4b96ad0a-ac2b-4b2e-9a61-cf90372592ff.xls
Worker Chemical Safety Assessment (CSA) Template
Guidance supporting the development of Generic Exposure Scenarios under
REACH
Disclaimer
The information contained in this paper is intended for guidance only and whilst the information is provided in
utmost good faith and has been based on the best information currently available, is to be relied upon at the user’s
own risk.
No representations or warranties are made with regards to its completeness or accuracy and no liability will be
accepted for damages of any nature whatsoever resulting from the use of or reliance on the information.
WARNING
Every company has a responsibility to ensure that it implements REACH in accordance with the
Regulation. As stated in the legal notice on RIP Guidance Documents, information contained in the
guidance does not constitute legal advice and only the REACH Regulation can serve as an authentic
reference. Although RIP guidance is issued by the European Chemicals Agency, the Agency does not
accept liability with regard to the content.
Document History
Version Comment Date
Version 0 First edition Dec-09
Version 1 Editorial adjustments applied Feb-10
Worksheet 0. 'Introduction and Contents'
Under 'References': added weblink to draft up-dates to ECHA guidance and
adjusted identified Version numbers.
Worksheet 2. 'Worker CSA Template'
a. Column 'C' Revised life cycle stage for 'Manufacture of Substance A' to
reflect 'Industrial - SU3'
b. Annotation added to the cell for the short term inhalation DNEL to highlight
that an adjustment to the worksheet is required if a short term DNEL is to be
applied in place of/alongside the long term inhalation DNEL.
Worksheet 3. 'Worker - Ex ES Annex'
a. Row 2, Revised reference to ECHA ES Template to reflect Draft Version 2
Ref 1 Example GES Titles
a. Additional comment included to indicate that Use Descriptors and scope
statements may be expected for Substances of Very High Concern (SVHC)
b. Some adjustments to Use Descriptor details.
c. Deleted entries for 'Propellant' and 'Polymer Production' which are not in the
Solvents GES Library of titles
Ref 3 TRA Worker Expo modifers
a. Updated entries to clarify where LEV efficiencies are applicable only to
'Solids' or 'Volatiles' for certain PROCs.
b. Deleted row 18 detailing 95% efficiency for LEV Professional for PROC17
and 18. Entry included in error. 95% efficiency not relevant for any PROCs
applicable to professional activities within the TRA.
Title Page & Document history Page 1
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Developing Generic Exposure Scenarios (GES) and their application in the
development of Substance-specific Exposure Scenarios for Workers
- Worker Chemical Safety Assessment (CSA) Template
0. Introduction
The development of GESs requires input from individuals knowledgeable in the identification of uses through
the supply chain and those competent in human health and environmental risk assessment processes under
REACH.
Users of this Template are referred to the CEFIC Guidance for Developing Generic Exposure Scenarios Under
REACH for further guidance.
The Microsoft Excel®-based spreadsheet Template can be used for developing Generic Exposure Scenarios
(GESs). Table 1 provides a structured format for the standardized collection of use information (use
description) and associated typical operational conditions (OCs) and risk management measures (RMMs).
Table 2 provides the means to document the chemical safety assessment for each use, termed Contributing
Scenario, and to record the relevant RMMs required or recommended for the demonstration of safe use. These
are then captured in an Exposure Scenario narrative document for subsequent communication. The
combination of both Tables 1 and 2 support consistency and transparency in the development of sector-
specific GES for occupational exposure.
The Template will also help Lead Registrants to translate available sector-specific GES’s into substance-
specific exposure scenarios for occupational exposure. Therefore Lead Registrants are encouraged to use this
structured format within Consortia and SIEFs.
Additionally the Template can be used to support data transfer into certain IT systems. An example is given
how data elements (standard phrases) can be transferred into an extended safety data sheet structure.
This Template addresses GES development for occupational exposure. Templates for environmental and
consumer exposure are under separate development.
Contents
The worksheets contained in this excel file comprise:
1. Outline procedure - Using the Worker CSA Template (READ THIS FIRST before using the
Template)
2. Worker CSA Template (Tables 1 and 2 GES process)
2.a. Phrase Pick lists - list of phrases used in the pick lists contained in the Worker CSA Template
3. Worker - Example ES Annex (for use in communicating the ES Narrative)
Ref 1: Example GES Titles and associated use descriptor details
Ref 2: Example Standard Phrases for use in Exposure Scenario development
Ref 3: TRA Worker Exposure modifiers - summary of exposure modifiers built into the ECETOC TRA
and examples of supporting Risk Management Measure phrases
References:
Cefic guidance: Developing Generic Exposure Scenarios Under REACH, July 2009, Version 0
ECETOC Targeted Risk Assessment (TRA) Version 2 - http://www.ecetoc.org/tra
ECHA Guidance on CSA & IR, Part D Exposure Assessment Version 1 May 2008. Including draft updates for
Ref 12 Use Descriptor System (draft Version 2, Nov 2009) and Exposure Scenario Format (draft Version 2 ....
2009). Draft updates available from ECHA web site: http://guidance.echa.europa.eu/guidance4_en.htm
0. Introduction and Contents Page 2
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Worksheet 1: Outline procedure for using the Worker CSA Template
step step description remarks
1. For the selected substance/group of substances, map Review available Sector-specific mapping to support the
the supply chain to compile an inventory of uses process
a. For a substance or group of substances with similar For example, working with inhouse knowledge and Downstream
applications, map the supply chain to compile an inventory of Users, the Solvents Manufacturers have grouped the main
uses involving potential for worker exposure. Identify the solvents applications into selected GES Titles, together with a
relevant uses throughout the substance(s) life-cycle. scope statement on what is covered and the associated Use
Descriptor. Refer to Worksheet titled 'Ref 1 Example GES Titles'
for a list of the current GES Titles applied in the solvents sectors.
b. Identify the available GESs for the substance(s) of interest. For example, for the list of Solvents GES titles, review the details
Select as appropriate to reflect the uses of the substance(s) of and mark each title that is relevant. Columns are provided in the
interest. If any of the GES titles contained in the example listing 'GES Titles' worksheet to identify those relevant and also to
in Ref 1 is relevant, select the title(s) and allocate an ES#. allocate an ES number (see columns G and H).
c. Where relevant GES information is available from an industry If no Sector Specific GES information is available on which to start
Sector Group, obtain the details for the chosen uses and building your CSA. The CSA may still be developed using Tables
associated substance type, e.g. based on physchem 1 and 2 of the worker template in liaison with Trade Associations
characteristics (such as volatility or dustiness), and hazard or selected key customers. See worksheet '2. 'Worker CSA'.
(based on an indicative DNEL) and use as the basis for
developing the substance CSA.
Refine / transform selected Worker-GESs into Use the Template in Worksheet titled '2.Worker CSA
2.
Substance-specific ESs Template' to document the process
a. Include substance specific information in the table at the top of As shown in worksheet 2 - example adjustments are indicated
the worksheet, including e.g. the substance name and in' red ' and the associated cells highlighted in 'blue'.
properties (e.g. CASNR, volatility, dustiness). In addition,
include the information for the relevant GES titles: See item 4 below for details on using the Standard Phrase pick
1. GES#, 2. Processes, Tasks, Activities covered, 3. Use lists.
Descriptor details. In addition, relevant default Operational
Conditions applicable to the Exposure Scenario may be added
as standard phrases. An example selection is provided as a
pick list.
b. In Tables 1 and 2, include the information for the substance Sector specific GES's are being developed in a number trade
type from the sector-specific GESs, where available. First associations. These are used as input to develop substance-
complete Table 1 Mapping Uses in the Supply Chain (located specific ES in this worksheet. Where trade associations use a
on row 22) by adding: different format the Consortium/Lead Registrant ultimately decides
- the ES-number in column 'A': which format to use to facilitate documentation of the CSA and
- the short title of the selected ES in column 'B' subsequent e-SDS development.
- select the general Sector of Use in column 'C' (SU3 Industrial
or SU22 Professional)
c. Remove or add Contributing Scenarios (CS) as appropriate - A list of standard phrases for Contributing Scenarios have been
column 'D', 'E' and 'F' in Table 1. developed by the Solvents Sector. By way of example, the current
For each identified ES Title, list the uses identified as list of CS phrases is included in Worksheet titled 'Ref 2 Ex
'Contributing Scenarios' to describe the type of activity involving Standard phrases', starting at line 7, and added to the Worker
potential for exposure and associated typical Operational CSA Template as a pick list for selection in the CS columns.
Conditions (OCs) and Risk Management Measures (RMMs),
adjust as appropriate. Each CS is mapped to a Process See item 4 below for details on using the Standard Phrase pick
Category (PROC) considered appropriate. This is not an exact lists.
science and may require discussion with Downstream Users.
d. Moving into Table 2 'Chemical Safety Assessment - evaluation The TRA exposure estimates may be extracted from the ECETOC
of safe use', include the relevant ECETOC TRA exposure value TRA look up tables in the Worker Module, or the ECETOC TRA
for inhalation (column L) and dermal (column T) for the Technical Report No. 107 (soon available).
associated PROC. Note for inhalation the estimates differ for
industrial and professional uses. Also for inhalation, adjust the
units in the column header to 'ppm' or 'mg/m3' as appropriate.
e. Include the substance-specific Reference Values (DNELs) in As shown in worksheet 2 (example adjustments are indicated
the table provided at the top of the worksheet (see Cell 'F5'). in red ).
Any existing Risk Characterisation Ratios (RCRs) will be The recalculation of the RCR is automated in the worksheet.
recalculated with the substance DNEL(s) - see columns 'AA',
'AB', 'AC'.
1. Outline procedure Page 3
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f. If the RCR 1 then refine TIER1 estimates (the relevant cells See also worksheet titled 'Ref 3 TRA Worker exposure modifiers'.
are automatically highlighted in pink). Proceed to add the This includes the list of exposure modifiers that are integrated into
exposure modifiers as appropriate for each Contributing the ECETOC TRA at the Tier 1 level for inhalation and dermal.
Scenario by selecting from the drop down lists. Review the This worksheet also includes associated RMM phrases to support
annotations linked to the column headings for further the communication of the identified RMM.
explanation. The RCR will recalculate automatically. Adjust the
RMM phrases accordingly to take account of the additional To apply additional exposure modifiers with associated exposure
measures identified. RMMs should be identified per reduction efficiencieis, it is necessary to identify supporting
Contributing Scenario and will be transferred across to the e- justification criteria and include details within the CSR. Summary
SDS Annex for communication to Downstream Users (See Step details may be included within Table 2 as free text within column
3). ' R ' for inhalation, and column ' Y ' for dermal.
Refer also to step 2.f. for guidance on the inclusion of RMM
phrases in the CSA Template.
h. If RCR still >1 or OC's or RMMs are inappropriate for the use of The details of the TIER2 exposure assessments should be
the substance than perform TIER2 exposure assessment, documented in the CSR.
recalculate RCRs and adjust RMMs accordingly
3. Prepare substance-specific ES (eSDS for each Example given in Worksheet: 3. Worker - example ES
substance) Annex
a. Transfer the relevant information from Worksheet 2 'Worker The use of the Exposure Scenario narrative is to:
CSA' into an ES Format, example given in Worksheet 3 'Worker 1. Communicate / review with Consortia, DU organisation
- example ES Annex' including: 2. To form the basis of the Annex to the e-SDS for customer
1. Substance specific information communication
2. Operational Conditions
3. Contributing Scenarios The standard phrases used to populate the Worker CSA
4. Risk Management Measures associated with each Template are automatically transferred across to populate the
Contributing Scenario. Worker ES Annex. For presentation purposes it may be
appropriate to consolidate certain Contributing Scenarios and
associated RMMs to avoid repetition. In this case, it is
necessary to over-ride the functionality in the worksheet
which may be done by creating a copy of the text and pasting
using the 'values' only option under the 'paste special' excel
cmnd. This may be done in a new worksheet to avoid losing
the ES Annex template functionality for the generation of
further Exposure Scenarios.
4 Using the Standard Phrase Pick Lists Worksheet '2.a. Pick Lists'
All the standard phrases currently included in the pick lists The list of standard phrases contained in Worksheet 2a can be
within the Worker CSA Template are contained in worksheet customised by users to reflect the standard phrases relevant for
'2.a. Pick Lists'. These comprise the list of phrases identified to the development of their Exposure Scenarios. However, it is
date by the Solvents Sector and included within the worksheet recommended to utilise existing standard phrases where possible
'Ref2 Ex Standard Phrases'. and extend only by exception. Ultimately these standard phrases
will require translation into all the European languages for use in
Additional phrases may be added to the pick lists in worksheet the extended-Safety Data Sheet.
2.a. using normal excel rules. More than one phrase may be
selected from each pick list for inclusion in the Worker
Template by utilising the 'Cntrl M' function. Phrases may be
deleted by highlighting the relevant value/text in the cell in the
Worker Template and pressing 'Delete'.
1. Outline procedure Page 4
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EXAMPLE (incomplete - for illustrative purposes only)
Worksheet 2. Worker Chemical Safety Assessment Template: Tables 1 and 2 - Worker Chemical Safety Assessment (CSA)
Example for Worker - based on Solvents sector information Please note comments included in cell annotations
Substance specific information
N.B. Read Substance Substance A Reference Values
worksheet 1. CASnr 123-45-678 DNEL worker - inhalation (long term) 10 ppm
Substance volatility: 25 hPA DNEL worker - inhalation (short term) 20 ppm
'Outline
TRA volatility range medium DNEL worker - dermal (long term) 5 mg/kg/day
Procedure'
physical property liquid
before using this ES# 1 2 3 4 5 6 7 8 9 10 11 12 13
Template. Processes, tasks, activities covered Manufacture of Substance A or use Formulation, packing Covers the industrial Covers the industrial use etc
as an intermediate or process and re-packing of manufacture of polymers of Substance A as a
chemical or extraction agent. Substance A ….. ….. component of cleaning
Includes recycling/ recovery, products including ……
material transfers, storage,
sampling, associated laboratory
Industrial (SU3, SU8, SU9) Industrial (SU3, SU10) Industrial (SU3, SU10) Industrial (SU3) etc
Life Cycle Stage / Sector of Use
Applicable Use Descriptors (PROC or PROC1, PROC2, PROC3, PROC1, PROC2, PROC1, PROC2, PROC1, PROC2, etc
PROC4, PROC8a, PROC8b, PROC3, PROC4, PROC3, PROC4, PROC3, PROC4,
PC) PROC15 PROC5, PROC8a, PROC5, PROC6, PROC7, PROC8a,
PROC8b, PROC9, PROC8a, PROC8b, PROC8b, PROC10,
PROC14, PROC15 PROC14, PROC21 PROC13
Applicable Use Descriptors (ERC or ERC1 ERC2 ERC 3 ERC4 etc
SpERC)
Default Operational Conditions
concentration of substance in product Covers percentage substance in the product up to 100 % (unless stated differently) [G13].
physical form of product Liquid, vapour pressure 0.5 - 10 kPa [OC4]. To Make Multiple Entries in a cell:
1. Select the cell, then
frequency and duration of use Covers daily exposures up to 8 hours (unless stated differently) [G2]
2. Press 'Ctrl'+'m'
other Operational Conditions of use Assumes use at not > 20oC above ambient [G15]; To delete entries, highlight the value/text
Assumes a good basic standard of occupational hygiene is implemented [G1]. in the cell and press 'Delete'
THE INCLUDED PHRASES REFLECT THE CURRENT STATUS OF WORK CARRIED OUT FOR THE SOLVENTS INDUSTRY ORGANIZED THROUGH ESIG/ESVOC. THESE PHRASES CLEARLY DO NOT CAPTURE ALL ACTIVITIES
THE PHRASES INCLUDED IN THE DROP DOWN LISTS REFLECT THE CURRENT STATUS OF WORK CARRIED OUT FOR THE SOLVENTS INDUSTRY ORGANIZED THROUGH ESIG/ESVOC. THESE PHRASES CLEARLY DO NOT CAPTURE ALL FOR ALL INDUSTRY SECTORS. OTHER SECTORS WILL NEED TO DEVELOP THEIR OWN PHRASE LIBRARIES. THE BUSINESS EUROPE REACH IMPLEMENTATION NETWORK SUPPORTS THE DEVELOPMENT OF A
ACTIVITIES FOR ALL INDUSTRY SECTORS. OTHER SECTORS WILL NEED TO DEVELOP THEIR OWN PHRASE LIBRARIES. THE BUSINESS EUROPE REACH IMPLEMENTATION NETWORK SUPPORTS THE DEVELOPMENT OF A EUROPEAN EUROPEAN STANDARD PHRASE CATALOGUE THAT WILL INCLUDE EXPOSURE SCENARIO PHRASE LIBRARIES. (http://reach.bdi.info/378.htm)
STANDARD PHRASE CATALOGUE THAT WILL INCLUDE EXPOSURE SCENARIO PHRASE LIBRARIES. (http://reach.bdi.info/378.htm)
Table 1: Mapping Uses in the Supply Chain Table 2: Characterising the Risk - Chemical Safety Assessment - Evaluation of Safe Use
DNEL = 10 ppm GES RMM phrases to build RMM advice (ref: GES Phrases ESIG/ESVOC 2009-12-07) - REACH ADVISED GES RMM phrases to build RMM advise (ref: GES Phrases ESIG/ESVOC 2009-12-07) - {RECOMMENDED}
Typical Mapped Personal Protection (ref: GES
Generic Exposure Scenario Contributing Scenarios Typical Mapped RMMs Inhalatory exposure Dermal exposure Risk Characterization Technical Measures and Conditions (ref: GES Phrases 2.1.1_2.1.2 ) Organizational Measures (ref: GES Phrases 2.1.3 ) Environmental Measures Technical Measures and Conditions (ref: GES Phrases 2.1.1_2.1.2 ) Organizational Measures (ref: GES Phrases 2.1.3 ) Personal Protection (ref: GES Phrases
Operating Risk Management Measures (RMMs) Phrases 2.1.4 ) Environment (ref: GES Phrases 2.2 )
(ref: GES Phrases 2.2 ) 2.1.4 )
Conditions Use Descriptor
TRA Predicted TRA Dermal extra Predicted Dermal RMMs for communication - Consolidate into GES or e-SDS Technical measures at process level Technical conditions and measures Organisational measures to Duration conjunction (respiratory & dermal protection) Environment Technical measures at process level Technical conditions and measures Organisational measures to Duration conjunction (respiratory & dermal protection) Environment
Dermal exposure exposure exposure Exposure (source) to prevent release to control dispersion from source prevent/limit releases, dispersion and (source) to prevent release to control dispersion from source prevent/limit releases, dispersion and
Life Cycle Stage / CS further TRA Predicted
TRA LEV :
Dilution
TRA TRA
Extra
Free text - comment to
Predicted
TRA Free text - comment to
REACH ADVISED: phrase [RMM code]
supporting phrase LEV Process Category Exposure - ventilation TRA RPE exposure Exposure - (mg/kg/d) - no LEV modifier: (mg/kg/d) - RCR RCR RCR
ES # Short Title Area of Title specification [free text] [free text] efficiency concentration duration clarify additional modifiers reduction concentration PPE factor [optional] clarify additional modified Recommended: {phrase [RMM code].} towards the worker exposure towards the worker exposure
[optional] (Yes/No] [scroll list] (ppm) - effectiveness factor modifier: (ppm) - (inhalation) (dermal) (all routes)
Application [free text] (%) factor factor modifier (inhalation) factor factor modifier (dermal)
no modifiers (%) [optional] modified
Manufacture of Industrial -SU3 General exposures Continuous process Continuous Closed processes Yes 1 - Use in closed process, 0.01 0.01 0.34 0.34 0.0 0.1 0.07 Handle substance within a closed system [E47].{Drain down and flush Handle substance within a closed {Drain down and flush system prior to {Clear spills immediately [C&H13]}. {Retain drain downs in sealed storage
Substance A [CS1]. [CS54]. process; daily; 15 - no likelihood of exposure system prior to equipment break-in or maintenance [E55]}.{Clear spills system [E47]. equipment break-in or maintenance pending disposal or for subsequent recycle
1 hour (time on immediately [C&H13]}. {Retain drain downs in sealed storage pending [E55]}. [ENVT4]}.
ES#1
plant); ambient disposal or for subsequent recycle [ENVT4]}.
temp.
Industrial -SU3 General exposures Continuous process With sample Continuous; daily; Enclosed process; No 2 - Use in closed process, 10 90 1.00 1.37 0.1 0.14 0.1 0.0 0.13 Handle substance within a closed system [E47].Ensure material Handle substance within a closed Ensure material transfers are under {Wear suitable gloves tested to EN374
[CS1]. [CS54]. collection [CS56] 15 mins - 1 hour Outside location; no likelihood of exposure transfers are under containment or extract ventilation [E66]. {Wear system [E47]. containment or extract ventilation [PPE15]}.
(time on plant) closed/semi- suitable gloves tested to EN374 [PPE15]}. [E66].
closed sampling
point
Industrial -SU3 General exposures Use in contained batch Batch process; Closed equipment, Yes 3 - Use in closed batch 25 90 2.50 0.34 0.1 0.03 0.3 0.0 0.26 Handle substance within a closed system [E47].Ensure material Handle substance within a closed Ensure material transfers are under
[CS1]. processes [CS37]. ; daily; 15 - 1 hour; enclosed or vented process (synthesis or transfers are under containment or extract ventilation [E66]. system [E47]. containment or extract ventilation
With sample collection ambient temp. sampling points formulation) [E66].
[CS56].
Industrial -SU3 Process sampling [CS2]. Daily; 10 kPa Covers frequency up to: monthly use Assumes activities are at ambient temperature Material transfers [CS3].
the product up to 25 % [G12]. [OC5]. [G4]. (unless stated differently) [G17].
Covers percentage substance in Solid, low dustiness [OC1]. Covers frequency up to: daily yearly Operation is carried out at elevated temperature (> Dipping, immersion and pouring [CS4].
the product up to 100 % (unless use [G5]. 20°C above ambient temperature) [OC7].
stated differently) [G13].
Solid, medium dustiness [OC2]. Covers frequency up to: daily use, Indoor [OC8]. Equipment maintenance [CS5].
weekly, monthly, yearly. [G6].
Solid, high dustiness [OC6]. Outdoor [OC9]. Drum and small package filling [CS6].
2.a. Pick lists Page 6
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concentration in product physical form product frequency/duration of use other Operational Conditions of use Contributing Scenarios
Liquid, vapour pressure 10 Pa Aerosol generation due to elevated process Drum/batch transfers [CS8].
[OC15]. temperature [OC25].
Pouring from small containers [CS9].
Spraying [CS10].
Printing [CS11].
Drying and storage [CS12].
Bulk transfers [CS14].
General exposures (closed systems)
[CS15].
General exposures (open systems)
[CS16].
2.a. Pick lists Page 7
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concentration in product physical form product frequency/duration of use other Operational Conditions of use Contributing Scenarios
Operation and lubrication of high energy
open equipment [CS17].
Maintenance of small items [CS18].
Remanufacture of reject articles [CS19].
Engine lubricant service [CS20].
Operation of total loss equipment and
systems [CS21].
Transfer from/pouring from containers
[CS22].
Spraying/fogging by manual application
[CS24].
Spraying/fogging by machine
application [CS25].
Ad hoc manual application via trigger
sprays, dipping, etc. [CS27].
Disposal of wastes [CS28].
2.a. Pick lists Page 8
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concentration in product physical form product frequency/duration of use other Operational Conditions of use Contributing Scenarios
Mixing operations (closed systems)
[CS29].
Mixing operations (open systems)
[CS30].
Mold forming [CS31].
Casting operations [CS32].
Machine [CS33].
Manual [CS34].
Treatment by dipping and pouring
[CS35].
Laboratory activities [CS36].
Use in contained batch processes
[CS37].
Use in contained systems [CS38].
2.a. Pick lists Page 9
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concentration in product physical form product frequency/duration of use other Operational Conditions of use Contributing Scenarios
Equipment cleaning and maintenance
[CS39].
Vapour degreasing bath [CS40].
Degreasing small objects in cleaning
station [CS41].
Cleaning with low-pressure washers
[CS42].
On site [CS43].
Cleaning with high pressure washers
[CS44].
Filling / preparation of equipment from
drums or containers. [CS45].
Large surfaces [CS46].
Cleaning [CS47].
Surfaces [CS48].
Spray Bottle [CS49].
Wiping [CS50].
Rolling, Brushing [CS51].
Manual spot cleaning (e.g. textiles etc)
[CS52].
Pelletizing [CS53].
Continuous process [CS54].
Batch process [CS55].
With sample collection [CS56].
No sampling [CS57].
Transport [CS58].
Internal [CS59].
No spraying [CS60].
Small scale [CS61].
Heating oil and diesel deliveries [CS62].
Vessel / container [CS63].
Calendering (including Banburys)
[CS64]
Polymerisation (bulk and batch) [CS65]
Intermediate polymer storage [CS66]
2.a. Pick lists Page 10
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concentration in product physical form product frequency/duration of use other Operational Conditions of use Contributing Scenarios
Pelletisation and pellet screening
[CS68]
Additivation and stabilisation [CS69]
Vulcanisation [CS70]
Cooling cured articles [CS71]
Hand application - fingerpaints, pastels,
adhesives [CS72]
Pressing uncured rubber blanks [CS73]
Cleaning of medical devices [CS74]
Initial factory fill of equipment [CS75]
Semi Automated process. (e.g.: Semi
automatic application of floor care and
maintenance products) [CS76]
Maintenance (of larger plant items) and
machine set up [CS77]
Engine lubricant service [CS78]
Metal machining operations [CS79]
Automated metal rolling/forming [CS80]
Dedicated facility [CS81]
Non-dedicated facility [CS82]
Semi-automated metal rolling/forming
[CS83]
Filling of articles/equipment [CS84]
Bulk product storage [CS85]
Rework of articles [CS86]
Polyol processes [CS87]
Extrusion and masterbatching [CS88]
Injection moulding of articles [CS89]
Small scale weighing [CS90]
Bulk weighing [CS91]
Additive premixing [CS92]
Automated process with (semi) closed
systems [CS93]
2.a. Pick lists Page 11
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concentration in product physical form product frequency/duration of use other Operational Conditions of use Contributing Scenarios
Film formation - force drying (50 -
100°C). Stoving (>100°C). UV/EB
radiation curing [CS94]
Film formation - air drying [CS95]
Preparation of material for application
[CS96]
Spraying (automatic/robotic) [CS97]
Roller, spreader, flow application
[CS98]
Production or preparation or articles by
tabletting, compression, extrusion or
pelletisation [CS100]
Application of cleaning products in
closed systems [CS101]
Finishing operations [CS102]
Vessel and container cleaning [CS103]
Maintenance and machine set up
[CS104]
Ion exchange processes [CS105]
phase separation [CS106]
(closed systems) [CS107]
(open systems) [CS108]
Tyre build up [CS112].
Production of articles by dipping and
pouring [CS113].
Bulk transfers from tote tanks and
supply vessels [CS114]
Drilling mud (re-)formulation [CS115]
Drill floor operations [CS116]
Operation of solids filtering equipment
[CS117]
Operation of solids filtering equipment -
vapour exposures [CS118]
Operation of solids filtering equipment -
aerosol exposures [CS119]
2.a. Pick lists Page 12
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concentration in product physical form product frequency/duration of use other Operational Conditions of use Contributing Scenarios
Cleaning of solids filtering equipment
[CS120]
Treatment and disposal of filtered solids
[CS121]
Extrusion and expansion of polymer
mass [CS122].
Collection and re-processing of
shavings, cuttings, etc [CS123].
Product packaging [CS124].
Production of foam-based objects
[CS125].
Installation of insulation panels
[CS126].
Centrifuging including discharging
[CS127].
Semi-bulk packaging [CS128].
Treatment by heating [CS129].
Article formation in mould [CS130].
Cutting by heated wire [CS131].
Foaming [CS132].
Compression [CS133].
Cutting and shaving [CS134].
General risk management measures
applicable to all activities [CS135].
Batch processes at elevated
temperatures [CS136].
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ADVISED MEASURES
Process Category Technical measures (prevention) Technical measures (dispersion) Organisational measures Duration
1 - Use in closed process, no Limit the substance content in the product to 1% Provide a good standard of general ventilation. If technical measures not practical: Avoid carrying out operation for
likelihood of exposure [OC16]. Natural ventilation is from windows and doors [G16]. more than 15 minutes [OC10]
etc. Controlled ventilation means air is supplied
or removed by a powered fan. [E1].
2 - Use in closed, continuous Limit the substance content in the product to 5% Ensure that enough fresh air is supplied to dilute Put lids on containers immediately after Avoid carrying out operation for
process with occasional controlled [OC17]. and remove dusts, fumes or vapours. Between 5 use [E9]. more than 1 hour [OC11]
exposure and 15 air changes per hour are recommended,
with a through draught. [E5].
3 - Use in closed batch process Limit the substance content in the product to Provide a good standard of general or controlled Label feed lines E23]. Avoid carrying out operation for
(synthesis or formulation) 25% [OC18]. ventilation (5 to 15 air changes per hour) [E40]. more than 4 hours [OC12]
4 - Use in batch and other process Limit the substance in product to 10% [OC19]. Provide enhanced mechanical ventilation by Carefully pour from containers [E62]. Avoid carrying out operation for
(synthesis) where opportunity for mechanical means [E48]. more than 0.5 hour [OC23]
exposure arises
5 -Mixing or blending in batch Limit the substance in product to 15% [OC20]. Use long handled tools where possible [E50]. Segregate the activity away from other Avoid carrying out operation for
processes (multistage and/or operations [E63]. more than 2 hours [OC24]
significant contact)
6 -Calendering operations Limit the substance in product to 20% [OC21]. Provide extract ventilation to points where Ensure doors and windows are opened
emissions occur [E54]. [E72].
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Process Category Technical measures (prevention) Technical measures (dispersion) Organisational measures Duration
7 -Industrial spraying Limit the substance content in the mixture to Use ventilation to extract vapours from freshly Ensure the ventilation system is regularly
50% [OC22]. coated articles/objects [E56]. maintained and tested [E74].
8a -Transfer of chemicals from/to Clear transfer lines prior to de-coupling [E39]. Carry out in a vented booth or extracted Clean equipment and the work area
vessels/ large containers at non enclosure [E57]. every day [C&H3].
dedicated facilities
8b -Transfer of chemicals from/to Use in semi-automated and predominantly Use long handled brushes and rollers where Dispose of empty containers and wastes
vessels/ large containers at enclosed filling lines [E41]. possible. [E58]. safely [C&H8].
dedicated facilities
9 -Transfer of chemicals into small Avoid dip sampling. [E42]. Carry out in a vented booth provided with Dispose of waste in accordance with
containers (dedicated filling line) laminar airflow [E59]. environmental legislation [C&H11].
10 - Roller application or brushing Use bulk or semi-bulk handling systems [E43]. Minimise exposure by partial enclosure of the Clear spills immediately [C&H13].
operation or equipment and provide extract
ventilation at openings [E60].
11 - Non industrial spraying Discharge sacks via suitable vented charge Minimise exposure by extracted full enclosure Contain and dispose of waste according
chute [E44]. for the operation or equipment [E61]. to local regulations [C&H14].
12 - Use of blow agents for foam Transfer materials directly to mixing vessels Ensure material transfers are under containment Avoid splashing [C&H15].
production [E45]. or extract ventilation [E66].
13 -Treatment of articles by Formulate in enclosed or ventilated mixing Provide extract ventilation to emission points Avoid spillage when withdrawing pump
dipping and pouring vessels [E46]. when contact with warm (>50 deg C) lubricant is [C&H16].
likely [E67].
14 - Production of preparations or Handle substance within a closed system [E47]. Ensure operation is undertaken outdoors [E69]. Handle all packages and containers
articles by tabletting, carefully to minimise spills [EI1].
compression, extrusion,
pelletisation
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Process Category Technical measures (prevention) Technical measures (dispersion) Organisational measures Duration
15 - Use of laboratory reagents in Handle substance within a predominantly closed Apply within a vented cab supplied with filtered Clear up spills immediately and dispose
small scale laboratories system provided with extract ventilation [E49]. air under positive pressure and with a protection of waste safely [EI9].
factor of >20 [E70].
16 - Using material as fuel Fill containers/cans at dedicated fill points Provide the operation with a properly sited Avoid manual contact with wet work
sources, limited exposure to supplied with local extract ventilation [E51] receiving hood [E71]. pieces [EI17].
unburned product to be expected
17 - Lubrication at high energy Transfer via enclosed lines [E52]. Ensure material transfers are under containment No specific measures identified [EI18].
conditions and in partly open or extract ventilation [E76].
process
18 - Greasing at high energy Use drum pumps [E53]. Drain or remove substance from equipment prior Ensure operatives are trained to
conditions to break-in or maintenance [E81]. minimise exposures [EI119].
19 - Hand-mixing with intimate Drain down and flush system prior to equipment Provide extract ventilation to material transfer No other specific measures identified
contact (only PPE available break-in or maintenance [E55]. points and other openings [E82]. [EI20].
20 - Heat and pressure transfer Use drum pumps or carefully pour from container Handle in a fume cupboard or under extract Allow time for product to drain from
fluids (closed systems) in [E64]. ventilation [E83]. workpiece [EI21].
dispersive use
21 - Low energy manipulation of Drain down system prior to equipment break-in Store substance within a closed system [E84]. Stay upwind/keep distance from source
substances bound in materials or maintenance [E65]. [EI22].
and/or articles
22a - Potentially closed operations Restrict area of openings to equipment [E68]. Use dedicated equipment [E85]. Apply vessel entry procedures including
with minerals at elevated use of forced supplied air [AP15].
temperature - pt mp - High
Fugacity
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Process Category Technical measures (prevention) Technical measures (dispersion) Organisational measures Duration
23a - Open processing and
transfer of minerals at elevated
temperature - pt mp - High
Fugacity
24a - High (mechanical) energy
work-up of substances bound in
materials and/or articles - pt
mp - High Fugacity
25a - Hot work operations with
metals - pt mp - High Fugacity
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Process Category Technical measures (prevention) Technical measures (dispersion) Organisational measures Duration
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Process Category Technical measures (prevention) Technical measures (dispersion) Organisational measures Duration
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Process Category Technical measures (prevention) Technical measures (dispersion) Organisational measures Duration
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Process Category Technical measures (prevention) Technical measures (dispersion) Organisational measures Duration
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RECOMMENDED MEASURES
Personal protection Environmental measures Technical measures (prevention) Technical measures (dispersion)
Use suitable eye protection and gloves Retain drain downs in sealed storage pending {Limit the substance in product to 1 % [OC16]}. {Provide a good standard of general ventilation.
[PPE14]. disposal or for subsequent recycle [ENVT4]. Natural ventilation is from doors, windows etc.
Controlled ventilation means air is supplied or
removed by a powered fan [E1]}.
Wear suitable gloves tested to EN374 Return IBCs to supplier [ENVT6]. {Limit the substance in product to 5 % [OC17]}. {Ensure that enough fresh air is supplied to
[PPE15]. dilute and remove dusts, fumes or vapours.
Between 5 and 15 air changes per hour are
recommended, with a through draught. [E5]}.
Wear chemically resistant gloves (tested to Return IBCs or tanks to supplier for re-use {Limit the substance content in the product to 25 {Provide a good standard of general or
EN374) in combination with ‘basic’ [ENVT7]. % [OC18]}. controlled ventilation (5 to 10 air changes per
employee training [PPE16]. hour) [E40]}.
Wear chemically resistant gloves (tested to All waste product is assumed to be collected and {Limit the substance in product to 10 % [OC19]}. {Provide enhanced mechanical ventilation by
EN374) in combination with specific activity returned for re-processing or use as a fuel mechanical means [E48].}
training [PPE17]. [ENVT8].
Wear chemically resistant gloves (tested to User sites are assumed to be provided with {Limit the substance in product to 15 % [OC20]}. {Use long handled tools where possible [E50]}.
EN374) in combination with intensive oil/water separators and for waste water to be
management supervision controls discharged via public sewer system [ENVT9].
[PPE18].
Wear suitable gloves (tested to EN374) Dispose of waste or used sacks/containers {Limit the substance in product to 20 % [OC21]}. {Provide extract ventilation to points where
and eye protection [PPE19]. according to local regulations [ENVT10]. emissions occur [E54]}.
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Personal protection Environmental measures Technical measures (prevention) Technical measures (dispersion)
Wear suitable respiratory protection Dispose of waste product or used containers {Limit the substance in product to 50% [OC22]}. {Use ventilation to extract vapours from freshly
(conforming to EN140 with Type A filter or according to local regulations [ENVT12]. coated articles/objects [E56]}.
better) and gloves (type EN374) if regular
skin contact likely. [PPE21]
Wear a respirator conforming to EN140 Clean IBCs or drums at approved facility {Clear transfer lines prior to de-coupling [E39]}. {Carry out in a vented booth or extracted
with Type A filter or better. [PPE22] [ENVT14]. enclosure [E57]}.
Wear suitable gloves (type EN374), User site assumed to be separate chemical and {Use in semi-automated and predominantly {Use long handled brushes and rollers where
coverall and eye protection. [PPE23] foul/rain water and be equipped with a WWTP enclosed filling lines [E41]}. possible. [E58]}.
[ENVT15].
Wear a full face respirator conforming to Do not wash equipment or storage containers {Avoid dip sampling [E42]}. {Carry out in a vented booth provided with
EN140 with Type A filter or better. [PPE24] [ENVT16]. laminar airflow [E59]}.
Change filter cartridge on respirator daily Remotely vent displaced vapours [ENVT17]. {Use bulk or semi-bulk handling systems [E43]}. {Minimise exposure by partial enclosure of the
[PPE25] operation or equipment and provide extract
ventilation at openings (professional use) [E60]}.
Use suitable eye protection [PPE26]. Additive package assumed to be blended direct {Discharge sacks via suitable vented charge {Minimise exposure by extracted full enclosure
to lubricant with no process steps [ENVT20]. chute [E44]}. for the operation or equipment [E61]}.
Wear suitable coveralls to prevent All contaminated waste water must be processed {Transfer materials directly to mixing vessels {Ensure material transfers are under
exposure to the skin [PPE27]. in an industrial or municipal wastewater treatment [E45]}. containment or extract ventilation [E66]}.
plant that incorporates both primary and
secondary treatments [W1].
Wear rubber boots [PPE28] Site should have a spill plan to ensure that {Formulate in enclosed or ventilated mixing {Provide extract ventilation to emission points
adequate safeguards are in place to minimize the vessels [E46]}. when contact with warm (>50oC) lubricant is
impact of episodic releases [W2]. likely [E67]}.
Wear a respirator conforming to EN140 A leak prevention plan is needed to prevent low {Handle substance within a closed system {Ensure operation is undertaken outdoors [E69]}.
with Type A/P2 filter or better {PPE29] level continual releases [W3]. [E47]}.
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Personal protection Environmental measures Technical measures (prevention) Technical measures (dispersion)
If above technical/organisational control A storm water management plan is needed to {Handle substance within a predominantly closed {Apply within a vented cab supplied with filtered
measures are not feasible, then adopt ensure that the wastewater treatment plant is not system provided with extract ventilation [E49]}. air under positive pressure and with a protection
following PPE: [PPE30]. overloaded with uncontaminated water [W4]. factor of >20 [E70]}.
Wear positive pressure air supplied Minimize water use and curtail all unnecessary {Fill containers/cans at dedicated fill points {Provide the operation with a properly sited
respirator if required by safe entry waste water generation [W5]. supplied with local extract ventilation [E51]}. receiving hood [E71]}.
procedures [PPE31].
Wear a full face respirator conforming to Ensure all waste water is collected and treated {Transfer via enclosed lines [E52]}. {Ensure material transfers are under
EN140 with Type A/P2 filter or better via a WWTP [W6]. containment or extract ventilation [E76]}.
[PPE32].
Contain and treat vapors from stripping {Use drum pumps [E53]}. {Drain or remove substance from equipment
operations [W7]. prior to break-in or maintenance [E81]}.
Do not wash equipment or storage containers {Drain down and flush system prior to equipment {Provide extract ventilation to material transfer
[W8]. break-in or maintenance [E55]}. points and other openings [E82]}.
Maximize waste water reuse [W9]. {Use drum pumps or carefully pour from {Handle in a fume cupboard or under extract
container [E64]}. ventilation [E83]}.
Adequate closed storage facilities (e.g., bulk {Drain down system prior to equipment break-in {Store substance within a closed system [E84]}.
storage tanks, intermediate bulk containers, or maintenance [E65]}.
drums) for VOC-containing raw materials [A1].
Use of closed transfers of liquids from storage to {Restrict area of openings to equipment [E68]}. {Use dedicated equipment [E85]}.
production equipment (e.g. metered piped or
pumped additions) [A2].
Use of closed production equipment, with no {Use dry break couplings for material transfer {Use high-performance fume cupboard [E86]}.
extraction, except when opening vessels for [E75]}.
additions/sampling [A3].
Use of closed filling equipment [A4].
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Personal protection Environmental measures Technical measures (prevention) Technical measures (dispersion)
Store finished products in closed containers (e.g.,
bulk tanks,, drums, cans) [A5].
Store all VOC-containing wastes in closed,
secure containers (e.g., bulk tanks, intermediate
bulk containers, drums) [A6].
Use vapour recovery units when necessary [A7].
Incinerate, absorb, or adsorb vapours stripped
from solution whenever necessary [A8].
All waste product is assumed to be collected and
returned for re-processing or use as a fuel [A9].
Formulation activity is assumed to be a
predominantly enclosed process [A10].
Dispose of waste or used sacks/containers
according to local regulations [S2].
Good housekeeping- e.g. inspection procedures
will ensure that there are no leaks to soil [S3].
Prevent leaks and prevent soil / water pollution
caused by leaks [S4].
Bund storage facilities to prevent soil and water
pollution in the event of spillage [S5].
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Personal protection Environmental measures Technical measures (prevention) Technical measures (dispersion)
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Personal protection Environmental measures Technical measures (prevention) Technical measures (dispersion)
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Personal protection Environmental measures Technical measures (prevention) Technical measures (dispersion)
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Personal protection Environmental measures Technical measures (prevention) Technical measures (dispersion)
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Organisational measures Duration Personal protection Environmental measures
{If technical measures not practical: {Avoid carrying out operation {Use suitable eye protection and gloves {Retain drain downs in sealed storage pending
[G16]}. for more than 15 minutes [PPE14]}. disposal or for subsequent recycle [ENVT4]}.
[OC10]}.
{Put lids on containers immediately after {Avoid carrying out operation {Wear suitable gloves tested to EN374 {Return IBCs to supplier [ENVT6]}.
use [E9]}. for more than 1 hour [PPE15]}.
[OC11]}.
{Label feed lines [E23]}. {Avoid carrying out operation {Wear chemically resistant gloves (tested {Return IBCs or tanks to supplier for re-use
for more than 4 hours to EN374) in combination with ‘basic’ [ENVT7]}.
[OC12]}. employee training [PPE16]}.
{Carefully pour from containers [E62]}. {Avoid carrying out operation {Wear chemically resistant gloves (tested {All waste product is assumed to be collected and
for more than 0.5 hour to EN374) in combination with specific returned for re-processing or use as a fuel
[OC23]}. activity training [PPE17]}. [ENVT8]}.
{Segregate the activity away from other {Avoid carrying out operation {Wear chemically resistant gloves (tested {User sites are assumed to be provided with
operations [E63]}. for more than 2 hours to EN374) in combination with intensive oil/water separators and for waste water to be
[OC24]}. management supervision controls discharged via public sewer system [ENVT9]}.
[PPE18]}.
{Ensure doors and windows are opened {Wear suitable gloves (tested to EN374) {Dispose of waste or used sacks/containers
[E72]}. and eye protection [PPE19]}. according to local regulations [ENVT10]}.
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Organisational measures Duration Personal protection Environmental measures
{Ensure the ventilation system is {Wear suitable respiratory protection {Dispose of waste solvent or used containers
regularly maintained and tested [E74]}. (conforming to EN140 with Type A filter or according to local regulations [ENVT12]}.
better) and gloves (type EN374) if regular
skin contact likely [PPE21]}.
{Clean equipment and the work area {Wear a respirator conforming to EN140 {Clean IBCs or drums at approved facility
every day [C&H3]}. with Type A filter or better [PPE22]}. [ENVT14]}.
{Dispose of empty containers and {Wear suitable gloves (type EN374), {User site assumed to be separate chemical and
wastes safely [C&H8]}. coverall and eye protection. [PPE23]}. foul/rain water and be equipped with a WWTP
[ENVT15]}.
{Dispose of waste in accordance with {Wear a full face respirator conforming to {Do not wash equipment or storage containers
environmental legislation [C&H11]}. EN140 with Type A filter or better [ENVT16]}.
[PPE24]}.
{Clear spills immediately [C&H13]}. {Change filter cartridge on respirator daily {Remotely vent displaced vapours [ENVT17]}.
[PPE25]}.
{Contain and dispose of waste according {Use suitable eye protection [PPE26]}. {Additive package assumed to be blended direct
to local regulations [C&H14]}. to lubricant with no process steps [ENVT20]}.
{Avoid splashing [C&H15]}. {Wear suitable coveralls to prevent {All contaminated waste water must be
exposure to the skin [PPE27]}. processed in an industrial or municipal
wastewater treatment plant that incorporates both
primary and secondary treatments [W1]}.
{Avoid spillage when withdrawing pump {Wear rubber boots [PPE28]}. {Site should have a spill plan to ensure that
[C&H16]}. adequate safeguards are in place to minimize the
impact of episodic releases [W2]}.
{Handle all packages and containers {Wear a respirator conforming to EN140 {A leak prevention plan is needed to prevent low
carefully to minimise spills [EI1]}. with Type A/P2 filter or better {PPE29]}. level continual releases [W3]}.
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Organisational measures Duration Personal protection Environmental measures
{Clear up spills immediately and dispose {If above technical/organisational control {A storm water management plan is needed to
of waste safely [EI9]}. measures are not feasible, then adopt ensure that the wastewater treatment plant is not
following PPE: [PPE30]}. overloaded with uncontaminated water [W4]}.
{Avoid manual contact with wet work {Wear positive pressure air supplied {minimize water use and curtail all unnecessary
pieces [EI17]}. respirator if required by safe entry waste water generation [W5]}.
procedures [PPE31]}.
{No specific measures identified [EI18]}. {Ensure all waste water is collected and treated
via a WWTP [W6]}.
{Ensure operatives are trained to {Contain and treat vapors from stripping
minimise exposures [EI119]}. operations [W7]}.
{No other specific measures identified {Do not wash equipment or storage containers
[EI20]}. [W8]}.
{Allow time for product to drain from {Maximize waste water reuse [W9]}.
workpiece [EI21]}.
{Stay upwind/keep distance from source {Adequate closed storage facilities (e.g., bulk
[EI22]}. storage tanks, intermediate bulk containers,
drums) for VOC-containing raw materials; [A1]}.
{Apply vessel entry procedures including {Use of closed transfers of liquids from storage to
use of forced supplied air [AP15]}. production equipment (e.g. metered piped or
pumped additions); [A2]}.
{Automate activity where possible {Use of closed production equipment, with no
[AP16]}. extraction, except when opening vessels for
additions/sampling; [A3]}.
{Use of closed filling equipment; [A4]}.
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Organisational measures Duration Personal protection Environmental measures
{Store finished products in closed containers
(e.g., bulk tanks,, drums, cans); [A5]}.
{Store all VOC-containing wastes in closed,
secure containers (e.g., bulk tanks, intermediate
bulk containers, drums) [A6]}.
{Use vapour recovery units when necessary
[A7]}.
{Incinerate, absorb, or adsorb vapours stripped
from solution whenever necessary [A8]}.
{All waste product is assumed to be collected and
returned for re-processing or use as a fuel [A9]}.
{Formulation activity is assumed to be a
predominantly enclosed process [A10]}.
{Dispose of waste or used sacks/containers
according to local regulations [S2]}.
{Good housekeeping- e.g. inspection procedures
will ensure that there are no leaks to soil [S3]}.
{Prevent leaks and prevent soil / water pollution
caused by leaks [S4]}.
{Bund storage facilities to prevent soil and water
pollution in the event of spillage [S5]}.
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Organisational measures Duration Personal protection Environmental measures
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Organisational measures Duration Personal protection Environmental measures
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Organisational measures Duration Personal protection Environmental measures
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Organisational measures Duration Personal protection Environmental measures
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Worksheet 3. Worker - Example ES Annex
Based on ECHA Template CSA&IR Part D draft Version 2, combined with the GES Narrative
Format
Section 1 Exposure Scenario Title
Title Manufacture of Substance A; CAS: 123-45-678
Use Descriptor Sector of Use: Industrial (SU3, SU8, SU9)
Process Categories: PROC1, PROC2, PROC3, PROC4, PROC8a, PROC8b, PROC15
Environmental Release Categories: ERC1
Processes, tasks, activities covered Manufacture of Substance A or use as an intermediate or process chemical or extraction agent.
Includes recycling/ recovery, material transfers, storage, sampling, associated laboratory activities,
maintenance and loading (including marine vessel/barge, road/rail car and bulk container).
Section 2 Operational conditions and risk management measures
Field for additional statements to explain scenario if required.
Section 2.1 Control of worker exposure
Product characteristics
Physical form of product Liquid, vapour pressure 0.5 - 10 kPa [OC4].
Concentration of substance in product Covers percentage substance in the product up to 100 % (unless stated differently) [G13].
Amounts used Not applicable
Frequency and duration of use Covers daily exposures up to 8 hours (unless stated differently) [G2]
Human factors not influenced by risk Not applicable
management
Other Operational Conditions affecting Assumes use at not > 20oC above ambient [G15];
worker exposure Assumes a good basic standard of occupational hygiene is implemented [G1].
Contributing Scenarios Risk Management Measures
Note: list RMM standard phrases according to the control hierarchy indicated in the ECHA template: 1.
Technical measures to prevent release, 2. Technical measures to prevent dispersion, 3. Organisational
measures , 4. Personal protection. Phrases between brackets are good practice advice only, beyond
REACH Chemical Safety Assessment and may be communicated in Section 5 of the ES or within the
main sections of the SDS.
General exposures [CS1]. Continuous Handle substance within a closed system [E47].{Drain down and flush system prior to equipment break-
process [CS54]. in or maintenance [E55]}.{Clear spills immediately [C&H13]}. {Retain drain downs in sealed storage
pending disposal or for subsequent recycle [ENVT4]}.
General exposures [CS1]. Continuous Handle substance within a closed system [E47].Ensure material transfers are under containment or
process [CS54]. With sample collection extract ventilation [E66]. {Wear suitable gloves tested to EN374 [PPE15]}.
[CS56]
General exposures [CS1]. Use in contained Handle substance within a closed system [E47].Ensure material transfers are under containment or
batch processes [CS37]. ; extract ventilation [E66].
With sample collection [CS56].
Process sampling [CS2]. Ensure material transfers are under containment or extract ventilation [E66].
Bulk transfers [CS14]. Internal [CS59]. Handle substance within a closed system [E47].Provide extract ventilation to points where emissions
occur [E54].
Equipment cleaning and maintenance Provide a good standard of general or controlled ventilation (5 to 15 air changes per hour) [E40].Wear
[CS39]. chemically resistant gloves (tested to EN374) in combination with ‘basic’ employee training [PPE16].
Bulk transfers [CS14]. Transport [CS58]. Ensure material transfers are under containment or extract ventilation [E76].
Laboratory activities [CS36]. Handle in a fume cupboard or under extract ventilation [E83].
Section 2.2 Control of environmental exposure (Not completed)
Product characteristics Standard phrases
Amounts used Standard phrases
Frequency and duration of use Standard phrases
Other Operational Conditions of use Standard phrases
affecting environmental exposure
Technical onsite conditions and measures Standard phrases
to reduce or limit discharges, air emissions
and releases to soil
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Organisation measures to prevent/limit Standard phrases
release from site
Conditions and measures related to Standard phrases
municipal sewage treatment plant
Conditions and measures related to Standard phrases
external treatment of waste for disposal
Conditions and measures related to Standard phrases
external recovery of waste
Other environmental control measures Standard phrases
additional to above
Section 3 TBD Exposure Estimation
3.1. Health Standard phrases. Ability to Include a web link.
3.2. Environment Standard phrases. Ability to Include a web link.
Section 4 TBD Guidance to check compliance with the Exposure Scenario
4.1. Health Standard phrases
4.2. Environment Standard phrases
Section 5 Additional good practice advice beyond the REACH Chemical Safety Assessment -
(Section Optional)
Note: The measures reported in this section have not been taken into account in the exposure estimates related to the exposure scenario above. They are not subject to
obligation laid down in Article 37 (4) of REACH.
Control of Worker Exposure
Selection of relevant Contributing Scenario Good practice RMM phrases may be incorporated in this section or consolidated into the main sections
phrases of the SDS, depending on the preference of the Registrant and functionality of the available e-SDS
system.
Control of environmental exposure
Selection of relevant RMM Core Phrases Good practice RMM phrases may be incorporated in this section or consolidated into the main sections
of the SDS, depending on the preference of the Registrant and functionality of the available e-SDS
system.
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REF 1: GES Titles (example list from Solvents Sector - ESIG/ESVOC)
Note: Details are under review with Downstream Users and subject to change. The allocation of Use
Descriptors is not an exact process and requires discussion amongst producers and users to come to
a common understanding.
An adjustment to the allocation of applicable Use Descriptors and scope statements is expected for
Substances of Very High Concern (SVHCs)
Applicable Use Appropriate GES to
Area of Draft GES scope / definition Applicable Use Descriptors Substance ES
GES Title Descriptors (ERC or develop substance
Application / UD (Processes, tasks, activities covered) (PROC or PC) number
SpERC) ESs
Manufacture of substance Industrial (SU3, Manufacture of the substance or use as an PROC1, PROC2, PROC3, ERC1, ERC4, ERC6A Yes ES#1
SU8, SU9) intermediate or process chemical or extraction PROC4, PROC8a, PROC8b,
agent. Includes recycling/ recovery, material PROC15
transfers, storage, maintenance and loading
(including marine vessel/barge, road/rail car
and bulk container), sampling and associated
laboratory activities
Professional not applicable
(SU22)
Consumer (SU21) not applicable
Distribution of substance Industrial (SU3, Loading (including marine vessel/barge, PROC1, PROC2, PROC3, ERC1 (loading) ERC2
SU8, SU9) rail/road car and IBC loading) and repacking PROC4, PROC8a, PROC8b, (repacking)
(including drums and small packs) of PROC9, PROC15
substance, including its distribution and
associated laboratory activities
Professional not applicable
(SU22)
Consumer (SU21) not applicable
Formulation & (re)packing of Industrial (SU3, Formulation, packing and re-packing of the PROC1, PROC2, PROC3, ERC2 Yes ES#2
substances and mixtures SU10) substance and its mixtures in batch or PROC4, PROC5, PROC8a,
continuous operations, including storage, PROC8b, PROC9, PROC14,
materials transfers, mixing, tabletting, PROC15
compression, pelletisation, extrusion, large and
small scale packing, sampling, maintenance
and associated laboratory activities
Professional not applicable
(SU22)
Ref 1 Example GES Titles Page 40
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Applicable Use Appropriate GES to
Area of Draft GES scope / definition Applicable Use Descriptors Substance ES
GES Title Descriptors (ERC or develop substance
Application / UD (Processes, tasks, activities covered) (PROC or PC) number
SpERC) ESs
Consumer (SU21) not applicable
Uses in Coatings Industrial (SU3) Covers the use in coatings (paints, inks, PROC1, PROC2, PROC3, ERC 4 Yes ES#3
adhesives, etc) including exposures during PROC4, PROC5, PROC7,
use (including materials receipt, storage, PROC8a, PROC8b, PROC10,
preparation and transfer from bulk and semi- PROC13, PROC15
bulk, application by spray, roller, spreader, dip,
flow, fluidised bed on production lines and film
formation) and equipment cleaning,
maintenance and associated laboratory
activities.
Professional Covers the use in coatings (paints, inks, PROC1, PROC2, PROC3, ERC 8A, ERC 8D Yes ES#4
(SU22) adhesives, etc) including exposures during PROC4, PROC5, PROC8a,
use (including materials receipt, storage, PROC8b, PROC10, PROC11,
preparation and transfer from bulk and semi- PROC13, PROC15, PROC19
bulk, application by spray, roller, brush,
spreader by hand or similar methods, and film
formation), and equipment cleaning,
maintenance and associated laboratory
activities.
Consumer (SU21) Covers the use in coatings (paints, inks, PC1, PC4, PC5, PC9, PC10, ERC 8A, ERC 8D Yes ES#5
adhesives, etc) including exposures during PC15, PC18, PC23, PC24,
use (including product transfer and preparation, PC31
application by brush, spray by hand or similar
methods) and equipment cleaning.
Use in Cleaning Agents Industrial (SU3) Covers the use as a component of cleaning PROC1, PROC2, PROC3, ERC4
products including transfer from storage, PROC4, PROC7, PROC8a,
pouring/unloading from drums or containers. PROC8b, PROC10, PROC13
Exposures during mixing/diluting in the
preparatory phase and cleaning activities
(including spraying, brushing, dipping, wiping,
automated and by hand), related equipment
cleaning and maintenance.
Professional Covers the use as a component of cleaning PROC1, PROC2, PROC3, ERC 8A, ERC 8D;
(SU22) products including pouring/unloading from PROC4, PROC8a, PROC8b,
drums or containers; and exposures during PROC10, PROC11, PROC13
mixing/diluting in the preparatory phase and
cleaning activities (including spraying,
brushing, dipping, wiping automated and by
hand).
Ref 1 Example GES Titles Page 41
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Applicable Use Appropriate GES to
Area of Draft GES scope / definition Applicable Use Descriptors Substance ES
GES Title Descriptors (ERC or develop substance
Application / UD (Processes, tasks, activities covered) (PROC or PC) number
SpERC) ESs
Consumer (SU21) Covers general exposures to consumers PC3, PC4, PC9, PC24, PC32, ERC 8A, ERC 8D Yes ES#6
arising from the use of household products sold PC35, PC38
as washing and cleaning products, aerosols,
coatings, de-icers, lubricants and air care
products.
Use in Oil field drilling and production Industrial (SU3) Oil field well drilling and production operations PROC1, PROC2, PROC3, ERC 4
operations (including drilling muds and well cleaning) PROC4, PROC8a, PROC8b
including material transfers, on-site formulation,
well head operations, shaker room activities
and related maintenance.
Professional Oil field well drilling operations (including PROC1, PROC2, PROC3, ERC 8D
(SU22) drilling muds and well cleaning) including PROC4, PROC8a, PROC8b
material transfers, on-site formulation, well
head operations, shaker room activities and
related maintenance.
Consumer (SU21) not applicable
Lubricants Industrial (SU3) Covers the use of formulated lubricants in PROC1, PROC2, PROC3, ERC 7, ERC 4
closed and open systems including transfer PROC4, PROC7, PROC8a,
operations, operation of machinery/engines PROC8b, PROC9, PROC10,
and similar articles, reworking on reject articles, PROC13, PROC17, PROC18
equipment maintenance and disposal of
wastes.
Professional Covers the use of formulated lubricants in PROC1, PROC2, PROC3, ERC 8A, ERC 8D
(SU22) closed and open systems including transfer PROC4, PROC8a, PROC8b, ERC 9A, ERC 9B
operations, operation of engines and similar PROC9, PROC10, PROC11,
articles, reworking on reject articles, equipment PROC13, PROC17, PROC18,
maintenance and disposal of waste oil.
PROC20
Consumer (SU21) Covers the consumer use of formulated PC1, PC6, PC24, PC31 ERC 8A, ERC 8D
lubricants in closed and open systems ERC 9A, ERC 9B
including transfer operations, application,
operation of engines and similar articles,
equipment maintenance and disposal of waste
oil.
Ref 1 Example GES Titles Page 42
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Applicable Use Appropriate GES to
Area of Draft GES scope / definition Applicable Use Descriptors Substance ES
GES Title Descriptors (ERC or develop substance
Application / UD (Processes, tasks, activities covered) (PROC or PC) number
SpERC) ESs
Metal working fluids / rolling oils Industrial (SU3) Covers the use in formulated MWFs/rolling oils PROC1, PROC2, PROC3, ERC 4
including transfer operations, rolling and PROC5, PROC7, PROC8a,
annealing activities, cutting/machining PROC8b, PROC9, PROC10,
activities, automated and manual application of PROC13, PROC17
corrosion protections (including brushing,
dipping and spraying), equipment
maintenance, draining and disposal of waste
oils.
Professional Covers the use in formulated MWFs including PROC1, PROC2, PROC3, ERC 8A
(SU22) transfer operations, open and contained PROC5, PROC8a, PROC8b,
cutting/machining activities, automated and PROC10, PROC11, PROC13,
manual application of corrosion protections, PROC17
draining and working on contaminated/ reject
articles, and disposal of waste oils.
Consumer (SU21) not applicable
Blowing agents Industrial (SU3) Use as a blowing agent for rigid and flexible PROC1, PROC2, PROC3, ERC 4
foams, including material transfers, mixing and PROC8b, PROC9, PROC12
injection, curing, cutting, storage and packing
Professional not applicable
(SU22)
Consumer (SU21) not applicable
Use as binders and release agents Industrial (SU3) Covers the use as binders and release agents PROC1, PROC2, PROC3, ERC4
including material transfers, mixing, application PROC4, PROC6, PROC7,
(including spraying and brushing), mould PROC8b, PROC10, PROC13,
forming and casting, and handling of waste. PROC14
Professional Covers the use as binders and release agents PROC1, PROC2, PROC3, ERC8A, ERC 8D
(SU22) including material transfers, mixing, application PROC4, PROC6, PROC 8a,
by spraying, brushing, and handling of waste. PROC8b, PROC10, PROC11,
PROC14
Consumer (SU21) not applicable
Agrochemical uses Industrial (SU3) not applicable
Professional Use as an agrochemical excipient for PROC1, PROC2, PROC8a, ERC8A, ERC 8D
(SU22) application by manual or machine spraying, PROC8b, PROC11, PROC13
smokes and fogging; including storage,
equipment clean-downs and disposal.
Ref 1 Example GES Titles Page 43
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Applicable Use Appropriate GES to
Area of Draft GES scope / definition Applicable Use Descriptors Substance ES
GES Title Descriptors (ERC or develop substance
Application / UD (Processes, tasks, activities covered) (PROC or PC) number
SpERC) ESs
Consumer (SU21) Covers the consumer use in agrochemicals in PC12, PC22, PC27 ERC8A, ERC 8D
liquid and solid forms.
Use as a fuel Industrial (SU3) Covers the use as a fuel (or fuel additive) and PROC1, PROC2, PROC3, ERC7
includes activities associated with its transfer, PROC8a, PROC8b, PROC16
use, equipment maintenance and handling of
waste.
Professional Covers the use as a fuel (or fuel additive) and PROC1, PROC2, PROC3, ERC 9A, ERC 9B
(SU22) includes activities associated with its transfer, PROC8a, PROC8b, PROC16
use, equipment maintenance and handling of
waste.
Consumer (SU21) Covers consumer uses in liquid fuels PC13 ERC 9A, ERC 9B
Functional Fluids Industrial (SU3) Use as functional fluids e.g. cable oils, transfer PROC1, PROC2, PROC3, ERC 7
oils, coolants, insulators, refrigerants, hydraulic PROC4, PROC 8a, PROC 8b,
fluids in industrial equipment including PROC9
maintenance and related material transfers
Professional Use as functional fluids e.g. cable oils, transfer PROC1, PROC2, PROC3, ERC 9A, ERC 9B
(SU22) oils, coolants, insulators, refrigerants, hydraulic PROC 8a, PROC9, PROC20
fluids in professional equipment including
maintenance and related material transfers.
Consumer (SU21) Use of sealed items containing functional fluids PC16, PC17 ERC 9A, ERC 9B
e.g. transfer oils, hydraulic fluids, refrigerants
De-icing and anti-icing applications Industrial (SU3) not applicable
Professional Ice prevention and de-icing of vehicles, aircraft PROC1, PROC2, PROC8a, ERC 8D
(SU22) and other equipment by spraying PROC8b, PROC11
Consumer (SU21) De-icing of vehicles and similar equipment by PC4 ERC 8D
spraying
Road and construction applications Industrial (SU3) not applicable .. Refers to bitumen blending.
Covered under 'Formulation'
Professional Application of surface coatings and binders in PROC8a, PROC8b, PROC9, ERC8D
(SU22) road and construction activities, including PROC10, PROC11, PROC13
paving uses, manual mastic and in the
application of roofing and water-proofing
membranes
Consumer (SU21) not applicable
Ref 1 Example GES Titles Page 44
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Applicable Use Appropriate GES to
Area of Draft GES scope / definition Applicable Use Descriptors Substance ES
GES Title Descriptors (ERC or develop substance
Application / UD (Processes, tasks, activities covered) (PROC or PC) number
SpERC) ESs
Other Consumer Uses Consumer (SU21) Consumer uses not covered in consumer PC28, PC39 ERC 8A, ERC 8D
examples listed above e.g. use as a carrier in
cosmetics/personal care products, perfumes
and fragrances.
Use in laboratories Industrial (SU3) Use of the substance within laboratory settings, PROC10, PROC15 ERC 2
including material transfers and equipment
cleaning
Professional Use of small quantities within laboratory PROC10, PROC15 ERC 8A
(SU22) settings, including material transfers and
equipment cleaning
Consumer (SU21) not applicable
Explosives manufacture & use Industrial (SU3) not applicable
Professional Covers exposures arising from the PROC1, PROC3, PROC5, ERC 8D
(SU22) manufacture and use of slurry explosives PROC8a, PROC8b
(including materials transfer, mixing and
charging) and
Consumer (SU21) not applicable equipment cleaning
Rubber production and processing Industrial (SU10) Manufacture of tyres and general rubber PROC1, PROC2, PROC3, ERC 1, ERC4
articles, including processing of raw (uncured) PROC4, PROC5, PROC6,
rubber, handling and mixing of rubber PROC7, PROC8a, PROC8b,
additives, vulcanising, cooling and finishing. PROC9, PROC13, PROC14,
PROC15, PROC21
Professional not applicable
(SU22)
Consumer (SU21) not applicable
Polymer processing Industrial (SU10) Processing of formulated polymers including PROC1, PROC2, PROC3, ERC 4
material transfers, additives handling (e.g. PROC4, PROC5, PROC6,
pigments, stabilisers, fillers, plasticisers, etc.), PROC8a, PROC8b, PROC9,
moulding, curing and forming activities, PROC13, PROC14, PROC21
material re-works, storage and associated
maintenance.
Professional Processing of formulated polymers including PROC1, PROC2, PROC6, ERC 8A,
(SU22) material transfers, moulding and forming PROC8a, PROC8b, PROC14,
activities, material re-works and associated PROC21
maintenance.
Water treatment chemicals Industrial (SU10) Covers the use of the substance for the PROC1, PROC2, PROC3, ERC3
treatment of water at industrial facilities in open PROC4, PROC8a, PROC8b,
and closed systems PROC13
Ref 1 Example GES Titles Page 45
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Applicable Use Appropriate GES to
Area of Draft GES scope / definition Applicable Use Descriptors Substance ES
GES Title Descriptors (ERC or develop substance
Application / UD (Processes, tasks, activities covered) (PROC or PC) number
SpERC) ESs
Professional Covers the use of the substance for the PROC1, PROC2, PROC3, ERC 8F
(SU22) treatment of water in open and closed systems PROC4, PROC8a, PROC8b,
PROC13
Consumer (SU21) Covers the use of the substance for the PC36, PC37 ERC 8F
treatment of water in open and closed systems
Mining chemicals Industrial (SU10) Covers the use of the substance in extraction PROC1, PROC2, PROC3, ERC 4
processes at mining operations, including PROC4, PROC5, PROC8a,
material transfers, winning and separation PROC8b, PROC9
activities, and substance recovery and
disposal.
Professional not applicable
(SU22)
Consumer (SU21) not applicable
Ref 1 Example GES Titles Page 46
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REF 2: Example Standard Phrases for use in Exposure Scenario Development:
Extract from library (Solvents Industry - ESIG/ESVOC)
Note: Details are under development and subject to change
ESIG_ESVOC Phrases
Code
GT11 Contributing Scenario
CS1 General exposures
CS2 Process sampling
CS3 Material transfers
CS4 Dipping, immersion and pouring
CS5 Equipment maintenance
CS6 Drum and small package filling
CS7 Small package filling
CS8 Drum/batch transfers
CS9 Pouring from small containers
CS10 Spraying
CS11 Printing
CS12 Drying and storage
CS14 Bulk transfers
CS15 General exposures (closed systems)
CS16 General exposures (open systems)
CS17 Operation and lubrication of high energy open equipment
CS18 Maintenance of small items
CS19 Remanufacture of reject articles
CS20 Engine lubricant service
CS21 Operation of total loss equipment and systems
CS22 Transfer from/pouring from containers
CS24 Spraying/fogging by manual application
CS25 Spraying/fogging by machine application
CS27 Ad hoc manual application via trigger sprays, dipping, etc.
CS28 Disposal of wastes
CS29 Mixing operations (closed systems)
CS30 Mixing operations (open systems)
CS31 Mold forming
CS32 Casting operations
CS33 Machine
CS34 Manual
CS35 Treatment by dipping and pouring
CS36 Laboratory activities
CS37 Use in contained batch processes
CS38 Use in contained systems
CS39 Equipment cleaning and maintenance
CS40 Vapour degreasing bath
CS41 Degreasing small objects in cleaning station
CS42 Cleaning with low-pressure washers
CS43 On site
CS44 Cleaning with high pressure washers
CS45 Filling / preparation of equipment from drums or containers.
CS46 Large surfaces
CS47 Cleaning
CS48 Surfaces
CS49 Spray Bottle
CS50 Wiping
CS51 Rolling, Brushing
CS52 Manual spot cleaning (e.g. textiles etc)
CS53 Pelletizing
CS54 Continuous process
CS55 Batch process
CS56 with sample collection
CS57 no sampling
CS58 transport
CS59 internal
CS60 no spraying
CS61 small scale
CS62 heating oil and diesel deliveries
CS63 vessel / container
CS64 Calendering (including Banburys)
CS65 Polymerisation (bulk and batch)
CS66 Intermediate polymer storage
CS68 Pelletisation and pellet screening
CS69 Additivation and stabilisation
Ref 2 Ex Standard phrases Page 47
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REF 2: Example Standard Phrases for use in Exposure Scenario Development:
Extract from library (Solvents Industry - ESIG/ESVOC)
Note: Details are under development and subject to change
ESIG_ESVOC Phrases
Code
CS70 Vulcanisation
CS71 Cooling cured articles
CS72 Hand application - fingerpaints, pastels, adhesives
CS73 Pressing uncured rubber blanks
CS74 Cleaning of medical devices
CS75 Initial factory fill of equipment
Semi Automated process. (e.g.: Semi automatic application of floor care and
CS76 maintenance products)
CS77 Maintenance (of larger plant items) and machine set up
CS78 Engine lubricant service
CS79 Metal machining operations
CS80 Automated metal rolling/forming
CS81 Dedicated facility
CS82 Non-dedicated facility
CS83 Semi-automated metal rolling/forming
CS84 Filling of articles/equipment
CS85 Bulk product storage
CS86 Rework of articles
CS87 Polyol processes
CS88 Extrusion and masterbatching
CS89 Injection moulding of articles
CS90 Small scale weighing
CS91 Bulk weighing
CS92 Additive premixing
CS93 Automated process with (semi) closed systems.
CS94 Film formation - force drying (50 - 100°C). Stoving (>100°C). UV/EB radiation
CS95 curing
Film formation - air drying
CS96 Preparation of material for application
CS97 Spraying (automatic/robotic)
CS98 Roller, spreader, flow application
Production or preparation or articles by tabletting, compression, extrusion or
CS100 pelletisation
CS101 Application of cleaning products in closed systems
CS102 Finishing operations
CS103 Vessel and container cleaning
CS104 Maintenance and machine set up
CS105 ion exchange processes
CS106 phase separation
CS107 (closed systems)
CS108 (open systems)
CS112 Tyre build up
CS113 Production of articles by dipping and pouring
CS114 Bulk transfers from tote tanks and supply vessels
CS115 Drilling mud (re-)formulation
CS116 Drill floor operations
CS117 Operation of solids filtering equipment
CS118 Operation of solids filtering equipment - vapour exposures
CS119 Operation of solids filtering equipment - aerosol exposures
CS120 Cleaning of solids filtering equipment
CS121 Treatment and disposal of filtered solids
CS122 Extrusion and expansion of polymer mass
CS123 Collection and re-processing of shavings, cuttings, etc
CS124 Product packaging
CS125 Production of foam-based objects
CS126 Installation of insulation panels
CS127 Centrifuging including discharging
CS128 Semi-bulk packaging
CS129 Treatment by heating
CS130 Article formation in mould
CS131 Cutting by heated wire
CS132 Foaming
CS133 Compression
CS134 Cutting and shaving
CS135 General risk management measures applicable to all activities
CS136 Batch processes at elevated temperatures
GT19 Operational conditions and risk management measures
Ref 2 Ex Standard phrases Page 48
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REF 2: Example Standard Phrases for use in Exposure Scenario Development:
Extract from library (Solvents Industry - ESIG/ESVOC)
Note: Details are under development and subject to change
ESIG_ESVOC Phrases
Code
G1 Assumes a good basic standard of occupational hygiene is implemented
G2 Covers daily exposures up to 8 hours (unless stated differently)
G3 Covers frequency up to: weekly use
G4 Covers frequency up to: monthly use
G5 Covers frequency up to: daily yearly use
G6 Covers frequency up to: daily use, weekly, monthly, yearly.
G7 Covers percentage substance in the product up to 1 %
G9 , or:
G10 , alternatively:
G11 Covers percentage substance in the product up to 5%
G12 Covers percentage substance in the product up to 25 %
G13 Covers percentage substance in the product up to 100 % (unless stated
differently)
G15 Assumes use at not more than 20°C above ambient temperature
G17 Assumes activities are at ambient temperature (unless stated differently)
OC1 Solid, low dustiness
OC2 Solid, medium dustiness
OC3 Liquid, vapour pressure 10 kPa
OC6 Solid, high dustiness
OC7 Operation is carried out at elevated temperature (> 20°C above ambient
temperature)
OC8 Indoor
OC9 Outdoor
OC13 Varies between milliliters (sampling) and cubic meters (material transfers)
OC14 Liquid, vapour pressure 10 Pa
OC25 Aerosol generation due to elevated process temperature
GT20 Control of worker exposure
GT21 Technical measures at process level (source) to prevent release
OC16 Limit the substance content in the product to 1 %
OC17 Limit the substance content in the product to 5 %
OC18 Limit the substance content in the product to 25 %
OC19 Limit the substance in product to 10 %
OC20 Limit the substance in product to 15 %
OC21 Limit the substance in product to 20 %
OC22 Limit the substance content in the mixture to 50 %
E39 Clear transfer lines prior to de-coupling
E41 Use in semi-automated and predominantly enclosed filling lines
E42 Avoid dip sampling.
E43 Use bulk or semi-bulk handling systems
E44 Discharge sacks via suitable vented charge chute
E45 Transfer materials directly to mixing vessels
E46 Formulate in enclosed or ventilated mixing vessels
E47 Handle substance within a closed system
E49 Handle substance within a predominantly closed system provided with extract
ventilation
E51 Fill containers/cans at dedicated fill points supplied with local extract ventilation
E52 Transfer via enclosed lines
E53 Use drum pumps
E55 Drain down and flush system prior to equipment break-in or maintenance
E64 Use drum pumps or carefully pour from container
E65 Drain down system prior to equipment break-in or maintenance
E68 Restrict area of openings to equipment
E75 Use dry break couplings for material transfer
GT22 Technical conditions and measures to control dispersion from
source towards the worker
Ref 2 Ex Standard phrases Page 49
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REF 2: Example Standard Phrases for use in Exposure Scenario Development:
Extract from library (Solvents Industry - ESIG/ESVOC)
Note: Details are under development and subject to change
ESIG_ESVOC Phrases
Code
E1 Provide a good standard of general ventilation. Natural ventilation is from doors,
windows etc. Controlled ventilation means air is supplied or removed by a
powered fan.
E5 Ensure that enough fresh air is supplied to dilute and remove dusts, fumes or
vapours. Between 5 and 15 air changes per hour are recommended, with a
E40 through draught.
Provide a good standard of general or controlled ventilation (5 to 15 air changes
per hour)
E48 Provide enhanced general ventilation by mechanical means
E50 Use long handled tools where possible
E54 Provide extract ventilation to points where emissions occur
E56 Use ventilation to extract vapours from freshly coated articles/objects
E57 Carry out in a vented booth or extracted enclosure
E58 Use long handled brushes and rollers where possible.
E59 Carry out in a vented booth provided with laminar airflow
E60 Minimise exposure by partial enclosure of the operation or equipment and provide
extract ventilation at openings
E61 Minimise exposure by extracted full enclosure for the operation or equipment
E66 Ensure material transfers are under containment or extract ventilation
E67 Provide extract ventilation to emission points when contact with warm (>50oC)
product is likely
E69 Ensure operation is undertaken outdoors
E70 Apply within a vented cab supplied with filtered air under positive pressure and
with a protection factor of >20
E71 Provide the operation with a properly sited receiving hood
E76 Ensure samples are obtained under containment or extract ventilation
E81 Drain or remove substance from equipment prior to break-in or maintenance
E82 Provide extract ventilation to material transfer points and other openings
E83 Handle in a fume cupboard or under extract ventilation
E84 Store substance within a closed system
E85 Use dedicated equipment
E86 Use high-performance fume cupboard
GT23 Organisational measures to prevent/limit releases, dispersion and exposure
G16 If technical measures not practical: [G16].
E9 Put lids on containers immediately after use.
E23 Label feed lines.
E62 Carefully pour from containers.
E63 Segregate the activity away from other operations
E72 Ensure doors and windows are opened
E74 Ensure the ventilation system is regularly maintained and tested
OC10 Avoid carrying out operation for more than 15 minutes
OC11 Avoid carrying out operation for more than 1 hour
OC12 Avoid carrying out operation for more than 4 hours
OC23 Avoid carrying out operation for more than 0.5 hour
OC24 Avoid carrying out operation for more than 2 hours
C&H3 Clean equipment and the work area every day.
C&H8 Dispose of empty containers and wastes safely.
C&H11 Dispose of waste in accordance with environmental legislation.
C&H13 Clear spills immediately.
C&H14 Contain and dispose of waste according to local regulations
C&H15 Avoid splashing
C&H16 Avoid spillage when withdrawing pump
EI1 Handle all packages and containers carefully to minimise spills.
EI9 Clear up spills immediately and dispose of waste safely.
EI17 Avoid manual contact with wet work pieces
EI18 No specific measures identified
EI19 Ensure operatives are trained to minimise exposures
EI20 No other specific measures identified
EI21 Allow time for product to drain from workpiece
EI22 Stay upwind/keep distance from source
AP15 Apply vessel entry procedures including use of forced supplied air.
AP16 Automate activity where possible
Ref 2 Ex Standard phrases Page 50
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REF 2: Example Standard Phrases for use in Exposure Scenario Development:
Extract from library (Solvents Industry - ESIG/ESVOC)
Note: Details are under development and subject to change
ESIG_ESVOC Phrases
Code
GT24 Personal Protection
PPE14 Use suitable eye protection and gloves.
PPE15 Wear suitable gloves tested to EN374.
PPE16 Wear chemically resistant gloves (tested to EN374) in combination with ‘basic’
employee training.
PPE17 Wear chemically resistant gloves (tested to EN374) in combination with specific
activity training.
PPE18 Wear chemically resistant gloves (tested to EN374) in combination with intensive
management supervision controls.
PPE19 Wear suitable gloves (tested to EN374) and eye protection.
PPE21 Wear suitable respiratory protection (conforming to EN140 with Type A filter or
better) and gloves (type EN374) if regular skin contact likely.
PPE22 Wear a respirator conforming to EN140 with Type A filter or better.
PPE23 Wear suitable gloves (tested to EN374), coverall and eye protection.
PPE24 Wear a full face respirator conforming to EN140 with Type A filter or better.
PPE25 Change filter cartridge on respirator daily
PPE26 Use suitable eye protection
PPE27 Wear suitable coveralls to prevent exposure to the skin
PPE28 Wear rubber boots
PPE29 Wear a respirator conforming to EN140 with Type A/P2 filter or better
PPE30 If above technical/organisational control measures are not feasible, then adopt
following PPE:
PPE31 Wear positive pressure air supplied respirator if required by safe entry procedures
PPE32 Wear a full face respirator conforming to EN140 with Type A/P2 filter or better.
GT25 Control of environmental exposure
ENVT4 Retain drain downs in sealed storage pending disposal or for subsequent recycle Please note that the environmental RMM phrases are
still under development and subject to change as
part of the development of Exposure Scenarios for
ENVT6 Return IBCs to supplier
the environment within the Cefic SPERC (Specific
ENVT7 Return IBCs or tanks to supplier for re-use Environmental Release Categories) project.
ENVT8 All waste product is assumed to be collected and returned for re-processing or
use as a fuel.
ENVT9 User sites are assumed to be provided with oil/water separators and for waste
water to be discharged via public sewer system
ENVT10 Dispose of waste or used sacks/containers according to local regulations.
ENVT12 Dispose of waste product or used containers according to local regulations
ENVT14 Clean IBCs or drums at approved facility
ENVT15 User site assumed to be separate chemical and foul/rain water and be equipped
with a WWTP
ENVT16 Do not wash equipment or storage containers
ENVT17 Remotely vent displaced vapours
ENVT20 Additive package assumed to be blended direct to lubricant with no process steps
W1 All contaminated waste water must be processed in an industrial or municipal
wastewater treatment plant that incorporates both primary and secondary
treatments
W2 Site should have a spill plan to ensure that adequate safeguards are in place to
minimize the impact of episodic releases
W3 A leak prevention plan is needed to prevent low level continual releases
W4 A storm water management plan is needed to ensure that the wastewater
treatment plant is not overloaded with uncontaminated water
W5 minimize water use and curtail all unnecessary waste water generation
W6 Ensure all waste water is collected and treated via a WWTP
W7 Contain and treat vapors from stripping operations
W8 Do not wash equipment or storage containers
W9 Maximize waste water reuse
A1 Adequate closed storage facilities (e.g., bulk storage tanks, intermediate bulk
containers, drums) for VOC-containing raw materials
A2 Use of closed transfers of liquids from storage to production equipment (e.g.
metered piped or pumped additions)
Ref 2 Ex Standard phrases Page 51
4b96ad0a-ac2b-4b2e-9a61-cf90372592ff.xls Page 52
REF 2: Example Standard Phrases for use in Exposure Scenario Development:
Extract from library (Solvents Industry - ESIG/ESVOC)
Note: Details are under development and subject to change
ESIG_ESVOC Phrases
Code
A3 Use of closed production equipment, with no extraction, except when opening
vessels for additions/sampling
A4 Use of closed filling equipment
A5 Store finished products in closed containers (e.g., bulk tanks,, drums, cans)
A6 Store all VOC-containing wastes in closed, secure containers (e.g., bulk tanks,
intermediate bulk containers, drums)
A7 Use vapour recovery units when necessary
A8 Incinerate, absorb, or adsorb vapours stripped from solution whenever necessary
A9 All waste product is assumed to be collected and returned for re-processing or
use as a fuel.
A10 Formulation activity is assumed to be a predominantly enclosed process
S2 Dispose of waste or used sacks/containers according to local regulations.
S3 Good housekeeping- e.g. inspection procedures will ensure that there are no
leaks to soil
S4 Prevent leaks and prevent soil / water pollution caused by leaks
S5 Bund storage facilities to prevent soil and water pollution in the event of spillage
GT26 Exposure estimation and reference to its source
G8 Estimated workplace exposures are not expected to exceed DNELs when the
identified risk management measures are adopted.
Ref 2 Ex Standard phrases Page 52
4b96ad0a-ac2b-4b2e-9a61-cf90372592ff.xls
Ref 3: Exposure Modifiers for Refinement of ECETOC TRA Estimates - WORKERS
Please note comments included in cell annotations
1. Inhalation exposure modifying factor description Examples only of RMM-standard phrases - Solvents Industry (ESIG/ESVOC)
a. Concentration 1 > 25% (not applicable)
0.6 5 - 25% Limit the substance content in the product to 25 % [OC18]
0.2 1 - 5% Limit the substance in product to 5 % [OC17]
0.1 20 [E70]
LEV-industrial PROC 12 (volatiles), 24 (solids) 80% LEV: 80% effective Provide extract ventilation to points where emissions occur [E54]
Ensure material transfers are under containment or extract ventilation [E66]
Provide extract ventilation to material transfer points and other openings [E82]
PROC 2,3,4,5,6,8a,9,10,13, 90% LEV: 90% effective Provide extract ventilation to points where emissions occur [E54]
14,15,16,19, 21 (solids), 22 Ensure material transfers are under containment or extract ventilation [E66]
(solids), 23 (solids), 25 (solids) Provide extract ventilation to material transfer points and other openings [E82]
PROC 7, 8b (solids), 17, 18 95% LEV: 95% effective Minimise exposure by enclosing the operation or equipment and provide extract ventilation at openings [E60]
Apply within a vented cab supplied with filtered air under positive pressure and with a protection factor of >20 [E70]
PROC 8b (volatiles) 97% LEV: 97% effective Provide extract ventilation to points where emissions occur [E54]
Ensure material transfers are under containment or extract ventilation [E66]
Provide extract ventilation to material transfer points and other openings [E82]
99% LEV: 99% effective Carry out in a vented booth provided with laminar airflow [E59]
justification statement required Minimise exposure by extracted full enclosure for the operation or equipment [E61]
c. Ventilation professional/industrial 30% 30% effective Ensure operation is undertaken outdoors [E69]
Provide a good standard of general ventilation. Natural ventilation is from windows and doors etc. Controlled ventilation
means air is supplied or removed by a powered fan. [E1]
professional/industrial 70% Controlled mechanical ventilation: 70% effective Provide enhanced general ventilation by mechanical means [E48]
justification statement required Provide a good standard of general or controlled ventilation (5 to 15 air changes per hour) (E40]
d. Duration of exposure (note: also check exposure during task against DNEL-short term where relevant)
1 > 4 hours (not applicable)
0.6 1-4 hours Avoid carrying out operation for more than 4 hours [OC12]
0.2 15 min - 1 hour Avoid carrying out operation for more than 1 hour [OC11]
0.1 25% (not applicable)
0.6 5 - 25% Limit the substance content in the product to 25 % [OC18]
0.2 1 - 5% Limit the substance in product to 5 % [OC17]
0.1 < 1% Limit the substance in product to 1 % [OC16]
b. LEV present PROC 1 0.1 Predicted dermal exposure value varies between
PROC 2 0.1 PROCs. Note: LEV modifier for dermal exposure may
PROC 3 0.1 differ from LEV modifiers for inhalatory exposure by
PROC 4 0.1 PROC
PROC 5 0.005
PROC 6 0.05
PROC 7 0.05
PROC 8a 0.01
PROC 8b 0.1
PROC 9 0.1
Ref 3 TRA Worker Expo modifiers Page 53