Table xx. Whole-rock geochemistry of host shales in, near, and remote from barite mineralized areas
% %oxide%oxide
%oxide %oxide %oxide %oxide %oxide%element
Sample number Location TOC Na Mg Al Si P S K Ca
Fancy Hill -- shale host
DDH103 92 Fancy Hill 0.43 0.69 2.29 21.2 58.5 0.13 0.08 4.47 1.23
DDH103 99.5 Fancy Hill 0.52 0.72 2.51 21.4 57.7 0.15 0.13 4.54 0.88
DDH103 104.25 Fancy Hill 0.52 0.76 2.45 21.4 57.6 0.15 0.10 4.63 0.74
DDH103 112.5 Fancy Hill 0.42 0.61 2.57 20.7 59.4 0.11 0.58 4.64 0.60
DDH103 117 Fancy Hill 1.03 0.32 1.50 13.1 72.0 0.13 0.08 2.77 0.88
DDH103 134.5 Fancy Hill 0.42 0.56 1.75 14.6 70.1 0.08 2.29 3.19 0.43
DDH103 136 Fancy Hill 1.90 0.45 1.60 12.8 68.3 0.39 2.68 2.91 1.83
DDH103 138 Fancy Hill 0.44 0.66 1.81 15.1 68.7 0.08 2.86 3.31 0.44
DDH103 164.3 Fancy Hill 0.41 0.91 2.52 20.9 59.1 0.14 0.13 4.89 1.01
DDH103 165.5 Fancy Hill 0.57 0.77 2.38 17.3 62.5 0.12 0.73 3.70 1.74
DDH103 179.2 Fancy Hill 0.52 0.65 2.89 21.1 55.5 0.14 0.82 5.31 0.95
DDH103 181 Fancy Hill 0.53 0.63 2.81 22.0 53.8 0.39 0.80 5.61 1.12
DDH103 296 Fancy Hill 0.54 0.65 2.83 19.8 57.6 0.25 0.59 4.81 1.44
DDH103 302.3 Fancy Hill 0.53 0.69 2.94 20.4 56.9 0.14 0.94 5.12 0.85
DDH103 310 Fancy Hill 0.83 0.78 3.05 19.1 59.0 0.13 1.47 4.31 0.89
DDH103 357.2 Fancy Hill 1.44 0.87 2.79 19.0 59.8 0.20 4.45 4.39 1.24
DDH103 387.1 Fancy Hill 0.33 0.91 2.96 18.7 61.0 0.11 2.83 4.17 0.87
DDH103 388 Fancy Hill 0.32 0.92 2.88 17.9 61.9 0.11 2.82 3.90 0.33
DDH103 403.5 Fancy Hill 0.41 0.86 2.91 17.7 60.5 0.10 5.07 3.79 1.01
DDH119 196.5 Fancy Hill 0.26 0.31 2.22 13.7 63.7 0.06 3.38 1.99 2.23
DDH119 206 Fancy Hill 0.16 0.01 0.09 1.2 81.1 0.03 9.65 0.00 0.54
DDH40 335 Fancy Hill 0.35 0.88 2.87 18.6 60.8 0.11 2.48 4.21 0.82
DDH40 373.5 Fancy Hill 0.42 0.66 2.69 16.4 65.2 0.09 1.80 3.20 1.27
DDH40 375 Fancy Hill 0.46 0.46 2.31 14.7 69.0 0.06 1.64 2.97 0.57
DDH40 388.5 Fancy Hill 0.61 0.13 1.90 13.5 70.3 0.08 4.42 2.83 0.34
DDH40 390 Fancy Hill 0.14 0.31 2.16 15.7 69.1 0.05 0.54 3.38 0.30
DDH40 405 Fancy Hill 0.56 0.20 2.41 19.9 55.9 0.07 1.44 4.16 0.37
DDH40 405.5 Fancy Hill 1.82 0.17 2.84 19.8 55.5 0.07 3.28 4.37 0.33
MDDH5 220 1.34 0.17 1.34 18.0 71.5 0.09 3.02 3.65 0.63
MDDH5 227.5 2.69 0.18 0.90 18.6 57.9 0.15 2.87 3.80 0.01
average FH shale 0.70 0.56 2.31 17.5 62.7 0.13 2.13 3.84 0.86
n= 30
Fancy Hill -- barites
DDH103 339.5 Fancy Hill 0.44 0.77 2.68 17.2 58.6 0.09 2.49 3.86 0.45
DDH40 345 Fancy Hill 1.30 0.65 2.17 15.8 60.0 0.22 3.36 3.66 1.20
DDH40 358.5 Fancy Hill 0.65 0.32 1.19 9.5 70.0 0.08 5.13 2.15 1.29
average FH barite 0.79 0.58 2.01 14.2 62.9 0.13 3.66 3.23 0.98
Unmineralized basal Stanley -- near mineralization
GWS 1 G&W Roofing 0.46 0.68 2.78 18.7 60.6 0.20 0.03 2.92 1.07
GWS 2 G&W Roofing 0.54 0.88 2.24 17.2 65.1 0.18 0.03 3.08 0.68
GWS 3 G&W Roofing 0.65 0.81 2.73 22.8 54.9 0.34 0.03 4.34 0.97
GWS 4 G&W Roofing 0.53 0.94 2.51 20.7 60.0 0.16 0.10 4.03 0.74
GWS 5 G&W Roofing 0.73 0.76 2.72 20.5 58.0 0.17 0.01 4.07 0.77
GWS 6 G&W Roofing 0.69 0.71 2.50 17.0 63.2 0.17 0.03 2.69 1.11
GWS 7 G&W Roofing 0.57 0.79 2.36 21.4 58.8 0.23 0.03 3.99 0.87
GWS 8 G&W Roofing 0.75 0.70 2.49 21.5 58.2 0.20 0.04 4.06 0.79
GWS 9 G&W Roofing 0.44 0.89 2.26 19.9 62.2 0.18 0.03 3.32 0.98
GWS 10 G&W Roofing 0.77 0.68 2.51 22.6 56.3 0.21 0.03 4.48 0.68
GWS 11 G&W Roofing 0.44 0.82 2.66 17.6 62.5 0.17 0.04 2.46 1.32
GWS 12 G&W Roofing 0.43 0.86 2.18 18.8 64.2 0.17 0.02 3.02 0.89
GWS 13 G&W Roofing 0.49 0.81 2.70 20.0 58.8 0.17 0.02 3.99 0.95
GWS 15 G&W Roofing 0.50 1.12 2.95 19.0 60.0 0.21 0.03 3.30 1.02
GWS 16 G&W Roofing 0.53 0.66 2.76 18.6 59.4 0.27 0.07 3.45 1.96
Average Caddo Gap 0.57 0.81 2.56 19.8 60.1 0.20 0.04 3.55 0.99
n= 15
Unmineralized basal Stanley -- remote from mineralization
HSS 1E Hot Springs E 0.57 0.18 1.83 22.3 57.3 0.13 0.03 4.03 0.38
HSS 2E Hot Springs E 0.61 1.01 2.02 22.4 57.9 0.27 0.05 4.53 0.89
HSS 3E Hot Springs E 0.64 1.03 1.85 16.8 63.8 0.17 0.05 3.08 1.27
HSS 4E Hot Springs E 0.16 1.35 4.37 13.5 32.4 1.40 0.84 1.70 12.78
HSS 5E Hot Springs E 0.53 0.61 2.08 25.0 54.8 0.17 0.04 5.26 0.71
HSS 6E Hot Springs E 0.40 0.87 1.72 15.6 70.0 0.13 0.03 2.33 1.00
HSS 7E Hot Springs E 0.47 0.40 1.31 20.3 63.2 0.13 0.04 3.76 0.42
HSS 83 Hot Springs E 0.52 0.27 2.23 19.1 60.8 0.15 0.03 3.68 1.57
HSS 9E Hot Springs E 0.55 0.44 1.41 20.9 63.2 0.15 0.04 4.23 0.09
HSS 10E Hot Springs E 0.51 0.86 1.91 19.9 63.1 0.16 0.03 3.71 0.75
HSS 11E Hot Springs E 0.56 0.11 3.22 20.8 51.4 0.21 0.02 3.79 1.46
HS W 1 Hot Springs W 0.75 0.75 2.52 20.6 58.6 0.20 0.03 3.98 0.96
HS W 2 Hot Springs W 0.78 1.04 2.42 20.3 58.9 0.17 0.04 3.73 0.93
HS W 3 Hot Springs W 0.71 1.00 2.23 18.9 62.5 0.17 0.02 3.37 0.83
HS W 4 Hot Springs W 0.66 0.63 2.15 22.3 58.8 0.14 0.04 4.75 0.49
HS W 5 Hot Springs W 0.76 0.77 2.14 21.7 59.1 0.16 0.03 4.70 0.51
HS W 6 Hot Springs W 1.14 0.40 2.26 22.7 56.4 0.14 0.03 5.23 0.39
HS W 7 Hot Springs W 0.55 0.69 2.37 18.6 61.3 0.19 0.03 3.55 0.95
HS W 8 Hot Springs W 0.78 0.87 2.48 22.0 56.8 0.20 0.02 4.53 0.87
HS W 9 Hot Springs W 0.67 0.96 2.17 20.7 60.4 0.18 0.03 3.95 0.70
HS W 10 Hot Springs W 0.70 0.79 2.58 20.2 57.5 0.21 0.04 4.04 1.05
average Hot Springs 0.62 0.71 2.25 20.2 58.5 0.23 0.07 3.90 1.38
n= 21
LRS 1 Little Rock 1.00 0.10 0.97 13.1 76.9 0.04 0.03 2.20 0.01
LRS 2 Little Rock 1.09 0.11 0.65 13.8 76.9 0.04 0.03 2.44 0.00
LRS 3 Little Rock 1.00 0.12 0.47 14.1 80.8 0.03 0.02 2.94 0.00
LRS 4 Little Rock 1.10 0.10 0.10 11.6 80.6 0.04 0.02 2.14 0.04
LRS 5 Little Rock 0.63 0.07 0.69 10.3 80.9 0.06 0.02 1.78 0.00
LRS 6 Little Rock 1.29 0.09 0.11 11.1 82.2 0.03 0.33 2.01 0.00
LRS 7 Little Rock 1.03 0.10 0.49 12.2 80.3 0.03 0.11 2.07 0.00
average Little Rock 1.02 0.10 0.50 12.3 79.8 0.04 0.08 2.23 0.01
n= 7
rite mineralized areas
%oxide ppm ppm %oxide %oxide ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm
Ti V Cr Mn Fe Ni Cu Zn Rb Sr Y Zr Nb Mo Ba Pb
0.96 138 83 0.072 5.63 49 33 165 189 128 32.2 208 19.2 0.7 2671 20
1.03 161 90 0.056 6.40 47 32 148 199 109 34.7 176 18.9 0.7 2915 20
1.01 158 95 0.049 6.44 53 40 116 205 99 28.6 140 18.4 0.1 3199 16
0.97 144 94 0.054 5.68 95 40 161 208 88 31.1 163 19.4 0.3 3164 35
0.64 185 163 0.070 4.16 89 70 246 146 92 33.3 126 12.7 0.7 1920 12
0.69 124 99 0.064 4.47 60 50 202 162 79 23.3 132 13.1 0.7 2744 17
0.62 165 253 0.083 4.40 136 62 378 149 175 29.7 124 11.1 2.2 2158 13
0.70 108 102 0.056 5.09 57 46 238 164 66 22.0 128 14.1 0.1 2477 18
1.08 142 79 0.046 5.51 32 25 127 199 90 39.6 263 21.8 1.7 4730 26
0.81 82 68 0.081 6.23 55 25 158 165 81 36.5 154 15.9 0.7 2912 42
1.06 123 94 0.056 7.13 48 38 149 227 66 34.2 151 21.0 0.2 3844 20
1.08 173 97 0.048 6.93 72 39 164 239 114 35.3 162 19.7 0.4 4285 37
0.96 137 90 0.071 6.82 51 34 185 205 108 35.3 147 16.8 0.3 4736 32
1.03 169 102 0.057 7.10 69 40 186 232 87 31.1 146 17.9 0.4 3292 27
0.97 122 88 0.071 6.57 50 33 203 183 90 38.8 168 18.6 0.7 3238 24
0.89 141 87 0.066 5.51 50 30 209 179 118 32.9 133 13.2 0.7 4188 22
0.84 120 71 0.082 5.86 35 27 156 176 122 26.8 151 15.5 0.9 3674 22
0.84 143 110 0.074 5.66 72 46 217 184 78 27.7 167 15.2 0.3 3191 22
0.81 114 91 0.100 6.30 58 39 202 158 165 24.9 119 14.0 2.4 8784 21
0.59 138 107 0.739 8.52 111 49 305 103 43 25.8 110 10.6 0.9 2729 15
0.06 23 47 0.015 8.33 39 14 2 8 14 10.4 21 2 2.9 542 6
0.89 119 82 0.086 5.77 41 29 139 193 101 28.0 134 15.9 0.4 3312 21
0.72 117 94 0.097 5.47 60 29 165 146 111 32.4 151 14.4 0.9 2957 20
0.68 161 132 0.069 5.20 64 64 172 146 73 24.9 123 14.5 0.5 2875 17
0.64 160 163 0.039 5.42 77 175 251 138 45 27.6 114 10.8 1.2 3220 16
0.79 122 111 0.060 4.65 47 37 163 161 52 28.8 147 14.1 0.5 3035 7
0.90 189 241 0.199 6.35 97 121 354 170 63 26.3 143 14.4 0.2 3834 8
0.89 231 520 0.131 6.32 158 516 441 177 47 46.0 147 13.0 0.3 5273 5
0.88 176 217 0.054 3.60 104 73 2 174 108 40.6 155 18.1 0.7 5374 27
0.84 158 355 0.032 2.69 118 90 10 195 169 46.0 156 15.6 3.2 6463 22
0.83 141 134 0.093 5.81 69.8 64.9 187 173 92.7 31.2 145 15.3 0.9 3591 20
0.81 112 189 0.065 5.85 89 60 268 157 329 27.8 142 14.9 0.9 30499 18
0.75 36 135 0.060 4.03 75 38 276 127 666 26.0 121 10.2 3.1 46808 13
0.49 5 71 0.040 2.89 43 38 91 58 727 15.9 93 5.7 1.4 72736 5
0.68 51 132 0.055 4.26 69 45.3 212 114 574 23.2 118 10.2 1.8 50014 12
0.84 130 86 0.037 8.64 54 34 254 121 105 30.0 142 15.2 0.7 591 30
0.84 116 93 0.027 6.26 47 21 77 152 112 31.2 147 15.9 0.3 696 16
1.04 156 105 0.033 7.59 48 35 159 196 124 41.6 168 17.5 0.5 853 22
1.00 153 100 0.115 5.60 90 46 283 202 116 37.9 180 18.7 0.5 845 14
0.93 154 105 0.053 6.96 88 35 265 187 111 31.8 150 16.3 0.3 836 29
0.83 113 88 0.094 8.24 60 31 159 132 97 30.7 148 15.1 0.5 579 25
0.98 133 94 0.063 6.78 43 22 112 188 127 39.4 165 18.4 0.8 840 20
1.00 131 95 0.042 6.95 46 26 174 185 118 36.1 171 18.2 0.1 847 19
0.87 134 79 0.077 6.20 43 23 135 141 121 35.6 200 15.5 0.5 685 25
1.02 124 102 0.041 6.73 54 37 218 195 125 35.9 163 18.1 0.1 930 28
0.90 114 87 0.060 8.57 45 24 193 104 103 33.3 200 16.6 1.0 458 21
0.82 112 85 0.045 6.11 34 19 117 140 120 31.9 211 15.7 1.0 597 17
0.86 122 102 0.038 7.82 56 30 171 185 106 30.8 133 14.4 0.1 982 17
0.92 142 99 0.038 7.52 66 36 143 151 120 39.9 147 15.4 0.2 634 21
0.87 118 89 0.186 7.50 50 29 362 157 137 39.9 145 14.3 0.1 607 33
0.91 130 93.9 0.063 7.16 54.9 29.9 188 162 116 35.1 165 16.4 0.4 732 22.5
0.84 121 97 0.077 7.03 32 27 156 179 51 28.9 159 15.9 0.6 729 18
0.99 132 90 0.058 5.76 48 23 160 191 100 32.6 180 18.9 0.5 761 23
0.83 122 75 0.067 6.39 30 21 161 147 112 29.4 155 18.1 0.4 506 23
4.35 534 32 0.171 9.29 11 138 90 36 756 27.4 326 149 2.2 798 7
1.12 159 100 0.057 5.81 34 17 93 195 93 38.9 258 23.0 1.4 799 14
0.65 63 76 0.055 5.43 43 13 114 98 73 28.6 197 13.9 2.4 396 26
0.82 91 66 0.129 5.03 40 18 102 158 171 36.0 223 17.0 0.8 627 16
0.81 96 77 0.092 7.15 41 19 150 144 83 28.9 140 15.1 0.4 596 19
0.97 143 85 0.038 4.15 34 30 110 208 78 33.8 180 19.9 0.3 731 19
0.88 119 71 0.047 5.33 37 19 181 159 81 32.7 210 17.9 0.4 605 19
0.83 168 101 0.093 11.97 55 28 222 143 61 31.5 119 12.3 0.2 718 15
0.94 149 86 0.055 7.63 47 32 162 167 78 34.4 152 16.5 0.2 690 22
0.94 157 94 0.046 7.64 62 35 219 173 84 34.0 152 17.6 0.2 852 22
0.91 119 83 0.043 6.76 48 29 180 162 87 37.3 163 17.0 0.4 690 18
1.02 151 99 0.038 5.82 47 31 183 192 83 37.6 212 18.7 1.2 911 27
0.99 143 101 0.038 5.73 44 36 122 205 82 36.3 165 18.5 0.2 844 21
1.07 174 125 0.041 6.45 54 32 130 215 79 35.1 157 17.3 0.4 967 22
0.87 117 85 0.055 7.76 44 29 139 158 72 30.6 159 15.8 0.3 655 15
1.01 147 102 0.053 7.17 43 28 122 191 83 35.2 162 18.3 0.2 866 19
0.98 135 92 0.049 6.02 47 36 105 176 88 35.8 175 18.5 0.1 719 17
0.92 151 99 0.055 8.46 47 31 211 174 79 35.8 138 15.5 0.2 794 23
1.08 152 87.4 0.065 6.80 42 32 148 165 118 33.4 180 23.6 0.6 726 19
0.64 135 149 0.014 2.93 35 38 89 122 43 30.6 134 14.3 0.2 1402 15
0.69 150 164 0.008 1.90 37 27 57 148 41 31.8 150 16.2 0.2 1536 20
0.70 161 147 0.004 1.20 20 24 30 164 55 33.3 147 14.3 0.2 1779 26
0.60 143 141 0.013 0.40 45 5 57 145 65 46.8 150 16.3 0.7 1444 29
0.52 149 166 0.014 3.15 23 49 67 111 42 40.0 112 11.3 0.4 1147 21
0.58 120 113 0.001 0.90 32 14 6 127 68 33.7 140 14.9 1.3 1393 29
0.59 152 117 0.005 1.16 41 26 29 130 48 29.1 139 15.5 0.5 1412 24
0.62 144 142 0.008 1.66 33 26.1 48 135 51.7 35.0 139 14.7 0.5 1445 23
ppm ppm atom%
Th U Al Mo/Al V/Cr Zn/Al Ba/Al Cu/Al Pb/Al Al/(Al+Fe+Mn)
15.2 1.4 11.2 0.063 1.66 14.74 239 2.95 1.79 0.737
16.1 1.9 11.3 0.062 1.79 13.05 257 2.82 1.76 0.715
16.3 2.3 11.3 0.009 1.66 10.24 282 3.53 1.41 0.714
15.5 2.6 11.0 0.027 1.53 14.69 289 3.65 3.19 0.732
10.5 4.3 6.9 0.101 1.13 35.44 277 10.08 1.73 0.701
11.4 2.2 7.7 0.091 1.25 26.19 356 6.48 2.20 0.708
9.8 7.5 6.8 0.325 0.65 55.88 319 9.17 1.92 0.683
11.0 2.5 8.0 0.006 1.06 29.79 310 5.76 2.25 0.689
15.3 2.5 11.1 0.154 1.80 11.48 427 2.26 2.35 0.740
12.4 1.9 9.2 0.076 1.21 17.22 317 2.72 4.58 0.675
15.8 1.1 11.1 0.018 1.31 13.38 345 3.41 1.80 0.689
16.5 2.0 11.6 0.034 1.78 14.12 369 3.36 3.19 0.704
15.2 2.1 10.5 0.029 1.52 17.69 453 3.25 3.06 0.684
15.8 3.5 10.8 0.037 1.66 17.26 305 3.71 2.50 0.683
13.7 3.7 10.1 0.069 1.39 20.10 321 3.27 2.38 0.685
13.1 1.4 10.1 0.070 1.62 20.75 416 2.98 2.18 0.721
13.0 2.1 9.9 0.091 1.69 15.75 371 2.73 2.22 0.704
12.3 1.8 9.5 0.032 1.30 22.89 337 4.85 2.32 0.702
13.0 3.3 9.4 0.256 1.25 21.51 935 4.15 2.24 0.677
8.9 2.2 7.2 0.124 1.29 42.14 377 6.77 2.07 0.526
4.2 2.1 0.7 4.397 0.49 3.03 822 21.23 9.10 0.102
13.1 1.4 9.9 0.041 1.45 14.10 336 2.94 2.13 0.706
12.7 5.5 8.7 0.104 1.24 19.02 341 3.34 2.30 0.690
10.4 3.8 7.8 0.064 1.22 22.08 369 8.22 2.18 0.679
9.6 2.9 7.1 0.168 0.98 35.24 452 24.57 2.25 0.651
11.1 3.4 8.3 0.060 1.10 19.59 365 4.45 0.84 0.716
11.3 3.7 10.5 0.019 0.78 33.55 363 11.47 0.76 0.697
11.7 2.2 10.5 0.029 0.44 42.12 504 49.28 0.48 0.699
12.8 3.9 9.5 0.073 0.81 0.21 564 7.66 2.83 0.788
12.9 4.8 9.8 0.325 0.45 1.02 657 9.14 2.24 0.838
12.7 2.9 9.2 0.23 1.30 22.25 388 7.62 2.40 0.67
10.4 3.9 9.1 0.099 0.59 29.42 3347 6.59 1.98 0.687
9.5 5.4 8.4 0.370 0.27 32.99 5594 4.54 1.55 0.745
5.7 1.3 5.0 0.278 0.07 18.08 14452 7.55 0.99 0.711
8.5 3.5 7.5 0.25 0.31 26.83 7798 6.23 1.51 0.71
12.2 2.8 9.9 0.071 1.51 25.72 60 3.44 3.04 0.619
13.7 2.2 9.1 0.033 1.25 8.45 76 2.31 1.76 0.674
15.4 3.4 12.0 0.042 1.49 13.20 71 2.91 1.83 0.693
15.7 2.8 11.0 0.046 1.53 25.78 77 4.19 1.28 0.733
15.5 2.6 10.9 0.028 1.47 24.38 77 3.22 2.67 0.689
12.7 3.1 9.0 0.056 1.28 17.70 65 3.45 2.78 0.606
16.5 3.3 11.3 0.071 1.41 9.91 74 1.95 1.77 0.702
15.2 3.8 11.4 0.004 1.38 15.28 74 2.28 1.67 0.699
13.8 2.3 10.5 0.047 1.70 12.81 65 2.18 2.37 0.706
16.7 2.6 11.9 0.008 1.22 18.25 78 3.10 2.34 0.716
13.3 2.8 9.3 0.107 1.31 20.72 49 2.58 2.25 0.607
14.2 1.8 9.9 0.101 1.32 11.77 60 1.91 1.71 0.698
16.5 3.3 10.6 0.009 1.20 16.16 93 2.83 1.61 0.658
14.6 0.1 10.0 0.020 1.43 14.26 63 3.59 2.09 0.655
13.1 3.6 9.9 0.010 1.33 36.74 62 2.94 3.35 0.647
14.6 2.7 10.5 0.044 1.39 18.07 69.59 2.86 2.17 0.67
16.1 3.4 11.8 0.051 1.25 13.25 62 2.29 1.53 0.703
15.4 3.3 11.9 0.042 1.47 13.49 64 1.94 1.94 0.744
13.6 0.8 8.9 0.045 1.63 18.11 57 2.36 2.59 0.663
7.0 1.3 7.1 0.308 16.69 12.60 112 19.33 0.98 0.519
15.8 4.1 13.2 0.106 1.59 7.03 60 1.29 1.06 0.763
11.4 3.4 8.3 0.290 0.83 13.79 48 1.57 3.15 0.683
13.2 1.8 10.8 0.074 1.38 9.49 58 1.67 1.49 0.748
12.2 2.4 10.1 0.040 1.25 14.85 59 1.88 1.88 0.666
15.8 3.9 11.0 0.027 1.68 9.97 66 2.72 1.72 0.790
13.8 3.1 10.6 0.038 1.68 17.15 57 1.80 1.80 0.737
15.5 3 11.0 0.018 1.66 20.14 65 2.54 1.36 0.566
15.5 2.4 10.9 0.018 1.73 14.88 63 2.94 2.02 0.669
16.3 3.5 10.7 0.019 1.67 20.41 79 3.26 2.05 0.666
14.1 4.6 10.0 0.040 1.43 17.98 69 2.90 1.80 0.678
14.9 3.7 11.8 0.102 1.53 15.52 77 2.63 2.29 0.742
14.7 4.4 11.5 0.017 1.42 10.61 73 3.13 1.83 0.740
14.8 2.1 12.0 0.033 1.39 10.84 81 2.67 1.83 0.725
14.3 4.9 9.8 0.030 1.38 14.13 67 2.95 1.52 0.643
16.5 7.2 11.7 0.017 1.44 10.47 74 2.40 1.63 0.698
16.6 4.4 11.0 0.009 1.47 9.58 66 3.28 1.55 0.721
15.0 1.8 10.7 0.019 1.53 19.70 74 2.89 2.15 0.642
14.4 3.3 10.7 0.06 2.19 14.00 68.24 3.26 1.82 0.69
10.4 3.7 6.9 0.029 0.91 12.81 202 5.47 2.16 0.771
11.3 4.1 7.3 0.027 0.91 7.81 210 3.70 2.74 0.846
11.1 3.6 7.4 0.027 1.10 4.03 239 3.22 3.49 0.898
11.1 3.4 6.2 0.114 1.01 9.26 235 0.81 4.71 0.955
9.3 4.6 5.5 0.073 0.90 12.25 210 8.96 3.84 0.712
11.3 1.9 5.9 0.222 1.06 1.02 238 2.39 4.95 0.903
11.4 2.9 6.4 0.078 1.30 4.50 219 4.04 3.73 0.887
10.8 3.5 6.5 0.08 1.03 7.38 221.77 4.08 3.66 0.85
Mn/Al
0.0050
0.0038
0.0034
0.0038
0.0079
0.0064
0.0096
0.0054
0.0033
0.0069
0.0039
0.0032
0.0053
0.0041
0.0055
0.0050
0.0064
0.0060
0.0083
0.0791
0.0174
0.0067
0.0086
0.0069
0.0042
0.0056
0.0146
0.0097
0.0044
0.0025
0.0091
0.0056
0.0056
0.0061
0.0058
0.0029
0.0023
0.0021
0.0081
0.0038
0.0081
0.0043
0.0028
0.0057
0.0026
0.0050
0.0035
0.0028
0.0030
0.0146
0.0048
0.0050
0.0038
0.0058
0.0185
0.0033
0.0052
0.0093
0.0071
0.0026
0.0035
0.0065
0.0039
0.0034
0.0033
0.0025
0.0026
0.0027
0.0043
0.0036
0.0035
0.0040
0.0050
0.0015
0.0009
0.0004
0.0017
0.0020
0.0002
0.0006
0.0010
6 11 12 13 14 15
% %oxide %oxide %oxide %oxide %oxide
TOC δ13C Na Mg Al Si P
Fancy Hill -- shale host
DDH103 92 Fancy Hill 0.43 -25.8 0.69 2.29 21.2 58.5 0.13
DDH103 99.5 Fancy Hill 0.52 -25.5 0.72 2.51 21.4 57.7 0.15
DDH103 104.25 Fancy Hill 0.52 -25.3 0.76 2.45 21.4 57.6 0.15
DDH103 112.5 Fancy Hill 0.42 -25.7 0.61 2.57 20.7 59.4 0.11
DDH103 117 Fancy Hill 1.03 -29.4 0.32 1.50 13.1 72.0 0.13
DDH103 134.5 Fancy Hill 0.42 -27.8 0.56 1.75 14.6 70.1 0.08
DDH103 136 Fancy Hill 1.90 -30.1 0.45 1.60 12.8 68.3 0.39
DDH103 138 Fancy Hill 0.44 -28.2 0.66 1.81 15.1 68.7 0.08
DDH103 164.3 Fancy Hill 0.41 -26.2 0.91 2.52 20.9 59.1 0.14
DDH103 165.5 Fancy Hill 0.57 -27.0 0.77 2.38 17.3 62.5 0.12
DDH103 179.2 Fancy Hill 0.52 -25.1 0.65 2.89 21.1 55.5 0.14
DDH103 181 Fancy Hill 0.53 -25.8 0.63 2.81 22.0 53.8 0.39
DDH103 296 Fancy Hill 0.54 -21.2 0.65 2.83 19.8 57.6 0.25
DDH103 302.3 Fancy Hill 0.53 -26.1 0.69 2.94 20.4 56.9 0.14
DDH103 310 Fancy Hill 0.83 -26.2 0.78 3.05 19.1 59.0 0.13
DDH103 357.2 Fancy Hill 1.44 -28.5 0.87 2.79 19.0 59.8 0.20
DDH103 387.1 Fancy Hill 0.33 -26.6 0.91 2.96 18.7 61.0 0.11
DDH103 388 Fancy Hill 0.32 -26.5 0.92 2.88 17.9 61.9 0.11
DDH103 403.5 Fancy Hill 0.41 -27.8 0.86 2.91 17.7 60.5 0.10
DDH119 196.5 Fancy Hill 0.26 -30.1 0.31 2.22 13.7 63.7 0.06
DDH119 206 Fancy Hill 0.16 -27.4 0.01 0.09 1.2 81.1 0.03
DDH40 335 Fancy Hill 0.35 -26.5 0.88 2.87 18.6 60.8 0.11
DDH40 373.5 Fancy Hill 0.42 -27.9 0.66 2.69 16.4 65.2 0.09
DDH40 375 Fancy Hill 0.46 -27.7 0.46 2.31 14.7 69.0 0.06
DDH40 388.5 Fancy Hill 0.61 -26.9 0.13 1.90 13.5 70.3 0.08
DDH40 390 Fancy Hill 0.14 -26.3 0.31 2.16 15.7 69.1 0.05
DDH40 405 Fancy Hill 0.56 -28.0 0.20 2.41 19.9 55.9 0.07
DDH40 405.5 Fancy Hill 1.82 -29.0 0.17 2.84 19.8 55.5 0.07
MDDH5 220 1.34 -29.5 0.17 1.34 18.0 71.5 0.09
MDDH5 227.5 2.69 -30.0 0.18 0.90 18.6 57.9 0.15
average FH shale 0.70 -27.1 0.56 2.31 17.5 62.7 0.13
std dev 0.58 1.9 0.27 0.69 4.13 6.45 0.08
Fancy Hill -- barites
DDH103 339.5 Fancy Hill 0.44 -27.7 0.77 2.68 17.2 58.6 0.09
DDH40 345 Fancy Hill 1.30 -30.2 0.65 2.17 15.8 60.0 0.22
DDH40 358.5 Fancy Hill 0.65 -29.2 0.32 1.19 9.5 70.0 0.08
average FH barite 0.79 -29.0 0.58 2.01 14.2 62.9 0.13
std dev 0.45 1.2 0.23 0.76 4.1 6.2 0.08
Unmineralized basal Stanley
GWS 1 G&W Roofing 0.46 -26.5 0.68 2.78 18.7 60.6 0.20
GWS 2 G&W Roofing 0.54 -26.7 0.88 2.24 17.2 65.1 0.18
GWS 3 G&W Roofing 0.65 -26.9 0.81 2.73 22.8 54.9 0.34
GWS 4 G&W Roofing 0.53 -26.4 0.94 2.51 20.7 60.0 0.16
GWS 5 G&W Roofing 0.73 -27.0 0.76 2.72 20.5 58.0 0.17
GWS 6 G&W Roofing 0.69 -26.7 0.71 2.50 17.0 63.2 0.17
GWS 7 G&W Roofing 0.57 -26.4 0.79 2.36 21.4 58.8 0.23
GWS 8 G&W Roofing 0.75 -28.3 0.70 2.49 21.5 58.2 0.20
GWS 9 G&W Roofing 0.44 -26.4 0.89 2.26 19.9 62.2 0.18
GWS 10 G&W Roofing 0.77 -26.2 0.68 2.51 22.6 56.3 0.21
GWS 11 G&W Roofing 0.44 0.82 2.66 17.6 62.5 0.17
GWS 12 G&W Roofing 0.43 -26.3 0.86 2.18 18.8 64.2 0.17
GWS 13 G&W Roofing 0.49 -26.6 0.81 2.70 20.0 58.8 0.17
GWS 15 G&W Roofing 0.50 -25.5 1.12 2.95 19.0 60.0 0.21
GWS 16 G&W Roofing 0.53 -26.1 0.66 2.76 18.6 59.4 0.27
Average Caddo Gap 0.57 -26.6 0.81 2.56 19.8 60.1 0.20
std dev 0.12 0.6 0.12 0.23 1.8 2.9 0.05
HSS 1E Hot Springs E 0.572 0.18 1.83 22.25 57.33 0.13
HSS 2E Hot Springs E 0.611 1.01 2.02 22.41 57.94 0.27
HSS 3E Hot Springs E 0.637 1.03 1.85 16.80 63.76 0.17
HSS 4E Hot Springs E 0.160 1.35 4.37 13.50 32.37 1.40
HSS 5E Hot Springs E 0.527 0.61 2.08 24.99 54.82 0.17
HSS 6E Hot Springs E 0.403 0.87 1.72 15.62 69.97 0.13
HSS 7E Hot Springs E 0.469 0.40 1.31 20.32 63.17 0.13
HSS 83 Hot Springs E 0.518 0.27 2.23 19.10 60.77 0.15
HSS 9E Hot Springs E 0.553 0.44 1.41 20.85 63.23 0.15
HSS 10E Hot Springs E 0.514 0.86 1.91 19.95 63.05 0.16
HSS 11E Hot Springs E 0.557 0.11 3.22 20.83 51.36 0.21
HS W 1 Hot Springs W 0.752 0.75 2.52 20.58 58.56 0.20
HS W 2 Hot Springs W 0.784 1.04 2.42 20.28 58.94 0.17
HS W 3 Hot Springs W 0.711 1.00 2.23 18.92 62.52 0.17
HS W 4 Hot Springs W 0.662 0.63 2.15 22.29 58.84 0.14
HS W 5 Hot Springs W 0.760 0.77 2.14 21.72 59.09 0.16
HS W 6 Hot Springs W 1.141 0.40 2.26 22.67 56.35 0.14
HS W 7 Hot Springs W 0.551 0.69 2.37 18.59 61.30 0.19
HS W 8 Hot Springs W 0.781 0.87 2.48 22.02 56.75 0.20
HS W 9 Hot Springs W 0.672 0.96 2.17 20.71 60.42 0.18
HS W 10 Hot Springs W 0.700 0.79 2.58 20.24 57.55 0.21
average Hot Springs 0.62 0.71 2.25 20.22 58.48 0.23
std dev
LRS 1 Little Rock 0.996 0.10 0.97 13.13 76.92 0.04
LRS 2 Little Rock 1.092 0.11 0.65 13.80 76.88 0.04
LRS 3 Little Rock 1.002 0.12 0.47 14.07 80.78 0.03
LRS 4 Little Rock 1.104 0.10 0.10 11.63 80.62 0.04
LRS 5 Little Rock 0.625 0.07 0.69 10.34 80.92 0.06
LRS 6 Little Rock 1.293 0.09 0.11 11.08 82.24 0.03
LRS 7 Little Rock 1.030 0.10 0.49 12.18 80.35 0.03
average Little Rock 1.02 0.10 0.50 12.32 79.82 0.04
std dev
TOC δ13C Na Mg Al Si P
6 11 12 13 14 15
SDO1 9.68 -29.9 0.38 1.54 12.3 49.3 0.11
min sh/SDO1 0.0720 0.908 1.483 1.497 1.421 1.271 1.186
unmin sh/SDO1 0.0588 0.888 2.123 1.660 1.606 1.220 1.837
log min/SDO1 -1.1425 -0.042 0.1712 0.1753 0.1527 0.1042 0.0741
log unmin/SDO1 -1.2306 -0.051 0.327 0.2202 0.2057 0.0864 0.264
GWS 14 qtz vein G&W Roofing 0.05 0.16 1.56 97.95 0.02
MDDH5 229 0.276 -29.72 0.00 0.04 1.14 93.30 0.02
16 19 20 22 23 24 25 26 27 28 29 30
%element pyrite %oxide %oxide %oxide ppm ppm %oxide %oxide ppm ppm ppm ppm
S δ34S K Ca Ti V Cr Mn Fe Co Ni Cu Zn
0.08 4.47 1.23 0.96 138 83 0.07 5.63 15 49 33 165
0.13 15.85 4.54 0.88 1.03 161 90 0.06 6.40 19 47 32 148
0.10 4.63 0.74 1.01 158 95 0.05 6.44 21 53 40 116
0.58 19.77 4.64 0.60 0.97 144 94 0.05 5.68 32 95 40 161
0.08 2.77 0.88 0.64 185 163 0.07 4.16 14 89 70 246
2.29 0.99 3.19 0.43 0.69 124 99 0.06 4.47 13 60 50 202
2.68 2.91 1.83 0.62 165 253 0.08 4.40 12 136 62 378
2.86 9.42 3.31 0.44 0.70 108 102 0.06 5.09 13 57 46 238
0.13 4.89 1.01 1.08 142 79 0.05 5.51 16 32 25 127
0.73 8.15 3.70 1.74 0.81 82 68 0.08 6.23 25 55 25 158
0.82 5.31 0.95 1.06 123 94 0.06 7.13 20 48 38 149
0.80 9.68 5.61 1.12 1.08 173 97 0.05 6.93 34 72 39 164
0.59 4.81 1.44 0.96 137 90 0.07 6.82 23 51 34 185
0.94 14.84 5.12 0.85 1.03 169 102 0.06 7.10 27 69 40 186
1.47 4.31 0.89 0.97 122 88 0.07 6.57 23 50 33 203
4.45 4.39 1.24 0.89 141 87 0.07 5.51 19 50 30 209
2.83 15.99 4.17 0.87 0.84 120 71 0.08 5.86 15 35 27 156
2.82 3.90 0.33 0.84 143 110 0.07 5.66 20 72 46 217
5.07 8.77 3.79 1.01 0.81 114 91 0.10 6.30 21 58 39 202
3.38 15.52 1.99 2.23 0.59 138 107 0.74 8.52 29 111 49 305
9.65 16.56 0.00 0.54 0.06 23 47 0.01 8.33 16 39 14 2
2.48 17.68 4.21 0.82 0.89 119 82 0.09 5.77 13 41 29 139
1.80 11.71 3.20 1.27 0.72 117 94 0.10 5.47 14 60 29 165
1.64 9.87 2.97 0.57 0.68 161 132 0.07 5.20 12 64 64 172
4.42 15.01 2.83 0.34 0.64 160 163 0.04 5.42 18 77 175 251
0.54 19.30 3.38 0.30 0.79 122 111 0.06 4.65 11 47 37 163
1.44 19.62 4.16 0.37 0.90 189 241 0.20 6.35 21 97 121 354
3.28 20.93 4.37 0.33 0.89 231 520 0.13 6.32 22 158 516 441
3.02 7.73 3.65 0.63 0.88 176 217 0.05 3.60 24 104 73 2
2.87 -3.85 3.80 0.01 0.84 158 355 0.03 2.69 16 118 90 10
2.13 12.68 3.84 0.86 0.83 141 134 0.09 5.81 19 70 65 187
2.02 6.44 1.11 0.50 0.20 37 98 0.13 1.25 6 31 91 97
2.49 5.14 3.86 0.45 0.81 112 189 0.07 5.85 12 89 60 268
3.36 5.96 3.66 1.20 0.75 36 135 0.06 4.03 13 75 38 276
5.13 -3.94 2.15 1.29 0.49 5 71 0.04 2.89 8 43 38 91
3.66 2.39 3.23 0.98 0.68 51 132 0.06 4.26 11 69 45 212
1.35 5.49 0.94 0.46 0.17 55 59 0.01 1.50 3 24 13 105
0.028 -4.45 2.92 1.07 0.84 130 86 0.04 8.64 21 54 34 254
0.031 5.80 3.08 0.68 0.84 116 93 0.03 6.26 13 47 21 77
0.031 -2.73 4.34 0.97 1.04 156 105 0.03 7.59 19 48 35 159
0.099 -3.91 4.03 0.74 1.00 153 100 0.11 5.60 30 90 46 283
0.012 -31.85 4.07 0.77 0.93 154 105 0.05 6.96 27 88 35 265
0.027 -2.47 2.69 1.11 0.83 113 88 0.09 8.24 16 60 31 159
0.029 -2.23 3.99 0.87 0.98 133 94 0.06 6.78 21 43 22 112
0.035 -1.55 4.06 0.79 1.00 131 95 0.04 6.95 20 46 26 174
0.033 -4.69 3.32 0.98 0.87 134 79 0.08 6.20 17 43 23 135
0.030 4.48 0.68 1.02 124 102 0.04 6.73 21 54 37 218
0.039 -6.00 2.46 1.32 0.90 114 87 0.06 8.57 15 45 24 193
0.024 -5.01 3.02 0.89 0.82 112 85 0.04 6.11 14 34 19 117
0.015 -9.96 3.99 0.95 0.86 122 102 0.04 7.82 23 56 30 171
0.027 -3.92 3.30 1.02 0.92 142 99 0.04 7.52 33 66 36 143
0.069 -16.03 3.45 1.96 0.87 118 89 0.19 7.50 20 50 29 362
0.04 -6.36 3.55 0.99 0.91 130 94 0.06 7.16 21 55 30 188
0.02 8.74 0.63 0.32 0.08 15 8 0.04 0.92 5.73 16 7 76
0.029 4.03 0.38 0.84 121 97 0.08 7.03 13 32 27 156
0.053 4.53 0.89 0.99 132 90 0.06 5.76 23 48 23 160
0.054 3.08 1.27 0.83 122 75 0.07 6.39 14 30 21 161
0.841 1.70 12.78 4.35 534 32 0.17 9.29 29 11 138 90
0.038 5.26 0.71 1.12 159 100 0.06 5.81 14 34 17 93
0.027 2.33 1.00 0.65 63 76 0.06 5.43 16 43 13 114
0.041 3.76 0.42 0.82 91 66 0.13 5.03 17 40 18 102
0.027 3.68 1.57 0.81 96 77 0.09 7.15 17 41 19 150
0.042 4.23 0.09 0.97 143 85 0.04 4.15 13 34 30 110
0.035 3.71 0.75 0.88 119 71 0.05 5.33 8 37 19 181
0.021 3.79 1.46 0.83 168 101 0.09 11.97 23 55 28 222
0.030 3.98 0.96 0.94 149 86 0.05 7.63 23 47 32 162
0.038 3.73 0.93 0.94 157 94 0.05 7.64 25 62 35 219
0.023 3.37 0.83 0.91 119 83 0.04 6.76 17 48 29 180
0.040 4.75 0.49 1.02 151 99 0.04 5.82 16 47 31 183
0.033 4.70 0.51 0.99 143 101 0.04 5.73 15 44 36 122
0.028 5.23 0.39 1.07 174 125 0.04 6.45 18 54 32 130
0.029 3.55 0.95 0.87 117 85 0.06 7.76 19 44 29 139
0.021 4.53 0.87 1.01 147 102 0.05 7.17 17 43 28 122
0.026 3.95 0.70 0.98 135 92 0.05 6.02 16 47 36 105
0.040 4.04 1.05 0.92 151 99 0.05 8.46 26 47 31 211
0.072 3.90 1.38 1.08 152 87.43 0.06 6.80 18.05 42.29 32.00 148
0.027 2.20 0.01 0.64 135 149 0.01 2.93 0.5 35 38 89
0.031 2.44 0.00 0.69 150 164 0.01 1.90 1 37 27 57
0.015 2.94 0.00 0.70 161 147 0.00 1.20 2 20 24 30
0.016 2.14 0.04 0.60 143 141 0.01 0.40 3 45 5 57
0.019 1.78 0.00 0.52 149 166 0.01 3.15 5 23 49 67
0.326 2.01 0.00 0.58 120 113 0.00 0.90 4 32 14 6
0.114 2.07 0.00 0.59 152 117 0.01 1.16 3 41 26 29
0.08 2.23 0.01 0.62 144 142 0.01 1.66 3 33 26 48
S δ34S K Ca Ti V Cr Mn Fe Co Ni Cu Zn
16 19 20 22 23 24 25 26 27 28 29 30
5.35 -25 3.35 1.05 0.71 160 66.4 0.042 9.34 46.8 99.5 60.2 64.1
0.399 -0.507 1.145 0.822 1.169 0.884 2.021 2.204 0.622 0.412 0.702 1.078 2.919
0.007 0.254 1.059 0.939 1.287 0.813 1.415 1.506 0.767 0.442 0.552 0.496 2.935
-0.399 #NUM! 0.0588 -0.085 0.0678 -0.05 0.305 0.343 -0.21 -0.39 -0.15 0.032 0.465
-2.182 -0.595 0.0248 -0.027 0.1096 -0.09 0.151 0.178 -0.12 -0.35 -0.26 -0.3 0.468
0.021 0.00 0.01 0.06 15 61 0.00 0.16 7 14 4 2
3.155 11.32 0.00 0.02 0.07 24 33 0.01 2.71 8 38 39 2
37 38 39 40 41 42 56 82 90 92
ppm ppm ppm ppm ppm ppm ppm ppm ppm ppm %
Rb Sr Y Zr Nb Mo Ba Pb Th U BaO
189 128 32.2 208 19.2 0.70 2671 20 15.2 1.4 0.30
199 109 34.7 176 18.9 0.70 2915 20 16.1 1.9 0.33
205 99 28.6 140 18.4 0.10 3199 16 16.3 2.3 0.36
208 88 31.1 163 19.4 0.30 3164 35 15.5 2.6 0.35
146 92 33.3 126 12.7 0.70 1920 12 10.5 4.3 0.21
162 79 23.3 132 13.1 0.70 2744 17 11.4 2.2 0.31
149 175 29.7 124 11.1 2.20 2158 13 9.8 7.5 0.24
164 66 22.0 128 14.1 0.05 2477 18 11.0 2.5 0.28
199 90 39.6 263 21.8 1.70 4730 26 15.3 2.5 0.53
165 81 36.5 154 15.9 0.70 2912 42 12.4 1.9 0.32
227 66 34.2 151 21.0 0.20 3844 20 15.8 1.1 0.43
239 114 35.3 162 19.7 0.40 4285 37 16.5 2.0 0.48
205 108 35.3 147 16.8 0.30 4736 32 15.2 2.1 0.53
232 87 31.1 146 17.9 0.40 3292 27 15.8 3.5 0.37
183 90 38.8 168 18.6 0.70 3238 24 13.7 3.7 0.36
179 118 32.9 133 13.2 0.70 4188 22 13.1 1.4 0.47
176 122 26.8 151 15.5 0.90 3674 22 13.0 2.1 0.41
184 78 27.7 167 15.2 0.30 3191 22 12.3 1.8 0.36
158 165 24.9 119 14.0 2.40 8784 21 13.0 3.3 0.98
103 43 25.8 110 10.6 0.90 2729 15 8.9 2.2 0.30
8 14 10.4 21 2.0 2.90 542 6 4.2 2.1 0.06
193 101 28.0 134 15.9 0.40 3312 21 13.1 1.4 0.37
146 111 32.4 151 14.4 0.90 2957 20 12.7 5.5 0.33
146 73 24.9 123 14.5 0.50 2875 17 10.4 3.8 0.32
138 45 27.6 114 10.8 1.20 3220 16 9.6 2.9 0.36
161 52 28.8 147 14.1 0.50 3035 7 11.1 3.4 0.34
170 63 26.3 143 14.4 0.20 3834 8 11.3 3.7 0.43
177 47 46.0 147 13.0 0.30 5273 5 11.7 2.2 0.59
174 108 40.6 155 18.1 0.70 5374 27 12.8 3.9 0.60
195 169 46.0 156 15.6 3.20 6463 22 12.9 4.8 0.72
173 93 31.2 145 15.3 0.86 3591 20 12.7 2.9 0.38
43 37 7.3 38 3.9 0.81 1504 8.8 2.7 1.4 0.17
157 329 27.8 142 14.9 0.90 30499 18 10.4 3.9 3.40
127 666 26.0 121 10.2 3.10 46808 13 9.5 5.4 5.22
58 727 15.9 93 5.7 1.40 72736 5 5.7 1.3 8.12
114 574 23.2 118 10.2 1.80 50014 12 8.5 3.5 5.58
51 214 6.4 25 4.6 1.15 21300 7 2.5 2.1 2.38
121 105 30.0 142 15.2 0.70 591 30 12.2 2.8 0.07
152 112 31.2 147 15.9 0.30 696 16 13.7 2.2 0.08
196 124 41.6 168 17.5 0.50 853 22 15.4 3.4 0.10
202 116 37.9 180 18.7 0.50 845 14 15.7 2.8 0.09
187 111 31.8 150 16.3 0.30 836 29 15.5 2.6 0.09
132 97 30.7 148 15.1 0.50 579 25 12.7 3.1 0.06
188 127 39.4 165 18.4 0.80 840 20 16.5 3.3 0.09
185 118 36.1 171 18.2 0.05 847 19 15.2 3.8 0.09
141 121 35.6 200 15.5 0.50 685 25 13.8 2.3 0.08
195 125 35.9 163 18.1 0.10 930 28 16.7 2.6 0.10
104 103 33.3 200 16.6 1.00 458 21 13.3 2.8 0.05
140 120 31.9 211 15.7 1.00 597 17 14.2 1.8 0.07
185 106 30.8 133 14.4 0.10 982 17 16.5 3.3 0.11
151 120 39.9 147 15.4 0.20 634 21 14.6 0.1 0.07
157 137 39.9 145 14.3 0.10 607 33 13.1 3.6 0.07
162 116 35.1 165 16.4 0.44 732 22 14.6 2.7 0.08
31 11 4.0 24 1.5 0.32 153 6 1.5 0.9 0.02
179 51 28.9 159 15.9 0.60 729 18 16.1 3.4 0.08
191 100 32.6 180 18.9 0.50 761 23 15.4 3.3 0.08
147 112 29.4 155 18.1 0.40 506 23 13.6 0.8 0.06
36 756 27.4 326 149.3 2.20 798 7 7.0 1.3 0.09
195 93 38.9 258 23.0 1.40 799 14 15.8 4.1 0.09
98 73 28.6 197 13.9 2.40 396 26 11.4 3.4 0.04
158 171 36.0 223 17.0 0.80 627 16 13.2 1.8 0.07
144 83 28.9 140 15.1 0.40 596 19 12.2 2.4 0.07
208 78 33.8 180 19.9 0.30 731 19 15.8 3.9 0.08
159 81 32.7 210 17.9 0.40 605 19 13.8 3.1 0.07
143 61 31.5 119 12.3 0.20 718 15 15.5 3.0 0.08
167 78 34.4 152 16.5 0.20 690 22 15.5 2.4 0.08
173 84 34.0 152 17.6 0.20 852 22 16.3 3.5 0.10
162 87 37.3 163 17.0 0.40 690 18 14.1 4.6 0.08
192 83 37.6 212 18.7 1.20 911 27 14.9 3.7 0.10
205 82 36.3 165 18.5 0.20 844 21 14.7 4.4 0.09
215 79 35.1 157 17.3 0.40 967 22 14.8 2.1 0.11
158 72 30.6 159 15.8 0.30 655 15 14.3 4.9 0.07
191 83 35.2 162 18.3 0.20 866 19 16.5 7.2 0.10
176 88 35.8 175 18.5 0.10 719 17 16.6 4.4 0.08
174 79 35.8 138 15.5 0.20 794 23 15.0 1.8 0.09
165 118 33 180 24 0.62 726 19 14.40 3.31 0.08
122 43 30.6 134 14.3 0.20 1402 15 10.4 3.7 0.16
148 41 31.8 150 16.2 0.20 1536 20 11.3 4.1 0.17
164 55 33.3 147 14.3 0.20 1779 26 11.1 3.6 0.20
145 65 46.8 150 16.3 0.70 1444 29 11.1 3.4 0.16
111 42 40.0 112 11.3 0.40 1147 21 9.3 4.6 0.13
127 68 33.7 140 14.9 1.30 1393 29 11.3 1.9 0.16
130 48 29.1 139 15.5 0.50 1412 24 11.4 2.9 0.16
135 52 35 139 15 0.50 1445 23 10.8 3.5 0.16
Rb Sr Y Zr Nb Mo Ba Pb Th U
37 38 39 40 41 42 56 82 90 92
126 75 40.6 165 11.4 134 397 27.9 10.5 48.8
1.370 1.236 0.767 0.880 1.344 0.006 9.046 0.729 1.208 0.059
1.289 1.548 0.864 0.998 1.435 0.003 1.844 0.805 1.391 0.055
0.1368 0.092 -0.11502 -0.055 0.12855 -2.1918 0.956 -0.14 0.082 -1.23
0.1102 0.19 -0.0635 -1E-03 0.156736 -2.4804 0.266 -0.09 0.143 -1.26
9 11 9.5 19 2.5 3.40 0 6 5.3 0.3
5 16 12.4 19 1.9 2.20 0 6 4.4 0.7
% ppm % log log
Mn/Fe Zr/TiO2 Nb/Y Y/TiO2 Zr/TiO2 Nb/Y
0.013 0.02162 0.596 0.0033 -1.665 -0.225
0.009 0.01706 0.543 0.0034 -1.768 -0.265
0.008 0.01386 0.641 0.0028 -1.858 -0.193
0.010 0.01684 0.624 0.0032 -1.774 -0.205
0.017 0.01956 0.382 0.0052 -1.709 -0.418
0.014 0.01920 0.563 0.0034 -1.717 -0.250
0.019 0.01986 0.375 0.0048 -1.702 -0.426
0.011 0.01825 0.641 0.0031 -1.739 -0.193
0.008 0.02432 0.552 0.0037 -1.614 -0.258
0.013 0.01900 0.435 0.0045 -1.721 -0.362
0.008 0.01426 0.615 0.0032 -1.846 -0.211
0.007 0.01490 0.558 0.0033 -1.827 -0.253
0.010 0.01520 0.475 0.0037 -1.818 -0.324
0.008 0.01421 0.574 0.0030 -1.848 -0.241
0.011 0.01729 0.480 0.0040 -1.762 -0.319
0.012 0.01504 0.400 0.0037 -1.823 -0.398
0.014 0.01794 0.578 0.0032 -1.746 -0.238
0.013 0.01992 0.550 0.0033 -1.701 -0.259
0.016 0.01468 0.562 0.0031 -1.833 -0.250
0.087 0.01855 0.411 0.0043 -1.732 -0.386
0.002 0.03247 0.193 0.0162 -1.488 -0.714
0.015 0.01507 0.566 0.0031 -1.822 -0.247
0.018 0.02081 0.444 0.0045 -1.682 -0.352
0.013 0.01821 0.584 0.0037 -1.740 -0.234
0.007 0.01780 0.392 0.0043 -1.750 -0.407
0.013 0.01847 0.490 0.0036 -1.734 -0.310
0.031 0.01592 0.549 0.0029 -1.798 -0.261
0.021 0.01664 0.282 0.0052 -1.779 -0.550
0.01753 0.446 0.0046 -1.756 -0.351
0.012 0.01859 0.340 0.0055 -1.731 -0.469
0.015 0.01810 0.502 0.0041
0.015 0.00364 0.111
0.011 0.01754 0.534 0.0034 -1.756 -0.273
0.015 0.01603 0.390 0.0035 -1.795 -0.408
0.014 0.01885 0.357 0.0032 -1.725 -0.447
0.013 0.01747 0.427 0.0034
0.002 0.00141 0.094
0.004 0.01697 0.506 0.0036 -1.770 -0.295
0.004 0.01757 0.510 0.0037 -1.755 -0.293
0.004 0.01604 0.421 0.0040 -1.795 -0.376
0.021 0.01798 0.493 0.0038 -1.745 -0.307
0.008 0.01615 0.513 0.0034 -1.792 -0.290
0.011 0.01788 0.493 0.0037 -1.748 -0.307
0.009 0.01679 0.467 0.0040 -1.775 -0.330
0.006 0.01713 0.504 0.0036 -1.766 -0.298
0.012 0.02306 0.434 0.0041 -1.637 -0.363
0.006 0.01606 0.503 0.0035 -1.794 -0.298
0.007 0.02221 0.497 0.0037 -1.653 -0.303
0.007 0.02565 0.490 0.0039 -1.591 -0.310
0.005 0.01546 0.468 0.0036 -1.811 -0.330
0.005 0.01604 0.387 0.0044 -1.795 -0.412
0.025 0.01667 0.360 0.0046 -1.778 -0.444
0.009 0.01811 0.470 0.0038
0.006 0.00303 0.048
0.011 0.01892 0.550 0.0034 -1.723 -0.260
0.010 0.01813 0.580 0.0033 -1.742 -0.237
0.010 0.01855 0.616 0.0035 -1.732 -0.210
0.018 0.00751 5.446 0.0006 -2.124 0.736
0.010 0.02303 0.591 0.0035 -1.638 -0.228
0.010 0.03054 0.485 0.0044 -1.515 -0.314
0.026 0.02718 0.472 0.0044 -1.566 -0.326
0.013 0.01741 0.523 0.0036 -1.759 -0.281
0.009 0.01854 0.590 0.0035 -1.732 -0.229
0.009 0.02377 0.548 0.0037 -1.624 -0.261
0.008 0.01434 0.390 0.0038 -1.844 -0.408
0.007 0.01624 0.480 0.0037 -1.789 -0.319
0.006 0.01617 0.518 0.0036 -1.791 -0.286
0.006 0.01795 0.456 0.0041 -1.746 -0.341
0.006 0.02073 0.497 0.0037 -1.683 -0.304
0.007 0.01657 0.510 0.0036 -1.781 -0.293
0.006 0.01463 0.494 0.0033 -1.835 -0.306
0.007 0.01824 0.517 0.0035 -1.739 -0.287
0.007 0.01599 0.519 0.0035 -1.796 -0.285
0.008 0.01775 0.517 0.0036 -1.751 -0.286
0.006 0.01510 0.432 0.0039 -1.821 -0.365
0.010 0.01844 0.749 0.0035
0.005 0.02111 0.466 0.0048 -1.675 -0.332
0.004 0.02186 0.509 0.0046 -1.660 -0.293
0.003 0.02101 0.429 0.0048 -1.677 -0.368
0.033 0.02502 0.349 0.0078 -1.602 -0.457
0.004 0.02171 0.282 0.0077 -1.663 -0.549
0.002 0.02400 0.441 0.0058 -1.620 -0.355
0.004 0.02370 0.535 0.0049 -1.625 -0.272
0.008 0.02263 0.430 0.0058
0.004 0.00161 0.281 -2.794 -0.552
3.545 0.00012 1.752 -3.939 0.244
1.963 0.00011 1.661 -3.953 0.220
11 12 13 14 15
pyrite %oxide %oxide %oxide %oxide %oxide
del13C del34S TOC Na Mg Al Si P
average FH DDH -27.15 12.23 0.62 0.59 2.35 17.11 62.55 0.13
Average Caddo Gap -26.56 -6.357 0.57 0.76 2.41 18.61 62.51 0.19
average Hot Springs 0.621 0.71 2.25 20.22 58.48 0.23
average Little Rock 1.02 0.10 0.50 12.32 79.82 0.04
overall average 0.60 2.12 17.69 63.36 0.16
16 19 20 22 23 24 25 26 27 28 29 30 37
%element%oxide %oxide %oxide ppm ppm %oxide %oxide ppm ppm ppm ppm ppm
TS K Ca Ti V Cr Mn Fe Co Ni Cu Zn Rb
2.23 3.78 0.91 0.81 131 124 0.09 5.83 18 67 62 201 166
0.035 3.33 0.93 0.86 123 92 0.06 6.73 20 52 28 177 153
0.072 3.90 1.38 1.08 152 87 0.06 6.80 18 42 32 148 165
0.078 2.23 0.01 0.62 144 142 0.01 1.66 3 33 26 48 135
3.54 0.94 0.87 136 112 0.07 5.82 17 55 44 161 159
38 39 40 41 42 56 82 90 92
ppm ppm ppm ppm ppm ppm ppm ppm ppm %
Sr Y Zr Nb Mo Ba Pb Th U BaO
136 151 0.88 7934 19.3 12.3 2.8 0.89
110 165 0.63 688 21.4 14.0 2.6 0.08
118 188 0.62 726 19.3 14.4 3.3 0.08
52 147 0.50 1445 23.4 10.8 3.5 0.16
117 163 0.77 3751 20.0 13.0 3.0 0.42
δ13C δ34S TOC Na Mg Al Si
6 11 12 13 14
SDO1 -29.9 -25 9.68 0.38 1.54 12.3 49.3
min sh/SDO1 0.908 -0.507 0.0720 1.483 1.497 1.421 1.271
unmin sh/SDO1 0.888 0.254 0.0588 2.123 1.660 1.606 1.220
log min/SDO1 -1.1425 0.171154 0.175341 0.152657 0.104193
log unmin/SDO1 -1.23062 0.327035 0.220188 0.205695 0.086382
P S K Ca Ti V Cr Mn Fe
15 16 19 20 22 23 24 25 26
0.11 5.35 3.35 1.05 0.71 160 66.4 0.042 9.34
1.186 0.399 1.145 0.822 1.169 0.884 2.021 2.204 0.622
1.837 0.007 1.059 0.939 1.287 0.813 1.415 1.506 0.767
0.07408 -0.3995 0.058794 -0.08514 0.067783 -0.05357 0.305477 0.343118 -0.20647
0.264014 -2.18157 0.02481 -0.0273 0.109616 -0.08973 0.150652 0.177736 -0.11515
Co Ni Cu Zn Rb Sr Y Zr Nb
27 28 29 30 37 38 39 40 41
46.8 99.5 60.2 64.1 126 75 40.6 165 11.4
0.412 0.702 1.078 2.919 1.370 1.236 0.767 0.880 1.344
0.442 0.552 0.496 2.935 1.289 1.548 0.864 0.998 1.435
-0.38544 -0.15397 0.032425 0.465293 0.136838 0.092018 -0.11502 -0.05527 0.12855
-0.35498 -0.25799 -0.30441 0.467608 0.110215 0.189896 -0.0635 -0.00098 0.156736
Mo Ba Pb Th U
42 56 82 90 92
134 397 27.9 10.5 48.8 0.004 0.00161
0.006 9.046 0.729 1.208 0.059 3.545 0.00012
0.003 1.844 0.805 1.391 0.055 1.963 0.00011
-2.19177 0.956454 -0.1374 0.082158 -1.23104
-2.48037 0.265722 -0.09407 0.143362 -1.25706
0.281 -2.794 -0.552
1.752 -3.939 0.244
1.661 -3.953 0.220
10.0
9.0
Mineralized shale
8.0
Unmineralized shale
7.0
6.0
Ratio to SDO1
5.0
4.0
3.0
2.0
1.0
0.0
0 10 20 30 40 50 60 70 80 90 100
Atomic Number
1.5
Mineralized shale
Ba
1.0 Unmineralized shale
0.5
0.0
Log ppm/ ppm SDO1
-0.5
-1.0
TOC
-1.5 U
-2.0
S
-2.5 Mo
-3.0
0 20 40 60 80 100
Atomic Number
1.0
0.5
0.0
Log ppm/ ppm SDO1
-0.5
-1.0
TOC U
-1.5
-2.0
S
-2.5
Mo
-3.0
0 20 40 60 80 100
Atomic Number
Results ppm
Sr Rb Y Zr Nb
DDH103-92 109.8 211 32.2 208 19.2 DDH103 92
DDH103-99.5 94.6 217 34.7 176 18.9 DDH103 99.5
DDH103-104.2 84.6 232 28.6 140 18.4 DDH103 104.25
DDH103-112.5 76.3 236 31.1 163 19.4 DDH103 112.5
DDH103-117 76.7 157 33.3 126 12.7 DDH103 117
DDH103-134.5 67.5 178 23.3 132 13.1 DDH103 134.5
DDH103-136.0 151.3 162 29.7 124 11.1 DDH103 136
DDH103-138 55.8 181 22.0 128 14.1 DDH103 138
DDH103-164.3 77.3 216 39.6 263 21.8 DDH103 164.3
DDH103-165.5 68.6 176 36.5 154 15.9 DDH103 165.5
DDH103-179.2 56.1 263 34.2 151 21.0 DDH103 179.2
DDH103-181 98.6 269 35.3 162 19.7 DDH103 181
DDH103-296 93.1 232 35.3 147 16.8 DDH103 296
DDH103-302.3 73.7 260 31.1 146 17.9 DDH103 302.3
DDH103-310 76.0 206 38.8 168 18.6 DDH103 310
DDH103-339.5 67.2 200 27.8 142 14.9 DDH103 339.5
DDH103-357.2 303.5 164 32.9 133 13.2 DDH103 357.2
DDH103-387.1 102.8 198 26.8 151 15.5 DDH103 387.1
DDH103-388 107.5 186 27.7 167 15.2 DDH103 388
DDH103-403.5 144.6 172 24.9 119 14.0 DDH103 403.5
DDH119-196.5 36.9 105 25.8 110 10.6 DDH119 196.5
DDH119-206 12.0 8 10.4 21 2.0 DDH119 206
DDH40335 84.4 210 28.0 134 15.9 DDH40 335
DDH40-345 726.4 130 26.0 121 10.2 DDH40 345
DDH40-358.5 834.3 60 15.9 93 5.7 DDH40 358.5
DDH40-373.5 94.2 157 32.4 151 14.4 DDH40 373.5
DDH40-3751 63.1 160 24.9 123 14.5 DDH40 375
DDH40-388.5 38.5 143 27.6 114 10.8 DDH40 388.5
DDH40-390 43.7 174 28.8 147 14.1 DDH40 390
DDH40-405 52.2 187 26.3 143 14.4 DDH40 405
DDH40405.5 40.5 194 46.0 147 13.0 DDH40 405.5
MDDH5-220 92.4 186 40.6 155 18.1 MDDH5 220
DDH5-227.5 149.3 210 46.0 156 15.6 MDDH5 227.5
MDDH5-229.0 13.3 5 12.4 19 1.9 MDDH5 229
GWS1 89.4 128 30.0 142 15.2 GWS 1
GWS2 94.2 166 31.2 147 15.9 GWS 2
GWS3 105.1 208 41.6 168 17.5 GWS 3
GWS4 99.2 214 37.9 180 18.7 GWS 4
GWS5 93.1 209 31.8 150 16.3 GWS 5
GWS6 82.1 131 30.7 148 15.1 GWS 6
GWS7 108.7 197 39.4 165 18.4 GWS 7
GWS8 100.9 196 36.1 171 18.2 GWS 8
GWS9 106.8 151 35.6 200 15.5 GWS 9
GWS10 110.4 218 35.9 163 18.1 GWS 10
GWS11 88.6 109 33.3 200 16.6 GWS 11
GWS12 102.1 141 31.9 211 15.7 GWS 12
xxxx 90.2 208 30.8 133 14.4 GWS 13
GWS15 103.9 165 39.9 147 15.4 GWS 15
GWS16 117.0 160 39.9 145 14.3 GWS 16
GWS14 8.3 9 9.5 19 2.5
HSS1E 43.3 188 28.9 159 15.9 HSS 1E
HSS2E 83.8 211 32.6 180 18.9 HSS 2E
HSS3E 96.3 155 29.4 155 18.1 HSS 3E
HSS4E 891.3 37 27.4 326 149.3 HSS 4E
HSS5E 77.2 216 38.9 258 23.0 HSS 5E
HSS6E 61.4 105 28.6 197 13.9 HSS 6E
HSS7E 145.7 175 36.0 223 17.0 HSS 7E
HSS8E 69.6 154 28.9 140 15.1 HSS 83
HSS9E 66.8 223 33.8 180 19.9 HSS 9E
HSS10E 69.2 175 32.7 210 17.9 HSS 10E
HSS11E 53.3 156 31.5 119 12.3 HSS 11E
HSW1 65.2 183 34.4 152 16.5 HS W 1
HSW2 70.1 185 34.0 152 17.6 HS W 2
HSW3 73.1 173 37.3 163 17.0 HS W 3
HSW4 71.1 218 37.6 212 18.7 HS W 4
HSW5 70.6 234 36.3 165 18.5 HS W 5
HSW6 68.5 249 35.1 157 17.3 HS W 6
HSW7 61.0 172 30.6 159 15.8 HS W 7
HSW8 72.1 216 35.2 162 18.3 HS W 8
HSW9 75.9 194 35.8 175 18.5 HS W 9
HSW10 66.9 195 35.8 138 15.5 HS W 10
LRS1 36.4 132 30.6 134 14.3 LRS 1
LRS2 33.9 155 31.8 150 16.2 LRS 2
LRS3 46.0 183 33.3 147 14.3 LRS 3
LRS4 55.8 154 46.8 150 16.3 LRS 4
LRS5 36.2 112 40.0 112 11.3 LRS 5
LRS6 56.6 140 33.7 140 14.9 LRS 6
LRS7 41.0 141 29.1 139 15.5 LRS 7
SDO1 70.9 113 39.7 144 11.4
Calibrations
ref 0.6743 8.2303
Measured Corrected
Nb Zr Y Sr Rb Nb Nb-0.08Y Zr
SDO1 0.7119 8.2353 1.8637 2.84 3.813 0.67433 0.4657 8.2303
GWS16 0.89323 8.4495 2.2084 4.6854 5.4025 0.8461 0.5989 8.4444
LRS16 0.83005 7.5465 1.702 1.4576 4.4473 0.7862 0.5957 7.5419
DDH40-373.5 0.86476 8.6933 1.9425 3.7718 5.3008 0.8191 0.6017 8.6880
GWS12 0.90917 12.333 1.81 4.0893 4.7517 0.8612 0.6586 12.3255
HSS7E 1.0186 13.155 2.1907 5.8342 5.9097 0.9648 0.7196 13.1470
HSW9 1.1057 10.082 2.3178 3.0392 6.5452 1.0473 0.7879 10.0759
GWS3 1.0918 9.7403 2.6043 4.2082 6.9946 1.0342 0.7426 9.7344
GWS11 0.93225 11.591 1.6288 3.55 3.6871 0.8831 0.7007 11.5840
HSW3 1.0207 9.3433 2.2111 2.9272 5.8163 0.9668 0.7193 9.3376
GWS8 1.0937 9.9041 2.3408 4.0417 6.6031 1.0360 0.7739 9.8981
HSW2 1.0461 8.6795 2.1919 2.8078 6.2358 0.9909 0.7455 8.6742
GWS4 1.1387 10.44 2.5316 3.9716 7.2272 1.0786 0.7952 10.4337
GWS7 1.1187 9.606 2.4602 4.3541 6.6548 1.0597 0.7842 9.6002
HSS2E 1.1256 10.435 2.3324 3.3578 7.1091 1.0662 0.8051 10.4287
HSS10E 1.0495 12.156 2.0759 2.7734 5.8803 0.9941 0.7617 12.1486
HSW10 0.96084 7.8833 2.3212 2.6792 6.5542 0.9101 0.6503 7.8785
DDH103-136.0 0.70012 7.2714 1.8884 6.0605 5.4716 0.6632 0.4518 7.2670
DDH103-302.3 1.1124 8.3881 2.6374 2.9525 8.7658 1.0537 0.7584 8.3830
DDH103-138 0.83041 7.2275 1.7722 2.2362 6.1019 0.7866 0.5882 7.2231
HSW8 1.1101 9.2953 2.4546 2.8891 7.2803 1.0515 0.7767 9.2897
LRS6 0.8777 7.9328 1.8583 2.2656 4.7066 0.8314 0.6233 7.9280
HSW7 0.93708 9.1094 1.9884 2.443 5.8003 0.8876 0.6650 9.1039
DDH40-405 0.86582 8.1281 1.9542 2.0924 6.3024 0.8201 0.6014 8.1232
HSS1E 0.94923 9.0337 2.0488 1.7328 6.3344 0.8991 0.6698 9.0282
DDH40-358.5 0.29921 7.4198 0.70407 33.417 2.0298 0.2834 0.2046 7.4153
xxxx 0.90137 7.619 2.2546 3.6112 7.0136 0.8538 0.6014 7.6144
DDH103-310 1.1339 9.6844 2.5042 3.0424 6.9576 1.0741 0.7937 9.6785
DDH103-117 0.78597 7.174 1.9644 3.0713 5.274 0.7445 0.5246 7.1696
DDH103-104.2 1.103 8.0262 2.3514 3.3903 7.8014 1.0448 0.7816 8.0213
LRS4 1.0105 8.5446 2.3877 2.2338 5.177 0.9572 0.6899 8.5394
HSW4 1.1408 12.285 2.5442 2.8471 7.3295 1.0806 0.7958 12.2775
DDH103-296 1.0535 8.4531 2.5749 3.7299 7.8182 0.9979 0.7096 8.4480
DDH103-92 1.14 12.168 2.3246 4.3963 7.1264 1.0798 0.8196 12.1606
GWS15 0.9503 8.5111 2.2444 4.1634 5.5709 0.9001 0.6489 8.5059
DDH40-345 0.61318 8.7788 1.5394 29.096 4.3926 0.5808 0.4085 8.7735
SDO1IUPW 0.7121 8.2463 1.8673 2.8142 3.8227 0.6743 0.4657 8.2303
DDH119-206 0.05811 0.73641 0.15198 0.47787 0.27768 0.0550 0.0380 0.7350
HSS6E 0.78105 11.397 1.4457 2.4362 3.5468 0.7396 0.5781 11.3749
DDH103-403.5 0.82831 6.9993 1.8059 5.74 5.8168 0.7844 0.5826 6.9857
DDH40-390 0.85067 8.3271 1.9485 1.7357 5.8874 0.8056 0.5878 8.3109
HSW5 1.1416 9.4904 2.6238 2.8008 7.8983 1.0810 0.7879 9.4720
SDO1IUPW 0.73376 8.2614 1.8586 2.7873 3.8327 0.6743 0.4657 8.2303
LRS3 0.91045 8.3465 2.149 1.808 6.1979 0.8367 0.5955 8.3151
DDH103-388 0.93772 9.7299 1.9886 4.2264 6.3066 0.8618 0.6385 9.6933
DDH40-388.5 0.68228 6.3981 1.6788 1.5117 4.8506 0.6270 0.4386 6.3740
DDH103-387.1 0.95753 8.8013 2.0425 4.0409 6.6934 0.8800 0.6507 8.7682
MDDH5-229.0 0.05912 0.65459 0.1941 0.52154 0.16831 0.0543 0.0325 0.6521
DDH119-196.5 0.62955 6.1428 1.3426 1.4501 3.5419 0.5786 0.4278 6.1197
DDH5-227.5 1.0513 9.1941 2.7572 5.8672 7.1168 0.9662 0.6566 9.1595
HSW6 1.1264 9.034 2.6794 2.6908 8.4272 1.0352 0.7344 9.0000
DDH103-339.5 0.93241 8.1242 2.0918 2.6414 6.7665 0.8569 0.6221 8.0936
LRS2 0.97416 8.5087 1.8999 1.3323 5.2515 0.8953 0.6820 8.4767
DDH103-134.5 0.80747 7.5586 1.7855 2.6517 6.0254 0.7421 0.5416 7.5301
HSS11E 0.78272 6.6957 1.9014 2.0957 5.3002 0.7193 0.5059 6.6705
HSS3E 1.0608 8.9785 1.8239 3.7863 5.2584 0.9749 0.7701 8.9447
GWS10 1.1403 9.54 2.4834 4.3387 7.3674 1.0479 0.7692 9.5041
DDH40405.5 0.90564 8.3647 2.6444 1.5937 6.583 0.8323 0.5354 8.3332
LRS5 0.72757 6.2659 1.8584 1.4248 3.7837 0.6686 0.4600 6.2423
GWS9 0.95129 11.694 1.9998 4.1991 5.1257 0.8742 0.6498 11.6500
SDO1IUPW 0.70686 8.2178 1.8595 2.8288 3.8213 0.6743 0.4657 8.2303
HSS4E 7.1687 21.455 0.911 35.56 1.2408 6.8388 6.7366 21.4876
HSS8E 0.87499 8.0047 1.7963 2.7778 5.1927 0.8347 0.6332 8.0169
GWS1 0.8613 8.1488 1.6478 3.5677 4.3206 0.8217 0.6368 8.1612
HSS5E 1.344 15.032 2.5735 3.0792 7.3028 1.2821 0.9934 15.0549
GWS6 0.86532 8.4944 1.6965 3.2759 4.4336 0.8255 0.6351 8.5073
DDH103-165.5 0.96041 8.781 2.2094 2.7353 5.9589 0.9162 0.6683 8.7944
HSS9E 1.1829 10.345 2.4549 2.6663 7.534 1.1285 0.8530 10.3607
DDH103-181 1.2155 9.345 2.8325 3.9327 9.0902 1.1596 0.8417 9.3592
LRS7 0.88572 7.854 1.7082 1.6346 4.7469 0.8450 0.6533 7.8659
DDH103-99.5 1.1308 10.177 2.4435 3.7744 7.3397 1.0788 0.8046 10.1925
DDH103-357.2 0.80757 8.2554 2.0053 12.11 5.549 0.7704 0.5454 8.2680
SDO1IUPW 0.68047 8.2389 1.8594 2.8006 3.8179 0.6743 0.4657 8.2303
MDDH5-220 1.0499 8.9544 2.4098 3.6496 6.2698 1.0404 0.7700 8.9451
DDH40-3751 0.80719 6.9864 1.7098 2.4935 5.3848 0.7999 0.6081 6.9791
DDH103-179.2 1.2222 8.5915 2.7539 2.2147 8.8773 1.2112 0.9022 8.5825
DDH103-164.3 1.2413 15.316 2.5933 3.0515 7.2953 1.2301 0.9391 15.3000
DDH103-112.5 1.1149 9.3797 2.4597 3.0141 7.9651 1.1048 0.8288 9.3699
SDO1IUPW 0.72432 8.2094 1.8416 2.8472 3.8289 0.6743 0.4657 8.2303
GWS14 0.08092 0.63666 0.12578 0.33253 0.31138 0.0753 0.0611 0.6383
HSW1 1.0131 8.657 2.1666 2.6175 6.1959 0.9432 0.6977 8.6790
DDH40335 0.97896 7.6673 2.1512 3.3872 7.1035 0.9114 0.6677 7.6868
GWS2 0.95477 8.4647 1.9426 3.7837 5.6286 0.8889 0.6688 8.4862
GWS5 1.0159 8.632 2.266 3.7401 7.0663 0.9458 0.6891 8.6540
2.6080 2.7743 3.8548
ppm
Zr-0.075Sr Y Y-.295Rb Sr Rb Nb Zr Y Sr Rb
8.0222 2.608 1.4708 2.7743 3.8548 #REF! #REF! #REF! #REF! #REF!
8.1011 3.0904 1.4792 4.5770 5.4617 #REF! #REF! #REF! #REF! #REF!
7.4351 2.3817 1.0554 1.4239 4.4961 #REF! #REF! #REF! #REF! #REF!
8.4117 2.7183 1.1374 3.6845 5.3589 #REF! #REF! #REF! #REF! #REF!
12.0259 2.5329 1.1157 3.9947 4.8038 #REF! #REF! #REF! #REF! #REF!
12.7196 3.0656 1.3031 5.6992 5.9745 #REF! #REF! #REF! #REF! #REF!
9.8532 3.2435 1.2915 2.9689 6.6170 #REF! #REF! #REF! #REF! #REF!
9.4261 3.6444 1.5583 4.1108 7.0713 #REF! #REF! #REF! #REF! #REF!
11.3239 2.2793 1.1797 3.4679 3.7275 #REF! #REF! #REF! #REF! #REF!
9.1232 3.0941 1.3595 2.8595 5.8801 #REF! #REF! #REF! #REF! #REF!
9.6020 3.2756 1.3064 3.9482 6.6755 #REF! #REF! #REF! #REF! #REF!
8.4685 3.0673 1.2075 2.7428 6.3042 #REF! #REF! #REF! #REF! #REF!
10.1427 3.5426 1.3872 3.8797 7.3064 #REF! #REF! #REF! #REF! #REF!
9.2812 3.4427 1.4580 4.2534 6.7278 #REF! #REF! #REF! #REF! #REF!
10.1827 3.2639 1.1437 3.2801 7.1870 #REF! #REF! #REF! #REF! #REF!
11.9454 2.9049 1.1512 2.7092 5.9448 #REF! #REF! #REF! #REF! #REF!
7.6822 3.2482 1.2935 2.6172 6.6261 #REF! #REF! #REF! #REF! #REF!
6.8230 2.6426 1.0107 5.9203 5.5316 #REF! #REF! #REF! #REF! #REF!
8.1667 3.6907 1.0764 2.8842 8.8619 #REF! #REF! #REF! #REF! #REF!
7.0593 2.4800 0.6602 2.1845 6.1688 #REF! #REF! #REF! #REF! #REF!
9.0780 3.4349 1.2637 2.8223 7.3601 #REF! #REF! #REF! #REF! #REF!
7.7620 2.6004 1.1968 2.2132 4.7582 #REF! #REF! #REF! #REF! #REF!
8.9249 2.7825 1.0527 2.3865 5.8639 #REF! #REF! #REF! #REF! #REF!
7.9699 2.7346 0.8551 2.0440 6.3715 #REF! #REF! #REF! #REF! #REF!
8.9013 2.8670 0.9779 1.6927 6.4038 #REF! #REF! #REF! #REF! #REF!
4.9670 0.9853 0.3799 32.6439 2.0521 #REF! #REF! #REF! #REF! #REF!
7.3498 3.1550 1.0633 3.5277 7.0905 #REF! #REF! #REF! #REF! #REF!
9.4556 3.5043 1.4293 2.9720 7.0339 #REF! #REF! #REF! #REF! #REF!
6.9446 2.7489 1.1760 3.0002 5.3318 #REF! #REF! #REF! #REF! #REF!
7.7729 3.2905 0.9638 3.3119 7.8869 #REF! #REF! #REF! #REF! #REF!
8.3758 3.3413 1.7973 2.1821 5.2338 #REF! #REF! #REF! #REF! #REF!
12.0689 3.5603 1.3744 2.7812 7.4098 #REF! #REF! #REF! #REF! #REF!
8.1747 3.6032 1.2716 3.6436 7.9039 #REF! #REF! #REF! #REF! #REF!
11.8385 3.2530 1.1276 4.2946 7.2045 #REF! #REF! #REF! #REF! #REF!
8.2009 3.1407 1.4793 4.0671 5.6320 #REF! #REF! #REF! #REF! #REF!
6.6418 2.1542 0.8442 28.4229 4.4408 #REF! #REF! #REF! #REF! #REF!
8.0222 2.6080 1.4708 2.7743 3.8548 #REF! #REF! #REF! #REF! #REF!
0.6996 0.2123 0.1297 0.4711 0.2800 #REF! #REF! #REF! #REF! #REF!
11.1948 2.0192 0.9641 2.4017 3.5766 #REF! #REF! #REF! #REF! #REF!
6.5613 2.5222 0.7919 5.6586 5.8656 #REF! #REF! #REF! #REF! #REF!
8.1826 2.7214 0.9700 1.7111 5.9368 #REF! #REF! #REF! #REF! #REF!
9.2649 3.6646 1.3150 2.7611 7.9646 #REF! #REF! #REF! #REF! #REF!
8.0222 2.6080 1.4708 2.7743 3.8548 #REF! #REF! #REF! #REF! #REF!
8.1801 3.0155 1.1766 1.7996 6.2336 #REF! #REF! #REF! #REF! #REF!
9.3778 2.7904 0.9192 4.2067 6.3430 #REF! #REF! #REF! #REF! #REF!
6.2612 2.3557 0.9165 1.5046 4.8786 #REF! #REF! #REF! #REF! #REF!
8.4665 2.8660 0.8801 4.0221 6.7320 #REF! #REF! #REF! #REF! #REF!
0.6132 0.2724 0.2224 0.5191 0.1693 #REF! #REF! #REF! #REF! #REF!
6.0114 1.8839 0.8331 1.4433 3.5623 #REF! #REF! #REF! #REF! #REF!
8.7215 3.8689 1.7574 5.8398 7.1578 #REF! #REF! #REF! #REF! #REF!
8.7991 3.7598 1.2594 2.6783 8.4758 #REF! #REF! #REF! #REF! #REF!
7.8964 2.9352 0.9276 2.6291 6.8055 #REF! #REF! #REF! #REF! #REF!
8.3772 2.6660 1.1078 1.3261 5.2818 #REF! #REF! #REF! #REF! #REF!
7.3322 2.5054 0.7177 2.6393 6.0601 #REF! #REF! #REF! #REF! #REF!
6.5140 2.6681 1.0955 2.0859 5.3308 #REF! #REF! #REF! #REF! #REF!
8.6621 2.5593 0.9991 3.7686 5.2887 #REF! #REF! #REF! #REF! #REF!
9.1802 3.4847 1.2988 4.3185 7.4099 #REF! #REF! #REF! #REF! #REF!
8.2142 3.7106 1.7575 1.5863 6.6210 #REF! #REF! #REF! #REF! #REF!
6.1360 2.6077 1.4851 1.4182 3.8055 #REF! #REF! #REF! #REF! #REF!
11.3365 2.8061 1.2853 4.1795 5.1553 #REF! #REF! #REF! #REF! #REF!
8.0222 2.6080 1.4708 2.7743 3.8548 #REF! #REF! #REF! #REF! #REF!
18.8720 1.2777 0.9085 34.8749 1.2517 #REF! #REF! #REF! #REF! #REF!
7.8126 2.5194 0.9741 2.7243 5.2382 #REF! #REF! #REF! #REF! #REF!
7.8988 2.3111 1.0253 3.4990 4.3585 #REF! #REF! #REF! #REF! #REF!
14.8284 3.6094 1.4362 3.0199 7.3668 #REF! #REF! #REF! #REF! #REF!
8.2664 2.3794 1.0600 3.2128 4.4725 #REF! #REF! #REF! #REF! #REF!
8.5932 3.0987 1.3255 2.6826 6.0111 #REF! #REF! #REF! #REF! #REF!
10.1646 3.4431 1.2011 2.6149 7.6000 #REF! #REF! #REF! #REF! #REF!
9.0699 3.9727 1.2675 3.8569 9.1699 #REF! #REF! #REF! #REF! #REF!
7.7457 2.3958 0.9832 1.6031 4.7885 #REF! #REF! #REF! #REF! #REF!
9.9149 3.4271 1.2429 3.7017 7.4040 #REF! #REF! #REF! #REF! #REF!
7.3772 2.8125 1.1612 11.8767 5.5976 #REF! #REF! #REF! #REF! #REF!
8.0222 2.6080 1.4708 2.7743 3.8548 #REF! #REF! #REF! #REF! #REF!
8.6739 3.3800 1.5125 3.6153 6.3304 #REF! #REF! #REF! #REF! #REF!
6.7939 2.3982 0.7943 2.4701 5.4368 #REF! #REF! #REF! #REF! #REF!
8.4180 3.8626 1.2185 2.1939 8.9631 #REF! #REF! #REF! #REF! #REF!
15.0733 3.6374 1.4645 3.0228 7.3658 #REF! #REF! #REF! #REF! #REF!
9.1460 3.4500 1.0776 2.9858 8.0421 #REF! #REF! #REF! #REF! #REF!
8.0222 2.6080 1.4708 2.7743 3.8548 #REF! #REF! #REF! #REF! #REF!
0.6140 0.1781 0.0856 0.3240 0.3135 #REF! #REF! #REF! #REF! #REF!
8.4878 3.0683 1.2281 2.5505 6.2378 #REF! #REF! #REF! #REF! #REF!
7.4393 3.0464 0.9367 3.3005 7.1516 #REF! #REF! #REF! #REF! #REF!
8.2097 2.7510 1.0794 3.6868 5.6667 #REF! #REF! #REF! #REF! #REF!
8.3807 3.2090 1.1104 3.6443 7.1141 #REF! #REF! #REF! #REF! #REF!
Stanley Shale at Fancy Hill barite mine
TOC del13C Na Mg Al Si P S del34S K Ca Ti V Cr
TOC 1.00
del13C -0.50 1.00
Na -0.28 0.48 1.00
Mg -0.14 0.50 0.73 1.00
Al 0.28 0.39 0.56 0.82 1.00
Si -0.31 -0.30 -0.54 -0.80 -0.90 1.00
P 0.22 0.26 0.39 0.38 0.53 -0.57 1.00
S 0.01 -0.39 -0.41 -0.56 -0.69 0.47 -0.35 1.00
del34S -0.38 0.47 -0.03 0.35 0.14 -0.10 -0.18 -0.15 1.00
K 0.24 0.47 0.59 0.81 0.97 -0.89 0.63 -0.67 0.12 1.00
Ca -0.26 -0.03 0.39 0.34 0.13 -0.26 0.25 -0.05 -0.04 0.07 1.00
Ti 0.25 0.44 0.56 0.80 0.99 -0.88 0.57 -0.71 0.13 0.98 0.12 1.00
V 0.31 0.26 0.02 0.54 0.74 -0.59 0.20 -0.49 0.37 0.67 -0.18 0.71 1.00
Cr 0.79 -0.36 -0.36 0.10 0.35 -0.39 -0.01 -0.04 0.02 0.30 -0.37 0.30 0.61 1.00
Mn -0.13 -0.31 -0.07 0.19 0.05 -0.17 -0.14 -0.01 0.22 -0.10 0.60 0.00 0.19 0.05
Fe -0.42 0.44 0.22 0.43 0.17 -0.34 0.10 0.08 0.60 0.15 0.43 0.15 0.27 -0.11
Co 0.06 0.30 0.10 0.39 0.51 -0.50 0.47 -0.28 0.33 0.49 0.38 0.51 0.53 0.12
Ni 0.67 -0.39 -0.33 0.16 0.39 -0.44 0.07 -0.10 0.06 0.30 -0.09 0.34 0.64 0.86
Cu 0.50 -0.21 -0.37 0.15 0.18 -0.22 -0.12 0.06 0.27 0.16 -0.29 0.14 0.53 0.86
Zn -0.01 0.00 0.18 0.63 0.42 -0.54 0.05 -0.22 0.35 0.39 0.16 0.37 0.44 0.42
Rb 0.24 0.50 0.54 0.75 0.96 -0.82 0.55 -0.71 0.13 0.96 0.00 0.97 0.75 0.29
Sr 0.21 -0.35 0.17 -0.03 -0.04 -0.14 0.25 0.17 -0.58 0.02 0.26 -0.01 -0.50 -0.05
Zr 0.29 0.35 0.56 0.74 0.94 -0.82 0.48 -0.71 -0.01 0.90 0.18 0.94 0.61 0.29
Mo 0.35 -0.50 -0.27 -0.57 -0.50 0.31 0.00 0.62 -0.43 -0.49 -0.08 -0.51 -0.56 -0.03
Ba 0.15 -0.36 0.06 -0.10 -0.14 -0.06 0.12 0.24 -0.56 -0.07 0.23 -0.11 -0.51 -0.03
Pb 0.01 0.45 0.56 0.42 0.56 -0.43 0.55 -0.49 -0.08 0.58 0.33 0.58 0.27 -0.20
Th 0.15 0.57 0.59 0.73 0.92 -0.76 0.57 -0.71 0.18 0.92 0.10 0.93 0.69 0.14
U 0.40 -0.24 0.06 0.19 0.32 -0.32 0.14 -0.13 -0.19 0.26 -0.06 0.29 0.22 0.31
Mn Fe Co Ni Cu Zn Rb Sr Zr Mo Ba Pb Th U
Fine clastics cluster K Ti Rb Al Th Zr
Metals cluster Cu Ni
Barite cluster Ba Sr
1.00
0.47 1.00
0.35 0.56 1.00
0.36 0.07 0.45 1.00
0.06 0.05 0.12 0.71 1.00
0.42 0.40 0.20 0.48 0.57 1.00
-0.07 0.16 0.52 0.31 0.12 0.30 1.00
-0.15 -0.42 -0.33 -0.08 -0.15 0.01 -0.18 1.00
0.00 0.00 0.36 0.30 0.09 0.31 0.89 0.09 1.00
-0.15 -0.28 -0.31 -0.10 -0.18 -0.41 -0.52 0.37 -0.47 1.00
-0.11 -0.39 -0.36 -0.07 -0.08 0.03 -0.28 0.97 -0.01 0.29 1.00
-0.09 0.18 0.64 0.01 -0.31 -0.16 0.64 -0.18 0.55 -0.27 -0.28 1.00
-0.08 0.22 0.58 0.20 0.01 0.18 0.96 -0.23 0.86 -0.47 -0.34 0.72 1.00
-0.05 -0.15 -0.04 0.33 -0.02 0.14 0.27 0.21 0.35 0.23 0.09 0.05 0.22 1.00
TOC del13C Na Mg Al Si P S del34S K Ca Ti
TOC 1.00
del13C -0.70 1.00
Na -0.39 0.54 1.00 Fine clastics cluster
Mg 0.17 0.19 0.01 1.00
Al 0.31 -0.38 0.01 0.14 1.00 Metals cluster
Si -0.44 0.27 0.17 -0.62 -0.83 1.00
P 0.16 0.03 -0.16 0.39 0.43 -0.62 1.00
S -0.14 0.14 0.08 -0.01 0.08 -0.03 0.09 1.00
del34S -0.26 -0.02 0.25 -0.41 -0.15 0.37 0.03 0.12 1.00
K 0.40 -0.38 0.00 0.22 0.91 -0.83 0.35 0.15 -0.30 1.00
Ca -0.17 0.36 -0.38 0.39 -0.26 -0.10 0.47 0.26 -0.26 -0.23 1.00
Ti 0.48 -0.34 0.12 0.21 0.88 -0.78 0.49 0.30 0.00 0.85 -0.25 1.00
V 0.30 -0.08 0.31 0.42 0.73 -0.70 0.30 0.19 -0.31 0.69 -0.31 0.78
Cr 0.48 -0.19 0.20 0.51 0.52 -0.67 0.24 -0.02 -0.31 0.74 -0.30 0.63
Mn -0.04 0.27 -0.27 0.08 -0.17 0.00 0.16 0.70 -0.28 -0.06 0.75 -0.05
Fe 0.18 0.01 -0.44 0.67 -0.18 -0.29 0.29 -0.40 -0.12 -0.22 0.42 -0.22
Co 0.06 0.29 0.47 0.68 0.32 -0.48 -0.04 0.26 -0.38 0.41 -0.06 0.43
Ni 0.30 0.08 0.22 0.46 0.08 -0.25 -0.27 0.33 -0.51 0.28 -0.18 0.26
Cu 0.18 0.12 0.19 0.67 0.24 -0.47 0.09 0.47 -0.27 0.31 0.00 0.41
Zn 0.10 0.04 -0.39 0.54 0.06 -0.37 0.16 0.55 -0.62 0.18 0.58 0.10
Rb 0.43 -0.34 0.08 0.12 0.79 -0.70 0.24 0.26 -0.22 0.95 -0.30 0.83
Sr -0.17 0.21 0.10 -0.01 0.39 -0.31 0.61 0.37 -0.07 0.35 0.44 0.40
Zr -0.26 -0.03 0.24 -0.67 0.26 0.23 -0.11 0.18 0.19 0.01 -0.27 0.13
Mo -0.37 0.26 0.03 -0.48 -0.02 0.31 -0.08 -0.08 0.23 -0.29 -0.23 -0.12
Ba 0.33 -0.43 0.02 0.07 0.74 -0.62 0.04 -0.02 -0.17 0.89 -0.45 0.62
Pb 0.13 0.10 -0.53 0.45 -0.17 -0.20 0.32 -0.12 -0.56 -0.22 0.69 -0.23
Th 0.21 -0.17 0.28 0.01 0.73 -0.55 0.03 -0.03 -0.16 0.85 -0.46 0.65
U 0.44 -0.63 -0.83 -0.08 0.36 -0.40 0.25 0.18 -0.10 0.41 0.20 0.28
V Cr Mn Fe Co Ni Cu Zn Rb Sr Zr Mo Ba Pb
Fine clastics cluster K Ti Rb Ba Th
Metals cluster Cu Ni
1.00
0.63 1.00
-0.13 -0.24 1.00
-0.15 0.05 -0.08 1.00
0.67 0.58 0.07 0.04 1.00
0.60 0.56 0.18 -0.05 0.76 1.00
0.67 0.55 0.20 0.19 0.76 0.84 1.00
0.24 0.13 0.69 0.20 0.41 0.52 0.59 1.00
0.62 0.79 0.00 -0.33 0.42 0.38 0.35 0.14 1.00
0.16 -0.03 0.42 -0.36 0.05 -0.30 -0.19 0.19 0.28 1.00
0.07 -0.41 -0.01 -0.70 -0.28 -0.31 -0.31 -0.28 -0.01 0.33 1.00
-0.08 -0.40 -0.17 -0.19 -0.32 -0.28 -0.23 -0.30 -0.28 -0.03 0.56 1.00
0.49 0.72 -0.26 -0.19 0.30 0.26 0.21 -0.04 0.89 0.01 -0.10 -0.31 1.00
0.00 -0.26 0.42 0.56 -0.01 0.04 0.08 0.58 -0.39 0.12 -0.31 -0.11 -0.43 1.00
0.49 0.70 -0.25 -0.35 0.41 0.22 0.13 -0.17 0.88 0.20 0.08 -0.12 0.89 -0.55
-0.06 0.07 0.31 0.18 -0.33 -0.13 -0.03 0.34 0.38 0.04 -0.14 -0.13 0.42 0.17
Th U
1.00
0.14 1.00
TOC del13C Na Mg Al Si P S del34S K Ca Ti
TOC 1.00
del13C -0.49 1.00
Na -0.29 0.60 1.00
Mg -0.15 0.54 0.71 1.00
Al 0.22 0.45 0.61 0.81 1.00
Si -0.27 -0.35 -0.54 -0.81 -0.91 1.00
P 0.11 0.41 0.53 0.46 0.60 -0.60 1.00
S 0.07 -0.53 -0.60 -0.60 -0.72 0.52 -0.56 1.00
del34S -0.13 -0.12 -0.39 -0.10 -0.24 0.20 -0.49 0.41 1.00
K 0.24 0.39 0.48 0.75 0.91 -0.86 0.51 -0.54 -0.02 1.00
Ca -0.26 0.11 0.37 0.38 0.17 -0.29 0.36 -0.17 -0.24 0.05 1.00
Ti 0.20 0.48 0.60 0.80 0.99 -0.89 0.62 -0.72 -0.20 0.93 0.16 1.00
V 0.30 0.25 0.08 0.54 0.71 -0.60 0.21 -0.43 0.08 0.67 -0.17 0.70
Cr 0.78 -0.40 -0.41 0.03 0.22 -0.30 -0.14 0.12 0.18 0.27 -0.38 0.19
Mn -0.11 -0.30 -0.14 0.14 -0.01 -0.12 -0.16 0.07 0.17 -0.10 0.55 -0.05
Fe -0.37 0.52 0.38 0.52 0.30 -0.41 0.38 -0.26 -0.16 0.12 0.47 0.27
Co 0.03 0.34 0.24 0.44 0.50 -0.51 0.40 -0.31 -0.10 0.47 0.32 0.51
Ni 0.63 -0.41 -0.37 0.08 0.22 -0.31 -0.15 0.10 0.15 0.27 -0.16 0.20
Cu 0.50 -0.28 -0.41 0.07 0.07 -0.14 -0.22 0.19 0.30 0.14 -0.31 0.04
Zn 0.00 0.03 0.10 0.58 0.36 -0.49 0.08 -0.18 -0.01 0.35 0.24 0.32
Rb 0.23 0.43 0.48 0.70 0.91 -0.80 0.47 -0.59 -0.05 0.96 -0.01 0.93
Sr 0.22 -0.34 0.08 -0.06 -0.07 -0.11 0.14 0.19 -0.21 0.02 0.21 -0.04
Zr 0.19 0.42 0.62 0.65 0.89 -0.74 0.52 -0.72 -0.28 0.75 0.19 0.87
Mo 0.34 -0.53 -0.40 -0.61 -0.55 0.38 -0.22 0.67 0.11 -0.46 -0.17 -0.56
Ba 0.17 -0.42 -0.12 -0.17 -0.23 0.03 -0.08 0.36 -0.04 -0.08 0.13 -0.19
Pb 0.00 0.44 0.46 0.44 0.52 -0.43 0.52 -0.47 -0.28 0.49 0.42 0.53
Th 0.09 0.60 0.68 0.72 0.92 -0.76 0.63 -0.76 -0.31 0.82 0.13 0.91
U 0.38 -0.30 -0.10 0.12 0.26 -0.28 0.09 -0.04 -0.04 0.27 -0.03 0.23
V Cr Mn Fe Co Ni Cu Zn Rb Sr Zr Mo
1.00
0.57 1.00
0.16 0.07 1.00
0.25 -0.21 0.30 1.00
0.52 0.06 0.27 0.49 1.00
0.57 0.82 0.36 -0.10 0.42 1.00
0.49 0.86 0.09 -0.08 0.07 0.70 1.00
0.41 0.36 0.43 0.33 0.26 0.45 0.49 1.00
0.74 0.25 -0.08 0.14 0.50 0.27 0.09 0.27 1.00
-0.49 -0.03 -0.12 -0.38 -0.29 -0.05 -0.12 0.01 -0.17 1.00
0.54 0.12 -0.06 0.12 0.29 0.07 -0.03 0.20 0.75 0.04 1.00
-0.53 0.06 -0.09 -0.40 -0.34 0.01 -0.07 -0.37 -0.51 0.36 -0.47 1.00
-0.51 0.04 -0.07 -0.45 -0.35 0.02 0.00 0.02 -0.28 0.95 -0.13 0.36
0.25 -0.23 -0.07 0.30 0.53 -0.04 -0.32 -0.02 0.52 -0.18 0.45 -0.30
0.63 0.01 -0.14 0.36 0.56 0.04 -0.11 0.13 0.88 -0.23 0.80 -0.55
0.17 0.28 0.00 -0.11 -0.13 0.26 0.00 0.18 0.27 0.19 0.20 0.20
Ba Pb Th U
1.00
-0.30 1.00
-0.42 0.58 1.00
0.10 0.06 0.14 1.00
100
Zn
90
Rb
80 Al
Sr
Ti
K
70 Th
Zr
Mineralized shale: normalized
60
Pb
50
Mg
40
30
20
P
10
0
0 20 40 60 80 100 120
Unmineralized shale: normalized
11 12 13 14 15 16
% %oxide %oxide %oxide %oxide %oxide %element
TOC del13C Na Mg Al Si P S
DDH103 99.5 Fancy Hill 0.52 -25.5 0.72 2.51 21.43 57.71 0.15 0.13
DDH103 112.5 Fancy Hill 0.42 -25.7 0.61 2.57 20.71 59.42 0.11 0.58
DDH103 134.5 Fancy Hill 0.42 -27.8 0.56 1.75 14.58 70.10 0.08 2.29
DDH103 138 Fancy Hill 0.44 -28.2 0.66 1.81 15.10 68.66 0.08 2.86
DDH103 165.5 Fancy Hill 0.57 -27.0 0.77 2.38 17.35 62.49 0.12 0.73
DDH103 181 Fancy Hill 0.53 -25.8 0.63 2.81 21.95 53.78 0.39 0.80
DDH103 302.3 Fancy Hill 0.53 -26.1 0.69 2.94 20.37 56.92 0.14 0.94
DDH103 339.5 Fancy Hill 0.44 -27.7 0.77 2.68 17.22 58.63 0.09 2.49
DDH103 387.1 Fancy Hill 0.33 -26.6 0.91 2.96 18.72 60.95 0.11 2.83
DDH103 403.5 Fancy Hill 0.41 -27.8 0.86 2.91 17.75 60.53 0.10 5.07
DDH119 196.5 Fancy Hill 0.26 -30.1 0.31 2.22 13.68 63.72 0.06 3.38
DDH119 206 Fancy Hill 0.16 -27.4 0.01 0.09 1.25 81.10 0.03 9.65
DDH40 335 Fancy Hill 0.35 -26.5 0.88 2.87 18.64 60.80 0.11 2.48
DDH40 345 Fancy Hill 1.30 -30.2 0.65 2.17 15.81 59.98 0.22 3.36
DDH40 358.5 Fancy Hill 0.65 -29.2 0.32 1.19 9.51 69.95 0.08 5.13
DDH40 373.5 Fancy Hill 0.42 -27.9 0.66 2.69 16.40 65.20 0.09 1.80
DDH40 375 Fancy Hill 0.46 -27.7 0.46 2.31 14.72 69.02 0.06 1.64
DDH40 388.5 Fancy Hill 0.61 -26.9 0.13 1.90 13.46 70.28 0.08 4.42
DDH40 390 Fancy Hill 0.14 -26.3 0.31 2.16 15.72 69.15 0.05 0.54
DDH40 405 Fancy Hill 0.56 -28.0 0.20 2.41 19.94 55.87 0.07 1.44
DDH40 405.5 Fancy Hill 1.82 -29.0 0.17 2.84 19.79 55.54 0.07 3.28
MDDH5 220 1.34 -29.5 0.17 1.34 18.02 71.48 0.09 3.02
MDDH5 227.5 2.69 -30.0 0.18 0.90 18.60 57.89 0.15 2.87
MDDH5 229 0.28 -29.7 0.00 0.04 1.14 93.30 0.02 3.16
avg 0.65 -27.77 0.49 2.10 15.91 64.69 0.11 2.70
normalized 13.03 19.44 42.06 79.56 64.69 10.60 40.55
GWS 1 G&W Roofing 0.46 -26.5 0.68 2.78 18.67 60.58 0.20 0.03
GWS 2 G&W Roofing 0.54 -26.7 0.88 2.24 17.21 65.14 0.18 0.03
GWS 3 G&W Roofing 0.65 -26.9 0.81 2.73 22.76 54.86 0.34 0.03
GWS 4 G&W Roofing 0.53 -26.4 0.94 2.51 20.75 60.02 0.16 0.10
GWS 5 G&W Roofing 0.73 -27.0 0.76 2.72 20.55 58.01 0.17 0.01
GWS 6 G&W Roofing 0.69 -26.7 0.71 2.50 16.98 63.17 0.17 0.03
GWS 7 G&W Roofing 0.57 -26.4 0.79 2.36 21.36 58.81 0.23 0.03
GWS 8 G&W Roofing 0.75 -28.3 0.70 2.49 21.53 58.23 0.20 0.04
GWS 9 G&W Roofing 0.44 -26.4 0.89 2.26 19.91 62.21 0.18 0.03
GWS 12 G&W Roofing 0.43 -26.27 0.86 2.18 18.78 64.18 0.17 0.02
GWS 13 G&W Roofing 0.49 -26.56 0.81 2.70 20.01 58.82 0.17 0.02
GWS 15 G&W Roofing 0.50 -25.49 1.12 2.95 18.95 60.02 0.21 0.03
GWS 16 G&W Roofing 0.53 -26.11 0.66 2.76 18.62 59.38 0.27 0.07
avg 0.56 -26.59 0.82 2.55 19.70 60.26 0.20 0.04
normalized 11.29 32.64 51.04 98.50 60.26 20.37 0.53
19 20 22 23 24 25 26 27 28 29 30 37 38
%element %oxide %oxide %oxide ppm ppm %oxide %oxide ppm ppm ppm ppm ppm ppm
del34S K Ca Ti V Cr Mn Fe Co Ni Cu Zn Rb Sr
15.85 4.54 0.88 1.03 161 90 0.06 6.40 19 47 32 148 199 109
19.77 4.64 0.60 0.97 144 94 0.05 5.68 32 95 40 161 208 88
0.99 3.19 0.43 0.69 124 99 0.06 4.47 13 60 50 202 162 79
9.42 3.31 0.44 0.70 108 102 0.06 5.09 13 57 46 238 164 66
8.15 3.70 1.74 0.81 82 68 0.08 6.23 25 55 25 158 165 81
9.68 5.61 1.12 1.08 173 97 0.05 6.93 34 72 39 164 239 114
14.84 5.12 0.85 1.03 169 102 0.06 7.10 27 69 40 186 232 87
5.14 3.86 0.45 0.81 112 189 0.07 5.85 12 89 60 268 157 329
15.99 4.17 0.87 0.84 120 71 0.08 5.86 15 35 27 156 176 122
8.77 3.79 1.01 0.81 114 91 0.10 6.30 21 58 39 202 158 165
15.52 1.99 2.23 0.59 138 107 0.74 8.52 29 111 49 305 103 43
16.56 0.00 0.54 0.06 23 47 0.01 8.33 16 39 14 2 8 14
17.68 4.21 0.82 0.89 119 82 0.09 5.77 13 41 29 139 193 101
5.96 3.66 1.20 0.75 36 135 0.06 4.03 13 75 38 276 127 666
-3.94 2.15 1.29 0.49 5 71 0.04 2.89 8 43 38 91 58 727
11.71 3.20 1.27 0.72 117 94 0.10 5.47 14 60 29 165 146 111
9.87 2.97 0.57 0.68 161 132 0.07 5.20 12 64 64 172 146 73
15.01 2.83 0.34 0.64 160 163 0.04 5.42 18 77 175 251 138 45
19.30 3.38 0.30 0.79 122 111 0.06 4.65 11 47 37 163 161 52
19.62 4.16 0.37 0.90 189 241 0.20 6.35 21 97 121 354 170 63
20.93 4.37 0.33 0.89 231 520 0.13 6.32 22 158 516 441 177 47
7.73 3.65 0.63 0.88 176 217 0.05 3.60 24 104 73 2 174 108
-3.85 3.80 0.01 0.84 158 355 0.03 2.69 16 118 90 10 195 169
11.32 0.00 0.02 0.07 24 33 0.01 2.71 8 38 39 2 5 16
11.34 3.43 0.76 0.75 124 138 0.10 5.49 18 71 71.3 177 153 145
68.62 22.87 74.93 61.79 68.98 18.13 27.47 55 71 71.3 88.67 76.27 72.40
-4.45 2.92 1.07 0.84 130 86 0.04 8.64 21 54 34 254 121 105
5.80 3.08 0.68 0.84 116 93 0.03 6.26 13 47 21 77 152 112
-2.73 4.34 0.97 1.04 156 105 0.03 7.59 19 48 35 159 196 124
-3.91 4.03 0.74 1.00 153 100 0.11 5.60 30 90 46 283 202 116
-31.85 4.07 0.77 0.93 154 105 0.05 6.96 27 88 35 265 187 111
-2.47 2.69 1.11 0.83 113 88 0.09 8.24 16 60 31 159 132 97
-2.23 3.99 0.87 0.98 133 94 0.06 6.78 21 43 22 112 188 127
-1.55 4.06 0.79 1.00 131 95 0.04 6.95 20 46 26 174 185 118
-4.69 3.32 0.98 0.87 134 79 0.08 6.20 17 43 23 135 141 121
-5.01 3.02 0.89 0.82 112 85 0.04 6.11 14 34 19 117 140 120
-9.96 3.99 0.95 0.86 122 102 0.04 7.82 23 56 30 171 185 106
-3.92 3.30 1.02 0.92 142 99 0.04 7.52 33 66 36 143 151 120
-16.03 3.45 1.96 0.87 118 89 0.19 7.50 20 50 29 362 157 137
-6.38 3.56 0.98 0.91 132 93.85 0.07 7.09 21 56 30 185 164 116
71.18 29.51 90.71 65.92 46.92 12.39 35.45 63 56 29.8 92.73 82.19 58.23
40 42 56 82 90 92
ppm ppm ppm ppm ppm ppm
Zr Mo Ba Pb Th U
184 0.7 2915 20 16.1 1.9
170 0.3 3164 35 15.5 2.6
142 0.7 2744 17 11.4 2.2
135 0.05 2477 18 11 2.5
161 0.7 2912 42 12.4 1.9
168 0.4 4285 37 16.5 2
154 0.4 3292 27 15.8 3.5
146 0.9 30499 18 10.4 3.9
174 0.9 3674 22 13 2.1
131 2.4 8784 21 13 3.3
118 0.9 2729 15 8.9 2.2
30 2.9 542 6 4.2 2.1
144 0.4 3312 21 13.1 1.4
145 3.1 46808 13 9.5 5.4
120 1.4 72736 5 5.7 1.3
159 0.9 2957 20 12.7 5.5
132 0.5 2875 17 10.4 3.8
122 1.2 3220 16 9.6 2.9
154 0.5 3035 7 11.1 3.4
149 0.2 3834 8 11.3 3.7
153 0.3 5273 5 11.7 2.2
163 0.7 5374 27 12.8 3.9
165 3.2 6463 22 12.9 4.8
28 2.2 320 6 4.4 0.7
139 1.08 9343 18.54 11.39 2.88
69.73 21.54 93.43 55.63 68.35 57.67
151 0.7 591 30 12.2 2.8
158 0.3 696 16 13.7 2.2
177 0.5 853 22 15.4 3.4
188 0.5 845 14 15.7 2.8
160 0.3 836 29 15.5 2.6
156 0.5 579 25 12.7 3.1
173 0.8 840 20 16.5 3.3
178 0.05 847 19 15.2 3.8
210 0.5 685 25 13.8 2.3
219 1 597 17 14.2 1.8
142 0.1 982 17 16.5 3.3
156 0.2 634 21 14.6 0.1
154 0.1 607 33 13.1 3.6
171 0.43 738 22.15 14.55 2.70
85.46 8.54 7.38 66.46 87.3 54.00
Stanley Formation tuffs from Loomis et a.
Beavers Bend Beavers Bend
Beavers Bend Hatton Hatton Hatton Mud Creek
Constituentatomic no. T33 T34 T36 T39 T40 T42 T1
Na2O 11 1.78 2.4 0.72 4.7 3.66 4.47 2.48
MgO 12 1 0.62 1.06 0.29 0.35 0.46 1.26
Al2O3 13 14.1 9.8 13.2 13.0 11.3 14.0 14.4
SiO2 14 73.8 82.4 77.5 77.1 80.8 74.7 71.6
P2O5 15 0.07 0.03 0.04 0.03 0.02 0.03 0.12
K2O 19 4.04 1.79 4 2.09 2.06 2.71 1.77
CaO 20 1.06 0.62 0.01 0.16 0.01 0.78 3.09
Sc 21 8.9 5.9 8 6.5 5.6 7.5 9.2
TiO2 22 0.39 0.25 0.34 0.21 0.16 0.27 0.61
V 23 33 20 29 13 11 19 75
Cr 24 17 12 16 7 6 11 33
MnO 25 0.04 0.03 0.04 0.06 0.02 0.05 0.09
Fe2O3 26 3.68 2.12 3.12 2.41 1.58 2.56 4.59
Co 27 3.8 1.8 0.8 2 0.6 2.6 8.5
Zn 30 61 48 75 70 47 63 72
Rb 37 189 86 188 94 105 132 78
Sr 38 85 62 20 79 48 12 189
Y 39 28 26 35 29 30 35 25
Zr 40 230 172 217 160 147 209 235
Nb 41 11.3 10 12.3 10.8 10.6 13.2 11.1
Ba 56 721 30 753 616 440 649 1027
La 57 36.5 47.2 42.9 39.6 31.7 43.3 30.4
Ce 58 70.5 87.7 86.2 79.2 68.1 86.7 58.9
Nd 60 28.6 36.5 36.9 35.1 30.3 38.3 25.4
Sm 62 5.82 6.93 7.55 6.71 5.57 6.89 5.06
Eu 63 1.07 0.74 1.1 0.73 0.45 0.75 1.17
Tb 65 0.95 0.85 1.08 0.88 0.81 1.09 0.67
Yb 70 3.04 3.19 3.72 3.42 3.5 4.1 2.33
Lu 71 0.45 0.44 0.52 0.47 0.48 0.58 0.35
Hf 72 6.64 5.09 6.29 4.96 4.37 6.35 6.14
Ta 73 1.02 0.94 1.17 1.08 1.01 1.33 0.88
Pb 82 18 19 16 21 16 29 3
Th 90 16.1 17.3 20 20.2 19.7 25 11.6
Sc/Th 0.336 0.180 0.065 0.185 0.057 0.197 0.766
Zr/Hf 0.5 0.5 0.5 0.5 0.5 0.5 0.5
Nb/Y 0.404 0.385 0.351 0.372 0.353 0.377 0.444
Zr/TiO2 0.0590 0.0688 0.0638 0.0762 0.0919 0.0774 0.0385
log Nb/Y -0.3941 -0.4150 -0.4542 -0.4290 -0.4518 -0.4235 -0.3526
log Zr/TiO2 -1.2293 -1.1624 -1.1950 -1.1181 -1.0368 -1.1112 -1.4143
LOI 3.03 1.8 2.43 1.22 1.11 1.93 4.24
Mud Creek Mud Creek
T5NX T29 average
3.1 2.97 3.73
1.18 1.16 1.94
14.6 15.1 13.2
73.6 68.8 69.4
0.1 0.13 1.56
3.24 1.37 4.21
0.71 4.39 3.08
7.1 8.5 8.8
0.45 0.55 2.52
45 68 34
17 26 17
0.03 0.13 2.55
2.98 5.35 5.44
6.8 5.5 6
50 67 58
140 51 110
90 242 87
27 22 30
225 194 183
11.2 9.1 14
802 3445 854
39.1 30.5 39.8
69.6 58.5 72.3
28 25.2 34.4
5.08 5.05 11.7
1.23 1.33 7.16
0.75 0.73 7.28
2.76 2.3 9.84
0.41 0.32 7.50
5.64 5.03 12.3
0.99 0.78 8.2
21 18 24.3
17 9.84 24.7
0.607 0.604 0.333
0.6 0.5 0.513
0.415 0.414 0.391
0.0500 0.0353 0.062
-0.3821 -0.3834 -0.410
-1.3010 -1.4526 -1.225
2.71 4.58
Ouachita B
PalosVerdes rooks Range
Nb/Y Zr/TiO2 log Nb/Y log Zr/TiO2
Arkansas 0.404 0.059 -0.394 -1.229 0.404 0.059
0.385 0.069 -0.415 -1.162 0.385 0.069
0.351 0.064 -0.454 -1.195 0.351 0.064
0.372 0.076 -0.429 -1.118 0.372 0.076
0.353 0.092 -0.452 -1.037 0.353 0.092
0.377 0.077 -0.423 -1.111 0.377 0.077
0.444 0.039 -0.353 -1.414 0.444 0.039
0.415 0.050 -0.382 -1.301 0.415 0.050
0.414 0.035 -0.383 -1.453 0.414 0.035
CA 0.468 0.011 -0.330 -1.961 0.468 0.011
0.956 0.011 -0.019 -1.957 0.956 0.011
0.422 0.013 -0.375 -1.883 0.422 0.013
0.462 0.011 -0.335 -1.945 0.462 0.011
0.454 0.008 -0.343 -2.115 0.454 0.008
0.945 0.010 -0.025 -2.006 0.945 0.010
0.694 0.024 -0.159 -1.622 0.694 0.024
0.796 0.024 -0.099 -1.615 0.796 0.024
0.412 0.013 -0.385 -1.902 0.412 0.013
0.675 0.015 -0.171 -1.829 0.675 0.015
0.580 0.011 -0.236 -1.974 0.580 0.011
0.650 0.015 -0.187 -1.829 0.650 0.015
0.320 0.014 -0.495 -1.850 0.320 0.014
0.651 0.014 -0.186 -1.843 0.651 0.014
0.337 0.013 -0.472 -1.903 0.337 0.013
0.298 0.014 -0.525 -1.866 0.298 0.014
0.549 0.018 -0.261 -1.756 0.549 0.018
0.460 0.017 -0.338 -1.774 0.460 0.017
0.593 0.017 -0.227 -1.777 0.593 0.017
0.301 0.013 -0.521 -1.890 0.301 0.013
0.257 0.013 -0.590 -1.873 0.257 0.013
0.630 0.018 -0.200 -1.748 0.630 0.018
0.525 0.011 -0.280 -1.944 0.525 0.011
Alaska 2.889 0.050 0.461 -1.300 2.889 0.050
2.690 0.054 0.430 -1.268 2.690 0.054
3.182 0.050 0.503 -1.302 3.182 0.050
4.473 0.129 0.651 -0.889 4.473 0.129
7.357 0.168 0.867 -0.775 7.357 0.168
2.875 0.021 0.459 -1.674 2.875 0.021
2.542 0.069 0.405 -1.160 2.542 0.069
0.257 0.008
Brooks Range
1.0
Ouachitas
Palos Verdes
Brooks Range
0.0
Zr/TiO2 %
-1.0
-2.0
-3.0
-2.0 -1.0 0.0 1.0 2.0
Nb/Y ppm