Kinetic Theory_1_

					Name: ___________________________________                                     Mrs. Polishchuk, Physical Science
                                              Unit 1.2 Lecture Notes
                                     WHAT MAKES MATTER “TICK”?

Kinetic Theory
   1. Explanation of how particles in matter behave.
   2. All matter is made of atoms
   3. Atoms are in constant motion
   4. Diffusion: The spreading of atoms throughout a substance until they are uniformly distributed
          a. Occurs from collisions between atoms
          b. Atoms need “personal space”
   5. Causes the atoms to “fight for space” and spread as evenly as possible
   6. Atoms collide with each other and the walls of the container
   7. Even solids vibrate in place.
   8. Temperature measures kinetic energy
   9. Higher temperature = faster motion; lower temperature = slower motion
   10. Absolute zero
          a. -273 C or 0 K
          b. Lowest kinetic energy possible, motion is so slow that no more energy could be removed
   11. Why did the hot balloon expand in lab?
          a. Increase in kinetic energy  faster collisions with other atoms  larger recoil from
             collision  faster and more energetic collision with walls of the balloon.
   12. Why did the cold balloon shrink in lab?
          a. Decrease in kinetic energy  slower collisions with other atoms  smaller recoil from
             collision  slower and less energetic collision with walls of the balloon.

States of Matter
http://mutuslab.cs.uwindsor.ca/schurko/animations/waterphases/status_water.htm

http://mutuslab.cs.uwindsor.ca/schurko/animations/phasescontainers/phasescontainer.html


Solids
    1.   Atoms are closely packed together into a geometric arrangement: crystal structure
    2.   Lowest state of kinetic energy
    3.   Ice – geometric arrangement of water molecules
    4.   Atoms vibrate in place
    5.   Fixed volume and shape, high attractive force between atoms
    6.   Sketch a salt (NaCl) crystal

Liquids
   1. Higher in kinetic energy than solids
   2. Energy absorbed from the environment allows atoms to overcome attractive forces from the solid
       structure and wiggle out of it.
           a. Melting point / heat of fusion: the amount of kinetic energy needed for this to happen
   3. The higher state of kinetic energy allows liquids to flow
           a. Slide past each other and not be snagged into a geometric pattern
           b. Hydrogen bonding: Like a static electricity attraction, still cling together a little, gives a definite
               volume
   4. Draw and label a hydrogen bond
   5. Fixed volume, unfixed shape, some attractive force between atoms

Gases
   1. Higher in kinetic energy than liquids
   2. Energy absorbed from the environment allows atoms to overcome attractive forces in the liquid state
      that makes liquids flow
         a. Atoms do not cling together
         b. Completely separate, no contact or attraction
   3. Vaporization: the process of atoms escaping the “clingy” hydrogen bond
         a. Evaporation: occurs at the surface of a liquid only
         b. Boiling: pockets of gas form all over and escape at the surface
         c. Boiling point / Heat of vaporization: the amount of kinetic energy required for this to happen
   4. Unfixed volume and shape, no attractive force between atoms

Plasma
   1. Most common in the universe
   2. Matter consisting of positively and negatively charged particles
   3. Highest kinetic energy – the collisions split the atom into pieces
   4. Still neutral – equal number of positive and negative
   5. Stars. florescent lights, neon lights, auroras

Heating Curves
   1. Shows temperature change as kinetic energy is added
   2. Diagonal lines: increase in energetic state
   3. Flat lines: absorption of energy occurring to overcome attractive forces in that state of matter.

Thermal Expansion and Contraction
   1. Examples: Thermometers, cracks in the side walk, pot holes, opening tight jars, hot air balloons
   2. How are these examples of thermal expansion?

                   What is Expanding?                                    How does it happen?
Thermometers                                            high kinetic energy causes a need for more space
                                                        for collisions, only way to expand is up

Cracks and potholes in pavement                         Water collects in small pores in the pavement.
                                                        When low kinetic energy ice forms, hydrogen
                                                        bonds at low KE take up more space than
                                                        hydrogen bonds in higher KE
Opening jars                                            high KE from hot water transfers some energy to
                                                        the jar lid. Atoms in the jar absorb and take up
                                                        more space when moving; expanding out
Hot air balloons                                        flame heats air inside the balloon, gives more KE to
                                                        air molecules, they move faster collide harder and
                                                        spread. Less dense that cold air outside balloon so
                                                        floats.


   3. The size of a substance increases when the temperature is increased
         a. More energy in collisions causes more pressure and bigger volume
         b. Expansion
   4. The size of a substance decreases when the temperature is decreased
        a. Less energy in collisions causes less pressure and less volume
        b. Contraction
   5. Water: the exception
        a. Expands when low in kinetic energy
        b. Hydrogen bonding causes large empty spaces when forming solids
   6. Amorphous Solids are important to industry
        a. A = without Morphous = form
        b. No set boiling or melting point
                 i. Glass, plastic
        c. Do not form crystal structure
        d. Molecules form chains that can be stacked or molded by manipulating temperature changes
                 i. Obsidian: forms only when lava cools very quickly
        e. Liquid crystals are used in LCD (liquid crystal display)
                 i. Substances that do not lose their geometric pattern in the liquid state of matter

Properties of Fluids: Liquid
   1. Two fluids: Liquids and Gases
           a. They “flow”: molecules are able to pass by with some interaction, but not so much that they
              are locked in a bond
           b. We live at the bottom of an ocean of air!
   2. Buoyancy – the ability of a fluid to give an upward force on an object in it
   3. Weight – the force of gravity plus an object’s mass
   4. Why can huge ships float?
           a. A greater force pushes up on the ship than opposes the downward force of weight
   5. If the buoyant force = weight, the object floats
   6. If the buoyant force is less than the weight, the object sinks
   7. Archimedes: Greek philosopher discovered the buoyant force
           a. Displacement: The weight of water pushed aside by an object
           b. The buoyant force an object receives is equal to the displacement of water
           c. The more water displaced, the higher the buoyant force
   8. Draw the buoyant force vs. displacement
           a. Skinny, heavy ships sink because they do not push aside enough water
           b. Heavy, fat boats float because they push aside an equal amount of water as their weight.
   9. Why does a ship’s hull need to be filled with air?
           a. The air makes the ship’s density less than water so it floats
   10. Water can be pushed aside because it has a definite volume
   11. Pascal discovered that fluids can exert pressure
           a. Force exerted per unit area or the weight of all fluid around an object
           b. Fluids flow from high pressure to low pressure
           c. Fluids transfer pressure from one area to another (squeezing a toothpaste tube)
   12. Hydraulic lifts work using Pascal’s principle
           a. Pressure on a small cylinder is transferred to a larger cylinder
           b. The force gets multiplied over the area

Properties of Fluids: Gases
   1. Bernoulli’s principle allows for flight
   2. Fast-moving fluid creates low pressure
          a. A fluid has “less time” to exert a force on its surroundings
   3. Slow-moving fluids are higher in pressure
   4. Airplane wings are airfoils that manipulate the flow of air into areas of different pressure
          a. Low pressure on top, high pressure on bottom
          b. High pressure pushes low pressure: lift force
   5. Pascal’s principle allows for flight also
          a. Transfer of pressure from one area to another
          b. Force multiplied over the area of the wing
   6. Other examples: Shower curtain
   7. Air pressure is measured by a barometer
          a. Weight of air pushes liquid up a tube
          b. Units: Atmospheres (atm), Torr, mmHg (millimeters of mercury)
          c. Air pressure at sea level is 1 atm, 760 torr, and 760 mmHg
          d. Draw and label the parts of a barometer

Behavior of Gases: Gas Laws
    1. Gases are usually confined to containers
            a. Force of gravity creates the “container” for atmosphere, tires, balloons, basketballs, tennis
                balls
    2. Collection of forces from collisions between gas molecules and gas molecules with its container have
        a set of relationships
Boyle’s Law
http://www.mhhe.com/physsci/chemistry/essentialchemistry/flash/gasesv6.swf
    1. Pressure and volume are inversely proportional – they change oppositely
    2. If volume decreases, pressure increases
    3. P1V1 = P2V2 – Solve using algebra
    4. From Lab:
            a. Cartesian diver – sketch it!

   5. Draw it! Three canisters increasingly compressing a set volume and amount of gas

   6. A helium balloon has 2L of air in it at sea level (1atm). What would the volume of the helium balloon
      be when it reaches the stratosphere with an air pressure of 0.5 atm?

   7. A child received a balloon with 2L of air in the mountains, but when she traveled to her sea side cottage,
      the balloon deflated and wouldn’t float. Why did this happen if the atmospheric pressure changed from
      0.7 atm to 1 atm?

Charles’ Law
http://www.mhhe.com/physsci/chemistry/essentialchemistry/flash/gasesv6.swf
    1. Temperature and volume are directly proportional; they change the same way
    2. As temperature increases, volume increases
    3. Molecular motion causes volume (draw it)




   4. Temperature is the measure of kinetic energy
   5. The more kinetic energy gas molecules have, the more it pushes against its container, therefore the
      larger the volume.
   6. From Lab
          a. Sketch the three different balloon temperatures:




   7. V1/T1 = V2 / T2 – plug in numbers and solve using cross multiplication
8. Why do tires need to have air added when it’s cold outside?

9. A sample of oxygen gas has a volume of 4.55L at 25 degrees C. Calculate the volume of the oxygen gas
   when the temperature is raised to 45 degrees C (4.86L)

10. A certain glass container is designed to hold no more 2L of any liquid or gas. If the bottle is sealed with
    2L of air at room temperature (25 degrees C) and is microwaved to a temperature of 45 degrees C, will
    the bottle survive?

				
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