Platoon BASF Crop Protection Ireland

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Platoon BASF Crop Protection Ireland Powered By Docstoc
					                                                                                                           FOR USE ONLY AS AN AGRICULTURAL FUNGICIDE, as directed below:




                                Platoon 200
                                                                                                           Crops                  Maximum                Maximum number       Latest time
                                                                                                                                  individual dose        of applications      of application

                                                                                                           Winter and spring      1.25 litre product     2 per season         Before watery ripe stage (GS 71)
                                                                                                           wheat                  per hectare

                                                                                                           Winter and spring      1.25 litre product     2 per season         Before end of headin (GS 59)
                                                                                                           barley, winter         per hectare
                                                                                                           and spring oats

                                                                                                           READ ALL PRECAUTIONS BEFORE USE.                                   PCS No.: 02615
  A protectant fungicide with curative properties for use in
  winter wheat, winter barley, spring wheat, spring barley,
  winter oats and spring oats                                                                             PRECAUTIONS
                                                                                                          WEAR SUITABLE PROTECTIVE GLOVES when handling the concentrate.


                                  1 litre ℮
                                                                                                          AVOID ALL CONTACT WITH SKIN.
                                                                                 UN 2902                  WASH HANDS AND EXPOSED SKIN before meals and after work.
                                                                                 Pesticide, liquid,
                                                                              toxic, N.O.S. (contains     WHEN USING DO NOT EAT, DRINK OR SMOKE.
                                  An emulsifiable concentrate containing         solvent naphtha,
                                  200 g/litre (19.2% w/w) pyraclostrobin.      pyraclostrobin 19%         KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDING STUFFS.
                                  Pyraclostrobin is a strobilurin fungicide      and fatty alcohol
                                                                                    ethoxylate)           KEEP OUT OF REACH OF CHILDREN.
                                  Risk and Safety Information                    Marine Pollutant
                                  Harmful by inhalation and if swallowed.                                 VERY TOXIC TO AQUATIC ORGANISMS, may cause long-term adverse effects in the aquatic
                                  Irritating to skin.                                                     environment. Do not contaminate surface waters or ditches with chemical or used container.
                                  Very toxic to aquatic organisms, may cause long term adverse
                                  effects in the aquatic environment                                      DO NOT ALLOW DIRECT SPRAY from ground crop sprayers to fall within 5 m of the top of the
                                                                                                          bank of a static or flowing waterbody. Direct spray away from water.
                                  Keep out of reach of children.
       HARMFUL                    Keep away from food, drink and animal feeding stuffs.
                                  Wear suitable gloves.
                                                                                                          KEEP IN ORIGINAL CONTAINER, tightly closed, in a safe place.
                                  If swallowed, seek medical advice immediately and show this             RINSE CONTAINER THOROUGHLY by using an integrated pressure rinsing device or manually
                                  container or label.                                                     rinsing three times. Add washings to sprayer at time of filling and dispose of safely.
                                  Do not allow direct spray from ground crop sprayers to fall within 5m
                                  of the top of the bank of a static or flowing waterbody. Direct spray   IF YOU FEEL UNWELL, seek medical advice (show label where possible).
                                  away from water.
                                  This material and its container must be disposed of in a safe way.
                                  Use appropriate containment to avoid environmental contamination.
                                                                                                          STORAGE
                                                                                                          Store in a suitable pesticide store, keep dry and protect from frost.
                                  Supplied by:                      Authorization holder:
                                  BASF Ireland Limited              BASF plc, P O Box 4,
                                  Bracetown Business Park           Earl Road, Cheadle Hulme,
                                  Bracetown                         Cheshire, SK8 6QG
                                  Clonee, Co. Meath                 UK
                                  Telephone: 01 825 5701
                                  Fax: 01 825 2038
     DANGEROUS FOR                Emergencies (24 hours freephone):
                                  Tel: 0049 180 227 3112
    THE ENVIRONMENT               Technical Enquiries:
                                  00 44 845 602 2553 (office hours)            PCS No.: 02615
                                                                                                                                              4 014348        575584

   To avoid risks to man and the environment, comply with the instructions for use.
                                                                                                           = Registered trademark of BASF                                                     81037203IE0118




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              DIRECTIONS FOR USE                                                                             RESISTANCE MANAGEMENT
                                                                                                             •
                                                                                                             A maximum of 2 applications of any strobilurin type (QoI) product can be made to any cereal
              Apply as a MEDIUM spray, as defined by BCPC.                                                   crop.
                                                                                                             •
              Platoon 200 is a fungicide with protectant and curative properties for disease control in      In cereals this product must always be applied in a mixture with an approved fungicide that
              winter and spring wheat, winter and spring barley and winter and spring oats as summarised     has a different mode of action. Both products must be applied at recommended rates.
              below:
                                                                                                             IMPORTANT NOTES
                                    Winter        Spring       Winter       Spring        Winter and         1.
                                    Wheat         Wheat        Barley       Barley        Spring Oats        Avoid spray drift on to neighbouring crops.
               Yellow rust          C             C            C            C                                2.
                                                                                                             Wash equipment thoroughly after use.
               Brown rust           C             C            C            C
               Crown rust                                                                 C
                                                                                                             TRADEMARK ACKNOWLEDGEMENTS
               Net blotch                                      C            C
                                                                                                             ®2 = registered trademark of Maag, Dielsdorf, Switzerland.
               Rhynchosporium                                  MC           MC                               ®3 = registered trademark of Bayer CropScience Ltd.
                                                                                                             ®4 = registered trademark of BASF.
              C = Control                                                                                    ®5 = registered trademark of Syngenta Crop Protection (UK) Ltd.
              MC = Moderate Control

              Yield response may be obtained in the absence of visual disease.

              Time of Application
              Apply Platoon 200 at the start of foliar disease attack. A maximum of two applications can
              be made up to and including flowering just complete in winter and spring wheat and up to
              and including emergence of ear just complete in winter and spring barley and winter and
              spring oats.
                                                                                                             The following does not form part of the product label under S.I. No. 83 of 2003:
              Rate of Application
              Apply 1.25 litres Platoon 200 in a minimum of 200 litres of water per hectare.                 With many products there is a general risk of resistance developing to the active ingredients.
                                                                                                             For this reason a change in activity cannot be ruled out. It is generally impossible to predict
              MIXING                                                                                         with certainty how resistance may develop because there are so many crop and use
                                                                                                             connected ways of influencing this. We therefore have to exclude liability for damage or loss
              Half fill the spray tank with clean water and start the agitation. SHAKE THE CONTAINER         attributable to any such resistance that may develop. To help minimise any loss in activity the
              WELL before use and pour in the required amount of product. Rinse any empty containers         BASF recommended rate should in all events be adhered to.
              thoroughly and add rinsings to the spray tank. Add the remainder of the water and continue
              agitation until spraying is completed.                                                         Numerous, particularly regional or regionally attributable, factors can influence the activity
              When tank mixes are to be used, each product should be added separately to the spray           of the product. Examples include weather and soil conditions, crop plant varieties, crop
              tank.                                                                                          rotation, treatment times, application amounts, admixture with other products, appearance
                                                                                                             of organisms resistant to active ingredients and spraying techniques. Under particular
              MIXTURES WITH OTHER SPRAY CHEMICALS                                                            conditions a change in activity or damage to plants cannot be ruled out. The manufacturer or
                                                                                                             supplier is therefore unable to accept any liability in such circumstances. All goods supplied
              Provided that all product recommendations are followed, Platoon 200 is fully compatible with   by us are of high grade and we believe them to be suitable, but as we cannot exercise control
              any of the following in two-way mix:                                                           over their mixing or use or the weather conditions during and after application, which may
              Cheetah®3 Super        Moddus®5 a                                                              affect the performance of the material, all conditions and warranties, statutory or otherwise,
              Corbel®2               Terpal®4                                                                as to the quality or fitness for any purpose of our goods are excluded and no responsibility will
              Eagle®3                Topik®5                                                                 be accepted by us for any damage or injury whatsoever arising from their storage, handling,
                                                                                                             application or use; but nothing should be deemed to exclude or restrict any liability upon us
              a   Some crop scorch or reduction in biomass may be noted with these mixes.                    which cannot be excluded or restricted under the provisions of the Unfair Contract Terms Act
                                                                                                             1977 or any similar applicable law.
              All tank mixes should be used immediately after mixing.




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               ADDITIONAL PRODUCT SAFETY INFORMATION                                                    3.   HAZARDS IDENTIFICATION

               This section does not form part of the product label under S.I. No. 83 of                     HARMFUL                    DANGEROUS FOR THE ENVIRONMENT
               2003                                                                                          HARMFUL by inhalation and if swallowed (R20/22)
                                                                                                             IRRITATING to skin (R38)
                                                                                                             VERY TOXIC TO AQUATIC ORGANISMS, MAY CAUSE LONG TERM ADVERSE
               Safety data sheet:                                                                            EFFECTS IN THE AQUATIC ENVIRONMENT (R50/53)


                                                                                                        4.   FIRST AID MEASURES
               1.   Substance/preparation and company name
                                                                                                             General advice:            If a person thinks that they have been exposed to this
                    Product Name:               PLATOON 200                                                                             product and feels unwell, call a doctor or take them to
                    PCS Number:                 02615                                                                                   a hospital. Remove all contaminated clothing. Keep
                    Company:                    BASF Ireland                                                                            them at REST away from source of contamination. DO
                                                Bracetown Business Park                                                                 NOT ALLOW smoking or eating. First aider should avoid
                                                Bracetown                                                                               becoming contaminated and wear protective clothing if
                                                Clonee                                                                                  necessary.
                                                Co Meath, Ireland
                                                                                                             Eye contact:               Immediately irrigate affected eyes for at least 15 minutes
                    Tel:                        (01) 8255701                                                                            under flowing water, with eyelids open.
                    Fax:                        (01) 8252038
                                                                                                             Skin contact:              Immediately remove contaminated clothing and footwear
                    Emergency information:      0049 180 2273 112 (24 hours freephone)                                                  and flush skin with plenty of water. Wash affected area
                                                                                                                                        thoroughly with soap and water as soon as possible.
               2.   COMPOSITION/INFORMATION ON INGREDIENTS                                                   Ingestion:                 Immediately rinse mouth then drink plenty of water. Seek
                                                                                                                                        medical attention immediately.
                    Use:         Agricultural fungicide.
                    Formulation: An emulsifiable concentrate containing 19.2 % w/w (200 g/litre)             Inhalation:                Keep person calm, remove to fresh air, summon medical help.
                                 pyraclostrobin
                                                                                                             Unconsciousness:           If danger of loss of consciousness, place person in recovery
                    Hazardous ingredients      CAS No.      % w/w      Symbol          R Phrases                                        position. Apply artificial ventilation if necessary, but care
                                                                                                                                        must be taken to avoid contamination of the first aider.
                    Pyraclostrobin             175013-18-0 19.2        Xn (Harmful)    R20, 38, 50/53
                                                                       N (Dangerous                          GUIDE TO PHYSICIAN – general advice
                                                                       for the environment)
                                                                                                             Active ingredient group:   Pyraclostrobin is a strobilurin fungicide
                    Fatty alcohol ethoxylate   68002-96-0   >=18% –    T (Toxic)       R23, 50               Toxic effects:             This material is of moderate general toxicity
                                                            <=20%      N (Dangerous                          Symptoms of accidental
                                                                       for the environment)                  over exposure:             There is no documentation of pathological effects in
                                                                                                                                        humans.
                    Calcium dodecylbenzene 26264-06-2       >=1.6% – Xi (Irritant)     R38, 41               Any unusual symptoms which occur after exposure (by any mode of entry) should be
                    sulfonate                               <=2.2%                                           recorded and reported to BASF at Cheadle.
                    2-ethylhexan-1-ol          104-76-7     >=1.1% – Xi (Irritant)     R36/38
                                                            <=1.5%
                                                                                                        5.   FIRE FIGHTING MEASURES
                    Solvent naphtha            64742-94-5   >=53% – Xn (Harmful)    R65, 66, 51/53           Suitable extinguishing media: Water spray, foam, dry extinguishing media.
                                                            <=55.5% N (Dangerous
                                                                    for the environment)                     Possible harmful fumes in a fire: Carbon monoxide, nitrogen oxides and hydrogen
                                                                                                                                               chloride fluoride can be released. Avoid breathing
                                                                                                                                               smoke and fumes.
                                                                                                             Protective equipment:             In case of fire wear self-contained breathing
                                                                                                                                               apparatus and protective clothing. Fire/explosion
                                                                                                                                               fumes should not be inhaled.




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                    Further information:             Call the Fire Brigade at once to deal with all fires                DO NOT ALLOW DIRECT SPRAY from ground crop sprayers to fall within 5 m
                                                     involving pesticides unless the fire is small and                   of the top of the bank of a static or flowing waterbody. Direct spray away from
                                                     immediately controllable. Spray unopened containers                 water.
                                                     with a mist spray to keep cool. If without risk, remove             KEEP IN ORIGINAL CONTAINER, tightly closed, in a safe place.
                                                     intact containers from exposure to fire. Contain fire-              RINSE CONTAINER THOROUGHLY by using an integrated pressure rinsing
                                                     fighting water, bunding if necessary with sand or                   device or manually rinsing three times. Add washings to sprayer at time of filling
                                                     earth. Do not allow contamination of public drains or               and dispose of safely.
                                                     surface or ground waters.                                           IF YOU FEEL UNWELL, seek medical advice (show label where possible).
                                                                                                                         STORAGE
               6.   ACCIDENTAL RELEASE MEASURES                                                                          Store in a suitable pesticide store, keep dry and protect from frost.
                    If spilled:                      Wear prescribed protective clothing. Clear spillage            (ii) PERSONAL PROTECTIVE EQUIPMENT
                                                     immediately. Contain spillage and absorb onto
                                                     earth, sand or suitable absorbent material. Collect                 In tests with a range of pesticide products, protective gloves made of nitrile
                                                     contaminated material and place in a marked container               Rubber at least 0.5 mm thick and 300 mm long have been found to be the most
                                                     for disposal. Thoroughly wash area of spillage.                     suitable. Gloves made of viton, butyl rubber, neoprene and PVC can also offer
                                                                                                                         good protection. Gloves must protect the whole hand and wrist and repeated
                    Personal protective equipment: See Section 8.                                                        use of these gloves depends upon spillages being washed off immediately. The
                    Environmental precautions:       Do not allow contamination of public drains or surface              gloves should be thoroughly washed after each operation. Decontaminate all
                                                     or ground waters. Inform local water plc if spillage                personal protective equipment after use. When this is not possible dispose of as
                                                     enters drains and the Environmental Protection                      contaminated wastes.
                                                     Agency if it enters surface or ground waters. Keep             (iii) OCCUPATIONAL EXPOSURE LIMITS (OESs)
                                                     people and animals away.
                                                                                                                         Hazardous ingredient                  Long term                Short term
                                                                                                                                                               exposure limit           exposure limit
               7.   HANDLING AND STORAGE                                                                                 Not applicable
                    Handling:                        No special measures are necessary provided the
                                                     product is used correctly. When using do not eat,         9.   PHYSICAL AND CHEMICAL PROPERTIES
                                                     drink or smoke.
                                                                                                                    Form:                        Liquid (emulsion concentrate)
                    Protection against fire                                                                         Colour:                      Dark Yellow
                    and explosion:                   Product is combustible.                                        Odour:                       Faintly aromatic
                                                     Prevent electrostatic charge. Keep away from                   Flash point:                 104 °C
                                                     sources of ignition.                                           Density:                     1.04 g/l (20 °C)
                                                     Keep at temperatures between 40 and 5 °C                       pH value:                    5 –7
                                                     Vapours may form explosive mixtures with air.                  Solubility in water:         Emulsifiable
                    Storage:                         Keep dry and frostproof in a suitable pesticide store.
                                                     Store separately from food, drink and animal feed.
                                                                                                               10. STABILITY AND REACTIVITY
                                                                                                                    Hazardous reactions:                   No decomposition if stored and applied as
               8.   EXPOSURE CONTROLS AND PERSONAL PROTECTION                                                                                              directed.
                    (i)   PRECAUTIONS (from product label)                                                          Substances to avoid:                   Unknown.
                          WEAR SUITABLE PROTECTIVE GLOVES when handling the concentrate.                            Hazardous decomposition products: None if stored and handled correctly.
                          AVOID ALL CONTACT WITH SKIN.
                          WASH HANDS AND EXPOSED SKIN before meals and after work.
                          WHEN USING DO NOT EAT, DRINK OR SMOKE.
                          KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDING STUFFS.
                          KEEP OUT OF REACH OF CHILDREN.
                          VERY TOXIC TO AQUATIC ORGANISMS, may cause long-term adverse effects
                          in the environment. Do not contaminate surface waters or ditches with chemical
                          or used container.




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               11. TOXICOLOGICAL INFORMATION                                                                         AIR
                                                                                                                     ICAO/IATA Class:           6.1
                   *Acute toxicity:                                                                                                             Pesticide, liquid, toxic, N.O.S. (contains solvent naphtha,
                   Ingestion:                      Moderate toxicity                (LD50 oral (rat): > 200                                     pyraclostrobin 19% and fatty alcohol ethoxylate )
                   < 500 mg/kg)                                                                                                                 – Marine Pollutant
                   Skin contact:                   Irritant                         (LD50     dermal     (rat):      Pack sizes:                1 litre       5 litres
                   > 4000 mg/kg)                                                                                     No per outer:              10            4
                   Inhalation of vapour:           Unlikely to cause a problem      (LC50 inhalation (rat) 4 h:
                   >1.14 mg/l)
                   Eye contact:                    Not irritant                                                   15. REGULATORY INFORMATION
                   Sensitising potential:          No sensitising effect
                                                                                                                     This product is authorised, cleared, notified or granted permission to market in
                   *Similar formulation tested.                                                                      accordance with the European Communities (Authorisation, Placing on the market,
                   Experiences in humans:                                                                            Use and Control of Plant Protection Products) Regulations 2003 as amended, and is
                   Solvent naphtha: lung damage, skin irritation, irritations of the mucous membrane.                labelled in accordance with European Communities (Classification, Packaging and
                                                                                                                     Labelling of Plant Protection Products and Biocide Products) Regulations 2001.
                   Avoid all unnecessary contact with the product.
                                                                                                                         R-phrases – see Section 3
                                                                                                                         S-phrases – see Section 8
               12. ECOLOGICAL INFORMATION
                   Ecotoxic effects: *Rainbow trout (Oncorhynchus mykiss)           LC50 96 h: 0.0229 mg/l        16. OTHER INFORMATION
                                     *Algae EC/LC50 (0 –72 h):                                   0.690 mg/l
                                     Daphnia EC/LC50 (48 h):                                     0.046 mg/l          For further medical advice Doctors should contact the National Poisons Information
                                                                                                                     Centre at Beaumont Hospital.
                   * Similar formulation tested.
                                                                                                                     In an emergency further information can be obtained from the UK National Chemical
                                                                                                                     Emergency Centre 0044 1865 407 333 (24 hours).
               13. DISPOSAL CONSIDERATIONS
                                                                                                                     The information contained herein is based on the present state of our knowledge and
                   Leaking containers:                  Damaged or leaking containers must be dealt with             does not therefore guarantee certain properties. Recipients of our product must take
                                                        as soon as noticed by sealing them in impermeable            responsibility for observing existing laws and regulations.
                                                        containers.
                   Disposal of used containers:         Used, cleaned, crushed or punctured containers
                                                        may be disposed of at licensed disposal sites.
                   Disposal of diluted pesticide:       Advice for the disposal may be given by local
                                                        authorities (Environmental Health Departments) who
                                                        will recommend a waste disposal contractor. Do not
                                                        re-use containers for any purpose.

               14. TRANSPORT INFORMATION
                   UN Number:                      2902
                   Packing Group:                  III
                   ROAD/RAIL
                   ADR/RID Class:                  6.1
                                                   Pesticide, liquid, toxic, N.O.S. (contains solvent naphtha,
                                                   pyraclostrobin 19% and fatty alcohol ethoxylate )
                   SEA
                   IMDG Class:                     6.1
                                                   Pesticide, liquid, toxic, N.O.S. (contains solvent naphtha,
                                                   pyraclostrobin 19% and fatty alcohol ethoxylate )
                                                   – Marine Pollutant




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                                                                                                            FOR USE ONLY AS AN AGRICULTURAL FUNGICIDE, as directed below:




                                 Platoon 200
                                                                                                            Crops                  Maximum                Maximum number       Latest time
                                                                                                                                   individual dose        of applications      of application

                                                                                                            Winter and spring      1.25 litre product     2 per season         Before watery ripe stage (GS 71)
                                                                                                            wheat                  per hectare

                                                                                                            Winter and spring      1.25 litre product     2 per season         Before end of headin (GS 59)
                                                                                                            barley, winter         per hectare
                                                                                                            and spring oats

                                                                                                            READ ALL PRECAUTIONS BEFORE USE.                                   PCS No.: 02615
  A protectant fungicide with curative properties for use in
  winter wheat, winter barley, spring wheat, spring barley,
  winter oats and spring oats                                                                              PRECAUTIONS
                                                                                                           WEAR SUITABLE PROTECTIVE GLOVES when handling the concentrate.


                                   1 litre ℮
                                                                                                           AVOID ALL CONTACT WITH SKIN.
                                                                                  UN 2902                  WASH HANDS AND EXPOSED SKIN before meals and after work.
                                                                                  Pesticide, liquid,
                                                                               toxic, N.O.S. (contains     WHEN USING DO NOT EAT, DRINK OR SMOKE.
                                   An emulsifiable concentrate containing         solvent naphtha,
                                   200 g/litre (19.2% w/w) pyraclostrobin.      pyraclostrobin 19%         KEEP AWAY FROM FOOD, DRINK AND ANIMAL FEEDING STUFFS.
                                   Pyraclostrobin is a strobilurin fungicide      and fatty alcohol
                                                                                     ethoxylate)           KEEP OUT OF REACH OF CHILDREN.
                                   Risk and Safety Information                    Marine Pollutant
                                   Harmful by inhalation and if swallowed.                                 VERY TOXIC TO AQUATIC ORGANISMS, may cause long-term adverse effects in the aquatic
                                   Irritating to skin.                                                     environment. Do not contaminate surface waters or ditches with chemical or used container.
                                   Very toxic to aquatic organisms, may cause long term adverse
                                   effects in the aquatic environment                                      DO NOT ALLOW DIRECT SPRAY from ground crop sprayers to fall within 5 m of the top of the
                                                                                                           bank of a static or flowing waterbody. Direct spray away from water.
                                   Keep out of reach of children.
        HARMFUL                    Keep away from food, drink and animal feeding stuffs.
                                   Wear suitable gloves.
                                                                                                           KEEP IN ORIGINAL CONTAINER, tightly closed, in a safe place.
                                   If swallowed, seek medical advice immediately and show this             RINSE CONTAINER THOROUGHLY by using an integrated pressure rinsing device or manually
                                   container or label.                                                     rinsing three times. Add washings to sprayer at time of filling and dispose of safely.
                                   Do not allow direct spray from ground crop sprayers to fall within 5m
                                   of the top of the bank of a static or flowing waterbody. Direct spray   IF YOU FEEL UNWELL, seek medical advice (show label where possible).
                                   away from water.
                                   This material and its container must be disposed of in a safe way.
                                   Use appropriate containment to avoid environmental contamination.
                                                                                                           STORAGE
                                                                                                           Store in a suitable pesticide store, keep dry and protect from frost.
                                   Supplied by:                      Authorization holder:
                                   BASF Ireland Limited              BASF plc, P O Box 4,
                                   Bracetown Business Park           Earl Road, Cheadle Hulme,
                                   Bracetown                         Cheshire, SK8 6QG
                                   Clonee, Co. Meath                 UK
                                   Telephone: 01 825 5701
                                   Fax: 01 825 2038
      DANGEROUS FOR                Emergencies (24 hours freephone):
                                   Tel: 0049 180 227 3112
     THE ENVIRONMENT               Technical Enquiries:
                                   00 44 845 602 2553 (office hours)            PCS No.: 02615
                                                                                                                                               4 014348        575584

  To avoid risks to man and the environment, comply with the instructions for use.                          = Registered trademark of BASF                                                     81037203IE0118




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