The Ozone Story
Presentation
Ozone Secretariat
UNEP
(updated July 2003)
Ozone Distribution in the Atmosphere
80 60 40
MESOSPHERE
STRATOSPHERE
TROPOSPHERE
20
km 0 50 100 150
Ozone Partial Pressure (b)
Scientific Background I
History
1839:
1850s: 1880: 1913: 1920:
Ozone discovered by C. F. Schönbein when observing electrical discharges. Ozone shown to be a natural atmospheric constituent. Experiments show that Ozone strongly absorbs Solar Ultraviolet (UV) radiation. Proof that most of the atmosphere's ozone is located in the stratosphere. G. M. B. Dobson (an Oxford Scientist) perfected an instrument to monitor quantitatively total atmospheric ozone.
3
Updated July 2003
Scientific Background II
The Current Science
The global Ozone layer recovery has been linked mainly to decreasing Chlorine and Bromine loading, but other factors such as the role of Green house gases and climate change are likely to contribute. Total Combined effective abundance of Ozone depleting compounds in the lower atmosphere peaked in 1992-1994 and since then it has been declining slowly. The abundance of HCFCs in the lower atmosphere is increasing. Chlorine abundance in the stratosphere is at or near its peak but Bromine abundance seems to be still increasing.
4
Updated July 2003
Scientific Background II
The Current Science (continued.)
The ozone depletion in the Antarctic, the Arctic and the mid-latitudes is still continuing, due to past emissions of CFCs. It will peak in the next few years. The Montreal Protocol is working and Ozone depletion from the Protocol’s controlled substances is expected to start recovering within the next decade or so. Even with full compliance of the Montreal Protocol, the Ozone layer will remain particularly vulnerable for the next decade or so. Failure to comply with the Montreal Protocol will delay or even prevent the recovery of the Ozone layer.
5
Updated July 2003
Why Protect the Ozone Layer?
Ozone Depletion leads to excessive UV-B radiation. Excessive UV-B radiation leads to: More skin cancers and eye cataracts. Less productivity of plants. Loss of immunity to diseases.
Adverse
effects on plastics.
Updated July 2003
6
CFCs: Ozone Depleting Substances
1928: 1950-70s: CFCs invented; Consumption and use of CFCs rises rapidly during the 50s-70s period. Used in Aerosols, Refrigeration, Air Conditioning and Manufacturing of Foams.
Updated July 2003
7
Scientific Activity on Ozone
1971: 1974: 1977: CFCs measured in the atmosphere. Rowland and Molina link CFCs with Ozone Depletion. Plan of Action on Ozone Layer established by UNEP in collaboration with WMO. UNEP sets up Co-ordinating Committee on Ozone Layer (CCOL). Findings on "The Ozone Hole" over the Antarctic (during spring) published by the British Antarctic Survey.
1985:
Updated July 2003
8
Measurements of Ozone and Reactive Chlorine from a Flight Into the Antarctic Ozone Hole, 1987 (Smoking gun..)
3000 Ozone (Scale at Left) 1.5 Reactive Chlorine Abundance (Parts per Billion) 2500 Ozone Abundance (Parts per Billion)
2000
1.0
1500
1000
0.5
500
Reactive Chlorine (Scale at Right)
Antarctic Polar Air 0 67 68 69 70 71 72
0 63 64 65 66 Latitude (Degrees South)
Updated July 2003
9
Scientific Activity on Ozone
(continued.)
1985: 1987: First Scientific Assessment of Stratospheric Ozone. Observations prove that the more the Chlorine in the Atmosphere, the less the amount of Ozone.
1989:
Scientific Assessment of Stratospheric Ozone under the Vienna Convention and Montreal Protocol
Scientific Assessment of Ozone Depletion under the Vienna Convention and Montreal Protocol.
10
1991:
Updated July 2003
Scientific Activity on Ozone
(continued.)
1994: Scientific Assessment of Ozone Depletion under the Vienna Convention and Montreal Protocol.
1995:
Nobel prize received by 3 scientists (Crutzen, Molina and Rowland) for pioneering the research on Ozone Depletion.
Scientific Assessment of Ozone Depletion under the Vienna Convention and Montreal Protocol. Scientific Assessment of Ozone Depletion under the Vienna Convention and Montreal Protocol.
1998: 2002:
Updated July 2003
11
International Commitments
1985: Vienna Convention for the Protection of the Ozone Layer calls for voluntary measures to reduce emissions of ozone-depleting substances (ODS). Montreal Protocol on Substances that Deplete the Ozone Layer establishes a schedule to reduce the production and consumption of CFCs and Halons.
1987:
Updated July 2003
12
International Commitments
(continued.)
1990,92,95,97,99: At meetings in London, Copenhagen, Vienna, Montreal and Beijing Parties approve adjustments and/or amendments to the Montreal Protocol to stipulate/accelerate the phase-out schedules and add additional ozone-depleting substances to the list. 1994: production and consumption of Halons by developed countries is stopped except for essential uses.
Updated July 2003
13
Ozone Protocol and Amendments Ratification Status
Ozone Protocol and Amendments Ratification Status
Vienna Convention (185) Montreal Protocol (184) London Amendment (165) Copenhagen Amendment (150) Montreal Amendment (101) Beijing Amendment (50)
(Information sent to the Ozone Secretariat by the Depositary, UN Office of Legal Affairs, July, 2003)
200 180 160 140 120 100 80 60 40 20 0
1986 1987 1988 1989 1990 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002 2003 2004
Number of Countries
Year
Updated July 2003
14
Ratification of the Montreal Protocol
(July 2003)
Countries that have NOT ratified the Montreal Protocol
Afghanistan Bhutan Cook Islands Equatorial Guinea Eritrea Iraq Niue Andorra Holy Sea San Marino East Timor
Countries that have NOT Ratified the Montreal Protocol (11 Countries)
Updated July 2003 15
International Commitments
(continued.)
1995: The phase-out schedule of all Ozone depleting substances applicable to developing parties is agreed by the parties with a ten-year grace period. Production and consumption of CFCs , Carbon tetrachloride and methyl chloroform by developed countries stopped except for essential uses while consumption of HBFCs stopped for all parties A system for licensing the import and export of all ozone depleting substances becomes mandatory to all parties to the Montreal Protocol in order to control illegal trade.
16
1996:
1997:
Updated July 2003
World CFC Production 1950 - 2002 World CFC Production 1950-2002
Source: DuPont, Worldwatch estimates and Ozone Secretariat
1400
Montreal Protocol Signed (1987)
1200
1000
First Ozone depletion theory published (1974)
Thousand Tons
800
600
400
200
0 1950
1960
1970
1980
1990
2000
2010
Year
Updated July 2003
17
Financial Mechanism The Multilateral Fund of the Montreal Protocol
1991: The Multilateral Fund established, with UNDP, UNEP, UNIDO and World Bank as the implementing agencies, to provide financial and technical assistance to developing countries (Article 5) to enable them comply with the control measures. The Multilateral Fund of the Protocol has been very successful. It has, between 1991 - 2002 disbursed close to $1.5 billion to more than 100 developing countries to phase-out more than half of their CFC consumption. It will continue assistance till the phase-out is completed.
18
Updated July 2003
Replenishments of the Multilateral Fund of the Montreal Protocol since 1990
No.
1* 2 3 4 5
Updated July 2003
Years covered
1991-1993 1994-1996 1997-1999 2000-2002 2003-2005
Amount Cumulative Year/ Venue millions US$ 200 200 1991/Nairobi
455 466 440 474
19
655 1,121 1,561 2,035
1993/Bangkok 1996/Costa Rica 1999/Beijing 2002/Rome
* In 1990, the Parties in Decision II/8 established on an interim basis a fund of US$160,000,000 which was increased in 1991 to US$200,000,000
Cumulative Replenishments of the Multilateral Fund of the Montreal Protocol
2,500
Cumulative Replenishment (million US$)
New Replenishment
2,000 1,500 1,000 500 1991-1993 1994-1996 1997-1999 2000-2002 2003-2005
Replenishment Period
Updated July 2003 20
CumulativeAllocations and Provisions by the MLF Cumulative Allocations and Provisions by and ODS Phased Out the MLF andODS Phased Out Since 1991 Since 1991
( Source: MLF Executive Meetings Reports )
140000
Cumulative ODP Tonnes Cumulative Funds Approved
1400
120000 1200 100000
ODP Tonnes of CFC
1000 80000 800 60000
600
40000
400
20000
200
0 1991 1992 1993 1994 1995 1996 1997 1998 1999 2000 2001 2002
0
Year
Updated July 2003
21
US$ Million
Funds Allocated to the Implementing Agencies by the Multilateral Fund of the Montreal Protocol (as at 11 July 2003)
Agency 1. UNEP US$ million 74.1
(Information clearing house, preparation of country programmes, institutional strengthening, networking and training)
2. UNDP (Technical assistance and Investment projects) 409.0 3. UNIDO (Investment projects) 319.2 4. World Bank (Investment projects) 621.4 Total 1,423.7
Updated July 2003 22
Countries with Economies in Transition (CEIT Countries)
The Global Environment Facility (GEF) assisted the Russian Federation and other Eastern and Central Europe countries (CEITs) to implement the Montreal Protocol. Russian Federation phased out its CFC and Halon production and consumption in 2001. GEF approved over US$ 160 million to 18 countries. The countries that have been assisted: Armenia, Azerbaijan, Belarus, Bulgaria, Czech Republic, Estonia, Hungary, Kazakhstan, Latvia, Lithuania, Poland, Russian Federation, Slovakia, Slovenia, Tajikistan, Turkmenistan, Ukraine and Uzbekistan.
23
Updated July 2003
CEIT Countries (continued.)
With support from GEF, consumption of CFCs in these countries has decreased from 146,000 tonnes in 1986 to only 1,340 tonnes in 2001. These countries have thus almost completed their phase-out of Annex A and B substances as provided by the Montreal Protocol. Additional funds of US$ 60 million ear-marked by GEF to CEIT countries for HCFC and Methyl Bromide phase-out.
Updated July 2003
24
Achievements
Global Production of CFCs and Halons fell by over one million tonnes (by 89%) between 1986 and 2000. Global Consumption fell in the same period by the same margin (89%) Atmospheric Concentration of Chlorine peaked in 1994 and is now declining. Millions of cases of Eye Cataracts and Skin Cancer averted Recovery of the Ozone Layer expected by the year 2050, if the Protocol is fully implemented by all Parties.
25
Updated July 2003
Atmospheric Concentrations of CFC-11, CFC-12, CFC-113, Carbon Tetrachloride, Methyl Chloroform and TotalCFC-113, Carbon Atmospheric Concentrations of CFC-11, CFC-12, Gaseous Chlorine
Tetrachloride, Methyl Chloroform and Total Gaseous Chlorine
(Source: World Resource 1998-1999, WRI) 600 3000
400
2000
300
1500
200
1000
100
500
0
0
1977 1978 1979 1980 1981 1982 1983 1984 1985 1986 1987 1988 1989 1990 1991 1992 1993 1994 1995 1996 1997
Year
Updated July 2003 26
Total Gaseous Chlorine in PPT
500
Gas Abundance in PPT
CFC-11 CFC-12 CFC-113 Carbon Tetrachloride Methyl Chloroform Total Gaseous Chlorine
2500
Total Chlorine Abundance in the Stratophere
Source: 2002 assessment of the Science Assessment Panel
Comments
Total chlorine abundance in the Stratophere is at or near its peak. Total chlorine and bromide abundance in the lower atmosphere peaked in 1992-1994 and continues to decline. Largely consistent with reported production of ODSs, CFC-11 abundance is near its peak, abundance of CTC and MCF is dropping but abundance of HCFC and halons is still increasing
27
Updated July 2003
Halons in the Atmosphere
Measured Atmospheric Concentrations of Halon-1211 at Cape Grim, Tasmania
3.6 3.2 2
Measured Atmospheric Concentrations of Halon-1301 at Cape Grim, Tasmania
2.4
(Source: Stratopheric Ozone 1996)
(Source: Stratopheric Ozone 1996)
H-1211 Mixing Ratio (pptv)
2.4 2.0 1.6 1.2 0.8 0.4 0.0 197 198 198 198 198 198 199 199 199 199 199 8 0 2 4 6 8 0 2 4 6 8
H-1301 Mixing Ratio (pptv)
2.8
1.6
1.2
0.8
0.4
0
Year
197 198 198 198 198 198 199 199 199 199 199 8 0 2 4 6 8 0 2 4 6 8
Year
Updated July 2003
28
If there were no Protocol, .....
The ozone depletion by the year 2050 would have been at least 50% in the mid latitudes in the northern half of the earth, 70% in the mid latitudes of the south, about 10 times larger than today. The UV-B radiation would have doubled in the north and quadrupled in the south in the same places. The ozone depleting chemicals in the atmosphere would have been 5 times higher. The implications of this increase would have been horrendous - 19 million more cases of nonmelanoma cancer, 1.5 million cases of melanoma cancer, 130 million more cases of eye cataracts.
29
Updated July 2003
Larger Ozone Losses Avoided Ozone-Damaging Stratospheric Chlorine/Bromine
20,000
No Protocol
Abundance (parts per trillion)
15,000
Montreal Protocol
10,000
5,000
Copenhagen Amendments
0 Year
20,000 18,000 16,000
Total Melanoma Deaths Non-Melanoma Deaths
Deaths Averted
14,000 12,000 10,000 8,000 6,000 4,000 2,000 0 1980
Updated July 2003
2000
2020
30 2040
2060
2080
2100
Year
Challenges
Many Parties are yet to ratify the Amendments to the Montreal Protocol. Meeting the control measures for production and consumption of CFCs in the developing countries: 1. The developing countries began their phase-out of ODSs with a freeze on CFCs from 1 July 1999, and a freeze from 1 January 2002 on Halons and Methyl Bromide. 2. In 2005, a 50% reduction in CFCs and Halons, and a 20% reduction in Methyl Bromide, is required.
Updated July 2003
31
Challenges
(continued.)
Meeting the control measure of complete phaseout of Methyl Bromide in the industrialised countries in 2005 and minimzing the quantities of Methyl Bromide used in those countries through Critical Use Exemptions. Meeting the control measure of 35% reduction of the production and consumption of HCFCS in the industrialised countries from 1 January 2004.
Updated July 2003
32
Challenges
(continued.)
Flow of illegal CFCs to the industrialised countries is of concern. Developing countries are concerned about increasing flow to their countries of CFCcontaining products, for example refrigerators, from countries, which have adopted Ozone-safe products. This will increase the demand for CFCs for maintenance of these products in developing countries implementation of ODS licensing system could check this problem. Global warming could increase ozone depletion. Also, HFCs, used as alternatives for CFCs in some applications, have global warming potential and are controlled by the Kyoto Protocol. These interconnections need to be studied.
33
Updated July 2003
Global Warming Potential of some Ozone Depleting Substances and Alternatives
Halon-1301 Halon-1301 Halon-1211 Halon-1211
3 1.1 1 1 1 0.8 0.6 0.6 0.11 0.1 0.065 0.055 0.022 10
Carbon Tetrachloride CFC-12
CFC-12
CFC-114 CFC-114 CFC-11
CFC-11
CFC-113 CFC-113 CFC-115 CFC-115
Methyl Bromide Methyl Bromide HCFC-141b HCFC-141b Methyl Chloroform Methyl Chloroform HCFC-142b HCFC-142b
HCFC-22 HCFC-22
HCFC-124 HCFC-124
HFC-32
HFC-32
HFC-134aHFC-134a 11000 10000 9000 8000 7000 6000 5000 4000 3000 2000 1000 0
0 1 2 3 4 5 6 7 8 9 10 11
Global Worming Potential (20 Year, CO2 = 1)
(Source: Scientific Assessment of Ozone Depletion)
Ozone Depletion Potential (CFC-11 = 1)
(Source: The Montreal Protocol)
Updated July 2003
34
Key Decisions
Decision XI/9 on control of export of products and equipment whose continuing functioning relies on Annex A and Annex B substances. The decision recommends each Party to adopt legislative and legislative measures, including labelling of products and equipment, to regulate the export and import, as appropriate, of products, equipment, components and technology whose continuing functioning relies on substances in Annex A and annex B of the Montreal Protocol..
Updated July 2003
35
Key Decisions
(continued.)
Decision X/9 on establishment of a list of countries that do not manufacture for domestic use and do not wish to import products and equipment whose continuing functioning relies on Annex A and Annex B substances.
On a voluntary basis, the decision invites Parties that do not manufacture for domestic use, products and equipment listed in the decision and do not permit the importation of such products and equipment from any source, to inform the Secretariat, that they do not wish to receive imports of such products and equipment.
36
Updated July 2003
Key Decisions
(continued.)
The Secretariat maintains a list of such Parties which is updated and distributed to Parties on annual basis. Decision XIV/7 on monitoring of trade in ozonedepleting substances and prevention of illegal trade in ODS. The decision, inter alia, invites Parties to report to the Ozone Secretariat fully proved cases of illegal trade in ODS to facilitate exchange of information. Such information received from the Parties will be disseminated periodically by the Secretariat to all Parties.
37
Updated July 2003
Licensing System
Article 4B (Licensing) of the Protocol Each Party is required to introduce a licensing system for import and export of ozone-depleting substances effective 1 January 2000 and report to the Secretariat on the establishment and operation of such a system within three months.
Updated July 2003
38
Compliance
The effective implementation of the Montreal Protocol and the considerable achievement in phasing out ozone-depleting substances owes a great deal to:
(a) Effective monitoring of compliance through the noncompliance procedure by the Implementation Committee and the Parties to the Montreal Protocol. (b) The financial mechanism of the Montreal Protocol through the Multilateral Fund as well as the Global Environmental Facility. (c) The Secretariat’s monitoring of information reporting, follow up action and appropriate recommendations for measures to be taken by the Parties.
Updated July 2003
39
Developing Countries
Fifteen years ago, the share of the developing countries in the total production of CFCs was 5.2%. In 2000, it is 58%. For Halons it was 5.7% fifteen years ago and is 93% now.
Updated July 2003
40
Lessons of the Montreal Protocol
Precautionary principle Sustainable development Integration of science with policy Recognition of the special situation, of the developing countries Need for international cooperation to solve transboundary environmental problems Common but differentiated responsibility among parties Flexibility to take into account scientific and technological developments over time.
41
Updated July 2003