Mass Transfer Coefficient
Mass transfer coefficients - simplified method to describe complex boundary condition involving flow and diffusion.
Mass transfer from a surface to a fluid
Mass Transfer Coefficient
Flux from surface into the fluid: Ci 1 Niy y 0 Dij dS S A y y 0
-Brackets denote a spatial average. -S is the surface area in the direction of the flux (plane of constant y = 0 in this case). Now, we define an empirical equation describing the flux: N iy y 0 k f (C s C0 ) kf unit = m/s. kf is not an intrinsic property of the system.
Ci 1 Dij dS Equating these two relations: kf S S Co S C y y 0
Mass Transfer Coefficient
Non-dimensionalization:
Ci C C s C0
*
y y L
*
Results:
kf L
1 C * * dS y Dij S s y* 0
A new parameter: Sherwood number
kf L
vL Sh f (Re, Sc) f ( , ) Dij Dij
Mass Transfer Coefficient
• Determine Sh experimentally for different system. (Table 7.5) • Estimate flux using the Sh number.
– Flux at wall for flat plate= Dij Cs C0 Sh L
Estimation of Flux in the Presence of Convection In many mass transfer problems with convection, the concentration gradient is confined to a thin “boundary layer” of thickness M (M <