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Alternative Energy

Solutions for Alabama



Production of Second-Generation

Biofuels from Alabama Resources









October 24 2006

WHO WE ARE



Gas Technology Institute

> GTI’s mission is to be the leader in the

development and deployment of

technology solutions that contribute to a

secure, abundant, and affordable energy

future.

– An independent,

501c (3)

not-for-profit









Serving the Energy Industry Since 1941

> Over 1,000 patents

> Nearly 500 products commercialized

2

Facilities & Staff

> Main Facility: 18 acre

campus near Chicago

– Over 200,000 ft2 of

laboratory space

– 28 specialized laboratories

and facilities

> Approximately Flex-Fuel



250 employees Test Facility





– 70% are

scientists Offices



and engineers & Labs









Energy & Environmental Technology Center



3

Strategic Account

GTI Locations Management

Needham, MA (NGA)

Headquarters Washington

Des Plaines, IL Operations

(a suburb of Washington, DC

Chicago)









California

Project

Development

Specialist

Folsom, CA







GTI/Catoosa Drilling

Test Facility Process Research

Catoosa, OK and Evaluation

(near Tulsa) Group

Houston Office Birmingham, AL

Sugar Land, TX

4

The Fully Integrated Biorefinery



An effective integrated

biorefinery must

include biological and

thermochemical

conversion





Maximize efficiency of

biomass (and land)

utilization by

producing fuels

thermochemically and

biologically





Source: 2005 DOE OBP Bi-Annual Peer Review (Nov 14-16, 2005), Dr. Richard Bain 5

Thermal Conversion Options Are

Important to Biofuels Production Goals

> Integrated biorefinery benefits from

thermal conversion of ‘byproducts’

> “2nd-generation biofuels” : thermal

conversion has potential for significantly

greater production efficiency of biofuels

than fermentation

> Two thermal options from biomass:

– Syngas intermediate  F-T, alcohols, DME

– Bio-oil intermediate  syngas or direct

refining/hydrotreating



6

Thermochemical Conversion Routes









Source: OBP Multi-Year Program Plan 2007-2012 (August 31, 2005) 7

Biomass-to-Liquids via Fischer-Tropsch

Gasification is a key conversion process









Source: H. Boerittger, Economy of Biomass-to-Liquid Plants (May 2006): ECN-C-06-019 8

GTI Experience in Gasification

Technologies

STEAM-IRON-H2







HYGAS-SNG









U-GAS-Syngas







RENUGAS-Syngas

Mild-GAS-Coal-refining









Leader of International Energy Agency Task 33 - Biomass Gasification

9

Proprietary Fluidized Bed Gasifier

HOT PRODUCT GAS





GASIFICATION

REACTOR

> Unique biomass gasification

CYCLONE technology developed for:

BIOMASS

– A wide a range of fuels including

agriculture and forest resources

– Scalable to all necessary sizes

– Multiple process applications

FEED HOPPER



> Many years of development and

FLUIDIZED BED optimization at GTI

> Demonstrated at commercial scale by

FEEDING SCREW

GRID

Carbona

AIR

> High-value syngas production possible

ASH REMOVAL – Combined heat and power

SCREW

– High-efficiency electric power

ASH – Hydrogen and/or liquid fuels

– Co-production



10

Fluidized-Bed

Gasifier

Scale-up Projects



100 ton per day Bioenergy Demo Plant in

Hawaii using bagasse









80 ton per day Gasification Pilot

Plant in Tampere, Finland using

biomass & coal







1000 ton per day U-GAS® Industrial fuel gas in

Shanghai, China using coal



11

Skive, Denmark

Combined Heat & Power PROJECT

• Pelletized wood fuel

• 165 tons/day fuel feed, max.

• 20 MWth for 5.5 MWe + 11.5 MW district heat

• GTI fluidized bed gasifier – 3 gas engines, 2

boilers

• International show case: DOE, EU, DEA- subsidy

for the project









STATUS of PROJECT

• Ground breaking took place in April 2005

• Engineering and procurement for gasification plant by Carbona

• Plant starting operation in fall 2006



12

GTI’s Flex-Fuel Test Facility



> Flexible fuel

capability

> Operational

flexibility

> Plug and play

systems

integration and

testing









13

Flex-Fuel Test Facility Capabilities

Features

• Coal – 10 tpd w/air; 17 tpd w/oxygen

• Biomass – 24 tpd w/air; 40 tpd w/oxygen

• Opportunity Fuels & Dual Fuel Operation

• On-line Syngas Analysis Systems

Integrated Process Evaluations

• Advanced Fuel Feeding Systems

• Syngas Cleanup Systems

• CO2 Capture Technologies

• Syngas-to-Liquids Production

• Advanced Power Conversion Systems

• Hydrogen Production





14

GTI Gasification and Gas Processing

> Highly experienced senior staff

> GTI gasification and gas conditioning know-how

(licenses and commercial projects)

> Flex-Fuel Test Facility

> Laboratory facilities – fuel reactivity, gasification, gas

contaminant removal, catalysts performance,

membrane permeation and stability, solvent

properties, high-volume gas test loop …



We are a performing RD&D organization, from concept

origination to real-world application.

15

Collaboration Opportunities

> Develop an Alabama thermal conversion R&D facility

– Syngas generation, conditioning and catalysis systems

– GTI has done similar projects:

> at Ajou University, Korea

> at Industrial Technology Research Institute, Taiwan

> Participate in new GTI project for AL resource

conversion to biofuels

– Pretreatment, gasification and pyrolysis conversion

technologies for AL biomass materials

> Partner on scale-up projects at GTI R&D facilities

– e.g., sabbatical & graduate work in bioenergy R&D







16



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