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Philip Hofmann

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• lectures accompanying the book: Solid State Physics: An

Introduction,by Philip Hofmann (1st edition, October 2008,

ISBN-10: 3-527-40861-4, ISBN-13: 978-3-527-40861-0,

Wiley-VCH Berlin.









www.philiphofmann.net

1

README







• This is only the outline of a lecture, not a final product.

• Many “fun parts” in the form of pictures, movies and

examples have been removed for copyright reasons.

• In some cases, www addresses are given for particularly

good resources (but not always).

• I have left some „presenter notes‟ in the lectures. They are

probably of very limited use only.









2

Mechanical properties of solids









3

Mechanical properties of solids: contents

at the end of this lecture you should understand....





• basic definitions: stress and strain

• elastic and plastic deformation, fracture

• macroscopic picture for elastic deformation: Young‟s

modulus, Hooke‟s law, Poisson‟s ratio, shear stress,

modulus of rigidity, bulk modulus.

• elastic deformation on the microscopic scale, forces

between atoms.

• atomic explanation of shear stress / yielding to shear stress,

dislocations and their movement

• plastic deformation, easy glide, work hardening, fracture

• brittle fracture, brittle-ductile transition 4

Basic definitions

wire under tensile stress



stress: force on an

object per area

perpendicular to force



unit: Pa (or MPa)





strain: length change relative

to absolute length



unit: dimensionless

technical: m/m



5

Basic definitions

tensile stress compressive stress

Elastic and plastic deformation, fracture

what happens when the tensile stress is increased?



1. elastic deformation (reversible)

2. plastic deformation (irreversible)

3. fracture





Materials which show plastic

deformation are called ductile.



Materials which show no plastic

deformation are called brittle.





7

stress/strain curve for a ductile metal









8

Macroscopic picture: elastic deformation

the linear region









behaviour is linear and reversible

for a strain of up to 0.01 or so

9

Young‟s modulus





stress: force on an

object per area









strain: length change relative Young‟s modulus

to absolute length









unit: Pa

10

Young‟s modulus and Hooke‟s law









Young‟s modulus Hooke‟s law









stress strain



11

Young‟s

modulus









12

Poisson‟s ratio









Poisson‟s ratio









ν≤0.5 This means that the volume of

the solid always increases

under tensile stress

13

Poisson‟s ratio









the volume is (assume the extensions are small)







change in volume









and since it follows that ν≤0.5

14

Poisson‟s ratio

• There is also a lower limit to the Poisson ratio. We get

-1 0.5

compressive stress: volume increase



ν = 0.5 no volume change, incompressible solid



“normal” case for most materials, volume increase upon tens.

0 the

yield stress decreases.

• At high temperature (50%

of the melting temperature),

the thermally elevated

movement of dislocations

gives rise to creep

(permanent deformation).

Can be important because

accumulative (in jet engines,

walls of fusion reactors....).



36

Plastic deformation: Easy glide









• once the yield stress is overcome, dislocation-assisted glide

sets in.

• the stress increases only slightly. 37

Plastic deformation: work hardening









• In the work hardening zone, the stress is increasing again.

• It is as if the easy glide process doesn‟t work anymore. 38

Plastic deformation: work hardening









example pictures









• At increased strain, the number of dislocations is increased.

• They start to prevent each other‟s free movement.

39 39

Plastic deformation: work hardening









• pre-straining a material can be used to increase the yield

stress (the elastic limit). 40

Plastic deformation: Fracture









• Close to fracture the stress is actually reduced. Why?

41 41

Plastic deformation: Fracture

necking









small A, large A,

high σ small σ







• Higher stress at the neck even if the overall stress is reduced.

• This is also why necks are self-amplifying.

42 42

Brittle fracture





• No transition to plastic

deformation before

fracture.

• Fracture stress should

correspond to pulling

the atomic layers apart

but it is often much

smaller. Why?









43

Brittle fracture: crack propagation

F









• Close to a crack of radius r and depth l, the stress is locally

increased, approximately by a factor

• This is not the same a necking but a local phenomenon!

• It is self-amplifying and if the stress is high enough, the

crack propagates with a very high speed.

44

Stress close to a very small crack









DFT calculation of this, e.g. from tcm.phy.cam.ac.uk









45

Brittle or ductile?





• Competition between stress relieve by propagating cracks

and stress relieve by moving a dislocation.

• Dislocation movement easy in metals or when molecules

can be shifted against each other. Difficult for ionic or

strongly covalent materials.

• Dislocation movement strongly temperature dependent but

crack propagation not: materials can be ductile at high

temperature and brittle at low temperature (for example,

glass or steel).





46

Not so useful example of brittle fracture









include picture of fractured Liberty Ship









47

Finally a word of caution...







• We have consider only the basic properties in a very simple

way.

• We have looked at simple stress and shear stress. In a more

formal treatment these become different aspects of the same

thing.

• We only looked at an isotropic solid (ok for metals but not

form many other materials, e.g. graphite or wood).







48 48



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