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Is the Reaction Endothermic or Exothermic? - Using Bond Energies









Click on the calculation

tab and see the calculation

set up for this reaction.



This extends the molecules

in a box approach done in

class.



You may type in the yellow

areas only or use the arrows.









Sinex 2003

Is the Reaction Endothermic or Exothermic? - Using Bond Energies

In the yellow areas, enter the bond, number of bonds either broken or formed, and the their bond energy.



bonds breaking bonds forming

# #

bond number of bonds bond energy* bond number of bonds bond energy*

N=-N 1 942 942 N-H 6 386 2316

H-H 3 432 1296 0

0 0

0 0

0 0

total energy 2238 total energy 2316

for bond breaking (absorbed) for bond forming (released)

#

atoms & type (single, double, triple) energy released is given a negative sign -2316



*Bond energies can be Energy difference (DH) = -78 Is energy released?

found in your textbook endothermic positive

or at the : Wired Chemist. exothermic negative Is the reaction endothermic or exothermic?

(This is an estimate of DH.)

See graphical displays below

scroll down! Sinex 2003

Just comparing totals: Using convention of negative sign for energy given off:

Which is larger? products if difference is negative - exothermic

exothermic if difference is positive - endothermic



3000

reactants 2238









endothermic

2500

reactants

2000 2238 products -2316 These graphs will

2000

Bond energy









products 2316 difference -78 respond to changes

1500

in the bond energy

1000 1000

calculator above!!!









Bond energy

500

0

0 reactants products difference

reactants products -1000



if reactants > products: endothermic -2000





exothermic

if products > reactants: exothermic

-3000







Sinex 2007



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