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									- - - - - - - - - - - - - - - - MATERIAL SAFETY DATA SHEET - - - - - - - - - - - - - - Miles
MANUFACTURER'S NAME: MILES INC. 12707 WEST 63RD STREET SHAWNEE MISSION, KS 66216-1846 TRANSPORTATION EMERGENCY, CALL CHEMTREC: 800-424-9300 DISTRICT OF COLUMBIA: 1-201-239-6633 MILES NON-TRANSPORTATION EMERGENCY NO.: 913-631-4800 MILES INFORMATION PHONE NO.: 913-631-4800 ISSUE DATE: 10/05/87 SUPERSEDES: 09/08/86 REVISION NO.: 5 ----------------------------------------------------------I. PRODUCT IDENTIFICATION ----------------------------------------------------------PRODUCT NAME: Negabot(R) Plus Paste PRODUCT CODE NUMBER: 134-20, 134-21, 134-56 CHEMICAL FAMILY: Guanidine and Organo phosphate oral paste wormer CHEMICAL NAME: Active Ingredient (A.I.) A. Dimethyl (2,2,2-trichloro-1-hydroxyethyl) phosphonate B. N-(2-methoxyacetamido-4-phenylthio-N'N"-bismethoxycarbonyl-guanidin SYNONYMS: (A.I.) Febantel & Trichlorfon CAS NUMBER: See Below T.S.C.A. STATUS: Product listed with FDA (NADA 131-412) CHEMICAL FORMULA: Mixture, does not apply HAZARD STATEMENT: This product is hazardous under the criteria of the Federal OSHA Hazard Communication Standard, 29 CFR 1910.1200. ----------------------------------------------------------II. HAZARDOUS INGREDIENTS ----------------------------------------------------------EXPOSURE LIMIT COMPONENTS Approx. % OSHAACGIHPEL/TWA TLV/TWA ----------------------------------------------------------Trichlorfon 40.0 NE NE CAS #52-68-2 Febantel 7.0 NE NE CAS #58306-30-2 Mineral Oil 42.0 NE Mist, 5 mg/m3 CAS #8012-95-1 10 mg/m3 STEL Inerts 11.0 NA NA ----------------------------------------------------------III. PHYSICAL DATA ----------------------------------------------------------APPEARANCE: Paste in plastic syringe COLOR: White to off white ODOR: NDA ODOR THRESHOLD: NDA MOLECULAR WEIGHT: NA MELTING POINT: NDA BOILING POINT: NA VAPOR PRESSURE: NDA VAPOR DENSITY (AIR=1): NDA pH: NDA SPECIFIC GRAVITY: 1.2 BULK DENSITY: NDA SOLUBILITY IN WATER: Insoluble % VOLATILE BY VOLUME: NDA ----------------------------------------------------------IV. FIRE & EXPLOSION DATA ----------------------------------------------------------FLASH POINT deg F (deg C): NA FLAMMABLE LIMITS: LEL: NA UEL: NA EXTINGUISHING MEDIA: Water Spray SPECIAL FIRE FIGHTING PROCEDURES, UNUSUAL FIRE OR EXPLOSION HAZARDS: Plastic syringes will burn if ignited. Keep out of smoke, cool exposed containers with water spray. Fight fire from upwind position. Use Self-contained Breathing Apparatus. Contain runoff to prevent entry into sewers or waterways.

NEGABOT(R) PLUS PASTE
----------------------------------------------------------V. HUMAN HEALTH EFFECTS DATA ----------------------------------------------------------PRIMARY ROUTE(S) OF ENTRY: Ingestion, dermal HUMAN EFFECTS AND SYMPTOMS OF OVEREXPOSURE: Inhibition of cholinesterase. EYE: Trichlorfon may cause eye irritation DERMAL: Avoid contact, Trichlorfon can be absorbed through the skin, excessive amounts can cause inhibition of cholinesterase. INHALATION: During manufacturing avoid inhalation of mineral oil. Mist can cause pneumonia. Trichlorfon will cause cholinesterase inhibition, avoid dust during manufacturing. INGESTION: Excessive amounts can lead to cholinesterase inhibition. SYMPTOMS: Cholinesterase inhibition will cause a sense of tightness in the chest, sweating, contracted pupils, stomach pains, vomiting and diarrhea. CARCINOGENICITY - (Human): NTP: Not Listed IARC: Not Listed OSHA: Not Listed MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE: NDA ----------------------------------------------------------VI. ANIMAL TOXICITY ----------------------------------------------------------ORAL, LD50 (INGESTION): Rat, 1000 mg/kg DERMAL, LD50 (SKIN CONTACT): Rabbit, 5400 mg/kg INHALATION, LC50: NE FISH, LC50: NE EYE EFFECTS: (A.I.) Mild irritant SKIN EFFECTS: Non irritating, Trichlorfon is a moderate contact Allergen for guinea pigs. CHRONIC EFFECTS: Trichlorfon, tumorigenic, reproductive and mutagenic effects listed RTECS. Febantel, potential teratogen in some species of animals. OTHER: Trichlorfon, cholinesterase inhibitor. CARCINOGENICITY - (Animal): NTP: Not Listed IARC: Not Listed OSHA: Not Listed ----------------------------------------------------------VII. EMERGENCY & FIRST AID PROCEDURES ----------------------------------------------------------IN CASE OF POISONING: If symptoms occur, IMMEDIATELY call physician, poison control center or hospital emergency room. EYE CONTACT: Flush with water for 15 minutes. SKIN CONTACT: Wash with soap and water. INHALATION: Move to fresh air. INGESTION: If person is conscious, give liquids to dilute, induce vomiting, repeat until clear, contact a physician. NOTE TO PHYSICIAN: Trichlorfon is a cholinesterase inhibitor. Atropine Sulfate is an antidote, give after cyanosis is overcome. 2-PAM is a supplemental treatment. Give supportive treatment. Do not walk the patient nor give morphine. ----------------------------------------------------------VIII. EMPLOYEE PROTECTION RECOMMENDATIONS ----------------------------------------------------------EYE PROTECTION: Wear safety glasses when packaging or goggles during manufacturing. SKIN PROTECTION: Wear rubber gloves when handling product. RESPIRATORY PROTECTION: Wear pesticide respirator during manufacturing if ventilation is not adequate. VENTILATION: General to maintain exposure levels below exposure limits. ENGINEERING CONTROLS & WORK PRACTICES: Avoid contact with product, and aerosols during manufacturing. HYGIENIC PRACTICES RECOMMENDED: Wash after handling product. Launder clothes daily after use. Personnel routinely exposed to this product should have their cholinesterase blood level monitored. OTHER: None

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- - - - - - - - - - - - - - - - MATERIAL SAFETY DATA SHEET - - - - - - - - - - - - - - Miles
----------------------------------------------------------IX. REACTIVITY DATA ----------------------------------------------------------STABILITY: Stable POLYMERIZATION: Will not occur. CONDITIONS TO AVOID: Light; temperature above 77 deg F and pH above 6.0 INCOMPATIBILITY (MATERIALS TO AVOID): Caustics and acids HAZARDOUS DECOMPOSITION PRODUCTS: DDVP, HCL, P2O5 if heated to decomposition ----------------------------------------------------------X. SPILL OR LEAK PROCEDURES ----------------------------------------------------------STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED: Place in sealed containers. Wash area with bleach and caustic solution, rinse with water. WASTE DISPOSAL METHOD: Send to EPA approved landfill. SUPERFUND REPORTABLE QUANTITY: 250 pounds which contains 100 pounds of Trichlorfon RCRA STATUS: Not Listed ----------------------------------------------------------XI. SPECIAL PRECAUTIONS & STORAGE DATA ----------------------------------------------------------STORAGE TEMPERATURE (MIN./MAX.): Not to exceed 77 deg F AVERAGE SHELF LIFE: See expiration date SPECIAL SENSITIVITY (HEAT, LIGHT, MOISTURE): Head and light PRECAUTIONS TO BE TAKEN IN HANDLING AND STORING: Store in cool dark place. ----------------------------------------------------------XII. SHIPPING DATA ----------------------------------------------------------D.O.T. SHIPPING NAME: NA TECHNICAL SHIPPING NAME: NA D.O.T. HAZARD CLASSIFICATION: NA UN/NA NO.: NA REPORTABLE QUANTITY: NA D.O.T. LABELS REQUIRED: NA D.O.T. PLACARDS: NA FREIGHT CLASS BULK: NA FREIGHT CLASS PACKAGE: Drugs & Medicines, released to value as described in Item NMFC 6000. ----------------------------------------------------------XIII. OTHER INFORMATION ----------------------------------------------------------For Veterinary Use Only. ----------------------------------------------------------XIV. DOCUMENTATION ----------------------------------------------------------REASON FOR ISSUE: Revisions APPROVED BY: Al Selland TITLE: HES Compliance Administrator DATE APPROVED: 10/05/87 ----------------------------------------------------------ADDENDUM ----------------------------------------------------------REVISION NO.: 0 This addendum is being provided to indicate the presence of chemicals covered by Section 302 and Section 313 of SARA Title III. This product contains: SECTION 302 EXTREMELY HAZARDOUS SUBSTANCES: Trichlorfon (CAS #52-68-6) - 40% SECTION 313 TOXIC CHEMICALS: Trichlorfon (CAS #52-68-6) 40% REASON FOR ISSUE: Additional Information APPROVED BY: Michael L. Carter TITLE: H.E.S. Compliance Administrator DATE APPROVED: 12/06/88 ----------------------------------------------------------NA = NOT APPLICABLE NE = NOT ESTABLISHED NDA = NO DATA AVAILABLE

NEGABOT(R) PLUS PASTE
----------------------------------------------------------DISCLAIMER OF EXPRESSED AND IMPLIED WARRANTIES: Although reasonable care has been taken in the preparation of this document, we extend no warranties and make no representation as to the accuracy or completeness of the information contained therein, and assume no responsibility regarding the suitability of this information for the user's intended purposes or for the consequences of its use. Each individual should make a determination as to the suitability of the information for their particular purpose(s). A request has been made to the manufacturer to approve the contents of this material safety data sheet. Upon receipt a new MSDS will be made available. ----------------------------------------------------------COMPAS Code: 11310290

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