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a6

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  • pg 1
									                                                   Gly-Lys : A
                                               Gly-Glu-Lys : B



    Glu           Asp         Lys        Gly       Ala
(CH2) 2-COOH   CH2 -COOH   (CH2) 4-NH2             CH3           R
                                          B
                                               A                     2 1
          13 = PH                           1 = PH
                                                          B          3-1




6 = Gly             PHi
                              3                                      (

                          3       Ala-Asp-Ala-Gly-Glu-Asp




  ASP
                                                      NH2            Gly
                                                                      -
                                                      13 = PH        2-
                                                                PH   3-
                                                     PH              4-
           %20            %15

              H                          H                H
  HOOC - CH2 - C - COOH , NH2 - (CH2 )4- C - COOH , H2N - C - COOH
             NH2                       NH2              CH2
              Asp                      Lys              Ala
                                                                                  1



                                                                                  2
    105
                                                                  HCL

                (1 )                      ((1)                                )

                                                                        Hcl

                                                                                  2




   HIS    THR               LEU       ALa        1

                                                     H2N NH2



      R1 H R2                       R2
H2N - CH - C - CH - CO - ... - NH - CH - COOH (                1) H2N NH2
                                 2
           O
                           R1      H
            (          1)(H2N - CH - C - N - NH2 + ...)    H2N - CH - COOH
                                      O                          O
                                                                               2

                                                                                    1
                                                                                    2




                      2
                                OH              CH3
R = - CH2             THR R = - CH     Leu R = - CH2 - CH    (Ala) R = - CH3
        N NH                    CH3             CH3
            CH


                 pH                                                                 3




pH
                                                                pH


        1                                                                          pH

                          Ala = 6,02                        THR = 5,65
                          His = 7,58
                          Leu = 5,98                                           2

             (LTC)          T                                                       1

                                                                        3
                        T
                1




                    1
                                2



LTC                         2




            2

      LTC
ARN m
        ARN m
ADN




                                                   Gly - Arg
                                                  Gly - Glu
                                            Gly - Glu - Arg




           H = GLY , (CH2)2 COOH = GLU                R
      NH
NH2 - C - NH - (CH2)3 = Arg


                                   1 = PH
                                                          13 = PH
                                                                       CMH




          NH2     CH2   CO   NH    CH       CO    NH    CH     COOH
                                                                         =B
                                  (CH2)2               (CH2)

                                  COOH                  NH2



                                                                                          PH =1


PH = 13

                                                   PHi = 6                                = gly


                                            Gly
                                        6                                                  PH
                                                                         [                gly ]
      Gly                                                      -
            Lys                                                              -
                                                                                          PH = 6
                                                                   +                            -
                                                                       Gly       Gly      Lys
                                                                             PHi = PH=6


                                            Ala-Asp      A a-Gly         Gly-Asp
                                                                        PH =
                                            A a-Asp-Coo-                 COOH
                                                Coo-
                                                                                   Ala-Asp
   A a - Gly - COO-                 COOH                       Ala -Gly
                                                                   1
  Glu - Asp - COO-                  COOH             3             Glu -Asp
COO- COO-
                                                                   3
                                        PH=13                      PH
                                                                          .4

                                                                       PH=13
                                A a-Gly    A a-Asp       Glu-Asp
                                  -1         -2            -3




                                                                       PH=


                      Ala-Gly
                                A a-Asp     Gly-Asp
                                  -2          -3


                      PH=6        PHi                        Gly A a
                                 1




                                     -
                  Ala
                 Asp
                  Lys




           HCl           1         2

                                   2

                         His Ala
                            1


His
                         Ala
                                   2
                      Ala His
           C
H2N - CH - C - NH - CH - COOH + H2O
      CH          CH2

                                   3


                 Ph      Ala Phi
             PH              is   Phi


                   is
                  Ala
                   PH

      7,5           PH             ,



            1
                         1
                        LT

      LT                 2

                         3
                                  LT

LTC


LTC

CMH               LTC
                    CD8

(LTC + A9)
                                                  2




           2
                       H                          2 2

                 2 2

                  OH



                                             2
                                                 N       2


                N
          NH2 - C - NH - (CH2)3 - C - COOH
                                    2




NH2 - C - CO - NH - C - CO - NH - C - COOH
                   (CH2)
                                 NH2 - C - NH - (CH2)3
                        OH
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