u i l d e r F o r m u l a t i o n
Components: % by Weight
Water 31.5
45% KOH 23.5
B u r c o s p e r s e LP 10.0
TKPP 10.0
Burco NPS-816 15.0
S t a r Grade Sodium S i l i c a t e 10.0
Procedure:
D i s s o l v e KOH i n w a t e r . S l o w l y add Burcosperse LP w h i l e
a g i t a t i n g . Keep t e m p e r a t u r e below 160F. Add TKPP and s t i r u n t i l
d i s s o l v e d . Add Burco NPS-816, t h e n S t a r Grade Sodium S i l i c a t e
and b l e n d u n t i l u n i f o r m .
Use l e v e l s a r e 6-12 ounces p e r 100 pounds, depending on s o i l
l o a d i n g , temperature, e t c .
SOURCE: B u r l i n g t o n Chemical Co., I n c . : Suggested F o r m u l a t i o n s
Washi np P a s t e w i t h 81 e a c h i n g A g e n t
Ingredients: % b y Weiaht
Water 39.0
Sodium t r i p o l y p h o s p h a t e 3.0
Sodium d i t h i o n i t 12.0
Xanthan Gum 2.0
Whi t e - s p i r i t 10.0
Lumorol 4154 30.0
Zusol a t 1005/85 5.0
SOURCE: Zschimmer & Schwarz GmbH & Co.: F o r m u l a t i o n CT 07-06-01
Laundry Products 83
L a u n d r y Deteraent-Consumer
(Liquid)
S o i l - B o d y o i l and p e r s p i r a t i o n , body w a s t e . make-up, food s o i l
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n Method-Household w a s h i n g machine
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composition: Wt%
Water 37.6
Fluorescent Brightener 0.2
C a r b o x y m e t h y l c e l l u l o s e (CMC) 0.5
* A c r y s o l A S E - I 08 6.0
**Nonylphenoxy P o l y e t h o x y e t h a n o l , 9-10 M o l e s €0 10.0
Potassium H y d r o x i d e (45%) 2.2
***Sodium C i t r a t e ( a n d / o r C i t r i c A c i d ) 25.0
K a s i l #6 Potassium S i l i c a t e 12.5
EDTA 5.0
Enzymes ( P r o t e a s e ) 1.o
x( Rohm & Haas; o r Rhone-Poulenc C o l l o i d 225/35 P o l y a c r y l a t e
(40%)
** Rhone-Poul enc I g e p a l CO-630
*** A d j u s t p H w i t h c i t r i c a c i d t o m a i n t a i n pH f o r e f f e c t i v e
enzyme p e r f o r m a n c e ( i . e . 8 . 5 - 9 . 5 p H ) .
L a u n d r y Detergent-Consumer
I Z e o l i t e B u i l t , Z e r o Phosphate, L i q u i d )
S o i l - B o d y o i l and p e r s p i r a t i o n , body w a s t e , f o o d s o i l , make-up
S u r f a c e - C o t t o n and c o t t o n - p o l y e s t e r
A p p l i c a t i o n Method-Household w a s h i n g machine
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composition : Wt%
Water 52.6
C a r b o p o l 674 0.5
D L i q u i d Sodium S i l i c a t e 8.1
* A c u s o l 445ND Sodium P o l y a c r y l a t e (92% s o l i d s ) 0.9
Sodium C a r b o n a t e 9.1
V a l f o r 100 Z e o l i t e A 24.5
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-.13, EO 6 . 5 M o l e s ) 4.3
t: Rohm & Haas
** S h e l l Chemical Neodol 23-6.5
SOURCE: PQ C o r p . : Detergent Formulary Guide
84 Advanced Cleaning Product Formulations
Laundry Detergent-Consumer
( Z e r o Phosphate, Powder)
S o i l - A c i d i c f o o d f a t , o i l grease, b l o o d , sebum and body waste
S u r f a c e - C o t t o n and c o t t o n - p o l y e s t e r
A p p l i c a t i o n Method-Household Washing Machine
Manufacture-Dry Blend/Agglomeration
Composition: Wt9/o
m
Sodi u Carbonate 30.0
B r i t e s i l H20 Hydrous P o l y s i l i c a t e 10.0
*Acusol 445ND Sodium P o l y a c r y l a t e (92% s o l i d s ) 2.0
* * L i n e a r A 1 k y l benzene S u l f o n a t e (LAS) 10.0
* * * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C12-15) 5.0
V a l f o r 100 Z e o l i t e A 30.0
Sodi u S u l f a t e
m 12.5
O p t i c a l B r i g h t e n e r , Perfume 0.5
Use L e v e l : 1000 ppm d e t e r g e n t d e l i v e r e d t o wash ( 1 gram
d e t e r g e n t / l i t e r o f water)
* Rohm & Haas
** Stepan Nacconol 9OG (90% a c t i v e ; powder)
*** Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical
Neodol 25-7
Laundry Detergent-Consumer
(Phosphate, Powder)
S o i l - A c i d i c f o o d f a t and p r o t e i n , body p e r s p i r a t i o n , g r a s s and
dirt
Surface-Polyester, cotton/polyester, cotton
A p p l i c a t i o n Method-Household washing machine
Manufacture-Dry blend/agglomeration
Composi t i on : Q
B r i t e s i l H20 Hydrous P o l y s i l i c a t e 10.0
*STPP 30.0
*Sodium Carbonate 30.0
m
Sodi u S u l f a t e 14.5
* * L i n e a r A1 k y l benzene Sul f o n a t e (LAS) 10.0
* * * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 Moles EO; C12-15) 5.0
O p t i c a l B r i g h t e n e r , Perfume 0.5
Use L e v e l : 1000 ppm d e t e r g e n t d e l i v e r e d t o wash ( 1 g r a m / l i t e r of
water)
* FMC
** Stepan Nacconol 90G (90% a c t i v e ; powder)
*** Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical Co.
Neodol 25-7
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
Laundry Products 85
Laundry B r e a k - I n d u s t r i a l & I n s t i t u t i o n a l
( L i q u i d , Phosphate1
S o i l - A c i d i c f o o d f a t , o i l a n d g r e a s e ; b l o o d , sebum and body
waste
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composition A :
Water 34.1
TKPP 10.0
P o t a s s i urn H y d r o x i d e (45%) 30.4
S t a r Sodium S i l i c a t e 18.0
Sodium H y d r o x i d e (50%) 7.5
C o m p o s i t i o n B: wts/,
Water 25.6
TKPP 10.0
P o t a s s i u m H y d r o x i d e (45%) 30.4
S t a r Sodi um S i 1 i c a t e 24.0
Sodium H y d r o x i d e (50%) 10.0
Use D i l u t i o n : Light Soil: 0.25% by w e i g h t o r 1 l b p e r 100 l b s
1a u n d r y
Medium t o Heavy S o i l : 0.25%-0.50% b y w e i g h t o r 1-2
l b s p e r 100 l b s l a u n d r y
N o t e : Use b u i l d e r s o l u t i o n i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t
( u n b u i l t ) a t 2-4 p a r t s o f b u i l d e r t o 1 p a r t d e t e r g e n t .
Laundry B r e a k - I n d u s t r i a l & Institutional
(Liquid)
S o i l - P e t r o l e u m o i l and g r e a s e , g r a p h i t e and c o l o r e d p i g m e n t
S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composition: %
Water 0-20
N C l e a r Sodium S i l i c a t e 70-90
Sodium H y d r o x i d e (50%) 10-20
Use D i l u t i o n : Light Soil: 0.25% b y w e i g h t o r 1 l b p e r 100 l b s
1a u n d r y
Medium/Heavy S o i l : 0.25%-0.50% b y w e i g h t o r 1-2
l b s p e r 100 l b s l a u n d r y
Notes: Blend t h i s b u i l d e r s o l u t i o n t o 1.7-2.0 r a t i o Si02/Na20 b w
f o r b e s t s t a b i l i t y and i n d u s t r i a l d e t e r g e n c y .
D o r BJ-120 sodium s i l i c a t e s c a n a l s o b e used as b u i l d e r
solutions without blending.
Use b u i l d e r s o l u t i o n i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t
( u n b u i l t ) a t 2-4 p a r t s bw o f b u i l d e r t o 1 p a r t d e t e r g e n t .
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n G u i d e
86 Advanced Cleaning Product Formulatiom
Laundry D e t e r s e n t - I n d u s t r i a l & I n s t i t u t i o n a l
(NTA/Zeol it e , P o w d e d
S o i l - A c i d i c f o o d f a t , o i l and g r e a s e ; b l o o d , sebum and body
waste
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
Manufacture-Dry blend/Agglomeration
Composi t i on :
M e t s o Beads 2048 25.0
Sodi um C a r b o n a t e 38.0
NTA 15.0
* L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C 1 2 - 1 5 ) 12.0
V a l f o r 100 Z e o l i t e A 10.0
Use L e v e l : L i g h t S o i l - O . 2 5 % b y w e i g h t o r 1 l b p e r 1 0 0 l b s
1a u n d r y
Medium S o i l - 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 1 0 0 l b s
1a u n d r y
Heavy S o i l - 0 . 7 5 % b y w e i g h t o r 3 l b s p e r 1 0 0 l b s
1a u n d r y
N o t e : Use B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y or
f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more s u s p e n d i n g /
e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n -
c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .
* Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r
S h e l l Chemical Neodol 25-7
L a u n d r y B r e a k - I n d u s t r i a1 & I n s t i t u t i o n a l
( Z e r o Phosphate, Powder)
S o i l - P e t r o l e u m o i l and g r e a s e , g r a p h i t e and c o l o r e d p i g m e n t
S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
M a n u f a c t u r e - U s e as r e c e i v e d
Composi t i on : Wt46
M e t s o Beads 2048 100.0
Use D i l u t i o n : L i g h t S o i l - O . 2 5 % by w e i g h t o r 1 l b p e r 1 0 0 l b s
1a u n d r y
Medium S o i l - 0 . 5 0 % by w e i g h t o r 2 l b s p e r 100 l b s
1a u n d r y -
Heavy S o i l - O . 7 5 % by w e i g h t o r 3 l b s p e r 100 I b s
1a u n d r y
N o t e : Use i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t ( u n b u i l t ) at
2-4 p a r t s b w o f b u i l d e r w i t h 1 p a r t d e t e r g e n t .
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
Laundqi Products 87
Laundry D e t e r g e n t - I n d u s t r i a l 8 I n s t i t u t i o n a l
(Phosphate, Powder)
S o i l - A c i d i c f o o d f a t , o i l and g r e a s e ; b l o o d , sebum and body
waste
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine
Manufacture-Dry blend/Agglomeration
Composition: WtO/o
Metso Beads 2048 25.0
*Sodium C a r b o n a t e 35.0
*STPP 30.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 m o l e s EO; C12-15) 10.0
Use L e v e l : L i g h t Soi 1-0.25% b y w e i g h t o r 1 l b p e r 100 l b s l a u n d r y
Medium S o i l - O . 5 0 % by w e i g h t o r 2 l b s p e r 100 l b s
1a u n d r y
Heavy S o i l - O . 7 5 % b y w e i g h t o r 3 l b s p e r 100 l b s
1a u n d r y
N o t e : Use B r i t e s i l H20 i n p l a c e o f Metso Beads 2048, p a r t i a l l y
o r f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more suspend-
i n g / e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o
i n c r e a s e t h e s u r f a c t a n t adosrbency o f d e t e r g e n t b l e n d .
x< FMC
** Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r
S h e l l Chemical Neodol 25-7
Laundry D e t e r g e n t - I n d u s t r i a l 8 I n s t i t u t i o n a l
(Sodium Carbonate, Powder)
S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body
waste
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine
Manufacture-Dry blend/Agglomeration
Composi t i on : Q
Metso Beads 2048 25.0
Sodium C a r b o n a t e 55.0
Sodi um S u l f a t e 10.0
* L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C12-15) 10.0
Use L e v e l : L i g h t Soi 1-0.25% b y w e i g h t o r 1 l b p e r 100 l b s l a u n d r y
Medium S o i l - 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 100 l b s
1a u n d r y
Heavy S o i l - O . 7 5 % b y w e i g h t o r 3 l b s p e r 100 l b s
1a u n d r y
N o t e : Use B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y o r
f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more s u s p e n d i n g /
e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n -
c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .
'
k Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r S h e l l Chemical Neodol
25-7
SQURCE: PQ G o r p . : D e t e r g e n t F o r m u l a t i o n G u i d e
88 Advanced Cleaning Product Formulations
Laundry B r e a k - I n d u s t r i a l & I n s t i t u t i o n a l
(Phosphate. Powder, H i g h A l k a l i n i t y )
S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body
waste
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine
Manufacture-Dry b l end/Agglomeration
Composition A : Wt%
Metso Beads 2048 60.0
Sodium H y d r o x i d e Beads 40.0
Composition 8: Wt%
Metso Beads 2048 30.0
*STPP 20.0
*Sodium Carbonate 28.0
Carboxymethylcellulose 2.0
Sodium H y d r o x i d e Beads 20.0
Use D i l u t i o n : L i g h t S o i l - 0 . 2 5 % by w e i g h t o r 1 l b p e r 100 l b s
1aundry
Medium S o i l - 0 . 5 0 % by w e i g h t o r 2 l b s p e r 1 0 0 I b s
1aundry
Heavy S o i l - 0 . 7 5 % by w e i g h t o r 3 l b s p e r 1 0 0 lbs
1aundry
Note: Use t h e s e a l k a l i b u i l d e r s i n c o n j u n c t i o n w i t h l a u n d r y
d e t e r g e n t ( u n b u i l t ) a t 2-4 p a r t s bw o f b u i l d e r w i t h 1 p a r t
detergent
* FMC
Laundrv B r e a k - I n d u s t r i a1 8, I n s t i t u t i o n a l
( Z e r o Phosphate Powder, H i ah A1 k a l in i t v )
S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body
waste
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing machine
Manufacture-Dry blend/Agglomeration
Composi t i on A : Wt%
Metso Beads 2048 60.0
Sodium H y d r o x i d e Beads 40.0
Composition 8: W S
Metso Beads 2048 30.0
m
Sodi u Carbonate 28.0
Carboxymethylcel l u l o s e 2.0
Sodium H y d r o x i d e Beads 20.0
V a l f o r 100 Z e o l i t e A 20.0
Use L e v e l : L i g h t S o i l - 0 . 2 5 % by w e i g h t o r 1 l b p e r 100 l b s l a u n d r y
Medium S o i l - 0 . 5 0 % by w e i g h t o r 2 l b s p e r 100 I b s
1aundry
Heavy S o i l - O . 7 5 % b y w e i g h t o r 3 l b s p e r 0 0 l b s
1aundry
N o t e : Use t h e s e a l k a l i b u i l d e r s i n c o n j u n c t i o n w i t h l a u n d r y d e t -
e r g e n t ( u n b u i l t ) a t 2 - 4 p a r t s bw o f b u i l d e r w t h 1 p a r t
detergent
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
Laundry Products 89
Laundry D e t e r g e n t - I n d u s t r i a l 8 I n s t i t u t i o n a l
(Reduced Phosphate, Powder)
S o i l - A c i d i c f o o d f a t , o i l and g r e a s e ; b l o o d , sebum and body
waste
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
Manufacture-Dry blend/Agglomeration
Composition: Wt%
M e t s o Beads 2048 25.0
*Sodium C a r b o n a t e 35.0
*STPP 20.0
% * L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 m o l e s EO; C12-15) 10.0
V a l f o r 100 Z e o l i t e A 10.0
Use L e v e l : L i g h t S o i l - 0 . 2 5 % by w e i g h t o r 1 l b p e r 1 0 0 l b s l a u n d r y
Medium S o i l - 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 1 0 0 l b s
1a u n d r y
Heavy S o i l - O . 7 5 % b y w e i g h t o r 3 l b s p e r 100 l b s
1a u n d r y
N o t e : Use B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y
o r f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more suspend-
i n g / e m u l s i f y i ng power i s needed. B r i t e s i 1 H20 w i 11 a1 so
i n c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .
96 FMC
dc* Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r
S h e l l Chemical Neodol 25-7
Laundry D e t e r g e n t - I n d u s t r i a l & I n s t i t u t i o n a l
(NTA, Powder)
S o i l - A c i d i c f o o d f a t , o i l and g r e a s e ; b l o o d , sebum and body
waste
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a1 washi ng machine
Manufacture-Dry blend/Agglomeration
Composi t i on : Wt%
M e t s o Beads 2048 25.0
Sodium C a r b o n a t e 40.0
NTA 25.0
* L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C12-15) 10.0
Use L e v e l : L i g h t S o i l - 0 . 2 5 % b y w e i g h t o r 1 l b p e r 100 l b s l a u n d r y
Medium S o i l - 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 100 l b s
1a u n d r y
Heavy S o i l - 0 . 7 5 % b y w e i g h t o r 3 l b s p e r 1 0 0 l b s
1a u n d r y
N o t e : U s e B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y o r
f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more s u s p e n d i n g /
e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l also i n -
crease t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .
*Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r S h e l l Chemical Neodol
25-7
SOURCE: PQ C s r p . : D e t e r g e n t F o r m u l a t i o n G u i d e
90 Advanced Cleaning Product Formulations
Laundry D e t e r q e n t - I n d u s t r i a l B I n s t i t u t i o n a l
(Sodium Carbonate w i t h F l o w A i d . Powder)
S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body
waste
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
Appl ic a t ion Method-I n d u s t r ia1 wash ing mach i ne
Manufacture-Dry blend/agglomeration
Composi t ion : Wt%
Metso Beads 2048 20.0
Sodium Carbonate 55.0
Sodi um S u l f a t e 10.0
* L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C 1 2 - 1 5 ) 10.0
V a l f o r 100 Z e o l i t e A 5.0
Use L e v e l : L i g h t S o i l : 0.25% by w e i g h t o r 1 l b p e r 1 0 0 l b s
1aundry
Medium S o i l : 0 . 5 0 % b y w e i g h t o r 2 l b s p e r 1 0 0 l b s
1 aundry
Heavy S o i l : 0.75% b y w e i g h t o r 3 l b s p e r 100 l b s
1 aundry
Note: Use B r i t e s i l H20 i n p l a c e o f Metso Beads 2048, p a r t i a l l y
o r f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more sus-
p e n d i n g / e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l
a l s o i n c r e a s e t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .
* Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r
S h e l l Chemical Neodol 25-7
Laundry D e t e r g a n t - I n d u s t r i a l & I n s t i t u t i o n a l
IPhosphate, S o l i d Block)
S o i l - A c i d i c f o o d f a t , o i l and grease; b l o o d , sebum and body
waste
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a1 washing machine
Manufacture-Sol i d b l o c k
Composi t i on : Wt%
Metso Beads 2048 25.0
NaOH ( 5 0 % S o l u t i o n ) 25.0
*STPP 35.0
*Sodium Carbonate 12.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (7-9 Moles EO; C12-15) 3.0
* M
F C
** Rhone-Poulenc Rhodasurf LA-7 o r LA-9 o r
S h e l l Chemical Neodol 25-7
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
Laundry Products 91
Laundry D e t e r g e n t - I n d u s t r i a l and I n s t i t u t i o n a l
(Zero Phosphate, Powder)
S o i l - A c i d i c f o o d f a t , o i l g r e a s e , b l o o d , sebum and body w a s t e
S u r f a c e - C o t t o n and c o t t o n p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
Manufacture-Dry Blend/Agglomeration
Composition : Wt%
Sodi um C a r b o n a t e 35.0
* L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles € 0 ; C12-15) 15.0
V a l f o r 100 Z e o l i t e A 25.0
M e t s o Beads 2048 25.0
Use L e v e l : L i g h t S o i l - 0 . 2 5 % b y w e i g h t o r 1 l b p e r 100 l b s l a u n d r y
Medium S o i l - O . 5 0 % b y w e i g h t o r 2 l b s p e r 100 l b s
1a u n d r y
Heavy S o i l - 0 . 7 5 % b y w e i g h t o r 3 l b s p e r 1 0 0 l b s
1a u n d r y
N o t e : Use B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y o r
f u l l y , i f l o w e r a1 k a l in i t y is d e s i r e d and more s u s p e n d i n g /
e m u l s i f y i n g powder i s needed. B r i t e s i l H20 w i l l a l s o i n -
crease t h e s u r f a c t a n t adsorbency o f d e t e r g e n t blend.
*Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r
S h e l l Chemical Neodol 25-7
L a u n d r y D e t e r g e n t - I n d u s t r i a l and I n s t i t u t i o n a l
( Z e r o Phosphate, Powder)
S o i l - P e t r o l e u m o i l and g r e a s e , g r a p h i t e and c o l o r e d p i g m e n t
S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
M a n u f a c t u r e - D r y B1 end/Aggl o m e r a t i on
Composi t ion : Wt%
Sodium C a r b o n a t e 44.5
* L i q u i d N o n i o n i c S u r f a c t a n t ( 7 - 9 moles EO; C12-15) 18.0
V a l f o r 100 Z e o l i t e A 30.0
* * A c u s o l 445ND Sodium P o l y a c r y l a t e (92% s o l i d s ) 2.5
M e t s o Beads 2048 5.0
Use L e v e l : L i g h t S o i 1-0.25% b y w e i g h t o r 1 l b p e r 1 0 0 l b s l a u n d r y
Medium S o i l - O . 5 0 % b y w e i g h t o r 2 l b s p e r 100 l b s
1a u n d r y
Heavy S o i l - 0 . 7 5 % b y w e i g h t o r 3 l b s p e r 100 l b s
1a u n d r y
N o t e : Use B r i t e s i l H20 i n p l a c e o f M e t s o Beads 2048, p a r t i a l l y o r
f u l l y , i f l o w e r a l k a l i n i t y i s d e s i r e d and more s u s p e n d i n g /
e m u l s i f y i n g power i s needed. B r i t e s i l H20 w i l l a l s o i n -
crease t h e s u r f a c t a n t adsorbency o f d e t e r g e n t b l e n d .
Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9 o r
S h e l l Chemical Neodol 25-7
** Rohm & Haas
SOURCE: PQ Corp. : D e t e r g e n t F o r m u l a t i o n G u i d e
92 Advanced Cleaning Product Formulations
Laundry D e t e r q e n t - I n d u s t r i a l & I n s t i t u t i o n a l
[ P h o s p h a t e B u i 1t , L i q u i d )
S o i l - B o d y o i l and p e r s p i r a t i o n , body waste, make-up, food s o i l
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composition A: Wt%
Water 54.5
TKPP 4.6
P o t a s s i u m H y d r o x i d e (45%) 13.7
S t a r s o Sodium S i l i c a t e 15.0
Sodi um H v d r o x i d e ( 5 0 %.)
, 4.2
*PhosphaGe E s t e r 5.0
**Liquid Nonionic Surfactant (C12-C15, 7-9 M o l e s € 0 ) 3.0
C o m p o s i t i o n B: Wt%
Water 59.1
P o t a s s i u m H y d r o x i d e (45%) 13.7
S t a r s o Sodi um S i 1 i c a t e 15.0
Sodium H y d r o x i d e ( 5 0 % ) 4.2
*Phosphate E s t e r 5.0
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-C15, 9 Moles EO) 3.0
Use D i l u t i o n : 0 . 2 5 % - 0 . 5 0 % b y w e i g h t or 1-2 l b s p e r 1 0 0 l b s
1a u n d r y
* Rhone-Poulenc Rhodafac RE-610
** Rhone-Poulenc R h o d a s u r f LA-7 o r LA-9
Laundry D e t e r g e n t - I n d u s t r i a l & Institutional
( L i quid)
Soi 1-Body o i 1 and p e r s p i r a t i o n , body w a s t e , make-up, food soi 1
S u r f a c e - C o t t o n and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composition: wts/,
Water 28.7
F1 u o r e s c e n t B r i g h t e n e r 0.1
C a r b o x y m e t h y l c e l l u l o s e (CMC) 0.5
* A c r y s o l ASE-108 ( A c r y l i c P o l y m e r ) 6.0
**Nonylphenoxy P o l y e t h o x y e t h a n o l , 9-1 0 M o l e s EO 10.0
P o t a s s i um H y d r o x i d e (45%) 2.2
TKPP (60%) 40.0
K a s i 1 #6 P o t a s s i um S i 1 i c a t e 12.5
Use D i l u t i i o n : 0.25%-0.50% by w e i g h t or 1-2 l b s p e r 1 0 0 I b s
1a u n d r y
* Rohm & Haas; or Rhone-Poulenc C o l l o i d 226/35 P o l y a c r y l a t e (40%)
**Rhone-Poulenc I g e p a l CO-630
SOURCE: PQ C o r p . : Detergent Formulary Guide
Laundry Products 93
Laundry B u i l d e r - I n d u s t r i a l & Institutional
(L iquid)
S o i l - A c i d i c f o o d , f a t , o i l and grease; b l o o d , sebum and body
waste
S u r f a c e - P o l y e s t e r and c o t t o n / p o l y e s t e r
A p p l i c a t i o n M e t h o d - I n d u s t r i a l w a s h i n g machine
Manufacture-Mix t a n k w i t h p r o p e l l e r s t i r r e r
Composition A : Wt%
P o t a s s i u m H y d r o x i d e (45%) 35-45
i C l e a r o r E Sodium S i l i c a t e
U 55-65
C o m p o s i t i o n B: Wt%
Water 11.0
Potassium Hydroxide ( S o l i d ) 37.0
N C l e a r or E Sodium S i l i c a t e 52.0
Composition C: Wt%
Water 6.0
Potassium Hydroxide ( S o l i d ) 28.0
N C l e a r o r E Sodium S i l i c a t e 52.0
Sodium H y d r o x i d e ( S o l i d ) 14.0
Use D i l u t i o n : Light Soil: 0.25% by w e i g h t o r 1 l b p e r 100 l b s
1a u n d r y
Medium t o Heavy S o i l : 0.25%-0.50% b y w e i g h t o r 1-2
l b s p e r 100 l b s l a u n d r y
N o t e : Use b u i l d e r s o l u t i o n i n c o n j u n c t i o n w i t h l a u n d r y d e t e r g e n t
( u n b u i l t ) a t 2-4 p a r t s bw o f b u i l d e r t o 1 p a r t d e t e r g e n t
Laundry D e t e r g e n t - I n d u s t r i a l & I n s t i t u t i o n a l
( Z e o l i t e B u i l t , Z e r o Phosphate, L i q u i d )
S o i l - B o d y o i l and p e r s p i r a t i o n , body waste, f o o d s o i l , make-up
S u r f a c e - C o t t o n and. c o t t o n - p o l y e s t e r -
A p p l i c a t i o n M e t h o d - I n d u s t r i a l washing a c h i ne
Manufacture-Mix t a n k w i t h p r o p e l l e r s t r r e r
Composition: WtO/o
Water 57.06
C a r b o p o l 674 0.5
Metso Beads 2048 2.7
*Acusol 445N Sodi um P o l y a c r y a t e (45% s o l d s ) 1.04
Sodium C a r b o n a t e 9.1
V a l f o r 100 Z e o l i t e A 24.5
* * L i q u i d N o n i o n i c S u r f a c t a n t (C12-13; EO 6 . 5 M o l e s ) 4.3
8 Rohm 8: Haas
** S h e l l Chemical Neodol 2 3 - 6 . 5
SOURCE: PQ C o r p . : D e t e r g e n t F o r m u l a t i o n Guide
94 Advanced Cleaning Product Formulations
Laundry P r e s o o t t e r S p r a y a b l e Gel
Carbopol ETD 2623 i s used i n t h i s f o r m u l a t i o n t o c o s t e f f e c -
t i v e l y t h i c k e n t h e s u r f a c t a n t system i n t o a g e l f o r m - which can
be a p p l i e d t o t h e f a b r i c by b r u s h o r sprayed on due to C a r b o p a l ' s
shear t h i n n i n g n a t u r e .
Inaredi ent:
D I water 83.75
Carbopol ETD 2623 ( 1 ) 0.20
C12-15 l i n e a r a l c o h o l , 3 moles €0 ( 2 ) 10.00
C12-13 l i n e a r a l c o h o l , 6 . 5 males €0 ( 3 ) 5.00
EDTA ( t e t r a sodium s a l t ) 0.50
Sodium h y d r o x i d e (18%) 0.55
B r o o k f i e l d v i s c o s i t y (RVT-20 rpm): 8,300 cps
P r o d u c t pH: 7.0-8.0
P r o d u c t c l a r i t y : Opaque
( 1 ) BFGoodrich
( 2 ) S h e l l Chemical Co.: Neodol 25-3
( 3 ) S h e l l Chemical C o . : Neodol 23-6.5
Procedure:
1 . U s i n g moderate a g i t a t i o n ( 8 0 0 rpm) p r o v i d e d by a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i ng and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
screen t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 15 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous.
2 . Add i n b o t h o f t h e a l c o h o l e t h o x y l a t e s u r f a c t a n t s . M i x u n t i l
homogeneous.
3. Add i n t h e EDTA.
4 . Add i n t h e sodium h y d r o x i d e u n t i l t h e pH i s a t t a i n e d .
5 . Add c o l o r and f r a g r a n c e , as d e s i r e d .
Total Actives:
C12-15 l i n e a r a l c o h o l , 3 moles EO ( 2 ) : 10.0
C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO ( 3 ) : 5.0
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-224
Laundry Products 95
Laundry Presootter Sorayable L i q u i d
Carbopol ETD 2 6 2 3 i s used i n t h i s f o r m u l a t i o n t o s l i g h t l y
t h i c k e n t h e s u r f a c t a n t system and e n a b l e t h e p r o d u c t t o s t a y i n
c o n t a c t w i t h t h e s o i l l o n g e r b y r e d u c i n g seepage t h r o u g h t h e
fabric.
I n s r e d ie n t : Wt%
D I water 84.30
Carbopol ETO 2623 ( 1 ) 0.05
C12-15 l i n e a r a l c o h o l , 3 moles €0 ( 2 ) 10.00
C12-13 l i n e a r a l c o h o l , 6 . 5 moles €0 ( 3 ) 5.00
EOTA ( t e t r a sodium s a l t ) 0.50
Sodi u h y d r o x i d e (18%)
m 0.15
B r o o k f i e l d v i s c o s i t y (RVT-20 rpm) : 2 5 0 cps
P r o d u c t pH: 7 . 0 - 8 . 0
P r o d u c t c l a r i t y : Opaque
( 1 ) BFGoodri ch
( 2 ) S h e l l Chemical Co.: Neodol 2 5 - 3
( 3 ) S h e l l Chemical Co.: Neodol 2 3 - 6 . 5
Procedure:
I . U s i n g moderate a g i t a t i o n (800 rpm) p r o v i d e d b y a L i g h t n i n '
M i x e r o r s i m i l a r v a r i a b l e speed u n i t and an i m p e l l e r s u i t a b l e
f o r g e n e r a l m i x i n g and b l e n d i n g o p e r a t i o n s , d i s p e r s e o r
s c r e e n t h e Carbopol r e s i n i n t o t h e D I w a t e r . M i x t h e s l u r r y
f o r a p p r o x i m a t e l y 1 5 m i n u t e s o r u n t i l t h e s l u r r y i s homogen-
eous.
2. Add i n b o t h o f t h e a l c o h o l e t h o x y l a t e s u r f a c t a n t s . Mix u n t i l
homogeneous.
3 . Add i n t h e EDTA.
4 . Add i n t h e sodium h y d r o x i d e u n t i l t h e pH i s a t t a i n e d .
5 . Add c o l o r s o l u t i o n and f r a g r a n c e , as d e s i r e d .
Total Actives:
C12-15 l i n e a r a l c o h o l , 3 moles EO: 10.0
C12-13 l i n e a r a l c o h o l , 6 . 5 moles EO: 5.0
SOURCE: BFGoodrich S p e c i a l t y Chemicals: DET-220
96 Advanced Cleaning Product Formulations
L i g h t Duty L i q u i d Detergent
Ingredients: wej-ghs
Water 48.45
P i l o t SXS-40 7.50
C a l s o f t L-60 30.00
Calamide C 5.00
C a l foam EA-603 8.30
C a l s o f t LAS-99 0.60
C i t r i c Acid 0.10
Sodium C i t r a t e 0.05
Comments a b o u t t h i s f o r m u l a :
1 . pH=7.1
2 . Add C i t r i c A c i d i f pH i s h i g h o r Sodium C i t r a t e i f pH i s l o w .
3 . V i s c o s i t y s h o u l d b e 300 c P s .
F o r m u l a t i o n LDL-001-01
L i s h t Duty Liquid Detergent
Ingredients: Weight%
Water 22.31
C a l s o f t L-60 39.70
P1 l o t s x s - 4 0 22.10
Calamide C 7.06
C a l f o a m EA-603 7.35
C a l s o f t LAS-99 0.56
Opaci f i e r 0.88
Sod1 um C i t r a t e 0.04
Comments a b o u t t h i s f o r m u l a :
1 . Add e i t h e r C i t r i c A c i d o r C a l s o f t LAS-99 t o a d j u s t pH t o
7.0-7.2.
2 . S o l i d s 45%.
3 . S u b s t i t u t i n g C a l s o f t L-40 for C a l s o f t L-60 w i l l lower
p r o d u c t s o l i d s t o 42%.
F o r m u l a t i o n LDL-002-01
L i g h t Duty L i q u i d Detergent
Ingredients: Weight%
Water 18.80
Calsuds A 70.00
C a l foam ES-303 10.00
Perfume 0.10
K a t h o n CG 0.10
Opaci f ie r 1.oo
Comments a b o u t t h i s f o r m u l a :
1 . I f o p a c i f i e r i s t o be added, w i t h h o l d 5% o f t h e w a t e r
2 . Add t h e o p a c i f i e r t o t h e w a t e r p r i o r t o a d d i n g t o t h e
detergent.
F o r m u l a t i o n LDL-004-01
SOURCE: P i l o t Chemical C o . : Suggested F o r m u l a t i o n s
Laundry Products 97
L i g h t -Duty L i q u i d Detergent
Ingredi ents : Weight%
Water 50.20
C a l s u d s CD-6 25.00
P i l o t SXS-40 6.80
C a l foam EA-603 10.00
Cal s o f t LAS-99 6.00
Comments a b o u t t h i s f o r m u l a :
1 . I n g r e d i e n t s s h o u l d be added i n t h e o r d e r l i s t e d t o a i d i n
blending.
2. Sodium C i t r a t e / C i t r i c A c i d s h o u l d be added f o r pH a d j u s t m e n t
t o 7+.
3 . S a l t ( S o d i u m o r Ammonium C h l o r i d e ) w i l l r a i s e t h e v i s c o s i t y .
F o r m u l a t i o n LDL-006-01
L i g h t Duty L i q u i d Detergent
In g r e d i e n t s : Weight%
Water 36.90
P i l o t SXS-40 5.00
C a l s o f t T-60 40.00
C a l foam ES-303 15.00
Calamide C 2.00
P r e s e r v a t iv e 0.10
S o d i um C h l o r i d e 1 .00
Comments a b o u t t h i s f o r m u l a :
V i s c o s i t y 275 cPs.
Sol i d ~ = 3 2 - 3 3 %
pH=6.2
F o r m u l a t i o n LOI-007-01
L i g h t Duty L i q u i d Detergent
Ingredients: Weight%
Water 65.16
P i l o t sxs-40 6.29
L i n e a r A1 coho1 E t h o x y l a t e 2.52
NaOH, 5 0 % 2.81
D i e t h a n o l am1 ne 0.43
C a l s o f t LAS-99 19.77
Comments a b o u t t h i s f o r m u l a :
S o l 1 ds=30%
Good f o r g r e a s y a p p l i c a t i o n s .
F o r m u l a t i o n IDL-006-01
SOURCE: P i l o t C h e m i c a l Co : S u g g e s t e d F o r m u l a t i o n s
98 Advanced Cleaning Product Formulations
L i g h t Duty L i q u i d Detergent
I n g r e d i ent-sl Weight%
Water 13.90
Ammonium C h l o r i d e 2.40
P i l o t sxs-40 19.60
C a l s o f t L-60 44.10
Cal foam ES-303 15.80
Calamide C 4.00
C i t r i c Acid 0.10
P r e s e r v a t iv e 0.10
Comments a b o u t t h i s f o r m u l a :
1 . “ A s i s ” pH=8.0.
2 . Add C i t r i c A c i d i n p l a c e o f Sodium C i t r a t e t o l o w e r pH.
F o r m u l a t i o n LDL-009-01
Ligh-t- D u t y L i q u i d D e t e r q e n t
C a l s o f t LAS-99 Based
Ingredients: Weight%
Water 43.60
NaOH, 50% 5.80
C a l s o f t LAS-99 21.70
P i l o t SXS-40 16.70
Cal foam ES-303 3.00
C a l o x y l a t e N-9 8.00
C i t r i c Acid 0.10
Opaci f ie r 1 .oo
Preservative 0.10
Comments a b o u t t h i s f o r m u l a :
A d d in g r e d i e n t s i n o r d e r 1 is t e d .
F o r m u l a t i o n LDL-011-01
L i g h t D u t y L i q u i d Detergent
C a l s o f t LAS-99 Based
Ingredients: Weight%
Water 52.40
NaOH, 50% 4.40
Cal s o f t LAS-99 16.30
Calamide C 5.00
P i l o t SXS-40 12.50
Cal foam ES-303 2.20
C a l o x y l a t e N-9 6.00
C i t r i c Acid 0.10
Opaci f ie r 1.oo
Comments a b o u t t h i s f o r m u l a :
Add ingredients i n order l i s t e d .
F o r m u l a t i o n LDL-012-01
SOURCE: P i l o t Chemical Co. : Suggested F o r m u l a t i o n s
Laundry Products 99
a h t Duty L i q u i d Detergent
__ o f t LAS-99 Based
Cals
Inaredients; Weight%
Water 54.60
C a l s o f t LAS-99 16.30
NaOH, 50% 4.35
Alcohol Ethoxyl a t e 10.00
Calamide C 2.05
P i l o t SXS-40 12.50
Perfume 0.10
P r e s e r v a t iv e 0.10
Comments a b o u t t h i s f o r m u l a :
Add i n g r e d i e n t s i n o r d e r l i s t e d .
Formul a t i on LDL-014-01
Light DutLLCquid D e t e r E n t
Dry Cleaner: Pre-Spot-Water S o l u b l e
Ingredients: Weight%
Water 75.70
Calamide C 2.00
C a l o x y l a t e N-9 11.00
C a l i mu1 s e PRS 11 .oo
C i t r i c Acid 0.20
Perfume & C o l o r 0.10
Comments a b o u t t h i s f o r m u l a :
1 . Add i n g r e d i e n t s i n o r d e r 1 i s t e d . V i s c o s i t y i n c r e a s e s as
C a l o x y l a t e N-9 i s added.
2 . A c l e a r p r o d u c t i s o b t a i n e d when a l l i n g r e d i e n t s a r e m i x e d
together.
3 . D e t e r g e n t f r a g r a n c e R-1264 can be used i n t h i s f o r m u l a .
4 . Use l e v e l : d i l u t e 8 : l w i t h w a t e r .
F o r m u l a t i o n LDY-001-01
Li-ght D u t y Li.qu2d D e t e r g e n t
Wool _Wash
I c g r e d i ents-: Wei g h t %
C a l s o f t T-60 14.15
C a l ami d e CW-100 5.48
C a l f o a m ES-303 39.64
C i t r i c Acid 0.13
Comments a b o u t t h i s f o r m u l a :
The room t e m p e r a t u r e v i s c o s i t y i s a b o u t 520 c P s .
F o r m u l a t i o n LDY-002-01
L i g h t D u t E L i q u j d Detergent
--
Wool Wash
ng
I r e d i g nt s : We1 g h t %
Calsuds A 50.06
Water 49.93
Comments a b o u t t h i s f o r m u l a :
The room t e m p e r a t u r e v i s c o s i t y i s a b o u t 25 c P s .
F o r m u l a t i o n LDY-004-01
SOURCE: P i l o t Chemical Co. : Stiggested F o r m u l a t i o n s
100 Advanced Cleaning Product Formulations
Two Part Industria1 Laundry Deteraents
Break Formulations
Hi q h l v A 1 kal ine Break
Components: % by Weight
Water 5
Burcosperse LP 10
Burcolite BSGH-255 5
Dequest 2000 5
50% NaOH 75
Mixed Builder Break
Components: % by Weight
Water 40.0
45% KOH 27.5
Burcosperse LP 10.0
TKPP 10.0
Sodi um Si 1 i cate (Star Grade) 12.5
Procedure:
Add components in the order listed. Blend until homogeneous
between each addition. Keep temperature below 160F during
bl endi ng.
Detergent Additive
Components: % by Weight
Water 60.00
Burco NPS-816 10.00
Neodol 25-7 12.50
Dodecylbenzenesulfonic Acid 11.65
TEA-85 5.85
Procedure:
Add components in the order listed. Blend until homogeneous
between each addition.
Use Level:
Break: 4-12 ounces/100 pounds
Detergent: 2-4 ounces/100 pounds
SOURCE: Burlington Chemical Co., Inc.: Suggested Formulations
Laundry Products 101
U l t r a L i q u i d Laundrv Deterqent
Ingredients: Wt%
A l p h a - S t e p MC-48 29.0
Sodi urn 01e a t e 5.0
Alcohol, Ethoxylate, 7 19.0
Borax 1.3
3A A l c o h o l 0.5
P r o p y l ene G1 y c o l 5.0
PVP K-15 0.8
W a t e r , f r a g r a n c e & dye Q . S . t o 100.0
M i x i n g Procedure:
Combine A l p h a - S t e p MC-48, p r o p y l e n e g l y c o l , a l c o h o l e t h o x y -
l a t e and w a t e r w h i l e m i x i n g u n t i l s o l u t i o n i s homogeneous.
H e a t t o a p p r o x i m a t e l y 50 deg. C, add sodium o l e a t e and m i x
u n t i l s o l u t i o n and i s a g a i n homogeneous. A l l o w m i x t u r e t o
c o o l t o room t e m p e r a t u r e and add t h e r e m a i n i n g i n g r e d i e n t s w i t h
m i x i n g . A d j u s t p H w i t h c a u s t i c soda o r c i t r i c a c i d i f n e c e s s a r y .
Typical Formulation Properties:
F o r m u l a t i o n D e s c r i p t i o n : SME/Soap Based HDL
pfl: 8-10
V i s c o s i t y : 200-350 c p s
Density: 8.6
Appearance: C l e a r , l i g h t y e l l o w 1 q u i d
Use I n s t r u c t i o n s : Use 1 / 3 c u p p e r n o r m a l s i z e w a s h l o a d
Comment:
A l p h a - S t e p MC-48 i s an e x c e l l e n t oap s o l u b i l i z e r t h a t c a n
make h i g h soap l e v e l s p o s s i b l e i n f i n i s h e d p r o d u c t s .
F o r m u l a t i o n N o . 658
F i n e F a b r i c Wash
Ingredients: Wt%
Water, D . I . 43.4
A l p h a - S t e p MC-48 46.0
N i n o l 30-LL 4.6
Sodi um c h l o r i d e 6.0
M i x i n g Procedure:
Charge w a t e r and MC-48 and m i x . Add 30-LL and m i x u n t i l
homogeneous. Add sodium c h l o r i d e t o t h i c k e n . A d j u s t pH w i t h
s u l f u r i c a c i d o r sodium h y d r o x i d e as n e c e s s a r y .
Properties:
Appearance: C l e a r y e l l o w l i q u i d
pH, as i s : 7 . 5
V i s c o s i t y @ 25 deg. C, c p s : 220
S o l i d s , %: 2 9 . 0
F r e e z e / t h a w , 3 c y c l e s : pass
C o l d s t o r a g e @ 4 deg. C, 1 week: p a s s
H i g h temp. s t o r a g e @ 50 deg. C, 1 week: p a s s
Density, l b s / g a l : 0.6
Use I n s t r u c t i o n s :
Use s m a l l amount f o r hand w a s h i n g o r 1 / 4 cup f o r machine
washing.
Comment :
The s u r f a c t a n t s used i n t h i s f o r m u l a t i o n a r e d e r i v e d f r o m
o l e o c h e m i c a l r e s o u r c e s and a r e b i o d e g r a d a b l e .
F o r m u l a t i o n No. 358
SOURCE: Stepan C o . : Suggested F o r m u l a t i o n s
9. Metal Cleaners and Polish
Metal Cleaners and Polishes 103
Acid Metal Cleaner*
The c o m b i n a t i o n o f Veegum and Rhodopol 2 3 suspends t h a a b r a -
s i v e and p r o v i d e s a s t a b l e , f r e e f l o w i n g c l e a n e r w i t h good
v e r t i c a l s u r f a c e c l i n g . Veegum i s p r o t e c t e d a g a i n s t f l o c c u l a t i o n
i n t h i s pH 1 c o m p o s i t i o n t h r o u g h base exchange w i t h t h e i m i d -
a z o l i n e . T e t r a s o d i u m EDTA f a c i l i t a t e s t h i s exchange. Veegum
and Rhodopol p r o v i d e s y n e r g i s t i c t h i c k e n i ng w i t h b e t t e r v i s c o s i t y
s t a b i l i t y and i n h i b i t i o n o f s y n e r e s i s t h a n i s p o s s i b l e w i t h
e i t h e r t h i c k e n e r a l o n e . Diatomaceous E a r t h p r o v i d e s good c l e a n s -
i n g and p o l i s h i n g .
Inqredients: &
y
A: Veegum 0.8
Rhodopol 23 0.4
Water 72.1
6: T e t r a s o d i u m EDTA 0.9
1 - H y d r o x y e t h y l - 2 - c a p r y l i m i d a z o l i ine 0.8
Phosphoric a c i d 15.0
Diatomaceous E a r t h 10.0
Procedure:
B l e n d Veegum and Rhodopol S l o w l y add them t o t h e w a t e r w h i l e
a g i t a t i ng a t maximum a v a i 1ab e s h e a r . C o n t i n u e m i x i n g u n t i l
smooth. Add B i n g r e d i e n t s i n o r d e r , m i x i n g w e l l a f t e r each
a d d i t i o n u n t i l smooth and un f o r m ( a v o i d i n c o r p o r a t i o n o f a i r ) .
Consistency: White, pourable l i q u i d .
Suggested P a c k a g i n g : P l a s t i c squeeze b o t t l e w i t h p r e c a u t i o n a r y
labeling f o r acid.
*U.S. P a t e n t No. 4,302,253
SOURCE: R.T. V a n d e r b i l t Co., I n c . : F o r m u l a t i o n No. 392
D i ppi ns C1 e a n e r f o r S i 1v e r
Ingredients:
Z u s o l a t 1008/85 2.5
Thiourea 8.0
Hydrochloric acid 3.0
Water 86.5
SOURCE: Zschimmer & Schwarz GmbH & C o . : F o r m u l a t i o n CT 0 2 - 1 5 - 0 2
104 Advanced Cleaning Product Formulations
A1 umi num C1 e a n e r / B r i g h t e n e r
T r a d i t i o n a l l y , a n i o n i c s u r f a c t a n t s have o f f e r e d b e t t e r d e t -
ergency t h e n n o n i o n i c s , b u t were n o t c o m p a t i b l e i n a c i d systems.
T h i s f o r m u l a t i o n uses Avanel S - 7 0 , an a n i o n i c m o l e c u l e w h i c h
p e r f o r m s even a t v e r y low p H ' s and a i d s i n t h e removal o f s u r f a c e
o i l s and d e p o s i t s . U n l i k e n o n i o n i c s , Avanel 5-70 w i l l d i s s o l v e
r e a d i l y i n t o the formulation without forming gel p a r t i c l e s thus
e l i m i n a t i n g t h e need f o r e x c e s s i v e a g i t a t i o n . T h i s f o r m u l a t i o n
can be used f o r o v e r - t h e - r o a d aluminum t r a i l e r s , w i r e wheels
on a u t o m o b i l e s o r i n t h e p r e p a r a t i o n o f aluminum f o r a n o d i z i n g
and c l eani ng.
Inqredients: Wt%
Dei o n i zed Water 83.0
Phosphoric A c i d ( 8 5 % ) 6.0
C i t r i c Acid (50%) 8.0
N i t r i c Acid (70%) 1.o
Avanel S-70 2.0
Procedure:
Charge t h e w a t e r t o a m i x i n g v e s s e l . Under slow a g i t a t i o n and
w i t h due c a r e , add t h e a c i d s t o t h e w a t e r . Add t h e Avanel S - 7 0
and m i x 10 m i n u t e s . NOTE: I f a d d i t i o n a l b r i g h t e n i n g i s r e q u i r e d ,
t h e n i t r i c a c i d c o n c e n t r a t i o n may be i n c r e a s e d t o 1 . 5 % .
F o r m u l a t i o n CM-101
Powdered M e t a l C l e a n i n g C o n c e n t r a t e
I n a r e d ients: Wt%
m
Sodi u H y d r o x i d e 58.5
Sodium Carbonate 13.5
STPP 20.0
Avanel 5-70 8.0
Procedure:
Add i n g r e d i e n t s as l i s t e d .
A1 u m i num C1 eaner
Ingredients:
D e i o n i z e d Water 85.0
Avanel S - 7 0 6.0
T e t r a p o t a s s i u m Pyrophosphate 5.0
Sodium M e t a s i l i c a t e P e n t a h y d r a t e 1.o
C a r b i t o l Solvent 3.0
Procedure:
Charge v e s s e l w i t h i n g r e d i e n t s i n t h e o r d e r l i s t e d u s i n g mod-
e r a t e a g i t a t i o n . NOTE: Other Avanel p r o d u c t s c o u l d be used i n
t h i s f o r m u l a t i o n t o achieve d i f f e r e n t s u r f a c t a n t c h a r a c t e r i s t i c s .
SOURCE: P G Industries,
P I n c . : Suggested F o r m u l a t i o n s
Metal Cleaners and Polishes 105
A1 umi num C l e a n e r C o n c e n t r a t e F-498
UhWeight
Water 75
Sodium M e t a s i l i c a t e (Anhydrous) 10
T e t r a Potassium Pyrophosphate (Powder) 5
Mona NF-10 10
Procedure:
D i s s o l v e sodium m e t a s i l i c a t e and t e t r a p o t a s s i u m p y r o p h o s p h a t e
i n w a t e r w i t h m i x i n g , t h e n add Mona N F - 1 0 .
Typical Properties:
Appearance : C l e a r 1 iq u i d
Cloud P o i n t : 8 8 C
Recommended Use D i l u t i o n : 1 t o 4 o z / g a l
Aluminum Wash F-499
% By Weiaht
Water 88
Sodium M e t a s i l i c a t e (Anhydrous) 2
T e t r a Sodium Pyrophosphate (Powder) 3
B u t y l Carbi t o 1 2
Mona N F - I 0 5
Procedure:
D i s s o l v e sodium m e t a s i l i c a t e and t e t r a sodium p y r o p h o s p h a t e
i n w a t e r , t h e n add B u t y l C a r b i t o l and Mona NF-10.
Typical Properties:
Appearance: C l e a r 1 iq u i d
pH: 1 2 . 8
Recommended Use D i l u t i o n : 1 : l O w i t h water
SOURCE: Mona I n d u s t r i e s , I n c . : Suggested F o r m u l a t i o n s
106 Advanced Cleaning Product Formulations
B u f f i nq Compound Remover
Component: %
Water 42.5
TEA 20.0
B u r c o t r o p e 1250 12.5
B u r c o s p e r s e LP 12.5
Borax 5.0
B u r c o TME 5.0
B u r c o LAF-6 5.0
Add components i n o r d e r l i s t e d . B l e n d u n t i l homogeneous between
each a d d i t i o n .
H o t A1 k a l in e P a i n t S t r i p p e r C o n c e n t r a t e
Compo n e n t s : a
45% KOH 67
K a s i l #1 32
B u r c o HCS-50 NF 1
Add components i n t h e o r d e r l i s t e d . B l e n d u n t i l homogeneous
bet