Corrosion of Materials and Testing Methods in H2S Environments

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							Fatigue Performance of High
   Strength Riser Materials
        RPSEA Project No. DW 1403

                   TAC Meeting
                  March 3, 2009
                  Houston, Texas

                  Presented by
             Stephen J. Hudak, Jr.
       Materials Engineering Department
         Southwest Research Institute


   Research Partnership to Secure Energy for America
                             1
    Background and Motivation
   Quest for offshore O&G leading to deeper
    water, increased temp. & pressure

   These conditions preclude the use of
    conventional riser materials

   New higher strength materials are needed

   The fatigue resistance of new materials is
    unknown, particularly in aggressive
    environments

                         2
          Project Objective
   Assess the fatigue resistance of new
    high strength HPHT riser materials in
    representative environments




                      3
             Project Benefits
   Results on corrosion-fatigue
    resistance of new materials will:
    • Decrease development time
    • Reduce technical risks
    • Enable optimum material selection
    • Provide the basis for fatigue design of light-
      weight HPHT risers
    • Enable NDE requirements to be set
    • Enable feasibility of more deepwater
      development projects

                            4
              Project Tasks
   Task 1: Fatigue Crack Growth Rate
            (FCGR) Testing

   Task 2: S-N Fatigue Life Testing

   Task 3: Recommended Phase 2 Work

   Task 4: Program Management,
            Tech. Transfer and Reporting


                        5
                             RPSEA PM
                              RPSEA PM
                            Jim Chitwood
                            Jim Chitwood
                               Chevron
                               Chevron
                                                      Industry
                                                     RPSEA PM
                                                 Working Committee
Project Team                                             Jim
                                                 Himanshu Gupta, BP
                                                Steven Shademan, BP
                                                        Chitwood
                                                    (Champions)
                                                        Chevron
                             SwRI®®PM
                             SwRI PM
                            Steve Hudak
                            Steve Hudak



  Task 0:
   Task 0:      Task 1:
                Task 0:       Task 2:
                               Task 0:       Task 3:
                                             Task 0:     Task 4: 0:
                                                            Task PM
Spec Design
Spec Design     FCGR
              Spec Design       S-N
                            Spec Design     Phase 2
                                           Spec Design   Spec Trans,
                                                         Tech Design
 and Prep
  and Prep     and Prep
               and Prep      Fatigue
                             and Prep         Plan
                                            and Prep      Reporting
                                                           and Prep
  Jason
  Jason          Jim
                Jason          Wally
                               Jason         Steve
                                             Jason          Steve
                                                            Jason
  Patton
  Patton        Feiger
                Patton        Robledo
                               Patton        Hudak
                                             Patton         Hudak
                                                            Patton


                                  6
               Materials
Supplier   Material         Selection Rationale

Sumitomo     C110          Highest strength steel with
                           sour resistance
Sumitomo     C125          Highest strength steel, but
                           sour resistance unknown
V&M          C125SS        Highest strength steel, but
                           sour resistance unknown
Sumitomo     Q125          Highest strength material for
                           non-sour applications
Sumitomo     140G          Potential for non-sour service,
                           but little data available
RTI          Ti-Gr29       Ti-alloy of choice to compare
                           against high-strength steels



                       7
             Environments
   Lab air (baseline): 70-75°F, 40-60% RH

   Seawater: ASTM D1141 substitute ocean
    water open to the air with cathodic
    protection: - 1050mv vs. Saturated
    Calomel electrode

   Sour Brine: Production brine with oxygen
    below 10 ppb and 35% H2S + 65% CO2


                       8
        Task 1: FCGR Testing
   Frequency scan (FS) tests at Constant-DK
    to determine optimum cyclic loading
    frequency for subsequent testing

   FCGR testing as a function of DK to
    determine cracking kinetics that can be
    used in fracture mechanics design and/or
    fitness-for-service assessments



                        9
FCGR Specimen




      10
       Task 1: FCGR Test Matrix
           Material         Air          Seawater Plus      Sour Brine         Applications
Material   Strength        Tests           CP Tests            Tests            Targeted
   6       Ti-Gr 29   (data available)   (data available)         2           SCR, Hybrids,
                                                            plus 1-f scan       Dry tree


   1       110 ksi           2                  2                 2            Inner Casing,
                                          plus 1 f-scan     plus 1-f scan      SCR, Hybrid


   2       125 ksi           2                  2                 2         Outer, Inner Casing,
                                          plus 1 f-scan     plus 1-f scan      SCR, Hybrid


   3       125 ksi           2                  2                 2         Outer, inner Casing,
                                          plus 1-f scan     plus 1 f-scan      SCR, Hybrid

   4       125 ksi           2                  2                           Outer Casing, Non-
                                          plus 1-f scan                     Sour SCR/ Hybrid

   5       140 ksi           2                  2                           Outer Casing, Non
                                          plus 1-f scan                     Sour SCR/ Hybrid

 Total FCGR tests           10                 15                9+3        Grand Total: 34+3
                                                                 Red tests not in current SOW

                                              11
           Frequency Scan Testing

   Corrosion fatigue
    performance highly
    dependent on
    loading frequency
                                X65 Steel
   Fatigue crack
    growth rates at
    constant-DK used
    to characterize
    frequency effect in
    frequency scan (FS)
    tests




                          12
    Effect of Sour Brine
on FCGR vs. DK in X65 Steel
                          10-3
                                     blue symbols - Air
                                     red symbols - H2S
                                                                            invalid



                          10-4
      da/dN (in /cycle)




                          10-5
                                                                        invalid




                          10-6




                          10-7                                            Test 603U-C3
                                                                          Test 603U-C2


                                 5             10                                     100

                                                          DK (ksiin)
                                                          13
    Task 2: S-N Fatigue Life Testing
   Use full-thickness strip specimens cut
    from pipes

   Use optimum frequency determined in
    Task 1

   Target Lives: 1,000s to 1,000,000 cycles
    (depending on loading frequency)




                        14
S-N Strip Specimen




         15
Task 2: S-N Fatigue Test Matrix
 Material     Strength         Air          Seawater Plus      Sour Brine     Applications
Designation    Level          Tests           CP Tests           Tests         Targeted
    6         Ti-Gr 29   (data available)   (data available)       8         SCR, Hybrids,
                                                                               Dry tree
    1           110             8                  8               8          Inner Casing,
                                                                              SCR, Hybrid
    2           125             8                  8               8          Outer, Inner
                                                                                Casing,
                                                                              SCR, Hybrid
    3           125             8                  8               8        Outer Casing, Non
                                                                            Sour SCR, Hybrid

    4           125             8                  8                        Outer Casing, Non
                                                                            Sour SCR/ Hybrid


    5           140             8                  8                        Outer Casing, Non
                                                                            Sour SCR/ Hybrid


    Total S-N tests:            40                 40             24 + 8 Grand Total: 104 + 8
                                                                 Red tests not in current SOW


                                              16
                                      Sour S-N Results
                                 on Conventional (X65) Steels
                          1000                       0.01Hz
                                                     Env. B
                                                     0.6%H2S
Local Stress Range, MPa




                                                     pH=4.1
                                                                            Class E Mean

                                     1-day test
                                                                                                          in-air             re-tested
                                                  0.01Hz
                                                  Env. A
                                                  6%H2S
                                                  pH=3.5   0.01Hz                                                                 re-tested
                                                           Env. A
                          100                              6%H2S             0.33Hz
                                                                             2.4%H2S                      0.5Hz
                                                           pH=3.5
                                                                             pH=3.5                       Env. B
                                                           McMaster '07
                                                                             Buitrago '02                 0.6%H2S
                                                                                                          pH=4.1

                                                                                                1.0Hz
                                                                                                Env. A
                                                                                                6%H2S
                                                                                                pH=3.5

                                              LCF                                      ICF                          HCF
                                                                                                                             9-month test
                           10
                            1.E+02            1.E+03               1.E+04              1.E+05        1.E+06         1.E+07               1.E+08

                                                                          Endurance, Cycles
                                                                                      17
     Task 4:Technology Transfer
   Project Working Committee (PWC) established

   Frequent communications with the PWC and
    RPSEA PM

   TAC Quarterly Presentations

   TAC Final Presentation

   Distribute reports and data to PWC

   Publications:
    • OMAE Conf. Proceedings
    • Industry Journal article


                                 18
                   Costs
   Task 0: Spec. Design/Prep:    $161K
   Task 1: FCGR Testing:         $191K
   Task 2: S-N Testing:          $409K
   Task 3: Phase 2 Plan:           $30K
   Task 4: PM, TT, Reporting:    $209K
                 Total Cost      $1,000K
                 BP Cost Share    $200K
                 RPSEA Funding    $800K


                       19
RPSEA Schedule
                                               Schedule
                                                                Schedule in Months
       Task                 Activity     1 2 3 4 5 6 7   8 9 10 11 12 13 14 15 16 17 18 19 20 21 22 23 24
                                         D J F M A M J   J A S O N D J F M A M J J A S O N

0. Spec Design/Prep Mat Proc+Spec Prep


1. FCGR Testing       Freq Scan
                      Air
                      SW+CP
                      Sour

2. S-N Fatigue        Air
                      SW+CP
                      Sour

3. Phase 2 Plan

4. Program Mgt.

       Deliverables                                      20
        Schedule Assumptions
   Freq. scan ave. duration: 2 mo./test
   Air ave. test duration: 0.5 mo./test
   SW+CP ave. duration: 1 mo./test
   Sour brine ave. duration: 1 mo./test
   FCGR testing: 4-5 machines/ 15 mo.
   S-N testing: 5 machines/22 mo.



                     21
          Programmatic Issues
   Schedule depends on test durations which
    depend on results of Task 1 freq. Scans

   Considering outsourcing more of the less
    complex tests to maintain or shorten
    schedule e.g. SW+CP tests

   Outsourcing will require RPSEA/DOE
    approval

                        22
                    Project Status
   Contract signed: Dec 15, 2008
   Progress after 2.5 months:
    • Admin. Kick-off telecom held Jan. 8
    • Tech. Kick-off meeting held Jan 16
    • Three of six materials procured -- at no cost to the project
    • Arranged for ConocoPhillips to donate Ti-alloy data base
    • S-N and FCGR specimens designed
    • FCGR specimens machined for materials in hand
    • Frequency-scan tests underway
    • 40% of S-N specimens machined for material in hand
    • 11 new fatigue tests in sour brine identified
    • Cost of new tests offset by arranging for NETL-Albany to do
      baseline air tests in initial plan
    • Considering additional outsourcing to reduce schedule




                                   23
         Plan for Next Quarter
   Take delivery of remaining materials
   Machine remaining specimens
   Complete 80% of freq. scan tests
   Machine grips and provide to NETL
   Initiate air S-N tests at NETL
   Initiate interlab. S-N test program (SwRI vs. NETL)
   Make decision on outsourcing seawater tests
   If needed, procure potentiostats for CP tests in
    seawater
   If needed, prepare chambers for seawater tests

                           24

						
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