Documents
Resources
Learning Center
Upload
Plans & pricing Sign in
Sign Out

MCR Chlorinated Rubber

VIEWS: 24 PAGES: 6

MCR Chlorinated Rubber

More Info
									                                                                                                              Revision:02
                                                                                                    Dated 31st March 2010
                                           MCR Chlorinated                                                    Page 1 of 6
                                              Rubber

                                Material Safety Data Sheet
             HAZARDOUS ACCORDING TO THE CRITERIA OF SAFE WORK AUSTRALIA
                           (Formerly ASCC, formerly NOHSC)

Section 1      Identification of the Preparation and the Company

Identification of the preparation
Product name: MCR Chlorinated Rubber
Product code:       None
Intended use:       Paint, surface coating

Identification of the Company
Manufacturer                               Supalux Paint Company Pty Ltd
                                           9 – 11 Tipping Road, Kewdale   1006 / 442 St. Kilda Road,
Address
                                           WA 6105                        Melbourne Vic 3004
                                           PO Box 151, Cloverdale         PO Box 608, South Melbourne
                                           WA 6895                        Vic 3205
Telephone                                  (08) 9353 2293                 (03) 9820 0207
Facsimile                                  (08) 9353 1131                 (03) 9820 0307
Australian emergency phone number          TOXFREE. Registration RDS0772
                                           Emergency Number 1800HAZMAT (1800 429 628)

                                           Poisons Information Centre. Phone (eg Australia 13 1126; New Zealand
                                           0800 764 766).


Section 2      Hazard Identification

 HAZARDOUS SUBSTANCE            The product is classified as hazardous according to the criteria of Safe Work Australia
                                (formerly the Australian Safety and Compensation Council (ASCC), formerly NOHSC)
 DANGEROUS GOOD                 The product is a Class 3 Flammable Liquid.
 CLASSIFICATION                 T Toxic
 RISK PHRASES                   R10 Flammable
                                R20/21 Harmful by inhalation and in contact with skin
                                R38 Irritating to skin.
                                R45 May cause cancer
                                R46 May cause heritable genetic damage
                                R64 May cause harm to breastfed babies.
                                R65 Harmful: May cause lung damage if swallowed.

 SAFETY PHRASES                 S24/25 Avoid contact with skin and eyes.
                                S45 In case of accident or if you feel unwell, seek medical advice immediately (show
                                the label where possible).
                                S53 Avoid exposure-obtain special instructions before use.
                                S60 This material and its container must be disposed of as hazardous waste
                                S61 Avoid release to the environment.
                                                                                                                Revision:02
                                                                                                      Dated 31st March 2010
                                             MCR Chlorinated                                                    Page 2 of 6
                                                Rubber


Section 3       Composition/Information on Ingredients

 Name                                                                     CAS Number                  Concentration
 Xylene                                                                   1330-20-7                       20-30%
 Chlorinated rubber                                                       Not available                   10-20%
 Iron oxide                                                               1317-60-6                       15-20%
 Barium sulphate                                                          7727-43-7                       10-20%
 Alkanes, chloro-, C14-17 (plasticiser)                                   85535-85-9                       5-15%
 Magnesium silicate                                                       1343-88-0                        5-15%
 Propylene glycol monomethyl ether                                        107-98-2                          3-5%
 Solvent naphtha (petroleum) light aromatic                               64742-95-6                        3-5%
 Propylene oxide                                                          75-56-9                        0.05-0.2%
 Ingredients not classified as hazardous or at concentrations lower                                       Balance
 than the cut-offs specified by Safe Work Australia



Section 4       First-aid Measures

EYES: Hold eyelids open and rinse the eye continuously with a gently stream of clean running water for at least fifteen
minutes. Seek medical attention.
SKIN: Remove contaminated clothing and wash thoroughly with soap and water. Use water alone, if soap is unavailable.
Apply a moisturising hand cream, if available. Seek medical attention if any soreness or inflammation of the skin persists
or develops later. Launder affected clothing before re-use.
INGESTION: NEVER GIVE AN UNCONSIOUCS PERSON ANYTHING TO DRINK NOR ATTEMPT TO INDUCE
VOMITING. If the person is conscious, rinse mouth out with water ensuring that mouthwash is not swallowed. Give about
250mL (2 glasses) of water to drink. DO NOT attempt to induce vomiting. Seek URGENT medical attention. For advice,
contact TOXFREE on 1800HAZMAT (1800 429 628) or a Poisons Information Centre (phone eg Australia 131 126; New
Zealand 0800 764 766).
INHALATION: Remove to fresh air. Keep warm and at rest. If breathing is laboured, hold in a half upright position (this
assists respiration). Apply artificial respiration if breathing has stopped. Seek medical attention. URGENT medical
attention is required if over-exposure has been severe.
ADVICE TO DOCTOR: Treat symptomatically. Advise Doctor of the presence of liquid hydrocarbons. Gastric lavage
should only be undertaken after endotracheal intubation because of the risk of aspiration.




Section 5        Fire-fighting Measures

EXTINGUISHING MEDIA: Extinguish using foam, carbon dioxide or dry chemical extinguishers. Water may be used to
cool fire-exposed containers but is not suitable for fire fighting.
HAZARDOUS COMBUSTION PRODUCTS: May evolve carbon monoxide, carbon dioxide, oxides of nitrogen or chlorine
compounds if incompletely burned in a fire situation.
PRECAUTIONS: Fire fighters should wear self-contained breathing apparatus and full protective clothing.




Section 6        Accidental Release Measures

Ensure that there are no sources of ignition present. Remove unnecessary personnel from the affected area.
Wear protective equipment as specified for handling. Cover with an absorbent such as earth, sand or a commercial oil
absorber. Sweep up and collect in sealable containers. Dispose to approved landfill.

Contaminated rags or other combustible materials may be liable to spontaneous ignition.
                                                                                                               Revision:02
                                                                                                     Dated 31st March 2010
                                             MCR Chlorinated                                                   Page 3 of 6
                                                Rubber


Section 7       Handling and Storage

Avoid any contact with the skin or eyes. Avoid breathing vapours.
This product is a flammable liquid. Keep potential sources of ignition away when using open containers, mixing, applying
and drying. Vapours from this product may form explosive mixtures in air, particularly in confined spaces. Care should be
taken to avoid the risk of electrostatic ignition.

Store in cool, dry area, away from heat, sparks and open flame. Depending on quantities involved, store as Dangerous
Goods of Class 3. Refer to the relevant State regulations for requirements. Keep containers sealed when not in use.
Store away from oxidising agents. Refer to AS 1940 - The storage and handling of flammable and combustible liquids




Section 8        Exposure Controls / Personal Protection

EXPOSURE STANDARDS
                                                              3
Xylene: TWA 80ppm, 350mg/m3, STEL 150ppm, 655mg/m
Propylene glycol monomethyl ether: TWA 100ppm, 369mg/m3, STEL 150ppm, 553mg/m3
                                                              3
Solvent naphtha (petroleum) light aromatic: TWA 480mg/m
                                         3
Propylene oxide: TWA 20ppm, 48mg/m
         Exposure standards represent airborne concentrations of individual chemical substances, which, according to
         current knowledge, should neither impair the health of, nor cause undue discomfort to, nearly all workers.
         Except where modified by consideration of excursion limits, exposure standards apply to long term exposure to a
         substance over an eight-hour day, for a five-day working week, over an entire working life.
         Except for short-term exposure limits (STELs), or where a peak value has been assigned, the exposure
         standards for airborne contaminants are expressed as a time-weighted average (TWA) concentration of that
         substance over an eight-hour working day, for a five-day working week.
         From: Adopted National Exposure Standards for Atmospheric Contaminants in the Occupational Environment
         [NOHSC:1003(1995)]
ENGINEERING CONTROLS: Prevent spark formation created by static electricity, by earthing vessels. When using this
product, all electrical equipment should be consistent with the requirements of AS 2430.1 and AS 2430.3, (Classification
of Hazardous Areas), and AS 3000, (SAA Wiring Rules). Use in well ventilated areas to prevent vapour build up. Use
mechanical and/or natural ventilation to ensure that solvent vapour levels are maintained below the recommended
exposure standard. Refer to AS 1940 - The storage and handling of flammable and combustible liquids and AS 2430 -
Explosive gas atmospheres for further information concerning ventilation requirements.
PERSONAL PROTECTION:
Respirator Type (AS 1716) - An air supplied respirator is required for all spray painting applications and a half face
respirator with particulate and organic solvent vapour filter may be required for other uses unless the work area is well
ventilated. In confined spaces use air supplied breathing apparatus. N.B. TAKE THE LIMITS OF ABSORPTION
CAPACITY INTO ACCOUNT. CHANGE FILTERS REGULARLY.
Eye Protection - Eye protection is required to prevent splashing in the eyes, eg. Safety glasses with side shields or
chemical goggles. Wear full-face shield if mixing or pouring operations pose risk of splashes. An eye wash station is
suggested as a good work place practice.
Glove Type - Wear nitrile, viton, neoprene or other similar solvent resistant gloves to keep skin contact to a minimum.




Section 9       Physical and Chemical Properties

  Appearance                                     Viscous liquid with a strong, solvent odour
  Melting Point                                  -480C (based on xylene)
                                                            0
  Boiling Point                                  136 – 145 C (based on xylene)
  Vapour Pressure                                8 mmHg @ 250C (based on xylene)
  Specific Gravity                               1.5
  Flash Point                                    250C Closed Cup (based on xylene)
  Lower Flammable. Limit LEL                     1.1%
  Upper Flammable. Limit UEL                     7.0%
  Solubility in Water                            Insoluble
  Volatile Component                             <50%
                                                           0
  Auto ignition Temp.                            430 - 520 C (based on xylene)
                                                                                                               Revision:02
                                                                                                     Dated 31st March 2010
                                               MCR Chlorinated                                                 Page 4 of 6
                                                  Rubber


Section 10         Stability and Reactivity

CHEMICAL STABILITY: Product is considered stable under normal handling conditions. However, heating may cause
flammable vapours to be evolved. Product will burn if exposed to heat or ignition sources.
CONDITIONS TO AVOID: Avoid all sources of ignition such as open flames, sparks, hot surfaces or burning cigarettes.
INCOMPATIBLE MATERIALS: The product may react with strong oxidising agents.
HAZARDOUS DECOMPOSITION PRODUCTS: Oxides of nitrogen and carbon, chlorine compounds, chlorine.
HAZARDOUS REACTIONS; None known




Section 11         Toxicological Information

HEALTH HAZARDS ACUTE
INGESTION: Moderately toxic. Tends to break up into foam if the patient vomits and there is the potential for aspiration
into the lungs to occur. This can result in chemical pneumonitis.
EYE Direct eye contact may cause moderate to severe irritation. The vapour is irritating to the eyes.
SKIN: Irritating. Contact with the product may defat the skin and contribute to dermatitis.
INHALATION: Inhalation of solvent vapour may cause nose and throat irritation. Overexposures are irritating to the
respiratory system. Inhalation may also result in nervous system effects such as dizziness, nausea, headache and
sleepiness. In extreme cases loss of consciousness may result
HEALTH HAZARDS CHRONIC
Prolonged and/or repeated skin contact may lead to irritant contact dermatitis. Prolonged and repeated over-exposure
may result in liver and kidney damage. Alkanes, chloro-, C14-17 may accumulate in body tissues and fluids rich in lipid
content hence may cause harm to breastfed babies
Solvent naphtha (petroleum) light aromatic and propylene oxide have been classified by Safe Work Australia as
Category 2 i.e. Probable Human Carcinogens. Probable human carcinogens are those substances for which there is
sufficient evidence to provide a strong presumption that human exposure might result in the development of cancer. This
evidence is generally based on appropriate long-term animal studies, limited epidemiological evidence or other relevant
information. However, the composition of petroleum solvents may vary significantly and the solvents included in this
product may not fall within this classification but without further information, this cannot be confirmed.
Xylene has been classified by the International Agency for Research on Cancer (I.A.R.C.) in Group 3 i.e. not classifiable
as to their carcinogenicity to humans.

 Xylene:                                              LD50 (oral-rat): 4300 mg/kg.
                                                      LC50 (inhaled, rat): 5000-ppm/4 hour.
                                                      LD50 (skin, rabbit): >1700mg/Kg.
 Solvent naphtha (petroleum) light aromatic:          LD50 (oral, rat): 8400mg/Kg

 PGME                                                 LD50 (oral-rat): 5660mg/Kg
                                                      LD50 (skin, rabbit): 13g/Kg
                                                      LC50 (inhaled, rat): 10000ppm/5H.
 Propylene oxide                                      LD50 (oral-rat): 380 mg/kg.
                                                      LC50 (inhaled, rat): 4000-ppm/8 hour.
                                                      LD50 (skin, rabbit): >1700mg/Kg.
                                                      Draize test, Rabbit, eye: 20mg/24H Moderate
                                                      Draize test, Rabbit, skin: 50mg/6M Severe
                                                                                                                   Revision:02
                                                                                                         Dated 31st March 2010
                                               MCR Chlorinated                                                     Page 5 of 6
                                                  Rubber


Section 12         Ecological Information

MOBILITY: Rubber, iron oxide, barium sulphate, magnesium silicate, and titanium dioxide components sink in water but
the solvents in this product are expected to float or dissolve in water. Highly mobile. May contaminate groundwater.
The solvents in this product are expected to have moderate to high mobility in soils based upon experimental Koc values
obtained with a variety of soils at differing pH values and organic carbon content. Volatilisation from moist soil surfaces is
expected based on experimental Henry's Law constants.
PERSISTANCE / DEGRADABILITY: Alkanes, chloro are hazardous to the aquatic environment. Rubber, iron oxide,
barium sulphate, magnesium silicate, and titanium dioxide components will persist but the solvents are readily
biodegradable. Based upon experimental vapour pressures, the solvents in this product are expected to exist entirely in
the vapour phase in the ambient atmosphere. Vapour-phase solvents are degraded in the atmosphere by reaction with
photo chemically produced hydroxyl radicals with an estimated atmospheric lifetime of about 1-2 days. Biodegradation is
an important environmental fate process for these solvents. In general, it has been found that these solvents are
biodegraded in soil and groundwater samples under aerobic conditions and may be degraded under anaerobic
denitrifying conditions. Solvents are not expected to absorb on sediments.
BIOACCUMULATION: Does not bioaccululate significantly. The potential for bioconcentration in aquatic organisms is
low based on an experimental BCF values of 20 or less.




Section 13         Disposal Considerations

Dispose to landfill or by controlled incineration in chemical waste disposal area in accordance with relevant
Commonwealth, State and Territory regulations. Empty containers may contain product residue, including flammable or
explosive vapours. Do not cut, puncture or weld on or near containers. All label warnings must be observed until the
containers have been cleaned or reconditioned.




Section 14        Transport Information

Proper Shipping Name: PAINT
UN Number: 1263
DG Class
         ADG: Class 3 - Road and Rail Transport
         IATA Classification: Class 3 – Air Transport.
         IMDG Reference: Class 3.3 – Sea Transport.
Packing Group: III
Hazchem Code: 3[Y]
Transport: Flammable liquids shall not be loaded in the same vehicle or packed in the same freight container with:
Class 1 Explosives
Class 2.1 Flammable Gases (if both are in tanks or other receptacles with a capacity individually exceeding 500L)
Class 3.2 Toxic Gases
Class 4.2Spontaneously Combustible Substances
Class 5.1 Oxidising Agents
Class 5.2 Organic Peroxides or
Class 7 Radioactive Materials.




Section 15        Regulatory Information

Product is a Scheduled 5 Poison (S5) according to the Standard for the Uniform Scheduling of Drugs and Poisons
(SUSDP).
AICS: Listed
Dangerous Goods Initial Emergency Response Guide (HB 76 2004): 14
                                                                                                                  Revision:02
                                                                                                        Dated 31st March 2010
                                              MCR Chlorinated                                                     Page 6 of 6
                                                 Rubber


Section 16        Further Information

REFERENCES
 List of Designated Hazardous Substances [NOHSC: 10005 (1999)]
 National Code of Practice for the Preparation of Material Safety Data Sheets 2nd Edition [NOHSC: 2011(2003)]
 Exposure Standards for Atmospheric Contaminants in the Occupational Environment [NOHSC: 1003(1995)] and
   subsequent amendments
 Australian Code for the Transportation of Dangerous Goods by Road and Rail (ADG Code), 7th Edition, 2007
 Australian/New Zealand Standard AS/NZS 1715, Selection, use and maintenance of respiratory protective devices
 Australian/New Zealand Standard AS/NZS 1716, Respiratory protective devices
 Australian/New Zealand Standard AS/NZS 1337- Eye protectors for industrial applications
 Australian/New Zealand Standard AS/NZS 2161 Occupational protective gloves - selection, use and maintenance.
 Australian Standard AS 1940 - The storage and handling of flammable and combustible liquids

ABBREVIATIONS
  BCF                  Bio Concentration Factor
  KOW                  Octanol-water partition coefficient
  LC50                 Lethal dose for 50% of test population, by inhalation.
  LDLo                 Lowest documented lethal dose
  LD50                 Lethal dose for 50% of test population, by ingestion or skin contact
  TDLo                 Lowest published toxic dose

This information Is for guidance only without warranty, representation, inducement or licence of any kind, except that it is
obtained from sources believed to be accurate at the date of issue. Recommendations/information are offered in good
faith, but no warranty is implied or expressed.

 Revision Number: 002
 Dated 31 March 2010

								
To top