Physics 102: Lecture 22 Quantum Mechanics: Blackbody Radiation, Photoelectric Effect, Wave-Particle Duality Hour Exam 3 • Monday, Nov 16 • Covers – Lectures through Lecture 21 – Homework through HW 10 – Discussions through Disc 10 – Labs through Lab 8 • No review session Recap. • Interference: Coherent waves – Full wavelength difference = Constructive – ½ wavelength difference = Destructive • Multiple Slits – Constructive d sin(q) = m l (m=1,2,3…) – Destructive d sin(q) = (m + 1/2) l 2 slit only – More slits = brighter max, darker mins • Huygens‟ Principle: Each point on wave front acts as coherent source and can interfere. (see Lab 8) • Single Slit: – Destructive: w sin(q) = m l (m=1,2,3…) – Resolution: Max from 1 at Min from 2 50 State of Late 19th Century Physics • Two great theories – Newton‟s laws of mechanics, including gravity – Maxwell‟s theory of electricity & magnetism, including propagation of electromagnetic waves • But…some unsettling experimental results calls into question these theories – Einstein and relativity – The quantum revolution Quantum Mechanics! • At very small sizes the world is VERY different! – Energy is discrete, not continuous. – Everything is probability; nothing is for certain. – Particles often seem to be in two places at same time. – Looking at something changes how it behaves. 5 Three Early Indications of Problems with Classical Physics • Blackbody radiation • Photoelectric effect • Wave-particle duality Blackbody Radiation Hot objects glow (toaster coils, light bulbs, the sun). As the temperature increases the color shifts from Red to Blue. The classical physics prediction was completely wrong! (It said that an infinite amount of energy should be radiated by an object at finite temperature.) Blackbody Radiation Spectrum Visible Light: ~0.4mm to 0.7mm Higher temperature: peak intensity at shorter l Blackbody Radiation: First evidence for Q.M. Max Planck found he could explain these curves if he assumed that electromagnetic energy was radiated in discrete chunks, rather than continuously. The “quanta” of electromagnetic energy is called the photon. Energy carried by a single photon is E = hf = hc/l Planck‟s constant: h = 6.626 X 10-34 Joule sec Preflights 22.1, 22.3 A series of light bulbs are colored red, yellow, and blue. Which bulb emits photons with the most energy? Blue! Lowest wavelength is highest energy. E = hf = hc/l The least energy? 80% correct! Red! Highest wavelength is lowest energy. Which is hotter? (1) stove burner glowing red (2) stove burner glowing orange Hotter stove emits higher-energy photons (lower wavelength = orange) ACT: Photon A red and green laser are each rated at 2.5mW. Which one produces more photons/second? 1) Red 2) Green 3) Same # photons Energy/second Power Power second Energy/photon Energy/photon hf Red light has less energy/photon so if they both have the same total energy, red has to have more photons! 33 Nobel Trivia For which work did Einstein receive the Nobel Prize? 1) Special Relativity E=mc2 2) General Relativity Gravity bends Light 3) Photoelectric Effect Photons 4) Einstein didn‟t receive a Nobel prize. 12 Photoelectric Effect • Light shining on a metal can “knock” electrons out of atoms. • Light must provide energy to overcome Coulomb attraction of electron to nucleus • Light Intensity gives power/area (i.e. Watts/m2) – Recall: Power = Energy/time (i.e. Joules/sec.) 25 Photoelectric Effect: Light Intensity • What happens to the rate electrons are emitted when increase the brightness? • What happens to max kinetic energy when increase brightness? Demo Photoelectric Effect: Light Frequency • What happens to rate electrons are emitted when increase the frequency of the light? • What happens to max kinetic energy when increase the frequency of the light? Photoelectric Effect Summary • Each metal has “Work Function” (W0) which is the minimum energy needed to free electron from atom. • Light comes in packets called Photons –E=hf h=6.626 X 10-34 Joule sec • Maximum kinetic energy of released electrons – K.E. = hf – W0 30 Quantum Physics and the Wave- Particle Duality I. Is Light a Wave or a Particle? • Wave – Electric and Magnetic fields act like waves – Superposition: Interference and Diffraction • Particle – Photons – Collision with electrons in photo-electric effect BOTH Particle AND Wave II. Are Electrons Particles or Waves? • Particles, definitely particles. • You can “see them”. • You can “bounce” things off them. • You can put them on an electroscope. • How would know if electron was a wave? Look for interference! Young‟s Double Slit w/ electron • JAVA d Source of monoenergetic L electrons 2 slits- separated Screen a distance by d L from slits 41 Electrons are Waves? • Electrons produce interference pattern just like light waves. – Need electrons to go through both slits. – What if we send 1 electron at a time? – Does a single electron go through both slits? 43 ACT: Electrons are Particles • If we shine a bright light, we can „see‟ which hole the electron goes through. (1) Both Slits (2) Only 1 Slit But now the interference is gone! 45 Electrons are Particles and Waves! • Depending on the experiment electron can behave like – wave (interference) – particle (localized mass and charge) • If we don’t look, electron goes through both slits. If we do look it chooses 1. I’m not kidding it’s true! 46 Schrödinger's Cat • Place cat in box with some poison. If we don‟t look at the cat it will be both dead and alive! Poison 46 More Nobel Prizes! • 1906 J.J. Thompson – Showing cathode rays are particles (electrons). • 1937 G.P. Thompson (JJ‟s son) – Showed electrons are really waves. • Both were right! 47 Quantum Summary • Particles act as waves and waves act as particles • Physics is NOT deterministic • Observations affect the experiment – (coming soon!) 49 See you Wednesday!
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