ID number name CAS number
p‐Bromo‐2‐fluoroacetanil
ID1371 ide 351-05-3
N‐(4‐Bromobenzyl)‐2‐flu
ID1372 oroacetamide 24312-44-5
ID1373 hydrogen iodide 10034-85-2
ID1374 Lasalocid 11054-70-9
ID1375 Fenaminosulf T-13
ID1376 Fenaminosulf 140-56-7
ID1377 trizinc diphosphide 1314-84-7
Thiocyanatoacetic acid
ID1378 ethyl ester 5349-28-0
ID1379 Cellulose, nitrate 9004-70-0
ID1380 1,3,5-trinitrobenzene 99-35-4
ID1381 Peroxyacetic acid 79-21-0
ID1382 lithium 7439-93-2
ID1383 Phosphorus 7723-14-0(2)
Celluloid, in blocks, rods,
ID1384 rolls, sheets, tubes, etc. 8050-88-2
ID1385 Calcium acetylide 75-20-7
ID1386 tricalcium diphosphide 1305-99-3
ID1387 Magnesium 7439-95-4
ID1388 Aluminium 7429-90-5
ID1389 Sodium dithionite 7775-14-6
ID1390 ammonium chlorate 10192-29-7
ID1391 potassium perchlorate 7778-74-7
ID1392 Sodium perchlorate 7601-89-0
ID1393 Ammonium perchlorate 7790-98-9
ID1394 dipotassium peroxide 17014-71-0
ID1395 Potassium nitrate 7757-79-1
ID1396 Sodium nitrate 7631-99-4
ID1397 Ammonium nitrate 6484-52-2
ID1398 Calcium hypochlorite 7778-54-3
ID1399 Hydrogen 1333-74-0
ID1400 Ethyne 74-86-2
ID1401 Ethene 74-85-1
ID1402 Methane 74-82-8
ID1403 Ethane 74-84-0
ID1404 Propane 74-98-6
GHS Classification
ID1371 ｐ‐Ｂｒｏｍｏ‐２‐ｆｌｕｏｒｏａｃｅｔａｎｉｌｉｄｅ
CAS 351-05-3 Date Classified： 2006/7/24 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not applicable - - - There are no chemical groups associated with explosive properties present in the molecules.
2 Flammable gases Not applicable - - - Solid (GHS definition)
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not applicable - - - Solid (GHS definition)
5 Gases under pressure Not applicable - - - Solid (GHS definition)
6 Flammable liquids Not applicable - - - Solid (GHS definition)
7 Flammable solids Classification not
- - - No data available
possible
8 Self-reactive substances and Not applicable - - - There are no chemical groups associated with explosive or self-reactive properties present in the molecule.
mixtures
9 Pyrophoric liquids Not applicable - - - Solid (GHS definition)
10 Pyrophoric solids Not classified - - - Non-pyrophoric when in contact with air at a room temperature and used as agricultural chemicals.
11 Self-heating substances and Classification not
- - - No data available
mixtures possible
12 Substances and mixtures, which
in contact with water, emit Not applicable - - - The chemical structure of the substance does not contain metals or metaloids(B, Si, P, Ge, As, Se, Sn, Sb, Te, Bi, Po, At).
flammable gases
13 Oxidizing liquids Not applicable - - - Solid (GHS definition)
14 Oxidizing solids Classification not
- - - No data available
possible
15 Organic peroxides Not applicable - - - Organic compounds containing no -0-0- structure
16 Corrosive to metals Classification not
- - - Test methods applicable to solid substances are not available.
possible
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) SPECIES: Rat
Skull and ENDPOINT: LD50
Category 2 Danger Fatal if swallowed
crossbones VALUE: 29mg/kg
REFERENCE SOURCE: RTECS(2006)
1 Acute toxicity (dermal) Skull and Fatal in contact with
Category 1 Danger It was set as Category 1base on rat LD50 = 7mg/kg (RTECS (1996)).
crossbones skin
1 Acute toxicity (inhalation: gas) Not applicable - - - Solid (GHS definition)
1 Acute toxicity (inhalation: vapour) Classification not - - - No data available
possible
1 Acute toxicity (inhalation: dust, Classification not
- - - There is data on the mouse. But exposure time is unknown, and since data is insufficient, it cannot classify.
mist) possible
2 Skin corrosion / irritation Classification not
- - - No data available
possible
3 Serious eye damage / eye Classification not
irritation - - - No data available
possible
4 Respiratory/skin sensitizer Respiratory
sensitization: (Respiratory
(Respiratory (Respiratory
Classification not sensitization)-;
sensitization)-; (Skin sensitization)-; (Skin No data available
possible; Skin (Skin
sensitization)- sensitization)-
sensitization: sensitization)-
Classification not
5 Germ cell mutagenicity possible
Classification not
- - - No data available
possible
6 Carcinogenicity Classification not
- - - No data available
possible
7 Toxic to reproduction Classification not
- - - No data available
possible
8 Specific target organs/systemic Classification not
- - - No data available.
toxicity following single exposure possible
9 Specific target organs/systemic
Classification not
toxicity following repeated - - - No data available
exposure
possible
10 Aspiration hazard Classification not
- - - No data available
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Classification not
- - - No data available
environment (acute) possible
11 Hazardous to the aquatic Classification not
- - - No data available.
environment (chronic) possible
GHS Classification
ID1372 Ｎ‐（４‐Ｂｒｏｍｏｂｅｎｚｙｌ）‐２‐ｆｌｕｏｒｏａｃｅｔａｍｉｄｅ
CAS 24312-44-5 Date Classified： 2006/7/24 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not applicable - - - There are no chemical groups associated with explosive properties present in the molecules.
2 Flammable gases Not applicable - - - Solid (GHS definition)
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not applicable - - - Solid (GHS definition)
5 Gases under pressure Not applicable - - - Solid (GHS definition)
6 Flammable liquids Not applicable - - - Solid (GHS definition)
7 Flammable solids Not classified because it can be considered as a flame-retardant substance and "It is incinerated with a flammable solvent
Not classified - - - in an incinerator attached an afterburner and a scrubber."(All Data of target substances for MSDS in Poisonous and
Violent Substances Control Law, The Chemical Daily、2001, as Attention in waste)
8 Self-reactive substances and Not applicable - - - There are no chemical groups associated with explosive or self-reactive properties present in the molecule.
mixtures
9 Pyrophoric liquids Not applicable - - - Solid (GHS definition)
10 Pyrophoric solids Not classified - - - Non-pyrophoric when in contact with air at a room temperature and used as agricultural chemicals.
11 Self-heating substances and Classification not
- - - Test methods applicable to solid (melting point ≦ 140℃) substances are not available.
mixtures possible
12 Substances and mixtures, which
in contact with water, emit Not applicable - - - The chemical structure of the substance does not contain metals or metaloids(B, Si, P, Ge, As, Se, Sn, Sb, Te, Bi, Po, At).
flammable gases
13 Oxidizing liquids Not applicable - - - Solid (GHS definition)
14 Oxidizing solids Organic compounds containing oxygen and fluorine, and these elements are chemically bonded only to carbon (but not to
Not applicable - - -
other elements).
15 Organic peroxides Not applicable - - - Organic compounds containing no -0-0- structure
16 Corrosive to metals Classification not
- - - Test methods applicable to solid substances are not available.
possible
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) Category 4 Exclamation mark Warning Harmful if swallowed Category 4 based on SPECIES: Rat; ENDPOINT: LD50;VALUE:410mg/kg; REFERENCE SOURCE: RTECS (1996)
1 Acute toxicity (dermal) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: gas) Not applicable - - - Solid (GHS definition)
1 Acute toxicity (inhalation: vapour) Classification not - - - No data available
possible
1 Acute toxicity (inhalation: dust, Classification not
- - - No data available
mist) possible
2 Skin corrosion / irritation Classification not
- - - No data available
possible
3 Serious eye damage / eye Classification not
irritation - - - No data available
possible
4 Respiratory/skin sensitizer Respiratory
sensitization: (Respiratory
(Respiratory (Respiratory
Classification not sensitization)-;
sensitization)-; (Skin sensitization)-; (Skin No data available
possible; Skin (Skin
sensitization)- sensitization)-
sensitization: sensitization)-
Classification not
5 Germ cell mutagenicity possible
Classification not
- - - No data available
possible
6 Carcinogenicity Classification not
- - - No data available
possible
7 Toxic to reproduction Classification not
- - - No data available
possible
8 Specific target organs/systemic Classification not
toxicity following single exposure possible - - - No data available.
9 Specific target organs/systemic Classification not
toxicity following repeated - - - No data available
exposure
possible
10 Aspiration hazard Classification not
- - - No data available
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Classification not
- - - Insufficient data available.
environment (acute) possible
11 Hazardous to the aquatic Classification not
- - - Classification not possible due to lack of data
environment (chronic) possible
GHS Classification
ID1373 hydrogen iodide
CAS 10034-85-2 Date Classified： 2006/8/18 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not applicable - - - Gas (GHS definition)
2 Flammable gases Not classified - - - Non-combustible (ICSC(J), 1999) UNRTDG No.2455, Class: 2.2.
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not classified - - - Not classified because it is UNRTDG No. 2197, Class: 2.3(8) but not Subsidiary risks Class: 5.1.
5 Gases under pressure Contains gas under
Liquefied gas(Low Low pressure liquefied gas because of "the critical temp: 151.0℃" (Merck, 13th, 2001) and the boiling point: -35.1℃ (at
Gas cylinder Warning pressure; may
pressure liquefied gas) 1atm).
explode if heated
6 Flammable liquids Not applicable - - - Gas (GHS definition)
7 Flammable solids Not applicable - - - Gas (GHS definition)
8 Self-reactive substances and Not applicable - - - Gas (GHS definition)
mixtures
9 Pyrophoric liquids Not applicable - - - Gas (GHS definition)
10 Pyrophoric solids Not applicable - - - Gas (GHS definition)
11 Self-heating substances and Not applicable - - - Gas (GHS definition)
mixtures
12 Substances and mixtures, which
in contact with water, emit Not applicable - - - Gas (GHS definition)
flammable gases
13 Oxidizing liquids Not applicable - - - Gas (GHS definition)
14 Oxidizing solids Not applicable - - - Gas (GHS definition)
15 Organic peroxides Not applicable - - - Gas (GHS definition)
16 Corrosive to metals Classification not Although it is corrosive gas as UNRTDG is classified into 2.3 (8) according to the UNRTDG No. (2197), test methods
- - -
possible suitable for gaseous substances are not established.
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) Classification not
- - - No data available
possible
1 Acute toxicity (dermal) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: gas) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: vapour) Not applicable - - - Gas (GHS definition)
1 Acute toxicity (inhalation: dust, Not applicable - - - Gas (GHS definition)
mist)
2 Skin corrosion / irritation Causes severe skin Since there is description that "skin necrosis" is seen to humans in Priority 1(PATTY (5th, 2001)), and it was classified in
Category 1A-1C Corrosion Danger burns and eye 'C;R35' of European risk phrases (EU-Annex I (access on Oct 2005)), it was set as category 1A-1C.
damage [view] It is more desirable to be set as 1A from a viewpoint of safety, when further categorizing needs to be performed.
3 Serious eye damage / eye From the description that critical irritation is indicated to the human eye in Priority 1 (PATTY (5th, 2001)), and the
Causes serious eye
irritation Category 1 Corrosion Danger document of Priority 2 had description "caustic is indicated to an eye" (ICSC (J) (1999), SITTIG (4th, 2002)), it was set as
damage
Category 1.
4 Respiratory/skin sensitizer Respiratory
sensitization: (Respiratory
(Respiratory (Respiratory
Classification not sensitization)-;
sensitization)-; (Skin sensitization)-; (Skin No data available
possible; Skin (Skin
sensitization)- sensitization)-
sensitization: sensitization)-
Classification not
5 Germ cell mutagenicity possible
Classification not
- - - No data available
possible
6 Carcinogenicity Classification not
- - - No data available
possible
7 Toxic to reproduction Classification not
- - - No data available
possible
8 Specific target organs/systemic Cause damage to
Since there is description that in Priority 1 and Priority 2, by inhalation of this product, it effects on the respiratory
toxicity following single exposure Category 1 organs
Health hazard Danger system, such as pulmonary edemas, an edema of larynx, an edema of glottis (PATTY (5th, 2001), ICSC (J) (1999), HSDB
(inhalation:respiratory) (inhalation:respirator
(2003), SITTIG (4th, 2002)), it was considerd as Category 1 (inhalation: respiratory systems).
y)
9 Specific target organs/systemic Causes damage to
toxicity following repeated organs (inhalation:
exposure Category 1 (inhalation:
testesrespiratory Since there was description that bronchitis was occured in the long-term or repetitive exposure of this product (PATTY
testesrespiratory Health hazard Danger
organs) through (5th, 2001), HSFS (2001) Priority 1 and Priority 2), it was classified into Category 1 (inhalation: respiratory systems).
organs)
prolonged or
repeated exposure
10 Aspiration hazard Not applicable - - - Gas (GHS definition)
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Classification not
- - - No data available
environment (acute) possible
11 Hazardous to the aquatic Classification not
- - - No data available.
environment (chronic) possible
GHS Classification
ID1374 Ｌａｓａｌｏｃｉｄ
CAS 11054-70-9 Date Classified： 3/23/2006
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives There are no chemical groups associated with explosive properties present in the molecules. (Since data on physical
Not applicable - - - chemical property of Lasalocid (CAS No.11054-70-9) was not available, Lassalocid A (CAS No.2599-31-9) which has less
one carbon than Lassalocid was classified in the physical chemical hazard.
2 Flammable gases Not applicable - - - Solid (GHS definition)
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not applicable - - - Solid (GHS definition)
5 Gases under pressure Not applicable - - - Solid (GHS definition)
6 Flammable liquids Not applicable - - - Solid (GHS definition)
7 Flammable solids The all substance data for Poisonous and Violent Substances Control Law MSDS (Chemical Daily, 2001) states about the
Not classified - - - disposal of Lasalocid A as "incinate with inflammable solvent in an incinerator with afterburner and scrubber". It was
considered to be flame retardant and was classified as out of Category.
8 Self-reactive substances and Not applicable - - - There are no chemical groups associated with explosive or self-reactive properties present in the molecule.
mixtures
9 Pyrophoric liquids Not applicable - - - Solid (GHS definition)
10 Pyrophoric solids Non-pyrophoric when in contact with air at a room temperature (antibiotic of microorganism origin and non-pyrophoric
Not classified - - -
structurally)
11 Self-heating substances and Classification not The test suitable for the solid state material with a melting point of 140 ℃ or less has not been established (in the case of
- - -
mixtures possible the free body instead of sodium salts).
12 Substances and mixtures, which
Metals or metalloids (B, Si, P, Ge, As, Se, Sn, Sb, Te, Bi, Po, At) is not included (in the case of the free body instead of
in contact with water, emit Not applicable - - -
flammable gases
sodium salts).
13 Oxidizing liquids Not applicable - - - Solid (GHS definition)
14 Oxidizing solids Not applicable - - - Organic compounds containing oxygen bonded to only carbon and hydrogen (not disodium salt but free body))
15 Organic peroxides Not applicable - - - Organic compounds containing no -0-0- structure
16 Corrosive to metals Classification not
- - - Test methods applicable to solid substances are not available.
possible
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) Classification not Although there is the data for horses (LD50=22mg/kg) (RTECS, 1986), there is no data for rodents. So this substance
- - -
possible cannot be classified.
1 Acute toxicity (dermal) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: gas) Not applicable - - - Solid (GHS definition)
1 Acute toxicity (inhalation: vapour) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: dust, Classification not
- - - No data available
mist) possible
2 Skin corrosion / irritation Causes mild skin
Category 3 - Warning From the description that it stimulates the rabbit skin at mild (Mild) degree (RTECS, 1986), it was set as category 3.
irritation
3 Serious eye damage / eye Causes serious eye
irritation Category 2A Exclamation mark Warning It was set as Category 2A from description that it stimulates to moderate to the rabbit eye (RTECS, 1986).
irritation
4 Respiratory/skin sensitizer Respiratory
sensitization: (Respiratory
(Respiratory (Respiratory
Classification not sensitization)-; Respiratory sensitization: no data available.
sensitization)-; (Skin sensitization)-; (Skin
possible; Skin (Skin Skin sensitization: no data available.
sensitization)- sensitization)-
sensitization: sensitization)-
Classification not
5 Germ cell mutagenicity possible
Classification not
- - - No data available
possible
6 Carcinogenicity Classification not
- - - No data available
possible
7 Toxic to reproduction Classification not
- - - No data available
possible
8 Specific target organs/systemic Classification not - - - No data available.
toxicity following single exposure possible
9 Specific target organs/systemic Classification not
toxicity following repeated - - - No data available
exposure
possible
10 Aspiration hazard Classification not
- - - No data available
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Classification not
- - - No data available
environment (acute) possible
11 Hazardous to the aquatic Classification not
- - - No data available.
environment (chronic) possible
GHS Classification
ID1375 Fenaminosulf
CAS T-13 Date Classified： 2007/2/20 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Classification not possible due to lack of data, though the substance contains nitrogen atoms adjacent to each other as
Classification not
- - - chemical groups with explosive properties present. (No data was available with no CAS number for this substance. Refer to
possible
the sodium salt, para-Dimethylaminobenzenediazosodium sulfonate (ID No.1376、CAS No.140-56-7))
2 Flammable gases Not applicable - - - Solid (GHS definition)
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not applicable - - - Solid (GHS definition)
5 Gases under pressure Not applicable - - - Solid (GHS definition)
6 Flammable liquids Not applicable - - - Solid (GHS definition)
7 Flammable solids Classification not
- - - No data available
possible
8 Self-reactive substances and Classification not Although the grouping relevant to explosive (adjoining nitrogen atom) is included, the grouping relevant to autoreactive is
- - -
mixtures possible not included. There is no data and it cannot be classified.
9 Pyrophoric liquids Not applicable - - - Solid (GHS definition)
10 Pyrophoric solids Classification not
- - - No data available
possible
11 Self-heating substances and Classification not
- - - No data available
mixtures possible
12 Substances and mixtures, which
in contact with water, emit Not applicable - - - The chemical structure of the substance does not contain metals or metaloids(B, Si, P, Ge, As, Se, Sn, Sb, Te, Bi, Po, At).
flammable gases
13 Oxidizing liquids Not applicable - - - Solid (GHS definition)
14 Oxidizing solids Classification not
- - - No data available
possible
15 Organic peroxides Not applicable - - - Organic compounds containing no -0-0- structure
16 Corrosive to metals Classification not
- - - Test methods applicable to solid substances are not available.
possible
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) No data.
Classification not
- - - [Note] We could not obtain the health hazard information in the Priority 1 and 2, because this substance does not have a
possible
CAS No. When necessary, we used the findings about p-dimethylaminobenzenediazo sodium sulfonate which is the sodium
salt of this substance. Refer to p-Dimethylaminobenzenediazo sodium sulfonate (ID 1376, CAS 140-56-7).
1 Acute toxicity (dermal) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: gas) Not applicable - - - Solid (GHS definition)
1 Acute toxicity (inhalation: vapour) Classification not - - - No data available
possible
1 Acute toxicity (inhalation: dust, Classification not
- - - No data available
mist) possible
2 Skin corrosion / irritation Classification not
- - - No data available
possible
3 Serious eye damage / eye Classification not
irritation - - - No data available
possible
4 Respiratory/skin sensitizer Respiratory
sensitization: (Respiratory
(Respiratory (Respiratory
Classification not sensitization)-;
sensitization)-; (Skin sensitization)-; (Skin No data available
possible; Skin (Skin
sensitization)- sensitization)-
sensitization: sensitization)-
Classification not
possible
5 Germ cell mutagenicity There is no this substance data. But there is no in vivo data with p-Dimethylaminobenzenediazo sulfonate (ID 1376, CAS
140-56-7). And in in vitro mutagenicity test, there is an Ames positive (RTECS, 2003; NTP DB, 2006), MLA positives (NTP
DB, 2006), CHL cell chromosome aberration positives (HSDB, 2003; RTECS, 2003), and CHO cells chromosome aberration
Classification not
- - - negatives (NTP DB, 2006). There is strong response of Ames but others are not strong, and the CHO chromosome
possible
aberration test of NTP is negative. Considering these points, it is judged as there is insufficient knowledge to be Category
2, and it is treated as it cannot be classified according to the guidelines. So it cannot be classified similarly about this
substance.
6 Carcinogenicity There is no data of this product. But sulfuric acid para-dimethyl aminophenydiazonium sodium (ID 1376, Chemical
Not classified - - - Abstracts Service 140-56-7) was classified into Group 3 (substance which cannot be classificationed into human
carcinogenicity) in IARC (Supple.7, 1987) and carried out the outside of Category. So this product was as well set to the
7 Toxic to reproduction Although there is no data on this substance, in sulfuric acid paradimethyl-aminophenyl-diazonium sodium (ID 1376, CAS:
Classification not 140-56-7), fetal death and musculoskeletal effects in teratogenicity studies using female rats were reported (RTECS,
- - -
possible 2003). However, it was judged to be unclassifiable due to insufficient data, so this substance was similarly judged to be
unclassified.
8 Specific target organs/systemic Although there is no data about this product, since in sulfuric acid paradimethyl aminophenyl diazonium sodium (ID 1376,
toxicity following single exposure Cause damage to CAS 140-56-7), it is supposed that in rat acute oral administration, renal tubular damages (HSDB, 2003) was observed at
Category 1 (kidneys) Health hazard Danger
organs (kidneys) the dose of guidance levels of Category 1 and it was considered as Category 1 (renal). So it was similarly considered as
Category 1 (renal) about the this product.
9 Specific target organs/systemic May cause damage Although there is no data of this product, since nephropathy was observed in feeding administration for 12 months in rat at
toxicity following repeated to organs (kidneys) 0.10% (= an equivalent for 1000 ppm and 50 mg/kg/day) by sulfuric para-dimethylaminophenyl diazonium sodium (ID 1376,
exposure Category 2 (kidneys) Health hazard Warning
through prolonged or CAS 140-56-7) (HSDB, 2003) and it was equivalent to the guidance value of Category 2, and thus it was classified into
repeated exposure Category 2 (kidney), it was similarly classified into Category 2 (kidney) on this product.
10 Aspiration hazard Classification not
- - - No data available
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Classification not
- - - No data available
environment (acute) possible
11 Hazardous to the aquatic Classification not
- - - No data available.
environment (chronic) possible
GHS Classification
ID1376 Fenaminosulf
CAS 140-56-7 Date Classified： 2006/7/24 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not classified because of no data on the explosibility, though the substance contains nitrogen atoms adjacent to each
Not classified - - - other as chemical groups associated with explosive properties present and has its oxygen balance calculated at -114.6,
higher than -200 of the criteria.
2 Flammable gases Not applicable - - - Solid (GHS definition)
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not applicable - - - Solid (GHS definition)
5 Gases under pressure Not applicable - - - Solid (GHS definition)
6 Flammable liquids Not applicable - - - Solid (GHS definition)
7 Flammable solids Classification not
- - - No data available
possible
8 Self-reactive substances and Although the grouping relevant to explosive (adjoining nitrogen atom) was included, the grouping relevant to autoreactive
mixtures Not classified - - - was not included and the data in which autoreactive is indicated was not found, either. So it was considered the outside of
Category.
9 Pyrophoric liquids Not applicable - - - Solid (GHS definition)
10 Pyrophoric solids Not classified - - - Non-pyrophoric when in contact with air at a room temperature and used as agricultural chemicals.
11 Self-heating substances and Classification not
- - - No data available
mixtures possible
12 Substances and mixtures, which
in contact with water, emit Not classified - - - Stable to water (the water solubility is obtained)
flammable gases
13 Oxidizing liquids Not applicable - - - Solid (GHS definition)
14 Oxidizing solids Classification not
- - - No data available
possible
15 Organic peroxides Not applicable - - - Organic compounds containing no -0-0- structure
16 Corrosive to metals Classification not
- - - Test methods applicable to solid substances are not available.
possible
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) Skull and Based on the LD50 value of 60mg/kg (HSDB, 2003; RTECS, 2003) in the oral administration test using female rats and rats,
Category 3 Danger Toxic if swallowed
crossbones the substance was classified as Category 3.
1 Acute toxicity (dermal) Classification not There is only a report of rat LD50 value >100mg/kg (HSDB, 2003) of the dermal administration test, and it cannot be
- - -
possible classified.
1 Acute toxicity (inhalation: gas) Not applicable - - - Solid (GHS definition)
1 Acute toxicity (inhalation: vapour) Classification not - - - No data available
possible
1 Acute toxicity (inhalation: dust, Classification not
- - - No data available
mist) possible
2 Skin corrosion / irritation Classification not
- - - No data available
possible
3 Serious eye damage / eye Classification not
irritation - - - No data available
possible
4 Respiratory/skin sensitizer Respiratory
sensitization: (Respiratory
(Respiratory (Respiratory
Classification not sensitization)-;
sensitization)-; (Skin sensitization)-; (Skin No data available
possible; Skin (Skin
sensitization)- sensitization)-
sensitization: sensitization)-
Classification not
5 Germ cell mutagenicity possible There is no in vivo data. And in in vitro mutagenicity test, there is an Ames positive (RTECS, 2003; NTP DB, 2006), MLA
positives (NTP DB, 2006), a CHL cell chromosome aberration positive (HSDB, 2003; RTECS, 2003), CHO cell chromosome
Classification not
- - - aberration negative (NTP DB, 2006). And although the response of Ames is strong, other positive reactions are not strong.
possible
Moreover, in the CHO chromosome aberration test of NTP was negative, it was not judged as 2 because of insufficient
knowledge. And it cannot be classified according to a guideline.
6 Carcinogenicity Since it was classificationed into Group 3 (substance which cannot be classificationed into human carcinogenicity) in IARC
Not classified - - - (Supple.7, 1987), it carried out the outside of Category. In addition, carcinogenic was also negative in the two-year feed-
mix administration tests for rats and mice of NTP TR101 (1978).
7 Toxic to reproduction Classification not Although fetal death and musculoskeletal effects in teratogenicity studies using female rats were reported (RTECS, 2003)
- - -
possible it was judged to be unclassifiable due to insufficient data.
8 Specific target organs/systemic Cause damage to Since in acute oral administration in rat, renal tubular damage (HSDB, 2003) was observed at the dose of guidance levels in
Category 1 (kidneys) Health hazard Danger
toxicity following single exposure organs (kidneys) Category 1, it was considered as Category 1 (renal).
9 Specific target organs/systemic May cause damage
Since nephropathy is observed in feeding administration for 12 months in rat at 0.10% (= an equivalent for 1000 ppm and 50
toxicity following repeated to organs (kidneys)
exposure Category 2 (kidneys) Health hazard Warning mg/kg/day) (HSDB, 2003) and it is equivalent to the guidance value of Category 2, it was classified into Category 2
through prolonged or
(kidney).
repeated exposure
10 Aspiration hazard Classification not
- - - No data available
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Category 2 - - Toxic to aquatic life It was classified into Category 2 from 96-hour LC50=3.7mg/L of Crustacea (Amphipod), and others (HSDB、2004).
environment (acute)
11 Hazardous to the aquatic Toxic to aquatic life
Classified into Category 2, since acute toxicity was Category 2, and supposed not rapidly degrading （BIOWIN）, though
environment (chronic) Category 2 Environment - with long lasting
lsupposed ess bio-accumulative （log Kow=-1.66（PHYSPROP Database、2005））.
effects
GHS Classification
ID1377 trizinc diphosphide
CAS 1314-84-7 Date Classified： 2006/7/24 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not applicable - - - There are no chemical groups associated with explosive properties present in the molecules.
2 Flammable gases Not applicable - - - Solid (GHS definition)
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not applicable - - - Solid (GHS definition)
5 Gases under pressure Not applicable - - - Solid (GHS definition)
6 Flammable liquids Not applicable - - - Solid (GHS definition)
7 Flammable solids Nonflammable (ICSC (J), 2001). (However, since it will decompose on contact with water, damp air or acid, and produce
Not classified - - -
flammable fumes, such as phosphine, cautions are needed.)
8 Self-reactive substances and Not applicable - - - There are no chemical groups associated with explosive or self-reactive properties present in the molecule.
mixtures
9 Pyrophoric liquids Not applicable - - - Solid (GHS definition)
10 Pyrophoric solids Not classified - - - Non-combustible (ICSC (J), 2001)
11 Self-heating substances and Not classified - - - Not combustible (ICSC(J) (2001))
mixtures
12 Substances and mixtures, which In contact with
in contact with water, emit water releases
flammable gases Category 1 Flame Danger flammable gases Category 1 UNRTDG No. 1714, Class: 4.3, PG Ⅰ
which may ignite
spontaneously
13 Oxidizing liquids Not applicable - - - Solid (GHS definition)
14 Oxidizing solids Not applicable - - - Inorganic compounds containing no oxygen and halogen.
15 Organic peroxides Not applicable - - - Inorganic compound
16 Corrosive to metals Classification not
- - - Test methods applicable to solid substances are not available.
possible
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) Based on the rat LD50 : 42.6mg/kg (99.9% purity), 43.8mg/kg (94% purity), 54mg/kg (87% purity) and 55.5mg/kg (83% purity)
Skull and
Category 2 Danger Fatal if swallowed (Agricultural Chemical Registration Data, 1992), we adopted the LD 50 value with 99.9% purity to classify the substance as
crossbones
Category 2.
1 Acute toxicity (dermal) Exclamation mark Harmful in contact It was set as Category 4 based on LD50 value of female rat (LD50 = 1123mg/kg) of the dermal administration test. ( Rat
Category 4 Warning
with skin LD50 = 1123mg/kg (female) and 1414mg/kg (male)(Agricultural Chemical Registration Data, 1992)).
1 Acute toxicity (inhalation: gas) Not applicable - - - Solid (GHS definition)
1 Acute toxicity (inhalation: vapour) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: dust, Classification not
- - - No data available
mist) possible
2 Skin corrosion / irritation Since four cases show the very slight redness 1 hour after eliminating coated gauze in the skin irritation test (3% zinc
Not classified - - - phosphites granules) using rabbits, but they were disappeared 24 hours afterward (Agricultural Chemical Registration Data,
1992), it carried out the outside of category.
3 Serious eye damage / eye By the eye irritation tests (3% zinc phosphites granules) using a rabbit, inflammation of the iris, moderate stimulus to
irritation conjunctiva was accepted, and muddiness of the cornea of diffusion was accepted by one example in the ocular-mucous
Category 2B - Warning Causes eye irritation membrane of non-washing group. Although slowdown of the gloss of the cornea usually seen was accepted in 3 examples
at 1 hour after medication, it became normal at 72 hours or at 7 days (Agricultural Chemical Registration Data). So it was
set as Category 2B.
4 Respiratory/skin sensitizer Respiratory
(Respiratory Respiratory sensitization: no data available.
sensitization: (Respiratory (Respiratory
sensitization)-; Skin sensitization: by the skin sensitization study (3% zinc phosphites granules) in the Buehler method using a guinea pig,
Classification not sensitization)-; (Skin sensitization)-; (Skin
(Skin from the result that skin sensitization is negative (Agricultural Chemical Registration Data, 1992), it carried out the outside
possible; Skin sensitization)- sensitization)-
sensitization)- of Category.
sensitization: Not
5 Germ cell mutagenicity classified
Classification not There is no test results of in vivo, and there is the negative result in in vitro gene mutagenicity test (Ames test)
- - -
possible (Agricultural Chemical Registration Data, 1992). So it cannot be classified because of insufficient data.
6 Carcinogenicity Classification not
- - - No data available
possible
7 Toxic to reproduction Classification not
- - - No data available
possible
8 Specific target organs/systemic Since it acts on the central nervous system by the hydrogen phosphide generated from zinc phosphide in the gastric as
toxicity following single exposure Cause damage to biological activity of zinc phosphide granules 3% and the lethal action was indicated (Agricultural Chemical Registration
Category 1 (central
Health hazard Danger organs (central Data, 1992), it was considered as Category 1 (central nervous systems). In addition, although there is description that a
nervous system)
nervous system) mildest positive histologic changes was observed in the kidney and lungs in rat acute oral toxicity test (Agricultural
Chemical Registration Data, 1992), data is insufficient only in these data.
9 Specific target organs/systemic May cause damage Since the small necrotic foci of liver was observed with high occurrence in male administration groups with 100 ppm
toxicity following repeated to organs (liver) (equivalent for estimate of 15mg/kg/day) in the three-month repeated oral feeding administration examination of a mouse,
exposure Category 2 (liver) Health hazard Warning
through prolonged or (Agricultural Chemical Registration Data, 1992), it was classified into Category 2 (liver) from comparison with a guidance
repeated exposure value.
10 Aspiration hazard Classification not
- - - No data available
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Classification not
- - - Insufficient data available.
environment (acute) possible
11 Hazardous to the aquatic Classification not
- - - Classification not possible due to lack of data
environment (chronic) possible
GHS Classification
ID1378 Ｔｈｉｏｃｙａｎａｔｏａｃｅｔｉｃ ａｃｉｄ ｅｔｈｙｌ ｅｓｔｅｒ
CAS 5349-28-0 Date Classified： 2006/7/24 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not applicable - - - There are no chemical groups associated with explosive properties present in the molecules.
2 Flammable gases Not applicable - - - Liquid (GHS definition)
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not applicable - - - Liquid (GHS definition)
5 Gases under pressure Not applicable - - - Liquid (GHS definition)
6 Flammable liquids Classification not
- - - No data available
possible
7 Flammable solids Not applicable - - - Liquid (GHS definition)
8 Self-reactive substances and Not applicable - - - There are no chemical groups associated with explosive or self-reactive properties present in the molecule.
mixtures
9 Pyrophoric liquids Not classified - - - Uses are agricultural chemicals, and even if it contacts the normal temperature air, it does not ignite spontaneously.
10 Pyrophoric solids Not applicable - - - Liquid (GHS definition)
11 Self-heating substances and Classification not
- - - Test methods applicable to liquid substances are not available
mixtures possible
12 Substances and mixtures, which
in contact with water, emit Not applicable - - - The chemical structure of the substance does not contain metals or metaloids(B, Si, P, Ge, As, Se, Sn, Sb, Te, Bi, Po, At).
flammable gases
13 Oxidizing liquids Not applicable - - - Organic compounds containing oxygen chemically bonded only to carbon and hydrogen (but not to other elements).
14 Oxidizing solids Not applicable - - - Liquid (GHS definition)
15 Organic peroxides Not applicable - - - Organic compounds containing no -0-0- structure
16 Corrosive to metals Classification not
- - - No data available
possible
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) Category 3 Skull and Danger Toxic if swallowed Category 3 based on SPECIES: Mouse; ENDPOINT: LD50; VALUE: 52mg/kg; REFERENCE SOURCE: RTECS (1997)
1 Acute toxicity (dermal) Classification not crossbones
- - - No data available
possible
1 Acute toxicity (inhalation: gas) Not applicable - - - Liquid (GHS definition)
1 Acute toxicity (inhalation: vapour) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: dust, Classification not
- - - No data available
mist) possible
2 Skin corrosion / irritation Classification not
- - - No data available
possible
3 Serious eye damage / eye
Classification not
irritation - - - No data available
possible
4 Respiratory/skin sensitizer Respiratory
sensitization: (Respiratory
(Respiratory (Respiratory
Classification not sensitization)-;
sensitization)-; (Skin sensitization)-; (Skin No data available
possible; Skin (Skin
sensitization)- sensitization)-
sensitization: sensitization)-
Classification not
5 Germ cell mutagenicity possible
Classification not
- - - No data available
possible
6 Carcinogenicity Classification not
- - - No data available
possible
7 Toxic to reproduction Classification not
- - - No data available
possible
8 Specific target organs/systemic Classification not - - -
Although respiratory irritant reaction was indicationed in the oral acuteness fatality examination of the mouse (RTECS,
toxicity following single exposure possible 1997), it cannot be classified due to insufficient data.
9 Specific target organs/systemic Classification not
toxicity following repeated - - - No data available
exposure
possible
10 Aspiration hazard Classification not
- - - No data available
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Classification not
- - - Insufficient data available.
environment (acute) possible
11 Hazardous to the aquatic Classification not
- - - Classification not possible due to lack of data
environment (chronic) possible
GHS Classification
ID1379 Cellulose, nitrate
CAS 9004-70-0 Date Classified： 2006/3/23 (Environmental Hazards: 2006/2/10)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Explosive; mass
Division 1.1 Exploding bomb Danger UNRTDG Class: 1.1D
explosion hazard
2 Flammable gases Not applicable - - - Solid (GHS definition)
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not applicable - - - Solid (GHS definition)
5 Gases under pressure Not applicable - - - Solid (GHS definition)
6 Flammable liquids Not applicable - - - Solid (GHS definition)
7 Flammable solids Not classified - - - UNRTDG Class: 1.1D
8 Self-reactive substances and
mixtures
Not applicable - - - Classified in explosives
9 Pyrophoric liquids Not applicable - - - Solid (GHS definition)
10 Pyrophoric solids Not classified - - - UNRTDG Class: 1.1D
11 Self-heating substances and
mixtures
Not classified - - - UNRTDG Class: 1.1D
12 Substances and mixtures, which
in contact with water, emit Not applicable - - - The chemical structure of the substance does not contain metals or metaloids(B, Si, P, Ge, As, Se, Sn, Sb, Te, Bi, Po, At).
flammable gases
13 Oxidizing liquids Not applicable - - - Solid (GHS definition)
14 Oxidizing solids Not classified - - - UNRTDG Class: 1.1D
15 Organic peroxides Not applicable - - - Containing no -0-0- structure
16 Corrosive to metals Not classified - - - UNRTDG Class: 1.1D
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) SPECIES: Rat
ENDPOINT: LD50
Not classified - - -
VALUE: > 5000 mg/kg
REFERENCE SOURCE: RTECS (Access on Aug 2005)
1 Acute toxicity (dermal) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: gas) Not applicable - - - Solid (GHS definition)
1 Acute toxicity (inhalation: vapour) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: dust, Classification not
- - - No data available
mist) possible
2 Skin corrosion / irritation Classification not There is description which suggests a possibility of stimulating the skin (HSFS (2001)). But there is no report of a specific
- - -
possible case, and since data is insufficient, it cannot be classified.
3 Serious eye damage / eye
Classification not Although there was description which suggests a possibility of stimulating an eye to HSFS (2001), there was no report of a
irritation - - -
possible concrete case. So data was insufficient, it was not able to classify.
4 Respiratory/skin sensitizer Respiratory
sensitization:
Classification not
- - - No data available
possible; Skin
sensitization:
Classification not
5 Germ cell mutagenicity possible
Classification not
- - - No data available
possible
6 Carcinogenicity Classification not
- - - Classification not possible due to lack of data
possible
7 Toxic to reproduction Classification not
- - - No data available
possible
8 Specific target organs/systemic May cause
toxicity following single exposure respiratory irritation
Since there is description in HSFS (2001) that it stimulates the throat in humans, and in high concentrations, it is
Category 3 (respiratory or may cause
Exclamation mark Warning suggested that it may cause dizziness, dyspnea and unconsciousness, it was judged that it has respiratory irritant and was
tract irritation) drowsiness and
considered as Category 3.
dizziness
(respiratory tract
9 Specific target organs/systemic Classification not irritation)
toxicity following repeated - - - No data available
exposure
possible
10 Aspiration hazard Classification not
- - - No data available
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Not classified - - - It carried out the outside of Category from 96-hour EC50=579000μg/L of algae (Selenastrum) (AQUIRE, 2003).
environment (acute)
11 Hazardous to the aquatic
environment (chronic)
Not classified - - - Since not water-insoluble (water solubility=1.00×106mg/L（PHYSPROP Database、2005)) and acute toxicity is low.
GHS Classification
ID1380 1,3,5-trinitrobenzene
CAS 99-35-4 Date Classified： 2006/5/24 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Explosive; mass
Division 1.1 Exploding bomb Danger UNRTDG Class: 1.1D
explosion hazard
2 Flammable gases Not applicable - - - Solid (GHS definition)
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not applicable - - - Solid (GHS definition)
5 Gases under pressure Not applicable - - - Solid (GHS definition)
6 Flammable liquids Not applicable - - - Solid (GHS definition)
7 Flammable solids Not classified - - - UNRTDG Class: 1.1D
8 Self-reactive substances and
mixtures
Not applicable - - - Classified in explosives
9 Pyrophoric liquids Not applicable - - - Solid (GHS definition)
10 Pyrophoric solids Not classified - - - UNRTDG Class: 1.1D
11 Self-heating substances and
mixtures
Not classified - - - UNRTDG Class: 1.1D
12 Substances and mixtures, which
in contact with water, emit Not applicable - - - The chemical structure of the substance does not contain metals or metaloids(B, Si, P, Ge, As, Se, Sn, Sb, Te, Bi, Po, At).
flammable gases
13 Oxidizing liquids Not applicable - - - Solid (GHS definition)
14 Oxidizing solids Not classified - - - UNRTDG Class: 1.1D
15 Organic peroxides Not applicable - - - Containing no -0-0- structure
16 Corrosive to metals Not classified - - - UNRTDG Class: 1.1D
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) Skull and Of the LD50 values of 450mg/kg and 275mg/kg in rats (IRIS, 1997), we adopted the lower value to classify the substance
Category 3 Danger Toxic if swallowed
crossbones as Category 3.
1 Acute toxicity (dermal) It was set as the outside of Category from the description that death was not observed by dermal exposure of 2000mg/kg
Not classified - - -
to rabbits (IRIS (1997)).
1 Acute toxicity (inhalation: gas) Not applicable - - - Solid (GHS definition)
1 Acute toxicity (inhalation: vapour) Classification not - - - No data available
possible
1 Acute toxicity (inhalation: dust, Classification not
- - - No data available
mist) possible
2 Skin corrosion / irritation From description that irritation was not admitted by the skin irritation test using the rabbit of IRIS (1997), it carried out the
Not classified - - -
outside of Category.
3 Serious eye damage / eye Causes serious eye It was set as Category 1 from description that the irreversible injury was admitted by the eye irritation tests using the
irritation Category 1 Corrosion Danger
damage rabbit (IRIS (1997)).
4 Respiratory/skin sensitizer Respiratory (Respiratory
sensitization: sensitization)-; (Skin Respirator: no data available.
Classification not Exclamation mark Warning sensitization)May Skin: it was referred to as Category 1 from description in which slight skin sensitization was admitted (sensitization rates:
possible; Skin cause allergic skin 85%) by the skin sensitization study by the Buehler method using the guinea pigs of IRIS (1997).
sensitization: Category1 reaction
5 Germ cell mutagenicity Classification not
- - - Classification not possible due to lack of data
possible
6 Carcinogenicity Classification not
- - - Classification not possible due to lack of data
possible
7 Toxic to reproduction Although the testicular degeneration is seen in the administration test in lactation period starting from pregnant or before
Classification not mating using rats (IRIS(1997)), any spesific toxicity has not been observed on reproductive potential and generation of
- - -
possible offspring. Since there was no description which clearly denies the hazard in other sources of Priority 1, it was presupposed
to be unclassifiable due to insufficient data.
8 Specific target organs/systemic Although there was description that ataxia and catalepsy were observed in IRIS (1997) in the single-dose oral study in rats,
Classification not
toxicity following single exposure - - - it was unknown whether these influences were temporary, and since there was no other data as same as this, it cannot be
possible
classified due to insufficient data.
9 Specific target organs/systemic May cause damage
Based on descriptions that the effect on testes and blood was observed within range of guidance value in Category 2 in
toxicity following repeated to organs (blood,
exposure Category 2 (blood, the rat oral study , and that the effect on testes was observed with the dose exceeding range of guidance value in
Health hazard Warning testes) through
testes) Category 2 a little in the mouse oral study (IRIS (1997)), blood and testes were considered to be target organ, and it
prolonged or
classified into Category 2.
repeated exposure
10 Aspiration hazard Classification not
- - - No data available
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Very toxic to
Category 1 Environment Warning It was classified into Category 1 from 96-hour LC50=380μg/L of fishes (American catfish) (AQUIRE, 2003) .
environment (acute) aquatic life
11 Hazardous to the aquatic Very toxic to
Classified into Category 1, since acute toxicity was Category 1, supposed not rapidly degrading (BIOWIN), though supposed
environment (chronic) Category 1 Environment Warning aquatic life with long
less bioaccumulative （log Kow=1.18（PHYSPROP Database、2005））.
lasting effects
GHS Classification
ID1381 Peroxyacetic acid
CAS 79-21-0 Date Classified： 2006/8/18 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not classified - - - UNRTDG Class: 5.2
2 Flammable gases Not applicable - - - Liquid (GHS definition)
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not applicable - - - Liquid (GHS definition)
5 Gases under pressure Not applicable - - - Liquid (GHS definition)
6 Flammable liquids Category 4 - Warning Combustible liquid Flash point: >60℃ and ≦90℃
7 Flammable solids Not applicable - - - Liquid (GHS definition)
8 Self-reactive substances and Not applicable - - - Classified in organic peroxidies
mixtures
9 Pyrophoric liquids Not classified - - - UNRTDG Class: 5.2
10 Pyrophoric solids Not applicable - - - Liquid (GHS definition)
11 Self-heating substances and Not classified - - - UNRTDG Class: 5.2
mixtures
12 Substances and mixtures, which
in contact with water, emit Not applicable - - - The chemical structure of the substance does not contain metals or metaloids(B, Si, P, Ge, As, Se, Sn, Sb, Te, Bi, Po, At).
flammable gases
13 Oxidizing liquids Not classified - - - UNRTDG Class: 5.2
14 Oxidizing solids Not applicable - - - Liquid (GHS definition)
15 Organic peroxides Type F (43% or less in Flame Warning Heating may cause a
UNRTDG Class: 5.2
mass and with fire
16 Corrosive to metals Not classified - - - UNRTDG Class: 5.2
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) SPECIES: Rat
ENDPOINT: LD50
Category 4 Exclamation mark Warning Harmful if swallowed
VALUE: 1540 mg/kg
REFERENCE SOURCE: DFGOT
1 Acute toxicity (dermal) Exclamation mark Harmful in contact
Category 4 Warning It was set as Category 4 based on rabbit LD50 value: 1410mg/kg (DFGOT).
with skin
1 Acute toxicity (inhalation: gas) Not applicable - - - Liquid (GHS definition)
1 Acute toxicity (inhalation: vapour) Based on LC50 value in 1 hour exposure on mice: 0.524mg/L (4-hour equivalent: 0.262mg/L) (DFGOT), it could be judged
Skull and as the steam with almost no mist from vapor pressure。And it was classified ｂｙ the ppm concentration standard. The
Category 1 Danger Fatal if inhaled
crossbones converted value was classified as 84ppm from conversion coefficient of 1ppm = 3.11mg/m3, and it was classified as
Category 1. This substance is caustic.
1 Acute toxicity (inhalation: dust, Classification not
- - - No data available
mist) possible
2 Skin corrosion / irritation From the description that severe irritation was acknowledged in the rabbit skin after open apply in 500mg (RTECS (Access
Causes severe skin
on Aug 2005)), and that eschar which attains to necrosis and depths by 3-hour apply on the rabbit skin was acknowledged
Category 1A-1C Corrosion Danger burns and eye
(DFGOT vol.7 (1996)), it judged that there were intensive skin irritations and skin corrosivenesses. So it was set as
damage
category 1A-1C.
3 Serious eye damage / eye There is the description that blindness was acknowledged accompanying the severe inflammation accompanied by corneal
irritation Causes serious eye clouding by the test which applied five drops of suspension 1% using the rabbit (DFGOT vol.7 (1996)). And the description
Category 1 Corrosion Danger
damage that severe eye irritations was acknowledged by the test which applied 1mg of peracetic equivalent to the eye of the rabbit
(RTECS (Access on Aug 2005)). And skin corrosiveness. So it was set as Category 1.
4 Respiratory/skin sensitizer Respirator: no data available.
Respiratory
Skin : in the skin sensitization study by the Draize's method using the guinea pig of IUCLID (2000), with description DFGOT
sensitization:
vol.7 (1996) that two sorts of tablets were negative, it is targeted at the patient who has shown the symptoms of eczema
Classification not
- - - in human who used drug product including the product for skin disinfection, since the positive example was not admitted by
possible; Skin
the examination which examined skin sensitization, the description that there will not be the potential of significant causing
sensitization: Not
sensitivity (PAA probably does not have significant allergic potential.), the potential which shows skin sensitization to
classified
humans was judged to estimate that it is very low, and carried out.
5 Germ cell mutagenicity Suspected of
causing genetic
defects (state route
Although there was a result (DFGOT) positive by the chromosome aberration test using the mammals bone marrow cells
of exposure if it is
Category 2 Health hazard Warning using a somatic which is an in vivo mutagenicity test, there was no result positive by the in vivo genotoxicity test using a
conclusively proven
germ cells. So it is classified into Category 2.
that no other routes
of exposure cause
the hazard)
6 Carcinogenicity Classification not
- - - Classification not possible due to lack of data
possible
7 Toxic to reproduction Classification not
- - - Classification not possible due to lack of data
possible
8 Specific target organs/systemic Cause damage to From description that it is a corrosive substances, and pulmonary edema was observed within the range of guidance value
toxicity following single exposure Category 1 (respiratory Health hazard Danger organs (respiratory in Category 1 in inhalation exposure test of the rat in DFGOT, it was judged that respiratory system is target organ, and
organs)
organs) considered as Category 1.
9 Specific target organs/systemic Causes damage to
toxicity following repeated organs Based on description that the pulmonary inflammation and bronchopneumonia were observed in inhalation exposure to the
exposure Category 1
(testesrespiratory mouse, cow, and pig (DFGOT vol.7 (1996)), and description that the hepatocellular necrosis was observed in dermal
(testesrespiratory Health hazard Danger
organs, liver) exposure to the guinea pigs (DFGOT vol.7 (1996)), respiratory tracts and liver were judged as target organs. Since these
organs, liver)
through prolonged or effects were observed in exposure with the guidance value range of Category 1, it was classified into Category 1.
repeated exposure
10 Aspiration hazard Classification not
- - - No data available
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Category 2 - - Toxic to aquatic life It was classified into Category 2 from 48-hour EC50=3.3mg/L of Crustacea (Daphnia magna) (IUCLID, 2000).
environment (acute)
11 Hazardous to the aquatic Since rapidly degrading (it hydrolyzed and acetic acid and hydrogen peraxide are generated), and supposed less bio-
Not classified - - -
environment (chronic) accumulative (log Kow=-1.07（PHYSPROP Database, 2005)).
GHS Classification
ID1382 lithium
CAS 7439-93-2 Date Classified： 2006/12/18 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not applicable - - - There are no chemical groups associated with explosive properties present in the molecules.
2 Flammable gases Not applicable - - - Solid (GHS definition)
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not applicable - - - Solid (GHS definition)
5 Gases under pressure Not applicable - - - Solid (GHS definition)
6 Flammable liquids Not applicable - - - Solid (GHS definition)
7 Flammable solids Not classified - - - UNRTDG Class: 4.3
8 Self-reactive substances and Not applicable - - - There are no chemical groups associated with explosive or self-reactive properties present in the molecule.
mixtures
9 Pyrophoric liquids Not applicable - - - Solid (GHS definition)
10 Pyrophoric solids Not classified - - - UNRTDG Class: 4.3
11 Self-heating substances and Not classified - - - UNRTDG Class: 4.3
mixtures
12 Substances and mixtures, which In contact with
in contact with water, emit water releases
flammable gases Category 1 Flame Danger flammable gases UNRTDG Class: 4.3; PG I
which may ignite
spontaneously
13 Oxidizing liquids Not applicable - - - Solid (GHS definition)
14 Oxidizing solids Not applicable - - - Containing no oxygen , chlorine and fluorine.
15 Organic peroxides Not applicable - - - Inorganic substance
16 Corrosive to metals Not classified - - - UNRTDG Class: 4.3
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) Classification not
- - - No data available
possible
1 Acute toxicity (dermal) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: gas) Not applicable - - - Solid (GHS definition)
1 Acute toxicity (inhalation: vapour) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: dust, Classification not
- - - No data available
mist) possible
2 Skin corrosion / irritation Causes severe skin
It was set as Category 1A-1C from description that caustics or severe irritation is indicated to the skin (ICSC (J) (1999),
Category 1A-1C Corrosion Danger burns and eye
HSFS (1999), and SITTIG (4th, 2002)).
damage
3 Serious eye damage / eye Causes serious eye It was set as Category 1 from description that caustics or severe irritation is indicated to the eye (ICSC (J), (1999), HSFS
irritation Category 1 Corrosion Danger
damage (1999), and SITTIG (4th, 2002)).
4 Respiratory/skin sensitizer Respiratory
sensitization:
Classification not
- - - No data available
possible; Skin
sensitization:
Classification not
5 Germ cell mutagenicity possible
Classification not
- - - No data available
possible
6 Carcinogenicity Classification not
- - - No data available
possible
7 Toxic to reproduction Classification not
- - - No data available
possible
8 Specific target organs/systemic May cause damage Respiratory system was judged as target organ and it was considered as Category 2 based on the description that it
Category 2 (respiratory
toxicity following single exposure Health hazard Warning to organs indicates caustic to the airway in ICSC (J) (1999), when inhaling it, pulmonary edemas is caused (HSFS (1999), and SITTIG
organs)
(respiratory organs) (4th, 2002))
9 Specific target organs/systemic Classification not
toxicity following repeated - - - Classification not possible due to lack of data
exposure
possible
10 Aspiration hazard Classification not
- - - No data available
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Classification not
- - - Insufficient data available.
environment (acute) possible
11 Hazardous to the aquatic Classification not
- - - Classification not possible due to lack of data
environment (chronic) possible
GHS Classification
ID1383 Phosphorus
CAS 7723-14-0(2) Date Classified： 2007/1/23 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not applicable - - - There are no chemical groups associated with explosive properties present in the molecules.
2 Flammable gases Not applicable - - - Solid (GHS definition)
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not applicable - - - Solid (GHS definition)
5 Gases under pressure Not applicable - - - Solid (GHS definition)
6 Flammable liquids Not applicable - - - Solid (GHS definition)
7 Flammable solids Category 2 Flame Warning Flammable solid UNRTDG Class: 4.2; PG III
8 Self-reactive substances and Not applicable - - - There are no chemical groups associated with explosive or self-reactive properties present in the molecule.
mixtures
9 Pyrophoric liquids Not applicable - - - Solid (GHS definition)
10 Pyrophoric solids Not classified - - - UNRTDG Class: 4.2 Flash point: 202℃ (Weiss, 2nd, 1986, p833)
11 Self-heating substances and Not classified - - - UNRTDG Class: 4.2
mixtures
12 Substances and mixtures, which
in contact with water, emit Not classified - - - UNRTDG Class: 4.2
flammable gases
13 Oxidizing liquids Not applicable - - - Solid (GHS definition)
14 Oxidizing solids Not applicable - - - Containing no oxygen , chlorine and fluorine.
15 Organic peroxides Not applicable - - - Containing no -0-0- structure
16 Corrosive to metals Not classified - - - UNRTDG Class: 4.2
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) SPECIES: Rat
ENDPOINT: LD50
Not classified - - -
VALUE: > 15000 mg/kg
REFERENCE SOURCE: IUCLID (2000)
1 Acute toxicity (dermal) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: gas) Not applicable - - - Solid (GHS definition)
1 Acute toxicity (inhalation: vapour) Classification not - - - No data available
possible
1 Acute toxicity (inhalation: dust, Classification not
- - - No data available
mist) possible
2 Skin corrosion / irritation Classification not There was description that it was non-irritant for 24-hour apply in Patch-test using the rabbit (IUCLID (2000)). But it
- - -
possible cannot be classified since there is no information which clearly negates hazardousness in the source of Priority 1.
3 Serious eye damage / eye Although there is description that there is no stimulativeness in the eye irritation tests of the rabbit in IUCLID (2000),
Classification not
irritation - - - there is description that an eye is stimulated as affect of the humans in HSDB (2005). And it cannot classify since data is
possible
insufficient.
4 Respiratory/skin sensitizer Respiratory
sensitization: (Respiratory
(Respiratory (Respiratory Respirator: no data available.
Classification not sensitization)-;
sensitization)-; (Skin sensitization)-; (Skin Skin: although there was description that skin sensitization was not acknowledged with the guinea pigs of IUCLID (2000), it
possible; Skin (Skin
sensitization)- sensitization)- presupposed that it cannot classify from there being no information which negates hazard clearly in the source of Priority1.
sensitization: sensitization)-
Classification not
5 Germ cell mutagenicity possible
Classification not
- - - No data available
possible
6 Carcinogenicity Classification not
- - - No data available
possible
7 Toxic to reproduction Classification not
- - - No data available
possible
8 Specific target organs/systemic Classification not
toxicity following single exposure possible - - - No data available.
9 Specific target organs/systemic Classification not
toxicity following repeated - - - No data available
exposure
possible
10 Aspiration hazard Classification not
- - - No data available
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Classification not
- - - No data available
environment (acute) possible
11 Hazardous to the aquatic Classification not
- - - No data available.
environment (chronic) possible
GHS Classification
ID1384 Celluloid, in blocks, rods, rolls, sheets, tubes, etc.
CAS 8050-88-2 Date Classified： 2006/4/20 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not classified - - - UNRTDG Class: 4.2 or 4.1
2 Flammable gases Not applicable - - - Solid (GHS definition)
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not applicable - - - Solid (GHS definition)
5 Gases under pressure Not applicable - - - Solid (GHS definition)
6 Flammable liquids Not applicable - - - Solid (GHS definition)
7 Flammable solids Category 2 (a casting) Flame Warning Flammable solid UNRTDG Class: 4.1; PG III
8 Self-reactive substances and Not classified - - - Classified in UNRTDG Class: 4.1 or 4.1
mixtures
9 Pyrophoric liquids Not applicable - - - Solid (GHS definition)
10 Pyrophoric solids Not classified - - - UNRTDG Class: 4.2 or 4.1
11 Self-heating substances and Self-heating in large
mixtures Category 2 (scrap) Flame Warning quantities; may UNRTDG Class: 4.2, PGⅢ
catch fire
12 Substances and mixtures, which
in contact with water, emit Not applicable - - - The chemical structure of the substance does not contain metals or metaloids(B, Si, P, Ge, As, Se, Sn, Sb, Te, Bi, Po, At).
flammable gases
13 Oxidizing liquids Not applicable - - - Solid (GHS definition)
14 Oxidizing solids Not classified - - - UNRTDG Class: 4.2 or 4.1
15 Organic peroxides Not applicable - - - Containing no -0-0- structure
16 Corrosive to metals Not classified - - - UNRTDG Class: 4.2 or 4.1
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) Classification not
- - - No data available
possible
1 Acute toxicity (dermal) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: gas) Not applicable - - - Solid (GHS definition)
1 Acute toxicity (inhalation: vapour) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: dust, Classification not
- - - No data available
mist) possible
2 Skin corrosion / irritation Classification not
- - - No data available
possible
3 Serious eye damage / eye
Classification not
irritation - - - No data available
possible
4 Respiratory/skin sensitizer Respiratory
sensitization:
Classification not
- - - No data available
possible; Skin
sensitization:
Classification not
5 Germ cell mutagenicity possible
Classification not
- - - No data available
possible
6 Carcinogenicity Classification not
- - - No data available
possible
7 Toxic to reproduction Classification not
- - - No data available
possible
8 Specific target organs/systemic Classification not - - - No data available.
toxicity following single exposure possible
9 Specific target organs/systemic Classification not
toxicity following repeated - - - No data available
exposure
possible
10 Aspiration hazard Classification not
- - - No data available
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Classification not
- - - No data available
environment (acute) possible
11 Hazardous to the aquatic Classification not
- - - No data available.
environment (chronic) possible
GHS Classification
ID1385 Calcium acetylide
CAS 75-20-7 Date Classified： 2006/11/20 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not applicable - - - There are no chemical groups associated with explosive properties present in the molecules.
2 Flammable gases Not applicable - - - Solid (GHS definition)
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not applicable - - - Solid (GHS definition)
5 Gases under pressure Not applicable - - - Solid (GHS definition)
6 Flammable liquids Not applicable - - - Solid (GHS definition)
7 Flammable solids Not classified - - - UNRTDG Class: 4.3. Non-combustible under dry condition (Hommel, 1991) Card No.243)
8 Self-reactive substances and Not applicable - - - There are no chemical groups associated with explosive or self-reactive properties present in the molecule.
mixtures
9 Pyrophoric liquids Not applicable - - - Solid (GHS definition)
10 Pyrophoric solids Not classified - - - UNRTDG Class: 4.3. Non-combustible under dry condition (Hommel, 1991, Card No.243)
11 Self-heating substances and Not classified - - - UNRTDG Class: 4.3. Non-combustible under dry condition (Hommel, 1991, Card No.243)
mixtures
12 Substances and mixtures, which Since reaction with water changes by the purity, particle form, and particle diameter of a sample, a given study is carried
in contact with water, emit In contact with out and it will be classified into one of the followings. As a result of an examination, the sample with the tendency of
flammable gases Classification not water releases reacting violently with the water and generating gas to ignite spontaneously or with the flammable/combustible gas
possible (Category 1 or Flame Danger flammable gases generating speed of 10L/minute/kg or higher (equivalent to PG I) is classified into category 1, and the sample with the
Category 2) which may ignite tendency of reacting rapidly with the water and indicating spontaneous combustibility but with the flammable/combustible
spontaneously gas generating speed that is under 10L/minute/kg and is 20L/hour/kg or higher (equivalent to PG II) is classified into
category 2.
13 Oxidizing liquids Not applicable - - - Solid (GHS definition)
14 Oxidizing solids Not applicable - - - Containing no oxygen , chlorine and fluorine.
15 Organic peroxides Not applicable - - - Inorganic substance
16 Corrosive to metals Not classified - - - UNRTDG Class: 4.3
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) Classification not
- - - No data available
possible
1 Acute toxicity (dermal) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: gas) Not applicable - - - Solid (GHS definition)
1 Acute toxicity (inhalation: vapour) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: dust, Classification not
- - - No data available
mist) possible
2 Skin corrosion / irritation Causes severe skin
Category 1A-1C Corrosion Danger burns and eye It was set as Category 1A-1C from description that it is the caustic (ICSC (J), (1995), and SITTIG (4th, 2002)).
damage
3 Serious eye damage / eye
Causes serious eye
irritation Category 1 Corrosion Danger It is set as Category 1 from description that it is caustic (ICSC(J)(1995) and SITTIG (4th, 2002)).
damage
4 Respiratory/skin sensitizer Respiratory
sensitization:
Classification not Respirator: no data available.
- - -
possible; Skin Skin: since data is insufficient, it cannot classify.
sensitization:
Classification not
5 Germ cell mutagenicity possible
Classification not
- - - No data available
possible
6 Carcinogenicity Classification not
- - - No data available
possible
7 Toxic to reproduction Classification not
- - - No data available
possible
8 Specific target organs/systemic May cause damage From the description in ICSC (J) (1995) and SITTIG (4th, 2002) that it is the caustic, and the description in ICSC (J)
Category 2 (respiratory
toxicity following single exposure Health hazard Warning to organs (1995), HSFS (2003) and SITTIG (4th, 2002) that pulmonary edemas is caused when inhaling it, and respiratory system was
organs)
(respiratory organs) judged as target organ, so it was considered as Category 2 .
9 Specific target organs/systemic Classification not
toxicity following repeated - - - Classification not possible due to lack of data
exposure
possible
10 Aspiration hazard Classification not
- - - No data available
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Classification not
- - - No data available
environment (acute) possible
11 Hazardous to the aquatic Classification not
- - - No data available.
environment (chronic) possible
GHS Classification
ID1386 tricalcium diphosphide
CAS 1305-99-3 Date Classified： 2006/12/18 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not applicable - - - There are no chemical groups associated with explosive properties present in the molecules.
2 Flammable gases Not applicable - - - Solid (GHS definition)
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not applicable - - - Solid (GHS definition)
5 Gases under pressure Not applicable - - - Solid (GHS definition)
6 Flammable liquids Not applicable - - - Solid (GHS definition)
7 Flammable solids Not classified - - - UNRTDG Class: 4.3 and non-combustible (ICSC(J), 2002)
8 Self-reactive substances and Not applicable - - - There are no chemical groups associated with explosive or self-reactive properties present in the molecule.
mixtures
9 Pyrophoric liquids Not applicable - - - Solid (GHS definition)
10 Pyrophoric solids Not classified - - - UNRTDG Class: 4.3 Non-combustible (ICSC (J), 2002)
11 Self-heating substances and Not classified - - - UNRTDG Class: 4.3 Non-combustible (ICSC(J), 2002)
mixtures
12 Substances and mixtures, which In contact with
in contact with water, emit water releases
flammable gases Category 1 Flame Danger flammable gases UNRTDG Class: 4.3; PG I
which may ignite
spontaneously
13 Oxidizing liquids Not applicable - - - Solid (GHS definition)
14 Oxidizing solids Not applicable - - - Containing no oxygen , chlorine and fluorine.
15 Organic peroxides Not applicable - - - Containing no -0-0- structure
16 Corrosive to metals Not classified - - - UNRTDG Class: 4.3
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) Classification not
- - - No data available
possible
1 Acute toxicity (dermal) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: gas) Not applicable - - - Solid (GHS definition)
1 Acute toxicity (inhalation: vapour) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: dust, Classification not
- - - No data available
mist) possible
2 Skin corrosion / irritation Category 2 Exclamation mark Warning Causes skin It was set as Category 2 from description that the skin is stimulated (ICSC (J) (2002)).
3 Serious eye damage / eye irritationserious eye From description that the eye is stimulated (ICSC (J) (2002)), it judged that there was eye irritation. And it was set as
Causes
irritation Category 2A-2B Exclamation mark Warning
irritation Category 2A-2B. Detailed categorization was not made.
4 Respiratory/skin sensitizer Respiratory
sensitization:
Classification not
- - - No data available
possible; Skin
sensitization:
Classification not
5 Germ cell mutagenicity possible
Classification not
- - - No data available
possible
6 Carcinogenicity Classification not
- - - No data available
possible
7 Toxic to reproduction Classification not
- - - No data available
possible
8 Specific target organs/systemic May cause
toxicity following single exposure respiratory irritation
Category 3 (respiratory or may cause From description in ICSC (J) (2002) that the airway is stimulated, it was judged that it has airway stimulativeness and was
Exclamation mark Warning
tract irritation) drowsiness and considered as Category 3.
dizziness
(respiratory tract
9 Specific target organs/systemic Classification not irritation)
toxicity following repeated - - - No data available
exposure
possible
10 Aspiration hazard Classification not
- - - No data available
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Classification not
- - - No data available
environment (acute) possible
11 Hazardous to the aquatic Classification not
- - - No data available.
environment (chronic) possible
GHS Classification
ID1387 Magnesium
CAS 7439-95-4 Date Classified： 2006/12/18 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not applicable - - - There are no chemical groups associated with explosive properties present in the molecules.
2 Flammable gases Not applicable - - - Solid (GHS definition)
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not applicable - - - Solid (GHS definition)
5 Gases under pressure Not applicable - - - Solid (GHS definition)
6 Flammable liquids Not applicable - - - Solid (GHS definition)
7 Flammable solids Not classified - - - UNRTDG Class: 4.3, Subsidiary risks Class: Class: 4.2
8 Self-reactive substances and Not applicable - - - There are no chemical groups associated with explosive or self-reactive properties present in the molecule.
mixtures
9 Pyrophoric liquids Not applicable - - - Solid (GHS definition)
10 Pyrophoric solids Classification not
- - - No data available. UNRTDG Subsidiary risks Class: 4.2
possible
11 Self-heating substances and Classification not
- - - No data available. UNRTDG Subsidiary risks Class: Class: 4.2
mixtures possible
12 Substances and mixtures, which In contact with
in contact with water, emit Classification not water releases
flammable gases No data (since reaction with water changes with purity, particle form, and particle diameter, it cannot be judged which
possible (Category 1，2 Flame Danger flammable gases
category it belongs unless a routine testing is carried out.)
or 3) which may ignite
spontaneously
13 Oxidizing liquids Not applicable - - - Solid (GHS definition)
14 Oxidizing solids Not applicable - - - Containing no oxygen , chlorine and fluorine.
15 Organic peroxides Not applicable - - - Containing no -0-0- structure
16 Corrosive to metals Not classified - - - UNRTDG Class: 4.3, Subsidiary risks Class: Class: 4.2
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) Classification not
- - - No data available
possible
1 Acute toxicity (dermal) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: gas) Not applicable - - - Solid (GHS definition)
1 Acute toxicity (inhalation: vapour) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: dust, Classification not
- - - No data available
mist) possible
2 Skin corrosion / irritation Causes skin It was set as Category 2 from description that the skin is stimulated (HSDB (Access on Jun 2005), HSFS (1999), SITTIG
Category 2 Exclamation mark Warning
irritation (4th, 2002)).
3 Serious eye damage / eye
Causes serious eye It was set as Category 2A-2B from description that the eye is stimulated (HSDB (Access on Jun 2005), HSFS (1999), and
irritation Category 2A-2B Exclamation mark Warning
irritation SITTIG (4th, 2002)). Since there was no data about reparable, detailed categorization did not carry out.
4 Respiratory/skin sensitizer Respiratory
sensitization:
Classification not
- - - No data available
possible; Skin
sensitization:
Classification not
5 Germ cell mutagenicity possible
Classification not
- - - No data available
possible
6 Carcinogenicity Classification not
- - - Classification not possible due to lack of data
possible
7 Toxic to reproduction Classification not
- - - No data available
possible
8 Specific target organs/systemic May cause
toxicity following single exposure respiratory irritation
Category 3 (respiratory or may cause From description in HSDB (Access on Jun 2005), HSFS (1999), and SITTIG (4th, 2002), that the respiratory organ, lungs,
Exclamation mark Warning
tract irritation) drowsiness and and a respiratory tract is stimulated, it was judged that it has respiratory irritant and was considered as Category 3.
dizziness
(respiratory tract
9 Specific target organs/systemic Classification not irritation)
toxicity following repeated - - - Classification not possible due to lack of data
exposure
possible
10 Aspiration hazard Classification not
- - - No data available
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Classification not
- - - Insufficient data available.
environment (acute) possible
11 Hazardous to the aquatic May cause long
environment (chronic) lasting harmful
Category 4 - - Classified into Category 4, since it is metal and the behavior in the water is unknown, though L(E) C50 0.3mg/L (RTECS, 2005), and it cannot be classified since data is
- - -
mist) possible insufficient.
2 Skin corrosion / irritation Category 2 Exclamation mark Warning Causes skin It was set as Category 2 from description that the skin is stimulated (HSDB (2005), HSFS (2002)).
3 Serious eye damage / eye irritation It was set as Category 2A-2B from description that the mucosa is stimulated (HSDB (2005)), and description which
Causes serious eye
irritation Category 2A-2B Exclamation mark Warning suggests a possibility of stimulating the eye (HSFS (2002)). Since the grade and recovery nature of the stimulus were
irritation
unknown, detailed categorization was not made.
4 Respiratory/skin sensitizer Respiratory
sensitization:
Classification not
- - - No data available
possible; Skin
sensitization:
Classification not
5 Germ cell mutagenicity possible There was a negative result by the micronucleus test which uses the erythrocytes of the rat and a mouse, which is an in
Not classified - - -
vivo mutagenicity test using a somatic (IRIS, 2005). So it is classified as the out of the Category.
6 Carcinogenicity Not classified - - - Since it was classified into NL according to EPA, it carried out the outside of Category.
7 Toxic to reproduction Classification not
- - - Classification not possible due to lack of data
possible
8 Specific target organs/systemic May cause
toxicity following single exposure respiratory irritation
From description in HSDB (2005) that the mucosa is stimulated, and description in HSFS (2002) that nose and throat may
Category 3 (respiratory or may cause
Exclamation mark Warning be stimulated by inhalation and coughing and wheezing may be started, it was judged that it has respiratory irritant and was
tract irritation) drowsiness and
considered as Category 3.
dizziness
(respiratory tract
9 Specific target organs/systemic irritation) It cannot be classifed because of insufficient data.
toxicity following repeated Classification not Since there was description that although the effect was observed in the thyroid in the rat oral study, in evidence of
exposure - - -
possible human occupational exposure, change of thyroid hormones or THS was not observed, and that human is not sensitive than
rat in thyroid functions disturbances (IRIS, 2005), it was not considered that the serious toxic effect for the human thyroid
10 Aspiration hazard Classification not
- - - No data available
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Classification not
- - - Insufficient data available.
environment (acute) possible
11 Hazardous to the aquatic Classification not
- - - Classification not possible due to lack of data
environment (chronic) possible
GHS Classification
ID1394 dipotassium peroxide
CAS 17014-71-0 Date Classified： 2006/8/18 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not classified - - - UNRTDG No. 1491, Class: 5.1
2 Flammable gases Not applicable - - - Solid (GHS definition)
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not applicable - - - Solid (GHS definition)
5 Gases under pressure Not applicable - - - Solid (GHS definition)
6 Flammable liquids Not applicable - - - Solid (GHS definition)
7 Flammable solids UNRTDG Class: 5.1
Not classified - - -
Non-combustible
8 Self-reactive substances and Not applicable - - - Classified in oxidizing solids
mixtures
9 Pyrophoric liquids Not applicable - - - Solid (GHS definition)
10 Pyrophoric solids Not classified - - - UNRTDG No. 1491, Class: 5.1
11 Self-heating substances and Not classified - - - UNRTDG Number:1491, Class: 5.1
mixtures
12 Substances and mixtures, which
in contact with water, emit Not classified - - - UNRTDG No. 1491, Class: 5.1
flammable gases
13 Oxidizing liquids Not applicable - - - Solid (GHS definition)
14 Oxidizing solids May cause fire or
Category 1 Flame over circle Danger explosion; strong UNRTDG Class: 5.1; PG I
oxidizer
15 Organic peroxides Not applicable - - - Inorganic substance
16 Corrosive to metals Classification not
- - - No data available
possible
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) Classification not
- - - No data available
possible
1 Acute toxicity (dermal) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: gas) Not applicable - - - Solid (GHS definition)
1 Acute toxicity (inhalation: vapour) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: dust, Classification not
- - - No data available
mist) possible
2 Skin corrosion / irritation Causes skin "If touched to solid, a burned will be caused on the skin."(HSDB (2005)) From this statement, it judged that there was skin
Category 2 Exclamation mark Warning
irritation irritation and was set as Category 2.
3 Serious eye damage / eye Causes serious eye From statement with "dust stimulates the eye, and solid causes a burn to the eye"(HSDB (2005)), it judged that there is
irritation Category 2A-2B Exclamation mark Warning
irritation eye irritation. And it is set as Category 2A-2B.
4 Respiratory/skin sensitizer Respiratory
sensitization:
Classification not
- - - No data available
possible; Skin
sensitization:
Classification not
5 Germ cell mutagenicity possible
Classification not
- - - No data available
possible
6 Carcinogenicity Classification not
- - - No data available
possible
7 Toxic to reproduction Classification not
- - - No data available
possible
8 Specific target organs/systemic May cause
toxicity following single exposure respiratory irritation
Category 3 (respiratory or may cause From the description in HSDB (2005) that "dust stimulates a nose and a throat. A coughing and shortness of breath may
Exclamation mark Warning
tract irritation) drowsiness and be caused when inhaling.", it was judged that it has respiratory irritant and was considered as Category 3.
dizziness
(respiratory tract
9 Specific target organs/systemic Classification not irritation)
toxicity following repeated - - - No data available
exposure
possible
10 Aspiration hazard Classification not
- - - No data available
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Classification not
- - - No data available
environment (acute) possible
11 Hazardous to the aquatic Classification not
- - - No data available.
environment (chronic) possible
GHS Classification
ID1395 Potassium nitrate
CAS 7757-79-1 Date Classified： 2006/7/24 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not classified - - - UNRTDG Class: 5.1
2 Flammable gases Not applicable - - - Solid (GHS definition)
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not applicable - - - Solid (GHS definition)
5 Gases under pressure Not applicable - - - Solid (GHS definition)
6 Flammable liquids Not applicable - - - Solid (GHS definition)
7 Flammable solids Not classified - - - Non-combustible (ICSC (J) (2001))
8 Self-reactive substances and Not applicable - - - Classified in oxidizing solids
mixtures
9 Pyrophoric liquids Not applicable - - - Solid (GHS definition)
10 Pyrophoric solids Not classified - - - Non-combustible (ICSC (J), 2001)
11 Self-heating substances and Not classified - - - Non-combustible (ICSC(J), 2001)
mixtures
12 Substances and mixtures, which
in contact with water, emit Not classified - - - UNRTDG Class: 5.1
flammable gases
13 Oxidizing liquids Not applicable - - - Solid (GHS definition)
14 Oxidizing solids Warning May intensify fire;
Category 3 Flame over circle UNRTDG Class: 5.1; PG III
oxidizer
15 Organic peroxides Not applicable - - - Inorganic substance
16 Corrosive to metals Not classified - - - UNRTDG Class: 5.1
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) May be harmful if We calculated based on the rat LD50 values : 3750mg/kg (RTECS, 2005, IUCLID, 2000), 3540mg/kg (RTECS, 2005) and
Category 5 - Warning
swallowed 3015mg/kg (IUCLID, 2000). The calculated value was 3229mg/kg, so the substance was classified as Category 5.
1 Acute toxicity (dermal) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: gas) Not applicable - - - Solid (GHS definition)
1 Acute toxicity (inhalation: vapour) Classification not - - - No data available
possible
1 Acute toxicity (inhalation: dust, Classification not
- - - No data available
mist) possible
2 Skin corrosion / irritation Category 2 Exclamation mark Warning Causes skin It was set as Category 2 from description that the skin is stimulated (ICSC (J) (2001), HSFS (2004), SITTIG (4th, 2002)).
3 Serious eye damage / eye irritation
Causes serious eye It was set as Category 2A-2B from description that the eye is stimulated (ICSC (J) (2001), HSFS (2004), and SITTIG (4th,
irritation Category 2A-2B Exclamation mark Warning
irritation 2002)). Since there was no data about reparable, detailed categorization was not made.
4 Respiratory/skin sensitizer Respiratory
sensitization:
Classification not
- - - No data available
possible; Skin
sensitization:
Classification not
5 Germ cell mutagenicity possible
Classification not
- - - Classification not possible due to lack of data
possible
6 Carcinogenicity Classification not
- - - No data available
possible
7 Toxic to reproduction Although there is no description on general toxicity in parent animals, based on the descriptions that increase in
Suspected of
miscarriage and fetal death were observed in water drinking administration tests using guinea pigs (RTECS (2005), IUCLID
Category 2 Health hazard Warning damaging fertility or
(2000), HSDB (2005)) and that malformation was observed in baby animals in two-generation reproduction studies by mixed
the undorn child
feeds administering using rats (IUCLID (2000), HSDB (2005)). So it was set as Category 2.
8 Specific target organs/systemic May cause damage
toxicity following single exposure to organs (blood
From the description in RTECS (2005) that methemoglobinemia was observed in the oral administrations test in rats, and
Category 2 (blood system); May cause
the description in ICSC (J) (2001), HSFS (2004), and SITTIG (4th, 2002) that methemoglobin may be generated, blood is
system); Category 3 Health hazard; respiratory irritation
Warning considered as target organ and considered as Category 2. Moreover, from description in ICSC (J) (2001), HSFS (2004), and
(respiratory tract Exclamation mark or may cause
SITTIG (4th, 2002) that the airway is stimulated, it was judged that it has airway stimulativeness and was considered as
irritation) drowsiness and
Category 3.
dizziness
(respiratory tract
9 Specific target organs/systemic irritation) damage
May cause
toxicity following repeated to organs (blood) Since there was description that the symptoms of methemoglobinemia were observed in oral administration for 12 days in
exposure Category 2 (blood) Health hazard Warning
through prolonged or humans (HSDB (2005)), blood was considered to be target organ and classified into Category 2.
repeated exposure
10 Aspiration hazard Classification not
- - - No data available
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Not classified - - - It considered as the outside of Category from 48-hour TLm=490mg/L of Crustacea (Daphnia magna ) (IUCLID, 2000).
environment (acute)
11 Hazardous to the aquatic
environment (chronic)
Not classified - - - Since not water-insoluble (water solubility=1g/2.8mL（PHYSPROP Database、2005）) and acute toxicity is low.
GHS Classification
ID1396 Sodium nitrate
CAS 7631-99-4 Date Classified： 2006/6/20 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not classified - - - UNRTDG Class: 5.1
2 Flammable gases Not applicable - - - Solid (GHS definition)
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not applicable - - - Solid (GHS definition)
5 Gases under pressure Not applicable - - - Solid (GHS definition)
6 Flammable liquids Not applicable - - - Solid (GHS definition)
7 Flammable solids Not classified - - - Non-combustible (ICSC (J) (2001))
8 Self-reactive substances and Not applicable - - - Classified in oxidizing solids
mixtures
9 Pyrophoric liquids Not applicable - - - Solid (GHS definition)
10 Pyrophoric solids Not classified - - - Non-combustible (ICSC (J), 2001)
11 Self-heating substances and Not classified - - - Not combustible (ICSC(J) (2001))
mixtures
12 Substances and mixtures, which
in contact with water, emit Not classified - - - UNRTDG Class: 5.1
flammable gases
13 Oxidizing liquids Not applicable - - - Solid (GHS definition)
14 Oxidizing solids Warning May intensify fire;
Category 3 Flame over circle UNRTDG Class: 5.1; PG III
oxidizer
15 Organic peroxides Not applicable - - - Inorganic substance
16 Corrosive to metals Not classified - - - UNRTDG Class: 5.1
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) We calculated based on the rat LD50 values : 1267mg/kg (RTECS, 2005, IUCLID, 2000), 3430mg/kg, 5200mg/kg and
Category 4 Exclamation mark Warning Harmful if swallowed
3236mg/kg (IUCLID, 2000). The calculated value was 1964mg/kg, so the substance was classified as Category 4.
1 Acute toxicity (dermal) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: gas) Not applicable - - - Solid (GHS definition)
1 Acute toxicity (inhalation: vapour) Classification not - - - No data available
possible
1 Acute toxicity (inhalation: dust, Classification not
- - - No data available
mist) possible
2 Skin corrosion / irritation Causes skin The specific case etc. was not shown. But it was set as category 2 from there is the description that the skin is stimulated
Category 2 Exclamation mark Warning
irritation as effect of short-term exposure (ICSC (J) (2001)).
3 Serious eye damage / eye Causes serious eye It was set as Category 2A-2B. Although there is description that an eye is stimulated as effect of short-term exposure in
irritation Category 2A-2B Exclamation mark Warning
irritation ICSC (J) and (2001), and the report of a concrete case was not indicated.
4 Respiratory/skin sensitizer Respiratory
sensitization:
Classification not
- - - No data available
possible; Skin
sensitization:
Classification not
5 Germ cell mutagenicity possible Suspected of
causing genetic
defects (state route There is a positive result by the micronucleus test which used the mouse bone marrow cells and the chromosome
of exposure if it is aberration test using bone marrow cells of rat and a mouse, which in vivo mutagenicity test using somatic cell (RTECS,
Category 2 Health hazard Warning
conclusively proven 2005). And there was no positive result in the in vivo genotoxicity test using a germ cells. So it is classified into Category
that no other routes 2.
of exposure cause
the hazard)
6 Carcinogenicity Classification not
- - - Since it is not evaluated in the institution indicated in the technical indicator, it cannot classify.
possible
7 Toxic to reproduction Classification not
- - - Classification not possible due to lack of data
possible
8 Specific target organs/systemic May cause damage From the description in RTECS (2005) that methemoglobinemia was observed in the oral administration examination using
Category 2 (blood
toxicity following single exposure Health hazard Warning to organs (blood the pig and intake of humans, and the description in ICSC (J) (2001) that methemoglobin may be generated by short-term
system)
system) exposure, it was judged that blood was target organ, and it was considered as Category 2.
9 Specific target organs/systemic Classification not
toxicity following repeated - - - Classification not possible due to lack of data
exposure
possible
10 Aspiration hazard Classification not
- - - No data available
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic
environment (acute) Not classified - - - It considered as the outside of Category from 96-hour LC50=5800mg/L of fishes (King salmon) (ECETOC TR 91 and 2003).
11 Hazardous to the aquatic Not classified - - - Since not water-insoluble (aqueous solubility =7.30×105mg/L（PHYSPROP Database、2005）） and acute toxicity is low.
environment (chronic)
GHS Classification
ID1397 Ammonium nitrate
CAS 6484-52-2 Date Classified： 2006/3/23 (Environmental Hazards: 2006/2/10)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not classified - - - UNRTDG Class: 5.1
2 Flammable gases Not applicable - - - Solid (GHS definition)
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not applicable - - - Solid (GHS definition)
5 Gases under pressure Not applicable - - - Solid (GHS definition)
6 Flammable liquids Not applicable - - - Solid (GHS definition)
7 Flammable solids Not classified - - - Non-combustible (ICSC (J) (2001))
8 Self-reactive substances and Not applicable - - - Classified in oxidizing solids
mixtures
9 Pyrophoric liquids Not applicable - - - Solid (GHS definition)
10 Pyrophoric solids Not classified - - - Non-combustible (ICSC (J), 2001)
11 Self-heating substances and Not classified - - - Not combustible (ICSC(J) (2001))
mixtures
12 Substances and mixtures, which
in contact with water, emit Not applicable - - - The chemical structure of the substance does not contain metals or metaloids(B, Si, P, Ge, As, Se, Sn, Sb, Te, Bi, Po, At).
flammable gases
13 Oxidizing liquids Not applicable - - - Solid (GHS definition)
14 Oxidizing solids Warning May intensify fire;
Category 3 Flame over circle UNRTDG Class: 5.1; PG III
oxidizer
15 Organic peroxides Not applicable - - - Inorganic substance
16 Corrosive to metals Not classified - - - UNRTDG Class: 5.1
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) We calculated based on the rat LD50 values : 2217mg/kg (RTECS, 2005, IUCLID, 2000), 2800mg/kg, 2462mg/kg,
May be harmful if
Category 5 - Warning 2950mg/kg, 5600mg/kg and 4820mg/kg (IUCLID, 2000), and 4500mg/kg (HSDB, 2005)s. The calculated value was 2798
swallowed
mg/kg, so the substance was classified as Category 5.
1 Acute toxicity (dermal) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: gas) Not applicable - - - Solid (GHS definition)
1 Acute toxicity (inhalation: vapour) Classification not - - - No data available
possible
1 Acute toxicity (inhalation: dust, Not classified - - - Not classified because of "SPECIES: Rat; ENDPOINT: LC50(4hr.; VALUE: >88.8mg/L"(IUCLID, 2000)
mist)
2 Skin corrosion / irritation There is description that skin irritation was not admitted by the test using the rabbit (IUCLID (2000)), it was set to
Causes skin
Category 2 Exclamation mark Warning category 2 since ICSC (J) (2001), HSDB (2005), HSFS (1998), and SITTIG (4th, 2002) had no report of specific cases but
irritation
there is description that the skin of what is indicated and is not may be stimulated.
3 Serious eye damage / eye Although change of the eye which corresponds to criteria for diagnosis of irritation by the eye irritation tests using the
Causes serious eye
irritation Category 2A-2B Exclamation mark Warning rabbit indicated to ECETOC TR 48 (1992) is not admitted. But there is description that there is stimulativeness to the
irritation
human eye in any of ICSC(J) (2001), HSDB (2005), HSFS (1998), and SITTIG (2002). So it was set as Category 2A-2B.
4 Respiratory/skin sensitizer Respiratory
sensitization:
Classification not
- - - No data available
possible; Skin
sensitization:
Classification not
5 Germ cell mutagenicity possible
Classification not
- - - Classification not possible due to lack of data
possible
6 Carcinogenicity Classification not
- - - No data available
possible
7 Toxic to reproduction Classification not
- - - Classification not possible due to lack of data
possible
8 Specific target organs/systemic May cause damage
toxicity following single exposure to organs (blood
From the description in RTECS (2005) that methemoglobinemia was observed in oral administration examination in rat, and
Category 2 (blood system); May cause
the description in ICSC (J) (2001), HSDB (2005), HSFS (1998), and SITTIG (4th, 2002) that methemoglobin or abnormal
system); Category 3 Health hazard; respiratory irritation
Warning hemoglobin may be generated, it was judged that blood was target organ, and it was considered as Category 2. Moreover,
(respiratory tract Exclamation mark or may cause
from the description in ICSC (J) (2001), HSDB (2005), HSFS (1998), and SITTIG (4th, 2002) that the airway is stimulated, it
irritation) drowsiness and
was judged that it has airway stimulativeness and was considered as Category 3.
dizziness
(respiratory tract
9 Specific target organs/systemic Classification not irritation)
toxicity following repeated - - - Classification not possible due to lack of data
exposure
possible
10 Aspiration hazard Classification not
- - - No data available
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Not classified - - - It carried out the outside of Category from 96-hour LC50=5657mg/L of fishes (Rainbow trout) (IUCLID, 2000).
environment (acute)
11 Hazardous to the aquatic
environment (chronic)
Not classified - - - Since not water-insoluble (water solubility=118.3g/100cc（HSDB、2004)) and acute toxicity is low.
GHS Classification
ID1398 Calcium hypochlorite
CAS 7778-54-3 Date Classified： 2006/6/20 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not classified - - - UNRTDG Class: 5.1
2 Flammable gases Not applicable - - - Solid (GHS definition)
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not applicable - - - Solid (GHS definition)
5 Gases under pressure Not applicable - - - Solid (GHS definition)
6 Flammable liquids Not applicable - - - Solid (GHS definition)
7 Flammable solids Not classified - - - Non-combustible (NFPA (12th, 1997) p 49-34, Hommel, 1991) Card No.59, 59a, 59b ; etc.)
8 Self-reactive substances and Not applicable - - - Classified in oxidizing solids
mixtures
9 Pyrophoric liquids Not applicable - - - Solid (GHS definition)
10 Pyrophoric solids Not classified - - - Non-combustible (NFPA (12th, 1997) p 49-34, Hommel, 1991 Card No.59, 59a, 59b etc.)
11 Self-heating substances and Not classified - - - Non-combustible (NFPA (12th, 1997) p 49-34, Hommel(1991) Card No.59, 59a, 59b; etc.)
mixtures
12 Substances and mixtures, which
in contact with water, emit Not classified - - - UNRTDG Class: 5.1
flammable gases
13 Oxidizing liquids Not applicable - - - Solid (GHS definition)
14 Oxidizing solids May intensify fire;
Category 2 Flame over circle Danger UNRTDG Class: 5.1; PG II
oxidizer
15 Organic peroxides Not applicable - - - Inorganic substance
16 Corrosive to metals Not classified - - - UNRTDG Class: 5.1
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) Category 4 based on SPECIES: Rat; ENDPOINT: LD50; VALUE: :850mg/kg; REFERENCE SOURCE: RTECS (2005), IUCLID
Category 4 Exclamation mark Warning Harmful if swallowed
(2000), HSDB (2005)
1 Acute toxicity (dermal) May be harmful in It was set as Category 5 based on rabbit LD50 >2000mg/kg (IUCLID (2000)) and rabbit LDLo value: 2000mg/kg (RTECS
Category 5 - Warning
contact with skin (2005)).
1 Acute toxicity (inhalation: gas) Not applicable - - - Solid (GHS definition)
1 Acute toxicity (inhalation: vapour) Classification not - - - No data available
possible
1 Acute toxicity (inhalation: dust, Classification not
- - - No data available
mist) possible
2 Skin corrosion / irritation Causes severe skin It was set as category 1A-1C from the description that the degree of middle class or serious damage is caused on the skin
Category 1A-1C Corrosion Danger burns and eye (HSDB (2005)), the description that the skin is stimulated seriously (HSFS (2003)), and the description that skin
damage corrosivenesses was admitted by the test using the rabbit (IUCLID (2000)).
3 Serious eye damage / eye Causes serious eye It is set as Category 1 from description that an eye is seriously stimulated by contact (HSFS (2003)), and description that
irritation Category 1 Corrosion Danger
damage caustic is admitted by the eye irritation tests using the animal (IUCLID (2000)).
4 Respiratory/skin sensitizer Respiratory
sensitization: (Respiratory
(Respiratory (Respiratory
Classification not sensitization)-;
sensitization)-; (Skin sensitization)-; (Skin No data available
possible; Skin (Skin
sensitization)- sensitization)-
sensitization: sensitization)-
Classification not
5 Germ cell mutagenicity possible
Classification not
- - - Classification not possible due to lack of data
possible
6 Carcinogenicity Not classified - - - Since it was classified into the group 3 according to IARC, it carried out the outside of Category.
7 Toxic to reproduction Classification not Although there is a statement that any effect was not found in teratogenicity studies by oral administration to pregnant
- - -
possible rats (IUCLID (2000)), there was no statement which clearly denies the hazard in Priority 1. So it was unclassifiable.
8 Specific target organs/systemic May cause damage
Category 2 (respiratory From the description in HSDB (2005) and HSFS (2003) that it stimulates lungs by inhalation, pulmonary edemas may be
toxicity following single exposure Health hazard Warning to organs
organs) caused, and respiratory system is considered as target organ, so it was considered as Category 2.
(respiratory organs)
9 Specific target organs/systemic Classification not
toxicity following repeated - - - Classification not possible due to lack of data
exposure
possible
10 Aspiration hazard Classification not
- - - Insufficient data available.
possible
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Very toxic to
Category 1 Environment Warning It was classified into Category 1 from 96-hour LC50=0.049-0.16mg/L of fishes (Bluegill) (IUCLID, 2000).
environment (acute) aquatic life
11 Hazardous to the aquatic Very toxic to
Classified into Category 1, since acute toxicity was Category 1, though less bio-accumulative and behavior in water is
environment (chronic) Category 1 Environment Warning aquatic life with long
unknown.
lasting effects
GHS Classification
ID1399 Hydrogen
CAS 1333-74-0 Date Classified： 2006/7/24 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not applicable - - - Gas (GHS definition)
2 Flammable gases Extremely flammable
Category 1 - Danger Ignitable when in a mixture of 13% or less by volume in air. UNRTDG Class: 2.1
gas
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not classified - - - UNRTDG Class: 2.1
5 Gases under pressure Contains gas under
pressure; may
Compressed gas or explode if heated According to its physical state when packed, classified in;
Refrigerated liquefied Gas cylinder Warning Contains Compressed gas: entirely gaseous at -50℃ or critical temp 15000ppm (IUCLID, 2000) (4-hour equivalent
Not classified - - -
>7500ppm), .
1 Acute toxicity (inhalation: vapour) Not applicable - - - Gas (GHS definition)
1 Acute toxicity (inhalation: dust, Not applicable - - - Gas (GHS definition)
mist)
2 Skin corrosion / irritation Classification not
- - - No data available
possible
3 Serious eye damage / eye Classification not Although it was indicated that the toxic effects to an eye was not known by HSDB (2005), there being no data which
irritation - - -
possible negates hazard clearly in Priority1. So it cannot classify.
4 Respiratory/skin sensitizer Respiratory
sensitization:
Classification not
- - - No data available
possible; Skin
sensitization:
Classification not
5 Germ cell mutagenicity possible
Classification not
- - - No data available
possible
6 Carcinogenicity Classification not
- - - No data available
possible
7 Toxic to reproduction Classification not
- - - No data available
possible
8 Specific target organs/systemic Classification not
- - - No data available.
toxicity following single exposure possible
9 Specific target organs/systemic
Classification not
toxicity following repeated - - - No data available
exposure
possible
10 Aspiration hazard Not applicable - - - Gas (GHS definition)
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Classification not There is no data to classify. (Since it is a gaseous substance which does not dissolve into water easily due to ordinary
- - -
environment (acute) possible temperatures, the test is not carried out.)
11 Hazardous to the aquatic Classification not No data available. (Since it is a gaseous substance which does not easily dissolve into water in the ordinary temperature,
- - -
environment (chronic) possible the test has not been carried out.)
GHS Classification
ID1400 Ethyne
CAS 74-86-2 Date Classified： 2006/7/24 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not applicable - - - Gas (GHS definition)
2 Flammable gases Extremely flammable
Category 1 - Danger Ignitable when in a mixture of 13% or less by volume in air. UNRTDG Class: 2.1
gas
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not classified - - - The substance is a reducing agent (ICSC(J), 2003). UNRTDG Class: 2.1
5 Gases under pressure Contains gas under
Dissolved gas Gas cylinder Warning pressure; may Gas compressed and dissolved in the liquid phase solvent. (ICSC(J), 2003)
explode if heated
6 Flammable liquids Not applicable - - - Gas (GHS definition)
7 Flammable solids Not applicable - - - Gas (GHS definition)
8 Self-reactive substances and Not applicable - - - Gas (GHS definition)
mixtures
9 Pyrophoric liquids Not applicable - - - Gas (GHS definition)
10 Pyrophoric solids Not applicable - - - Gas (GHS definition)
11 Self-heating substances and Not applicable - - - Gas (GHS definition)
mixtures
12 Substances and mixtures, which
in contact with water, emit Not applicable - - - Gas (GHS definition)
flammable gases
13 Oxidizing liquids Not applicable - - - Gas (GHS definition)
14 Oxidizing solids Not applicable - - - Gas (GHS definition)
15 Organic peroxides Not applicable - - - Gas (GHS definition)
16 Corrosive to metals Not classified - - - UNRTDG Class: 2.1
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) Not applicable - - - Gas (GHS definition)
1 Acute toxicity (dermal) Not applicable - - - Gas (GHS definition)
1 Acute toxicity (inhalation: gas) It was considered as the outside of Category based on the description that it was nontoxic to humans below 25000ppm
Not classified - - -
(PATTY, 4th (1994)).
1 Acute toxicity (inhalation: vapour) Not applicable - - - Gas (GHS definition)
1 Acute toxicity (inhalation: dust, Not applicable - - - Gas (GHS definition)
mist)
2 Skin corrosion / irritation Classification not
- - - No data available
possible
3 Serious eye damage / eye Classification not
irritation - - - No data available
possible
4 Respiratory/skin sensitizer Respiratory
sensitization: (Respiratory
(Respiratory (Respiratory
Classification not sensitization)-;
sensitization)-; (Skin sensitization)-; (Skin No data available
possible; Skin (Skin
sensitization)- sensitization)-
sensitization: sensitization)-
Classification not
5 Germ cell mutagenicity possible
Classification not
- - - Classification not possible due to lack of data
possible
6 Carcinogenicity Classification not
- - - No data available
possible
7 Toxic to reproduction Classification not
- - - No data available
possible
8 Specific target organs/systemic May cause
toxicity following single exposure respiratory irritation
Category 3 (narcotic or may cause It was considered as Category 3 (anesthetic actions) from description in ACGIH (7th, 2001) and PATTY (4th, 1994) that an
Exclamation mark Warning
effects) drowsiness and anesthetic action is indicated at the high concentrations .
dizziness (narcotic
effects)
9 Specific target organs/systemic Classification not
toxicity following repeated - - - No data available
exposure
possible
10 Aspiration hazard Not applicable - - - Gas (GHS definition)
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Classification not
- - - Insufficient data available.
environment (acute) possible
11 Hazardous to the aquatic Classification not
- - - Classification not possible due to lack of data
environment (chronic) possible
GHS Classification
ID1401 Ethene
CAS 74-85-1 Date Classified： 2006/4/20 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not applicable - - - Gas (GHS definition)
2 Flammable gases Extremely flammable
Category 1 - Danger Ignitable when in a mixture of 13% or less by volume in air. UNRTDG Class: 2.1
gas
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not classified - - - UNRTDG Class: 2.1
5 Gases under pressure Contains gas under
pressure; may
Compressed gas or explode if heated According to its physical state when packed, classified in;
Refrigerated liquefied Gas cylinder Warning Contains Compressed gas: entirely gaseous at -50℃ or,
gas refrigerated gas; Refrigerated liquefied gas: partially liquid because of its low temperature
may cause
cryogenic burns or
6 Flammable liquids Not applicable - - injury - Gas (GHS definition)
7 Flammable solids Not applicable - - - Gas (GHS definition)
8 Self-reactive substances and Not applicable - - - Gas (GHS definition)
mixtures
9 Pyrophoric liquids Not applicable - - - Gas (GHS definition)
10 Pyrophoric solids Not applicable - - - Gas (GHS definition)
11 Self-heating substances and Not applicable - - - Gas (GHS definition)
mixtures
12 Substances and mixtures, which
in contact with water, emit Not applicable - - - Gas (GHS definition)
flammable gases
13 Oxidizing liquids Not applicable - - - Gas (GHS definition)
14 Oxidizing solids Not applicable - - - Gas (GHS definition)
15 Organic peroxides Not applicable - - - Gas (GHS definition)
16 Corrosive to metals Not classified - - - UNRTDG Class: 2.1
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) Not applicable - - - Gas (GHS definition)
1 Acute toxicity (dermal) Not applicable - - - Gas (GHS definition)
1 Acute toxicity (inhalation: gas) It was judged as the outside of Category. Based on the description that effect was not observed by 500000ppm 4-hour
Not classified - - - exposure in rat (ACGIH, 7th (2001)), and that effect was not observed by 57000ppm 4-hour exposure and 10000ppm 5-
hour exposure in rat (IARC 60 (1994)).
1 Acute toxicity (inhalation: vapour) Not applicable - - - Gas (GHS definition)
1 Acute toxicity (inhalation: dust, Not applicable - - - Gas (GHS definition)
mist)
2 Skin corrosion / irritation Not classified - - - From the description that the skin is not stimulated in PATTY (4th, 1994), it carried out the outside of category.
3 Serious eye damage / eye
irritation Not classified - - - From description that the eye is not stimulated (PATTY (4th, 1994)), it was set as the outside of Category.
4 Respiratory/skin sensitizer Respiratory
sensitization:
Classification not
- - - No data available
possible; Skin
sensitization:
Classification not
5 Germ cell mutagenicity possible There was a negative result (IARC 60, 1994) by the micronucleus test which used the bone marrow of the rat and mouse,
Not classified - - -
which is an in vivo mutagenicity test using a somatic. So it is classified as the out of the Category.
6 Carcinogenicity Since it is classified into a group 3 according to IARC and classified into A4 according to ACGIH, it considered as the
Not classified - - -
outside of Category.
7 Toxic to reproduction Classification not
- - - No data available
possible
8 Specific target organs/systemic May cause
toxicity following single exposure respiratory irritation
It is used as an anesthetic in the humans, and after the discontinuation of exposure, it was recovered promptly and impact
Category 3 (narcotic or may cause
Exclamation mark Warning on others was not observed (ACGIH (7th, 2001) and PATTY (4th, 1994)), it was observed as Category 3 (anesthetic
effects) drowsiness and
actions).
dizziness (narcotic
effects)
9 Specific target organs/systemic Since in the rat exposure test for 90 days (ACGIH 7th, 2001, DFGOT vol.10, 1998 and IARC 60, 1994) and the rat exposure
toxicity following repeated Not classified - - - test during two years (PATTY 4th, 1994 and IARC 60, 1994), a toxic effect was not observed at the high concentrations
exposure exceeding the range of guidance value in Category 2, either, it was carried out the outside of Category.
10 Aspiration hazard Not applicable - - - Gas (GHS definition)
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Harmful to aquatic
Category 3 - - It was classified into Category 3 from 72-hour ErC50=72mg/L of algae (Selenastrum) (SIDS, 1998).
environment (acute) life
11 Hazardous to the aquatic Harmful to aquatic
Classified into Category 3, since acute toxicity was Category 3 and rapid degradability is unknown, though supposed less
environment (chronic) Category 3 - - life with long lasting
bio-accumulative （log Kow=1.13 （PHYSPROP Database、2005））.
effects
GHS Classification
ID1402 Methane
CAS 74-82-8 Date Classified： 2007/3/15 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not applicable - - - Gas (GHS definition)
2 Flammable gases Extremely flammable
Category 1 - Danger Ignitable when in a mixture of 13% or less by volume in air. UNRTDG Class: 2.1
gas
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not classified - - - UNRTDG Class: 2.1
5 Gases under pressure Contains gas under
pressure; may
Compressed gas or explode if heated According to its physical state when packed, classified in;
Refrigerated liquefied Gas cylinder Warning Contains Compressed gas: entirely gaseous at -50℃ or,
gas refrigerated gas; Refrigerated liquefied gas: partially liquid because of its low temperature
may cause
cryogenic burns or
6 Flammable liquids Not applicable - - injury - Gas (GHS definition)
7 Flammable solids Not applicable - - - Gas (GHS definition)
8 Self-reactive substances and Not applicable - - - Gas (GHS definition)
mixtures
9 Pyrophoric liquids Not applicable - - - Gas (GHS definition)
10 Pyrophoric solids Not applicable - - - Gas (GHS definition)
11 Self-heating substances and Not applicable - - - Gas (GHS definition)
mixtures
12 Substances and mixtures, which
in contact with water, emit Not applicable - - - Gas (GHS definition)
flammable gases
13 Oxidizing liquids Not applicable - - - Gas (GHS definition)
14 Oxidizing solids Not applicable - - - Gas (GHS definition)
15 Organic peroxides Not applicable - - - Gas (GHS definition)
16 Corrosive to metals Not classified - - - UNRTDG Class: 2.1
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) Not applicable - - - Gas (GHS definition)
1 Acute toxicity (dermal) Not applicable - - - Gas (GHS definition)
1 Acute toxicity (inhalation: gas) It was considered as the outside of Category based on mouse LC50 (2 hours): >500000ppm (4 hour equivalent:
Not classified - - -
>353553ppm) (RTECS, Access on Aug 2005).
1 Acute toxicity (inhalation: vapour) Not applicable - - - Gas (GHS definition)
1 Acute toxicity (inhalation: dust, Not applicable - - - Gas (GHS definition)
mist)
2 Skin corrosion / irritation Not classified - - - From the description that the skin is not stimulated in ACGIH (7th, 2001), it carried out the outside of category.
3 Serious eye damage / eye
irritation Not classified - - - From description that the eye is not stimulated (ACGIH (7th, 2001)), it was set as the outside of Category.
4 Respiratory/skin sensitizer Respiratory
sensitization:
Classification not
- - - No data available
possible; Skin
sensitization:
Classification not
5 Germ cell mutagenicity possible
Classification not
- - - Classification not possible due to lack of data
possible
6 Carcinogenicity Classification not
- - - No data available
possible
7 Toxic to reproduction Classification not
- - - Classification not possible due to lack of data
possible
8 Specific target organs/systemic From description in ACGIH (7th, 2001) and PATTY (4th, 1994) that it has no hazard, and it was considered as the outside
Not classified - - -
toxicity following single exposure of Category.
9 Specific target organs/systemic
Based on description that there is no hazard (ACGIH (7th, 2001) and PATTY (4th, 1994)), it was carried out the outside of
toxicity following repeated Not classified - - -
exposure
Category.
10 Aspiration hazard Not applicable - - - Gas (GHS definition)
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Classification not
- - - No data available
environment (acute) possible
11 Hazardous to the aquatic Classification not
- - - No data available.
environment (chronic) possible
GHS Classification
ID1403 Ethane
CAS 74-84-0 Date Classified： 2007/3/15 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not applicable - - - Gas (GHS definition)
2 Flammable gases Extremely flammable
Category 1 - Danger Ignitable when in a mixture of 13% or less by volume in air. UNRTDG Class: 2.1
gas
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not classified - - - UNRTDG Class: 2.1
5 Gases under pressure Contains gas under
pressure; may
Compressed gas or explode if heated According to its physical state when packed, classified in;
Refrigerated liquefied Gas cylinder Warning Contains Compressed gas: entirely gaseous at -50℃ or,
gas refrigerated gas; Refrigerated liquefied gas: partially liquid because of its low temperature
may cause
cryogenic burns or
6 Flammable liquids Not applicable - - injury - Gas (GHS definition)
7 Flammable solids Not applicable - - - Gas (GHS definition)
8 Self-reactive substances and Not applicable - - - Gas (GHS definition)
mixtures
9 Pyrophoric liquids Not applicable - - - Gas (GHS definition)
10 Pyrophoric solids Not applicable - - - Gas (GHS definition)
11 Self-heating substances and Not applicable - - - Gas (GHS definition)
mixtures
12 Substances and mixtures, which
in contact with water, emit Not applicable - - - Gas (GHS definition)
flammable gases
13 Oxidizing liquids Not applicable - - - Gas (GHS definition)
14 Oxidizing solids Not applicable - - - Gas (GHS definition)
15 Organic peroxides Not applicable - - - Gas (GHS definition)
16 Corrosive to metals Not classified - - - UNRTDG Class: 2.1
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) Not applicable - - - Gas (GHS definition)
1 Acute toxicity (dermal) Not applicable - - - Gas (GHS definition)
1 Acute toxicity (inhalation: gas) Classification not
- - - No data available
possible
1 Acute toxicity (inhalation: vapour) Not applicable - - - Gas (GHS definition)
1 Acute toxicity (inhalation: dust, Not applicable - - - Gas (GHS definition)
mist)
2 Skin corrosion / irritation Classification not
- - - No data available
possible
3 Serious eye damage / eye Classification not
irritation - - - No data available
possible
4 Respiratory/skin sensitizer Respiratory
sensitization:
Classification not
- - - No data available
possible; Skin
sensitization:
Classification not
5 Germ cell mutagenicity possible
Classification not
- - - No data available
possible
6 Carcinogenicity Classification not
- - - No data available
possible
7 Toxic to reproduction Classification not
- - - No data available
possible
8 Specific target organs/systemic May cause
toxicity following single exposure respiratory irritation
Category 3 (narcotic or may cause From description in ACGIH (7th, 2001) and PATTY (4th, 1994) that anesthetic action or central nervous system depression
Exclamation mark Warning
effects) drowsiness and is observed at the high concentrations, it was judged that it has an anesthetic action and it was considered as Category 3.
dizziness (narcotic
effects)
9 Specific target organs/systemic Classification not
toxicity following repeated - - - No data available
exposure
possible
10 Aspiration hazard Not applicable - - - Gas (GHS definition)
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Classification not
- - - No data available
environment (acute) possible
11 Hazardous to the aquatic Classification not
- - - No data available.
environment (chronic) possible
GHS Classification
ID1404 Propane
CAS 74-98-6 Date Classified： 2006/7/24 (Environmental Hazards: 2006/3/31)
Physical Hazards Reference Manual： 2/10/2006
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Explosives Not applicable - - - Gas (GHS definition)
2 Flammable gases Extremely flammable
Category 1 - Danger Ignitable when in a mixture of 13% or less by volume in air. UNRTDG Class: 2.1
gas
3 Flammable aerosols Not applicable - - - Not aerosol products
4 Oxidizing gases Not classified - - - UNRTDG Class: 2.1
5 Gases under pressure Contains gas under
Liquefied gas Gas cylinder Warning pressure; may Critical temp: >-50℃ (Partially liquid at temperatures above -50℃)
explode if heated
6 Flammable liquids Not applicable - - - Gas (GHS definition)
7 Flammable solids Not applicable - - - Gas (GHS definition)
8 Self-reactive substances and Not applicable - - - Gas (GHS definition)
mixtures
9 Pyrophoric liquids Not applicable - - - Gas (GHS definition)
10 Pyrophoric solids Not applicable - - - Gas (GHS definition)
11 Self-heating substances and Not applicable - - - Gas (GHS definition)
mixtures
12 Substances and mixtures, which
in contact with water, emit Not applicable - - - Gas (GHS definition)
flammable gases
13 Oxidizing liquids Not applicable - - - Gas (GHS definition)
14 Oxidizing solids Not applicable - - - Gas (GHS definition)
15 Organic peroxides Not applicable - - - Gas (GHS definition)
16 Corrosive to metals Not classified - - - UNRTDG Class: 2.1
Health Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
1 Acute toxicity (oral) Not applicable - - - Gas (GHS definition)
1 Acute toxicity (dermal) Not applicable - - - Gas (GHS definition)
1 Acute toxicity (inhalation: gas) It was considered as the outside of Category based on guinea pigs LC50 (2 hours): >55000ppm (4 hour equivalent:
Not classified - - -
>38890ppm) (ACGIH 7th, 2001).
1 Acute toxicity (inhalation: vapour) Not applicable - - - Gas (GHS definition)
1 Acute toxicity (inhalation: dust, Not applicable - - - Gas (GHS definition)
mist)
2 Skin corrosion / irritation It was carried out the outside of category from the description that only slight erythema was acknowledged transiently in
Not classified - - -
the humans of ACIGH (7th, 2001), and the primary skin irritation can be disregarded.
3 Serious eye damage / eye Classification not
irritation - - - No data available
possible
4 Respiratory/skin sensitizer Respiratory
sensitization:
Classification not
- - - No data available
possible; Skin
sensitization:
Classification not
5 Germ cell mutagenicity possible
Classification not
- - - Classification not possible due to lack of data
possible
6 Carcinogenicity Classification not
- - - No data available
possible
7 Toxic to reproduction Classification not
- - - No data available
possible
8 Specific target organs/systemic May cause
toxicity following single exposure respiratory irritation
Category 3 (narcotic or may cause It was considered as Category 3 (anesthetic actions) from description in ACGIH (7th, 2001) that an anesthetic action is
Exclamation mark Warning
effects) drowsiness and indicated as effect on humans
dizziness (narcotic
effects)
9 Specific target organs/systemic Classification not
toxicity following repeated - - - No data available
exposure
possible
10 Aspiration hazard Not applicable - - - Gas (GHS definition)
Environmental Hazards
Hazard class Classification symbol signal word hazard statement Rational for the classification
11 Hazardous to the aquatic Classification not
- - - No data available
environment (acute) possible
11 Hazardous to the aquatic Classification not
- - - No data available.
environment (chronic) possible