GFS Chemicals Organic Manufacturing - GFS Organics

							GFS Chemicals, Inc.
Innovation and Commercialization through Chemistry
ISO 9001:2008 Certified
Agenda

 •Introduction
 •Reagents-Catalog
 •Inorganics
 •Organic Chemical Division
 •Electronic Chemicals
 •Discussion/Action
Decades of both chemical and engineering experience
allow GFS to address opportunities in highly specialized
     custom inorganic and organic manufacturing.
Background
  •1928-Founded, Columbus Ohio.
  Perchlorate salts defined early
  business.
  •Third generation privately held
  company.
  •Global Business.
  •100 Employees
  •Commercial quantities from
  gram samples up to metric ton
  quantities.
  •Customer base ranges from
  development companies to
  Fortune 500 companies.
International Operations

  • Sourcing Operations in
  • Shanghai China
  • Serving over 80 countries
    worldwide
  • www.GFSInternational.com
     – Japanese
     – German
     – French
     – Spanish
Customer Support

 • 96%+ of orders ship on time
 • GFS maintains inventory for the
   most popular reagents
 • 95% Lead Time Accuracy
 • 80 Years excellent product
   quality
 • Knowledgeable/Technical Staff
 • Customer Satisfaction scores are
   among the highest in the
   industry
Customer Benefits

  • Problem Solving Chemists
    Complement Your Project
    Team
  • Supporting Major Industry
    Around the Globe
  • Manufacturing High Quality
    Chemicals up to metric tons
  • Custom Packaging, Drying
    and Production
  • Competence
  • Your Global Sourcing artner
Industries Served

  •   Environmental
  •   Semiconductor
  •   Pharmaceutical
  •   Flavor & Fragrance
  •   Superconductivity
  •   Petrochemical
  •   Agricultural
  •   Automotive
  •   Defense
  •   Biotechnology
  •   Power and Energy (Fuel
      Cells, Batteries, etc)
Industries Served

  • Electronics
  • Chemicals
  • Aerospace
  • Polymers
  • Coatings
  • Catalysts
  • Optics
  • Contract Manufacturing
  • Water treatment and
    Analysis
  • Beverage/Dairy
  • Quality Control Laboratories
Safety and Environment

  • GFS is a Tier II Chem Stewards organization
    focused on safety improvement practices and
    waste minimization, recovery policies and
    controls

  • Selected Employees are DOT, IATA and IMO
    certified to support all modes of material
    logistics to ensure safe and legal shipments
    world wide.
Compliance and Quality

  • GFS organic production operations are a
    zero discharge facility compliant with all
    local and federal EPA regulations

  • We adhere to ISO 9001:2008 standards for
    quality practices and have been ISO
    certified since 1997
GFS Catalog Operations


   • 70,000 Sq Ft. Operation, Manufacturing and
     Distribution Center
   • Repack and Fulfillment Center
   • Private Label Operation
   • Amco Clear Water Analysis Division
   • Bottling Operations
   • Quality Control Labs
   • Manufacturing and Sourcing over 4000
     Analytical Reagents
Inorganic Bulk
Manufacturing

U.S. Based Inorganic
Product Development
and Manufacturing
Bulk Inorganics

   • Lithium Perchlorate (Battery Electrolyte & Organic
     Catalyst)
   • Lithium Carbonate, 99.998% (Lithium Crystals &
     Organic Catalyst)
   • Lithium Iodide (Battery Electrolyte & Organic Catalyst
   • Precious Metal Salts (Silver Nitrate)
   • Ammonium Borane (OSU & EBA &D)
Inorganic Specialties

   • Perchloric acid & Salts
   • Ceric Ammonium Nitrate (Etchants & Catalysis)
   • Purified compounds for metal complexes
   • Ultra dry salts for moisture sensitive applications
   • Rare Earths, Lithium, Sodium and Magnesium salts
     & solutions
   • Precious metal ion exchange resins
Bulk Inorganic Salts

    •   Nitrates       •   Oxalates
    •   Sulfates       •   Acetates
    •   Chlorides      •   Formates
    •   Perchlorates   •   Phosphates
                       •   Citrates
    •   Carbonates
    •   Periodates
Specialty Inorganics

  • Rubrene (OLED & Dye)
  • Anhydrous Cerous Chloride (Fuel Cell & Grignard
    Initiator)
  • Hydroxyquinoline, Aluminum Salt (OLED)
  • Polyoxometalate complexes
Organic
Manufacturing


Leaders in the
development and
commercialization of
specialty alkynes and
derivatives
Markets Served

  •   Electronics/Semiconductors
  •   Pharmaceutical/Biotechnology
  •   Agribusiness (Pesticides $Herbicides)
  •   Polymers
  •   Catalysts
  •   Flavors & Fragrances
  •   Dyes & Colorants
Product Offering

  • GFS Chemicals remains focused on a core set of
    synthetic methodologies

  • In support of alkyne production, we offer down
    stream intermediates such as olefins,
    heteroaromatics and heterocycles

  • We offer over 2000 organic chemicals in our product
    base
Core Synthetic Chemistry

  Na & Li/Liquid Ammonia
    Chemistry
     –   Alkylations
     –   Aminations
     –   Reductions (Birch, trans)
     –   Ethynylations
  Halogenations
     – Brominations
     – Chlorinations
     – Iodinations
Core Synthetic Chemistry

   Alkyne Chemistry
   –   Eliminations
   –   Ethynylations
   –   Sonogashira
   –   Glaser Coupling
   –   Cadiot-Chodkiewicz
   –   Click Chemistry
Core Synthetic Chemistry

  • Organometallic
    Chemistry
     – Grignard
     – Alkyl lithium
     – Coupling (Suzuki, Stille,
       Negishi, Kumada)
     – Heck Reaction
     – LI/NA Amide
     – Cis-reductions
Core Synthetic Structures

   • Alkynes                • Olefins
     –   Aromatic            –   Cis/trans
     –   Terminal            –   En-yne
     –   Internal            –   Cyclic
     –   Alcohols            –   Grignards
     –   Ketones             –   Vinyl
     –   Acids               –   Aryl
     –   Conjugated          –   Alkyl
Core Synthetic Structures

  • Halogenated Organics • Heteroaromatic
    –   Alkynes             –   Quinolines
    –   Olefins             –    Indoles
    –   Alkyl               –   Pyrimidines
    –   Aromatic            –   Bipyridines
                            –   Phenanthrolines
                            –   Terpyridines
Electronics
Chemicals
GFS Serves a Range of
Electronics Applications
•Conductive Inks
•Thermally Conductive
Interface Materials
•Thermal Imaging
•Electro-Optic Materials
•Metal Polishing
•Photo Resists
•OLED’s
Function/Technology

    Function                         Technology
    Chromophores                     Alkynes
    Photo Chromic Indicators         Acetylene
    Oxidation Reduction Indicators   Phenanthrolines, Bipyridine
    Fiber Optics                     Heterocyclic Amine Ligands
    Thermally Conductive Interface   Alkynes
    Materials
    Electroplating Chemicals         Alkynes
    Electro-optics Materials         Alkynes
    OLED’s                           Bis tips ethynl pentacene
    Photo Voltaics                   Alkynes
Electronics Products

          109                     294                    770                  1597
      2,2’-bipyridine         Bathocuproine,        4,4-dicarboxy-              Tris-
                            Sulfonated, Sodium      2,2’biquinoline      (Bathophanthroline)
                                   Salt             Potassium Salt          Ruthenium (II)
                                                                              Chloride

         3110                    3282                   3287                  3294
   1,1-diphenyl-2-propyn-   2-phenyl-3-butyn-2-   1-phenyl-2-propyn-1-    Propargyl Acrylate
            1-ol                    ol                     ol

         3340                    3395                   3721                  3906
      (Trimethylsilyl)      3-amino-3-methyl-1-   Tert-butyl Magnesium   3-methyl-1-hexyne
         Acetylene                butyne                 Chloride


         3979                    5195                   5515                  5382
     Hexylmagnesium         Isopropylmagnesium     3-ethyl-1-heptyne     2,4,6-Tri(4-pyridyl)-
        Bromide                   Bromide                                   1,3,5-Triazine
Acetylene Chemistry
                         O

                             O




  HC   CH    R1C   CR2




                                 (CH2)9CH3
Propargylic Amines


                          N




                              N
                              H
       H2N



                     N
                     H


                     NH
Specialty Thiophenes

                                            Br


 •OLED/Conductive Polymer
                                            S        S
 Applications
 •Pharma and Biotech
 Applications
                                O
                                    H                    O       O

                                        H
                            S                                S
                                    O

                                                 R



                                                 S
Why GFS Chemicals

  •Broad Product Range

  •Experienced

  •Customer Focus

  •Customer Service
Discussion/Action

  • Questions

  • Areas of interest or cooperative effort opportunities

  • Consider GFS Chemicals for your future Specialty
    Organic Chemicals needs