Chapter 3 The Iron Age
212 = 4096 years ago => 2094 BC “You should hammer your iron when it is glowing hot” Maxim 262 - Publius Syrus 142 BC
At Ancients associated metals with Celestial Objects
• • • • • • Sun = Moon = Jupiter = Saturn = Mars = Mercury = Gold Silver Bronze Copper Iron Mercury
World history in 2000 BC
• The East
– The Indus culture is collapsing West – The Shang Dynasty (northern China) is rising
– Bronze Casting is well established
Rest
East
– Mesopotamia culture is waning – Start of Assyrian trading colonies in Anatolia (Hittites)
• The West
– Trade Routes, ceramics, Adena Mounds (c1000 BC) in Ohio
• The Rest
– Stonehenge being built in England – Egyptians are about done building the Pyramids
Assyrians trade with Hittites at Kanesh, Anatolia (Turkey)
• Recorded sales on clay tablets show dealings with the Hittites • Had self-fluxing ores near Black Sea
– magnetite and olivine
• Skilled metal workers in Chalybes tribe (Armenia) • Invasion in 1200 BC destroyed empire but spread the iron-making technology
Invasion of the Sea peoples c1200 BC
• From direction of today’s Greece - settled in Palestine as the hated Philistines • Destroyed culture, political and trade routes • Ended the Bronze Age (no tin) • Locals switched to iron as best local material
– just needed to improve the metal’s properties
Iron in The East
• The Iron Pillar near Delhi, India
– from 4th century AD – Made of wrought iron (sections hammered together) has yet to rust!!! – More data in Chapter 4
• Iron in The West???
– Meteorite in today’s Canadian Arctic had 10,000 Stone Age stone hammers strewn around it.
Iron in The Rest
• Earliest source = meteorites (iron+nickel)
– steel knife in King Tut’s tomb 1339 B.C.
• Copper mining by Egyptians at Timna, Israel
– Used iron ore as flux for copper smelting
• Bloomery iron (mixed with slag) could be hammered into shapes
– very weak and rusted quickly
More European links to the Iron Age
• Hallstatt, Austria
– Looking for salt (Roman salary) – using iron from 700-500 BC
• They spread the technology across Europe
– Spain, France, Denmark Norway, and
• the Celts in England
– horseshoes, iron rim chariot wheels, plowshare
Patina = Surface treatment
• Copper => Copper Oxide (green) • Aluminum => Aluminum Oxide (dull) • Zinc => Zinc Oxide (galvanized iron) • Iron=>Iron
Oxide=>Iron=>Iron Oxide
Wrought Iron is improved through Processing
• Hot working iron in carbon atmosphere introduces <1.2% carbon to surface (steeling)
– Becomes twice the strength of bronze
Wrought Iron is improved through Processing
• Hot working iron in carbon atmosphere introduces <1.2% carbon to surface (steeling) – Becomes twice the strength of bronze
• Quenching described in Ulysses' Odyssey (800 BC)
– harder but more brittle
Wrought Iron is improved through Processing
• Hot working iron in carbon atmosphere introduces <1.2% carbon to surface (steeling) – Becomes twice the strength of bronze • Quenching described in Odyssey (800 BC) – harder but more brittle
• Tempering (brief reheating to 700°C) helps improve Surface properties - reduce breakage
– Used today for drill bits, chisels, concrete nails, railroad wheels and even glass
Wrought Iron is improved through Processing
• Hot working in carbon atmosphere introduces <1.2% carbon to surface (steeling) – Becomes twice the strength of bronze • Quenching described in Odyssey (800 BC) – harder but more brittle • Tempering (brief reheating to 700°C) helps improve Surface properties - reduce breakage – Used for drill bits, chisels, concrete nails, glass, railroad wheels
• Annealing (Time & Temperature) - Tempers complete object
– Used in metals and glass processing
The Fayette connection to Annealing
• All glass products must be annealed to relieve internal stresses
– Window glass, light bulbs, headlights, TV picture tubes, drinking glasses, beer bottles
• 80% of all the glass products in the world are annealed in a furnace built in Fayette County • E.W. Bowman, Uniontown, PA
– the world’s leading producer of glass lehrs
Makin’ Metals Today
Flux
Mining
Grinding
Smelting Separating
Slag
Usin’ Metals
Finished Products
Forming
Alloys
Ingots+Slag
Homework: Religions
(1) Date the start of each religion, and (2) summarize its view of our relationship with nature. (3) How are metals related?
• The East
– S=Hinduism+Buddhism, N=Taoism+ Shintoism
• The West ??
– S=Aztecs+Incas, N=Norse+Celtic
• The Rest
– S=Judaism+Christianity, N=Islam+Greek/Roman
Transition Vitamin B12 = Cobalt + Cyanide
http://www.perl.com/pub/1999/08/onion/talk1.html
Recipe for Cornbread
• • • • • • • • 1 cup 1 cup 2 Tbsp 4 tsp 1/2 tsp 1 cup 1/4 cup 1 Yellow Cornmeal All purpose flour Sugar Baking Powder Salt Milk Shortening Egg