جهبس شئون البيئة
المشروع المصرى للحد من التلوث
دليل الزصد الذاتى
صىبعة المىتجبت المعدوية
مراجعة: إعداد:
د. سميز الموافى د/ حسه الحبرس
د. أحمد جمبل عبد الزحيم
يناير 3002
5 1
6 1 1
6 1 1 1
7 2 1 1
8 2 1
8 1 2 1
8 2 2 1
10 2
10 1 2
12 2 2
15 1 2 2
17 2 2 2
20 3 2 2
33 3 2
33 1 3 2
34 2 3 2
35 3 3 2
35 4 3 2
35 5 3 2
36 6 3 2
36 7 3 2
36 8 3 2
38 4 2
38 1 4 2
38 2 4 2
39 3 4 2
42 3
43 1 3
44 2 3
51 3 3
54 4
54 1 4
2
56 2 4
60 3 4
61 4 4
63 5 4
63 6 4
64 5
64 1 5
67 2 5
67 1 2 5
69 2 2 5
73 3 2 5
79 4 2 5
81 3 5
82 6
82 1 6
83 2 6
84 3 6
84 EMS 1 3 6
87 2 3 6
90 3 3 6
90 4 6
90 1 4 6
91 2 4 6
93 7
96 1 7
96 2 7
97 3 7
98 4 7
99 5 7
99 1 5 7
102 Mass balance 2 5 7
103 Emission factors 3 5 7
3
103 4 5 7
104 8
104 1 8
105 2 8
106 3 8
107 9
107 1 9
110 2 9
112 10
112 1 10
113 2 10
118 3 10
119 11
119 1 11
119 2 11
121 1 2 11
121 2 2 11
122 3 2 11
122 4 2 11
122 5 2 11
122 6 2 11
4
-1
EPAP
FINNIDA
EPAP FINNIDA
(GIM, EPAP-2002)
5
-
11
EPAP
1 1 1
6
2 1 1
7
2 1
1 2 1
3800 ISIC
2 2 1
95
8
60
3800 ISIC
50 50
3.6 750
34 53
22.000
5.500
3.800 BOD
7.800 COD
2.100
3
1994 4 5
3
16 14
3 3 3
35 9
75
115
50 1994 4
100
9
2
1 2
1
ethylene-glycol
Workpiece
metal cutting tools
10
trichloroethane, methyl ethyl ketone
(VOC
1،1،1
Softness
11
1
emulsion
surfactants
Anodizing
Chemical conversion coating
Electroplating
Plating
Painting
2 2
2
1
12
2
-
-
-
-
-
-
-
-
-
-
-
13
1
VOC
VOC
Metal
Complexes
14
( Metal shaping) 1 2 2
(Casting )
(Shearing)
(Punching)
(Parting) (Cutoff) (blanking) (Piercing)
(Trimming)
(bending)
(Rolling) (Drawing) (Extrusion) (Forming )
(Forging) (Coining)
extruding
15
(milling) (drilling) (Machining)
(Grinding) (Sawing)
16
( Surface preparation) - -
222
sand blasting
silicosis
17
1
2
5
95 80
surfactants
18
1,1,1
(Pickling
19
…
3
3
3 2 2
20
2
2
21
22
(Complexes)
23
3
24
25
3
Electroless
plating
26
4
27
4
28
29
(Polishing)
(Polishing)
(hot dipping)
(Galvanization)
5
(Etching)
(etching)
etching
Polishing
30
etching
31
AGM
5
32
3 2
6
1 3 2
(Calcination)
33
2 3 2
(Resins) (Softener)
(Cation exchange)
6 (pH) (back wash)
8
(Hardness)
35
(ultra-filtration)
(Sludge)
(Water Softening)
(Reverse osmosis)
34
(Cooling Towers) 3 3 2
make-up water
4 3 2
…
1994 4
5 3 2
35
6 3 2
1994 4
7 3 2
8 3 2
36
6
37
38
4 2
4
1 4 2
10
2 4 2
39
3 4 2
40
4
VOC
VOC
41
VOC
(Etching)
42
3
43
1 3
1993 Toxic Release Inventory TRI
1,1,1
44
TRI
TRI
1,1,1
2 3
EPA
HSDB
45
46
1
47
DCM
DCM
DCM
48
MEK
TCE 1,1,1
49
TCE
ثالثي كلوريد
اإليثيلين
05
51
52
3 3
765 BOD
1524 COD
53
18.2
72
1128 TSS
196 O&G
10 pH
500
BOD
O&G COD
54
55
4
1 4
42 1994 4 40
6
1.5
15000 7000
36 18
56
15000
5،6
5
3
2500 4000
2500 4000
250 250
500 500
250 250
6
3
3400
250
50
57
2 4
residual chlorine
7
8
58
7
1982 48
1962 93
1994 4
2000 44
60 60 30 20 600 60 5 BOD
100 80 40 30 1100 100 COD
9 6 9 6 9 6 9 6 9.5 6 9 6 pH
10 10 5 5 100 15
43 10
35 35 35 35
60 50 30 30 800 60
20 10 3 8
30 3 15
2000 2000 1200 800 2000
10 1 5
25
59
8
1982 48
1962 93 4
1994
2000 44
3
40 50 30 30 40
0.005 0.002 0.001 0.05 1
0.5 0.5 0.5 1
1 1 1 1 10 1
1 1
0.05 0.05
5000 5000 2500 2500 5000 3 100
3
0.05 0.05 2 0.05
2
0.2 0.1
100
60
8
1982 48
1962 93
1994 4
2000 44
0.01 0.01 0.2 0.05
1
1 1 1 0.5
1 1 1.5 1.5
1 1 1.5
0.05 0.05 1 0.5
0.5 0.5 1
0.001 0.001 0.2 0.005
0.1 0.1 1 0.1
0.05 0.05 0.5 0.1
1 1 5
1 1 1 1 0 5
0.01
61
Parcom Helcom
0.2 0.2
0.05 0.05
0.5 0.7
0.1 0.2
0.5 0.5
0.5 0.5
0.5 1
0.1 0.2
0.5 2
2
0.2 0.2
0.1 0.1
2
3 4
1967 38
134
1968
62
1967 38 1976 31
1979 43
38 37 1994 4
4 4
4 43
9 8 45 1994
10 1994 4
4 44
9 46 1994
45 1994 4 43
8
44 1994 4 42
7 1
63
47 1994 4 45
48 1994 4 46
1981 52
380 1981 137
1982 380 1983
9
3 3
27000 15000 9000 5000
440 400 55 50
10 5 5 2
10
3 3
2375 1000 1780 750
20 10
5
27000 15000 9000 5000
440 400 55 50
125 50 125 50
885 300 590 200
805 150 270 50
10 5
655 150 435 100
64
5
65
5 4
1994 4
33 29
1995 338 32 31 25
25
6 4
17 22 1994 4
66
5
-
15
in-plant modifications
in-process modifications
End-of-pipe
4
1994
67
end-of-pipe
Waste Segregation
Recycling
batch
68
69
2 5
6
1 2 5
1
1
2
3
4
5
6
7
70
8
9
1
2
1
2
3
1
2
3
71
4
5
coalescing unit
2 2 5
1
up-
stream operations
1
Counter Current 2
flow)
3
4
1
FREEBOARD
100
72
3
2
3
1
2
3
2
4
1
2
VOC
73
3
4
5
6
1
2
3
surfactants
fog spray rinsing technique
74
4
5
6
7
8
9
1
2
2 4
3
4
5
75
1
2
3
electrolysis
4
5
6
7
3 2 5
1
1
1
76
2
flow restrictors
3
20 10
4
77
5
6
1
fluoborate copper
2
3
chelating agents 4
1،1،1 5
1
6
7
1
78
-
-
Holding Tanks
-
1
2
3
4
5
6
7
92 8
95
electrodialysis 9
10
79
80
1
2
3
1
2
1
2
3
4
curing oven
1
81
30
87
1
1
2
stripping
3
hydrolysis
1
2
resins
3
4
5
1
82
1
1
1
2
4 2 5
83
End-of-
pipe
equalization)
11 8.5
Filter Press
Metal Complexes
84
CIP
3 5
85
6
SMS
1 6
Trends
86
2 6
1994 4
87
3 6
EMS 1 3 6
ISO 14000
7
88
1
aspects 2
objective
target
25
3
4
internal auditing
5
89
ISO 14000 7
Environmental Policy
Management Planning
Review
Continuous Improvement
Internal Auditing Implementatio
n
90
EMS SM 2 3 6
ISO 14000
SMS
end-of-
pipe
•
•
•
•
•
•
•
91
•
•
•
•
•
8
SMS EMS
92
SMS EMS
SMS EMS 8
93
3 3 6
end-of-pipe
Cost benefit analysis
4 6
1 4 6
1994 4
94
•
•
•
2 4 6
QA/QC
•
•
•
•
95
96
7
•
•
•
•
•
•
•
QC QA •
97
9
98
Objectives
9
99
1 7
11
11
BOD
COD)
2 7
100
EPAP 1999
•
•
•
trends
3 7
•
•
•
•
•
•
•
•
101
4 7
trends •
•
•
time-averaged means
frequency distribution
daily mean value
17 1994 4 22 10
•
•
•
•
102
5 7
•
Mass balance •
Emission Factors •
•
1 5 7
103
99 99
•
•
corrosive substances
•
•
surrogate parameters
12
•
104
VOCs
•
•
•
•
•
12
• •
•
•
• •
SO2
• •
•
•
dioxin
•
•
105
Mass balance 2 5 7
106
Emission factors 3 5 7
DSS
4 5 7
107
8
1 8
13
13
Indication
108
2 8
14
14
Indication
109
3 8
15
15
Indication
110
111
9
1 9
16
112
16
113
16
114
2 9
•
•
•
•
17
115
17
116
10
18 4 2
18
3 2 2 2
1 10
Cl, CO2, CO, SO2 , NOx
117
SOx
CO2
2 10
COD / BOD5, TSS, AOX
3 Q •
TSS •
C •
mgO2/l. CODCr •
mgO2/l. BOD5) •
N •
Cr •
•
118
mS/m •
Venturi
grab sample
24
119
7 5 24
TSS,COD
BOD5
BOD5, COD
120
121
18
122
18
123
3 10
•
•
•
•
124
11
QA/QC
1 11
10
2 11
125
10
126
1 2 11
•
•
•
•
•
2 2 11
EPAP
1994 4
1994 4
127
3 2 11
4 2 11
5 2 11
128
6 2 11
129
Reliability 1
10
20 2
1 -أ
Comparability 2
Data Production Chain 3
2 -أ
pH
3 -أ
4 3
O2 ppm 3
Residence time
C
4 -أ
Quality Control and Quality Assurance 4
Certification
Certification and Accreditation
5 -أ
94 4
-1
-2
-3
-4
-5
-6
-7
17
27
37
47
-8
18
28
-9
- 10
- 11
1 -ة
4 49 71
84 2891 13 7691 4 4991 39 2691 83 7691
3
4 49
1
1 1
1 2
1 3
2
2 1
2 2
ة- 2
2
1:00002
1:005 1:0001
2 3
2 4
3
3 1
3 2
3 3
3 4
ة- 3
4
5
1 5
2 5
3 5
4 5
6
1 6
1 1 6
4 -ة
2 1 6
3 1 6
4 1 6
2 6
1 2 6
mg/l
m3/d
kg/d
2 2 6
5 -ة
6 2 3
6 3
6 3 1
6 3 2
6 4
6 4 1
6 4 2
6 5
6 5 1
6 5 2
ة- 6
7
7 1
7 2
7 3
7 4
7 5
7 6
ة- 7
2002 1
1- “Monitoring and Control Practices of Emissions in Pulp and Paper Industry
in Finland”, 1998, Saarinen K., Jouttijarvi T. and Forsius K., Saarinen K.,
Finnish Environment Institute
2- “Data Production Chain in Monitoring of Emissions”, 1999, Saarinen K,
Finnish Environment Institute.
1