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									                                                                                        Last update November 2009

                                                              Address: ICCOM-CNR
                                                                       Area di Ricerca di Firenze, room C158
Luca Gonsalvi                                                          Via Madonna del Piano 10
                                                                       50019 Sesto Fiorentino (FI), Italy (EU)
Born 23rd November 1968; Italian, male, married               Email:   l.gonsalvi@iccom.cnr.it
www.iccom.cnr.it/gonsalvi/                                    Phone: +39 055 5225251
                                                              Fax:    +39 055 5225203
  Keywords: homogeneous multiphase catalysis (oxidation, hydrogenation, carbonylation, hydroformylation);
   heterogenised catalysts; catalytic mechanisms; PGM organometallic chemistry; ligand design; chemical
   kinetics; green chemistry; HP-NMR and HP-IR spectroscopy.

Education and Research
Research Staff (permanent, collaborations Dr. Maurizio Peruzzini, Dr. Claudio Bianchini)
Istituto di Chimica dei Composti Organometallici, Area di Ricerca CNR di Firenze (ICCOM-CNR), Sesto
Fiorentino, Firenze, Italy, 2001-present
   Research Lines: (a) Synthesis of novel water soluble transition metal cyclopentadienyl complexes
     [(C5R5)MX(PTA)2] (R = H, Me; M = Ru, Re, Rh, Ir; X = H, halogen, solvent; PTA = 1,3,5-triaza-7-
     phosphaadamantane) and use as regioselective catalysts for hydrogenation of unsaturated substrates in
     aqueous biphasic conditions (b) Selective homogeneous oxidations of benzothiophene derivatives for
     ODS. (c) P4 chemical activation via mono- and bimetallic complexes (d) Synthesis of novel H-storage
     materials.
Post-doctoral Research Assistant (Supervisor Prof. Dr. Roger A. Sheldon)
Delft University of Technology (TUD) and IOP Catalysis, The Netherlands, 1999-2001
   Research Project: Catalytic oxidation of ethers and acetals to esters. Development and optimisation of highly
     selective oxidation protocols for the catalytic conversion of ethers and acetals to esters with high atom
     efficiency and low E-factor, using oxygen/air, hydrogen peroxide and other cheap oxidants (i.e.
     hypochlorite), under homogeneous, heterogeneous, biphasic conditions.
Doctor of Philosophy – Organometallic Chemistry and Catalysis (Supervisors Dr. Anthony Haynes, Prof.
Peter M. Maitlis FRS) University of Sheffield and BP Chemicals, United Kingdom, 1996-1999.
 Research Project: “Ligand Effects on Homogeneous Methanol Carbonylation”. Synthesis of chelated
   complexes [M(CO)I(LL)] (M = Rh, Ir; LL = PS, PP, PO, NN bidentate ligands) and kinetic studies of oxidative
   addition and migratory insertion in the reaction with MeI as models for stereoelectronic ligand effects in
   methanol carbonylation.
Contract Research Assistant (Supervisors Prof. Giovanni Predieri, Prof. Mirco Costa)
Department of General and Inorganic Chemistry, University of Parma, Italy, 1994.
 Research Project: Study of catalytic properties of xerogel-bonded ruthenium clusters. Synthesis of organically-
   modified materials by sol-gel process; binding of ruthenium clusters and application in alkyne hydrogenation
   and olefin hydroformylation processes.
Laurea in Chimica (Supervisors Prof. Giovanni Predieri, Prof. Antonio Tiripicchio)
University of Parma, Italy (B. Sc. Hons Chemistry, 5 years course, 12 months research project), 1987-1993.
 Research Project: “New hybrid inorganic-organic materials from sol-gel process. Applications in catalysis and
   precious metals recovery”. Synthesis of thiourea-modified silica by sol-gel process, binding of Rh(I) and
   Pd(II) and application in alkyne hydrogenation and olefin hydroformylation. Use of the materials as stationary
   phase for selective extraction of Pd(II), Rh(I), Ru(III), Ag(I), Pt(IV) from acidic aqueous solutions.

Technical Skills
      Schlenk, vacuum and inert-atmosphere manipulation of moderate air, moisture sensitive organometallic
     and organic compounds.  Liquid phase NMR including multi-nuclear, variable temperature, sapphire tube
     HP-NMR.  Fischer-Porter apparatus and Parr autoclaves.  Synthesis of heterogenised catalysts via LDH
     and modified silica.  Fully conversed in GC, GC-MS, HPLC techniques and HP-IR, IR, UV-vis
     spectroscopy.  Non-standard analytical techniques (SEM, XRF).  Solvent and reagent purification, product
     isolation using vacuum distillation, crystallization or sublimation.  Graphic design, molecular visualization
     (Chemdraw, Chem3D, ISIS Draw)  Detailed knowledge and use of MS Office and other packages (PC and
     Macintosh).  On-line multimedia presentations for progress report and meetings.
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                                                                                    Last update November 2009

Teaching and Supervisor Activity
    Scientific supervision of two postdoctoral projects (FP6 MC-RTN Aquachem), ICCOM-CNR, 2004-2007;
    Scientific supervision of three postdoctoral projects (FP5 MC-RTN Hydrochem), ICCOM-CNR, May 2003-
    present; Full supervision of a short term secondment project, ICCOM-CNR, 2002; Full supervision of a
                                                                                       rd
    IAESTE 3-months stage undergraduate project, TUD, 2001; Co-supervision of a 3 year undergraduate
    project, University of Sheffield, 1999; Three years demonstrating in inorganic chemistry undergraduate
    teaching laboratories, University of Sheffield, 1996-1999; Tutorship and teaching General and Inorganic
    Chemistry to undergraduate Chemistry students, University of Parma, 1992-1994. Co-supervision of
    undergraduate final year projects in Inorganic Chemistry, University of Parma, 1994; Demonstrating and
    teaching in inorganic and analytical chemistry undergraduate teaching laboratories, University of Parma,
    1992-1994.

Other Activities
-   Member elected of Scientific Committee of ICCOM (2009-2011)
-   AQUACHEM Network Manager, Transition Metal Chemistry and Catalysis in Aqueous Media
      th
    6 Framework Program Research Training Network Project n° MRTN-CT-2003-503864, 2004-2008.
-   Responsible for CNR projects DG.RSTL.020.004 (Valorisation of Inorganic Feedstocks) and strategic
    module PM03.005.001 (Hydrogen production and Storage)
-   Responsible for Joint Mobility Project Italy-USA 2008-2010 (joint reviewed), Ministry for Foreign Affairs.
                                       th
-   Scientific Secretary of EWPC-6, 6 European Workshop on Phosphorus Chemistry, Florence 26-27/3/2009.
-   Proposal co-writer in FP7 (MC-ITN “MADOC”) submitted for evaluation on September 2008
-   Referee for Inorg. Chim. Acta, Inorg. Chem. Commun., Eur. J. Inorg. Chem., J. Organomet. Chem.
-   Liaison manager and proposal co-writer for a Network of Excellence in Sustainable Development via
    Catalytic Technology (SusDeCat) under the EC Framework Project 6.
-   Italian National Service, 12 months, 1995
-   Languages: English (fluent), Spanish (advanced), Dutch (basic), French (basic), Italian (native).

Awards and Memberships

Awards, Fellowships
-  University of Sheffield Turner Prize for best Chemistry PhD Thesis, 2000.
-  IOP Catalysis Postdoctoral Fellow, Dutch Ministry for Economic Affairs, 1999-2001.
-  BP Chemicals Doctoral Studentship, 1996-1999.
Professional Affiliations
-   Member, Royal Society of Chemistry (MRSC), 1997-2005

Reference

Em. Prof. Dr. Roger A. Sheldon                                 Dr. Anthony Haynes
Laboratory for Biocatalysis and Organic Chemistry              Department of Chemistry
Delft University of Technology                                 University of Sheffield
Julianalaan 136                                                Sheffield S3 7HF, England
2628 BL Delft, The Netherlands                                 Tel:     +44 (0)114 222 9326
Tel: +31 15 2782675                                            Fax:     +44 (0)114 273 8673
Fax: +31 15 2781415                                            E-mail: a.haynes@sheffield.ac.uk
Email: R.A.Sheldon@tnw.tudelft.nl

Em. Prof. P. M. Maitlis FRS                                    Dr. Glenn J. Sunley
Department of Chemistry                                        BP Amoco Chemicals Ltd.
University of Sheffield                                        Hull Research and Technology Centre
Sheffield S3 7HF, England                                      Saltend, Hull, HU12 8DS, England
Tel: +44 (0)114 222 9320                                       Tel.:   +44 1482 892570
Fax: +44 (0)114 273 8673                                       Fax:    +44 1482 892945
E-mail: p.maitlis@sheffield.ac.uk                              E-mail: SunleyG@BP.com




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                                                                                            Last update November 2009


Publications

1.    Gutsul, E. I.; Rossin, A.; Belkova, N. V.; Epstein, L. M.; Gonsalvi, L.; Lledós, A.; Lyssenko, K. A.; Peruzzini,
      M.; Zanobini, F.; Shubina, E. S.
                        3
      Protonation of (k -NP3)Ir(H)3 [NP3 = N(CH2CH2PPh2)3] by HBF4 and fluorinated alcohols: a combined
      experimental and DFT analysis of the reaction process
      to be submitted
2.    Di Credico, B.; Gonsalvi, L.; Peruzzini, M.; Reginato, G.; Rossin, A.
      Selective Synthesis of 2-Substituted 4-Carboxy Oxazoles, Thiazoles and Thiazolidines from Serine or
      Cysteine Amino Acids
      to be submitted
3.    Caporali, M.; Gonsalvi, L.; Rossin, A.; Peruzzini, M.
      P4 activation by Late Transition Metals
      submitted
4.    Caporali, M.; Gonsalvi, L.; Zanobini, F.; Peruzzini, M.
      Synthesis of the Water Soluble phosphine PTA [PTA=1,3,5-triaza-7-Phosphatricyclo[3.3.1.1]decane]
      Inorg. Synth. 2009, accepted
5.    Caporali, M.; Gonsalvi, L.; Zanobini, F.; Peruzzini, M.
      Synthesis of the Water Soluble Bidentate (P,N) Ligand PTN(Me) [PTN(Me) = 7-Phospha-3-methyl-1,3,5-
      triazabicyclo[3.3.1]nonane]
      Inorg. Synth. 2009, accepted
6.    Bravo Bernardez, J.; Bolaño, S.; Gonsalvi, L.; Peruzzini, M.
      Coordination chemistry of 1,3,5-Triaza-7-phosphaadamantane (PTA) and derivatives. Part II. The quest for
      tailored ligands, complexes and related applications.
      Coord. Chem. Rev. 2009, DOI: 10.1016/j.ccr.2009.08.006 [article]
7.    Di Credico, B.; Fabrizi de Biani, F.; Gonsalvi, L.; Guerri, A.; Ienco, A.; Laschi, F.; Reginato, G.; Rossin, A.;
      Zanello, P.; Peruzzini, M.
      Cyclopentadienyl Ruthenium(II) Complexes with Bridging Alkynylphosphine Ligands.
      Chem. Eur. J. 2009, 15, 11985 – 11998 [article]
8.    Bolaño, S.; Plaza, M.; Bravo, J.; Castro, J.; Peruzzini, M.; Gonsalvi, L.; Ciancaleoni, G.; Macchioni, A.
      New Highly Water-Soluble Rhodium Complexes Bearing 1,3,5-Triaza-7-phosphaadamantane (PTA) and/or
      Tris(hydroxymethyl) phosphine (THP)
      Inorg. Chim. Acta 2009, DOI: 10.1016/j.ica.2009.05.041 [article]
9.    Rossin, A.; Caporali, M.; Gonsalvi, L.; Guerri, A.; Lledos, A.; Peruzzini, M.; Zanobini, F.
      Selective B-H vs. N-H bond activation in ammonia borane by [Ir(dppm)2][OTf]
      Eur. J. Inorg. Chem., 2009, 3055-3059 [article]
10.   Servin, P.; Laurent, R.; Gonsalvi, L.; Tristany, M.; Peruzzini, M.; Majoral, J.-P.; Caminade, A.-M.
      Grafting of water-soluble phosphines to dendrimers and their use in catalysis: positive dendritic effects in
      aqueous media
      Dalton Trans. 2009, 4432 - 4434 [article]
11.   Legrand, F.-X.; Hapiot, F.; Tilloy, S.; Guerriero, A.; Peruzzini, M.; Gonsalvi, L.; Monflier, E.
      Aqueous rhodium-catalyzed hydroformylation of 1-decene in the presence of randomly methylated -
      cyclodextrin and 1,3,5-triaza-7-phosphaadamantane derivatives
      Appl. Catal. A: Gen. 2009, 362, 62-66 [article]
12.   Renfrew, A. K.; Phillips, A. D.; Egger, A.; Hartinger, C. G.; Bosquain, S. S.; Nazarov, A. A.; Keppler, B. K.;
      Gonsalvi, L.; Peruzzini, M.; Dyson, P. J.
      Influence of structural variation on the anticancer activity of RAPTA-type complexes: ptn versus pta
      Organometallics 2009, 28, 1165–1172 [article]
13.   Caporali, M.; Barbaro, P.; Bolaño, S.; Gonsalvi, L.; Mañas Carpio, S.; Peruzzini, M.
      NMR studies on the novel heterobimetallic complexes [M(dppm)(Ph2PCH2PPh2PPPP){Pt(PPh3)2}]OTf (M =
      Rh, Ir) derived from the stepwise activation of white phosphorus

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                                                                                           Last update November 2009
      Magn. Res. Chem. 2008, 46, S120-S125 [article]
14.   Rossin, A; Ienco, A.; Costantino, F.; Montini, F.; Di Credico, B.; Caporali, M.; Gonsalvi, L; Fornasiero, P.;
      Peruzzini, M.
      Crystal-to-crystal phase transition and CO2 adsorption properties of polymeric magnesium formate
      Cryst. Growth Des. 2008, 8, 3302–3308 [article]
15.   Caporali, M.; Bianchini, C.; Bolaño, S.; Bosquain, S. S.; Gonsalvi, L.; Oberhauser, W.; Rossin, A.;
      Peruzzini, M.
                                          1        2
      Synthesis and characterisation of k -P and k -P,N palladium(II) complexes of the open cage water soluble
      aminophosphine PTN
      Inorg. Chim. Acta 2008, 361, 3017-3023 [article]
16.   Bolaño, S.; Albinati, A.; Bravo, J.; Caporali, M.; Gonsalvi, L.; Male, L.; Rodriguez-Rocha, M.; Rossin, A.;
      Peruzzini, M.
      Synthesis and Reactivity of Rhodium(III) Pentamethylcyclopentadienyl Complexes of N–B–PTA(BH3). X-
                                                                                            2
      ray crystal structures of [Cp*RhCl2(N–B–PTA(BH3)] and [Cp*Rh{N–B–PTA(BH3)}( -CH2=CHPh)]
      J. Organomet. Chem. 2008, 693, 2397–2406 [article]
17.   Ciclosi, M.; Dinoi, C.; Gonsalvi, L.; Peruzzini, M.; Manoury, E.; Poli, R.
      Oxidation of thiophene derivatives with H2O2 in acetonitrile catalyzed by [Cp*2M2O5] (M = Mo, W): a kinetic
      study
      Organometallics 2008, 27, 2281–2286 [article]
18.   Caporali, M.; Barbaro, P.; Gonsalvi, L.; Ienco, A.; Yakhvarov, D.; Peruzzini, M.
      Heterobimetallic cooperation mediates the transformation of white phosphorus into zwitterionic catena-
                    (+)             (-)
      phosphonium diphosphenide ligands
      Angew. Chem. Int. Ed. 2008, 47, 3766-3768 [article]; Angew. Chem. 2008, 120, 3826-3828 [article]
19.   Yakhvarov, D.; Peruzzini, M.; Caporali, M.; Gonsalvi, L.; Midollini, S.; Orlandini, A.; Ganushevich, Y.;
      Sinyashin, O.
      Bimetallic activation of white phosphorus
      Phosphorus, Sulfur, and Silicon 2008, 183, 487–493 [article]
20.   Bolaño, S.; Ciancaleoni, G.; Bravo, J.; Gonsalvi, L.; Macchioni, A.; Peruzzini, M.
      PGSE NMR studies on RAPTA derivatives: evidence for the formation of H-bonded dicationic species
      Organometallics 2008, 27, 1649-1652 [article]
21.   Erlandsson, M.; Landaeta, V. R.; Gonsalvi, L.; Peruzzini, M.; Phillips, A. D.; Dyson, P.J.; Laurenczy, G.
      Methylcyclopentadienyl iridium PTA complexes and their application in catalytic water phase carbon
      dioxide hydrogenation (PTA = 1,3,5-triaza-7-phosphaadamantane)
      Eur. J. Inorg. Chem. 2008, 620-627 [article]
22.   Erlandsson, M.; Gonsalvi, L.; Ienco, A.; Peruzzini, M.
      Diastereomerically enriched analogues of the water soluble phosphine PTA. Synthesis of phenyl-(1,3,5-
                                       3,7
      triaza-7-phosphatricyclo [3.3.1.1 ]dec-6-yl)methanol (PZA) and the Sulfide PZA(S) and X-ray Crystal
      Structures of the Oxide PZA(O) and [Cp*IrCl2(PZA)]
      Inorg. Chem. 2008, 47, 8-10 [article]
23.   Bolaño, S.; Bravo, J.; Castro, J.; Rodriguez-Rocha, M.; Guedes da Silva, M. F. C.; Pombeiro, A. J. L.;
      Gonsalvi, L.; Peruzzini, M.
      Synthesis, reactivity, x-ray crystal structures and electrochemical behavior of tris(pyrazolyl)borate
      ruthenium(II) complexes of PTA (PTA = 1,3,5-triaza-7-phosphaadamantane)
      Eur. J. Inorg. Chem. 2007, 5523-5532 [article]
24.   Bosquain, S. S.; Dorcier, A.; Dyson, P. J.; Erlandsson, M.; Gonsalvi, L.; Laurenczy, G.; Peruzzini, M.
      Aqueous phase carbon dioxide and bicarbonate hydrogenation catalysed by cyclopentadienyl ruthenium
      complexes
      Appl. Organomet. Chem. 2007, 21, 947-951 [article]
25.   Ciardi, C.; Romerosa, A., Serrano-Ruiz, M.; Gonsalvi, L.; Peruzzini, M.; Reginato, G.
      Synthesis of New Enantiomerically Enriched -Hydroxy, -Amino Phosphines by Selective Transformation
      of Naturally Occurring Amino Acids
      J. Org. Chem. 2007, 72, 7787 - 7789 [article]
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                                                                                                Last update November 2009

26.   Rossin, A.; Gonsalvi, L.; Phillips, A. D.; Maresca, O.; Lledos, A.; Peruzzini, M.
      Water-assisted H-H bond splitting mediated by [CpRu(PTA)2Cl] (PTA=1,3,5-triaza-7-
      phosphaadamantane). A DFT analysis.
      Organometallics 2007, 26, 3289-3296 [article]
27.   Best, J.; Wilson, J. M.; Adams, H.; Gonsalvi, L.; Peruzzini, M.; Haynes, A.
      Reactivity of Rh(I) iminophosphine carbonyl complexes with methyl iodide
      Organometallics 2007, 26, 1960-1965 [article]
28.   Le Roux, E.; Malacea, R. ; Manoury, E. ; Poli, R. ; Gonsalvi, L. ; Peruzzini, M.
      Highly efficient asymmetric hydrogenation of alkyl aryl ketones catalyzed by iridium complexes with chiral
      planar ferrocenyl phosphino-thioether ligands
      Adv. Synth. Catal. 2007, 349, 309-313 [article]
29.   Pelagatti, P.; Bacchi, A.; Balordi, M.; Caneschi, A.; Giannetto, M.; Pelizzi, C.; Gonsalvi, L.; Peruzzini, M.;
      Ugozzoli, F.
      Ligand driven geometry switch in octahedral and trigonal bipyramidal iron complexes containing (H)PNO
      and PNN ligands
      Eur. J. Inorg. Chem. 2007,162-171 [article]
30.   Gutkin, V.; Gun, J.; Prikhodchenko, P. V.; Lev, O.; Gonsalvi, L.; Peruzzini, M.; Romerosa, A.; Campos
      Malpartida, T.; Lidrissi, C.
      Electrooxidation of ruthenium cyclopentadienyl PTA complexes in DMF: ESI-MS, cyclic voltammetry and
      on-line electrochemistry/ESI-MS studies
      J. Electrochem Soc. 2007, 154, F7-F15 [article]
31.   Landaeta, V. R.; Gonsalvi, L.; Peruzzini, M.
      Ruthenium catalyzed selective oxidation of aryl thiophenes using hydrogen peroxide
      J. Mol. Catal. A: Chem. 2006, 257, 112-117 [article].
32.   Dorcier, A.; Ang, W. H.; Bolaño, S.; Gonsalvi, L.; Juillerat-Jeannerat, L.; Laurenczy, G.; Peruzzini, M.;
      Phillips, A. D.; Zanobini, F.; Dyson, P. J.
      In vitro evaluation of rhodium and osmium RAPTA analogues: the case for organometallic anticancer
      drugs not based on ruthenium
      Organometallics 2006, 25, 4090-4096 [article].
33.   Yakhvarov, D.; Barbaro, P.; Gonsalvi, L.; Mañas Carpio, S.; Midollini, S.; Orlandini, A.; Peruzzini, M.;
      Sinyashin, O.; Zanobini, F.
      A snapshot of P4 tetrahedron opening: Rh and Ir mediated bimetallic activation of white phosphorus
      Angew. Chem. Int. Ed. 2006, 45, 4182-4185 [article]. Angew. Chem. 2006, 118, 4288-4291
34.   Pelagatti, P.; Bacchi, A.; Balordi, M.; Bolaño, S.; Calbiani, F.; Elviri, L.; Gonsalvi, L.; Pelizzi, C.; Peruzzini, M.;
      Rogolino, D.
      Octahedral Ru(II) complexes with [PNO] hydrazonic ligands. Synthesis, structure, reactivity and catalytic
      activity in the addition of benzoic acid to alkynes
      Eur. J. Inorg. Chem. 2006, 2422-2436 [article]
35.   Phillips, A. D.; Bolaño, S.; Bosquain, S. S.; Daran, J.-C.; Malacea, R.; Peruzzini, M.; Poli, R.; Gonsalvi, L.
                                    1        2
      A new class of rhodium(I) k -P and k -P,N complexes with rigid PTN(R) ligands (PTN = 7-phospha-3-
      methyl 1,3,5-triazabicyclo[3.3.1]nonane)
      Organometallics 2006, 25, 2189-2200. [article]
36.   Bolaño, S.; Albinati, A.; Bravo, J.; Gonsalvi, L.; Peruzzini, M.
      Borane adducts of the water soluble phosphine PTA (PTA = 1,3,5-triaza-7-phosphaadamantane)
      Inorg. Chem. Commun. 2006, 9, 360-363 [article].
37.   Bolaño, S.; Gonsalvi, L.; Barbaro, P.; Albinati, A.; Rizzato, S.; Gutsul, E.; Belkova, N.; Epstein, L.; Shubina,
      E.; Peruzzini, M.
      Synthesis, characterization, protonation studies and X-ray crystal structure of ReH5(PPh3)2(PTA) (PTA =
      1,3,5-triaza-7-phosphaadamantane)
      J. Organomet. Chem. 2006, 691, 629-637 [article]
38.   Andrieu, J.; Camus, J.-M. ; Richard, P.; Poli, R.; Gonsalvi, L.; Vizza, F.; Peruzzini, M.

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                                                                                           Last update November 2009
      Amino-phosphanes in RhI-Catalyzed Hydroformylation: Hemilabile Behavior of P,N Ligands under High CO
      Pressure and Catalytic Properties
      Eur. J. Inorg. Chem. 2006, 51-61 [article].
39.   Peruzzini, M.; Gonsalvi, L.; Romerosa, A.
      Coordination Chemistry and Functionalization of White Phosphorus via transition metal complexes
      Chem. Soc. Rev. 2005, 34, 1038 -1047 [article].
40.   Akbayeva, D. N.; Moneti, S.; Peruzzini, M.; Gonsalvi, L.; Ienco, A.; Vizza, F.
      On the Protonation of Ruthenium-PTA Complexes in Water. X-ray crystal structure of RuCl4(PTAH)2 4H2O
      (PTA = 1,3,5-triaza-7-phosphaadamantane)
      C. R. Chimie 2005, 8, 1491-1496. [article]
41.   Lidrissi, C.; Romerosa, A.; Saoud, M.; Serrano-Ruiz, M.; Gonsalvi, L.; Peruzzini, M.
      Stable, water soluble PTA based Ru-Ag organometallic polymers
      Angew. Chem. Int. Ed. 2005, 44, 2568-2572. Angew. Chem. 2005, 117, 2624-2628 [article]
42.   Mantovani, N.; Brugnati, M.; Gonsalvi, L.; Grigiotti, E.; Laschi, F.; Marvelli, L.; Peruzzini, M.; Reginato, G.;
      Rossi, R.; Zanello, P.
      Synthesis, characterization and electrochemical behavior of mono- and bimetallic Ru and Re allenylidenes
      bearing multiconjugated organic spacers
      Organometallics 2005, 24, 405-418. [article]
43.   Bolaño, S.; Gonsalvi, L.; Zanobini, F.; Vizza, F.; Bertolasi, V.; Romerosa, A.; Peruzzini, M.
      Water soluble ruthenium cyclopentadienyl and aminocyclopentadienyl PTA complexes as catalysts for
      selective hydrogenation of -unsaturated olefins. (PTA = 1,3,5-triaza-7-phosphaadamantane)
      J. Mol. Catal. A: Chem. 2004, 224, 61-70. [article]
44.   Phillips, A. D.; Gonsalvi, L.; Romerosa, A.; Vizza, F.; Peruzzini, M.
      Coordination chemistry of 1,3,5-Triaza-7-phosphaadamantane (PTA). Transition metal complexes and
      related catalytic, medicinal and photo-luminescent applications
      Coord. Chem. Rev. 2004, 248, 955-993 [article]
45.   Ciardi, C.; Reginato, G.; Gonsalvi, L.; de los Rios, I.; Romerosa, A.; Peruzzini, M.
      Ruthenium(II) -alkyne and vinylidene complexes derived from glycoynitols: new precursors for water
      soluble unsaturated carbenes
      Organometallics 2004, 23, 2020-2026. [article]
46.   Baucherel, X.; Gonsalvi, L.; Arends, I. W. C. E.; Ellwood, S.; Sheldon, R. A.
      Aerobic oxidation of cycloalkanes, alcohols and ethylbenzene catalyzed by the novel carbon radical chain
      promoter NHS (N-hydroxy saccharin)
      Adv. Synth. Catal. 2004, 346, 286-296. [article]
47.   Gonsalvi, L.; Arends, I. W. C. E.; Moilanen, P.; Sheldon, R. A.
      The effect of pH control on the selective ruthenium-catalyzed oxidation of ethers and alcohols with sodium
      hypochlorite
      Adv. Synth. Catal. 2003, 345, 1321-1328. [article]
48.   Bianchini, C.; Gonsalvi, L.; Oberhauser, W.; Seméril, D.; Brüggeller, P; Gutmann, R.
      Schulz-Flory oligomerisation of ethylene by the binuclear nickel(II) complex Ni2Cl4[cis, trans, cis-1,2,3,4-
      tetrakis-(diphenylphosphino)cyclobutane]
      Dalton Trans. 2003, 3869 - 3875. [article]
49.   Saoud, M.; Romerosa, A.; Mañas Carpio, S.; Gonsalvi, L.; Peruzzini, M.
      Ruthenium-catalysed selective transetherification of substituted vinyl ethers to acetals and aldehydes
      Eur. J. Inorg. Chem. 2003, 1614-1619. [article]
50.   Gonsalvi, L.; Gaunt, J. A.; Adams, H.; Castro, A.; Sunley, G. J.; Haynes, A.
      Quantifying steric effects of -diimine ligands. Oxidative addition of MeI to Rh(I) and migratory insertion in
      Rh(III) complexes
      Organometallics 2003, 22, 1047-1054. [article]
51.   Akbayeva, D. N.; Gonsalvi, L.; Oberhauser, W.; Peruzzini, M.; Vizza, F.; Brüggeller, P.; Romerosa, A.;
      Sava, G.; Bergamo, A.

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                                                                                            Last update November 2009
      Synthesis, catalytic properties and biological activity of new water soluble ruthenium cyclopentadienyl PTA
      complexes [(C5R5)Ru(PTA)2Cl] (R = H, Me; PTA = 1,3,5-triaza-7-phosphaadamantane)
      Chem. Commun. 2003, 264-265. [article]
52.   Gonsalvi, L.; Adams, H.; Sunley, G. J.; Ditzel E.; Haynes, A.
      Steric and electronic effects on the reactivity of Rh and Ir complexes containing P-S, P-P and P-O ligands;
      implications for the effects of chelate ligands in catalysis
      J. Am. Chem. Soc. 2002, 124, 13597-13612. [article]
53.   Gonsalvi, L.; Arends, I. W. C. E.; Sheldon, R. A.
      Selective ruthenium-catalyzed oxidation of 1,2:4,5-di-O-isopropylidene--D-fructopyranose and other
      alcohols with NaOCl
      Org. Lett. 2002, 4, 1659-1561. [article]
54.   Gonsalvi, L.; Arends, I. W. C. E.; Sheldon, R. A.
      Highly efficient use of NaOCl in the Ru-catalysed oxidation of aliphatic ethers to esters
      Chem. Commun. 2002, 202-203. Also quoted in Chem. Br. Perspectives, April 2002. [article]
55.   Gonsalvi, L.; Adams, H.; Sunley, G. J.; Ditzel E.; Haynes, A.
      A Dramatic Steric Effect on the Rate of Migratory CO Insertion on Rhodium
      J. Am. Chem. Soc. 1999, 121, 11233-11234. [article]
56.   Cauzzi, D.; Costa, M.; Gonsalvi, L.; Pellinghelli, M. A.; Predieri, G.; Tiripicchio A.; Zanoni, R.
      Anchoring rhodium(I) on thiourea-functionalized silica xerogels and silsesquioxanes.
      Part II. Matrix effects on the selectivity in the hydroformylation of styrene
      J. Organomet. Chem. 1997, 541, 377-389. [article]


Patents

1.    Sheldon, R. A.; Gonsalvi, L.; Arends, I. W. C. E.; Kühnle, A.; Jost, C.; Fries, G.; Neumann, M.
      Process for the oxidation of organic compounds, e.g. for production of esters from ethers, uses a liquid
      multi-phase ruthenium catalyst system and an oxygen atom donor and is carried out using an aqueous
      phase of neutral or alkaline pH
      German Patent DE 10163579A1 (2003), to Degussa. [espacenet]


Conferences

1.    Mirabello, V.; Caporali, M.; Gonsalvi, L.; Peruzzini, M.
      Reactivity of White Phosphorus with Mononuclear Complexes of Ruthenium
                             th
      FIGIPAS 10th, The 10 International Meeting in Inorganic Chemistry
      Palermo, Italy, 1-4 July 2009
2.    Malacea, R.; Routaboul, L.; Vincendeau, S.; Poli, R.; Daran, J.-C.; Manoury, E.; Le Roux, E.; Gonsalvi, L.;
      Peruzzini, M.; Hayes, J. M.; Ujaque, G.; Lledos, A.
      New Planar Chiral Ferrocenyl P,S Ligands for Asymmetric Catalysis
                             th
      FIGIPAS 10th, The 10 International Meeting in Inorganic Chemistry
      Palermo, Italy, 1-4 July 2009
3.    Rossin, A.; Giambastiani, G.; Giannasi, A.; Gonsalvi, L.; Ienco, A.; Peruzzini, M; Ulivi, L.; Ziparo, C.; Zoppi,
      M.
      Phase transitions and H2 uptake by H[Mg(HCOO)3] NHMe2
      MOFCAT2009 Workshop, MOFs on the Road to Applications
      Oslo, Norway, 17-19 June 2009
4.    Rodriguez-Rocha, M.; Bolaño Garcia, S.; Bravo Bernardez, J.; Castro Fojo, J.; Gonsalvi, L.; Peruzzini, M.
      Reactivity of [TpRuCl(PTA)(PPh3)] with Alkynes and Propargylic Alcohols
       th
      6 European Symposium of Phosphorus Chemistry (EWPC-6)
      Firenze, Italy, 26-27 March 2009
5.    Yakhvarov, D. G.; Peruzzini, M.; Gonsalvi, L.; Caporali, M.; Ganushevich, Y.; Morozov, V.; Sinyashin, O.
      Electrochemical Properties of Co, Rh And Ir Complexes bearing Oligophosphorus Ligands

                                                                                                                    7
                                                                                          Last update November 2009
       th
      6 European Symposium of Phosphorus Chemistry (EWPC-6)
      Firenze, Italy, 26-27 March 2009
6.    Caporali, M.; Barbaro, P.; Gonsalvi, L.; Ienco, A.; Zanobini, F.; Peruzzini, M.; Yakhvarov, D. G.
      Zwitterionic Catena-Phosphonium(+)Diphosphenide(-) Ligands from Stepwise Activation of White
      Phosphorus
       th
      6 European Symposium of Phosphorus Chemistry (EWPC-6)
      Firenze, Italy, 26-27 March 2009
7.    Rossin, A.; Costantino, F.; Di Credico, B.; Fornasiero, P.; Gonsalvi, L.; Ienco, A.; Montini, T.; Peruzzini, M.
      Phase transitions and CO2 adsorption of polymeric magnesium formate
      MOF08, 1st International Conference on Metal-Organic Frameworks and Open Framework Compounds
      Augsburg, Germany, 8-10 October 2008
8.    Gonsalvi, L.; Peruzzini, M.
      How to teach an old dog new tricks: the renaissance of the water soluble phosphine PTA (1,3,5-triaza-7-
      phosphaadamantane) and its analogues (oral communication)
      ISHC XVI, 16th International Symposium on Homogeneous Catalysis
      Florence, Italy, 7-11 July 2008
9.    Guerriero, A.; Erlandsson, M.; Ienco, A.; Reginato, G.; Peruzzini, M.; Gonsalvi, L.
      Synthesis of diastereomerically enriched analogues of the water soluble phosphine PTA and use in
      catalytic hydrogenations
      ISHC XVI, 16th International Symposium on Homogeneous Catalysis
      Florence, Italy, 7-11 July 2008
10.   Urbina-Blanco, C. A.; Landaeta, V. R.; Erlandsson, M.; Peruzzini, M.; Gonsalvi, L.
      Indenyl iridium(iii) complexes bearing the water soluble phosphine PTA (PTA = 1,3,5-triaza-7-
      phosphaadamantane)
      ISHC XVI, 16th International Symposium on Homogeneous Catalysis
      Florence, Italy, 7-11 July 2008
11.   Rossin, A.; Kovacs, G.; Lledos, A.; Gonsalvi, L.; Peruzzini, M.
      Homolytic Vs. Heterolytic Water-Assisted Dihydrogen Splitting By Ru(II)-PTA Complexes: A DFT Analysis
      of the reaction mechanism (PTA = 1,3,5-Triaza-7-Phosphaadamantane)
      ISHC XVI, 16th International Symposium on Homogeneous Catalysis
      Florence, Italy, 7-11 July 2008
12.   Malacea, R.; Routaboul, L.; Vincendeau, S.; Poli, R.; Daran, J.-C.; Manoury, E.; Le Roux, E.; Gonsalvi, L.;
      Peruzzini, M.; Hayes, J. M.; Ujaque, G.; Lledos, A.
      Asymmetric Hydrogenation of ketones catalyzed by Iridium complexes of Ferrocenyl P,S ligands
      ISHC XVI, 16th International Symposium on Homogeneous Catalysis
      Florence, Italy, 7-11 July 2008
13.   Di Credico, B.; Fabrizi de Biani, F.; Gonsalvi, L.;Guerri, A.; Ienco, A.; Laschi, F.; Peruzzini, M.; Reginato,
      G.; Rossin, A.; Zanello, P.
      Reactivity studies of cyclopentadienyl ruthenium(II) complexes towards alkynylphosphine ligands
                         th
      COGICO 2008, 9 Italian Congress of Organometallic Chemistry
      Perugia, Italy, 25-28 June 2008
14.   Guerriero, A.; Coletti, C.; Gonsalvi, L.; Marvelli, L.; Re, N.; Reginato, G.; Peruzzini, M.
      NMR and DFT studies on the nucleophilic addition of phosphines to C(gamma)-activated rhenium
      allenylidenes
                         th
      COGICO 2008, 9 Italian Congress of Organometallic Chemistry
      Perugia, Italy, 25-28 June 2008
15.   Coletti, C.; Guerriero, A.; Gonsalvi, L.; Marvelli, L.; Re, N.; Peruzzini, M.
      A DFT study on the electronic structure of rhenium allenylidenes and their reactivity towards phosphines
                         th
      COGICO 2008, 9 Italian Congress of Organometallic Chemistry
      Perugia, Italy, 25-28 June 2008
16.   Rossin, A.; Gonsalvi, L.; Kovacs, G.; Lledos, A.; Peruzzini, M.
      A combined experimental and DFT approach to the analysis of dihydrogen activation By by water-soluble
      ruthenium complexes

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                                                                                       Last update November 2009
                       th
      COGICO 2008, 9 Italian Congress of Organometallic Chemistry
      Perugia, Italy, 25-28 June 2008
17.   Dinoi, C.; Ciclosi, M.; Vincendeau, S.; Poli, R.; Gonsalvi, L.; Peruzzini, M.
      Efficient oxidation of thiophene derivatives catalyzed by organomolybdenum and tungsten oxido
      complexes
      235th ACS National Meeting, Cotton Memorial Symposium
      New Orleans, LA, 6-10 April 2008.
18.   Caporali, M.; Bianchini, C.; Gonsalvi, L.; Oberhauser, W.; Peruzzini, M.
      Synthesis and characterisation of Rh(I), Ru(II) and Pd(II) complexes of the open cage water soluble
      aminophosphine PTN
      5th European Workshop on Phosphorus Chemistry
      Regensburg, Germany, 10-11 March 2008.
19.   Gonsalvi, L.; Peruzzini, M.
      Aqueous phase catalysis, organometallic reactivity and much more: the renaissance of the water soluble
      monodentate phosphine PTA
      CIAM Workshop – Catalysis in Aqueous Media (Plenary Lecture)
      Toulouse, France, 30 November-1 December 2007
20.   Erlandsson, M.; Landaeta, V. R.; Bosquain, S. S.; Dorcier, A.; Phillips, A. D.; Dyson, P.J.; Laurenczy, G.;
      Gonsalvi, L.; Peruzzini, M.
      Comparative studies for the catalytic wate pahse carbon dioxide hydrogenation using iridium and
      ruthenium PTA complexes (PTA=1,3,5-triaza-7-phospha-adamantane)
      CIAM Workshop – Catalysis in Aqueous Media
      Toulouse, France, 30 November-1 December 2007
21.   Servin, P.; Laurent, R.; Gonsalvi, L.; Peruzzini, M.; Majoral, J.-P.; Caminade, A.-M.
      PTA ligands as end groups of water-soluble phosphorus dendimers. Use of their Ru(II) complexes as
      catalysts
      CIAM Workshop – Catalysis in Aqueous Media
      Toulouse, France, 30 November-1 December 2007
22.   Mallqui Ayala, I. M.; Gonsalvi, L.; Peruzzini, M.; Romerosa, A.; Serrano-Ruiz, M.
      Catalytic hydrogenations in water phase using ruthenium(II) complexes bearing sulfonated phosphines and
      diamines
      CIAM Workshop – Catalysis in Aqueous Media
      Toulouse, France, 30 November-1 December 2007
23.   Landaeta, V. R.; Erlandsson, M.; Vasquez-Perez, M. E.; Urbina-Blanco, C. A.; Phillips, A. D.; Gonsalvi, L.;
      Peruzzini, M.
      Synthesis and characterisation of novel iridium complexes with water-soluble phosphine ligands
      CIAM Workshop – Catalysis in Aqueous Media
      Toulouse, France, 30 November-1 December 2007
24.   Caporali, M.; Gonsalvi, L.; Ienco, A.; Peruzzini, M.; Yakhvarov, D. G.
      Double activation of white phosphorus mediated by diphosphine complexes of Group 8 metals and Pt(0)
      moieties
       th
      6 ISOC International School of Organometallic Chemistry
      Camerino, Italy, 8-12 September 2007
25.   Bosquain, S. S.; Dorcier, A.; Dyson, P. J.; Erlandsson, M.; Gonsalvi, L.; Laurenczy, G.; Peruzzini, M.
      Aqueous phase carbon dioxide and bicarbonate hydrogenation catalysed by cyclopentadienyl ruthenium
      complexes
       th
      6 ISOC International School of Organometallic Chemistry
      Camerino, Italy, 8-12 September 2007
26.    Mallqui Ayala, I. M.; Serrano Ruiz, M.; Romerosa, A.; Gonsalvi, L.; Peruzzini, M.
      Synthesis and reactivity of water soluble allenylidene ruthenium complexes bearing Cp(CONC(CH3)3)2
      ligand and PPh3, PTA, mPTA and TPPMS
        th
       6 ISOC International School of Organometallic Chemistry
       Camerino, Italy, 8-12 September 2007


                                                                                                               9
                                                                                         Last update November 2009
27.   Servin, P.; Tristany, M.; Laurent, R.; Caminade, A.-M.; Majoral, J.-P.; Gonsalvi, L.; Peruzzini, M.
      Ru(II) catalysis in the presence of water with a PTA dendritic ligand
       th
      5 IDS – International Dendrimer Symposium
      Toulouse, France, 28 August – 1 September 2007
28.   Malacea, R.; Routaboul, L. ; Vincendeau, S.; Poli, R.; Daran, J.-C; Manoury, E. ; Le Roux E., Gonsalvi L.,
      Peruzzini M.; Hayes, J. M.; Ujaque, G.; Lledos, A.
      Asymmetric Hydrogenation Of Ketones Catalysed By Iridium Complexes of Planar Chiral Phosphane
      Thioether Ligands
       nd
      2 German-French Congress in Organic Chemistry and Biomolecular Chemistry
      Calvi, France, 30 June - 5 July 2007
29.   Dinoi, C.; Gonsalvi, L.; Peruzzini, M.; Poli, R.
      Binuclear Cyclopentadienyl Oxo Molybdenum and Tungsten Complexes as Catalysts for Aryl Thiophenes
      Oxidation using H2O2
       rd
      3 International Conference on Green and Sustainable Chemistry
      Delft, The Netherlands, 1-5 July 2007
30.   Peruzzini, M.; Akbayeva, D. N.; Barbaro, P.; Caporali, M.; Di Vaira, M.; Gonsalvi, L.; Midollini, S.;
      Sinyashin, O.; Seniori Costantini, S.; Stoppioni, P.; Yakhvarov, D.
      New Pathways in metal-mediated P4 activation
       th
      9 FIGIPAS Meeting in Inorganic Chemistry
      Vienna, Austria, 4-7 July 2007
31.   Mallqui Ayala, I. M.; Gonsalvi, L.; Peruzzini, M.; Romerosa, A.; Serrano Ruiz, M.
      Water phase catalytic hydrogenations with ruthenium(II) complexes bearing sulfonated phosphines and
      diamines
       th
      9 FIGIPAS Meeting in Inorganic Chemistry
      Vienna, Austria, 4-7 July 2007
32.   Servin, P.; Tristany, M.; Laurent, R.; Caminade, A.-M.; Majoral, J.-P.; Gonsalvi, L.; Peruzzini, M.
      Water soluble dendritic catalysts
       th
      9 FIGIPAS Meeting in Inorganic Chemistry
      Vienna, Austria, 4-7 July 2007
33.   Yakhvarov, D. V.; Peruzzini, M.; Caporali, M.; Barbaro, P.; Gonsalvi, L.; Midollini, S.; Orlandini, A.;
      Zanobini, F.; Ganushevich, Y.; Sinyashin, O.
      Bimetallic Activation of White Phosphorus
      17th International Conference on Phosphorus Chemistry (ICPC-17)
      Xiamen, China, 15-19 April 2007
34.   Rossin A., Gutsul E., Peruzzini M., Gonsalvi L., Reginato G., Giambastiani G., Bianchini C.
      Hydrogen storage with MOFs and transition metal borohydride complexes
      IDECAT Workshop “Catalysis for Sustainable Energy Production”
      Sesto Fiorentino, Italy, 29 November – 1 December 2006
35.   Peruzzini M., Gonsalvi L., Romerosa A.
      Water-soluble complexes stabilized by 1,3,5-triaza-7-phosphaadamatane and its derivatives
      The Fourth Italian-Korean Joint Meeting On Inorganic Chemistry (Kimic Iv)
      Malcesine, Verona, Italy, 2-6 October 2006. Book of Abstracts, p 26
36.   Reginato G., Ciardi C., Peruzzini M., Gonsalvi L., Romerosa A.
      Sintesi di Nuove g-Ammino b-Idrossifosfine Chirali per Elaborazione di Amminoacidi Naturali
      XXII CONGRESSO NAZIONALE DELLA SOCIETA’ CHIMICA ITALIANA
      Firenze, Italy, 10-15 September 2006. Atti del Congresso. Abstract ORG-P95, p. 377
37.   Rossin, A.; Gonsalvi, L.; Peruzzini, M.; Phillips, A. D.; Lledos, A.
      Water-assisted dihydrogen activation in Ruthenium PTA complexes: a DFT study (PTA=1,3,5-triaza-7-
      phospha-adamantane)
      XXII CONGRESSO NAZIONALE DELLA SOCIETA’ CHIMICA ITALIANA
      Firenze, Italy, 10-15 September 2006




                                                                                                               10
                                                                                        Last update November 2009
38.   Manoury E., Malacea R., Routaboul L., Vincentedeau S., Poli R., Daran J.-C., Turrin C. O., Majoral J.-P-,
      Caminade, A.-M., Dunne J. P., Withwood A. C., Godard C., Duckett S. B., Le Roux E., Gonsalvi L.,
      Peruzzini M.
      New Chiral Ferrocenyl Phosphane-Thioether Ligands: Coordination amd Asymmetric Catalysis
      EXPERIMENT & THEORY IN TRANSTION METAL CHEMISTRY: A MEETING POINT (E&Ttmc)
      Bellaterra, Spain, 27-29 September 2006. Book of Abstracts, Poster 30, p 64
39.   Malacea R., Manoury E., Daran J.-C., Poli R., Le Roux E., Gonsalvi L., Peruzzini M..
      Coordination Chemistry of Chiral Planar Ferrocenyl Phosphine-Thioether. Application in Hydrogenation of
      Ketones
      EXPERIMENT & THEORY IN TRANSTION METAL CHEMISTRY: A MEETING POINT (E&Ttmc)
      Bellaterra, Spain, 27-29 September 2006. Book of Abstracts, OD.3, p 19
40.   Rossin A., Gonsalvi L., Peruzzini M., Phillips A. D., Lledos A., Maresca O.
      H2 activation mediated by Ru(II) PTA water-soluble complexes: how the water solvent takes an active part
      in the process (PTA = 1,3,5-triaza-7-phosphaadamatane
      EXPERIMENT & THEORY IN TRANSTION METAL CHEMISTRY: A MEETING POINT (E&Ttmc)
      Bellaterra, Spain, 27-29 September 2006. Book of Abstracts, OC.6, p 16
41.   Malacea R., E. Le Roux, Manoury E., Poli R., Gonsalvi L., Peruzzini M.
      Asymmetric Hydrogenation Of Ketones Catalysed By Chiral Planar Phosphine Thioether Iridium
      Complexes
      VII Conference on Mechanisms of Catalytic Reactions
      St. Petersburg, Russia, July 3-8, 2006
42.   Malacea, R.; Routaboul, L. ; Vincendeau, S.; Poli, R.; Daran, J.-C; Manoury, E. ; Dunne, J. P.; Withwood A.
      C.; Godard, C.; Duckett, S. B.; Le Roux, E.; Gonsalvi , L.; Peruzzini, M.
      New chiral ferrocenyl P,S ligands for asymmetric catalysis
      XXIInd ICOMC, 22nd International Conference on Organometallic Chemistry
      Zaragoza, Spain, 23-28 July 2006
43.   Rossin, A.; Gonsalvi, L.; Peruzzini, M.; Phillips, A. D.; Lledos, A., Maresca, O..
      The active role of the water solvent in the dihydrogen activation in Ru(II) water soluble complexes bearing
      PTA ligands: a DFT analysis (PTA=1,3,5-triaza-7-phospha-adamantane)
      XXIInd ICOMC, 22nd International Conference on Organometallic Chemistry
      Zaragoza, Spain, 23-28 July 2006
44.   Albinati, A.; Bolaño, S.; Bravo, J.; García-Fontán, S.; Gonsalvi, L.; Male, L.; Peruzzini, M.; Rodríguez-
      Rocha, M.
      Synthesis, characterization and reactivity of [RhCp*(H)2{PTA(N-BH3)}]
      XXIInd ICOMC, 22nd International Conference on Organometallic Chemistry
      Zaragoza, Spain, 23-28 July 2006
45.   Mallqui, M.; Serrano-Ruiz, M.; Romerosa, A.; Gonsalvi, L.; Peruzzini, M.
      Aquosoluble ruthenium complexes with the Cp(CONC(CH3)3)2 ligand and PPh3, PTA, mPTA and TPPMS
      XXIInd ICOMC, 22nd International Conference on Organometallic Chemistry
      Zaragoza, Spain, 23-28 July 2006
46.   Malacea, R.; Manoury, E.; Daran, J.-C; Poli, R.; Le Roux, E.; Gonsalvi , L.; Peruzzini, M.
      Coordination chemistry of chiral planar ferrocenyl phosphine-thioether. Applications in hydrogenation of
      ketones
                        th
      COGICO 2006, 7 Italian Congress of Organometallic Chemistry
      Parma, Italy, 9-12 July 2006
47.   Barbaro, P.; Gonsalvi, L.; Mañas Carpio, S.; Midollini, S.; Orlandini, A.; Sinyashin, O.; Yakhvarov, D.;
      Zanobini, F.; Peruzzini, M.
      Opening of the P4-tetrahedron caught into action: experimental evidence for bimetallic activation of white
      phosphorus
                        th
      COGICO 2006, 7 Italian Congress of Organometallic Chemistry
      Parma, Italy, 9-12 July 2006
48.   Bolaño, S.; Bosquain, S. S.; Phillips, A. D.; Peruzzini, M.; Romerosa, A.; Gonsalvi, L.
      A multi-faceted water soluble phosphine: coordination chemistry, organometallic reactivity and catalytic
      applications of PTA-based transition metal complexes

                                                                                                                 11
                                                                                             Last update November 2009
                        th
      COGICO 2006, 7 Italian Congress of Organometallic Chemistry
      Parma, Italy, 9-12 July 2006
49.   Ciardi, C.; Gonsalvi, L.; Peruzzini, M.; Reginato, G.; Romerosa, A.; Serrano, M.
      Synthesis of New Chiral Water Soluble Phosphines from Naturally Occurring Amino Acids
      OMCOS 13 – IUPAC Symposium on Organometallic Chemistry directed towards Organic Synthesis
      Geneva, Switzerland, 17-21 July 2005
50.   Bosquain, S. S.; Bolaño, S.; Phillips, A. D.; Gonsalvi, L.; Peruzzini, M.
      Rh(I)-PTN Based Catalysts for Olefin Hydroformylation and Hydrogen Transfer Reactions
      ISHHC XII, 12th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis
      Firenze, Italy, 18-22 July 2005
51.   Landaeta, V.; Gonsalvi, L.; Peruzzini, M.
      Ruthenium – Catalyzed Selective Oxidation of Aryl Thiophenes Using H2O2
      ISHXC XII, 12th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis
      Firenze, Italy, 18-22 July 2005
52.   Laurenczy, G.; Dorcier, A.; Dyson, P. J.; Bosquain, S.; Peruzzini, M.; Gonsalvi, L.
      Catalytic CO2 Reduction in Aqueous Solution Using CpRu(PTA)2Cl and Cp*Ru(PTA)2Cl Precursors
      ISHHC XII, 12th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis
      Firenze, Italy, 18-22 July 2005
53.   Bacchi, A.; Balordi, M.; Bolaño, S.; Calbiani, F.; Carcelli, M.; Elviri, L.; Gonsalvi, L. ; Pelagatti, P.; Pelizzi,
      C.; Peruzzini, M.; Rogolino, D.
      Synthesis, Characterization and Catalytic Behaviour of Ruthenium(Ii) Complexes with PNO Tridentate
      Ligands
      ISHHC XII, 12th International Symposium on Relations between Homogeneous and Heterogeneous Catalysis
      Firenze, Italy, 18-22 July 2005
54.   Romerosa, A.; Campos, T.; Lidrissi, C. Saoud, M.; Serrano, M.; Gonsalvi, L.; Bolaño, S.;Peruzzini, M.
      New water soluble vinylidene and allenylidene ruthenium complexes containing hydrosoluble phosphines
      and cyclopentadiene derivatives
      Green Solvents for Synthesis
      Bruchsal, Germany, 3-6 October 2004
55.   Peruzzini, M.; Bolaño Garcia, S.; Bosquain, S; Campos, T.; Gonsalvi, L.; Lidrissi, C.; Mañas Carpio, S.;
      Phillips, A. D; Romerosa, A.; Saoud, M.; Serrano Ruiz, M.
      Nuovi complessi metallici idrosolubili stabilizzati dalla fosfina PTA (PTA = 1,3,5-triaza-7-fosfaadamantano)
      XXXII Congresso Nazionale della Divisione di Chimica Inorganica
      Roma, Italy, 20-24 September 2004
56.   Phillips, A. D.; Ienco, A.; Gonsalvi, L.; Peruzzini, M.; Mealli, C.
      Understanding the molecular properties in hetero-substituted phosphaadamantanes
      EuroConference on New Theoretical and Spectroscopical Approaches to Inorganic Chemistry Problems
      San Feliu de Guixols, Spain, 4-9 September 2004
57.   Bolaño, S.; Gonsalvi, L.; Zanobini, F.; Vizza, F.; Bertolasi, V.; Romerosa, A.; Peruzzini, M.
      Regioselective hydrogenation of benzylidene acetone and cinnamaldehyde catalysed by water soluble
      ruthenium complexes
                                                 th
      Summer School on Green Chemistry – 7 Edition
      Venezia, Italy, 5-11 September 2004
58.   Poli, R.; Phillips, A. D.; Gonsalvi, L.; Malacea, R.; Daran, J.-C.; Peruzzini, M.
      A new class of rhodium-P,N complexes derived from cage-type phosphabicyclo[3.3.1]-nonane ligands for
      use in hydroformylation catalysis
      III Euchem Conference on Nitrogen Ligands in Organometallic Chemistry and Homogeneous Catalysis
      Camerino, Italy, 8-12 September 2004
59.   Ortiz-Frade, L. A.; Ruiz-Ramirez, L.; Moreno-Esparza, R.; Gonsalvi, L.; Masi, D.; Peruzzini, M.; Zanobini,
      F.; Vizza, F.
      Reactivity study in solution of a New Ru(II) Compound Containing the Ligand 1,8-bis(2-Pyridyl)-3,6-
      dithiaoctane (pdto) and triphenylphosphine. Electrochemical & structural study of the dimeric product
      [Ru(pdto)Cl]2

                                                                                                                      12
                                                                                            Last update November 2009
      XXXVI ICCC, 36th International Conference on Coordination Chemistry
      Merida, Mexico, 18-23 July 2004
60.   Gonsalvi, L.; Phillips, A. D.; Maresca, O.; Lledos, A.; Peruzzini, M.
      Stable water soluble Cp and Cp* Ru hydrides. HP-NMR, DFT studies and catalytic tests for the selective
      hydrogenation of activated olefins
      ISHC XIV, 14th International Symposium on Homogeneous Catalysis
      Munich, Germany, 5-9 July 2004
61.   Gonsalvi, L.; Reginato, G.; Mantovani, N.; Marvelli, L.; Rossi, R.; Grigiotti, E.; Zanello, P.; Peruzzini, M.
      Multiconjugated carbon-carbon chains based on bimetallic allenylidene units
      MOLMAT 2004, International Symposium on Molecular Materials and Organometallics
      Rennes, France, 12-14 May 2004
62.   Phillips, A. D.; Gonsalvi, L.; Romerosa, A.; Vizza, F.; Peruzzini, M.
      Novel water soluble Ru-PTA complexes: recent advances in catalytic and biological applications
      RSC Dalton Discussion 6, Organometallic Chemistry and Catalysis
      York, UK, 9-11 September 2003
63.   Gonsalvi, L.; Arends, I. W. C. E.; Sheldon, R. A.
      Simple yet efficient optimisation of ruthenium catalysed oxidations with NaOCl via pH control
      ISHC XIII, 13th International Symposium on Homogeneous Catalysis
      Tarragona, Spain, 3-7 September 2002
64.   Gaunt, J.; Gonsalvi, L.; Sunley, G.; Cavallo, L.; Haynes, A.
      Ligand effects on organometallic reactivity
      XXth ICOMC, 20th International Conference on Organometallic Chemistry
      Corfu, Greece, 7-12 July 2002
65.   Gonsalvi, L.; Arends, I. W. C. E.; Sheldon, R. A.
      Green catalytic -oxidation of ethers to esters (oral communication)
      NCCC II, Second Netherlands Catalysis and Chemistry Conference
      Noordwijkerhout, The Netherlands, 5-7 March 2001
66.   Gonsalvi, L.; Arends, I. W. C. E.; Sheldon, R. A.
      A Clean Catalytic Process for the Oxidation of Ethers and Acetals to Esters via O2
      ISHC XII, 12th International Symposium on Homogeneous Catalysis
      Stockholm, Sweden, 27 August - 1 September 2000
67.   Gaunt, J.; Haynes, A.; Gonsalvi, L.; Sunley, G.
      Stereoelectronic Effects on the Rate of Migratory CO Insertion in Rhodium
      catalysed Methanol Carbonylation
      ISHC XII, 12th International Symposium on Homogeneous Catalysis
      Stockholm, Sweden, 27 August - 1 September 2000
68.   Gonsalvi, L.; Haynes, A.; Adams, H.; Maitlis, P. M.
      Ligand Effects on Rhodium and Iridium Catalysed Methanol Carbonylation
      XVIIIth ICOMC, 18th International Conference on Organometallic Chemistry
      Munich, Germany, 16-21 August 1998
69.   Gonsalvi, L.; Adams, H.; Haynes, A.
      Ligand Effects on Homogeneous Rhodium-Catalysed Methanol Carbonylation
      ISHC XI, 11th International Symposium on Homogeneous Catalysis
      St Andrews, Scotland, UK, 12-17 July 1998
70.   Haynes, A.; Gonsalvi, L.; Evans, D.; Sunley, G. J.
      Oxidative Addition of Methyl Iodide to [RhI(CO){Ph2PCH2P(S)Ph2}]
      ECTOC-3, Electronic Conference on Trends in Organometallic Chemistry
      Web conference, 30 June-31 July 1997
71.   Cauzzi, D.; Costa, M.; Predieri, G.; Gonsalvi, L.; Tiripicchio, A.; Zanoni, R.
      Metal Catalysts anchored to hybrid organic-inorganic sol-gel materials
      CO.GI.C.O. 94, 2nd Italian Congress of Organometallics,
      Marina di Ascea (Italy), 18-21 September 1994

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                                                                                        Last update November 2009


Lectures - invited

1.    Aqueous phase catalysis, organometallic reactivity and much more: the renaissance of the water soluble
      monodentate phosphine PTA
      CIAM (Catalysis in Aqueous Media) Workshop, CNRS-LCC, Toulouse, France, 30 November 2007
2.    A multi-faceted water soluble phosphine: coordination chemistry, organometallic reactivity and catalytic
      applications of PTA-based transition metal complexes
      INEOS Seminar, Russian Academy of Sciences, Moscow, Russia, 12 September 2006
3.    Aqueous phase hydrogenations catalysed by water soluble half sandwich ruthenium hydrides. Synthesis,
      catalytic tests and mechanism.
      Sustainable / Green Chemistry and Chemical Technology Workshop, Venice, Italy, 20-21 February 2004
4.    Aquous hydride Chemistry: hydrosoluble ligands and complexes for selective hydrogenations
      Ciclo de Conferencias Semanales, Universidad Nacional Autonoma de Mexico, Mexico, 20 January 2004
5.    Advances in Rhodium Catalysed Methanol Carbonylation
      Ciclo de Conferencias Semanales, Universidad Nacional Autonoma de Mexico, Mexico, 20 January 2004
6.    Liquid Phase Organic Oxidations for Fine Chemicals. An example of process optimisation.
      Inorganic Chemistry Seminar, University of Parma, Italy, 20 December 2002.
7.    Advances in Rhodium Catalysed Methanol Carbonylation
      Inorganic Chemistry Seminar, University of Parma, Italy, 13 December 2002.
8.    Modelling Ligand Effects in Catalytic Methanol Carbonylation
      Inorganic Chemistry Seminar, University of Parma, Italy, 8 November 2000.


Books
                           th
1.    Proceedings of the 6 European Symposium on Phosphorus Chemistry (EWPC-6), Florence 26-27 March
      2009, (Eds L. Gonsalvi, M. Caporali), Tassinari (Firenze) 2009, ISBN 9-788887-057492
2.    Bianchini, C.; Gonsalvi, L.; Peruzzini, M.
      Iridium-Catalyzed C=O Hydrogenation, Ch. 4 in Iridium Complexes in Organic Synthesis, pages 55-106.
      Edited by L. Oro and C. Claver, Wiley-VCH, Weinheim, 2008 ISBN: 978-3-527-31996-1[book]
3.    Peruzzini, M.; Bianchini, C.; Gonsalvi, L.
      Comprehensive Organometallic Chemistry III, chapter 7.04, pages 267-425
      Edited by R. H. Crabtree and D. M. P. Mingos, Elsevier: Oxford 2007 ISBN: 008044590X [chapter]
                                th
4.    Proceedings of the 12 International Symposium on Relations between Homogeneous and Heterogeneous
      Catalysis (ISHHC-XII), Florence 18-22 July 2005, (Eds V. Dal Santo, G. Giambastiani, L. Gonsalvi, M.
      Guidotti), Tassinari (Firenze) 2005, ISBN 88-87057-34-6


Past and Present Collaborations

Prof. Rinaldo Poli, CNRS LCC Toulouse, France; Dr. Donald A. Krogstad, Concordia College at Moorhead, USA;
Dr Frederic Hapiot, Université d’Artois, Lens, France; Prof Paul Dyson and Dr Gabor Laurenczy, EPFL
Lausanne, Switzerland; Dr Paolo Pelagatti, University of Parma, Italy; Dr Willem Schipper, Thermphos Int. BV,
Vlissingen, The Netherlands; Prof. Dr. J-G. de Vries, DSM Life Sciences, Geleen, The Netherlands; Dr. Anthony
Haynes, University of Sheffield, UK and Dr G. J. Sunley, BP Chemicals, Hull, UK.




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