ARGON

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MATERIAL SAFETY DATA SHEET Last changed: 25/Nov/1999 Internal no.: Rev. LdV-3 Replaces date: 18/Nov/1999 ARGON 1. PRODUCT AND COMPANY TRADE NAME APPLICATION ARGON WELDING PRODUCTS Producer/Importer Address Zipcode & City Country Telephone Fax Contactperson Issued by Emergency number UNITOR ASA P.O. BOX 300 Skøyen 0212 OSLO Norway +47 22 13 14 15 +47 22 13 45 00 Product Group Repair & Maintenance Leen de Visser (+31 6 538 63736) Int. +44 1865 407333 Int. +1 703 5273887 USA (800) 424-9300 Greece Int. +30 1 7793777 2. COMPOSITION OF PRODUCT No 1 Legend Ingredients name Agon (compressed) CAS-NO 7440-37-1 Conc.(weight%) >99 % Classification T+=Very toxic, T=Toxic, C=Corrosive, Xn=Harmful, Xi=Irritant, IK=No classification required, E=Explosive, O=Oxidising, F+=Extremely flammable, F=Very flammable, Fo=Flammable, N=Dang. to the environment, Mut=Genetoxic, Sens=Sensitizing, Carc=Carcinogen, Repr=Causes birth defects 3. HAZARD IDENTIFICATION Gas.Colourless.Odourless. Not regarded as a health or environmental hazard under current legislation. 4. FIRST AID GENERAL Move to fresh air, keep the patient warm and at rest. INHALATION See "General". SKIN CONTACT Is not considered a potential risk. 1/6 MATERIAL SAFETY DATA SHEET Last changed: 25/Nov/1999 Internal no.: Rev. LdV-3 Replaces date: 18/Nov/1999 ARGON EYE CONTACT Is not considered a potential risk. INGESTION Is not considered a potential risk. 5. FIRE FIGHTING MEASURES PROPER FIREFIGHTING EQUIPMENT Cool the cylinder with large amounts of water from a safe distance. IMPROPER FIREFIGHTING EQUIPMENT not applicable FIRE AND EXPLOSION HAZARDS Containers may explode if heated. The substance is not combustible. PERSONAL PROTECTION WHEN FIREFIGHTING If possible, fight fire from protected position. Use self-contained breathing apparatus if substance is involved in fire. OTHER INFORMATION Do not move any cylinder which has been involved in fire until it is cold. 6. ACCIDENTAL RELEASE MEASURES SAFETY MEASURES TO PROTECT PERSONS Evacuate personnel to safe area. Provide fresh air supply to closed/confined spaces.Vapours are heavier than air and may cause asphyxiation by reducing oxygen available for breathing. SAFETY MEASURES TO PROTECT THE ENVIRONMENT Not required PROPER METHODS FOR DAMAGE LIMITATION AND CLEANUP Stop leak if possible without risk. OTHER INFORMATION Vapours are heavier than air and may cause asphyxiation by reducing oxygen available for breathing. 7. HANDLING AND STORAGE HANDLING Suck back of water into the cylinder must be prevented. HANDLING ADVICE Use only equipment and materials approved for this gas. STORAGE Protect gas cylinders against direct sunlight, precipitation and corrosive environment.Secure gas cylinders to prevent them from falling; avoid shocks and heating. OTHER INFORMATION Do not expose cylinders to temperatures above 45 ºC.Gas cylinders must be equipped with valve protection caps during transport. 8. EXPOSURE CONTROL AND PERSONAL PROTECTION 2/6 MATERIAL SAFETY DATA SHEET Last changed: 25/Nov/1999 Internal no.: Rev. LdV-3 Replaces date: 18/Nov/1999 ARGON EXPOSURE CONTROL Occupational exposure limit value: Not applicable. RESP. PROTECTION Not relevant. EYE PROTECTION Wear suitable filter lenses when welding / cutting. HAND PROTECTION Wear work gloves which are suited to the work area. SKIN PROTECTION Not applicable OTHER INFORMATION Wear safety boots when handling cylinders 9. PHYSICAL AND CHEMICAL PROPERTIES Form Colour Odour Solubility Melting point/range Expl. limit LEL-UEL., %-%: Vapor pressure Decomposition temp. pH Solution Flash point Molecular weight Auto Ignition temp. Rel. vapor density (air=1) Air reactive Gas. Colourless. Odourless. Not applicable -189 ºC N/A N//A N/A N/A N/A N/A N/A 1.4 N/A Density Solubility in water Saturation conc. Rel. density sat. air (air=1) Boiling point/range pH concentrate: Viscosity Smelling limits lo-hi Rel. evap. velocity Water reactive N/A 0 N/A 1.4 -186 ºC N/A N/A N/A N/A N/A OTHER INFORMATION N/A = Not applicable. N/E = Not established. 10. STABILITY AND REACTIVITY STABILITY No particular stability concerns. MATERIALS TO AVOID No hazardous reactions known. HAZARDOUS DECOMPOSITION PRODUCTS None. OTHER INFORMATION Gas cylinders must not be exposed to shock and heat.Store containers so that they are not exposed to shocks, falls etc. 3/6 MATERIAL SAFETY DATA SHEET Last changed: 25/Nov/1999 Internal no.: Rev. LdV-3 Replaces date: 18/Nov/1999 ARGON 11. TOXICOLOGICAL INFORMATION GENERAL Not known or expected to be harmful to health in normal use. INHALATION Not hazardous by inhalation Vapours are heavier than air and may cause asphyxiation by reducing oxygen available for breathing. SKIN CONTACT No hazardous reactions known. The gas is very cold when it escapes from the cylinder and skin contact may cause frostbite. EYE CONTACT No hazardous reactions known. The gas is very cold when it escapes from the cylinder and skin contact may cause frostbite. INGESTION Not regarded as a potential route of exposure. CANCER Not known. 12. ECOLOGICAL INFORMATION MOBILITY Not applicable BREAKDOWN Not relevant. ACCUMULATION Does not bioaccumulate. ECOTOXITY No ecological damage is known or expected in normal use. 13. DISPOSAL Return gas cylinder with residual pressure to supplier. 14. TRANSPORT INFORMATION GENERAL Goods classified for transport UN-no: PROPER SHIPPING NAME Flash point Packing group : : : : : YES 1006 Argon, compressed N/A N/A 4/6 MATERIAL SAFETY DATA SHEET Last changed: 25/Nov/1999 Internal no.: Rev. LdV-3 Replaces date: 18/Nov/1999 ARGON Label information: ADR Class Item. Haz. id. no. ERI-Card TREM-Card Labeltype Labelcolour : : : : : : : 2 1A 20 2-03 20G30 2 Green. IMDG-CODE Class Subsidiary risk Marine pollutant EMS MFAG Page Number Labeltype Labelcolour : : : : : : : : 2.2 N/A NO 2-04 620 2105 2 Green. IATA-DGR Class Subsidiary risk Labeltype Labelcolour Aircraft Cat. : : : : : 2.2 -2 Green. Passenger & Cargo aircraft US DOT Class Marine pollutant RQ Labeltype Labelcolour : : : : : 2.2 NO N/A 2.2 Green. GENERAL Gas cylinders must be equipped with valve protection caps during transport. Packaging: Approved gas cylinder. 15. REGULATORY INFORMATION Classification R-PHRASES Not required S-PHRASES 5/6 MATERIAL SAFETY DATA SHEET Last changed: 25/Nov/1999 Internal no.: Rev. LdV-3 Replaces date: 18/Nov/1999 ARGON S-9 Keep container in a well-ventilated place. S-23 Do not breathe gas/fumes/vapour/spray REFERENCES Classified according to European directive on classification of dangerous preparations 90/492/EEC. OTHER INFORMATION The product is labelled in accordance with EU directive 88/379. 16. OTHER INFORMATION ISSUED: 25/Nov/1999 VENDOR NOTES The safety data sheet fulfills requirements specified in Directive 93/112/EEC. The safety data sheet has been prepared on the basis of information given by our suppliers and our present knowledge. Information in this safety data sheet is based on our present knowledge, and is intended to be a description of the health and safety aspects of the product.Information given applies only to the product itself, and not in combination with other products or in any processed form, unless this is specified in the text. We believe that all information in this safety data sheet (which replaces all previous versions) was correct at the date of issue. 6/6

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