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Biocide MSDS avoid contacts with

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Biocide MSDS avoid contacts with

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									                        Material Safety Data Sheet
                                     IWE 2113
                                     Date issued: 01-06-2004


 1. IDENTIFICATION OF THE PREPARATION AND OF THE COMPANY

 Product Name:                       IWE 2113
 Application:                        Biocide


 Industrial Water Equipment
 124 North Parade
 Matlock Bath
 DE4 3NS

 TEL : 07775 661688



 2. COMPOSITION/INFORMATION ON INGREDIENTS
 CHEMICAL DESCRIPTION:
 Preparation containing: 5-chloro-2-methyl -4-isothiazolin-3-one, 2-Methyl-4-isothiazolin-3-one, Sodium
 nitrate in aqueous solution

 HAZARDOUS INGREDIENTS:
 CAS NO.      EINECS NO.             CHEMICAL NAME              WT %      SYMBOL      R-PHRASES
                                     Mixture:
 26172-55-4        2475007           5-chloro-2-methyl -4-      0.5-0.8              23/24/25,34,43,
                                     isothiazolin-3- one                                  50
 2682-20-4         2202396           2-Methyl-4-isothiazolin-             T,C,N
                                     3-one
 7631-99-4         2315543           Sodium nitrate             1-5       O                8


 3. HAZARD IDENTIFICATION

 HUMAN HEALTH HAZARDS - ACUTE:
 INHALATION:
 Corrosive to respiratory system.
 SKIN CONTACT:
 Causes burns. May cause sensitization by skin contact.
 EYE CONTACT:
 Causes burns.
 INGESTION:
 Corrosive, causes burns to gastro-intestinal tract. Nausea, vomiting and stomach pain may occur. In
 severe cases blood may be vomited.
 HUMAN HEALTH HAZARDS - CHRONIC:
 May cause sensitization by skin contact.




Material Safety Data Sheet
                        Material Safety Data Sheet
                                      IWE 2113
                                      Date issued: 01-06-2004


 4. FIRST AID MEASURES

 INHALATION:
 Remove to fresh air, rest, treat symptomatically. Obtain medical attention immediately.
 SKIN CONTACT:
 Speed is essential. Remove contaminated clothing. Wash off affected area immediately with plenty of
 water. Obtain medical attention immediately.
 EYE CONTACT:
 Speed is essential. Immediately gently irrigate with clean water for at least 15 minutes. Move eyeball
 and keep eyelids wide open and apart whilst irrigating. Obtain medical attention immediately.
 INGESTION:
 Do not induce vomiting without medical advice. If conscious washout mouth and give one pint of
 water to drink. Obtain medical attention immediately.
 ADDITIONAL INFORMATION
 Note to Physician: Probable mucosal damage may contraindicate the use of gastric lavage. Measures
 against circulatory shock, respiratory depression and convulsions may be needed.


 5. FIRE FIGHTING MEASURES
 EXTINGUISHING MEDIA:
 Use extinguishing media appropriate for surrounding fire.
 Water mist may be used to cool closed containers.
 FIRE AND EXPLOSION HAZARD
 Oxides of nitrogen, Oxides of sulphur, Oxides of carbon, Hydrogen chloride.
 SPECIAL PROTECTIVE EQUIPMENT FOR FIRE FIGHTING:
 In case of fire, wear a full face positive-pressure self contained breathing apparatus and protective
 suit.




 6. ACCIDENTAL RELEASE MEASURES

 PERSONAL PRECAUTIONS:
 Do not breathe vapour. Avoid contact with skin and eyes. In case of contact with eyes, rinse
 immediately with plenty of water and seek medical advice. After contact with skin, wash immediately
 with plenty of water.
 Ensure adequate ventilation. Use personal protective equipment recommended in Section 8.
 ENVIRONMENTAL PRECAUTIONS:
 Do not allow to enter sewers or water courses. If spillage does enter sewers or water courses,
 immediately inform the appropriate water authorities.
 METHODS FOR CLEANING UP:
 Soak up with inert absorbent material. Transfer contaminated material to suitable containers for
 disposal. Contaminated surfaces should be swabbed with deactivation solution, let stand for 30
 minutes and rinse thoroughly with clean water. DO NOT add deactivation solution to the waste
 container to deactivate the absorbed material. Do not use cotton waste, sawdust or other combustible
 substances as absorbent materials, these may ignite when dried out. * DEACTIVATION SOLUTION -
 prepare fresh a solution of 5% Sodium bicarbonate and 5% Sodium hypochlorite in water. Use at a
 ratio of 10 volumes decontamination solution per estimated volume of residual spill.



                        Material Safety Data Sheet

Material Safety Data Sheet
                                      IWE 2113
                                      Date issued: 01-06-2004


 7. HANDLING AND STORAGE

 Do not breathe vapour. Prevent contact with skin, eyes and clothing. Use with adequate ventilation.
 Avoid generating aerosols and mists.
 Discard contaminated shoes, belts and other articles made of leather. Skin reaction can be delayed
 and therefore wetting of the skin and/or clothes does not always give an indication of contamination.
 Treat all wetting of the skin and/or clothes which occurs during handling as contact with the product
 and administer first aid immediately.
 STORAGE CONDITIONS:
 Protect from freezing. Keep container tightly closed in a cool, well-ventilated place. Store separately
 from acids. Store away from: Combustible materials, Organic materials and reducing agents.



 8. EXPOSURE CONTROL/PERSONAL PROTECTION

 OCCUPATIONAL EXPOSURE LIMITS
 5-chloro-2-methyl -4-isothiazolin-3-one: Manufacturers Recommendation 0.076 mg/m 3 (TWA), 0.23
 mg/m 3 (STEL)
 2-Methyl-4-isothiazolin-3-one Manufacturers Recommendation 1.5 mg/m 3 (TWA), 4.5 mg/m 3 (STEL)
 ENGINEERING MEASURES Use general ventilation with local exhaust ventilation. Use a closed
 dosing system.
 RESPIRATORY PROTECTION: An approved respirator must be worn if the occupational exposure
 limit is likely to be exceeded. Selfcontained breathing apparatus.
 HAND PROTECTION: PVC gloves, Nitrile gloves
 SKIN PROTECTION: Apron and boots. Complete suit protecting against chemicals.
 EYE PROTECTION: Chemical splash goggles, face shield.
 HYGIENE RECOMMENDATIONS: Keep an eye wash fountain available. Keep a safety shower
 available. If clothing is contaminated, remove clothing and thoroughly wash the affected area. Launder
 contaminated clothing before reuse. Wash hands during breaks and at end of the shift.




 9. PHYSICAL AND CHEMICAL PROPERTIES

 NOTE: These physical properties are typical values for this product
 FORM: Liquid
 COLOUR: Clear
 RELATIVE DENSITY: 1.02 - 1.04
 SOLUBILITY IN WATER: Complete
 pH 4
 Abbreviation: NE = not evaluated, NA = not applicable, NR = not relevant




Material Safety Data Sheet
                        Material Safety Data Sheet
                                      IWE 2113
                                      Date issued: 01-06-2004


 10. STABILITY AND REACTIVITY

 STABILITY:
 Stable under ambient conditions.
 CONDITIONS TO AVOID:
 Extremes of temperature.
 MATERIALS TO AVOID:
 Oxidizing agents, Reducing agents.
 HAZARDOUS DECOMPOSITION PRODUCTS:
 Oxides of nitrogen, Oxides of sulphur, Oxides of carbon, Hydrogen chloride (under fire conditions).




 11. TOXICOLOGICAL INFORMATION
 Please refer to section 3 for hazards identification.
 SENSITIZATION:
 May cause sensitization by skin contact.
 CHRONIC TOXICITY DATA:
 A 90-day dietary study in dogs of 840 ppm of isothiazolinone resulted in no mortalities or pathological
 findings. A 90-day dermal study in rabbits of 0.4 mg/kg/day of isothiazolinone resulted in irritation but
 no pathological effects. A 30-month skin painting study with mice using 400 ppm isothiazolinone three
 times per week showed no increased tumor frequency over control. A teratology study with rabbits and
 rats was negative using dosages of 1.5 to 15 mg/kg isothiazolinone. Mutagenicity results have been
 equivocal.




 12. ECOLOGICAL INFORMATION

 MOBILITY AND BIOACCUMULATION POTENTIAL:
 The following results are for the active ingredient:
 log Kow = < 3
 Fish: BCF < 100
 ECOTOXICOLOGICAL EFFECTS:
 The following results are for the active ingredient:
 Bobwhite Quail 21-Day Oral LD50 = 85 mg/kg
 Bobwhite Quail 8-Day Dietary LC 50 = > 560 ppm
 Pekin Duck 8-Day Dietary LC50 = > 560 ppm
 LC50/6D/Lepomis macrochirus (Bluegill Sunfish)= 0.54 ppm
 LC50/6D/Oncorhynchus Mykiss (Rainbow Trout)= 0.14 ppm
 LC50/96H/Cyprinodon variegatus (Sheepshead Minnow)= 0.3 ppm
 LC50/48H/Daphnia magna (Water Flea) : 0.13 ppm
 LC50/96H/Mytilus edulis = 1.9 ppm
 Mytilus edulis NOEC: 0.40 ppm
 Mytilus edulis embryo/larvae, 48 Hour LC50 = 14 ppb
 Mytilus edulis embryo/larvae, NOEC: 3.2 ppb
 Eastern oyster 48 Hour LC„50„ = 28 ppb




Material Safety Data Sheet
                        Material Safety Data Sheet
                                     IWE 2113
                                     Date issued: 01-06-2004


 13. DISPOSAL CONSIDERATIONS

 Via authorized contractor. If this product becomes a waste, the final user must define and assign the
 appropriate European Waste Catalogue code.
 NATIONAL REGULATIONS UK
 In accordance with the Environmental Protection ( Duty of Care) Regulations 1991. Special Waste
 Regulations 1996 apply.




 14. TRANSPORT INFORMATION

 Class: 8 Packing Group: II
 Sea Transport: 8
 UN No: 3265
 Proper shipping name: CORROSIVE LIQUID, ACIDIC, ORGANIC,
 N.O.S. Contains: 5-chloro-2-methyl -4- isothiazolin-3-one, 2-Methyl-4-isothiazolin-3- one
 ADR/RID, H.I.n.: 80
 ADR/RID, No: 40 b)
 IMDG Page 8147-1
 EmS-Nr.: 8-15
 MFAG-Nr.: 760
 Marine pollutant: No
 Tariffcode: 38084090-90


 15. REGULATORY INFORMATION

 CLASSIFICATION:
 HAZARD SYMBOL: C, CORROSIVE




 C, CORROSIVE
 Contains: 5-chloro-2-methyl -4-isothiazolin-3-one, 2-Methyl-4-isothiazolin-3-one
 RISK PHRASES:
 R34 Causes burns. R43 May cause sensitization by skin contact.
 SAFETY PHRASES:
 S45 In case of accident or if you feel unwell, seek medical advice immediately (show the label where
 possible) S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical
 advice. S28 After contact with skin, wash immediately with plenty of water S36/37/39 Wear suitable
 protective clothing, gloves and eye/face protection.
 NATIONAL REGULATIONS UK
 COSHH regulations apply. A precaution card is available and should be displayed wherever this
 product is used and stored (Ref.Ciso).




Material Safety Data Sheet
                       Material Safety Data Sheet
                                    IWE 2113
                                    Date issued: 01-06-2004


 16. OTHER INFORMATION


 Relevant Risk Phrases:
 R8 Contact with combustible material may cause fire. R23/24/25 Toxic by inhalation, in contact with
 skin and if swallowed. R34 Causes burns. R43 May cause sensitization by skin contact. R50/53 Very
 toxic to aquatic organisms, may cause long term adverse effects in the aquatic environment.




 Emergency Telephone Number
 TEL : 07775 661688




Material Safety Data Sheet

								
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