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Material Safety Data Sheet Attached Glycerine

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Material Safety Data Sheet Attached Glycerine

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									        152 Kennedy Road South
           Brampton, Ontario
                Canada
               L6W 3G4

  General Inquiry Number: (905) 459-1232



Material Safety Data Sheet
         Attached
Cognis Oleochemicals Canada
Limited
                                                                            This product is distributed by Canada Colors and Chemicals Limited
                                                                            General Inquiry Phone Number: (905) 459-1232
                                                                            24 Hour Emergency Phone Number (416) 444-2112
Material Safety Data Sheet                                                                    465526
                                                                            CCC Product Code:______________________
                                                                                              EMERY 916 GLYCERINE 99.7% USP
                                                                            CCC Product Name:_______________________________________
                                                                                              <>

                                                                                                                                                 Page 1 of 7
                                                                                                                                 SDS no. : 245474
EMERY 916 GLYCERINE 99.7% USP                                                                                        Revision: 02/01/2008
                                                                                                                 printing date: 02/07/2008



  1. Chemical product and company identification
      Product name
         EMERY 916 GLYCERINE 99.7% USP
      Synonyms:
         1,2,3-Propanetriol
         Glycerol
      Product use:
         Various

      Supplier:
         Cognis Oleochemicals Canada Limited
         2290 Argentia Road
         Mississauga, ON             L5N 6H9
         Phone:        +1 (416) 259-3751

      Emergency Information Canutec:
        +1-613-996-6666




  2. Composition / information on ingredients
      General chemical description:
         Refined Glycerine

      COMPONENT:                           CAS-No.           Tox. Data                                       CONCENTRATION (Wt. %):
                                                             LD50 oral (rat): 27,200 mg/kg
      Glycerol                             56-81-5           LD50 dermal: No data                            >= 99.7 - <=100
                                                             LC50 inhalative: No data
                                                             LD50 oral: No data
      Water, decontaminated, desalinated   7732-18-5         LD50 dermal: No data                            >= 0 - <= 0.3
                                                             LC50 inhalative: No data



  3. Hazards identification
                                                     EMERGENCY OVERVIEW

                                      Low hazard for usual industrial or commercial handling.

      Delivery state:
        liquid

      State:
         liquid
         clear
Cognis Oleochemicals Canada
Limited

Material Safety Data Sheet

                                                                                                                Page 2 of 7
                                                                                                            SDS no. : 245474
EMERY 916 GLYCERINE 99.7% USP                                                                         Revision: 02/01/2008
                                                                                                  printing date: 02/07/2008

    Odor:
      odorless

    Color(s):
      colourless

    Routes of entry:
       Skin contact

    Potential Health Acute Effects:
    Inhalation:
       May cause respiratory irritation.

    Skin contact:
       not irritating

    Eye contact:
       May cause slight irritation.

    Ingestion:
       Considered practically non-toxic.

    Potential Chronic Health Effects:
       None known




4. First aid measures
    After inhalation:
       Move to fresh air, consult doctor if complaint persist.

    After skin contact:
       Wash thoroughly with soap and water.

    After eye contact:
       Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes.
       Do not rub eyes; mechanical action may cause corneal damage.
       If adverse health effects develop seek medical attention.

    After ingestion:
       Do not induce vomiting.
       Seek medical advice.
Cognis Oleochemicals Canada
Limited

Material Safety Data Sheet

                                                                                                   Page 3 of 7
                                                                                               SDS no. : 245474
EMERY 916 GLYCERINE 99.7% USP                                                            Revision: 02/01/2008
                                                                                     printing date: 02/07/2008

5. Fire fighting measures
    Flash point:
        390.02 °F (198.9 °C)
       ASTM D56;; Tagliabue Closed Cup

    Flammability:
       Not flammable.



    Flammable/Explosive limits:
       Lower limits:
        Not determined.
       Upper limits:
        Not determined.

    Suitable extinguishing media:
        Foam.
        Carbon dioxide.
        Dry Chemical
        Water Spray

    Unusual fire or explosion hazards:
       None known

    Hazardous combustion products:
       Carbon dioxide., carbon monoxide

    Additional fire fighting advice:
       In case of fire, keep containers cool with water spray.
       If a spill or leak has not ignited, use water spray to disperse the vapors.
       Water spray may be used to flush spills away from fire.




6. Accidental release measures
    Personal precautions:
       Wear adequate personal protective clothing and equipment.

    Environmental precautions:
       Add dry material to absorb spill (if large spill, dike to contain).

    Process for cleaning and take-up:
       Pick up spilled material and containerize for recovery or disposal.
       Flush area with water to remove residues.
Cognis Oleochemicals Canada
Limited

Material Safety Data Sheet

                                                                                                       Page 4 of 7
                                                                                                   SDS no. : 245474
EMERY 916 GLYCERINE 99.7% USP                                                               Revision: 02/01/2008
                                                                                        printing date: 02/07/2008


7. Handling and storage
     Handling:
     Handling advice:
        Ensure adequate ventilation.

     Storage:
     Storage conditions to keep:
        Store in a cool, dry place.
        Store in sealed original container.




8. Exposure controls / personal protection
     Indication for system design:
        Local exhaust ventilation recommended.


     Components with specific control parameters for workplace:

        Valid for       Canada

Name on list                     Basis        Type                           Value      Category      Remarks
GLYCERIN MIST                    CAD AB       Time Weighted Average (TWA).   10 mg/m3
                                 OEL
GLYCERIN MIST                    CAD ON       Time Weighted Average (TWA).   10 mg/m3
                                 OEL
GLYCERIN - MIST,                 CAD BC       Time Weighted Average (TWA).   3 mg/m3
RESPIRABLE                       OEL
GLYCERIN - MIST                  CAD BC       Time Weighted Average (TWA).   10 mg/m3
                                 OEL
GLYCERIN - MIST,                 CAD BC                                                              Listed.
RESPIRABLE                       OEL
GLYCERIN - MIST                  CAD BC                                                              Listed.
                                 OEL
GLYCÉRINE (BROUILLARDS)          OEL (QUE)    Time Weighted Average (TWA):   10 mg/m3

     Personal protection measures:
     Respiratory protection:
        Respirator with organic vapor cartridge.

     Hand protection:
        Protective gloves made of plastic.
Cognis Oleochemicals Canada
Limited

Material Safety Data Sheet

                                                                                                                Page 5 of 7
                                                                                                            SDS no. : 245474
EMERY 916 GLYCERINE 99.7% USP                                                                         Revision: 02/01/2008
                                                                                                  printing date: 02/07/2008

     Eye protection:
        Safety glasses with side shields.




9. Physical and chemical properties
     General description:
     Delivery state:                                      liquid
     State:                                               liquid
                                                          clear
     Odor:                                                odorless
     Color(s):                                            colourless


     Designation                                          Value                  Method
     Boiling point                                        290 °C (554°F)
     Melting point                                        18 °C (64.4 °F)
     Vapor pressure                                       < 0.001 mbar           no information
     Density                                              1.2607 g/cm3
     Solubility in Water                                  Complete, Soluble in   no information
                                                          All Proportions
     Analysis of Volatile matter                          0%                     no information
     Analysis of Volatile organic components              0%                     no information




10. Stability and reactivity
     Stability:
     Conditions to avoid:
        Avoid excessive heat.
        Keep away from sources of ignition and naked flames.

     Dangerous decomposition products:
        Carbon dioxide.
        carbon monoxide

     Decomposition advices:
        No decomposition if used according to specifications.

     Reactivity:
     Materials to avoid:
        Oxidizers
        Bases
        Strong Acids

     Hazardous polymerization:
        Will not occur
Cognis Oleochemicals Canada
Limited

Material Safety Data Sheet

                                                                                                                           Page 6 of 7
                                                                                                                      SDS no. : 245474
EMERY 916 GLYCERINE 99.7% USP                                                                                  Revision: 02/01/2008
                                                                                                           printing date: 02/07/2008



11. Toxicological information
    Acute oral toxicity:
       LD50 > 5000 mg/kg body weight

    Skin irritation:
       not irritating

    Eye irritation:
        slightly irritating
       Method: Draize test




12. Ecological information
    General ecological information:
       no data available




13. Disposal considerations

    Waste disposal of product:
      Dispose of in an approved landfill in accordance with federal, state / provincial and local regulations.




14. Transport information
    General information:
    Not hazardous according to RID, ADR, ADNR, IMDG, IATA-DGR, CFR and TDG.



15. Regulatory information
     This product has been classified in accordance with the hazard criteria of the Controlled Products Regulation (CPR), and
     the MSDS contains all the information required by the CPR.

     DSL Inventory Status:                  This product or all of its components are currently listed on the Domestic Substances
                                            List (DSL), as described under the Canadian Environmental Protection Act.
     WHMIS hazard class:                    none;
Cognis Oleochemicals Canada
Limited

Material Safety Data Sheet

                                                                                                                           Page 7 of 7
                                                                                                                      SDS no. : 245474
EMERY 916 GLYCERINE 99.7% USP                                                                                 Revision: 02/01/2008
                                                                                                          printing date: 02/07/2008


16. Other information

                                                  NFPA Rating (US)        Value
                                                  Health                  1
                                                  Fire                    1
                                                  Reactivity              0
                                                  Special Hazard

    Prepared by:
       Cognis Oleochemicals Regulatory Affairs; Phone: 513-482-2100



    All information, recommendations, and suggestions appearing herein concerning our product are based upon tests and
    data believed to be reliable. However, it is the user's responsibility to determine the safety, toxicity, and suitability for his
    own use of the product described herein. Since the actual use by others is beyond our control, no guarantee, express or
    implied, is being made as to the effects of such use, the results obtained, or the safety and toxicity of the product nor is
    their any assumed liability arising out of use, by others, of the product referred to herein. The information herein is not to
    be construed as absolutely complete since additional information may be necessary or desirable when particular or
    exceptional conditions or circumstances exist or because of applicable laws or government regulations.

								
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