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Writing NanoImprint Templates by Shaped E-Beam Lithography Dirk Beyer, Peter Hudek, Olaf Fortagne, Timothy Groves, Juergen Gramss Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Framework Close Cooperation between: Leica Microsystems Lithography Motorola IMS - Chips Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Template Writing Strategy Active imprint area 25mm x 25mm 6025 plate with layout of four SFIL templates Single SFIL pedestal template, 65mmx 65mm external dimension Template obtained by dicing a 6025 plate Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Template Writing Strategy Conventional template process using 15nm of Cr as hard mask - 6” blank covered with a 15nm Cr-layer (Motorola) - 180nm spin coated ZEP 7000 resist (Leica) - Exposure at Leica SB350 MW (Leica) - Multiple puddle developed 60s in ZED500 developer (Leica) - Cr-layer etching with Cl-based RIE & resist removal (Motorola) - Pattern transfer through Cr into SiO2 in a F-based RIE to a depth of 100-200nm (Motorola) Motorola Pattern Transfer Process Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Template Writing Strategy Critical Specs: - Minimum Feature Size: Gate / Contact at 1x - Image Placement (25mm x 25mm) - CD Uniformity - Defects Writing Options: Gaussian Beam - high Resolution but low Throughput, not optimized for Placement Variable Shaped Beam - better Throughput, excellent Placement, but....... Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Mask Maker‘s Tool Today: - 50kV Variable Shaped E-Beam, Vector Scan - 1nm Grid - Up to 20A/cm² for high Throughput - Continuously Moving Stage - Step and Repeat Stage - Robotic Reticle Management Station - Handles Blanks & Substrate Holders Up To 9 Inch - Data Preparation Interface to CATS & MGS - Proximity Correction (Hardware or Software) Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 General View SB350 Reticle Management Station (CAR) Control Electronic Equipment Controller Asyst Versaport 2200 Operator (outside) Basic Unit Operator (grey room) Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Outer Handling Station Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Chamber & Mask Stage Assembly Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Cassette for Mask 6025 calibration detector mask 6025 baseplate (Zerodur) contact Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 MW & DW Specifications Placement Overlay CD Uniformity DW Resolution Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Placement Leica SB350 MW (0,48m clear lines) Image Placement 3 10 / 8 nm Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Placement Leica SB350 MW (0,48m opaque lines) Image Placement 3 9 / 8 nm Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Overlay Leica SB350 MW Mask to Mask Overlay 3 8 / 8nm Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 CD Uniformity Leica SB350 MW (0,48m clear lines) CD - Uniformity 3 7 / 6 nm Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 1x Resolution 60nm Writing on 300mm Wafers 70/240nm L/S Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 1x Resolution 45nm SRAM Gate Patterning 45nm 50 nm after lithography 1st 65nm node structures 114 nm gate on active (active and gate have been printed using SB350 DW) Leica Microsystems Lithography GmbH after etch Source: MEDEA+ T201: Final Report Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Resolution Capabilities Gaussian Beam Variable Shaped Beam One exposure shot One exposure shot Pattern contour Increased Throughput: (some degree of parallelism introduced into the exposure process) Beam Shape: Fixed (focused) Variable in x and y axis Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Resolution Capabilities Generation of Axis-Parallel 45o Rotated Rectangles and Triangles Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Resolution Capabilities Rectangular Shaped Beam Beam Blur & Aerial Image Slope Determined by: - optical aberrations; - space charge effect y c ty cuiity cu ty acuiit edge edge edge edge e m eam eam Beam Leica Microsystems Lithography GmbH Influence: - CD Linearity/Uniformity Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Resolution Capabilities 20%-80% Edge acuity versus aperture angle for four different probe currents and two emission currents in the best focus plane. Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Resolution Capabilities Aerial Image Resolution controls printable feature size Single – Line exposure Line - Array exposure Position [nm] Position [nm] Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 1nm CD Control Nominal Line Width: 0.92µm (No Proximity Correction applied) Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Tasks to be solved: - find a trade off between throughput and resolution - optimize the dose control Proximity Correction Beam current is fixed at production tools ! Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Dose Control Pattern design Proximity affected pattern (after Lift-Off) Contours simulation INTRA INTER Proximity Effect - an example Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Dose Control PEC-Input Parameters Determination (Fine-Tuning of the Point-Spread Function) Including Exposure, Resist patterning & Pattern transfer processes Exposure, „PROX-In“ – software package Reconstruction / Back-Simulation of Patterns and/or Pattern Geometry Variations - uses non-corrected simple test patterns exposed in an exposure wedge; - CD-measurements of patterns in selected/specified points; - Search for optimized input parameters to reconstruct the measured data -> Back-Simulation. Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Dose Control „FinePSF – „Fine-Tuning“ Dose Factor 2-Gauss PSF Measured Amount of exposure energy required to produce the proper dimension of the written feature Simulated Linewidth Dose Factor 3-Gauss PSF after „Fine-Tuning“ of the PSF parameters ... Measured „Dose to Size“ Leica Microsystems Lithography GmbH Simulated Linewidth Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Dose Control Line in „Duty-Ratio“ Linewidth The shape of the measured curve is process-dependent ! Measured Simulated Duty.Ratio: Duty.Ratio: (1:1) (1:2) (1:3) (1:10) (1:20) Single Line NNT‘04 Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography Dose Control Proximity Effect Correction – a Recipe Expose of Pattern for Monitoring on Test Blank Development and Development and Etching/Cleaning Etching CD measurement CD measurement „Beta“ - Simulation „Beta“„Beta“ simulation Program program Result: Parameter Result: Parameter ( ( , , , , ) ) for complete for complete process Process Back simulation of Back Simulation of - incl. tool and , , , , - incl. Tool and process influences Process influences Output: ,,Calculation Output: Calculation of of and and Expose of CD Test Pattern and CD Measurement Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Dose Control Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Results Leica SB350 MW 100nm Test data provided by Motorola Leica Microsystems Lithography GmbH 50nm 40nm Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Results Trenches etched into quartz 50nm 40nm 33nm 29nm Contacts 55nm Test data provided by Motorola Leica Microsystems Lithography GmbH 44nm Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Results Gaussian Beam (Leica VB6) 100keV ONE SHOT Shaped Beam (Leica SB350 MW) 50keV ONE SHOT 100nm 50nm 40nm Template Results: Gaussian vs. Shaped Beam Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Summary - Well proven Production Tools for Mask Making and Wafer Direct Writing are available to fabricate S-FIL Templates - It is essential to adapt the Tool to the Technology Process - 33nm L/S and 44nm Contacts are well resolved using ZEP700 and a Motorola Pattern Transfer Process - Standardization of Templates is necessary Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04 Thank you for your Attention! Leica Microsystems Lithography GmbH Writing NanoImprint Templates by Shaped E-Beam Lithography NNT‘04

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