00069859

COBRATEC 1,2,3 BZ-FG PRODUCT DISTRIBUTED BY / PRODUIT DISTRIBUÉ PAR Brenntag Canada Inc. WHMIS Number: 00069859 43 Jutland Road. Index: HCI8999/06D Toronto, Ontario Effective Date: 2006 October 1 M8Z 2G6 Date of Revision: 2006 October 1 (416) 259-8231 Website: http://www.brenntag.ca _______________________________________________________________________________________________ EMERGENCY TELEPHONE NUMBERS / EN CAS D'URGENCE Toronto, ON (416) 226-6117 Montréal, QC (514) 861-1211 Winnipeg, MB (204) 943-8827 Edmonton, AB (780) 424-1754 Calgary, AB (403) 263-8660 Vancouver, BC (604) 685-5036 _______________________________________________________________________________________________ This document consists of an English MSDS and a Product Tech Data Sheet. Le présent document comprend une fiche signalétique en anglais et une fiche technique. READ THE ENTIRE MSDS FOR THE COMPLETE HAZARD EVALUATION OF THIS PRODUCT. LIRE LA FICHE SIGNALÉTIQUE EN ENTIER POUR UNE ÉVALUATION COMPLÈTE DES DANGERS QUE REPRÉSENTE CE PRODUIT Material Safety Data Sheet COBRATEC 1,2,3 BZ−FG Product: 1238808 Section 1: PRODUCT INFORMATION Chemical family: Triazole. Supplier: MultiChem Inc. 1570 Ampere, suite 106 Boucherville, Quebec J4B 7L4. Emergency Phone Number: Canutec (613) 996−6666. Manufacturer: Various manufacturers. TDG classification: Not regulated. WHMIS classification: D2B Revision Date: 2006/10/01 DSL status: Appears on DSL. Section 2: HAZARDOUS INGREDIENTS C.A.S. 95−14−7 CONCENTRATION % Ingredient Name SILICA−AMORPHOUS, HYDRATED BENZOTRIAZOLE > 99 T.L.V. 10 MG/M3 LD/50 NOT AVAILABLE LC/50 NOT AVAILABLE 1910 MG/M3/3H RAT INHALATION 112926−00−8 0.5 MAX NOT AVAILABLE 560 MG/KG RAT ORAL 615 MG/KG MOUSE ORAL >1000 MG/KG RAT DERMAL Section 3: PHYSICAL DATA Physical state: Solid Appearance & odor: Off−white. Powder. Slight characteristic odor. 1238808 − COBRATEC 1,2,3 BZ−FG 1/5 Odor threshold (PPM): Not available. Vapour pressure (mm hg): 0.04 @ 20°C Vapour density (air=1): 4.1 Volatiles (%) By volume: None Evaporation rate Not volatile. (butyl acetate = 1): Boiling point (°C): 200−201°C / 5.0 mm hg Freezing point (°C): 94 − 99 PH: Not available. Specific gravity @ 20 °C: Not applicable. Solubility in water (%): 2 @ 20°C Coefficient of water\oil dist.: Not available. Section 4: FIRE & EXPLOSION DATA Flammability: Not flammable as per WHMIS. Conditions of flammability: At temperatures at or above flash point. Extinguishing media: Carbon dioxide, dry chemical, foam. Water spray may be ineffective. If water is used, fog nozzles are preferable. Special procedures: Self−contained breathing apparatus required. Firefighters should wear the usual protective gear. Auto−ignition temperature: Not available. Flash point (°C), method: Closed cup. 171.1°C Lower flammability Not applicable. limit (% vol): Upper flammability Not applicable. limit (% vol): Explosion Data Sensitivity to static discharge: Dust may be sensitive. Sensitivity to mechanical impact: Not available. Hazardous combustion products: Oxides of carbon (CO,CO2). Oxides of nitrogen. Hydrogen cyanide. Explosive power: High dust concentration could form explosive mixture with air. Section 5: REACTIVITY DATA Chemical stability: Product is stable. Conditions of reactivity: None known. 1238808 − COBRATEC 1,2,3 BZ−FG 2/5 Hazardous polymerization: Will not occur. Incompatible substances: Oxidizing agents. Hazardous decomposition See hazardous combustion products in section 4. products: Section 6: TOXICOLOGICAL PROPERTIES Route of entry: Eye contact, skin contact, skin absorption, inhalation and ingestion. Effects of acute exposure Eye contact: May cause severe irritation. Skin contact: May cause drying. Inhalation: May cause lung irritation. May cause discomfort. May cause coughing. Ingestion: Moderately toxic. Effects of chronic exposure: May cause conjunctivitis. May cause dermatitis. May cause asthma. Pre−existing respiratory diseases may be aggravated by exposure. Pre−existing skin disorders may be aggravated by exposure. LD50 of product, species & route: Not available for mixture, see the ingredients section. LC50 of product, species & route: Not available for mixture, see the ingredients section. Exposure limit of material: Not available for mixture, see the ingredients section. Sensitization to product: Not available. Carcinogenic effects: Not listed as a carcinogen. Reproductive effects: Not available. Teratogenicity: Not available. Mutagenicity: Component 2 has exhibited mutagenicity in bacteria. Synergistic materials: Not available. Section 7: PREVENTATIVE MEASURES Precautionary Measures Gloves/Type: Impervious gloves. Respiratory/Type: If TLV is exceeded, wear a NIOSH approved mist/dust respirator. Eye/Type: Chemical safety goggles. Footwear/Type: Safety boots per local regulations. 1238808 − COBRATEC 1,2,3 BZ−FG 3/5 Clothing/Type: Wear adequate protective clothes. Other/Type: Eye wash facility should be in close proximity. Emergency shower should be in close proximity. Ventilation requirements: Local exhaust at points of emission. Leak/Spill: Ventilate area. Wear appropriate protective equipment. Avoid generating airborne dust. Sweep up or shovel into appropriate containers. Waste disposal: In accordance with municipal, provincial and federal regulations. Handling procedures and Keep away from heat, sparks, and open flame. equipment: Use adequate ventilation. Wash thoroughly after handling. Keep out of reach of children. Avoid contact with skin, eyes and clothing. Do not smoke in handling or storage area. Wear suitable protective clothing. Avoid generating or breathing dust. Launder contaminated clothing prior to reuse. Do not ingest. Storage requirements: Store away from all sources of ignition. Store away from incompatible materials (See MSDS section 5). Keep container tightly closed. Store in a cool, dry and well ventilated area. Grounding and bonding procedures should be observed during the transfer of this material and during the storage of opened containers. Special shipping information: See transportation information in section 1. Section 8: FIRST AID MEASURES Skin contact: Wash thoroughly with soap and water. Remove contaminated clothing. If irritation persists, consult a physician. Thoroughly clean contaminated clothing before reuse. Eye contact: Immediately flush eyes with large amounts of water for at least 15 minutes, lifting upper and lower lids. Get prompt medical attention. Inhalation: Remove victim to fresh air. If symptoms persist, get medical attention. Ingestion: Get medical attention immediately. If conscious, give several glasses of water. Never give anything by mouth to an unconscious person. Keep airway clear. Additional information: To the best of our knowledge, the information contained herein is accurate. However, neither MultiChem Inc. nor any of its subsidiaries assumes any liability whatsoever for the accuracy or completeness of the information contained herein. Final determination of the suitability of any material is the sole responsibility of the user. All materials may present unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot guarantee that these are the only hazards that exist. 1238808 − COBRATEC 1,2,3 BZ−FG 4/5 Section 9: ADDITIONAL INFORMATION General note: This Material Safety Data Sheet was prepared from information obtained from various sources, including product suppliers and the Canadian Center for Occupational Health and Safety. Data prepared by: Conform−Action Data Systems A division of 2843471 Canada inc. 1975 Hymus Blvd. suite 230 Dorval, QC H9P 1J8 Tel: (514) 683−2060 Fax: (514) 683−1445 24 hr. 1−800−990−5093 support@netmsds.com. This MSDS was generated by Conform−Plus Application Service. Visit us at www.netmsds.com. 1238808 − COBRATEC 1,2,3 BZ−FG 5/5 COBRATEC® BF Metal Protection PMC Specialties Group, Inc • 501 Murray Road • Cincinnati, OH 45217 • Customer Service: 800-543-2466 COBRATEC® 1,2,3 BZ-FG COBRATEC® 1,2,3 BZ-FG is a corrosion inhibitor for copper and copper base alloys. COBRATEC® 1,2,3 BZ-FG is a proven high performance product used in a broad range of applications. COBRATEC® 1,2,3 BZ-FG forms a barrier film on the surface of copper, and precipitates copper from solution, thereby providing galvanic corrosion protection for other metals. FIELDS OF APPLICATION: ♦ GENERAL DESCRIPTION: Chemical Name: Synonyms: CAS #: Molecular Wt.: Formula: Appearance: Benzotriazole 1-H-1-1,2,3-Benzotriazole Azimidobenzene Benzene Azimide 95-14-7 119.12 C6H5N3 Off-white fine granules Direct Treatment On mill products, fabricated and decorative items, statuary. ♦ ♦ Circulating Cooling Systems Cooling towers and air conditioning systems. Functional Fluids Hydraulic fluids, specialty lubricants, automotive coolants, and metal working fluids. SPECIFICATIONS: Assay Moisture Ash Specif. 98.0% min 0.5% max 0.5% max Typical 99.5% 0.1% 0.2% ♦ Wrapping Tissue and Box Board Used for wrapping, interleaving, shipping, and storing mill products, or fabricated items. ♦ ♦ Corrosion Prevention Coatings Including lacquers and waxes. SOLUBILITY: SOLVENT WT. % @ 25°C Water 1.98 Isopropanol 53.9 Ethylene Glycol 50.7 White Mineral Oil* 0.1 *Petroleum oil formulations containing polar additives such as tricresyl phosphate and alkylbenzenesulfonic acid derivatives will increase the apparent solubility. Cleaners Soaps, detergents, and strong alkali or acid cleaners. METHOD OF APPLICATION: COBRATEC® 1,2,3 BZ-FG is incorporated in either aqueous or non-aqueous liquids at concentration between 0.1% and 2.0%. AVAILABILITY: COBRATEC® 1,2,3 BZ-FG is readily available from stock in 55 lb. fiber drums. Call Customer Service for more product information. Order Entry #:X18BT6595 Technical Bulletin #: COR4315BZ-FG EFFECTIVE: 10 OCTOBER 03 SUPERSEDES: 22 OCTOBER 02 INFORMATION WINDOW SOLUTIONS TB #: COR4331 TOXICITY/REGULATORY TB #: CORTR4315XX ANALYTICAL PROCEDURES APP #: 3001 AIDS TO FORMULATION APP #: 3005 INDUSTRIAL USE GUIDE APP #: 3010 DIRECT TREATMENT APP #: 3033 PMC Specialties Group, Inc. 501 Murray Road • Cincinnati, OH 45217 • Tel (800) 543-2466 • Fax (513) 482-7373 • CincyTech@pmcsg.com This information is believed to be reliable; however, all recommendations are made without guarantee, since the conditions of use are beyond our control. All products are sold without warranty, expressed or implied, and on the condition that purchasers shall make their own tests to determine the suitability of such products for their purpose and that all risks are assumed by the user. Statements contained herein shall not be a recommendation to infringe any patent.