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					Eni Schmiertechnik
MATERIAL SAFETY DATA SHEET according to 1907/2006/EC
Date of issue:     01.06.2004                                       Revised on:   21.12.2009
                                                                                                   Agip Rotra CT 10W      Page 1 of 4



1. Identification of substance/preparation and of the company.
   Identification of the substance or
   preparation:                           AGIP Rotra CT 10W
   Type of product and use:               Gear oil
   Company identification:                Eni Schmiertechnik GmbH
   Address and telephone no.:             Paradiesstr. 14, 97080 Würzburg
                                          TEL. (+ 49) 931 - 900 98-145 FAX (+ 49) 931-98442
   Emergency telephone (24 h):            Advisory office in case of poisoning: (+ 49) 228-19240


2. Hazards identification.
   Hazards description:               R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
                                      aquatic environment
   Informations pertaining to special See also item 11, 12 and 15.
   dangers for human and environment: Product can build up a film on the water surface, which can inhibit the oxygen
                                      exchange.


3. Composition/information on ingredients.
   General description:                   Mineral oil, additives.
   Chemical identification:              Calcium long-chain alkylphenate sulfide, 1,2 - 2,0% w/w, Classification: R53
                                         CAS/EINECS: Confidential
                                         Zinc dialkyl dithiophosphate, 1,0 - < 1,8% w/w, Classification: Xi; R36/38,
                                         CAS: 68649-42-3
                                         Phenol, 4-dodecyl-, < 0,5% w/w, Classification: Repro. Cat.3; Xi, N; R38-50/53-62,
                                         CAS: 104-43-6
                                         Zinc alkarylsulfonate, < 0,5% w/w, Classification: Xi; R36/38, CAS/EINECS: Confidential
                                         Alkarylpolyether, < 0,5% w/w, Classification: Xi, N; R36/38-51/53, CAS/EINECS:
                                         Confidential
   Full text of hazard symbols and R-phrases: See section 16.


4. First aid measures.
   Skin contact:                          At skin contact wash immediately with plenty of soap and water. Remove dirty, soaked
                                          clothing immediately. In case of skin irritation (reddening, etc.) get medical attention.
   Eye contact:                           At eye contact rinse immediately with plenty of water for several minutes and get
                                          medical attention. Carry along Material Safety Data Sheet.
   Ingestion:                             Do not induce vomiting, get immediate medical attention. Danger of aspiration.
   Inhalation:                            Provide affected person with fresh air. In case of accident or illness/indisposition, seek
                                          medical advice immediately (show doctor directions for use or Safety Data Sheet if
                                          possible).


5. Fire fighting measures.
   Extinguishing media:
   - Suitable:                            Foam, dry fire-extinguishing media, CO2, water spray jet. Cool containers at risk with
                                          water.
   - Not to be used:                      Full water jet.
   Particularly hazardous through the     In case of fire it may be formed: Toxic pyrolysis products, formation of flammable
   material, its combustion products or   vapour/air mixtures possible, smoke, carbon oxides, nitrogen oxides, sulphur oxides,
   developed gases:                       phosphor oxides, aldehydes, hydrocarbons, mercaptanes, zinc oxide, calcium oxide,
                                          hydrogen sulphide. Hot product forms flammable vapours.
   Special protection equipment
   for fire fighting:                     Mount air recycling independent breathing apparatus, depending on the size of fire, fully
                                          protection.
   Other information:                     Dispose contaminated fire-fighting water according to the local regulations.


6. Accidental release measures.
MSDS/10/1209/0314_KE
Eni Schmiertechnik
MATERIAL SAFETY DATA SHEET according to 1907/2006/EC
Date of issue:    01.06.2004                                    Revised on:      21.12.2009
                                                                                                   Agip Rotra CT 10W      Page 2 of 4


   See item 13, as well as personal protection equipment item 8.
   Person-related safety precautions:       Take care of sufficient ventilation. Remove ignition sources, do not smoke. Avoid eye
                                            and skin contact as well as inhalation. Never put rags contaminated by the product
                                            into cloth-pockets. Particular danger of slipping on leaked/spilled product.
   Environmental protection measures:       Stem if larger quantities are leaking. Do not allow to enter the sewage system. Avoid
                                            penetration into surface and ground water as well as ground. Inform local authorities in
                                            case of accidental release in the sewage system.
   Measures for cleaning/collecting:        Absorb with liquid-binding material (e. g. universal binder). Dispose of the material
                                            collected according to item 13.


7. Handling and Storage.
   Information for safe handling:           See item 6. Avoid eye and skin contact. Avoid formation of oil mist. Keep away from
                                            ignition sources - do not smoke. Wash hands before breaks and at the end of work.
                                            The usual precautionary measures should be adhered to in handling chemicals and
                                            mineral oil products. Observe the information on the label as well as the using
                                                                                                                    C.
                                            directions. Do not heat at temperatures close to the Flashpoint; T > 220°
                                            If necessary take measures against electrostatic charge / explosion protection.
   Fire classification:                     B (fires of liquid or liquefying materials)
   Storage:
   Requirements to be met by                Do not store in passages and stairwells. Store only closed in original containers.
   storerooms and containers:               Do not store together with fire supporting or self-ignitable materials.
   Special storage conditions:              See item 10. Store closed and protected from humidity. Store cool. Do not store over
                                              C.
                                            50°


8. Exposure controls/personal protection.
   Exposure limit values:
   Chemical name:                           Mineral oil mist, AGW-, BGW-, TWA-value: 5 mg/m³ (TLV-ACGIH)
   Exposure controls:
   Occupational exposure controls:          Ensure sufficient aeration. This can be achieved by local exhaust ventilation or
                                            general exhaust air. If this is not sufficient to keep the concentration below the AGW-
                                            values suitable respiratory protection apparatus has to be worn. See also section 7.
   Respiratory protection:                  Not required in normal case. At oil mist formation: At vapour formation: Filter A - P2
                                            (EN 141).
   Hand protection:                         Suitable are for example hand gloves from the company KCL GmbH, D-36124
                                            Eichenzell, e-mail: vertrieb@kcl.de with the following specification (test according to
                                            EN 374):
                                            In full contact / splash contact:
                                            Article 731 Camatril, Glove material: Nitril, Layer thickness (min). 0,33 mm,
                                            Breakthrough time 480 min. Article 740 Dermatril, Glove material: Nitril, Layer
                                            thickness (min.) 0,11 mm, Breakthrough time 30 min.
                                            The protective gloves to be used must comply with the specifications of EC Directive
                                            89/686/EEC and the resultant standard EN374. The breakthrough times stated above
                                            were determined by KCL in laboratory tests according to EN374 and are only
                                            authoritative for the recommended glove types.
                                            Skin cream is recommendable.
   Eye protection:                          In case of danger of eye contact. Safety glasses tightly sealed with side protection
                                            shields (EN 166).
   Protective clothing:                     Protection cloth (e.g. safety shoes EN 344, working cloth with long sleeves).
                                            According to working process wear apron, boots (EN 347).
   Environmental exposure controls:         See section 6.


9. Physical and chemical properties (typical values).
   Appearance:                              Liquid
   Odour:                                   Characteristic
   Colour:                                  Yellow, brown
   Boiling point/range:                     > = 320°C

MSDS/10/1209/0314_KE
Eni Schmiertechnik
MATERIAL SAFETY DATA SHEET according to 1907/2006/EC
Date of issue:    01.06.2004                               Revised on:       21.12.2009
                                                                                             Agip Rotra CT 10W     Page 3 of 4


   Rel. Density at 15° C:              855 - 880 kg/m³ (DIN 51 757)
   Vapour density (air = 1):           Vapours, heavier than air
   Vapour pressure:                    1013 mbar (370°  C)
   Viscosity at 40° C:                 30 - 110 mm²/s (DIN 51 562)
   Water solubility:                   Insoluble
   Flashpoint:                                C
                                       > 220° (DIN ISO 2592)
   Ignition temperature:                      C
                                       > 250° (ASTM E 659)
   Explosion limits:
   - Lower:                            In case of formation of oil sprays, ~ 0,6 Vol.%
   - Upper:                            In case of formation of oil sprays, ~ 6,5 Vol.%
   Partition coefficient (P o/w):      No data available


10. Stability and reactivity.
   Conditions to avoid:                See item 7. Not to be expected at correct storage and handling (stable).
                                       Decomposition: > = ~ 250° C
                                       Formation of flammable vapour/air mixtures possible: > 220°C
   Materials to avoid:                 See also item 7. Avoid contact with strong oxidants.
   Hazardous decomposition products:   See item 5.


11. Toxicological information.
   General remarks:                    Toxicological data for the preparation are not available. The preparation was
                                       evaluated on the basis of the calculation procedure of the preparation Directive
                                       1999/45/EC.
   CMR effects (carcinogenity,         On basis of present data the components (base oil & additives) in this preparation do
   mutagenicity and toxicity for       not meet the criteria for classification as CMR category 1 or 2. This information is
   reproduction):                      based on our present-day knowledge.
   Other information.                  It can occur: Eye irritation.
                                       In case of prolonged exposure: Skin dehydration. Skin irritation. Dermatitis.


12. Ecological information.
                                       Eco-toxicological data of the preparation are not available. The preparation was
                                       evaluated on the basis of the calculation procedure of the preparation Directive
                                       1999/45/EC and due to its eco-toxicological hazards classified. See items 2 and 15 for
                                       details.
   Persistence and degradability:      Not readily biodegradable (according to OECD criteria). Inherently biodegradable
                                       (main ingredient indication).
   Behaviour in waste water            Can be separated mechanically.
   treatment plants:                   Contains no AOX according to its formulation.


13. Disposal considerations.
   Appropriate disposal / product:     Saturated contaminated cloth, paper or other organic material pose a fire danger and
                                       have to be collected and disposed in a controlled way.
   Waste code EC:                      The named waste codes are recommendations because of the likely use of this
                                       product. Due to specific use and disposal circumstances at the user other waste
                                       codes may be suitable.
                                       13 02 05 - mineral-based non-chlorinated engine, gear and lubricating oils
   Recommendation:                     Send to a facility for oil re-refining in compliance with official regulations.
   Uncleaned packaging:                See above. Observe official regulations. Non-contaminated packages can be re-used.
                                       Packaging that cannot be cleaned have to be disposed like the product.



14. Transport information.
   RID/ADR:                            Does not belong to any class of danger

MSDS/10/1209/0314_KE
Eni Schmiertechnik
MATERIAL SAFETY DATA SHEET according to 1907/2006/EC
Date of issue:    01.06.2004                                     Revised on:      21.12.2009
                                                                                                    Agip Rotra CT 10W       Page 4 of 4


   ICAO/IATA:                                Does not belong to any class of danger
   IMO-IMDG code:                            Does not belong to any class of danger
   Additional information:                   No hazardous material as defined by the above mentioned transport regulations.


15. Regulatory information.
   Classification according to EC Guidelines:
   Symbols:                                 ---
   Indications:                             --
   R-Sets:                                  R52/53 Harmful to aquatic organisms, may cause long-term adverse effects in the
                                                      aquatic environment
   S-Sets:                                  S29       Do not empty into drains
                                            S35       This material and its container must be disposed of in a safe way
                                            S61       Avoid release to the environment. Refer to special instructions / Safety Data
                                                      Sheets
   Voluntarily:                             S13       Keep away from food, drink and animal feedingstuffs
                                            S24/25 Avoid contact with skin and eyes
                                            S26       In case of contact with eyes rinse immediately with plenty of water and seek
                                                      medical advice
                                            S28.b After contact with skin, wash immediately with plenty of water and soap
   National regulations:
   Water hazardous class (WGK):             2 (self-classification, VwVwS)
   Additions:                               Not applicable
   Restrictions to observe:                 Not applicable
   Material Safety Data Sheet is available on request for professional users.


16. Other information.
   These details refer to the product in delivery condition.
   Storage class according to VCI:            10
   Revised particulars:                       1 - 16


   Symbols named in item 3 (not classification of the preparation!):
   Xi       Irritant
   N        Hazardous for the environment

   R-phrases named in item 3 (not classification of preparation!):
   R38      Irritating to skin
   R53      May cause long-term adverse effects in the aquatic environment
   R62      Possible risk of impaired fertility
   R36/38 Irritating to eyes and skin
   R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment
   R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment


   This information relates only to the specific product and may not be valid if the product is used in combination with any other
   material or in any process.
   The informations in this sheet are according to our best knowledge at the date of printing.




MSDS/10/1209/0314_KE

				
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