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Use of HFCs as ODS replacements

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HFCs: A Critical Link in Protecting Climate

and the Ozone Layer

A. R. Ravishankara

Guus Velders

Melanie Miller

Mario Molina

Steering committee headed by Joseph Alcamo









Disclaimer:

I am not talking as a co-Chair of WMO/ENEP SAP panel

Opinions expressed are mine and not necessarily those of NOAA

Provisions of the MP led to

decreases in ODS

10



Lower atmospheric Cl+Br

8

Lower Atmospheric Cl+Br (PPb)









Without Montreal

Protocol

6







4 HCFCs



CFCs, Halons, Others

2





Natural CH3Br and CH3Cl

0

1950 1970 1990 2010 2030 2050

Year





 The Montreal Protocol is working and the ODSs are declining.

 HCFCs, the transition substitutes, are not contributing greatly

to ozone depletion.

Montreal Protocol’s role in safeguarding

the ozone layer.









Newman et al. WMO/UNEP SAP 2011





 MP prevented major global ozone layer depletion

 Current ozone layer depletions are small, except for the polar

spring time ozone depletions.

 Ozone layer will recover in this century. Ozone hole will heal

towards the end of this century.

Montreal Protocol effectively protected

climate









 ODS-Phase out led to a drop of ~ 8.0 GtCO2eq per year (1988 -2010).

 The avoided annual ODS emission (~ 10 Gt CO2eq in 2010 alone)

- x5 the Kyoto target for 2008-2012 (1st commitment period).

 ODS decrease: one of the largest intentional global GHG emission

reductions to date

Montreal Protocol “led” to HFC use









 MP successfully phased out CFCs and is phasing out HCFCs.

 Phase out done via use of substitute chemicals or other approaches



 HFCs are the main replacements in many ODS applications

Use of HFCs is increasing



60



HFC abundances

50







40









Abundances (ppt)

30







20 HFC -134a

HFC -125

10

HFC -143a

0 HFC -152a

1990 1995 2000 2005 2010

Year









 Consumption of HFCs is increasing rapidly

 Consequent atmospheric growth rate of some HFCs are increasing

very rapidly (some as much as 10% per year)

 The current contributions of HFCs to radiative forcing is still small

(<1% of GHGs)

Climate benefits of Montreal Protocol

may be lost because of growth in HFCs









 Unabated, future HFC emissions may offset climate benefit of MP.

 HFC emissions expected could be ~3.5 to 8.8 Gt CO2eq in 2050.

 Roughly equivalent to:

- ODS annual emissions drop of 8.0 GtCO2eq per year for 1988 -2010

- 7 to 19% of the CO2 emissions in 2050 (SRES)

- 18 to 45% of CO2 emissions for the 450 ppm CO2.

There is, of course, inherent uncertainty in such projections.

HFCs contribution to climate change by

future emissions can be large









 Unabated, future HFC contribution radiative forcing can be large.

 Radiative forcing by future HFC emissions can be ~25% of that of

CO2 future emissions (SRES scenarios).

 Future HFC emissions can significantly hinder the 450 ppm

stabilization target.

Low GWP-HFCs can retain climate

benefits of MP.









 Currently HFC contrbute <1% of the total radiative forcing.

 HFCs are not all the same! Many HFCs (with shorter lifetimes)

have very low GWPs.

 There do not appear to be other major environmental problems with

the use of very low GWP HFCs.

 Possible to retain a <1% contribution in 2050 using low-GWP

HFCs (GWP <20) and other alternatives, even for the upper range

emissions Scenarios.

Summary

 MP effectively protected climate.

 HFCs were introduced mostly because of MP

 Currently HFCs are not significant for climate forcing

 Future climate forcing by HFCs can be very large because of

using high-GWP HFCs

 There are many ways to reduce the climate influence of high-

GWP HFCs





Thank you for your attention

&

Over to Dr. Melanie Miller



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