Docstoc

Chemwatch Australian MSDS

Document Sample
Chemwatch Australian MSDS Powered By Docstoc
					                                       O'CONNELL FORM RELEASE AGENT
Chemwatch Independent Material Safety Data Sheet
Issue Date: 23-Aug-2011                                                                                 CHEMWATCH 28-1590
C9317EC                                                                                                       Version No:2.0
                                                                                                        CD 2011/2 Page 1 of 8




               Section 1 - CHEMICAL PRODUCT AND COMPANY IDENTIFICATION


PRODUCT NAME
O'CONNELL FORM RELEASE AGENT

PRODUCT USE
Form release agent.

SUPPLIER
Company: O' Connell Agencies
Address:
9/6 Ingleston Road
Wakerly
QLD, 4154
Australia
Telephone: +61 7 3890 8088
Fax: +61 7 3890 8388
Email: kcaso@bigpond.net.au
Website: www.oconnellagencies.com.au




               Section 2 - HAZARDS IDENTIFICATION


STATEMENT OF HAZARDOUS NATURE
HAZARDOUS SUBSTANCE. NON-DANGEROUS GOODS. According to NOHSC Criteria, and ADG Code.
COMBUSTIBLE LIQUID, regulated under AS1940 for Bulk Storage purposes only.




RISK
Risk Codes              Risk Phrases
R20/21/22               • Harmful by inhalation, in contact with skin and if
                        swallowed.
R38                     • Irritating to skin.
R40(3)                  • Limited evidence of a carcinogenic effect.
R51/53                  • Toxic to aquatic organisms, may cause long- term adverse
                        effects in the aquatic environment.
R65                     • HARMFUL- May cause lung damage if swallowed.
R66                     • Repeated exposure may cause skin dryness and cracking.
R67                     • Vapours may cause drowsiness and dizziness.
R68/20/21/22            • Harmful:possible risk of irreversible effects through
                        inhalation, in contact with skin and if swallowed.

SAFETY
Safety Codes            Safety Phrases
S23                     • Do not breathe gas/fumes/vapour/spray.
S24                     • Avoid contact with skin.
S25                     • Avoid contact with eyes.
S36                     • Wear suitable protective clothing.
S37                     • Wear suitable gloves.
S39                     • Wear eye/face protection.
S51                     • Use only in well ventilated areas.
S09                     • Keep container in a well ventilated place.
S29                     • Do not empty into drains.
S401                    • To clean the floor and all objects contaminated by this material, use water
                        and detergent.

                                                                                                               continued...
                                            O'CONNELL FORM RELEASE AGENT
Chemwatch Independent Material Safety Data Sheet
Issue Date: 23-Aug-2011                                                                                                 CHEMWATCH 28-1590
C9317EC                                                                                                                       Version No:2.0
                                                                                                                        CD 2011/2 Page 2 of 8
                                                                                                        Section 2 - HAZARDS IDENTIFICATION

S07                         • Keep container tightly closed.
S35                         • This material and its container must be disposed of in a safe way.
S13                         • Keep away from food, drink and animal feeding stuffs.
S26                         • In case of contact with eyes, rinse with plenty of water and contact Doctor or
                            Poisons Information Centre.
S46                         • If swallowed, IMMEDIATELY contact Doctor or Poisons Information Centre. (show
                            this container or label).
S57                         • Use appropriate container to avoid environmental contamination.
S61                         • Avoid release to the environment. Refer to special instructions/Safety data
                            sheets.




               Section 3 - COMPOSITION / INFORMATION ON INGREDIENTS

NAME                                                                                             CAS RN                %
diesel                                                                                           68334-30-5            60-99
lanolin                                                                                          8006-54-0             1-5
methanol                                                                                         67-56-1               1-5
other non hazardous ingredients                                                                                        balance



               Section 4 - FIRST AID MEASURES


SWALLOWED
■ - If swallowed do NOT induce vomiting.
- If vomiting occurs, lean patient forward or place on left side (head-down position, if possible) to maintain open airway and
prevent aspiration.
- Observe the patient carefully.
- Never give liquid to a person showing signs of being sleepy or with reduced awareness; i.e. becoming unconscious.
- Avoid giving milk or oils.
- Avoid giving alcohol.
- If spontaneous vomiting appears imminent or occurs, hold patient's head down, lower than their hips to help avoid possible
aspiration of vomitus.

EYE
■ If this product comes in contact with the eyes:
- Wash out immediately with fresh running water.
- Ensure complete irrigation of the eye by keeping eyelids apart and away from eye and moving the eyelids by occasionally lifting
the upper and lower lids.
- Seek medical attention without delay; if pain persists or recurs seek medical attention.
- Removal of contact lenses after an eye injury should only be undertaken by skilled personnel.

SKIN
■ If skin contact occurs:
- Immediately remove all contaminated clothing, including footwear.
- Flush skin and hair with running water (and soap if available).
- Seek medical attention in event of irritation.

INHALED
■ - If fumes or combustion products are inhaled remove from contaminated area.
- Lay patient down. Keep warm and rested.
- Prostheses such as false teeth, which may block airway, should be removed, where possible, prior to initiating first aid
procedures.
- Apply artificial respiration if not breathing, preferably with a demand valve resuscitator, bag-valve mask device, or pocket
mask as trained. Perform CPR if necessary.

NOTES TO PHYSICIAN
■ For acute or short term repeated exposures to petroleum distillates or related hydrocarbons:
- Primary threat to life, from pure petroleum distillate ingestion and/or inhalation, is respiratory failure.
- Patients should be quickly evaluated for signs of respiratory distress (e.g. cyanosis, tachypnoea, intercostal retraction,
obtundation) and given oxygen. Patients with inadequate tidal volumes or poor arterial blood gases (pO2 50 mm Hg) should be
intubated.
- Arrhythmias complicate some hydrocarbon ingestion and/or inhalation and electrocardiographic evidence of myocardial injury has
been reported; intravenous lines and cardiac monitors should be established in obviously symptomatic patients. The lungs excrete
inhaled solvents, so that hyperventilation improves clearance.
- A chest x-ray should be taken immediately after stabilisation of breathing and circulation to document aspiration and detect
the presence of pneumothorax.
Any material aspirated during vomiting may produce lung injury. Therefore emesis should not be induced mechanically or
pharmacologically.
Treat symptomatically.
                                                                                                                                 continued...
                                             O'CONNELL FORM RELEASE AGENT
Chemwatch Independent Material Safety Data Sheet
Issue Date: 23-Aug-2011                                                                                                    CHEMWATCH 28-1590
C9317EC                                                                                                                           Version No:2.0
                                                                                                                           CD 2011/2 Page 3 of 8
                                                                                                               Section 4 - FIRST AID MEASURES

For acute and short term repeated exposures to methanol:
- Toxicity results from accumulation of formaldehyde/formic acid.
- Clinical signs are usually limited to CNS, eyes and GI tract Severe metabolic acidosis may produce dyspnea and profound
systemic effects which may become intractable. All symptomatic patients should have arterial pH measured. Evaluate airway,
breathing and circulation.
- Stabilise obtunded patients by giving naloxone, glucose and thiamine.
- Decontaminate with Ipecac or lavage for patients presenting 2 hours post-ingestion. Charcoal does not absorb well; the
usefulness of cathartic is not established.



               Section 5 - FIRE FIGHTING MEASURES


EXTINGUISHING MEDIA
■ - Foam.
- Dry chemical powder.
- BCF (where regulations permit).
- Carbon dioxide.

FIRE FIGHTING
■ - Alert Fire Brigade and tell them location and nature of hazard.
- Wear full body protective clothing with breathing apparatus.
- Prevent, by any means available, spillage from entering drains or water course.
- Use water delivered as a fine spray to control fire and cool adjacent area.

FIRE/EXPLOSION HAZARD
■ - Combustible.
- Slight fire hazard when exposed to heat or flame.
- Heating may cause expansion or decomposition leading to violent rupture of containers.
- On combustion, may emit toxic fumes of carbon monoxide (CO).
Combustion products include: carbon dioxide (CO2), other pyrolysis products typical of burning organic material.
May emit poisonous fumes.
May emit corrosive fumes.

FIRE INCOMPATIBILITY
■ - Avoid contamination with oxidising agents i.e. nitrates, oxidising acids, chlorine bleaches, pool chlorine etc. as ignition
may result.

HAZCHEM
None

Personal Protective Equipment
Breathing apparatus.
Chemical splash suit.



               Section 6 - ACCIDENTAL RELEASE MEASURES


MINOR SPILLS
■ - Remove all ignition sources.
- Clean up all spills immediately.
- Avoid breathing vapours and contact with skin and eyes.
- Control personal contact by using protective equipment.

MAJOR SPILLS
■ Moderate hazard.
- Clear area of personnel and move upwind.
- Alert Fire Brigade and tell them location and nature of hazard.
- Wear breathing apparatus plus protective gloves.
- Prevent, by any means available, spillage from entering drains or water course.

               Personal Protective Equipment advice is contained in Section 8 of the MSDS.




                                                                                                                                  continued...
                                             O'CONNELL FORM RELEASE AGENT
Chemwatch Independent Material Safety Data Sheet
Issue Date: 23-Aug-2011                                                                                                       CHEMWATCH 28-1590
C9317EC                                                                                                                             Version No:2.0
                                                                                                                              CD 2011/2 Page 4 of 8


               Section 7 - HANDLING AND STORAGE


PROCEDURE FOR HANDLING
■ - Containers, even those that have been emptied, may contain explosive vapours.
- Do NOT cut, drill, grind, weld or perform similar operations on or near containers.
- DO NOT allow clothing wet with material to stay in contact with skin.
- Electrostatic discharge may be generated during pumping - this may result in fire.
- Ensure electrical continuity by bonding and grounding (earthing) all equipment.
- Restrict line velocity during pumping in order to avoid generation of electrostatic discharge (<=1 m/sec until fill pipe
submerged to twice its diameter, then <= 7 m/sec).
- Avoid splash filling.
- Avoid all personal contact, including inhalation.
- Wear protective clothing when risk of exposure occurs.
- Use in a well-ventilated area.
- Prevent concentration in hollows and sumps.

SUITABLE CONTAINER
■ - Metal can or drum
- Packaging as recommended by manufacturer.
- Check all containers are clearly labelled and free from leaks.

STORAGE INCOMPATIBILITY
■ Diesel Fuel 1-D or Diesel Fuel 2-D or Diesel Fuel 4-D (CAS 68334-30-5; 68476-31-3; 68476-34-6; 77650-28-3)
- reacts violently with strong oxidisers, concentrated nitric acid, fluorine
- is incompatible with ammonia, ammonium nitrate
- may generate electrostatic charges due to low conductivity.
- Avoid reaction with oxidising agents.

STORAGE REQUIREMENTS
■ - Store in original containers.
- Keep containers securely sealed.
- No smoking, naked lights or ignition sources.
- Store in a cool, dry, well-ventilated area.



               Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION


EXPOSURE CONTROLS
Source                            Material                          TWA ppm           TWA mg/m³         STEL ppm             STEL mg/m³    Notes
___________                       ___________                       _______           _______           _______              _______       _______
Australia Exposure                O' Connell Form                   200               262               250                  328           Sk
Standards                         Release Agent (Methyl
                                  alcohol)

The following materials had no OELs on our records
• diesel:                                    CAS:68334- 30- 5 CAS:68512- 90- 3 CAS:64742- 81- 0 CAS:68476- 30-
                                             2
• lanolin:                                   CAS:8006- 54- 0 CAS:8020- 84- 6 CAS:68424- 58- 8



PERSONAL PROTECTION

RESPIRATOR
•Type AX Filter of sufficient capacity. (AS/NZS 1716 & 1715, EN 143:2000 & 149:2001, ANSI Z88 or national equivalent)

EYE
■ - Safety glasses with side shields.
- Chemical goggles.
- Contact lenses may pose a special hazard; soft contact lenses may absorb and concentrate irritants. A written policy document,
describing the wearing of lens or restrictions on use, should be created for each workplace or task. This should include a review
of lens absorption and adsorption for the class of chemicals in use and an account of injury experience. Medical and first-aid
personnel should be trained in their removal and suitable equipment should be readily available. In the event of chemical
exposure, begin eye irrigation immediately and remove contact lens as soon as practicable. Lens should be removed at the first
signs of eye redness or irritation - lens should be removed in a clean environment only after workers have washed hands
thoroughly. [CDC NIOSH Current Intelligence Bulletin 59], [AS/NZS 1336 or national equivalent].

HANDS/FEET
■ - Wear chemical protective gloves, eg. PVC.
- Wear safety footwear or safety gumboots, eg. Rubber.
                                                                                                                                     continued...
                                            O'CONNELL FORM RELEASE AGENT
Chemwatch Independent Material Safety Data Sheet
Issue Date: 23-Aug-2011                                                                                          CHEMWATCH 28-1590
C9317EC                                                                                                                Version No:2.0
                                                                                                                 CD 2011/2 Page 5 of 8
                                                                              Section 8 - EXPOSURE CONTROLS / PERSONAL PROTECTION

Suitability and durability of glove type is dependent on usage. Important factors in the selection of gloves include:
- frequency and duration of contact,
- chemical resistance of glove material,
- glove thickness and
- dexterity.

OTHER
■ - Overalls.
- P.V.C. apron.
- Barrier cream.
- Skin cleansing cream.

ENGINEERING CONTROLS
■ Engineering controls are used to remove a hazard or place a barrier between the worker and the hazard. Well-designed
engineering controls can be highly effective in protecting workers and will typically be independent of worker interactions to
provide this high level of protection.
The basic types of engineering controls are:
Process controls which involve changing the way a job activity or process is done to reduce the risk.
Enclosure and/or isolation of emission source which keeps a selected hazard "physically" away from the worker and ventilation
that strategically "adds" and "removes" air in the work environment.



               Section 9 - PHYSICAL AND CHEMICAL PROPERTIES


APPEARANCE
Pale yellow liquid with a mild, non-offensive odour; insoluble in water.

PHYSICAL PROPERTIES
Liquid.
Does not mix with water.
Floats on water.

State                                         Liquid                            Molecular Weight                           Not Applicable
Melting Range (° C)                           Not Available                     Viscosity                                  Not Available
Boiling Range (°C)                            180                               Solubility in water (g/L)                 Immiscible
             C)
Flash Point (°                                66                                pH (1% solution)                          Not Applicable
Decomposition Temp (°  C)                     Not Available                     pH (as supplied)                          Not A pplicable
Autoignition Temp (°C)                        Not Available                     Vapour Pressure (kPa)                      Not Available
Upper Explosive Limit (%)                     7.0                               Specific Gravity (water=1)                 0.85
Lower Explosive Limit (%)                     0.7                               Relative Vapour Density                    Not Available
                                                                                (air=1)
Volatile Component (%vol)                      100                              Evaporation Rate                          Not Available



               Section 10 - STABILITY AND REACTIVITY


CONDITIONS CONTRIBUTING TO INSTABILITY
■ - Presence of incompatible materials.
- Product is considered stable.
- Hazardous polymerisation will not occur.
For incompatible materials - refer to Section 7 - Handling and Storage.



               Section 11 - TOXICOLOGICAL INFORMATION


POTENTIAL HEALTH EFFECTS
ACUTE HEALTH EFFECTS                                                            CHRONIC HEALTH EFFECTS
■ Irritating to skin.                                                           ■ Limited evidence of a carcinogenic effect.
■ HARMFUL- May cause lung damage if swallowed.                                  ■ Repeated exposure may cause skin dryness and
                                                                                cracking.
■ Harmful by inhalation, in contact with skin and
if swallowed.
■ Vapours may cause dizziness or suffocation.
■ Vapours may cause drowsiness and dizziness.

TOXICITY AND IRRITATION
■ unless otherwise specified data extracted from RTECS - Register of Toxic Effects of Chemical Substances.

                                                                                                                             continued...
                                              O'CONNELL FORM RELEASE AGENT
Chemwatch Independent Material Safety Data Sheet
Issue Date: 23-Aug-2011                                                                                                 CHEMWATCH 28-1590
C9317EC                                                                                                                       Version No:2.0
                                                                                                                        CD 2011/2 Page 6 of 8
                                                                                                   Section 11 - TOXICOLOGICAL INFORMATION


DIESEL:
O'CONNELL FORM RELEASE AGENT:
■ For "kerosenes"
Acute toxicity: Oral LD50s for three kerosenes (Jet A, CAS No. 8008-20-6 and CAS No.
■ The material may produce severe skin irritation after prolonged or repeated exposure, and may produce a contact dermatitis
(nonallergic). This form of dermatitis is often characterised by skin redness (erythema) thickening of the epidermis.<</>.

O'CONNELL FORM RELEASE AGENT:
■ No significant acute toxicological data identified in literature search.

DIESEL:
TOXICITY                                                                  IRRITATION
Oral (rat) LD50: 7500 mg/kg                                               Skin (rabbit): 500 uL/24h SEVERE
Dermal (rabbit) LCLo: 4200 mg/kg
■ The substance is classified by IARC as Group 3:
            NOT classifiable as to its carcinogenicity to humans.
Evidence of carcinogenicity may be inadequate or limited in animal testing.

LANOLIN:
■ No data of toxicological significance identified in literature search.

METHANOL:
TOXICITY                                                                     IRRITATION
Oral (human) LDLo: 143 mg/kg                                                 Skin (rabbit): 20 mg/24 h- Moderate
Oral (man) LDLo: 6422 mg/kg                                                  Eye (rabbit): 40 mg- Moderate
Oral (man) TDLo: 3429 mg/kg                                                  Eye (rabbit): 100 mg/24h- Moderate
Oral (rat) LD50: 5628 mg/kg
Inhalation (human) TCLo: 86000 mg/m³
Inhalation (human) TCLo: 300 ppm
Inhalation (rat) LC50: 64000 ppm/4h
Dermal (rabbit) LD50: 15800 mg/kg
■ The material may cause skin irritation after prolonged or repeated exposure and may produce a contact dermatitis (nonallergic).
This form of dermatitis is often characterised by skin redness (erythema) and swelling the epidermis.


SKIN
methanol                             Australia Exposure                      Notes                            Sk
                                     Standards - Skin




               Section 12 - ECOLOGICAL INFORMATION

Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
Avoid release to the environment.
Refer to special instructions/ safety data sheets.

Ecotoxicity
Ingredient                                          Persistence:                Persistence: Air        Bioaccumulation              Mobility
                                                    Water/Soil
O' Connell Form Release Agent                       No Data                     No Data
                                                    Available                   Available
diesel                                              No Data                     No Data
                                                    Available                   Available
lanolin                                             No Data                     No Data
                                                    Available                   Available
methanol                                            HIGH                        No Data                 LOW                          HIGH
                                                                                Available




               Section 13 - DISPOSAL CONSIDERATIONS

■ - Containers may still present a chemical hazard/ danger when empty.
- Return to supplier for reuse/ recycling if possible.
Otherwise:
- If container can not be cleaned sufficiently well to ensure that residuals do not remain or if the container cannot be used to
store the same product, then puncture containers, to prevent re-use, and bury at an authorised landfill.
- Where possible retain label warnings and MSDS and observe all notices pertaining to the product.


                                                                                                                                   continued...
                                                    O'CONNELL FORM RELEASE AGENT
Chemwatch Independent Material Safety Data Sheet
Issue Date: 23-Aug-2011                                                                                                                  CHEMWATCH 28-1590
C9317EC                                                                                                                                        Version No:2.0
                                                                                                                                         CD 2011/2 Page 7 of 8
                                                                                                                      Section 13 - DISPOSAL CONSIDERATIONS

Legislation addressing waste disposal requirements may differ by country, state and/ or territory. Each user must refer to laws
operating in their area.
A Hierarchy of Controls seems to be common - the user should investigate:
- Reduction.
- DO NOT allow wash water from cleaning or process equipment to enter drains.
- It may be necessary to collect all wash water for treatment before disposal.
- In all cases disposal to sewer may be subject to local laws and regulations and these should be considered first.
- Where in doubt contact the responsible authority.
- Recycle wherever possible or consult manufacturer for recycling options.
- Consult State Land Waste Authority for disposal.
- Bury or incinerate residue at an approved site.
- Recycle containers if possible, or dispose of in an authorised landfill.



                 Section 14 - TRANSPORTATION INFORMATION




Labels Required: COMBUSTIBLE LIQUID, regulated under AS1940 for Bulk Storage purposes only.

HAZCHEM:
None (ADG7)


NOT REGULATED FOR TRANSPORT OF DANGEROUS GOODS: ADG7, UN, IATA, IMDG



                 Section 15 - REGULATORY INFORMATION

POISONS SCHEDULE S5

REGULATIONS

Regulations for ingredients

diesel (CAS: 68334-30-5,68512-90-3,64742-81-0,68476-30-2) is found on the following regulatory
lists;
"Australia Hazardous Substances","Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory of Chemical
Substances (AICS)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix E (Part 2)",
"Shipping Names (Dutch)"

lanolin (CAS: 8006-54-0,8020-84-6,68424-58-8) is found on the following regulatory lists;
"Australia Inventory of Chemical Substances (AICS)","Australia Therapeutic Goods Administration (TGA) Substances that may be used
as active ingredients in Listed medicines"

methanol (CAS: 67-56-1) is found on the following regulatory lists;
"Australia - New South Wales Hazardous Substances Prohibited for Specific Uses","Australia Exposure Standards","Australia
Hazardous Substances","Australia High Volume Industrial Chemical List (HVICL)","Australia Inventory of Chemical Substances
(AICS)","Australia National Pollutant Inventory","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) -
Appendix E (Part 2)","Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Appendix F (Part 3)",
"Australia Standard for the Uniform Scheduling of Medicines and Poisons (SUSMP) - Schedule 5","Australia Standard for the Uniform
Scheduling of Medicines and Poisons (SUSMP) - Schedule 6","GESAMP/EHS Composite List - GESAMP Hazard Profiles","IMO IBC Code
Chapter 17: Summary of minimum requirements","IMO MARPOL 73/78 (Annex II) - List of Other Liquid Substances","International
Council of Chemical Associations (ICCA) - High Production Volume List"

No data for O'Connell Form Release Agent (CW: 28-1590)



                 Section 16 - OTHER INFORMATION


INGREDIENTS WITH MULTIPLE CAS NUMBERS
Ingredient Name                                                     CAS
diesel                                                              68334- 30- 5, 68512- 90- 3, 64742- 81- 0, 68476- 30- 2
lanolin                                                             8006- 54- 0, 8020- 84- 6, 68424- 58- 8

■ Classification of the preparation and its individual components has drawn on official and authoritative sources as well as
independent review by the Chemwatch Classification committee using available literature references.
A list of reference resources used to assist the committee may be found at:


                                                                                                                                                continued...
                                            O'CONNELL FORM RELEASE AGENT
Chemwatch Independent Material Safety Data Sheet
Issue Date: 23-Aug-2011                                                                                                CHEMWATCH 28-1590
C9317EC                                                                                                                      Version No:2.0
                                                                                                                       CD 2011/2 Page 8 of 8
                                                                                                          Section 16 - OTHER INFORMATION

www.chemwatch.net/references.

■ The (M)SDS is a Hazard Communication tool and should be used to assist in the Risk Assessment. Many factors determine whether
the reported Hazards are Risks in the workplace or other settings.


This document is copyright. Apart from any fair dealing for the purposes of private study, research, review or
criticism, as permitted under the Copyright Act, no part may be reproduced by any process without written
permission from CHEMWATCH. TEL (+61 3) 9572 4700.

Issue Date: 23-Aug-2011
Print Date: 24-Aug-2011


This is the end of the MSDS.

				
DOCUMENT INFO
Shared By:
Categories:
Tags:
Stats:
views:16
posted:3/28/2012
language:English
pages:8