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Polyatomic Ions
Binary vs. Polyatomic
So far, we have only been talking about
binary compounds (compounds made up
of only 2 different elements).
Many compounds are polyatomic
(consisting of more than 2 different
elements).
Several common polyatomic ions exist,
consisting of 2 or more different
nonmetals joined together by covalent
bonds.
The formulas, names and charges of the
most common ones must be memorized.
Name Chemical Formula
ammonium NH4+
hydroxide OH–
carbonate CO32–
nitrate NO3–
phosphate PO43–
sulfate SO42–
chlorate ClO3-
acetate C2H3O2-
Rules for Dealing with Polyatomics
Treat the polyatomic ion as one ion –
don’t think about the different elements.
Most end with “-ate” instead of “-ide”.
When you need to indicate more than
one polyatomic, place it in brackets first.
Examples
Write the formula for potassium hydroxide.
K+ OH¯
Use the cross-over method to get the
formula.
KOH
Examples
Write the formula for sodium sulfate.
Na+ SO42-
Use the cross-over method to get the
formula.
Na2SO4
Examples
Write the formula for ammonium sulfide.
NH4+ S2-
Use the cross-over method to get the
formula.
(NH4)2S
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